JP6841614B2 - 水性被覆材 - Google Patents
水性被覆材 Download PDFInfo
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- JP6841614B2 JP6841614B2 JP2016156335A JP2016156335A JP6841614B2 JP 6841614 B2 JP6841614 B2 JP 6841614B2 JP 2016156335 A JP2016156335 A JP 2016156335A JP 2016156335 A JP2016156335 A JP 2016156335A JP 6841614 B2 JP6841614 B2 JP 6841614B2
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- RWLALWYNXFYRGW-UHFFFAOYSA-N 2-Ethyl-1,3-hexanediol Chemical compound CCCC(O)C(CC)CO RWLALWYNXFYRGW-UHFFFAOYSA-N 0.000 description 1
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- AJKXDPSHWRTFOZ-UHFFFAOYSA-N 2-ethylhexane-1,6-diol Chemical compound CCC(CO)CCCCO AJKXDPSHWRTFOZ-UHFFFAOYSA-N 0.000 description 1
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- CRWNQZTZTZWPOF-UHFFFAOYSA-N 2-methyl-4-phenylpyridine Chemical compound C1=NC(C)=CC(C=2C=CC=CC=2)=C1 CRWNQZTZTZWPOF-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
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- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/028—Pigments; Filters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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Description
1. 吸放湿性を有する水性被覆材であって、
合成樹脂エマルション(A)、
平均粒子径5μm以上200μm以下の吸放湿性粉体(B)、
平均粒子径0.4μm以上80μm未満、屈折率1.4以上2.0以下の粉粒体(C)、及び
平均粒子径80μm以上の骨材(D)を含み、
上記吸放湿性粉体(B)は、ベーマイト、シリカゲル、ゼオライト、硫酸ナトリウム、アルミナ、アロフェン、珪藻土、珪質頁岩、セピオライト、アタバルジャイト、モンモリロナイト、ゾノライト、イモゴライト、大谷石粉、活性白土、木炭、竹炭、活性炭、木粉、貝殻粉、多孔質合成樹脂粒から選ばれる1種以上を含み、
上記骨材(D)は、少なくとも2種以上の異色の着色骨材、または着色骨材と透明性骨材を含み(ただし、珪質頁岩を除く)、
上記粉粒体(C)と上記骨材(D)との重量比[(C)/(D)]が0.1/1〜10/1であることを特徴とする水性被覆材。
2.上記合成樹脂エマルション(A)の固形分100重量部に対し、
上記吸放湿性粉体(B)を5重量部以上500重量部以下、
上記粉粒体(C)及び上記骨材(D)を合計で100重量部以上3000重量部以下含有することを特徴とする1.記載の水性被覆材。
吸湿率(%)={(吸湿後の重量−乾燥後の重量)/乾燥後の重量}×100
表1に示す原料を用い、表2に示す配合にて各原料を常法にて混合攪拌し、水性被覆材を製造した。
上記試験体の仕上外観を目視にて評価した。評価は、自然石調の多色感を有するものを「A」、多色感に欠くものを「C」とする3段階評価(A>B>C)で行った。
上記試験体の側面及び裏面をアルミニウム粘着テープでシールした後、JIS A6909:2014「建築用仕上塗材」7.29の手順によって、吸放湿量(g/m2)を測定した。評価基準は、次の通りである。結果は表2に示す。
A:吸放湿量80g/m2以上
B:吸放湿量70g/m2以上80g/m2未満
C:吸放湿量60g/m2以上70g/m2未満
D:吸放湿量60g/m2未満
製造後50℃環境下で7日間保管した水性被覆材を用いた以外は、上記吸放湿性1と同様の方法で試験体を作製し、吸放湿量を測定した。結果は表2に示す。
表2に示す配合以外は、実施例1と同様の方法で水性被覆材を製造し、実施例1と同様の試験を行った。結果は表2に示す。
Claims (2)
- 吸放湿性を有する水性被覆材であって、
合成樹脂エマルション(A)、
平均粒子径5μm以上200μm以下の吸放湿性粉体(B)、
平均粒子径0.4μm以上80μm未満、屈折率1.4以上2.0以下の粉粒体(C)、及び
平均粒子径80μm以上の骨材(D)を含み、
上記吸放湿性粉体(B)は、ベーマイト、シリカゲル、ゼオライト、硫酸ナトリウム、アルミナ、アロフェン、珪藻土、珪質頁岩、セピオライト、アタバルジャイト、モンモリロナイト、ゾノライト、イモゴライト、大谷石粉、活性白土、木炭、竹炭、活性炭、木粉、貝殻粉、多孔質合成樹脂粒から選ばれる1種以上を含み、
上記骨材(D)は、少なくとも2種以上の異色の着色骨材、または着色骨材と透明性骨材を含み(ただし、珪質頁岩を除く)、
上記粉粒体(C)と上記骨材(D)との重量比[(C)/(D)]が0.1/1〜10/1であることを特徴とする水性被覆材。 - 上記合成樹脂エマルション(A)の固形分100重量部に対し、
上記吸放湿性粉体(B)を5重量部以上500重量部以下、
上記粉粒体(C)及び上記骨材(D)を合計で100重量部以上3000重量部以下含有することを特徴とする請求項1記載の水性被覆材。
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JP2002080798A (ja) | 2000-06-28 | 2002-03-19 | Sk Kaken Co Ltd | 吸放湿性塗料組成物及び吸放湿性シート |
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JP3827305B2 (ja) * | 2002-01-31 | 2006-09-27 | エスケー化研株式会社 | 内装用水性塗料組成物 |
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