WO2007114078A1 - アルミニウム合金鍛造部材およびその製造方法 - Google Patents
アルミニウム合金鍛造部材およびその製造方法 Download PDFInfo
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- WO2007114078A1 WO2007114078A1 PCT/JP2007/056024 JP2007056024W WO2007114078A1 WO 2007114078 A1 WO2007114078 A1 WO 2007114078A1 JP 2007056024 W JP2007056024 W JP 2007056024W WO 2007114078 A1 WO2007114078 A1 WO 2007114078A1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21K—MAKING FORGED OR PRESSED METAL PRODUCTS, e.g. HORSE-SHOES, RIVETS, BOLTS OR WHEELS
- B21K1/00—Making machine elements
- B21K1/06—Making machine elements axles or shafts
- B21K1/12—Making machine elements axles or shafts of specially-shaped cross-section
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/05—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys of the Al-Si-Mg type, i.e. containing silicon and magnesium in approximately equal proportions
Definitions
- the present invention has high strength and high toughness and excellent corrosion resistance such as stress corrosion cracking resistance.
- the present invention relates to an aluminum alloy forging used for automobile undercarriage parts and the like and a manufacturing method thereof (hereinafter, aluminum is also simply referred to as A1).
- A1 such as 6000 series (A ⁇ Mg-Si series) in the AA or JIS standards, especially as structural parts or structural parts of transport equipment such as automobiles, especially as suspension parts such as upper arms and lower arms. Alloy forging is used. 6000 series A1 alloy forgings have high strength, high toughness and relatively excellent corrosion resistance. In addition, the 6000 series A1 alloy itself is also excellent in recyclability in that the scrap with a small amount of alloy elements can be reused again as a 6000 series A1 alloy melting raw material.
- These 6000 series A1 alloy forging materials are subjected to homogenization heat treatment of A1 alloy forging materials, followed by hot forging (die forging) such as mechanical forging and hydraulic forging, followed by solution treatment and quenching treatment.
- a so-called tempering treatment with an artificial age hardening treatment is performed.
- an extruded material obtained by once extruding the forged material may be used as the forging material.
- Suspension and other undercarriage parts are required to have materials that achieve high strength, high toughness, and high corrosion resistance.
- the aluminum alloy forged material is superior in strength and high in reliability compared with the aluminum alloy forged material.
- the A1 alloy forged material has higher strength and higher strength.
- Toughness has also been proposed. These controls can improve corrosion resistance against intergranular corrosion and stress corrosion cracking.
- transition elements having a grain refinement effect such as Mn, Zr, Cr, etc. are added to refine the grains or sub-grains. Improvement of fracture toughness and fatigue properties is also described in these proposals (see Patent Documents 3, 4, and 5).
- transition elements having a crystal grain refining effect such as Mn, Zr, and Cr are added, and 450 to 570 are added. It is known to start hot forging at a relatively high temperature of ° C (see Patent Documents 6 to 7 and 8 to 10).
- Patent Document 1 JP 07-145440 A
- Patent Document 2 Japanese Patent Laid-Open No. 06-256880
- Patent Document 3 JP 2000-144296 A (Registration 3684313)
- Patent Document 4 Japanese Patent Laid-Open No. 2001-107168
- Patent Document 5 JP 2002-294382 A
- Patent Document 6 Japanese Patent Laid-Open No. 5-247574
- Patent Document 7 Japanese Patent Laid-Open No. 2002-348630
- Patent Document 8 Japanese Unexamined Patent Application Publication No. 2004-43907
- Patent Document 9 JP-A-2004-292937
- Patent Document 10 Japanese Patent Application Laid-Open No. 2004-292892
- Automotive undercarriage parts such as suspension arms also have a component force having an arm portion and a ball joint portion on one end side of the arm portion.
- These automobile undercarriage parts in particular, have a relatively narrow and thick peripheral rib and a relatively thin central part in order to achieve light weight while giving a predetermined strength. It has a substantially H-shaped cross-sectional shape consisting of a web.
- the web in order to further reduce the thickness and weight of automobile undercarriage parts while maintaining rigidity, etc., in order to further reduce the weight of the automobile, the web must be made thinner and necessary. Accordingly, it is necessary to increase the width according to the shape, further reduce the width and thickness of the ribs, and reduce the weight (hereinafter also referred to as the “weight-reduced shape”). For this reason, automobile undercarriage parts having thin arm parts with a web wall thickness of 10 mm or less have begun to be adopted.
- the maximum stress is applied to an arm portion having a substantially H-shaped cross-sectional force formed by such a rib and a thin web during use.
- the part of the arm where the maximum stress is applied also depends on the overall shape of the automobile underbody parts and the shape requirements such as the wall thickness. However, the maximum stress is generated in the part of the arm that is determined by the overall shape and shape requirements, not the other joints.
- the degree of processing of the thinner web portion and the further narrower and thicker rib portion tends to be larger (stricter). For this reason, at the temperature for hot forging, the thinned web part and the narrower and thicker rib part have coarse crystal grains (crystal grains) recrystallized at the parting line and in the vicinity thereof. There is a problem that it is more likely to occur.
- an object of the present invention is to provide an aluminum alloy forged member that has high strength, high toughness, and high corrosion resistance even in a lightweight bowl shape. It is.
- the summary of the aluminum alloy forged material of the present invention is mass%, Mg: 0.5-1.25%, Si: 0.4-1.4%, Cu: 0.01-0.7%, Fe: 0.05- 0.4%, Mn: 0.001 to 1.0%, Cr: 0.01 to 0.35%, Ti: 0.005 to 0.1%, respectively, and Zr: Less than 0.15%, the balance is made of Al and inevitable impurities.
- Narrow and thick! Aluminum alloy forging with an approximately H-shaped cross section in the width direction, consisting of a peripheral rib and a relatively wide central web.
- the crystallized density observed in the structure of the cross-sectional part where the maximum stress is generated is 1.5% or less in average area ratio, including the parting line generated during forging
- the interval between the grain boundary precipitates observed in the structure of the cross-sectional site is assumed to be 0.7 m or more in average interval.
- the aluminum alloy forged material of the present invention has a cross-sectional portion where the maximum stress is generated in the cross-sectional structure in the width direction at the maximum stress-generating portion of the rib.
- the size of the dispersed particles observed in the structure of the above is 1200 A or less in average diameter, and the density of these dispersed particles is 4% or more in average area ratio, and the recrystallization observed in the cross-sectional structure of these ribs
- the area ratio occupied by the grains is 10% or less in terms of the average area ratio, and the area ratio occupied by the recrystallized grains observed in the cross-sectional structure in the width direction of the web adjacent to the cross-sectional structure of these ribs is the average area ratio. It is preferably 20% or less.
- the above-mentioned crystallized substance density is preferably 1.0% or less in terms of the average area ratio, and the distance between the above-mentioned grain boundary precipitates is preferably 1.6 m or more in terms of the average distance.
- the aluminum-forum alloy forging material in the component composition of the molten aluminum alloy described later, Mg: 0.7-1.25%, Si: 0.8-1.3%, Cu: 0.1-0.6%, Fe: 0.1-0.4%, Mn: 0.2-0.6%, Cr: 0.1-0.3%, Ti: 0.01- It is preferable that each element contains 0.1% and is restricted to Zr: less than 0.15%, and the balance is made of Al and inevitable impurities.
- Mg 0.9-ll%
- Si 0.9-ll%
- Cu 0.3-0.5%
- Fe 0.1-0.4%
- Mn 0.2-0.6%
- Cr 0.1-0.2%
- Ti It is preferable that the content of each element is 0.01 to 0.1% and that Zr is limited to less than 0.15% and the balance is made of Al and inevitable impurities.
- the present invention is preferably applied to a forged aluminum alloy material in which the web has a thin wall thickness of 10 mm or less.
- the main point of the method for producing an aluminum alloy forged material of the present invention for achieving the above-described object is the method for producing an aluminum alloy forged material according to the above-mentioned summary or a preferred summary described later,
- This forged mass is heated in a temperature range of 460 to 570 ° C at a heating rate of 10 to 1500 ° C / hr and subjected to a homogenization heat treatment that keeps this temperature range for 2 hours or more.
- the forging end temperature is 350 ° C or higher,
- quenching is performed at an average cooling rate in the range of 200 to 300 ° C / s, and further, artificial age hardening is performed.
- the cross-sectional structure in the width direction of each of the specific portions of the rib at the portion of the rib where the maximum stress is generated in the arm portion of the aluminum alloy forging material having a light and bowl shape is as described above. It stipulates.
- the components are adjusted and manufactured so that the cross-sectional structure in the width direction of each specific portion of the rib at the portion where the maximum stress of the rib is generated in the arm portion of the forged aluminum alloy forged material becomes the structure described above.
- the present invention suppresses the coarsening of crystal grains in the rib part and the web part during forging, particularly in a specific part where the maximum stress is generated in the aluminum alloy forged material arm part having a light and bowl shape. To do.
- this increases the strength, the high toughness, and the high corrosion resistance of the maximum stress generating portion of the arm portion, which will be described later, which should have strength.
- an aluminum alloy forging having a thin H with a wall thickness of 10 mm or less and a relatively wide central web force that has an arm portion with a substantially H-shaped cross section (lightweight forging shaped forging (Even if it is a forged aluminum alloy), it should be made stronger, tougher and more corrosion resistant.
- FIG. 1 is a plan view showing an automobile underbody part made of forged A1 alloy material.
- the A1 alloy chemical composition of the automobile undercarriage parts of the present invention guarantees high corrosion resistance and durability such as high strength, high toughness and stress corrosion cracking resistance as undercarriage parts such as upper arm and lower arm.
- the chemical composition of the A1 alloy is mass%, Mg: 0.5 to 1.25%, Si: 0.4 to 1.4%, Cu: 0.01 to 0.7%, Fe: 0.05 to 0.4%, Mn: 0.001 to 1.0 %, CnO.Ol to 0.35%, Ti: 0.005 to 0.1%, respectively, and Zr: Less than 0.15%, with the balance consisting of A1 and inevitable impurities.
- % display in each element amount means the mass%.
- Mg 0.7 to 1.25% as a narrower composition range
- Si 0.8-1.3%
- Cu 0.1-0.6%
- Fe 0.1-0.4%
- Mn 0.2-0.6%
- Cr 0.1-0.3%
- Ti 0.01-0.1%
- Zr 0.15 It is preferable that the content is limited to less than% and the balance is made of Al and inevitable impurities.
- composition range Mg: 0.9 to ll%, Si: 0.9 to ll%, Cu: 0.3 to 0.5%, Fe: 0.1 to 0.4%, Mn: 0.2 to 0.6%, Cr: 0.1 to 0.2%, It is more preferable that Ti: 0.01% to 0.1% each is contained, and that Zr is limited to less than 0.15%, the balance being A1 and inevitable impurity power.
- Mg 0.5 to 1.25%, preferably 0.7 to 1.25%, more preferably 0.9 to 1.1%.
- Mg is an essential element for imparting high strength (yield strength) when using automobile undercarriage parts, as it precipitates in the crystal grains mainly as acicular j8 'phase with Si by artificial aging treatment.
- yield strength yield strength
- the age hardening amount at the time of artificial aging treatment will fall.
- the strength (proof strength) becomes too high and the forgeability is impaired.
- the Mg content is in the range of 0.5 to 1.25%, preferably 0.7 to 1.25%, more preferably 0.9 to 1.1%.
- Si 0.4 to 1.4%, preferably 0.8 to 1.3%, more preferably 0.9 to 1.1%.
- Si together with Mg, precipitates mainly as an acicular j8 'phase by artificial aging treatment, and is an essential element for imparting high strength (yield strength) when using automobile undercarriage parts. If the Si content is too small, sufficient strength cannot be obtained by artificial aging treatment. On the other hand, if the Si content is too high, coarse single-piece S insulators crystallize during fabrication and during quenching after solution treatment. Protrusions and precipitates, reducing corrosion resistance and toughness. In addition, excessive amounts of Si cannot provide high corrosion resistance, high toughness, and high fatigue characteristics. In addition, workability is hindered, such as lower elongation. Therefore, the Si content is in the range of Si: 0.4 to 1.4%, preferably 0.8 to 1.3%, more preferably 0.9 to 1.1%.
- Mn 0.001 to 1.0%, preferably 0.2 to 0.6%.
- CnO.Ol to 0.35%, preferably 0.1 to 0.3%, more preferably 0.1 to 0.2%.
- Mn and Cr are A ⁇ Mn and A ⁇ Cr metals in which Fe, Mn, Cr, Si, Al, etc. are selectively bonded according to their contents during homogenization heat treatment and subsequent hot forging. Dispersed particles (dispersed phase) that are (consisting of) intermetallic compounds are produced.
- Representative examples of Al-Mn and A-Cr intermetallic compounds include Al- (Fe, Mn, Cr) -Si compounds, (Fe, Mn, Cr) 3SiA112, and the like.
- These dispersed particles of Mn and Cr are dispersed according to the manufacturing conditions. They are dispersed finely, densely and uniformly, and have the effect of hindering grain boundary movement after recrystallization. In addition, it is highly effective in reducing crystal grains. Mn is also expected to increase in strength and Young's modulus due to solid solution in the matrix.
- Mn and Cr are contained, and the Mn content is 0.001 to 1.0%, preferably 0.2 to 0.6% in each range, and the Cr content is 0.01 to 0.35%, preferably 0.1 to 0.3%. Preferably, each range of 0.1 to 0.2% is contained.
- Zr that produces dispersed particles (dispersed phase) like Mn and Cr
- Zr produces a Ti-Zr compound that inhibits the refinement of Ti, Ti, and B crystal grains, and causes coarsening of the crystal grains. Therefore, in the present invention, Zr is not used, and the content of Zr contained as an impurity is suppressed as much as possible. Specifically, Zr is less than 0.15%, preferably less than 0.05%.
- Cu 0.01 to 0.7%, preferably 0.1 to 0.6%, more preferably 0.3 to 0.5%.
- Cu not only contributes to strength improvement by solid solution strengthening, but also has the effect of remarkably accelerating age hardening of the final product during aging treatment. If the Cu content is too low, these effects will not be achieved. On the other hand, if the Cu content is too high, the susceptibility to stress corrosion cracking and intergranular corrosion of the structure of the A1 alloy forging is remarkably increased, and the corrosion resistance and durability of the A1 alloy forging are reduced. Therefore, the Cu content is in the range of 0.01 to 0.7%, preferably 0.1 to 0.6%, more preferably 0.3 to 0.5%.
- Fe 0.05 to 0.4%, preferably 0.1 to 0.4%.
- the Fe content should be 0.05 to 0.4%, preferably 0.1 to 0.4%.
- Ti 0.005 to 0.1%, preferably 0.01 to 0.1%.
- Ti has the effect of refining the crystal grains of the lumps and making the forged material structure fine sub-crystal grains. If the Ti content is too small, this effect cannot be exhibited. However, if the Ti content is too large, coarse crystal precipitates are formed, and the workability is lowered. Therefore, the Ti content is 0.005 to 0.1%, preferably 0.01 to 0.1%.
- Hydrogen 0.25 ml / 100 g A1 or less.
- hydrogen H2
- the hydrogen concentration per 100 g of Al is preferably 0.25 ml or less and the smallest possible content.
- B is an impurity, as with Ti, it has the effect of refining the crystal grains of the lumps and improving workability during extrusion and forging. However, if the content exceeds 300 ppm, coarse crystal precipitates are formed and the workability is lowered. Therefore, B is allowed up to 300ppm.
- the structure of the rib part in the specific part where the maximum stress is generated is defined as described above in the arm part of the lightweight forged car undercarriage part. Therefore, the meaning of the specific part where the maximum stress is generated in the automobile underbody part of the present invention will be described first.
- Fig. 1 (a) is a plan view showing the overall shape of the automobile undercarriage part 1 and the specific part of the arm where the maximum stress occurs.
- Fig. 1 (b) is a cross-sectional view of the AA line in Fig. 1 (a) (maximum stress).
- FIG. 5 is a cross-sectional view in the width direction of a specific part of an arm portion where the occurrence of sag.
- the automobile underbody part 1 is also an aluminum alloy forging material that is forged into this shape.
- the automobile undercarriage part 1 has a substantially triangular overall shape as shown in Fig. 1 (a), and has joint parts 5a, 5b, 5c such as ball joints at the apex part of each triangle.
- the car suspension parts have a shape in which these are connected by the arm portions 2a and 2b, respectively.
- the arm portions 2a and 2b always have ribs extending in the longitudinal directions of the arm portions at the respective peripheral portions (both end portions) in the width direction.
- the arm part 2a has ribs 3a and 3b, and the arm part 2b has ribs 3a and 3c.
- the arm portions 2a and 2b always have webs extending in the longitudinal directions of the arm portions at the center portions in the width direction.
- the arm part 2a has a web 4a
- the arm part 2b has a web 4b.
- the ribs 3a, 3b, 3c are common in the automobile underbody parts and are relatively narrow and thick.
- the webs 4a and 4b are common to automobile underbody parts and are thinner than the ribs 3a, 3b and 3c, and are relatively wide with a thickness of 10 mm or less.
- the arms 2a and 2b have a substantially H-shaped cross-sectional shape in the cross-section in the width direction, which is common to automobile underbody parts.
- the vertical wall portions of the H type mean the ribs 3a, 3b, 3c
- the central horizontal wall portions mean the webs 4a, 4b.
- the specific part that generates the maximum stress during use (the maximum stress is applied) is located on the ball joint side of the rib part.
- the arm parts 2a, 2b and the ball joint parts 5a, 5b, 5c are structurally designed so that Of course, the maximum stress generation site is inevitably on the ball joint side of one of the ribs, although it depends on the structural design conditions.
- the specific part where the maximum stress is generated during use is indicated by the diagonal line in Fig. 1 (a) on the ball joint side of the rib part. It is a hatched portion extending in the longitudinal direction. That is, in the example of FIG. 1 (a), it is a part partially including the rib 3a and the web 4a on one side of the arm part 2a on the ball joint part 5a side, which is indicated by hatching. Further, the maximum stress generation site in the cross section in the width direction in this arm portion is the 6a portion on the upper end side of the rib 3a, which is surrounded by a circle in FIG.
- the specific part of the arm part to which the maximum stress is applied (one side of the arm part 2a on the ball joint part 5a side: the rib 3a and the web 4a shown by hatching in FIG. 1 (a)
- the site of each part is defined as described above. If it can be manufactured, it is preferable that only the specific portion of the arm portion to which the maximum stress is applied is used.
- the structure of the entire arm portions 2a and 2b is as described above.
- crystallized substances and grain boundary precipitates of the rib 3a structure which are the maximum stress generation sites of the arm part described in FIG.
- the dispersed particles which are intermetallic compounds and the recrystallization ratio are further defined respectively.
- the recrystallization ratio of the web 4a structure at the maximum stress generation site of the arm part is further defined.
- the crystallized material of the rib 3a structure is specified by the structure of the maximum stress generation site in the cross section in the width direction.
- the grain boundary precipitates and dispersed particles in the rib 3a structure are specified in the structure of the parting line in the cross section in the width direction.
- the recrystallization ratio of the rib 3a structure and the web 4a structure is defined by the cross-section in the width direction of the maximum stress generation site.
- the crystal of the cross-sectional structure in the width direction in the arm portion 2a to which the maximum stress is applied is a portion surrounded by a circle in FIG. 1 (b), which is a portion to which the maximum stress in the cross-section in the width direction is applied. It is specified by the 6a part on the upper end side of 3a.
- the specific part where the maximum stress is generated during use extends to the rib 3b side which is not only the rib 3a, it is surrounded by a circle in FIG. 6b is also designated as a crystallized part.
- the crystallized product referred to in the present invention is an AFe-Si-based crystallized product.
- Fe content is too high, coarse A-Fe-Si-based crystals such as coarse crystals that deteriorate the fracture toughness and fatigue properties are generated.
- Fe is an element that is particularly likely to be mixed as an impurity from melting raw materials such as scrap. For this reason, even if the content is about the normal impurity level, there is a high possibility that coarse crystals such as A ⁇ Fe-Si crystals will be produced.
- the density of the A ⁇ Fe-Si-based crystallized product is specified, and coarse crystallized products such as the A ⁇ Fe-Si-based crystallized product in the structure are suppressed. That is, the A Fe—Si crystallized product in the structure is 1.5% or less in average area ratio, preferably 1.0% or less.
- the average area ratio of the A ⁇ Fe-Si-based crystallized material exceeds 1.5% or less, preferably 1.0% or less, coarse crystals are formed, and the fracture toughness of automobile undercarriage parts And fatigue characteristics.
- the average area ratio of the A ⁇ Fe-Si-based crystallized material is the portion where the maximum stress is applied in the cross section in the width direction, which is the portion on the upper end side of the rib 3a surrounded by circles in Fig. 1 (b).
- the grain boundary precipitate is a part of the cross-sectional structure in the width direction of the arm portion 2a to which the maximum stress is applied, including the parting line PL (including) of the rib 3a in FIG. 1 (b). It is specified in the part.
- the part line PL of the rib 3b corresponding to 8 of the rib 3a is included.
- Part is also a grain boundary precipitate prescribed part.
- This parting line PL shown in FIG. 1 (b) is a parting surface, and can be used as a boundary between both molds in hot mold forging using upper and lower molds. It inevitably occurs as a boundary surface (surface to be divided). If the above-mentioned maximum stress is the load site, and fracture occurs starting from the crystallized material on the upper end side 6b of the rib 3b in Fig. 1 (b), the fracture is directed toward this part line PL. Propagates grain boundaries. The grain boundary propagation of the directional fracture in this parting line PL varies greatly depending on the presence of grain boundary precipitates.
- the present invention by reducing the precipitates on the grain boundary in the arm portion (particularly the rib portion) where the maximum stress is loaded, the propagation of the grain boundary of the fracture is prevented or suppressed, so that Improve fracture toughness and fatigue properties.
- Grain boundary precipitates referred to in the present invention are Mg2Si and simple substance Si.
- Mg2Si is mainly precipitated in the crystal grains as ⁇ and phase, and gives high strength (proof strength) of automobile undercarriage parts.
- this Mg2Si or simple substance Si precipitates at the grain boundary, it becomes the starting point of the fracture, promotes the grain boundary propagation of the fracture toward the parting line PL, and the fracture toughness of automobile undercarriage parts. And deteriorate fatigue characteristics.
- the grain boundary precipitate is defined by the part. That is, by increasing the average interval between grain boundary precipitates such as Mg2Si and elemental Si at the grain boundaries of this structure to 0.7 ⁇ m or more, preferably 1.6 ⁇ m or more, the precipitates on the grain boundaries are reduced.
- the average interval between the grain boundary precipitates is the TEM (magnification in the width direction) of the part 8 (partial cross-sectional structure) of the parting line PL (including) of the rib 3a in Fig. 1 (b).
- Ten fields of view were observed with a transmission electron microscope, and 1 / n was calculated from the number n of grain boundary precipitates per grain boundary length. In order to make the measurement reproducible, these observations are conducted at 10 arbitrary measurement points, and these are averaged to calculate the average area ratio.
- the dispersed particles are also parting lines of the ribs 3a in FIG. 1 (b) among the cross-sectional yarns and weaves in the width direction in the arm portions 2a to which the maximum stress is applied, like the grain boundary precipitates. It is defined by the 8 part that is the PL (including) part.
- the partition line PL (of the rib 3b corresponding to 8 of the rib 3a is included.
- Part is also the grain boundary precipitate regulation part.
- the forging rate is the largest, and it is a part that is easy to recrystallize. For this reason, it is important to prevent recrystallization of the most easily recrystallized portion. Therefore, in the present invention, recrystallization is performed at the most recrystallized portion.
- recrystallization is performed at the most recrystallized portion.
- the dispersed particles referred to in the present invention are A ⁇ Mn-based, A ⁇ Cr-based, and A ⁇ Zr-based intermetallic compounds.
- these dispersed particles have the effect of hindering grain boundary movement after recrystallization if they are finely dispersed at a high density and uniformly, the crystal grains are prevented from being recrystallized and coarsened.
- the effect of miniaturizing is high.
- the heating rate or cooling rate is too small in the thermal history such as forging, homogeneous heat treatment, hot forging, solution treatment, and quenching treatment, depending on the production conditions, Easy to convert. For this reason, the effect of suppressing recrystallization (grain refinement) is lost, and the fracture toughness and fatigue characteristics of automobile undercarriage parts may be deteriorated.
- the average diameter and the average area ratio are defined as the size of the dispersed particles. It is preferable. That is, it is not indispensable as described above for the crystallized and grain boundary precipitates of the rib 3a structure, but preferably, the average diameter of the dispersed particles is 1200 A or less and the density of the dispersed particles is an average.
- the area ratio is 4% or more.
- the average diameter of the dispersed particles in the structure exceeds 1200 A, or the density of the dispersed particles is less than 4% in terms of the average area ratio, it can be finely and uniformly dispersed. Not. For this reason, the fracture toughness and fatigue characteristics of automobile undercarriage parts may be degraded.
- the average diameter and average area ratio of the dispersed particles are the ratio of the structure of 8 part (including the cross-sectional structure in the width direction) of the parting line PL (including cross section) of rib 3a in Fig. 1 (b).
- the total area of the dispersed particles to be observed is obtained, and the ratio to the observation visual field area is calculated to obtain the average area ratio of the dispersed particles.
- these observations are made at 10 arbitrary measurement points, and these are averaged and calculated.
- the width direction of the rib 3a in FIG. It is preferable to regulate the area ratio (also referred to as the recrystallization area ratio) occupied by the recrystallized grains in the two parts of the entire structure in the cross section and the entire structure in the cross section in the width direction of the web 4a adjacent thereto. Accordingly, it is preferable to regulate the ratio of the recrystallized area of the arm portion combining the rib and the web.
- the web 4a also includes a parting line PL site and is easily recrystallized.
- the crystal grain size (recrystallization area ratio) of the web also greatly affects the fatigue strength. Also, because the web has a different degree of forging than ribs, the recrystallization area ratio of ribs is likely to be different from that of ribs. Therefore, when specifying the recrystallization area ratio of the arm part to which the maximum stress is applied, it is necessary to specify both the web and the rib.
- the specified portion of the rib is the portion where the maximum stress in the cross section in the width direction is applied to the entire structure in the cross section in the width direction of the rib 3a in FIG. 1 (b).
- the specified portion of the web is the entire structure in the cross-section in the width direction of the web 4a in Fig. 1 (b).
- specify (measure) 9 parts including the above-mentioned parting line PL part which is most easily recrystallized. That is, the area ratio of the recrystallized grains at these two measurement sites 9 is regulated to an average area ratio of 20% or less on behalf of the entire structure in the cross-section in the width direction of the web, the subcrystal grains are increased, Refine crystal grains to about 10 m or less. This suppresses the grain boundary breakage of the web and improves the strength and toughness of automobile undercarriage parts.
- the area ratio of the recrystallized surface is observed by optically magnifying the surface of the observation part (cross-sectional structure) of the rib and web that has been mirror-polished by mechanical polishing after 0.05 to 0.1 mm with an optical microscope. Then, image processing is performed to calculate the ratio of the recrystallization area to the observation visual field area. Since the recrystallized grains are large in size, the crystal grains including other sub-crystals that easily reflect light and light in color are dark in color because they are small in size. As a result, it is possible to discriminate by the difference in the shades of the color as well as the difference in size between them, and image processing is possible. In order to make the measurement reproducible, these observations are made at 10 arbitrary measurement points, and these are averaged.
- the rib portion and the web portion of the arm portion are increased in strength and toughness. Even if it is an automobile undercarriage part that has an arm part with an approximately H-shaped cross section that is a thin wall with a wall thickness of 10 mm or less and a relatively wide central web force (lightweight forged car undercarriage part) Even so, it is made stronger, tougher and more corrosion resistant.
- the manufacturing process itself of the A1 alloy forging material in the present invention can be manufactured by a conventional method.
- each of the following explanations is required in order to increase the strength, toughness, and corrosion resistance of the car undercarriage parts having the structure described above. Manufacturing under specific conditions is required in the manufacturing process.
- Forging is performed by appropriately selecting a usual melting and forging method such as a continuous forging rolling method, a semi-continuous forging method (DC forging method), and a hot top forging method.
- a usual melting and forging method such as a continuous forging rolling method, a semi-continuous forging method (DC forging method), and a hot top forging method.
- the structure of at least the maximum stress generation site (the maximum stress generation site rib 3a of the arm portion of the automobile underbody part).
- DAS dendrite secondary arm spacing
- the average cooling rate shall be 100 ° C / s or higher.
- the homogenized heat treatment of the produced slag is 460-570.
- Heat to a temperature range of C, preferably 460 to 520 ° C, 10 to 1500 ° C / hr, preferably 20 to 1000 ° C / hr, and hold in this temperature range for 2 hr or more .
- the cooling rate after the homogenization heat treatment is set to 40 ° C./hr or more, and this cooling rate is allowed to cool to room temperature.
- the homogenization heat treatment temperature is too high, the crystallized product is likely to dissolve, but the dispersed particles are coarsened and cannot be finely and uniformly dispersed, and the effect of refining crystal grains by the finely uniform dispersion is impaired.
- the homogenization heat treatment temperature is too low, the crystallized material is not sufficiently melted and coarse crystallized material remains, making it difficult to increase the strength and toughness of the automobile undercarriage part.
- the holding time in this homogeneous heat treatment temperature range is less than 2 hr, the homogenization time is insufficient, the crystallized material is insufficiently melted, and coarse crystallized material remains, resulting in an automobile undercarriage part. It becomes difficult to achieve high strength and toughness.
- the cooling rate after the homogenization heat treatment is less than 40 ° C / hr, Mg2Si precipitates in the crystal grains before the solution treatment. For this reason, Mg2Si deposited by solution treatment is insufficient, resulting in insufficient solution treatment, making it difficult to increase the strength and toughness of automobile undercarriage parts.
- the lump once cooled to room temperature at the above cooling rate is reheated to the hot forging start temperature.
- hot forging is performed by forging with a mechanical press or forging with a hydraulic press, and forged into the final product shape of a car undercarriage part.
- This shape is the above-described lightweight shape, and is a relatively narrow and thick peripheral rib, and a thin and relatively wide central web having a thickness of 10 mm or less and a substantially H-shaped cross section. It is processed into an automobile undercarriage part having a shaped arm portion.
- the end temperature at the time of this hot forging is 350 ° C or more, and the forging start temperature is 350 ° C depending on conditions such as the number of hot forgings performed several times without any reheating.
- the temperature should be C or higher.
- the hot forging start temperature is less than 350 ° C, the end temperature is 350 ° C. It becomes difficult to guarantee a higher temperature than C.
- the end temperature during hot forging is less than 350 ° C, the dispersed particles cannot be finely and uniformly dispersed. Therefore, the average grain size of the A1 alloy at the maximum stress generation site of the arm part of the automobile undercarriage part Even forged automobile undercarriage parts with a lighter diameter diameter cannot be refined to 50 m or less. Further, the ratio of sub-crystal grains is also reduced. As a result, it becomes impossible to increase the strength, toughness and corrosion resistance of automobile undercarriage parts.
- the heating rate is increased to 100 ° C / hr or more, and cooling after hot forging is completed.
- the speed is preferably as high as 100 ° C / hr or higher.
- tempering treatment of T6, ⁇ 7, ⁇ 8, etc. to obtain the necessary strength, toughness and corrosion resistance as automobile undercarriage parts is performed as appropriate.
- ⁇ 6 is an artificial age hardening treatment that obtains the maximum strength after solution treatment and quenching treatment.
- ⁇ 7 is after solution treatment and quenching treatment To obtain the maximum strength, it is an excessive age-hardening treatment that exceeds the artificial age-hardening treatment conditions.
- T8 is an artificial aging hardening treatment that obtains the maximum strength by cold working after solution treatment and quenching treatment.
- the structure of at least the maximum stress generation site of the arm portion is finally optimized as defined in the present invention. That is, the density of A ⁇ Fe-Si crystals is 1.0% or less in average area ratio, the average maximum diameter of each Mg2Si grain boundary precipitate is 2 ⁇ m or less, and the average of each Mg2Si grain boundary precipitate is between The spacing is 1.6 ⁇ m or more, the average diameter of dispersed particles that are A ⁇ Mn-based or A ⁇ Cr-based intermetallic compounds is 1200A or less, and the density is 5% or less in terms of the average area ratio.
- the T7 tempered material is an excessive age hardening treatment because of the difference between the solution age hardening and the artificial age hardening treatment after the quenching treatment. Get higher.
- This ⁇ phase lowers the intergranular corrosion susceptibility, which is difficult to elute in a corrosive environment, and increases the stress corrosion cracking resistance.
- ⁇ 6 tempered material is an artificial aging hardening treatment that obtains the maximum strength, and a large amount of ⁇ ′ phase is precipitated.
- This ⁇ 'phase dissolves in a corrosive environment and immediately increases the intergranular corrosion susceptibility and decreases the stress corrosion cracking resistance. Therefore, by using the A1 alloy forged material as the above-mentioned 7 tempered material, although the rust resistance is slightly lowered, the corrosion resistance is higher than other tempering treatments.
- the solution treatment is maintained in a temperature range of 530 to 570 ° C for 20 minutes to 8 hours. If the solution treatment temperature is too low, or if the time is too short, there will be insufficient solution solution, resulting in insufficient solid solution of Mg2Si and a decrease in strength. When heating to the solution treatment temperature, it is preferable to increase the rate of temperature rise to 100 ° C./hr or more in order to prevent the dispersion particles from becoming coarse and to guarantee the effect.
- a quenching treatment is performed at an average cooling rate of 200 to 300 ° C / s.
- the cooling during the quenching process is performed by water cooling. If the cooling rate during this quenching process is reduced, Mg2Si, Si, etc. will precipitate on the grain boundaries, and in the product after artificial aging, grain boundary fracture will easily occur and the toughness and fatigue properties will be lowered.
- the stable phases Mg2Si and Si are formed in the grains, and the amount of
- hot-water quenching at 50 to 85 ° C. in which quenching distortion is reduced, is preferable in order to shorten the product manufacturing process and reduce costs.
- the hot water quenching temperature is less than 50 ° C, the quenching strain becomes large, and when it exceeds 85 ° C, the cooling rate becomes too low, and the toughness, fatigue characteristics and strength are lowered.
- the artificial age-hardening treatment after solution treatment and quenching treatment is carried out in the temperature range of 530 to 570 ° C and the retention time of 20 minutes to 8 hours from the tempering treatment of T6, ⁇ 7, ⁇ 8, etc. Select a condition.
- an air furnace, an induction heating furnace, a glass stone furnace, or the like is appropriately used. Furthermore, an air furnace, an induction heating furnace, an oil bath or the like is appropriately used for the artificial age hardening treatment.
- the automobile underbody component of the present invention may be appropriately subjected to machining, surface treatment, and the like necessary as an automobile underbody component before and after the tempering treatment.
- Aluminium alloy ingots (A1 alloy forged material, both forged rods with a diameter of 82 mm) with the chemical composition of alloy numbers A to R and S to Y shown in Table 1 were prepared by the semi-continuous forging method. Forging was performed at a relatively high cooling rate shown in Fig. 1.
- a to C and D, F, H, L, M, N, and Q are invention examples
- E, G, I, J, K, 0, P, R, and S to Y are It is a comparative example.
- Zn, V, and Hf of each A1 alloy example are total, except for Comparative Example P, where the specific impurity content such as Zr is too high. Less than 0.2% and B was 300ppm or less. Also, hydrogen concentration in 100g A1 of each A1 alloy example Were all 0.10-0.15 ml.
- each A1 alloy ingot of these chemical composition compositions was chamfered to a thickness of 3 mm and cut to a length of 500 mm, and then homogenized heat treatment and mechanical press under the conditions shown in Tables 2 and 3, respectively.
- the car undercarriage parts with the shape shown in Fig. 1 were manufactured by hot die forging using solution, solution hardening and age hardening.
- the homogenization heat treatment the heating rate, the cooling rate, and the holding time at the homogenization temperature were changed.
- Hot forging changed the end temperature.
- the solution quenching treatment the solution temperature, the holding time at the solution temperature, and the cooling rate were changed.
- the age hardening treatment the aging temperature and the holding time at the aging temperature were changed.
- the manufactured automobile undercarriage parts are ribs 3a, 3b, 3c with a relatively narrow width with a wall thickness of 30 mm, and a relatively wide (width: 60 mm) center with a wall thickness of 10 mm.
- the arm portions 2a and 2b having a substantially H-shaped cross section composed of the webs 4a and 4b.
- the cooling rate during the homogenization heat treatment was controlled by whether or not a cooling fan was used after the furnace exit.
- a fan with a cooling rate of 100 ° C / hr was forcibly cooled with air, and a fan with a cooling rate of 20 ° C / hr was allowed to cool without using a fan as usual.
- the solution treatment was performed using an air furnace, and after the solution treatment, water quenching was performed, and the temperature of this water was adjusted to control the cooling rate during water quenching as shown in Tables 2 and 3. .
- the cooling rate is 200 ° C / s
- quenching is performed in hot water at 60 ° C
- the cooling rate is 250 ° C / s
- the temperature is 40 ° C.
- Quenching was carried out in water, and when the cooling rate was 300 ° C / s, quenching was carried out in water at room temperature of about 20 ° C.
- the one with a cooling rate of 20 ° C / s was air-cooled.
- Tables 4 and 5 show the state of grain boundary precipitates and dispersed particles in part 8 and the recrystallization area ratio in parts 7 and 8, respectively.
- Tables 4 and 5 show the recrystallization area ratio of the structure of the portion 9 of the web 4a in FIG. 1 (b) adjacent to the rib 3a.
- Tables 4 and 5 also show the characteristics of the tensile test pieces including the portion 7 in the cross section in the width direction of the rib 3a of each automobile underbody part. Tables 4 and 5 also show the properties of the tensile specimen including the portion 9 in the cross section in the width direction of the web 4a.
- the A1 alloy numbers in Tables 2 to 5 correspond to the A1 alloy numbers in Table 1
- Table 4 corresponds to Table 2
- the numbers in Table 2 correspond to the numbers in Table 5
- Table 3 corresponds to Table 5, respectively.
- Two tensile test pieces A (L direction) and Charpy test piece B (LT direction) are collected from any part in the longitudinal direction, including each part of the rib 3a and web 4a, and tensile strength ( MPa), 0.2% resistance to moisture (MPa), elongation (%), Charpy impact value, etc. were measured, and each average value was determined.
- the test piece should include at least the maximum stress generation part (shaded part in FIG. 1) of the arm part of each automobile undercarriage part, including both parts 7 and 8 of the rib 3a.
- the intergranular corrosion susceptibility test conditions were in accordance with the provisions of the former JIS-W1103. In this state, after 6 hours of immersion for a specified time, the sample was pulled up, and then the cross section of the test piece was cut and polished, and the corrosion depth from the sample surface was measured using an optical microscope. The magnification was X100. A corrosion depth of less than 200 m was evaluated as “ ⁇ ” as minor corrosion. Moreover, the case of exceeding 200 ⁇ m was evaluated as “X J” as a large corrosion.
- the stress corrosion cracking test is performed so that both the parts 7 and 8 of the rib 3a are included from at least the maximum stress generation part (shaded part in Fig. 1) of the arm part of each automobile undercarriage part. Pieces were collected and processed into C-ring shaped test pieces. The stress corrosion cracking test conditions were determined in accordance with the ASTM G47 alternate dipping method for the C-ring test piece. However, the test conditions further simulated the fact that a tensile stress was applied to the automobile undercarriage parts, and the proof stress in the L direction of the test piece of the mechanical characteristics in the ST direction of the C ring test piece. The condition was more severe than the actual operating condition with 75% stress.
- the structure of the maximum stress generation site of the arm part of the automobile underbody part satisfies the provisions of the present invention. That is, the crystallized density observed in the cross-sectional structure in the width direction at the maximum stress generation site of the rib is 1.5% or less in average area ratio, and the distance between each grain boundary precipitate is 0.7 m or more in average interval. is there.
- the inventive example has a tensile strength of S350 MPa or more for both the rib and the web, and a Charpy impact value of the rib of 10 J / cm 2 or more.
- the inventive examples are excellent in the intergranular corrosion susceptibility and stress corrosion cracking resistance of the rib portion at the maximum stress generation site.
- invention examples 1 to 3 have a preferable composition (content of each element).
- the size of the dispersed particles in this structure is 1200 A or less in average diameter, and the density of these dispersed particles is in a preferable range of 4% or more in terms of average area ratio.
- the area ratio of the recrystallized grains observed in the cross-sectional structure of these ribs is 10% or less in terms of average area ratio.
- the area ratio of the recrystallized grains observed in the cross-sectional structure in the width direction of the web adjacent to the cross-sectional structure of these ribs is 20% or less in average area ratio.
- the ribs and webs each have a tensile strength of 400 MPa or more and the Charpy impact value of the ribs is 15 J / cm 2 or more.
- Inventive Examples 1 to 3 are also excellent in the intergranular corrosion susceptibility and stress corrosion cracking resistance of the rib portion at the maximum stress generation site.
- Comparative Examples 4, 5, and 9 to 16 manufactured out of the optimum manufacturing conditions use the A1 alloy having the composition of B within the scope of the present invention.
- the tissue of the maximum stress generation site of the arm part does not satisfy the provisions of the present invention.
- any of the strength, toughness, and corrosion resistance of the maximum stress generation site of the arm part of the automobile undercarriage part is significantly inferior to the invention example.
- Comparative Example 4 the forging cooling rate is too low.
- Comparative Example 5 the soaking temperature is too low.
- Comparative Example 9 the soaking cooling rate is too low.
- Comparative Example 10 the forging end temperature is too low.
- Comparative Example 11 the solution temperature is too low.
- Comparative Example 12 the solution temperature is too high.
- Comparative Example 13 the cooling rate during quenching is too low.
- Comparative Example 14 since the soaking temperature was too high, burning (local melting) occurred in the lump, and subsequent production and characteristic evaluation were impossible.
- Comparative Example 15 the soaking rate is too low.
- Comparative Example 16 has an excessive soaking rate.
- Comparative Examples 18, 20, 22-24, 28, 29, using A1 alloys E, G, I, J, K, 0, P, R, and S to Y having a composition outside the scope of the present invention. 31 to 38 are manufactured within the optimum manufacturing conditions, but any of the strength, toughness, and corrosion resistance of the maximum stress generation site of the arm part of the automobile undercarriage part is significantly inferior to the invention example. .
- Comparative Example 32 Mg is insufficient. Comparative Example 18 is excessive in Mg. In Comparative Example 33, Si is insufficient. Comparative Example 20 is excessive Si. Comparative Example 34 has too little Cu. Comparative Example 22 is excessive in Cu. In Comparative Example 23, Fe is insufficient. In Comparative Example 24, Fe is excessive. In Comparative Example 35, Mn is insufficient. Comparative Example 36 is excessive in Mn. In Comparative Example 37, Cr is insufficient. Comparative Example 28 is excessive in Cr. Comparative Example 29 is excessive in Zr. Comparative Example 38 is too scarce. Comparative Example 31 is excessive.
- an automobile underbody component having high strength, high toughness, and high corrosion resistance, and a method for manufacturing the same. Therefore, it has great industrial value in that it can be used for transporting A ⁇ Mg-Si based aluminum alloy forgings (for example, various structural members of automobiles). .
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Abstract
Description
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CN2007800021260A CN101365818B (zh) | 2006-03-31 | 2007-03-23 | 铝合金锻造构件及其制造方法 |
US12/279,189 US8152940B2 (en) | 2006-03-31 | 2007-03-23 | Aluminum alloy forging member and process for producing the same |
CA2637273A CA2637273C (en) | 2006-03-31 | 2007-03-23 | Aluminum alloy forging member and method for producing the same |
EP07739465.8A EP2003219B1 (en) | 2006-03-31 | 2007-03-23 | Aluminum alloy forging member and process for producing the same |
KR1020087023855A KR101060917B1 (ko) | 2006-03-31 | 2007-03-23 | 알루미늄합금 단조 부재 및 그 제조 방법 |
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JPWO2021230080A1 (ja) * | 2020-05-13 | 2021-11-18 | ||
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CN113798430A (zh) * | 2021-08-11 | 2021-12-17 | 广东华昌集团有限公司 | 基于共挤压的钢铝导电轨的制备方法及导电轨 |
WO2024142830A1 (ja) * | 2022-12-27 | 2024-07-04 | 株式会社レゾナック | アルミニウム合金鍛造用素材、アルミニウム合金鍛造品及びその製造方法 |
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Publication number | Publication date |
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JP5110938B2 (ja) | 2012-12-26 |
CN101365818A (zh) | 2009-02-11 |
KR101060917B1 (ko) | 2011-08-30 |
CN101365818B (zh) | 2011-03-23 |
EP2003219A8 (en) | 2009-08-19 |
EP2003219A9 (en) | 2009-04-22 |
EP2003219A4 (en) | 2011-05-18 |
KR20080102414A (ko) | 2008-11-25 |
JP2008163445A (ja) | 2008-07-17 |
CA2637273A1 (en) | 2007-10-11 |
US20090000705A1 (en) | 2009-01-01 |
EP2003219A2 (en) | 2008-12-17 |
EP2003219B1 (en) | 2014-02-26 |
US8152940B2 (en) | 2012-04-10 |
CA2637273C (en) | 2014-02-25 |
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