CN101809040B - 保护性胶体稳定的聚合物产品的制备方法 - Google Patents

保护性胶体稳定的聚合物产品的制备方法 Download PDF

Info

Publication number: CN101809040B
Authority: CN; China
Prior art keywords: heat exchanger; weight; reactor; protective colloid; carbon atom
Prior art date: 2007-08-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CN2008801046255A

Other languages

English (en)

Chinese (zh)

Other versions

CN101809040A (zh

Inventor

H-P·魏策尔

M·居纳尔塔伊

M·泽利希

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Wacker Chemie AG

Original Assignee

Wacker Chemie AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2007-08-29

Filing date

2008-08-11

Publication date

2012-07-04

2008-08-11 Application filed by Wacker Chemie AG filed Critical Wacker Chemie AG

2010-08-18 Publication of CN101809040A publication Critical patent/CN101809040A/zh

2012-07-04 Application granted granted Critical

2012-07-04 Publication of CN101809040B publication Critical patent/CN101809040B/zh

Status Expired - Fee Related legal-status Critical Current

2028-08-11 Anticipated expiration legal-status Critical

Links

238000000034 method Methods 0.000 title claims abstract description 41
230000001681 protective effect Effects 0.000 title claims abstract description 23
229920000642 polymer Polymers 0.000 title claims abstract description 12
238000004519 manufacturing process Methods 0.000 title abstract description 4
238000001816 cooling Methods 0.000 claims abstract description 28
230000003068 static effect Effects 0.000 claims abstract description 13
239000011541 reaction mixture Substances 0.000 claims abstract description 4
239000000178 monomer Substances 0.000 claims description 23
238000006116 polymerization reaction Methods 0.000 claims description 21
-1 alkyl carboxylic acid Chemical class 0.000 claims description 20
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 17
150000001721 carbon Chemical group 0.000 claims description 17
229910052799 carbon Inorganic materials 0.000 claims description 16
239000000084 colloidal system Substances 0.000 claims description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
229920001567 vinyl ester resin Polymers 0.000 claims description 11
NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
230000007062 hydrolysis Effects 0.000 claims description 9
238000006460 hydrolysis reaction Methods 0.000 claims description 9
239000000843 powder Substances 0.000 claims description 8
239000000126 substance Substances 0.000 claims description 8
JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 claims description 6
150000001336 alkenes Chemical class 0.000 claims description 4
238000007334 copolymerization reaction Methods 0.000 claims description 4
229910052736 halogen Inorganic materials 0.000 claims description 4
150000002367 halogens Chemical class 0.000 claims description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
238000012546 transfer Methods 0.000 claims description 3
239000004215 Carbon black (E152) Substances 0.000 claims description 2
239000004815 dispersion polymer Substances 0.000 claims description 2
229930195733 hydrocarbon Natural products 0.000 claims description 2
150000002430 hydrocarbons Chemical class 0.000 claims description 2
229920001038 ethylene copolymer Polymers 0.000 claims 1
238000007720 emulsion polymerization reaction Methods 0.000 abstract description 5
239000000203 mixture Substances 0.000 description 16
239000003795 chemical substances by application Substances 0.000 description 11
XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
238000001035 drying Methods 0.000 description 8
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 7
239000002253 acid Substances 0.000 description 7
239000004568 cement Substances 0.000 description 7
239000006185 dispersion Substances 0.000 description 7
239000003999 initiator Substances 0.000 description 7
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 6
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
150000002148 esters Chemical class 0.000 description 6
239000000463 material Substances 0.000 description 6
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 6
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 5
239000003995 emulsifying agent Substances 0.000 description 5
239000000945 filler Substances 0.000 description 5
238000002156 mixing Methods 0.000 description 5
229920002472 Starch Polymers 0.000 description 4
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 4
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 4
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
229920001577 copolymer Polymers 0.000 description 4
230000000694 effects Effects 0.000 description 4
230000002209 hydrophobic effect Effects 0.000 description 4
SAJLIOLJORWJIO-UHFFFAOYSA-N hydroxymethanesulfinic acid;sodium Chemical compound [Na].OCS(O)=O SAJLIOLJORWJIO-UHFFFAOYSA-N 0.000 description 4
230000002829 reductive effect Effects 0.000 description 4
239000007787 solid Substances 0.000 description 4
239000000243 solution Substances 0.000 description 4
238000005507 spraying Methods 0.000 description 4
239000008107 starch Substances 0.000 description 4
235000019698 starch Nutrition 0.000 description 4
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 description 3
125000003545 alkoxy group Chemical group 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
239000008199 coating composition Substances 0.000 description 3
238000013461 design Methods 0.000 description 3
GLVVKKSPKXTQRB-UHFFFAOYSA-N ethenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC=C GLVVKKSPKXTQRB-UHFFFAOYSA-N 0.000 description 3
239000001530 fumaric acid Substances 0.000 description 3
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
239000002609 medium Substances 0.000 description 3
150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 3
DNTMQTKDNSEIFO-UHFFFAOYSA-N n-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 description 3
230000005855 radiation Effects 0.000 description 3
229920002554 vinyl polymer Polymers 0.000 description 3
BPMMHGIISLRQDW-ODZAUARKSA-N (z)-but-2-enedioic acid;ethenoxyethene Chemical compound C=COC=C.OC(=O)\C=C/C(O)=O BPMMHGIISLRQDW-ODZAUARKSA-N 0.000 description 2
SQAINHDHICKHLX-UHFFFAOYSA-N 1-naphthaldehyde Chemical compound C1=CC=C2C(C=O)=CC=CC2=C1 SQAINHDHICKHLX-UHFFFAOYSA-N 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
LDHQCZJRKDOVOX-UHFFFAOYSA-N 2-butenoic acid Chemical compound CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 2
FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 2
IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
229920000856 Amylose Polymers 0.000 description 2
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical class C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
108010010803 Gelatin Proteins 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
229920001732 Lignosulfonate Polymers 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 2
150000001241 acetals Chemical class 0.000 description 2
150000003863 ammonium salts Chemical class 0.000 description 2
229910052728 basic metal Inorganic materials 0.000 description 2
150000003818 basic metals Chemical class 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
239000004202 carbamide Substances 0.000 description 2
235000013877 carbamide Nutrition 0.000 description 2
150000001735 carboxylic acids Chemical class 0.000 description 2
239000005018 casein Substances 0.000 description 2
BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 2
229940071162 caseinate Drugs 0.000 description 2
235000021240 caseins Nutrition 0.000 description 2
239000001913 cellulose Substances 0.000 description 2
229920002678 cellulose Polymers 0.000 description 2
239000000919 ceramic Substances 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
229920000159 gelatin Polymers 0.000 description 2
239000008273 gelatin Substances 0.000 description 2
235000019322 gelatine Nutrition 0.000 description 2
235000011852 gelatine desserts Nutrition 0.000 description 2
230000009477 glass transition Effects 0.000 description 2
150000004676 glycans Chemical class 0.000 description 2
230000017525 heat dissipation Effects 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229920001519 homopolymer Polymers 0.000 description 2
235000019357 lignosulphonate Nutrition 0.000 description 2
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
125000002496 methyl group Chemical class [H]C([H])([H])* 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
239000002245 particle Substances 0.000 description 2
239000010695 polyglycol Substances 0.000 description 2
229920000151 polyglycol Polymers 0.000 description 2
229920001282 polysaccharide Polymers 0.000 description 2
239000005017 polysaccharide Substances 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000011591 potassium Substances 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
235000018102 proteins Nutrition 0.000 description 2
108090000623 proteins and genes Proteins 0.000 description 2
102000004169 proteins and genes Human genes 0.000 description 2
238000007789 sealing Methods 0.000 description 2
238000010008 shearing Methods 0.000 description 2
229910000077 silane Inorganic materials 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
239000007921 spray Substances 0.000 description 2
238000001694 spray drying Methods 0.000 description 2
229920001059 synthetic polymer Polymers 0.000 description 2
230000007704 transition Effects 0.000 description 2
NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 description 1
UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
NDGXZYRXRPWLOE-UHFFFAOYSA-N 2-(prop-2-enoylamino)oxyacetic acid Chemical compound OC(=O)CONC(=O)C=C NDGXZYRXRPWLOE-UHFFFAOYSA-N 0.000 description 1
GWRKYBXTKSGXNJ-UHFFFAOYSA-N 2-methyl-1-(2-methylpropoxyperoxy)propane Chemical group CC(C)COOOCC(C)C GWRKYBXTKSGXNJ-UHFFFAOYSA-N 0.000 description 1
PMNLUUOXGOOLSP-UHFFFAOYSA-M 2-sulfanylpropanoate Chemical compound CC(S)C([O-])=O PMNLUUOXGOOLSP-UHFFFAOYSA-M 0.000 description 1
FPFSGDXIBUDDKZ-UHFFFAOYSA-N 3-decyl-2-hydroxycyclopent-2-en-1-one Chemical compound CCCCCCCCCCC1=C(O)C(=O)CC1 FPFSGDXIBUDDKZ-UHFFFAOYSA-N 0.000 description 1
QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 description 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
241001093575 Alma Species 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 1
LIBYMGVPNPHWEB-WSIDDKTASA-N C(\C=C/C(=O)O)(=O)OC(C)C.C(\C=C\C(=O)O)(=O)O Chemical compound C(\C=C/C(=O)O)(=O)OC(C)C.C(\C=C\C(=O)O)(=O)O LIBYMGVPNPHWEB-WSIDDKTASA-N 0.000 description 1
208000031639 Chromosome Deletion Diseases 0.000 description 1
ZDQWESQEGGJUCH-UHFFFAOYSA-N Diisopropyl adipate Chemical compound CC(C)OC(=O)CCCCC(=O)OC(C)C ZDQWESQEGGJUCH-UHFFFAOYSA-N 0.000 description 1
239000004593 Epoxy Substances 0.000 description 1
IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical group OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 1
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000011398 Portland cement Substances 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
239000003570 air Substances 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
125000003368 amide group Chemical group 0.000 description 1
XLJMAIOERFSOGZ-UHFFFAOYSA-N anhydrous cyanic acid Natural products OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
229920005601 base polymer Polymers 0.000 description 1
230000005540 biological transmission Effects 0.000 description 1
244000309464 bull Species 0.000 description 1
235000011132 calcium sulphate Nutrition 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
230000001112 coagulating effect Effects 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
FNMTVMWFISHPEV-AATRIKPKSA-N dipropan-2-yl (e)-but-2-enedioate Chemical compound CC(C)OC(=O)\C=C\C(=O)OC(C)C FNMTVMWFISHPEV-AATRIKPKSA-N 0.000 description 1
238000007599 discharging Methods 0.000 description 1
238000004821 distillation Methods 0.000 description 1
GRWZHXKQBITJKP-UHFFFAOYSA-N dithionous acid Chemical compound OS(=O)S(O)=O GRWZHXKQBITJKP-UHFFFAOYSA-N 0.000 description 1
238000010556 emulsion polymerization method Methods 0.000 description 1
IGBZOHMCHDADGY-UHFFFAOYSA-N ethenyl 2-ethylhexanoate Chemical group CCCCC(CC)C(=O)OC=C IGBZOHMCHDADGY-UHFFFAOYSA-N 0.000 description 1
MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
125000005670 ethenylalkyl group Chemical group 0.000 description 1
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
238000009422 external insulation Methods 0.000 description 1
239000004744 fabric Substances 0.000 description 1
238000011049 filling Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000005243 fluidization Methods 0.000 description 1
239000006260 foam Substances 0.000 description 1
VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
239000011507 gypsum plaster Substances 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
125000002768 hydroxyalkyl group Chemical group 0.000 description 1
230000010354 integration Effects 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
235000012204 lemonade/lime carbonate Nutrition 0.000 description 1
239000001095 magnesium carbonate Substances 0.000 description 1
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
229960001708 magnesium carbonate Drugs 0.000 description 1
229910000021 magnesium carbonate Inorganic materials 0.000 description 1
235000014380 magnesium carbonate Nutrition 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
125000005395 methacrylic acid group Chemical group 0.000 description 1
GSJFXBNYJCXDGI-UHFFFAOYSA-N methyl 2-hydroxyacetate Chemical compound COC(=O)CO GSJFXBNYJCXDGI-UHFFFAOYSA-N 0.000 description 1
JMSTYCQEPRPFBF-UHFFFAOYSA-N methyl 2-methoxy-2-(prop-2-enoylamino)acetate Chemical compound COC(=O)C(OC)NC(=O)C=C JMSTYCQEPRPFBF-UHFFFAOYSA-N 0.000 description 1
239000004570 mortar (masonry) Substances 0.000 description 1
AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
230000036961 partial effect Effects 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000011505 plaster Substances 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 description 1
NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
238000005086 pumping Methods 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000012966 redox initiator Substances 0.000 description 1
239000003507 refrigerant Substances 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000012216 screening Methods 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000002893 slag Substances 0.000 description 1
239000002002 slurry Substances 0.000 description 1
150000003384 small molecules Chemical class 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000000758 substrate Substances 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
150000003460 sulfonic acids Chemical class 0.000 description 1
229910021653 sulphate ion Inorganic materials 0.000 description 1
239000000454 talc Substances 0.000 description 1
235000012222 talc Nutrition 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Images

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/002—Scale prevention in a polymerisation reactor or its auxiliary parts
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/20—Aqueous medium with the aid of macromolecular dispersing agents
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/90—Heating or cooling systems
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
- F28D2021/0019—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
- F28D2021/0052—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for mixers
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F13/00—Arrangements for modifying heat-transfer, e.g. increasing, decreasing
- F28F13/06—Arrangements for modifying heat-transfer, e.g. increasing, decreasing by affecting the pattern of flow of the heat-exchange media
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerisation Methods In General (AREA)

CN2008801046255A 2007-08-29 2008-08-11 保护性胶体稳定的聚合物产品的制备方法 Expired - Fee Related CN101809040B (zh)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
DE102007040850A DE102007040850A1 (de)	2007-08-29	2007-08-29	Verfahren zur Herstellung von Schutzkolloid-stabilisierten Polymerisaten und Vorrichtung zur Durchführung des Verfahrens
DE102007040850.3		2007-08-29
PCT/EP2008/060503 WO2009027212A1 (fr)	2007-08-29	2008-08-11	Procédé de production de polymères stabilisés par colloïde protecteur et dispositif permettant de mettre en oeuvre ledit procédé

Publications (2)

Publication Number	Publication Date
CN101809040A CN101809040A (zh)	2010-08-18
CN101809040B true CN101809040B (zh)	2012-07-04

Family

ID=39930724

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CN2008801046255A Expired - Fee Related CN101809040B (zh)	2007-08-29	2008-08-11	保护性胶体稳定的聚合物产品的制备方法

Country Status (11)

Country	Link
US (1)	US8119708B2 (fr)
EP (1)	EP2181124B1 (fr)
JP (1)	JP5181113B2 (fr)
KR (1)	KR101169974B1 (fr)
CN (1)	CN101809040B (fr)
AT (1)	ATE499389T1 (fr)
BR (1)	BRPI0816479A2 (fr)
DE (2)	DE102007040850A1 (fr)
MY (1)	MY183932A (fr)
RU (1)	RU2471810C2 (fr)
WO (1)	WO2009027212A1 (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
ES2750259T3 (es) *	2008-12-08	2020-03-25	Construction Research & Technology Gmbh	Procedimiento semicontinuo para la preparación de copolímeros
JP5156878B2 (ja) *	2011-01-28	2013-03-06	株式会社ニチレイバイオサイエンス	細長い容器内液体の攪拌手段・方法
DE102011005388A1 (de)	2011-03-10	2012-09-13	Wacker Chemie Ag	Verfahren zur Herstellung von Polymerisaten mittels Emulsions- oder Suspensionspolymerisation
JP2013065999A (ja) *	2011-09-16	2013-04-11	Toshiba Corp	送信システム、送信機及び送信機監視制御方法
US9156920B2 (en) *	2012-09-26	2015-10-13	Wacker Chemical Corporation	Process for the preparation of an aqueous emulsifier-stabilized vinyl acetate-ethylene copolymer dispersion with fine particle size
EP2952248B1 (fr) *	2014-06-05	2019-08-07	Saint-Gobain Placo SAS	Appareil et procédé pour la production de mousse
JP6675132B2 (ja)	2015-11-20	2020-04-01	秀之春山	熱交換ミキシング装置及び溶液移送冷却装置
RU2607916C1 (ru) *	2015-12-21	2017-01-11	Владимир Леонидович Письменный	Теплообменник
CN106732273B (zh) *	2016-12-26	2024-05-24	江苏新宏大集团有限公司	一种半水法磷酸专用搅拌装置
EP3692078B1 (fr) *	2017-10-04	2021-03-03	Wacker Chemie AG	Procédé de polymérisation avec une refrigération externe
CN111615523A (zh) *	2018-01-31	2020-09-01	巴斯夫欧洲公司	制备聚合物组合物的方法
CN112912405B (zh)	2019-07-25	2023-05-05	瓦克化学股份公司	用于制备水性聚合物分散体的方法
CN114471407B (zh) *	2022-01-27	2022-12-20	云南正邦科技有限公司	多重釜式-管式的串-并联连续聚合生产eva的生产系统及方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN1184819A (zh) *	1996-10-02	1998-06-17	巴斯福股份公司	乳液均聚物和共聚物的制备及其设备
US6117939A (en) *	1997-11-12	2000-09-12	Basf Aktiengesellschaft	Free radical miniemulsion polymerization with low shear and heat exchanger
EP1067147A2 (fr) *	1999-07-06	2001-01-10	Air Products Polymers, L.P.	Emulsions d'acetate de vinyle/éthylène à taux en matières solides élevées
EP1174445A1 (fr) *	2000-07-21	2002-01-23	Wacker Polymer Systems GmbH & Co. KG	Procédé continu de polymérisation en émulsion pour la préparation de polymères stabilisés par des colloides protecteurs
US6595679B2 (en) *	2000-02-08	2003-07-22	Bayer Aktiengesellschaft	Static mixer with at least three interleaved grids
EP1384502A1 (fr) *	2002-07-24	2004-01-28	Bayer Aktiengesellschaft	Mélangeur, échangeur de chaleur

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS58201801A (ja) *	1982-02-01	1983-11-24	Japan Synthetic Rubber Co Ltd	重合反応熱の除熱方法
JPS63297407A (ja) *	1987-05-12	1988-12-05	大蓮化学工業股ふん有限公司	エマルジョンの製法
JP2836765B2 (ja)	1991-07-05	1998-12-14	信越化学工業株式会社	塩化ビニル系重合体の製造装置
JP3095304B2 (ja)	1992-12-28	2000-10-03	信越化学工業株式会社	塩化ビニル系重合体の製造方法
DE59504339D1 (de) *	1995-07-26	1999-01-07	Sulzer Chemtech Ag	Verfahren und Einrichtung zum Durchführen einer Polymerisation in einem Rohrreaktor
DE19620817A1 (de) *	1996-05-23	1997-11-27	Wacker Chemie Gmbh	Flexible Baustoffmassen
JP3550987B2 (ja) *	1997-12-03	2004-08-04	住友化学工業株式会社	食品衛生用品製造用水性エマルジョン組成物
DE19853461A1 (de) *	1998-11-19	2000-05-25	Elotex Ag Sempach Station	Schutzkolloid-stabilisierte Copolymerisat-Latexteilchen mit heterogener Morphologie auf Basis eines Vinylacetat/Ethylen-Copolymerisats, Verfahren zu ihrer Herstellung sowie ihre Verwendung
AT413268B (de)	1999-05-05	2006-01-15	Tigerwerk Lack U Farbenfabrik	Verfahren zum auf- und/oder zubereiten einer thermoplastischen masse und vorrichtung zur durchführung des verfahrens
DE19940399A1 (de)	1999-08-25	2001-03-01	Basf Ag	Vorrichtung zum Fördern von Polymerdispersionen
DE10103709A1 (de)	2001-01-26	2002-08-01	Basf Ag	Verfahren zur Herstellung einer wässrigen Polymerisatdispersion durch radikalisch initiierte wässrige Emulsionspolymerisation
DE10134023A1 (de) *	2001-07-12	2003-01-23	Basf Ag	Verfahren und Vorrichtung zur Herstellung von Polymerdispersionen
JP4041534B2 (ja) *	2003-06-18	2008-01-30	電気化学工業株式会社	エチレン−酢酸ビニル系共重合体エマルジョン、その製造方法および接着剤用組成物
DE102007038332A1 (de)	2007-08-14	2009-02-19	Wacker Chemie Ag	Kontinuierliches Polymerisationsverfahren

2007
- 2007-08-29 DE DE102007040850A patent/DE102007040850A1/de not_active Withdrawn
2008
- 2008-08-11 BR BRPI0816479-7A patent/BRPI0816479A2/pt not_active IP Right Cessation
- 2008-08-11 EP EP08787078A patent/EP2181124B1/fr active Active
- 2008-08-11 DE DE502008002688T patent/DE502008002688D1/de active Active
- 2008-08-11 MY MYPI2010000800A patent/MY183932A/en unknown
- 2008-08-11 RU RU2010111843/04A patent/RU2471810C2/ru not_active IP Right Cessation
- 2008-08-11 KR KR1020107004094A patent/KR101169974B1/ko not_active IP Right Cessation
- 2008-08-11 JP JP2010522297A patent/JP5181113B2/ja not_active Expired - Fee Related
- 2008-08-11 CN CN2008801046255A patent/CN101809040B/zh not_active Expired - Fee Related
- 2008-08-11 AT AT08787078T patent/ATE499389T1/de active
- 2008-08-11 US US12/675,052 patent/US8119708B2/en not_active Expired - Fee Related
- 2008-08-11 WO PCT/EP2008/060503 patent/WO2009027212A1/fr active Application Filing

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN1184819A (zh) *	1996-10-02	1998-06-17	巴斯福股份公司	乳液均聚物和共聚物的制备及其设备
US6117939A (en) *	1997-11-12	2000-09-12	Basf Aktiengesellschaft	Free radical miniemulsion polymerization with low shear and heat exchanger
EP1067147A2 (fr) *	1999-07-06	2001-01-10	Air Products Polymers, L.P.	Emulsions d'acetate de vinyle/éthylène à taux en matières solides élevées
US6595679B2 (en) *	2000-02-08	2003-07-22	Bayer Aktiengesellschaft	Static mixer with at least three interleaved grids
EP1174445A1 (fr) *	2000-07-21	2002-01-23	Wacker Polymer Systems GmbH & Co. KG	Procédé continu de polymérisation en émulsion pour la préparation de polymères stabilisés par des colloides protecteurs
EP1384502A1 (fr) *	2002-07-24	2004-01-28	Bayer Aktiengesellschaft	Mélangeur, échangeur de chaleur

Also Published As

Publication number	Publication date
EP2181124B1 (fr)	2011-02-23
KR101169974B1 (ko)	2012-08-06
JP2010537022A (ja)	2010-12-02
BRPI0816479A2 (pt)	2015-03-17
JP5181113B2 (ja)	2013-04-10
EP2181124A1 (fr)	2010-05-05
US8119708B2 (en)	2012-02-21
US20110112218A1 (en)	2011-05-12
WO2009027212A1 (fr)	2009-03-05
RU2010111843A (ru)	2011-11-10
MY183932A (en)	2021-03-17
CN101809040A (zh)	2010-08-18
RU2471810C2 (ru)	2013-01-10
DE102007040850A1 (de)	2009-03-05
DE502008002688D1 (de)	2011-04-07
ATE499389T1 (de)	2011-03-15
KR20100046033A (ko)	2010-05-04

Publication	Publication Date	Title
CN101809040B (zh)	2012-07-04	保护性胶体稳定的聚合物产品的制备方法
CN101778872B (zh)	2013-04-24	连续的聚合方法
CN101168577B (zh)	2012-10-10	包括二聚表面活性剂的分散粉末组合物
CN100579992C (zh)	2010-01-13	用于制造聚乙烯醇稳定化的胶乳的方法
TWI239965B (en)	2005-09-21	Process for preparing protective-colloid-stabilized polymers by continuous emulsion polymerization
CN100586998C (zh)	2010-02-03	用保护胶体稳定化的分散粉末
CN102300940B (zh)	2013-12-18	在水中可再分散的可交联聚合物粉末化合物
CN101296878B (zh)	2011-07-27	包含脂肪酸酐的分散体粉末
CN104261720A (zh)	2015-01-07	一种醚类聚羧酸减水剂及其制备方法
US6664322B2 (en)	2003-12-16	Process for preparing protective-colloid-stabilized polymers by continuous emulsion polymerization
TWI287020B (en)	2007-09-21	Process for preparing two-phase polymers in the form of their aqueous dispersions and water-redispersible powders
CN107586366A (zh)	2018-01-16	一种改性聚羧酸减水剂及其制备方法
JP2007084835A (ja)	2007-04-05	再分散性粉末の製造方法
CN104364278B (zh)	2017-04-12	用于水硬固化结构材料物质的乙酸乙烯酯共聚物
CN103415538B (zh)	2015-07-15	在喷射环流反应器中通过乳液聚合或悬液聚合生产聚合物的方法
JP4646185B2 (ja)	2011-03-09	凝結促進作用を有する水中に再分散可能なポリマー粉末−組成物、その製法及びその使用
CN107602879A (zh)	2018-01-19	一种改性丁苯可再分散乳胶粉
CN103998495B (zh)	2016-02-24	用于生产聚合物水分散体的方法
CN100360569C (zh)	2008-01-09	(甲基)丙烯酸树脂系乳状液及其制造方法
CN110191900A (zh)	2019-08-30	用于生产水可再分散的聚合物粉末组合物的连续和模块化方法

Legal Events

Date	Code	Title	Description
2010-08-18	C06	Publication
2010-08-18	PB01	Publication
2010-10-06	C10	Entry into substantive examination
2010-10-06	SE01	Entry into force of request for substantive examination
2012-07-04	C14	Grant of patent or utility model
2012-07-04	GR01	Patent grant
2022-07-19	CF01	Termination of patent right due to non-payment of annual fee	Granted publication date: 20120704 Termination date: 20210811
2022-07-19	CF01	Termination of patent right due to non-payment of annual fee