Revision date: 10/01/2020 Revision: 4A Supersedes date: 03/10/2015

SAFETY DATA SHEET

CONPLAST R

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name CONPLAST R

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Concrete Retarding Admixture

1.3. Details of the supplier of the safety data sheet

Supplier Fosroc Chemical (India) Pvt. Ltd
Embassy Point, No 150, 2nd Floor,
Infantry Road,
Bangalore - 560001
+91 80 2355 1500/ 4252 1900
+91 80 2355 1510

1.4. Emergency telephone number

Emergency telephone +91 80 2355 1500/ 4252 1900

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Eye Irrit. 2 - H319 Carc. 1B - H350

Environmental hazards Not Classified

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H319 Causes serious eye irritation.

H350 May cause cancer.

Precautionary statements P264 Wash contaminated skin thoroughly after handling.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/ attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P501 Dispose of contents/ container in accordance with national regulations.

Contains FORMALDEHYDE

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Supplementary precautionary P201 Obtain special instructions before use.

statements P202 Do not handle until all safety precautions have been read and understood.
P405 Store locked up.

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

NONYL PHENOL CONDENSATE 1-5%

CAS number: 9016-45-9

Classification
Acute Tox. 4 - H302
Eye Dam. 1 - H318
STOT SE 3 - H335

SULPHONATED NAPTHALENE FORMALDEHYDE (SNF 1-5%

Powder)
CAS number: 36290-04-7

Classification Classification (67/548/EEC or 1999/45/EC)

Acute Tox. 4 - H302 -

FORMALDEHYDE <1%
CAS number: 50-00-0 EC number: 200-001-8 REACH registration number: 01-
2119488953-20

Classification
Acute Tox. 3 - H301
Acute Tox. 3 - H311
Acute Tox. 3 - H331
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Skin Sens. 1 - H317
Muta. 2 - H341
Carc. 1B - H350
STOT SE 3 - H335

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing.

Inhalation Rinse nose and mouth with water.

Ingestion Rinse mouth thoroughly with water. Do not induce vomiting.

Skin contact Remove contaminated clothing. Wash skin thoroughly with soap and water.

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Eye contact Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15
minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Inhalation May cause coughing and difficulties in breathing.

Ingestion May cause stomach pain or vomiting.

Skin contact Prolonged skin contact may cause redness and irritation.

Eye contact Severe irritation, burning and tearing.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

5.2. Special hazards arising from the substance or mixture

Specific hazards No specific hazard known.

Hazardous combustion Does not decompose when used and stored as recommended.
products

5.3. Advice for firefighters

Protective actions during Containers close to fire should be removed or cooled with water. Fight fire from safe distance
firefighting or protected location.

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear suitable protective clothing, gloves and eye/face protection.

6.2. Environmental precautions

Environmental precautions Prevent entry into drains, sewers and water courses.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Collect and place in suitable waste disposal containers and seal securely. Label the
containers containing waste and contaminated materials and remove from the area as soon
as possible.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

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Usage precautions Avoid spilling. Avoid contact with skin and eyes. Provide adequate ventilation. Avoid inhalation
of vapours. Use approved respirator if air contamination is above an acceptable level.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.

Storage class Chemical storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
FORMALDEHYDE
Long-term exposure limit (8-hour TWA): WEL 2 ppm 2.5 mg/m³
Short-term exposure limit (15-minute): WEL 2 ppm 2.5 mg/m³
WEL = Workplace Exposure Limit

FORMALDEHYDE (CAS: 50-00-0)

DNEL Workers - Inhalation; Long term systemic effects: 9 mg/m³

Workers - Inhalation; Long term local effects: 0,5 mg/m³
Workers - Inhalation; Short term local effects: 1 mg/m³
Workers - Dermal; Long term systemic effects: 240 mg/kg/day
Workers - Dermal; Long term local effects: 37 µg/cm2

PNEC - Fresh water, marine water; 0.47 mg/l

- STP; 0.19 mg/l
Water, Intermittent release; 4,7 mg/l
Sediment (Freshwater), Sediment (Marinewater); 2,44 mg/kg
Soil; 0,21 mg/kg

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation.

controls

Eye/face protection Chemical splash goggles and face shield.

Hand protection Nitrile gloves are recommended, but be aware that the liquid may penetrate the gloves.
Frequent change is advisable.

Other skin and body Wear appropriate clothing to prevent any possibility of liquid contact and repeated or
protection prolonged vapour contact. Wear apron or protective clothing in case of contact.

Hygiene measures When using do not eat, drink or smoke.

Respiratory protection Gas filter, type A2.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

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Appearance Liquid.

Colour Brown.

pH pH (concentrated solution): 6.2

Initial boiling point and range >100 ̊ C

Flammability (solid, gas) Product is not flammable.

Upper/lower flammability or The product is not flammable.

explosive limits

Relative density ~ 1.14 @ 25°C

Solubility(ies) Completely soluble in water.

Explosive properties Not considered to be explosive.

Explosive under the influence Not considered to be explosive.

of a flame

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information

Other information Not determined.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity The reactivity data for this product will be typical of those for the following class of materials:
Epoxides. Strong oxidising agents.

10.2. Chemical stability

Stability Hazardous polymerisation will not occur.

10.3. Possibility of hazardous reactions

Possibility of hazardous No potentially hazardous reactions known.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials

Materials to avoid Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Hazardous decomposition Does not decompose when used and stored as recommended.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
ATE oral (mg/kg) 10,297.48

Acute toxicity - dermal

ATE dermal (mg/kg) 202,702.7

Acute toxicity - inhalation

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ATE inhalation (gases ppm) 472,972.97

Inhalation May cause coughing and difficulties in breathing.

Ingestion May cause stomach pain or vomiting.

Skin contact Prolonged skin contact may cause redness and irritation.

Eye contact Severe irritation, burning and tearing.

Target organs Skin Eyes

Toxicological information on ingredients.

FORMALDEHYDE

Acute toxicity - oral

Notes (oral LD₅₀) LD₅₀ > 200 mg/kg, Oral, Rat

ATE oral (mg/kg) 100.0

Acute toxicity - dermal

Notes (dermal LD₅₀) LD₅₀ 270 mg/kg, Dermal, Rabbit

ATE dermal (mg/kg) 300.0

Acute toxicity - inhalation

Notes (inhalation LC₅₀) CL50 0,58 mg/l, 4 hours, Gas. Rat

Carcinogenicity

IARC carcinogenicity IARC Group 1 Carcinogenic to humans.

Inhalation Prolonged inhalation of high concentrations may damage respiratory system. May
cause respiratory system irritation.

Ingestion Toxic if swallowed.

Skin contact Corrosive to skin. May cause sensitisation or allergic reactions in sensitive
individuals.

Eye contact Causes serious eye damage.

SECTION 12: Ecological information

12.1. Toxicity
Toxicity Not considered toxic to fish.

Ecological information on ingredients.

FORMALDEHYDE

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 41 mg/l, Brachydanio rerio (Zebra Fish)

Acute toxicity - aquatic EC₅₀, 24 hours: 42 mg/l, Daphnia magna

invertebrates

Acute toxicity - aquatic EC₅₀, 72 hours: 3,48 - 4,89 mg/l, Algae

plants

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12.2. Persistence and degradability

Persistence and degradability Expected to be not readily biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.

12.4. Mobility in soil

Mobility Soluble in water.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information The generation of waste should be minimised or avoided wherever possible.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).

14.1. UN number
Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

No transport warning sign required.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

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National regulations The Manufacture, storage and import of hazardous chemicals rules 1989.

EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration,Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).

Guidance Workplace Exposure Limits EH40.

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

General information For professional use only. Only trained personnel should use this material.

Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.

Revision date 10/01/2020

Revision 4A

Supersedes date 03/10/2015

SDS number 23338

Hazard statements in full H301 Toxic if swallowed.

H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H341 Suspected of causing genetic defects.
H350 May cause cancer.

The information on this data sheet represents our current data and is reliable provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.

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