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SP179 Hand Sanitiser

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Revision date: 05/03/2020 Revision: 1

SAFETY DATA SHEET


Hand Sanitizer Gel

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier


Product name Hand Sanitizer Gel

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Hand Cleanser

1.3. Details of the supplier of the safety data sheet


Supplier Rumenco T/A Nettex Ltd
Hoo Industrial Estate
Vicarage Lane
Hoo
Rochester
Kent
ME3 9LB
+44 (0) 1283 524 222

1.4. Emergency telephone number


Emergency telephone +44 (0)800 246 1274 (24 hrs) EcoStar Environmental Ltd

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture


Classification (EC 1272/2008)
Physical hazards Flam. Liq. 2 - H225

Health hazards Not Classified

Environmental hazards Not Classified

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H225 Highly flammable liquid and vapour.

Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/ container in accordance with national regulations.

2.3. Other hazards

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SECTION 3: Composition/information on ingredients

3.2. Mixtures

benzyl-C12-14-alkyldimethylammonium chloride <1%


CAS number: — EC number: 939-350-2 REACH registration number: 01-
2119970550-39-XXXX
M factor (Acute) = 10 M factor (Chronic) = 1

Classification
Acute Tox. 4 - H302
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures


Inhalation IF INHALED: Remove affected person from source of contamination. Get medical attention
immediately.

Ingestion Rinse nose and mouth with water. Get medical attention immediately.

Skin contact Remove contaminated clothing and rinse skin thoroughly with water. Get medical attention if
irritation persists after washing.

Eye contact Remove any contact lenses and open eyelids wide apart. Rinse immediately with plenty of
water. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Inhalation Vapours may cause headache, fatigue, dizziness and nausea.

Ingestion May cause stomach pain or vomiting. May cause nausea, headache, dizziness and
intoxication.

Skin contact Prolonged or repeated exposure may cause the following adverse effects: Dryness and/or
cracking.

Eye contact Symptoms following overexposure may include the following: Irritation and redness, followed
by blurred vision.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

5.2. Special hazards arising from the substance or mixture

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Hand Sanitizer Gel

Specific hazards The product is flammable.

Hazardous combustion Toxic and corrosive gases or vapours.


products

5.3. Advice for firefighters


Protective actions during Evacuate area. Containers close to fire should be removed or cooled with water.
firefighting

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


Personal precautions Avoid inhalation of vapours and contact with skin and eyes. Wear protective clothing as
described in Section 8 of this safety data sheet.

6.2. Environmental precautions


Environmental precautions Do not discharge into drains or watercourses or onto the ground. Avoid the spillage or runoff
entering drains, sewers or watercourses.

6.3. Methods and material for containment and cleaning up


Methods for cleaning up Eliminate all sources of ignition. Absorb spillage with non-combustible, absorbent material.
Collect and place in suitable waste disposal containers and seal securely.

6.4. Reference to other sections


Reference to other sections For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling


Usage precautions For personal protection, see Section 8. Take precautionary measures against static
discharge.

7.2. Conditions for safe storage, including any incompatibilities


Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place. Keep away
from food, drink and animal feeding stuffs.

Storage class Flammable liquid storage.

7.3. Specific end use(s)


Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

benzyl-C12-14-alkyldimethylammonium chloride

DNEL Workers - Dermal; Long term systemic effects: 5.7 mg/kg/day


Workers - Inhalation; Long term systemic effects: 3.96 mg/m³

8.2. Exposure controls

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Protective equipment

Appropriate engineering As this product contains ingredients with exposure limits, process enclosures, local exhaust
controls ventilation or other engineering controls should be used to keep worker exposure below any
statutory or recommended limits, if use generates dust, fumes, gas, vapour or mist. This
product must not be handled in a confined space without adequate ventilation.

Eye/face protection Wear chemical splash goggles.

Hand protection Wear protective gloves made of the following material: Polytetrafluoroethylene (PTFE, Teflon).
Polyvinyl chloride (PVC). Rubber (natural, latex).

Other skin and body Wear apron or protective clothing in case of contact.
protection

Hygiene measures Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
Remove contaminated clothing and wash the skin thoroughly with soap and water after work.

Respiratory protection Respiratory protection complying with an approved standard should be worn if a risk
assessment indicates inhalation of contaminants is possible.

Environmental exposure Keep container tightly sealed when not in use.


controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties


Appearance Gel.

Colour Colourless.

Odour Alcoholic.

Flash point 21°C

Relative density 0.89

Solubility(ies) Miscible with water.

9.2. Other information


Other information None.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity Under normal conditions of storage and use, no hazardous reactions will occur.

10.2. Chemical stability


Stability Stable at normal ambient temperatures and when used as recommended.

10.3. Possibility of hazardous reactions


Possibility of hazardous Flammable/combustible materials.
reactions

10.4. Conditions to avoid


Conditions to avoid Containers can burst violently or explode when heated, due to excessive pressure build-up.
Avoid heat, flames and other sources of ignition.

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10.5. Incompatible materials


Materials to avoid None known.

10.6. Hazardous decomposition products


Hazardous decomposition Carbon dioxide (CO2). Carbon monoxide (CO).
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Inhalation Vapour may irritate respiratory system/lungs.

Ingestion Gastrointestinal symptoms, including upset stomach. May cause stomach pain or vomiting.
May cause nausea, headache, dizziness and intoxication.

Skin contact Repeated exposure may cause skin dryness or cracking.

Eye contact A single exposure may cause the following adverse effects: Severe irritation, burning, tearing
and blurred vision. Pain. Redness.

SECTION 12: Ecological information

12.1. Toxicity
Toxicity Not known.

12.2. Persistence and degradability


Persistence and degradability The product is expected to be biodegradable.

12.3. Bioaccumulative potential


Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.

12.4. Mobility in soil


Mobility The product is miscible with water and may spread in water systems.

12.5. Results of PBT and vPvB assessment


Results of PBT and vPvB Not known.
assessment

12.6. Other adverse effects


Other adverse effects The product contains volatile organic compounds (VOCs) which have a photochemical ozone
creation potential.

SECTION 13: Disposal considerations

13.1. Waste treatment methods


Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority. Waste, residues, empty containers, discarded work clothes
and contaminated cleaning materials should be collected in designated containers, labelled
with their contents.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 1170

UN No. (IMDG) 1170

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UN No. (ICAO) 1170

UN No. (ADN) 1170

14.2. UN proper shipping name


Proper shipping name ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)
(ADR/RID)

Proper shipping name (IMDG) ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)

Proper shipping name (ICAO) ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)

Proper shipping name (ADN) ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)

14.3. Transport hazard class(es)


ADR/RID class 3

ADR/RID classification code F1

ADR/RID label 3

IMDG class 3

ICAO class/division 3

ADN class 3

Transport labels

14.4. Packing group


ADR/RID packing group II

IMDG packing group II

ICAO packing group II

ADN packing group II

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant


No.

14.6. Special precautions for user


EmS F-E, S-D

ADR transport category 2

Emergency Action Code •2YE

Hazard Identification Number 33


(ADR/RID)

Tunnel restriction code (D/E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

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SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Dangerous Preparations Directive 1999/45/EC.
Dangerous Preparations Directive 1999/45/EC.

15.2. Chemical safety assessment


No chemical safety assessment has been carried out.

SECTION 16: Other information

Issued by HS&E Manager.

Revision date 05/03/2020

Revision 1

SDS number 5545

Hazard statements in full H225 Highly flammable liquid and vapour.


H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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