No : F/QCL/008 Rev.

01

MATERIAL SAFETY DATA SHEET

SILVER SULPHATE

Revision : 01 Date: 10.03.2018 MSDS Number : 201

Section 1 - Chemical Product and Company Identification

1.1 Product Name : SILVER SULPHATE

Synonyms : Disilver sulphate, Sulphuric acid disilver (I) salt
CAS No. : 10294-26-5
HS Code : 2843 29 00
Molecular Weight : 311.79 g/mol
Chemical Formula : Ag2SO4
Product Code : A-2045
Brand : SMART-LAB
1.2 Manufacturer :PT.Smart-Lab Indonesia
Address : Ruko Boulevard TamanTekno Blok E No.10 -11BSD SektorXI
Serpong, Tangerang - Indonesia
Website :www.smartlab.co.id
Email :sales@smartlab.co.id
For information :Telp: +62-21- 7588 0205(Hunting) , fax:+62-21-7588 0198
1.3 Application : General Chemical reagent
Emergency Telephone: +62-21-7588 0205(Hunting)

Section 2 - Hazards Identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008
Serious eye damage (Category 1), H318
Acute aquatic toxicity (Category 1), H400
Chronic aquatic toxicity (Category 1), H410

For the full text of the H-Statements mentioned in this Section, see Section 16

2.2 Label elements

Labelling according Regulation (EC) No 1272/2008

Pictogram

Signal word Danger

Hazard statement(s)
H318 Causes serious eye damage.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary statement(s)
P280 Wear eye protection/ face protection.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Immediately call a POISON
CENTER/doctor.

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No : F/QCL/008 Rev. 01

MATERIAL SAFETY DATA SHEET

SILVER SULPHATE

Revision : 01 Date: 10.03.2018 MSDS Number : 201

Supplemental Hazard Statements none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Section 3 - Composition, Information on Ingredients

3.1 Substances
Synonyms : Disilver sulphate, Sulphuric acid disilver (I) salt
Formula : Ag2SO4
Molecular weight : 311.79 g/mol
CAS-No. : 10294-26-5
EC-No. : 233-653-7

Hazardous ingredients according to Regulation (EC) No 1272/2008

Component Classification Concentration

Disilver(1+) sulphate Eye Dam. 1; Aquatic Acute 1; Aquatic
CAS-No. 10294-26-5 Chronic 1; H318, H400, H410 M- <=100 %
EC-No. 233-653-7 Factor - Aquatic Acute: 100

For the full text of the H-Statements mentioned in this Section, see Section 16.

Section 4 - First Aid Measures

4.1 Description of first aid measures

General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11

4.3 Indication of any immediate medical attention and special treatment needed
No data available

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MATERIAL SAFETY DATA SHEET

SILVER SULPHATE

Revision : 01 Date: 10.03.2018 MSDS Number : 201

Section 5 - Firefighting Measures

5.1 Extinguishing media

Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Special hazards arising from the substance or mixture

Sulphur oxides, Silver/silver oxides

5.3 Advice for firefighters

Wear self-contained breathing apparatus for firefighting if necessary.

5.4 Further information

Use water spray to cool unopened containers

Section 6 - Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see
section 8.

6.2 Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.

6.3 Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers
for disposal.

6.4 Reference to other sections

For disposal see section 13.

Section 7 - Handling and Storage

7.1 Precautions for safe handling

Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is
formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Light sensitive. Storage
class (TRGS 510): Combustible Solids

7.3 Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

Section 8 - Exposure Controls, Personal Protection

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MATERIAL SAFETY DATA SHEET

SILVER SULPHATE

Revision : 01 Date: 10.03.2018 MSDS Number : 201

8.1 Control parameters

8.2 Exposure controls
Appropriat engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at
the end of workday
Personal protective equipment

Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal
technique (without touching glove's outer surface) to avoid skin contact with this product.
Dispose of contaminated gloves after use in accordance with applicable laws and good
laboratory practices. Wash and dry hands.

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC
and the standard EN 374 derived from it.

Full contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril® (KCL 740, Size M)

Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril® (KCL 740, Size M)

Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be
selected according to the concentration and amount of the dangerous substance at the specific
workplace.

Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use (EN 143)
respirator cartridges as a backup to engineering controls. If th full-face supplied air
respirator. Use respirators and components tested and approved under appropriate
government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided.

Section 9 - Physical and Chemical Properties

9.1 Information on basic physical and chemical properties

Appearance Form: crystalline
Colour: white
Odour No data available
Odour Threshold No data available

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MATERIAL SAFETY DATA SHEET

SILVER SULPHATE

Revision : 01 Date: 10.03.2018 MSDS Number : 201

pH No data available
Melting point/freezingpoint Melting point/range: 652 °C - lit
Initial boiling point and boiling range No data available
Flash point Not applicable
Evaporation rate No data available
Flammability (solid, gas) No data available
Upper/lower flammability or No data available
explosive limits No data available
Vapour pressure No data available
Vapour density No data available
Relative density 5.450 g/cm3
Water solubility No data available
Partition coefficient: noctanol/water No data available
Auto-ignition temperature No data available
Decomposition temperature No data available
Viscosity No data available
Explosive properties No data available
Oxidizing properties No data available

9.2 Other safety information

No data available

Section 10 - Stability and Reactivity

10.1 Reactivity
No data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

No data available

10.4 Conditions to avoid

Light.

10.5 Incompatible materials

Strong oxidizing agents

10.6 Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Sulphur oxides, Silver/silver oxides
Other decomposition products - No data available
In the event of fire: see section 5

Section 11 - Toxicological Information

11.1 Information on toxicological effects

Acute toxicity
No data availableDisilver(1+) sulphate

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MATERIAL SAFETY DATA SHEET

SILVER SULPHATE

Revision : 01 Date: 10.03.2018 MSDS Number : 201

Skin corrosion/irritation
Skin - Rabbit(Disilver(1+) sulphate)
Result: No skin irritation (OECD Test Guideline 404)

Serious eye damage/eye irritation

Eyes - Rabbit(Disilver(1+) sulphate)
Result: Risk of serious damage to eyes. (OECD Test Guideline 405)

Respiratory or skin sensitisation

No data available(Disilver(1+) sulphate)

Germ cell mutagenicity

No data available(Disilver(1+) sulphate)

Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity
No data available(Disilver(1+) sulphate)

Specific target organ toxicity - single exposure

No data available(Disilver(1+) sulphate))

Specific target organ toxicity - repeated exposure

No data available

Aspiration hazard
No data available(Disilver(1+) sulphate)

Additional Information
RTECS: Not available
May cause argyria (a slate-gray or bluish discoloration of the skin and de silver)., To the best of our
knowledge, the chemical, physical, and toxicological properties have not been thoroughly
investigated.(Disilver(1+) sulphate)

Section 12 - Ecological Information

12.1 Toxicity
Toxicity to fish
static test EC10 - Salmo trutta - 0.00019 mg/l - 217 d(Disilver(1+) sulphate)

Toxicity to daphnia and other aquatic invertebrates

EC50 - Daphnia (water flea) - 0.004 mg/l - 48 h(Disilver(1+) sulphate)

12.2 Persistence and degradability

The methods for determining biodegradability are not applicable to inorganic substances.

12.3 Bioaccumulative potential

Bioaccumulation
Oncorhynchus mykiss (rainbow trout) - 8 d at 15 °C(Disilver(1+) sulphate)
Bioconcentration factor (BCF): 2.5

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MATERIAL SAFETY DATA SHEET

SILVER SULPHATE

Revision : 01 Date: 10.03.2018 MSDS Number : 201

12.4 Mobility in soil

No data available(Disilver(1+) sulphate)

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Other adverse effects

Very toxic to aquatic life with long lasting effects.

Section 13 - Disposal Considerations

13.1 Waste treatment methods

Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
with a combustible solvent and burn in a chem scrubber.

Contaminated packaging
Dispose of as unused product.

Section 14 - Transport Information

14.1 UN number
ADR/RID: 3077 IMDG: 3077 IATA: 3077

14.2 UN proper shipping name

ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Disilver(1+)
sulphate)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Disilver(1+)
sulphate)
IATA: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Disilver(1+)
sulphate)

14.3 Transport hazard class(es)

ADR/RID: 9 IMDG: 9 IATA: 9

14.4 Packaging group

ADR/RID: I II IMDG: III IATA: III

14.5 Environmental hazards

ADR/RID: yes IMDG Marine pollutant: no IATA: yes

14.6 Special precautions for user

No data available

Section 15 - Regulatory Information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.2 Chemical safety assessment
For this product a chemical safety assessment was not carried out
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MATERIAL SAFETY DATA SHEET

SILVER SULPHATE

Revision : 01 Date: 10.03.2018 MSDS Number : 201

Section 16 - Additional Information

Full text of H-Statements referred to under sections 2 and 3.

H318 Causes serious eye damage.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

National Fire Protection Association (U.S.A.):

Health: 2
Flammability: 0
Reactivity: 0

Further information
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as
a guide. The information in this document is based on the present state of our knowledge and is applicable to
the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties
of the product. PT. Smartlab Indonesia Corporation and its Affiliates shall not be held liable for any damage
resulting from handling or from contact with the above product. See www.sigmaaldrich.com and/or the reverse
side of invoice or packing slip for additional terms and conditions of sale.

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