JPWO2014188715A1 - 半導体装置及びその製造方法 - Google Patents
半導体装置及びその製造方法 Download PDFInfo
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- 238000004519 manufacturing process Methods 0.000 title description 45
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- 230000008859 change Effects 0.000 claims description 3
- 238000009792 diffusion process Methods 0.000 abstract description 188
- 230000001629 suppression Effects 0.000 abstract description 163
- 230000004888 barrier function Effects 0.000 abstract description 145
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- 230000004048 modification Effects 0.000 description 65
- 238000012986 modification Methods 0.000 description 65
- 239000011777 magnesium Substances 0.000 description 60
- JMASRVWKEDWRBT-UHFFFAOYSA-N Gallium nitride Chemical compound [Ga]#N JMASRVWKEDWRBT-UHFFFAOYSA-N 0.000 description 52
- 229910002601 GaN Inorganic materials 0.000 description 51
- 229910002704 AlGaN Inorganic materials 0.000 description 50
- 238000001312 dry etching Methods 0.000 description 34
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- 239000013078 crystal Substances 0.000 description 15
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 13
- 230000006866 deterioration Effects 0.000 description 13
- 239000000758 substrate Substances 0.000 description 13
- 229910052782 aluminium Inorganic materials 0.000 description 12
- 238000005530 etching Methods 0.000 description 11
- 239000007789 gas Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- 230000007547 defect Effects 0.000 description 8
- 229910052738 indium Inorganic materials 0.000 description 8
- 238000002488 metal-organic chemical vapour deposition Methods 0.000 description 8
- 230000010287 polarization Effects 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 239000000470 constituent Substances 0.000 description 6
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 6
- 230000005684 electric field Effects 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 230000015556 catabolic process Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000005669 field effect Effects 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 238000004544 sputter deposition Methods 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 238000001771 vacuum deposition Methods 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- NWAIGJYBQQYSPW-UHFFFAOYSA-N azanylidyneindigane Chemical compound [In]#N NWAIGJYBQQYSPW-UHFFFAOYSA-N 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
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- 239000007769 metal material Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 description 1
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910019080 Mg-H Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
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- 239000012159 carrier gas Substances 0.000 description 1
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Abstract
Description
以下、第1の実施形態に係る半導体装置について、図4、5を参照しながら説明する。
図4は、本開示の第1の実施形態に係る窒化物半導体装置100の構成を示す断面図である。この窒化物半導体装置100は、本開示における半導体装置の一例であり、例えば電界効果トランジスタである。
次に、本実施形態に係る窒化物半導体装置の製造方法について説明する。図5の(a)〜(e)は、本実施形態に係る窒化物半導体装置100の製造工程を示す図である。
以下、第1の実施形態の変形例1について、図6を参照しながら説明する。
次に、第1の実施形態の変形例2について説明する。本変形例に係る窒化物半導体装置は、本開示における半導体装置の一例であり、第1の実施形態に係る窒化物半導体装置100とほぼ同じであるが、拡散抑制層にIn及びAlが添加されていない点が異なる。
次に、第1の実施形態の変形例3について説明する。本変形例に係る窒化物半導体装置は、本開示における半導体装置の一例であり、第1の実施形態の変形例2に係る窒化物半導体装置100とほぼ同じであるが、拡散抑制層がn型である点が異なる。
次に、第1の実施形態の変形例4について説明する。本変形例に係る窒化物半導体装置は、本開示における半導体装置の一例であり、第1の実施形態の変形例2に係る窒化物半導体装置160とほぼ同じであるが、チャネル層がアンドープGaNからなり、バリア層がアンドープAlGaNからなり、p型導電層がp型GaNからなる点が異なる。
次に、第1の実施形態の変形例5について説明する。本変形例に係る窒化物半導体装置は、半導体装置の一例であり、第1の実施形態に係る窒化物半導体装置100とほぼ同じであるが、拡散抑制層が、n型AluGa1−uN(u=0.03)で表される半導体層と、アンドープAlaGa1−aNで表される半導体層との積層構造である点が異なる。
以下、第2の実施形態について、図11を参照しながら説明する。本実施形態に係る窒化物半導体装置は、半導体装置の一例であり、第1の実施形態に係る窒化物半導体装置100とほぼ同じであるが、さらにバリア層104上に形成されたキャップ層を備える点が異なる。なお、以下に示す各実施形態において、上記第1の実施形態と実質的に同一の構成要素には同一の符号を付して、その説明を省略する場合がある。
次に、第3の実施形態について、図12を参照しながら説明する。本実施形態に係る窒化物半導体装置は、半導体装置の一例であり、第1の実施形態に係る窒化物半導体装置100とほぼ同じであるが、さらに、拡散抑制層105とp型導電層106との間に形成されたp型AlGaNからなるp型導電層を備える点が異なる。
次に、第4の実施形態について、図13を参照しながら説明する。本実施形態に係る窒化物半導体装置は、半導体装置の一例であり、第1の実施形態に係る窒化物半導体装置100とほぼ同じであるが、バリア層の上面がゲート電極107の下方に形成された凹部を有し、拡散抑制層が凹部に埋まるように形成されている点が異なる。
101 Si基板
102 バッファ層
103,112 チャネル層(第1の半導体層)
104,113,404 バリア層(第2の半導体層)
105,110,111A,111B,115,116,405 拡散抑制層(第3の半導体層)
106,114,301,406 p型導電層(第4の半導体層)
107 ゲート電極
107a ゲート電極層
108,903 ソース電極
109,904 ドレイン電極
404a 凹部
901 GaN層
902 AlGaNバリア層
905 p型GaN層
Claims (16)
- InpAlqGa1−p−qN(0≦p+q≦1、0≦p、0≦q)からなる第1の半導体層と、
前記第1の半導体層上に形成され、前記第1の半導体層よりバンドギャップの大きなInrAlsGa1−r−sN(0≦r+s≦1、0≦r)からなる第2の半導体層と、
前記第2の半導体層の上に選択的に形成され、IntAluGa1−t−uN(0≦t+u≦1、0≦t、s>u)からなる第3の半導体層と、
前記第3の半導体層の上に形成され、p型の導電性を有するInxAlyGa1−x−yN(0≦x+y≦1、0≦x、0≦y)からなる第4の半導体層と、
前記第4の半導体層の上に形成されたゲート電極とを備える
半導体装置。 - 前記第3の半導体層は、膜厚方向の長さあたりのp型ドーパント量の変化量が第4の半導体層における変化量よりも小さい
請求項1に記載の半導体装置。 - 前記第2の半導体層は、上面に形成された凹部を有し、
前記第3の半導体層は、積層方向から見て前記凹部の少なくとも一部が埋まるように形成されている
請求項1と2のいずれか1項に記載の半導体装置。 - 前記第3の半導体層は、積層方向から見て前記凹部が埋まるように形成されている
請求項3に記載の半導体装置。 - 前記第4の半導体層のp型ドーパントはMgであり、
前記第2の半導体層は、前記第3の半導体層と接する部分において、1×1019(/cm3)以下のMg濃度を有し、
前記第3の半導体層は、前記第2の半導体層と接する部分において、1×1019(/cm3)以下のMg濃度を有する
請求項1と2のいずれか1項に記載の半導体装置。 - 前記第3の半導体層がGaNである
請求項1と2のいずれか1項に記載の半導体装置。 - 前記第3の半導体層が1×1018(/cm3)以上のSi濃度を有する
請求項1と2のいずれか1項に記載の半導体装置。 - 前記第3の半導体層は、AlaGa1−aN(0<a≦1)からなる層と、GaNからなる層とが積層された構造である
請求項3に記載の半導体装置。 - 前記第3の半導体層のAlaGa1−aN(0<a≦1)からなる層が1×1018(/cm3)以上のSi濃度を有する
請求項8に記載の半導体装置。 - 前記第3の半導体層のGaNからなる層が1×1018(/cm3)以上のSi濃度を有する
請求項8に記載の半導体装置。 - 前記第2の半導体層が1×1018(/cm3)以上のSi濃度を有する
請求項1と2のいずれか1項に記載の半導体装置。 - 前記第2の半導体層は、前記第1の半導体層と接する側に形成されたSiをドーピングしていない層と、ソース電極及びドレイン電極と接する側に形成された1×1018(/cm3)以上のSi濃度を有する層とが積層された構造である
請求項1と2のいずれか1項に記載の半導体装置。 - 前記第4の半導体層がGaNである
請求項1と2のいずれか1項に記載の半導体装置。 - 前記第4の半導体層がAlzGa1−zN(0<z≦1)である
請求項1と2のいずれか1項に記載の半導体装置。 - 前記第4の半導体層は、前記第3の半導体層と接する側に形成されたAlzGa1−zN(0<z≦1)からなる層と、ゲート電極と接する側に形成されたGaNからなる層とが積層された構造である
請求項1と2のいずれか1項に記載の半導体装置。 - InpAlqGa1−p−qN(0≦p+q≦1、0≦p、0≦q)からなる第1の半導体層を形成する工程と、
前記第1の半導体層上に、前記第1の半導体層よりバンドギャップの大きなInrAlsGa1−r−sN(0≦r+s≦1、0≦r)からなる第2の半導体層を形成する工程と、
前記第2の半導体層の上に、IntAluGa1−t−uN(0≦t+u≦1、0≦t、s>u)からなる第3の半導体層を形成する工程と、
前記第3の半導体層の上に、p型の導電性を有するInxAlyGa1−x−yN(0≦x+y≦1、0≦x、0≦y)からなる第4の半導体層を形成する工程と、
前記第4の半導体層の上にゲート電極を形成する工程と、
前記第4の半導体層を形成する工程の後、前記第3の半導体層および前記第4の半導体層のうち前記ゲート電極に対応する領域以外を除去する工程とを含む
半導体装置の製造方法。
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