JP5586466B2 - レーザー感受性被覆組成物 - Google Patents
レーザー感受性被覆組成物 Download PDFInfo
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- JP5586466B2 JP5586466B2 JP2010521393A JP2010521393A JP5586466B2 JP 5586466 B2 JP5586466 B2 JP 5586466B2 JP 2010521393 A JP2010521393 A JP 2010521393A JP 2010521393 A JP2010521393 A JP 2010521393A JP 5586466 B2 JP5586466 B2 JP 5586466B2
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- polymer
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- tungsten
- laser
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- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 1
- 229940075614 colloidal silicon dioxide Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 150000002016 disaccharides Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- NRJXUPLBIUZXLW-UHFFFAOYSA-N ethene;prop-1-ene;styrene Chemical compound C=C.CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 NRJXUPLBIUZXLW-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006025 fining agent Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- XLYMOEINVGRTEX-UHFFFAOYSA-N fumaric acid monoethyl ester Natural products CCOC(=O)C=CC(O)=O XLYMOEINVGRTEX-UHFFFAOYSA-N 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical group NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229940087248 metasol Drugs 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 150000002772 monosaccharides Chemical class 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- MVLMQGYYLCWMFP-UHFFFAOYSA-N neodymium yttrium Chemical compound [Y].[Nd] MVLMQGYYLCWMFP-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 239000001254 oxidized starch Substances 0.000 description 1
- 235000013808 oxidized starch Nutrition 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- HDBWAWNLGGMZRQ-UHFFFAOYSA-N p-Vinylbiphenyl Chemical group C1=CC(C=C)=CC=C1C1=CC=CC=C1 HDBWAWNLGGMZRQ-UHFFFAOYSA-N 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 1
- 239000013034 phenoxy resin Substances 0.000 description 1
- 229920006287 phenoxy resin Polymers 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 1
- 229920001490 poly(butyl methacrylate) polymer Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- 238000010023 transfer printing Methods 0.000 description 1
- IKXFIBBKEARMLL-UHFFFAOYSA-N triphenoxy(sulfanylidene)-$l^{5}-phosphane Chemical class C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=S)OC1=CC=CC=C1 IKXFIBBKEARMLL-UHFFFAOYSA-N 0.000 description 1
- 238000001392 ultraviolet--visible--near infrared spectroscopy Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/267—Marking of plastic artifacts, e.g. with laser
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/26—Thermosensitive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Optics & Photonics (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Description
実施例1:アナターゼ型の二酸化チタンを含む組成物の製造
(白色グラビアインキ)
Wacker Chemie AG製のVinnapas(登録商標)C501樹脂(酸価7.5mg KOH/g、分子量170000g/モル及びTg約43℃を有する、酢酸ビニルとクロトン酸との固体のコポリマー)(20部)と、酢酸プロピル(80部)とを混合することによってワニスを調製する。Huntsmanから市販のTioxide(登録商標)A−HR、0.15μmの結晶サイズを有するアナターゼ型の二酸化チタン(45部)を、次いで予め調製されたワニス(55部)に5分間にわたって添加して、白いグラビアインキを製造する。
実施例1のインキを、標準的なK2バーを使用して標準的なタバコの包装紙に適用し、その後乾燥させる。1064nmでのNd:YAGレーザーを用いた描画は、優れた品質のマーキングをもたらす。
実施例1で製造されたインキを、標準的なK2バーを使用して標準的なタバコの包装紙に適用し、その後乾燥させる。Neorez R−1010から製造されたオーバーラッカーを、DSM Neoresinsから市販のウレタン分散液(90部)、水(5部)及びエポキシプロパノール(5部)を次いで標準的なK2バーを使用して印刷物の上に塗布し、その後乾燥させる。保護的なトップコートにもかかわらず、1064nmでのNd:YAGレーザーを用いた描画は、なお優れた品質の暗いマーキングを白色背景の上に与える。
実施例1で製造されたインキを、標準的なK2バーを使用してクラフトボールに適用し、その後乾燥させる。実施例3に記載されたオーバーラッカーを、次いで、標準的なK2バーを使用して印刷物の上に塗布し、その後乾燥させる。保護的なトップコートにもかかわらず、1064nmでのNd:YAGレーザーを用いた描画は、なお優れた品質の暗いマーキングを白色背景の上に与える。
実施例1で製造されたインキを、標準的なK2バーを使用して被覆された紙に適用し、その後乾燥させる。実施例3に記載されたオーバーラッカーを、次いで、標準的なK2バーを使用して印刷物の上に適用し、その後乾燥させる。保護的なトップコートにもかかわらず、1064nmでのNd:YAGレーザーを用いた描画は、なお優れた品質の暗いマーキングを白色背景の上に与える。
実施例1で製造されたインキを、標準的なK2バーを使用して不透明な配向ポリプロピレンフィルムに適用し、その後乾燥させる。実施例3に記載されたオーバーラッカーを、次いで、標準的なK2バーを使用して印刷物の上に塗布し、その後乾燥させる。保護的なトップコートにもかかわらず、1064nmでのNd:YAGレーザーを用いた描画は、なお優れた品質の暗いマーキングを白色背景の上に与える。
実施例1で製造されたインキを、標準的なK2バーを使用して透明な配向ポリプロピレンフィルムに適用し、その後乾燥させる。このレーザー転写シートを、次いでタバコボードに向かって被覆された側でタバコボードに接触させて配置する。ポリプロピレンの被覆されていない側からのNd:YAGレーザーによる像がポリプロピレンをマーキングするだけでなく、該像は転写されてタバコボード上に高コントラストのマーキングを与える。
Vinnapas(登録商標)C501樹脂(実施例1を参照)(20部)と酢酸プロピル(80部)とを混合することによってワニスを調製する。Huntsmanから市販のTioxide(登録商標)R−XL、ルチル型の二酸化チタン(45部)を、次いで予め調製されたワニス(55部)に5分間にわたって添加して、白いグラビアインキを製造する。
比較例1のインキを、標準的なK2バーを使用して標準的なタバコの包装紙に適用し、その後乾燥させる。1064nmでのNd:YAGレーザーを用いた描画は、実施例2で得られるマーキングよりも(低コントラストの)弱い、マーキングを与える。
分子量200000g/molを有する32質量%の70/30(質量比)スチレン−メチルメタクリレートコポリマーを分子量6000g/molを有する14質量%の65/35(質量比)のスチレン−アクリル酸コポリマーで安定化したものを含有する46質量%のポリマーマイクロエマルション100gを、水100gで希釈することによって水相を調製し、次にTioxide(登録商標)A−HR(Huntsmanから販売の結晶サイズ0.15μmを有するアナターゼ型の二酸化チタン)50gと、架橋剤として機能する亜鉛酸化物5gとを高速ミキサーの下で分散させる。別個に、分子量40000g/モルを有し、両親媒性安定剤として機能する90/10(質量比)ステアリルメタクリレート−メタクリル酸コポリマーの20質量%溶液30gと、lsopar G(蒸留範囲155〜179℃を有するイソパラフィン、ExxonMobilから入手可能)500gとを混合することによって油相を調製する。上記の水相を、高剪断ホモジナイザの下で油相に添加して、平均粒径10〜20μmの水性の液滴を有する油中水型エマルションを形成する。形成されたエマルションを、蒸留用に設定された1リットルのフラスコに移す。エマルションを真空蒸留に供して、水/lsopar G混合物を除去する。真空蒸留を100℃で、留出物内に水が収集されなくなるまで続ける。次に、フラスコの内容物を25℃に冷却し、封入されたアナターゼ型二酸化チタンを含むポリマー粒子を濾過によって単離し、且つ90℃のオーブンで乾燥させる。最終的な生成物は平均粒径14μmを有する易流動性の白く着色されたポリマー粒子である。
Vinnapas(登録商標)C501樹脂(実施例1を参照)(20部)と酢酸プロピル(80部)とを混合することによってワニスを調製する。実施例8のアナターゼ型の封入された二酸化チタンを含むポリマー粒子(90部)を、予め調製されたワニス(55部)に5分間にわたって添加して、白いグラビアインキを製造する。
実施例9のインキを、標準的なK2バーを使用して標準的なタバコの包装紙に適用し、その後乾燥させる。1064nmでのNd:YAGレーザーを用いた描画は明確に読み取れるマーキングを生成する。
パラタングステン酸アンモニウム粉末((NH4)10W12H20O42・4H2O、Osram Sylvania)を、10g/分で動作する振動型粉末フィーダーによってアルゴンキャリアガス中に一緒に運ぶ。流動粉末を、65kWの出力で動作するTekna PL−50プラズマトーチを有するプラズマ反応器中へ供給する。典型的に反応器のプラズマ高温領域に達する温度範囲は5000〜10,000Kである。100slpmアルゴンと2slpm水素の混合物[slpm=standard liters per minute;slpmの計算の標準条件は次のように定義される:Tn0℃(32°F),Pn=1.01バール(14.72psi)]をシースガスに使用する。反応物の蒸気をクエンチガスによって冷却し且つ得られた粉末をバグフィルター中に回収する。得られた粉末を粉末X線回析、電子顕微鏡、及びUV−vis−NIR分光法によって分析し、該粉末は35.59質量%のWO3H0.53(特定の「水素タングステンブロンズ」)、55.73質量%のWO3及び8.69質量%のWで構成されることが見出される。
Rofin、ネオジムイットリウムバナデート(Nd:YVO4)1064nm 10w
1500mms 20kHz fill 60、出力は10〜25Aである
レーザー設定は、設計及び要求される品質によって速度、出力及び周波数が変化する。
赤外線吸収剤としてWO3H0.53、WO3及びWからなる混合物0.1%を含有する実施例11に記載されたインク(以下インクZと示される)、並びに45.0質量%のA−HRアナターゼ型TiO2(実施例1で記載された)、53.6質量%のC501 Varnish(実施例1で記載された)及び1.4質量%(実施例12に記載されたように0.1%ではない)の六ホウ化ランタンから構成されるインク(以下インクYと示される)を、それぞれ、上記吸収剤を含まない類似のインク(以下インクXと示される)と比較する。
Claims (13)
- アナターゼ型の二酸化チタン及びポリマーバインダーを含む組成物であって、該化合物は、タングステン亜酸化物、タングステンブロンズ、又は三酸化タングステン、タングステンブロンズ及び金属タングステンの混合物を更に含む、組成物。
- 組成物は、式WO3−X(式中、xは0.1〜1である)のタングステン酸化物を含む、請求項1に記載の組成物。
- タングステン酸化物は、WO2.7である、請求項2に記載の組成物。
- 基材上にレーザー感受性被覆層を形成する方法において、i)請求項1〜3のいずれか1項に記載の組成物を基材に適用する工程及びii)レーザー感受性被覆層を形成する工程を含む、基材上にレーザー感受性被覆層を形成する方法。
- 基材が紙、ボール紙又はポリマーである、請求項4に記載の方法。
- 請求項4又は5に記載の方法によって得られたレーザー感受性被覆層、及び所望の場合、その上に保護被覆層を有する基材。
- マーキングされた基材の製造方法において、i)請求項6に記載の基材を提供する工程、及びiii)工程i)の基材のマーキングが意図されている部分を赤外線レーザー照射に曝してマーキングを生成する工程を含む、マーキングされた基材の製造方法。
- マーキングされた基材の製造方法において、i)1種又は複数種の水不溶性ポリマーを含むポリマーマトリックスと該ポリマーマトリックス中に封入されたアナターゼ型の二酸化チタンとを含むポリマー粒子及びポリマーバインダーを含む組成物を基材に適用する工程、及びii)被覆された基材のマーキングを意図する部分を赤外線レーザー照射に曝してマーキングを生成する工程を含む、マーキングされた基材の製造方法。
- 組成物は、赤外線吸収剤をさらに含む、請求項8に記載の方法。
- 組成物は、タングステン亜酸化物、タングステンブロンズ、又は三酸化タングステン、タングステンブロンズ及び金属タングステンの混合物を更に含む、請求項9に記載の方法。
- 組成物は、式WO3−X(式中、xは0.1〜1である)のタングステン酸化物を含む、請求項10に記載の方法。
- タングステン酸化物は、WO2.7である、請求項11に記載の方法。
- 基材が紙、ボール紙又はポリマーである、請求項8〜12のいずれか1項に記載の方法。
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-
2008
- 2008-08-12 ES ES08787124T patent/ES2377852T3/es active Active
- 2008-08-12 WO PCT/EP2008/060550 patent/WO2009024497A1/en active Application Filing
- 2008-08-12 AT AT08787124T patent/ATE538185T1/de active
- 2008-08-12 CN CN2008801038511A patent/CN101784620B/zh not_active Expired - Fee Related
- 2008-08-12 CA CA2696032A patent/CA2696032A1/en not_active Abandoned
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- 2008-08-12 JP JP2010521393A patent/JP5586466B2/ja active Active
- 2008-08-12 EP EP08787124A patent/EP2181163B1/en active Active
- 2008-08-12 KR KR1020107006045A patent/KR20100077149A/ko not_active Application Discontinuation
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EP2181163A1 (en) | 2010-05-05 |
US20110065576A1 (en) | 2011-03-17 |
JP2010536970A (ja) | 2010-12-02 |
EP2181163B1 (en) | 2011-12-21 |
WO2009024497A1 (en) | 2009-02-26 |
CN101784620B (zh) | 2013-05-29 |
TW200911561A (en) | 2009-03-16 |
ES2377852T3 (es) | 2012-04-02 |
CA2696032A1 (en) | 2009-02-26 |
KR20100077149A (ko) | 2010-07-07 |
CN101784620A (zh) | 2010-07-21 |
US9045619B2 (en) | 2015-06-02 |
ATE538185T1 (de) | 2012-01-15 |
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