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CN102653665A - Hot melt adhesive - Google Patents

Hot melt adhesive Download PDF

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Publication number
CN102653665A
CN102653665A CN2012101311210A CN201210131121A CN102653665A CN 102653665 A CN102653665 A CN 102653665A CN 2012101311210 A CN2012101311210 A CN 2012101311210A CN 201210131121 A CN201210131121 A CN 201210131121A CN 102653665 A CN102653665 A CN 102653665A
Authority
CN
China
Prior art keywords
parts
hot melt
melt adhesive
wax
eva
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2012101311210A
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Chinese (zh)
Inventor
曾维松
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHENGDU XINSANYANG TECHNOLOGY Co Ltd
Original Assignee
CHENGDU XINSANYANG TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHENGDU XINSANYANG TECHNOLOGY Co Ltd filed Critical CHENGDU XINSANYANG TECHNOLOGY Co Ltd
Priority to CN2012101311210A priority Critical patent/CN102653665A/en
Publication of CN102653665A publication Critical patent/CN102653665A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a hot melt adhesive which comprises the following components in parts by mass: 5-10 parts of EVA (ethylene-co-vinyl acetate), 2-6 parts of tackifier, 5-10 parts of diluent, 0.5-1.5 parts of antioxidant and 0.5-1.5 parts of plasticizer. The tackifier is one of rosin resin, petroleum resin, terpene resin, phenolic resin and epoxy resin; the diluent includes one or both of wax and low-molecular polyolefin; the antioxidant is phenolic antioxidant; and the plasticizer is DCHP (Dicyclohexyl phthalate). The EVA contains 20-30% of vinyl acetate monomer; and the wax is microcrystalline wax with molecular weight of 3,000-4,000 and melting point of 65-85 DEG C.

Description

A kind of hot melt adhesive
Technical field
The embodiment of the invention relates to hot melt adhesive and preparation method thereof.
Background technology
Hot melt adhesive is a kind of plastic tackiness agent; Its physical condition changes with temperature change in certain temperature range, and chemical property is constant, and is nonpoisonous and tasteless; Belong to the environmental-protecting chemical product; The many at home industries of hot melt adhesive are used widely, and the cables manufacturing industry also has use Hot melt adhesive tape or hot melt adhesive film to be wrapped in needs bonding cable position, and bonding effect is played in the fusing of heating back.Present existing cable with the melt viscosity relay a little less than, melt viscosity is big, facility investment is big, production rate is slow, can not adapt to the needs of bonding cable.
Summary of the invention
The invention reside in the defective that solves above-mentioned prior art, the hot melt adhesive that a kind of bonding force is strong, melt viscosity is little is provided.
For solving above-mentioned technical problem, the present invention adopts following technical scheme:
A kind of hot melt adhesive comprises following component: EVA (chemical English name: ethylene-vinyl acetate copolymer by this hot melt adhesive of mass parts; Chemical Chinese: 5-10 part ethylene-vinyl acetate copolymer); Tackifier 2-6 part; Thinner 5-10 part; Oxidation inhibitor 0.5-1.5 part; Softening agent 0.5-1.5 part.
Hot melt adhesive of the present invention, tackifier are a kind of in Gum Rosin, petroleum resin, terpine resin, resol, the epoxy resin; Thinner is one or both in wax, the low molecular weight polycaprolactone alkene; The oxidation inhibitor kind antioxidant; Softening agent is a DCHP (chemical English name: Dicyclohexyl Phthalate; Chemical Chinese: dicyclohexyl phthalate).
Hot melt adhesive of the present invention comprises 8 parts of following component: EVA by this hot melt adhesive of mass parts; 4 parts of tackifier; 8 parts of thinners; 1 part in oxidation inhibitor; 1 part in softening agent.
Hot melt adhesive of the present invention, tackifier are Gum Rosins; Thinner is wax, low molecular weight polycaprolactone alkene; Oxidation inhibitor is phenolic antioxidant; Softening agent is DCHP.
Hot melt adhesive of the present invention comprises 8 parts of following component: EVA by this hot melt adhesive of mass parts; 4 parts of Gum Rosins; 4 parts in wax; 4 parts in low molecular weight polycaprolactone alkene; 1 part of phenolic antioxidant; 1 part of DCHP.
Hot melt adhesive of the present invention, said EVA contains the 20%-30% vinyl acetate monomer.
Hot melt adhesive of the present invention, said wax are that molecular weight is that 3000-4000, fusing point are 65 ℃-85 ℃ Microcrystalline Wax.
A kind of method for preparing hot melt adhesive comprises EVA, tackifier, thinner is mixed by a certain percentage, heats then, stirs, melts, cools off, and adopts the heated at high speed mixing machine to stir, and stirring velocity is 200 rev/mins-750 rev/mins; Heating temperature is 200 ℃-400 ℃; Adopt cooling demoulding technology that hot melt adhesive is cooled off then, cooling temperature is 10 ℃-25 ℃.
The method for preparing hot melt adhesive of the present invention, the churning time of said heated at high speed mixing machine are 500 rev/mins; Heating temperature is 300 ℃.
The method for preparing hot melt adhesive of the present invention, said cooling demoulding technology is that hot melt adhesive is flowed on the cloth, and cloth is layered on the mould, naturally cooling in air, cooling temperature are 15 ℃.
The method for preparing hot melt adhesive of the present invention, said cloth are through resin processed cloth.
The method for preparing hot melt adhesive of the present invention, cloth and mould can be changed.
Advantage of the present invention:
1, formulating of recipe of the present invention is reasonable, is more suitable for the requirement of cable production technique, and it is strong to have a bonding force, the characteristics that melt viscosity is little.
2, production technique is reasonable, and facility investment is little, and production rate is fast.
3, the no three wastes produce, and have reduced the pollution to environment.
Embodiment
According to one embodiment of present invention, this hot melt adhesive is mixed by mass parts by following material, 5 parts of EVA; 2 parts of Gum Rosins; 2 parts in wax; 3 parts in low molecular weight polycaprolactone alkene; 0.5 part of phenolic antioxidant; 0.5 part of DCHP; Said EVA contains 30% vinyl acetate monomer; Said Gum Rosin softening temperature is 100 ℃; Said wax is that molecular weight is 3000, fusing point is 65 ℃ Microcrystalline Wax.
According to one embodiment of present invention, mix 8 parts of EVA by mass parts by following material; 4 parts of Gum Rosins; 4 parts in wax; 4 parts in low molecular weight polycaprolactone alkene; 1.5 parts of phenolic antioxidants; 1.5 parts of DCHP; Said EVA contains 35% vinyl acetate monomer; 110 ℃ of said Gum Rosins; Said wax is that molecular weight is 4000, fusing point is 85 ℃ Microcrystalline Wax.
According to one embodiment of present invention, with 8 parts of EVA, 4 parts of Gum Rosins, 4 parts in wax, 4 parts in low molecular weight polycaprolactone alkene, 1 part of phenolic antioxidant, 1 part of mixing of DCHP, adopt the heated at high speed mixing machine to stir, stirring velocity is 200 rev/mins; Heating temperature is 200 ℃; Then hot melt adhesive is flowed into through on the resin processed cloth, cloth is layered on the mould, naturally cooling in air, cooling temperature are 10 ℃.
According to one embodiment of present invention, with 8 parts of EVA, 4 parts of Gum Rosins, 4 parts in wax, 4 parts in low molecular weight polycaprolactone alkene, 1 part of phenolic antioxidant, 1 part of mixing of DCHP, adopt the heated at high speed mixing machine to stir, stirring velocity is 700 rev/mins; Heating temperature is 400 ℃; Then hot melt adhesive is flowed into through on the resin processed cloth, cloth is layered on the mould, naturally cooling in air, cooling temperature are 20 ℃.
Above-described embodiment describes embodiment of the present invention; Be not that this scope is limited; Design under the prerequisite of spirit not breaking away from the present invention; Various distortion and improvement that those of ordinary skills make technical scheme of the present invention all should fall in the definite protection domain of claims of the present invention.

Claims (7)

1. a hot melt adhesive is characterized in that, comprises following component by this hot melt adhesive of mass parts: EVA 5-10 part; Tackifier 2-6 part; Thinner 5-10 part; Oxidation inhibitor 0.5-1.5 part; Softening agent 0.5-1.5 part.
2. hot melt adhesive according to claim 1 is characterized in that, tackifier are a kind of in Gum Rosin, petroleum resin, terpine resin, resol, the epoxy resin; Thinner is one or both in wax, the low molecular weight polycaprolactone alkene; Oxidation inhibitor is phenolic antioxidant; Softening agent is DCHP.
3. hot melt adhesive according to claim 1 is characterized in that, comprises 8 parts of following component: EVA by this hot melt adhesive of mass parts; 4 parts of tackifier; 8 parts of thinners; 1 part in oxidation inhibitor; 1 part in softening agent.
4. hot melt adhesive according to claim 2 is characterized in that tackifier are Gum Rosins; Thinner is wax, low molecular weight polycaprolactone alkene.
5. hot melt adhesive according to claim 4 is characterized in that, comprises 8 parts of following component: EVA by this hot melt adhesive of mass parts; 4 parts of Gum Rosins; 4 parts in wax; 4 parts in low molecular weight polycaprolactone alkene; 1 part of phenolic antioxidant; 1 part of DCHP.
6. hot melt adhesive according to claim 5 is characterized in that said EVA contains the 20%-30% vinyl acetate monomer.
7. hot melt adhesive according to claim 5 is characterized in that, said wax is that molecular weight is that 3000-4000, fusing point are 65-85 ℃ Microcrystalline Wax.
CN2012101311210A 2012-04-28 2012-04-28 Hot melt adhesive Pending CN102653665A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012101311210A CN102653665A (en) 2012-04-28 2012-04-28 Hot melt adhesive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2012101311210A CN102653665A (en) 2012-04-28 2012-04-28 Hot melt adhesive

Publications (1)

Publication Number Publication Date
CN102653665A true CN102653665A (en) 2012-09-05

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN2012101311210A Pending CN102653665A (en) 2012-04-28 2012-04-28 Hot melt adhesive

Country Status (1)

Country Link
CN (1) CN102653665A (en)

Cited By (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103013392A (en) * 2012-11-22 2013-04-03 芜湖众力部件有限公司 Special epoxidized cottonseed butyl oleate-containing binding agent for compositing woven fabric on surfaces of automotive upholsteries
CN103087655A (en) * 2012-11-22 2013-05-08 芜湖众力部件有限公司 Special epoxy-cotton-oil-containing binding agent for automobile interior ornament surface composite leather
CN103386462A (en) * 2013-08-13 2013-11-13 厦门固特威蜡制品有限公司 Adhesive wax
CN103387803A (en) * 2013-07-01 2013-11-13 江苏达胜热缩材料有限公司 Hot melt adhesive
CN103468167A (en) * 2013-08-13 2013-12-25 安徽东方金河精密机械制造有限公司 Anti-ultraviolet EVA hot melt adhesive
CN103468156A (en) * 2013-08-13 2013-12-25 蚌埠市鸿安精密机械有限公司 Anti-aging eva hot melt adhesive
CN103468166A (en) * 2013-08-13 2013-12-25 蚌埠市鸿安精密机械有限公司 Anticorrosive hot melt adhesive
CN103468163A (en) * 2013-08-13 2013-12-25 蚌埠市鸿安精密机械有限公司 Flame retardant hot melt adhesive containing modified fire retardant
CN103468164A (en) * 2013-08-13 2013-12-25 蚌埠市鸿安精密机械有限公司 Modified filler-containing hot melt adhesive used for PVC hoses
CN103509493A (en) * 2013-09-18 2014-01-15 滁州市光威化工有限公司 Hot melt adhesive for automobile interior trim part
CN103571396A (en) * 2013-10-24 2014-02-12 芜湖众力部件有限公司 Environmental-friendly hot melt adhesive
CN103571416A (en) * 2013-10-24 2014-02-12 芜湖众力部件有限公司 Nano clay containing hot melt adhesive
CN103571407A (en) * 2013-10-24 2014-02-12 芜湖众力部件有限公司 Automotive upholstery hot melt adhesive not easy to crack
CN103571392A (en) * 2013-10-24 2014-02-12 芜湖众力部件有限公司 Anti-corrosion hot melt adhesive for automotive upholstery
CN103571391A (en) * 2013-10-24 2014-02-12 芜湖众力部件有限公司 Environmental-friendly non-toxic hot melt adhesive
CN103602289A (en) * 2013-10-28 2014-02-26 江苏达胜热缩材料有限公司 Pipeline joint watertightness anticorrosion hot melt adhesive
CN103788895A (en) * 2014-01-14 2014-05-14 安徽金门工贸有限公司 Hot melt adhesive special for producing cables
CN103788893A (en) * 2014-01-14 2014-05-14 安徽金门工贸有限公司 Hot melt adhesive for medical dialyzing paper
CN103788892A (en) * 2014-01-14 2014-05-14 安徽金门工贸有限公司 Hot melt glue for optical fiber cable
CN104119820A (en) * 2014-07-08 2014-10-29 安徽神舟飞船胶业有限公司 Paper-use low temperature EVA (ethylene-vinyl acetate copolymer) hot melt adhesive formulation and preparation process thereof
CN104388019A (en) * 2014-12-06 2015-03-04 赵冯 Hot melt adhesive
CN105038618A (en) * 2015-07-31 2015-11-11 全椒海丰印刷包装有限公司 High softening point hot melt adhesive containing microcrystalline wax
CN105566967A (en) * 2016-01-23 2016-05-11 中山顺富节能科技有限公司 Corrosion-resistant water dispenser electricity saving device
CN105694765A (en) * 2016-03-16 2016-06-22 苏州华周胶带有限公司 Sizing material short in curing time
CN105733473A (en) * 2016-04-14 2016-07-06 金猴集团威海鞋业有限公司 EVA-based nano-modification anti-bacterial function hot melt adhesive material
CN106833458A (en) * 2017-01-05 2017-06-13 毕同召 A kind of household electrical appliances foaming PUR and preparation method thereof
CN107365564A (en) * 2017-08-23 2017-11-21 和平世家钟表有限公司 A kind of novel glue and preparation method and application
CN108977122A (en) * 2018-06-22 2018-12-11 安徽索亚装饰材料有限公司 A kind of tackifier improving EVA hot-melt adhesive glue performance
CN110467906A (en) * 2019-08-28 2019-11-19 佛山市南海骏驰新材料有限公司 A kind of heat molten type carpenter overlay film glue and its production technology
CN111635712A (en) * 2020-06-18 2020-09-08 无锡奥飞斯商用地毯有限公司 Soft-bottom square carpet and preparation method thereof
CN113021159A (en) * 2021-03-12 2021-06-25 安徽禾臣新材料有限公司 Polishing pad for fine polishing of electronic display screen and production method thereof
CN113528037A (en) * 2021-06-22 2021-10-22 广东硕成科技有限公司 Medical protective clothing adhesive tape and preparation method thereof
CN114958248A (en) * 2022-07-04 2022-08-30 盛虹石化集团上海新材料有限公司 Hot melt adhesive and preparation method thereof

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CN101538450A (en) * 2009-04-29 2009-09-23 同济大学 High speed cigarette mouth building hot melt adhesive and preparation method thereof
CN101928530A (en) * 2010-09-02 2010-12-29 上海天洋热熔胶有限公司 Edge sealing hot melt adhesive for furniture and preparation method thereof

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EP0776955A1 (en) * 1995-12-01 1997-06-04 H.B. Fuller Licensing & Financing, Inc. Hot melt adhesive
CN1687280A (en) * 2005-06-03 2005-10-26 江苏工业学院 New type hot-melt adhesive and preparation method thereof
CN101538450A (en) * 2009-04-29 2009-09-23 同济大学 High speed cigarette mouth building hot melt adhesive and preparation method thereof
CN101928530A (en) * 2010-09-02 2010-12-29 上海天洋热熔胶有限公司 Edge sealing hot melt adhesive for furniture and preparation method thereof

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Cited By (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103087655A (en) * 2012-11-22 2013-05-08 芜湖众力部件有限公司 Special epoxy-cotton-oil-containing binding agent for automobile interior ornament surface composite leather
CN103013392A (en) * 2012-11-22 2013-04-03 芜湖众力部件有限公司 Special epoxidized cottonseed butyl oleate-containing binding agent for compositing woven fabric on surfaces of automotive upholsteries
CN103387803A (en) * 2013-07-01 2013-11-13 江苏达胜热缩材料有限公司 Hot melt adhesive
CN103468164A (en) * 2013-08-13 2013-12-25 蚌埠市鸿安精密机械有限公司 Modified filler-containing hot melt adhesive used for PVC hoses
CN103468167A (en) * 2013-08-13 2013-12-25 安徽东方金河精密机械制造有限公司 Anti-ultraviolet EVA hot melt adhesive
CN103468156A (en) * 2013-08-13 2013-12-25 蚌埠市鸿安精密机械有限公司 Anti-aging eva hot melt adhesive
CN103468166A (en) * 2013-08-13 2013-12-25 蚌埠市鸿安精密机械有限公司 Anticorrosive hot melt adhesive
CN103468163A (en) * 2013-08-13 2013-12-25 蚌埠市鸿安精密机械有限公司 Flame retardant hot melt adhesive containing modified fire retardant
CN103386462A (en) * 2013-08-13 2013-11-13 厦门固特威蜡制品有限公司 Adhesive wax
CN103468163B (en) * 2013-08-13 2016-02-10 蚌埠市鸿安精密机械有限公司 A kind of flame-retardant hot-melt adhesive containing modified flame-retardant agent
CN103468164B (en) * 2013-08-13 2016-02-10 蚌埠市鸿安精密机械有限公司 A kind of PVC hose hot melt adhesive containing modified filler
CN103468166B (en) * 2013-08-13 2016-02-10 蚌埠市鸿安精密机械有限公司 A kind of antiseptic hot melt glue
CN103468167B (en) * 2013-08-13 2016-02-10 安徽东方金河精密机械制造有限公司 A kind of Anti-ultraviolet EVA hot melt adhesive
CN103468156B (en) * 2013-08-13 2015-07-22 蚌埠市鸿安精密机械有限公司 Anti-aging eva hot melt adhesive
CN103509493A (en) * 2013-09-18 2014-01-15 滁州市光威化工有限公司 Hot melt adhesive for automobile interior trim part
CN103509493B (en) * 2013-09-18 2016-03-23 滁州市光威化工有限公司 A kind of Hot melt adhesive for automobile interior trim part
CN103571407B (en) * 2013-10-24 2015-06-17 芜湖众力部件有限公司 Automotive upholstery hot melt adhesive not easy to crack
CN103571391A (en) * 2013-10-24 2014-02-12 芜湖众力部件有限公司 Environmental-friendly non-toxic hot melt adhesive
CN103571391B (en) * 2013-10-24 2016-04-13 芜湖众力部件有限公司 A kind of Environmental-friendnon-toxic non-toxic hot melt adhesive
CN103571392B (en) * 2013-10-24 2016-04-13 芜湖众力部件有限公司 A kind of Anti-corrosion hot melt adhesive for automotive upholstery
CN103571396A (en) * 2013-10-24 2014-02-12 芜湖众力部件有限公司 Environmental-friendly hot melt adhesive
CN103571416B (en) * 2013-10-24 2015-06-17 芜湖众力部件有限公司 Nano clay containing hot melt adhesive
CN103571416A (en) * 2013-10-24 2014-02-12 芜湖众力部件有限公司 Nano clay containing hot melt adhesive
CN103571407A (en) * 2013-10-24 2014-02-12 芜湖众力部件有限公司 Automotive upholstery hot melt adhesive not easy to crack
CN103571392A (en) * 2013-10-24 2014-02-12 芜湖众力部件有限公司 Anti-corrosion hot melt adhesive for automotive upholstery
CN103602289A (en) * 2013-10-28 2014-02-26 江苏达胜热缩材料有限公司 Pipeline joint watertightness anticorrosion hot melt adhesive
CN103788893A (en) * 2014-01-14 2014-05-14 安徽金门工贸有限公司 Hot melt adhesive for medical dialyzing paper
CN103788895A (en) * 2014-01-14 2014-05-14 安徽金门工贸有限公司 Hot melt adhesive special for producing cables
CN103788892A (en) * 2014-01-14 2014-05-14 安徽金门工贸有限公司 Hot melt glue for optical fiber cable
CN104119820A (en) * 2014-07-08 2014-10-29 安徽神舟飞船胶业有限公司 Paper-use low temperature EVA (ethylene-vinyl acetate copolymer) hot melt adhesive formulation and preparation process thereof
CN104388019A (en) * 2014-12-06 2015-03-04 赵冯 Hot melt adhesive
CN105038618A (en) * 2015-07-31 2015-11-11 全椒海丰印刷包装有限公司 High softening point hot melt adhesive containing microcrystalline wax
CN105566967A (en) * 2016-01-23 2016-05-11 中山顺富节能科技有限公司 Corrosion-resistant water dispenser electricity saving device
CN105694765A (en) * 2016-03-16 2016-06-22 苏州华周胶带有限公司 Sizing material short in curing time
CN105733473A (en) * 2016-04-14 2016-07-06 金猴集团威海鞋业有限公司 EVA-based nano-modification anti-bacterial function hot melt adhesive material
CN106833458A (en) * 2017-01-05 2017-06-13 毕同召 A kind of household electrical appliances foaming PUR and preparation method thereof
CN107365564A (en) * 2017-08-23 2017-11-21 和平世家钟表有限公司 A kind of novel glue and preparation method and application
CN108977122A (en) * 2018-06-22 2018-12-11 安徽索亚装饰材料有限公司 A kind of tackifier improving EVA hot-melt adhesive glue performance
CN110467906A (en) * 2019-08-28 2019-11-19 佛山市南海骏驰新材料有限公司 A kind of heat molten type carpenter overlay film glue and its production technology
CN111635712A (en) * 2020-06-18 2020-09-08 无锡奥飞斯商用地毯有限公司 Soft-bottom square carpet and preparation method thereof
CN113021159A (en) * 2021-03-12 2021-06-25 安徽禾臣新材料有限公司 Polishing pad for fine polishing of electronic display screen and production method thereof
CN113021159B (en) * 2021-03-12 2022-03-15 安徽禾臣新材料有限公司 Polishing pad for fine polishing of electronic display screen and production method thereof
CN113528037A (en) * 2021-06-22 2021-10-22 广东硕成科技有限公司 Medical protective clothing adhesive tape and preparation method thereof
CN114958248A (en) * 2022-07-04 2022-08-30 盛虹石化集团上海新材料有限公司 Hot melt adhesive and preparation method thereof

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Application publication date: 20120905