CN107365564A - A kind of novel glue and preparation method and application - Google Patents
A kind of novel glue and preparation method and application Download PDFInfo
- Publication number
- CN107365564A CN107365564A CN201710727068.3A CN201710727068A CN107365564A CN 107365564 A CN107365564 A CN 107365564A CN 201710727068 A CN201710727068 A CN 201710727068A CN 107365564 A CN107365564 A CN 107365564A
- Authority
- CN
- China
- Prior art keywords
- parts
- thermosol
- adhesive sticker
- glue
- novel glue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J111/00—Adhesives based on homopolymers or copolymers of chloroprene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
- C09J5/06—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving heating of the applied adhesive
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of novel glue and preparation method and application, including thermosol, adhesive sticker and diluent, wherein, the mass ratio of thermosol and adhesive sticker is 2:3.The glue of the present invention has tack, it ensure that and coordinated product when being pasted onto product carrying, QC is checked, be not easy to release in secondary processing process, it can be convenient for changing for bad accessory caused by imprudence in secondary processing process again simultaneously, so as to save production cost, and production efficiency can be improved.In addition, after product pressing and stoving, glue stability of the present invention is good, has a good anti seismic efficiency, and will not be peeled off for a long time from product, can reach glue digestion period under confined conditions.
Description
Technical field
The present invention relates to glue technical field, and in particular to a kind of novel glue and preparation method and application.
Background technology
Glue is mainly used in connecting two kinds of materials.Existing glue typically can only PASTE SPECIAL certain or certain class material,
Such as rubber, paper, plastics, timber, and it is poor for the sticking effect of the hardware such as clock and watch, glasses, ornaments.Traditional glue is divided into
Two kinds of adhesive sticker and thermosol, adhesive sticker typically using the technique such as point, painting, wire mark, are bonded, be characterized in glue can compared with
Bonded in long interval of time, but physics easily occurs because adhesive sticker weatherability is poor after adhesive product, after a period of time and becomes
Change, so as to influence the fastness of product so that adhesive product is got loose.Thermosol, typically also with works such as point, painting, wire marks
Skill, Pressurized-heated bonding is carried out, is characterized in that product firmness is very high, but shortcoming is that thermosol itself is inviscid, in product not
Product is easy to fall off during inspection is processed when bonding completely, so as to produce processing puzzlement, causes in accessory process
Easily become flower, stain, non-defective unit percent of pass is influenceed during for quality high request, when changing bad accessory after bonding extremely it is cumbersome simultaneously
It is bad to produce secondary operation.
The content of the invention
Poor in order to solve traditional glue weatherability, the problems such as easily getting loose, it is an object of the invention to provide one kind
Novel glue and preparation method and application.
The purpose of the present invention is achieved through the following technical solutions：A kind of novel glue, including thermosol, adhesive sticker and dilution
Agent, wherein, the mass ratio of thermosol and adhesive sticker is 2:3.
Preferably, described a kind of novel glue, the thermosol are liquid oiliness thermosol, liquid oiliness thermosol bag
Include ethylene-vinyl acetate copolymer, butyl rubber, butylphenol resin, dibutyl phthalate, calcium carbonate, ethyl acetate,
Acetone, isophorone.
Preferably, described a kind of novel glue, is calculated in parts by mass, and liquid oiliness thermosol includes 100 portions of ethene-vinegar
Sour ethenyl copolymer, 30 parts of butyl rubbers, 20 parts of butylphenol resins, 5 parts of dibutyl phthalates, 5 parts of calcium carbonate, 130
Part ethyl acetate, 30 parts of acetone, 50 parts of isophorones.
Preferably, described a kind of novel glue, the adhesive sticker are liquid oiliness adhesive sticker, liquid oiliness adhesive sticker bag
Include tertiary butyl phenol formaldehyde resin, N- phenyl-2-naphthylamines, ethyl acetate, industrial naptha, accelerator, magnesia, neoprene, oxidation
Zinc.
Preferably, described a kind of novel glue, is calculated in parts by mass, and liquid oiliness adhesive sticker includes 120 parts of tertiary butyl phenols
Formaldehyde resin, 2 parts of N- phenyl-2-naphthylamines, 270 parts of ethyl acetates, 150 parts of industrial napthas, 2 parts of accelerator, 8 parts of magnesia, 120
Part neoprene, 5 parts of zinc oxide.
Preferably, a kind of described novel glue, the accelerator are divided into Vulcanization accelerator TMTD and diphenylguanidine, accelerator
The mass ratio of TMTD and diphenylguanidine is 1:1.
Preferably, described a kind of novel glue, the diluent include ethyl acetate, acetone, cyclohexanone, isophorone
In one or more.
A kind of preparation method of novel glue, after the thermosol is mixed in rustless steel container with adhesive sticker, in heating
Stirring, and diluent is gradually added, untill thermosol uniformly mixes with adhesive sticker.
A kind of application of novel glue, glue is placed on hot plate and warmed, and product cooperation can be carried out after glue softening
Paste, then using pressing and stoving, pressure is 2~5Kg/cm2, drying temperature is 80 DEG C, drying time 5s.
Compared with prior art, the invention has the advantages that：The present invention glue there is tack, ensure that by
It coordinates product when being pasted onto product carrying, QC is checked, be not easy to release in secondary processing process, while is directed to secondary operation again
During bad accessory caused by imprudence can be convenient for changing, so as to save production cost, and production efficiency can be improved.
In addition, after product pressing and stoving, glue stability of the present invention is good, has a good anti seismic efficiency, and for a long time will not be from
Peeled off on product, glue digestion period can be reached under confined conditions.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment 1
A kind of preparation method of novel glue, including thermosol, adhesive sticker and diluent, wherein, thermosol and adhesive sticker
Mass ratio be 2:3.After thermosol is mixed in rustless steel container with adhesive sticker, heat while stirring, and be gradually added diluent,
Untill thermosol uniformly mixes with adhesive sticker.
Thermosol is liquid oiliness thermosol, and liquid oiliness thermosol includes ethylene-vinyl acetate copolymer, butyl rubber
Glue, butylphenol resin, dibutyl phthalate, calcium carbonate, ethyl acetate, acetone, isophorone.Calculate in parts by mass,
Liquid oiliness thermosol is by 100 parts of ethylene-vinyl acetate copolymers, 30 parts of butyl rubbers, 20 parts of butylphenol resins, 5 parts of neighbours
Dibatyl phithalate, 5 parts of calcium carbonate, 130 parts of ethyl acetates, 30 parts of acetone, 50 parts of isophorone compositions.
Adhesive sticker is liquid oiliness adhesive sticker, and liquid oiliness adhesive sticker includes tertiary butyl phenol formaldehyde resin, N- phenyl -2- naphthalenes
Amine, ethyl acetate, industrial naptha, accelerator, magnesia, neoprene, zinc oxide.Calculate in parts by mass, liquid oiliness is not done
Glue is by 120 parts of tertiary butyl phenol formaldehyde resins, 2 parts of N- phenyl-2-naphthylamines, 270 parts of ethyl acetates, 150 parts of industrial napthas, 2 parts of promotions
Agent, 8 parts of magnesia, 120 parts of neoprenes, 5 parts of zinc oxide compositions.Accelerator is divided into Vulcanization accelerator TMTD and diphenylguanidine, accelerator
The mass ratio of TMTD and diphenylguanidine is 1:1.
Diluent includes the one or more in ethyl acetate, acetone, cyclohexanone, isophorone.
Embodiment 2
A kind of application of novel glue, on the basis of glue described in embodiment, after product is printed, you can carry out accessory
Bonding assembling, if needed after product is printed be spaced the long period assembling, printed product is covered with release liners, try not by
Product is stored in ventilation.Glue, is first put on hot plate and is warmed, glue is soft by the glue used for the interval long period
Accessory bonding is carried out after change again, and is assembled by pipeline system in heating, heating-up temperature is 80 DEG C.After the completion of assembling, adopt
With pressing and stoving, pressure is 2~5Kg/cm2, drying temperature is 80 DEG C, drying time 5s.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
God any modification, equivalent substitution and improvements made etc., should be included in the scope of the protection with principle.
Claims (9)
- A kind of 1. novel glue, it is characterised in that：Including thermosol, adhesive sticker and diluent, wherein, thermosol and adhesive sticker Mass ratio is 2:3.
- A kind of 2. novel glue according to claim 1, it is characterised in that：The thermosol is liquid oiliness thermosol, Liquid oiliness thermosol include ethylene-vinyl acetate copolymer, butyl rubber, butylphenol resin, dibutyl phthalate, Calcium carbonate, ethyl acetate, acetone, isophorone.
- A kind of 3. novel glue according to claim 2, it is characterised in that：Calculate in parts by mass, liquid oiliness thermosol Including 100 parts of ethylene-vinyl acetate copolymers, 30 parts of butyl rubbers, 20 parts of butylphenol resins, 5 parts of fourths of phthalic acid two Ester, 5 parts of calcium carbonate, 130 parts of ethyl acetates, 30 parts of acetone, 50 parts of isophorones.
- A kind of 4. novel glue according to claim 1, it is characterised in that：The adhesive sticker is liquid oiliness adhesive sticker, Liquid oiliness adhesive sticker includes tertiary butyl phenol formaldehyde resin, N- phenyl-2-naphthylamines, ethyl acetate, industrial naptha, accelerator, oxidation Magnesium, neoprene, zinc oxide.
- A kind of 5. novel glue according to claim 4, it is characterised in that：Calculate in parts by mass, liquid oiliness adhesive sticker Including 120 parts of tertiary butyl phenol formaldehyde resins, 2 parts of N- phenyl-2-naphthylamines, 270 parts of ethyl acetates, 150 parts of industrial napthas, 2 parts of promotions Agent, 8 parts of magnesia, 120 parts of neoprenes, 5 parts of zinc oxide.
- A kind of 6. novel glue according to claim 5, it is characterised in that：The accelerator is divided into Vulcanization accelerator TMTD and rush Enter agent D, the mass ratio of Vulcanization accelerator TMTD and diphenylguanidine is 1:1.
- A kind of 7. novel glue according to claim 1, it is characterised in that：The diluent include ethyl acetate, acetone, One or more in cyclohexanone, isophorone.
- A kind of 8. preparation method of novel glue, it is characterised in that：After the thermosol is mixed in rustless steel container with adhesive sticker, Heat while stirring, and be gradually added diluent, untill thermosol uniformly mixes with adhesive sticker.
- A kind of 9. application of novel glue, it is characterised in that：Glue is placed on hot plate and warmed, can be carried out after glue softening Product, which coordinates, to be pasted, and then using pressing and stoving, pressure is 2~5Kg/cm2, drying temperature is 80 DEG C, drying time 5s.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710727068.3A CN107365564A (en) | 2017-08-23 | 2017-08-23 | A kind of novel glue and preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710727068.3A CN107365564A (en) | 2017-08-23 | 2017-08-23 | A kind of novel glue and preparation method and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107365564A true CN107365564A (en) | 2017-11-21 |
Family
ID=60310686
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710727068.3A Pending CN107365564A (en) | 2017-08-23 | 2017-08-23 | A kind of novel glue and preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107365564A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102653665A (en) * | 2012-04-28 | 2012-09-05 | 成都鑫三洋科技发展有限公司 | Hot melt adhesive |
| CN103911097A (en) * | 2013-11-18 | 2014-07-09 | 吴江市凯盈贸易有限公司 | Novel chloroprene rubber adhesive and preparation method thereof |
| CN105585976A (en) * | 2016-03-16 | 2016-05-18 | 苏州华周胶带有限公司 | Adhesive material with high adhesion performance |
-
2017
- 2017-08-23 CN CN201710727068.3A patent/CN107365564A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102653665A (en) * | 2012-04-28 | 2012-09-05 | 成都鑫三洋科技发展有限公司 | Hot melt adhesive |
| CN103911097A (en) * | 2013-11-18 | 2014-07-09 | 吴江市凯盈贸易有限公司 | Novel chloroprene rubber adhesive and preparation method thereof |
| CN105585976A (en) * | 2016-03-16 | 2016-05-18 | 苏州华周胶带有限公司 | Adhesive material with high adhesion performance |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101548204B (en) | Pressure-sensitive adhesive for optical films | |
| CN104004477B (en) | A kind of room-temperature self crosslinking polyacrylate pressure-sensitive and preparation method thereof and application | |
| CN104031596B (en) | A kind of low mold temperature water-based polyurethane adhesive and preparation method thereof | |
| CN107868639B (en) | Acrylate pressure-sensitive adhesive, pressure-sensitive adhesive tape and preparation method of acrylate pressure-sensitive adhesive | |
| US10703938B2 (en) | Hot-melt adhesive and preparation method therefor | |
| CN102051149A (en) | Preparation methods of hot melt pressure-sensitive adhesive and protective film as well as hot melt pressure-sensitive adhesive | |
| CN109021851B (en) | A kind of acrylic protective film and preparation method thereof | |
| CN102040930A (en) | Pressure-sensitive adhesive for PET (Polyester) adhesive tapes and preparation method thereof | |
| TW201606017A (en) | Pressure-sensitive adhesive composition, pressure-sensitive adhesive polarizing plate and liquid crystal display device | |
| CN103468197B (en) | PVC laminating adhesive and preparation method and application thereof | |
| CN104194695A (en) | Grafted nano ambary fiber crystal whisker modified urea formaldehyde resin adhesive and preparation method thereof | |
| CN102732192A (en) | Emulsion acrylate pressure-sensitive adhesive, preparation method and application thereof | |
| CN107365564A (en) | A kind of novel glue and preparation method and application | |
| CN109679540B (en) | High-temperature-resistant adhesive and preparation method of high-temperature-resistant aluminum foil tape | |
| CN104164203A (en) | White latex for leatherworking and preparation method thereof | |
| CN110003807A (en) | A kind of water based emulsion xenogenesis graft materials and preparation method thereof and its application in soft pvc film pressure sensitive adhesive tape | |
| CN102101996A (en) | Pressure-sensitive adhesive used for cotton paper or non-woven fabrics and preparation method thereof | |
| CN110003826A (en) | A kind of melt pressure sensitive gluing agent | |
| CN104212384A (en) | Preparation method of heat-resisting adhesive for connecting metal and PVC (polyvinyl chloride) | |
| JP4920400B2 (en) | Waterproof and airtight adhesive sheet | |
| JP5378484B2 (en) | Cross-linked solid-type pressure-sensitive adhesive composition, pressure-sensitive adhesive sheet thereof, and method for producing waterproof and air-tight pressure-sensitive adhesive sheet | |
| CN111138994A (en) | Removable polypropylene label material for mobile phone cover and preparation method thereof | |
| CN111320955A (en) | Waterproof coiled material hot-melt pressure-sensitive adhesive and preparation method thereof | |
| CN109609048A (en) | A kind of heat thickening glue film and its manufacturing method | |
| CN103289628B (en) | Polyethylene hot melt adhesive used for sheet materials and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171121 |
|
| RJ01 | Rejection of invention patent application after publication |