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CN103571392A - Anti-corrosion hot melt adhesive for automotive upholstery - Google Patents

Anti-corrosion hot melt adhesive for automotive upholstery Download PDF

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Publication number
CN103571392A
CN103571392A CN201310505653.0A CN201310505653A CN103571392A CN 103571392 A CN103571392 A CN 103571392A CN 201310505653 A CN201310505653 A CN 201310505653A CN 103571392 A CN103571392 A CN 103571392A
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CN
China
Prior art keywords
parts
hot melt
melt adhesive
automotive upholstery
corrosion hot
Prior art date
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Granted
Application number
CN201310505653.0A
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Chinese (zh)
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CN103571392B (en
Inventor
戴远鹏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beiqi Hanyi Chongqing Automobile Accessories Co ltd
Original Assignee
Wuhu Zhongli Parts Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Wuhu Zhongli Parts Co Ltd filed Critical Wuhu Zhongli Parts Co Ltd
Priority to CN201310505653.0A priority Critical patent/CN103571392B/en
Publication of CN103571392A publication Critical patent/CN103571392A/en
Application granted granted Critical
Publication of CN103571392B publication Critical patent/CN103571392B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Abstract

The invention discloses an anti-corrosion hot melt adhesive for automotive upholstery. The anti-corrosion hot melt adhesive is prepared from the following raw materials in parts by weight: 20-30 parts of EVA (Ethylene-Vinyl Acetate), 5-8 parts of bisphenol-A epoxy resin, 8-10 parts of terpene resin T-120, 5-8 parts of carnauba wax, 3-5 parts of glycerol triacetate, 2-4 parts of titanium dioxide, 3-5 parts of antimonous oxide, 1-2 parts of antioxygen DLTP (Dilauryl Thiodipropionate), 1-2 parts of sodium tripolyphosphate, 0.1-0.2 parts of copper sulfate, 1-2 parts of 3-mm shortly chopped glass fiber and 7-8 parts of composite filler. According to the anti-corrosion hot melt adhesive disclosed by the invention, the raw materials are reasonably configured, wherein addition of the shortly chopped glass fiber and the cooperation between the shortly chopped glass fiber and the rest raw materials enable the anti-corrosion hot melt adhesive disclosed by the invention to have quite good anti-corrosion, anti-acid and anti-alkaline effects.

Description

A kind of automotive upholstery protection against corrosion hot melt adhesive
Technical field
The invention belongs to binding agent field, relate in particular to a kind of automotive upholstery protection against corrosion hot melt adhesive.
Background technology
Hot melt adhesive is a kind of plastic tackiness agent, and in certain temperature range, its physical condition changes with temperature change, and chemical property is constant, and it is nonpoisonous and tasteless, belongs to environmental-protecting chemical product.
People's custom was regarded automotive upholstery as the annex of vehicle body in the past, this several years high speed developments along with Domestic Automotive Industry, automotive upholstery is in the development of advancing by leaps and bounds, become project with fastest developing speed in trolley part, the requirement of human consumer's to interior is more and more higher, making automotive upholstery is the field that appellation tackiness agent consumption increases rapidly, and the demand of automotive upholstery hot melt adhesive was more and more in recent years.
Summary of the invention
The object of this invention is to provide a kind of automotive upholstery protection against corrosion hot melt adhesive.
The present invention adopts following technical scheme to achieve these goals:
A kind of automotive upholstery protection against corrosion hot melt adhesive; it is characterized in that; it is that raw material by following weight parts makes: EVA 20-30; bisphenol A type epoxy resin 5-8, terpine resin T-120 8-10, carnauba wax 5-8; Vanay 3-5; titanium dioxide 2-4, antimonous oxide 3-5, anti-oxidant DLTP 1-2, tripoly phosphate sodium STPP 1-2, copper sulfate 0.1-0.2,3mm short glass fiber 1-2, compounded mix 7-8;
Described compounded mix is made by the raw material of following weight parts: Sumstar 190 6-10, rosin 8-10; barium sulfate 3-5, aluminium sesquioxide 5-8, dioctyl sebacate 0.3-0.6, Radix Angelicae Sinensis oil 0.3-0.5, titanium dioxide 1-2, Trisodium Citrate 0.4-0.6, alcohol ether glucoside 1-2, stearic acid 0.3-0.5, methyl acrylate 0.1-0.2;
The preparation method of described compounded mix is:
After Sumstar 190 and aluminium sesquioxide are mixed, add suitable quantity of water and stir, adding 10-15% hydrochloric acid soln, to adjust pH be 5-6, and ground slurry is to 400-500 order, and repeated hydrogenation sodium hydroxide solution is adjusted to neutrality, dry, then mixes with surplus stock, grind even after and get final product.
Described a kind of automotive upholstery protection against corrosion hot melt adhesive, is characterized in that:
Preparation method is: kneader is preheated to wall temperature 165-175 ℃, then add EVA, bisphenol A type epoxy resin, titanium dioxide, Vanay, mediate 15-25min, after add surplus stock, at 170-180 ℃, mediate 10-20min, take out cooling and get final product.
Beneficial effect of the present invention: raw material configuration of the present invention rationally, wherein adding of short glass fiber, with all the other raw material synergies, makes the present invention have corrosion-resistant acid and alkali-resistance effect well, is particularly useful for automotive upholstery and uses.
Embodiment
A kind of automotive upholstery protection against corrosion hot melt adhesive; it is that raw material by following weight kg makes: EVA 28; bisphenol A type epoxy resin 8; terpine resin T-120 10; carnauba wax 8, Vanay 5, titanium dioxide 4, antimonous oxide 5, anti-oxidant DLTP 2, tripoly phosphate sodium STPP 1-2, copper sulfate 0.2; 3mm short glass fiber 2, compounded mix 8;
Described compounded mix is made by the raw material of following weight kg: Sumstar 190 10, rosin 10; barium sulfate 5, aluminium sesquioxide 8, dioctyl sebacate 0.6, Radix Angelicae Sinensis oil 0.5, titanium dioxide 2, Trisodium Citrate 0.6, alcohol ether glucoside 1, stearic acid 0.5, methyl acrylate 0.2;
The preparation method of described compounded mix is:
After Sumstar 190 and aluminium sesquioxide are mixed, add suitable quantity of water and stir, adding 15% hydrochloric acid soln, to adjust pH be 5.8, and after ground slurry to 500 order, repeated hydrogenation sodium hydroxide solution is adjusted to neutrality, dry, then mixes with surplus stock, grind even after and get final product.
Described a kind of automotive upholstery protection against corrosion hot melt adhesive,
Preparation method is: kneader is preheated to 165 ℃ of wall temperatures, then adds EVA, bisphenol A type epoxy resin, titanium dioxide, Vanay, mediates 18min, after add surplus stock, at 180 ℃, mediate 20min, take out cooling and get final product.
The apparent viscosity of the binding agent of the present embodiment is 5200MPa.s, stripping strength 57N/2.5cm 2, initial bonding strength reaches steel ball No. 5, open hour 38s, and within 24 hours, thermally-stabilised proterties is stable.

Claims (2)

1. an automotive upholstery protection against corrosion hot melt adhesive; it is characterized in that; it is that raw material by following weight parts makes: EVA 20-30; bisphenol A type epoxy resin 5-8, terpine resin T-120 8-10, carnauba wax 5-8; Vanay 3-5; titanium dioxide 2-4, antimonous oxide 3-5, anti-oxidant DLTP 1-2, tripoly phosphate sodium STPP 1-2, copper sulfate 0.1-0.2,3mm short glass fiber 1-2, compounded mix 7-8;
Described compounded mix is made by the raw material of following weight parts: Sumstar 190 6-10, rosin 8-10; barium sulfate 3-5, aluminium sesquioxide 5-8, dioctyl sebacate 0.3-0.6, Radix Angelicae Sinensis oil 0.3-0.5, titanium dioxide 1-2, Trisodium Citrate 0.4-0.6, alcohol ether glucoside 1-2, stearic acid 0.3-0.5, methyl acrylate 0.1-0.2;
The preparation method of described compounded mix is:
After Sumstar 190 and aluminium sesquioxide are mixed, add suitable quantity of water and stir, adding 10-15% hydrochloric acid soln, to adjust pH be 5-6, and ground slurry is to 400-500 order, and repeated hydrogenation sodium hydroxide solution is adjusted to neutrality, dry, then mixes with surplus stock, grind even after and get final product.
2. a kind of automotive upholstery protection against corrosion hot melt adhesive according to claim 1, is characterized in that:
Preparation method is: kneader is preheated to wall temperature 165-175 ℃, then add EVA, bisphenol A type epoxy resin, titanium dioxide, Vanay, mediate 15-25min, after add surplus stock, at 170-180 ℃, mediate 10-20min, take out cooling and get final product.
CN201310505653.0A 2013-10-24 2013-10-24 A kind of Anti-corrosion hot melt adhesive for automotive upholstery Expired - Fee Related CN103571392B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310505653.0A CN103571392B (en) 2013-10-24 2013-10-24 A kind of Anti-corrosion hot melt adhesive for automotive upholstery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310505653.0A CN103571392B (en) 2013-10-24 2013-10-24 A kind of Anti-corrosion hot melt adhesive for automotive upholstery

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CN103571392A true CN103571392A (en) 2014-02-12
CN103571392B CN103571392B (en) 2016-04-13

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103952094A (en) * 2014-03-24 2014-07-30 铜陵市松马食品包装机械制造有限责任公司 Paper-plastic package heat-sealing glue and preparation method thereof
CN104073174A (en) * 2014-06-26 2014-10-01 无锡新腾东方电缆附件有限公司 Adhesive for high-temperature-resistant insulation high-pressure adhesive tape
CN107513331A (en) * 2017-07-11 2017-12-26 成都联利达五金制品有限公司 A kind of gold plating of high intensity five
WO2023201795A1 (en) * 2022-04-18 2023-10-26 广东汇齐新材料有限公司 Hot melt adhesive film having high-viscosity metal force and preparation method therefor

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102250574A (en) * 2010-05-18 2011-11-23 四川久远科技股份有限公司 Hot-melt adhesive for preventing corrosion of repaired mouth of pipeline
US20120168068A1 (en) * 2010-12-29 2012-07-05 Saint-Gobain Technical Fabrics America, Inc. Contourable core fabric and method of making same
CN102653665A (en) * 2012-04-28 2012-09-05 成都鑫三洋科技发展有限公司 Hot melt adhesive
JP2013500359A (en) * 2009-07-24 2013-01-07 ボスティック,インコーポレイテッド Hot melt adhesives based on olefin block copolymers
CN103045112A (en) * 2012-12-28 2013-04-17 阿特斯(中国)投资有限公司 Heat-conduction EVA (ethylene-vinyl acetate) packaging adhesive film for photovoltaic module and method for preparing adhesive film
CN103102814A (en) * 2013-01-28 2013-05-15 苏州井上高分子新材料有限公司 EVA (ethylene-vinyl acetate) hot-melting adhesive and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013500359A (en) * 2009-07-24 2013-01-07 ボスティック,インコーポレイテッド Hot melt adhesives based on olefin block copolymers
CN102250574A (en) * 2010-05-18 2011-11-23 四川久远科技股份有限公司 Hot-melt adhesive for preventing corrosion of repaired mouth of pipeline
US20120168068A1 (en) * 2010-12-29 2012-07-05 Saint-Gobain Technical Fabrics America, Inc. Contourable core fabric and method of making same
CN102653665A (en) * 2012-04-28 2012-09-05 成都鑫三洋科技发展有限公司 Hot melt adhesive
CN103045112A (en) * 2012-12-28 2013-04-17 阿特斯(中国)投资有限公司 Heat-conduction EVA (ethylene-vinyl acetate) packaging adhesive film for photovoltaic module and method for preparing adhesive film
CN103102814A (en) * 2013-01-28 2013-05-15 苏州井上高分子新材料有限公司 EVA (ethylene-vinyl acetate) hot-melting adhesive and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103952094A (en) * 2014-03-24 2014-07-30 铜陵市松马食品包装机械制造有限责任公司 Paper-plastic package heat-sealing glue and preparation method thereof
CN103952094B (en) * 2014-03-24 2016-04-06 铜陵市松马食品包装机械制造有限责任公司 A kind of paper-plastic package heat-seal adhesive and preparation method thereof
CN104073174A (en) * 2014-06-26 2014-10-01 无锡新腾东方电缆附件有限公司 Adhesive for high-temperature-resistant insulation high-pressure adhesive tape
CN104073174B (en) * 2014-06-26 2016-05-11 无锡新腾东方电缆附件有限公司 A kind of high-temperature insulation high pressure adhesive tape sticks with glue agent
CN107513331A (en) * 2017-07-11 2017-12-26 成都联利达五金制品有限公司 A kind of gold plating of high intensity five
WO2023201795A1 (en) * 2022-04-18 2023-10-26 广东汇齐新材料有限公司 Hot melt adhesive film having high-viscosity metal force and preparation method therefor

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Effective date of registration: 20190612

Address after: 211111 No. 2 Lanxia Road, Ziling Street, Jiangning District, Nanjing City, Jiangsu Province

Patentee after: Wu Yan

Address before: 241009 auto parts road of Yijiang high tech Industrial Development Zone, Wuhu, Anhui

Patentee before: WUHU ZHONGLI PARTS Co.,Ltd.

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20190715

Address after: 401135 Chongqing Yubei District City Longxing Zhen Ying Long Road No. 19

Patentee after: Beiqi Hanyi (Chongqing) Automobile Accessories Co.,Ltd.

Address before: Moling streets blue Xia Road Jiangning District Nanjing City, Jiangsu Province, No. 2 211111

Patentee before: Wu Yan

TR01 Transfer of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160413

CF01 Termination of patent right due to non-payment of annual fee