Safety Data Sheet

BOSTIK ALL PURPOSE SILICONE Trans Revision Date 09-Jan-2018

Revision Number 3 Supersedes Date: 20-Jul-2017
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Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1. Product Identifier

Product Name BOSTIK ALL PURPOSE SILICONE Trans

Pure substance/mixture Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended use Sealant.

Uses advised against No information available.

1.3. Details of the supplier of the safety data sheet

Company Name
Bostik New Zealand Limited
19 Eastern Hutt Road Wingate,
Lower Hutt, New Zealand
Tel: 04-567 5119
Fax: 04-567 5412

1.4. Emergency telephone number

Emergency Telephone 24 Hr: 0800 243 622

+64 4 917 9888
Poison Centre : 0800 764 766

E-mail address SDS.AP@Bostik.com

Section 2: HAZARD IDENTIFICATION

2.1. Classification of the substance or mixture

Serious Eye Damage/Eye Irritation Category 2A (6.4A)

Skin sensitization Category 1B
Carcinogenicity Category 2 (6.7B)

ERMA Group HSR002679

2.2. Label Elements

Signal Word WARNING

Hazard statements
H317 - May cause an allergic skin reaction
H351 - Suspected of causing cancer
H319 - Causes serious eye irritation

Precautionary Statements - Prevention

P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood
P281 - Use personal protective equipment as required
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P264 - Wash face, hands and any exposed skin thoroughly after handling
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray
P272 - Contaminated work clothing should not be allowed out of the workplace
P280 - Wear protective gloves
Precautionary Statements - Response
P321 - Specific treatment (see supplemental first aid instructions on this label)
Skin
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention
P363 - Wash contaminated clothing before reuse
EYES
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing
P337 + P313 - If eye irritation persists: Get medical advice/attention
Precautionary Statements - Storage
P405 - Store locked up
Precautionary Statements - Disposal
P501 - Dispose of contents/ container to an approved waste disposal plant

2.3. Other Hazards

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances
Mixture

3.2 Mixtures
Chemical Name CAS No Weight-%
2-Butanone, O,O',O''-(methylsilylidyne)trioxime 22984-54-9 1 - <5
2-Butanone, oxime 96-29-7 1 - <3

*** Any remaining ingredients are not hazardous

Section 4: FIRST AID MEASURES

4.1. Description of first aid measures

General Advice If symptoms persist, call a physician. Do not breathe dust/fume/gas/mist/vapors/spray.

Do not get in eyes, on skin, or on clothing.

Inhalation Remove to fresh air. If breathing is irregular or stopped, administer artificial respiration.
Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. Call a
physician. Immediate medical attention is not required. Move to fresh air in case of
accidental inhalation of vapors. If symptoms persist, call a physician.

Skin Contact Consult a physician if necessary. Wash off immediately with soap and plenty of water
while removing all contaminated clothes and shoes. Wash off immediately with soap and
plenty of water. Immediate medical attention is not required. If skin irritation persists, call
a physician.

Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses
and continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If
symptoms persist, call a physician. Rinse thoroughly with plenty of water for at least 15
minutes, lifting lower and upper eyelids. Consult a physician.

Ingestion Do NOT induce vomiting. Drink plenty of water. If symptoms persist, call a physician.
Rinse mouth. Clean mouth with water and drink afterwards plenty of water. Never give
anything by mouth to an unconscious person. Call a physician.

Self-Protection of the First Aider Use personal protective equipment as required.

4.2. Most important symptoms and effects, both acute and delayed

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Symptoms None known.

4.3. Indication of any immediate medical attention and special treatment needed

Note to physicians May cause sensitization of susceptible persons. Treat symptomatically.

4.4. Reference to Other Sections

Reference to other sections Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION. Section 11:

TOXICOLOGY INFORMATION.

Section 5: FIRE-FIGHTING MEASURES

5.1. Extinguishing media

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.

Unsuitable Extinguishing Media No information available.

5.2. Special hazards arising from the substance or mixture

Specific Hazards Arising from the In the event of fire and/or explosion do not breathe fumes. May cause sensitization by
Chemical inhalation and skin contact. Thermal decomposition can lead to release of irritating and
toxic gases and vapors.

5.3. Advice for firefighters

Special Protective Equipment for Wear self-contained breathing apparatus and protective suit.
Fire-fighters

Section 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Personal Precautions Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.

6.2. Environmental precautions

Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas. Do not flush into
surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do
so. Prevent product from entering drains. See Section 12 for additional Ecological
Information.

6.3. Methods and material for containment and cleaning up

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Cover liquid spill with sand, earth or other non-combustible absorbent material. Cover
powder spill with plastic sheet or tarp to minimize spreading. Pick up and transfer to
properly labeled containers. Soak up with inert absorbent material. Dam up.

6.4. Reference to other sections

Reference to other sections Section 7: HANDLING AND STORAGE

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Section 13: DISPOSAL CONSIDERATIONS

Section 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Advice on safe handling Avoid contact with skin, eyes or clothing. Wash contaminated clothing before reuse. Do
not eat, drink or smoke when using this product. Use personal protective equipment as
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Revision Number 3 Supersedes Date: 20-Jul-2017
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required. Do not breathe dust/fume/gas/mist/vapors/spray. Use with local exhaust
ventilation.

7.2. Conditions for safe storage, including any incompatibilities

General Hygiene Considerations When using do not eat, drink or smoke. Regular cleaning of equipment, work area and
clothing is recommended.

Storage Conditions Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of
children. Keep containers tightly closed in a cool, well-ventilated place. Keep in properly
labeled containers. Keep container tightly closed and dry. Product cures with moisture.

Incompatible Materials No information available

7.3. Specific end use(s)

Other Information No information available.

7.4. References to Other Sections

Reference to other sections Section 13: DISPOSAL CONSIDERATIONS. Section 10: STABILITY AND REACTIVITY.

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Exposure Limits
This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the
region specific regulatory bodies

Derived No Effect Level (DNEL) No information available

Predicted No Effect Concentration No information available

(PNEC)

OTHER INFORMATION No information available

8.2. Exposure controls

Engineering Controls Ensure adequate ventilation, especially in confined areas.

PPE - Personal Protection Equipment

Eye/Face Protection Wear safety glasses with side shields (or goggles).
Skin and Body Protection Wear suitable protective clothing. No special technical protective measures are
necessary under normal conditions.
Hand Protection Wear suitable chemical resistant gloves. The selection of suitable gloves does not only
depend on the material, but also on further marks of quality and various manufacturers.
Respiratory Protection No protective equipment is needed under normal use conditions. Respiratory protection
required in insufficiently ventilated working areas and during spraying. An air-fed mask,
or for short periods of work, a combination of professional filter is recommended.
General Hygiene Do not eat, drink or smoke when using this product. Wash hands thoroughly after
Considerations handling. Avoid contact with skin, eyes or clothing. Take off contaminated clothing and
wash before reuse.

Environmental Exposure Controls Do not allow into any sewer, on the ground or into any body of water.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Paste

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Color Clear, colorless
Odor Characteristic
Odor Threshold No information available

Property Values Remar

ks •Met
hod
pH No information available
Melting point / freezing point No information available
Boiling point / boiling range No information available
Flash Point No information available
Evaporation Rate No information available
Flammability (solid, gas) No information available
Flammability Limit in Air
Upper flammability limit: No information available
Lower flammability limit: No information available
Vapor Pressure No information available
Vapor Density No information available
Relative Density No information available
Water Solubility No information available
Solubility in Other Solvents No information available
Partition Coefficient No information available
Autoignition Temperature No information available
Decomposition Temperature No information available
Kinematic Viscosity No information available
Dynamic Viscosity No information available
Explosive Properties No information available
Oxidizing Properties No information available

9.2. Other information

Softening Point No information available
Molecular Weight No information available
Solvent content (%) No information available
Solid content (%) No information available
Density 1 g/cm³
Bulk Density No information available
VOC 51 g/L

Section 10: STABILITY AND REACTIVITY

10.1. Reactivity

Reactivity None under normal use conditions.

10.2. Chemical stability

10.3. Possibility of hazardous reactions

Possibility of Hazardous Reactions None under normal processing.

Hazardous Polymerization None under normal processing.

10.4. Conditions to avoid

Conditions to avoid Protect from moisture. Product cures with moisture.

10.5. Incompatible materials

Incompatible Materials No information available.

10.6. Hazardous decomposition products

Hazardous decomposition None under normal use conditions.

products

Section 11: TOXICOLOGY INFORMATION

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BOSTIK ALL PURPOSE SILICONE Trans Revision Date 09-Jan-2018
Revision Number 3 Supersedes Date: 20-Jul-2017
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11.1. Information on toxicological effects

Acute Toxicity

Product Information Product does not present an acute toxicity hazard based on known or supplied
information.
Inhalation No data available.
Eye contact No data available.
Skin Contact No data available.
Ingestion No data available.

Numerical measures of toxicity

Unknown acute toxicity

0 % of the mixture consists of ingredient(s) of unknown acute oral toxicity
4.9 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity
6.9 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas)
6.9 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor)
6.9 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist)

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

2-Butanone, LD50 = 2463 mg/Kg (Rat) LD50 >2000 mg/Kg (Rat) -
O,O',O''-(methylsilylidyne)trioxime (OECD 401) (OECD guideline 402)
22984-54-9
2-Butanone, oxime = 930 mg/kg ( Rat ) 1000 - 1800 mg/kg ( Rabbit ) > 4800 mg/m3 ( Rat ) 4 h
96-29-7

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin Corrosion/Irritation No information available.

Serious Eye Damage/Eye Irritation No information available.
Sensitization No information available.
Germ Cell Mutagenicity No information available.
Reproductive Toxicity Repeated inhalation or oral exposure of mice and rats to octamethylcyclotetrasiloxane
produced an increase in liver size. No gross histopathological or significant clinical
chemistry effects were observed. An increase in liver metabolizing enzymes, as well as
a transient increase in the number of normal cells (hyperplasia) followed by an increase
in cell size (hypertrophy) were determined to be the underlying causes of the liver
enlargement. The biochemical mechanisms producing these effects are highly sensitive
in rodents, while similar mechanisms in humans are insensitive. Good industrial hygiene
practice minimizes inhalation exposure to any chemical. In developmental toxicity
studies in which rats and rabbits were exposed to octamethylcyclotetrasiloxane by vapor
inhalation at concentrations up to 700 ppm and 500 ppm respectively, no teratogenic
effects were observed. Octamethylcyclotetrasiloxane administered to rats by whole body
inhalation at concentrations of 500 and 700 ppm for 70 days prior to mating, through
mating, gestation and lactation resulted in decreases in live litter size. Additionally,
increases in the incidence of deliveries of offspring extending over an unusually long
time period (dystocia) were observed at these concentrations. Statistically significant
alterations in these parameters were not observed in the lower concentrations evaluated
(300 and 70 ppm). In a previous range-finding study, rats exposed to vapor
concentrations of 700 ppm had decreases in the number of implantation sites and live
litter size. The significance of these findings to humans is not known. Classification is
based on mixture calculation methods based on component data.
STOT - Single Exposure No information available.
STOT - Repeated Exposure No information available.
Target Organ Effects Liver.
Aspiration hazard No information available.
Carcinogenicity The following substance(s) are classified in Annex VI CLP (1272/2008) as carcinogenic.

Section 12: ECOLOGICAL INFORMATION

12.1. Toxicity
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Ecotoxicity

Product Information
Harmful to aquatic life with long lasting effects.

Component Information
Data obtained on the component(s) include

Chemical Name Algae/aquatic plants Fish Crustacea

2-Butanone, - EC50 (96h) >120 mg/L Fish -
O,O',O''-(methylsilylidyne)trioxime (Oncorhynchus mykiss)Freshwater
22984-54-9 static
(OECD guideline 203)
2-Butanone, oxime EC50 72 h = 83 mg/L LC50 96 h 777 - 914 mg/L EC50 48 h = 750 mg/L (Daphnia
96-29-7 (Desmodesmus subspicatus) (Pimephales promelas magna )
flow-through) LC50 96 h 320 -
1000 mg/L (Leuciscus idus static)
LC50 96 h = 760 mg/L (Poecilia
reticulata static)

12.2. Persistence and degradability

No information available.

12.3. Bioaccumulative potential

No information available.

12.4. Mobility in soil

No information available.

12.5. Results of PBT and vPvB assessment

The components in this formulation do not meet the criteria for classification as PBT or vPvB.

12.6. Other adverse effects

No information available.

Section 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Waste from Residues/Unused Disposal should be in accordance with applicable regional, national and local laws and
Products regulations.

Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and
regulations.

Section 14: TRANSPORTATION INFORMATION

IMDG Not regulated

IATA Not regulated

ADR Not regulated

Section 15: REGULATORY INFORMATION

National Regulations

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BOSTIK ALL PURPOSE SILICONE Trans Revision Date 09-Jan-2018
Revision Number 3 Supersedes Date: 20-Jul-2017
___________________________________________________________________________________________
Section 16: OTHER INFORMATION

Key or legend to abbreviations and acronyms used in the safety data sheet
No information available

Key Literature References and Sources for Data

No information available

Prepared By Product Safety & Regulatory Affairs

Revision Date 09-Jan-2018

Revision Note Not applicable.

Training Advice No information available

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of
its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only
to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process, unless specified in the text.

End of Safety Data Sheet

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