SAFETY DATA SHEET

Revision Date 13-May-2020 Version 7

1. IDENTIFICATION
Product identifier
Product Name ULTRA BLUE GASKET MAKER 3.35 OZ

Other means of identification

Product Code 81724

Recommended use of the chemical and restrictions on use

Recommended Use Sealant
Uses advised against No information available

Details of the supplier of the safety data sheet

Manufacturer Address May Also Be Distributed by:
ITW Permatex ITW Permatex Canada
6875 Parkland Blvd. 101-2360 Bristol Circle
Solon, Ohio 44139 USA Oakville, ON Canada L6H 6M5
Telephone: 1-87-Permatex Telephone: (800) 924-6994
(866) 732-9502
24-hour emergency phone number
Chem-Tel: 800-255-3924
International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453

E-mail address: mail@permatex.com

2. HAZARDS IDENTIFICATION
Classification

OSHA Regulatory Status

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Serious eye damage/eye irritation Category 2A

Skin sensitization Category 1
Carcinogenicity Category 2

Label elements

Emergency Overview
Signal word
Warning

Causes serious eye irritation

May cause an allergic skin reaction
Suspected of causing cancer

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Appearance Blue Physical state Paste Liquid Odor Mild

Precautionary Statements - Prevention

Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Avoid breathing dust/fume/gas/mist/vapors/spray
Contaminated work clothing should not be allowed out of the workplace
Wear protective gloves/protective clothing/eye protection/face protection

Precautionary Statements - Response

IF exposed or concerned: Get medical advice/attention
Specific treatment (see .? on this label)

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN: Wash with plenty of soap and water
If skin irritation or rash occurs: Get medical advice/attention
Wash contaminated clothing before reuse

Precautionary Statements - Storage

Store locked up

Precautionary Statements - Disposal

Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)

Not applicable

Other Information
Harmful to aquatic life with long lasting effects.

Unknown acute toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS No Weight-%

CALCIUM CARBONATE 471-34-1 10 - 30
LIMESTONE 1317-65-3 10 - 30
STEARIC ACID 57-11-4 1-5
2-BUTANONE OXIME 96-29-7 1-5

4. FIRST AID MEASURES

Description of first aid measures

General advice If symptoms persist, call a physician.

Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and
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continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptoms
persist, call a physician.

Skin contact IF ON SKIN:. Wash with soap and water. If skin irritation or rash occurs: Get medical
advice/attention. Wash contaminated clothing before reuse. Immediate medical attention is
not required. Wash off immediately with soap and plenty of water while removing all
contaminated clothes and shoes. If skin irritation persists, call a physician.

Inhalation Immediate medical attention is not required. If symptoms persist, call a physician. Move to
fresh air in case of accidental inhalation of vapors or decomposition products.

Ingestion Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth
to an unconscious person. Call a physician. Do NOT induce vomiting.

Self-protection of the first aider Use personal protective equipment as required.

Most important symptoms and effects, both acute and delayed

Symptoms May cause allergic skin reaction.

Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use dry chemical, Carbon dioxide (CO2), Alcohol resistant foam, Use, Water spray (fog)

Unsuitable extinguishing media

None

Specific hazards arising from the chemical

Keep product and empty container away from heat and sources of ignition. Risk of ignition.

Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.

Protective equipment and precautions for firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.
Remove all sources of ignition. Pay attention to flashback. Take precautionary measures
against static discharges. Use personal protective equipment as required.

Environmental precautions

Environmental precautions See section 12 for additional ecological information. Prevent further leakage or spillage if
safe to do so. Prevent product from entering drains.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Use personal protective equipment as required. Dam up. Cover liquid spill with sand, earth
or other non-combustible absorbent material. Take up mechanically, placing in appropriate
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containers for disposal. Clean contaminated surface thoroughly. Soak up with inert
absorbent material. Pick up and transfer to properly labeled containers. Take precautionary
measures against static discharges.

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Use with local exhaust ventilation. All equipment used when handling the product must be
grounded. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use
personal protective equipment as required. Do not breathe
dust/fume/gas/mist/vapors/spray. Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapors).

Conditions for safe storage, including any incompatibilities

Storage Conditions Protect from moisture. Store locked up. Keep containers tightly closed in a cool,
well-ventilated place. Keep away from heat. Keep in properly labeled containers.

Incompatible materials Strong oxidizing agents, Acids, Water

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines .
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
CALCIUM CARBONATE - - TWA: 10 mg/m3 total dust
471-34-1 TWA: 5 mg/m3 respirable dust
LIMESTONE - TWA: 15 mg/m3 total dust TWA: 10 mg/m3 total dust
1317-65-3 TWA: 5 mg/m3 respirable fraction TWA: 5 mg/m3 respirable dust
(vacated) TWA: 15 mg/m3 total
dust
(vacated) TWA: 5 mg/m3 respirable
fraction
STEARIC ACID TWA: 10 mg/m3 inhalable - -
57-11-4 particulate matter
TWA: 3 mg/m3 respirable
particulate matter
NIOSH IDLH Immediately Dangerous to Life or Health

Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).

Appropriate engineering controls

Engineering Controls Showers

Eyewash stations
Ventilation systems

Individual protection measures, such as personal protective equipment

Eye/face protection Tight sealing safety goggles.

Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene™ or PVC gloves.

Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as
appropriate.

General Hygiene Considerations When using do not eat, drink or smoke. Regular cleaning of equipment, work area and
clothing is recommended.
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9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Physical state Paste Liquid
Appearance Blue
Odor Mild
Odor threshold No information available

Property Values Remarks • Method

pH No information available
Melting point / freezing point No information available
Boiling point / boiling range No information available Not Polymerization
Applicable
Flash point > 95 °C / > 203 °F Tag Closed Cup
Evaporation rate No information available
Flammability (solid, gas) No information available
Flammability Limit in Air
Upper flammability limit: No information available
Lower flammability limit: No information available
Vapor pressure <5 mm Hg @ 80°F
Vapor density 3.0 Air = 1
Relative density 1.44
Water solubility Not applicable Polymerization
Solubility(ies) No information available
Partition coefficient No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
Explosive properties No information available
Oxidizing properties No information available

Other Information
Softening point No information available
Molecular weight No information available
VOC Content (%) <3%
Density No information available
Bulk density No information available
SADT (self-accelerating No information available
decomposition temperature)

10. STABILITY AND REACTIVITY

Reactivity
No information available

Chemical stability
Stable under normal conditions

Possibility of Hazardous Reactions

None under normal processing.

Conditions to avoid
Heat, flames and sparks.

Incompatible materials
Strong oxidizing agents, Acids, Water

Hazardous Decomposition Products

Carbon dioxide (CO2)

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Nitrogen oxides (NOx)

Formaldehyde
May release 2-butanone oxime (ethyl methyl ketoxime) at elevated temperature

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Inhalation May cause irritation of respiratory tract.

Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes.

Skin contact May cause skin irritation and/or dermatitis. May cause sensitization by skin contact.

Ingestion Ingestion may cause irritation to mucous membranes.

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

CALCIUM CARBONATE = 6450 mg/kg ( Rat ) - -
471-34-1
STEARIC ACID = 4600 mg/kg ( Rat ) > 5 g/kg ( Rabbit ) -
57-11-4
2-BUTANONE OXIME = 930 mg/kg ( Rat ) 1000 - 1800 mg/kg ( Rabbit ) > 4.83 mg/L ( Rat ) 4 h
96-29-7

Information on toxicological effects

Symptoms No information available.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Sensitization No information available.

Germ cell mutagenicity No information available.
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Target Organ Effects Eyes, Respiratory system, Skin.

The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 14057 mg/kg
ATEmix (dermal) 23726 mg/kg

12. ECOLOGICAL INFORMATION

Ecotoxicity

0.001 % of the mixture consists of component(s) of unknown hazards to the aquatic environment

Persistence and degradability

No information available.

Bioaccumulation
No information available.

Mobility
No information available.

Chemical Name Partition coefficient

2-BUTANONE OXIME 0.65
96-29-7

Other adverse effects

No information available

13. DISPOSAL CONSIDERATIONS

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Waste treatment methods

Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.

Contaminated packaging Do not reuse container.

US EPA Waste Number Not applicable

This product contains one or more substances that are listed with the State of California as a hazardous waste.

14. TRANSPORT INFORMATION

DOT
Proper shipping name: Not regulated

IATA
Proper shipping name: Not regulated

IMDG
Proper shipping name: Not regulated

15. REGULATORY INFORMATION

International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Not determined
ENCS Not determined
IECSC Complies
KECL Complies
PICCS Complies
AICS Complies

Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances

US Federal Regulations

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories

Acute health hazard Yes
Chronic Health Hazard No
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No

CWA (Clean Water Act)

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This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)

CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material

US State Regulations

California Proposition 65
This product contains the following Proposition 65 chemicals
Chemical Name California Proposition 65
SILICA, QUARTZ *Carcinogen (airborne particles of respirable size only)
14808-60-7
• *The asterisked chemical(s) listed are not subject to Proposition 65 because they are not airborne in the finished product
U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania

LIMESTONE X X X
1317-65-3
ALUMINIUM POWDER X X X
7429-90-5
CI PIGMENT BLUE 15, CI #74160 X - X
147-14-8
SILICA, QUARTZ X X X
14808-60-7
U.S. EPA Label Information
EPA Pesticide Registration Number Not applicable

WHMIS Hazard Class

D2A - Very toxic materials

16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION

NFPA Health hazards 2 Flammability 1 Instability 0 -
HMIS Health hazards 2 Flammability 1 Physical hazards 0 Personal protection B

NFPA (National Fire Protection Association)

HMIS (Hazardous Material Information System)

Revision Date 13-May-2020

Disclaimer
Illinois Tool Works Inc. believes the information contained in this data sheet is accurate as of the date compiled.
However, Illinois Tool Works Inc. makes no warranty, express or implied, as to the accuracy, reliability or completeness
of the information. User is responsible for evaluating whether such information or this product is fit for a particular
purpose and suitable for a particular use or application. The information in this data sheet may not be valid if this
product is used in combination with other products or in processes for which it was not designed. Illinois Tool Works Inc.
disclaims any liability for consequential or incidental damages of any kind, including lost profits, arising from the sale or
use of this product. Ensure you have the most current version of this data sheet by contacting us or reviewing our web
site.

End of Safety Data Sheet

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