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WO2015065098A3 - 양극 활물질, 이의 제조방법, 및 이를 포함하는 리튬 이차전지 - Google Patents

양극 활물질, 이의 제조방법, 및 이를 포함하는 리튬 이차전지 Download PDF

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Publication number
WO2015065098A3
WO2015065098A3 PCT/KR2014/010355 KR2014010355W WO2015065098A3 WO 2015065098 A3 WO2015065098 A3 WO 2015065098A3 KR 2014010355 W KR2014010355 W KR 2014010355W WO 2015065098 A3 WO2015065098 A3 WO 2015065098A3
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WIPO (PCT)
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active material
cathode active
same
secondary battery
composite particles
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PCT/KR2014/010355
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English (en)
French (fr)
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WO2015065098A2 (ko
Inventor
곽익순
조승범
채화석
윤여준
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주식회사 엘지화학
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Priority to EP14853151.0A priority Critical patent/EP3062373B1/en
Priority to US14/437,085 priority patent/US9960418B2/en
Priority to CN201480002932.8A priority patent/CN104995769B/zh
Priority to JP2015546411A priority patent/JP6108249B2/ja
Publication of WO2015065098A2 publication Critical patent/WO2015065098A2/ko
Publication of WO2015065098A3 publication Critical patent/WO2015065098A3/ko

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • H01M4/366Composites as layered products
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028Positive electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00Batteries for particular applications
    • H01M2220/20Batteries in motive systems, e.g. vehicle, ship, plane
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00Batteries for particular applications
    • H01M2220/30Batteries in portable systems, e.g. mobile phone, laptop
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/60Other road transportation technologies with climate change mitigation effect
    • Y02T10/70Energy storage systems for electromobility, e.g. batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

본 발명은 리튬 전이금속 산화물 입자; 및 복합 입자를 포함하고, 상기 복합 입자는 YSZ(yttria stabilized zirconia), GDC(gadolinia-doped ceria), LSGM(lanthanum strontium gallate magnesite), LSM(lanthanum strontium manganite) 및 Ni-YSZ로 이루어진 군으로부터 선택되는 어느 하나 또는 이들 중 2종 이상의 혼합물을 포함하며, 상기 양극 활물질은 X-레이 회절 (X-Ray Diffraction; XRD) 분석 측정시 단일상 피크의 복합 입자를 갖는 것을 특징으로 하는 양극 활물질을 제공한다. 본 발명의 일 실시예에 따른 양극 활물질은 이차전지의 용량 감소나 출력 감소를 최소화할 수 있을 뿐만 아니라, 수명 특성을 더욱 향상시킬 수 있다.
PCT/KR2014/010355 2013-10-31 2014-10-31 양극 활물질, 이의 제조방법, 및 이를 포함하는 리튬 이차전지 WO2015065098A2 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP14853151.0A EP3062373B1 (en) 2013-10-31 2014-10-31 Cathode active material, method for preparing same, and lithium secondary battery comprising same
US14/437,085 US9960418B2 (en) 2013-10-31 2014-10-31 Cathode active material, preparation method thereof, and lithium secondary battery comprising the same
CN201480002932.8A CN104995769B (zh) 2013-10-31 2014-10-31 正极活性物质及其制备方法以及包含该正极活性物质的锂二次电池
JP2015546411A JP6108249B2 (ja) 2013-10-31 2014-10-31 正極活物質、この製造方法、及びこれを含むリチウム二次電池

Applications Claiming Priority (2)

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KR10-2013-0131636 2013-10-31
KR20130131636 2013-10-31

Publications (2)

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WO2015065098A2 WO2015065098A2 (ko) 2015-05-07
WO2015065098A3 true WO2015065098A3 (ko) 2015-06-25

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US (1) US9960418B2 (ko)
EP (1) EP3062373B1 (ko)
JP (1) JP6108249B2 (ko)
KR (1) KR101539898B1 (ko)
CN (1) CN104995769B (ko)
TW (1) TWI525889B (ko)
WO (1) WO2015065098A2 (ko)

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EP3062373A4 (en) 2017-05-17
EP3062373B1 (en) 2019-05-22
KR101539898B1 (ko) 2015-07-27
KR20150050509A (ko) 2015-05-08
EP3062373A2 (en) 2016-08-31
US20160028077A1 (en) 2016-01-28
CN104995769A (zh) 2015-10-21
WO2015065098A2 (ko) 2015-05-07
CN104995769B (zh) 2018-03-16
TW201530877A (zh) 2015-08-01
JP2016506032A (ja) 2016-02-25
JP6108249B2 (ja) 2017-04-05
TWI525889B (zh) 2016-03-11
US9960418B2 (en) 2018-05-01

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