TW198731B - - Google Patents
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- Publication number
- TW198731B TW198731B TW080109204A TW80109204A TW198731B TW 198731 B TW198731 B TW 198731B TW 080109204 A TW080109204 A TW 080109204A TW 80109204 A TW80109204 A TW 80109204A TW 198731 B TW198731 B TW 198731B
- Authority
- TW
- Taiwan
- Prior art keywords
- compounds
- resin
- powder
- lubricant
- compound
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M3/00—Liquid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single liquid substances
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M103/00—Lubricating compositions characterised by the base-material being an inorganic material
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
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- C10M111/00—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/003—Inorganic compounds or elements as ingredients in lubricant compositions used as base material
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/0403—Elements used as base material
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/043—Sulfur; Selenenium; Tellurium
- C10M2201/0433—Sulfur; Selenenium; Tellurium used as base material
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- C10M2201/06—Metal compounds
- C10M2201/061—Carbides; Hydrides; Nitrides
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- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
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- C10M2201/065—Sulfides; Selenides; Tellurides
- C10M2201/066—Molybdenum sulfide
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- C10M2201/08—Inorganic acids or salts thereof
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- C10M2201/08—Inorganic acids or salts thereof
- C10M2201/081—Inorganic acids or salts thereof containing halogen
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- C10M2201/08—Inorganic acids or salts thereof
- C10M2201/082—Inorganic acids or salts thereof containing nitrogen
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- C10M2201/084—Inorganic acids or salts thereof containing sulfur, selenium or tellurium
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- C10M2201/085—Phosphorus oxides, acids or salts
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- C10M2201/087—Boron oxides, acids or salts
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- C10M2201/10—Compounds containing silicon
- C10M2201/102—Silicates
- C10M2201/103—Clays; Mica; Zeolites
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- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/003—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions used as base material
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- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/022—Ethene
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- C10N2040/245—Soft metals, e.g. aluminum
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Forging (AREA)
Description
經濟部屮央標準杓Π工消奸合作社印级 Λ 6 Β6 五、發明説明(1 ) 本發明係有關在冷、溫或熱之鍛造鋁合金的作茱中, 可藉由一般之噴霧法或靜電式噴霧法噴鍍於模型或噴鍍為 鋁合金之鍛造鋁合金用粉末潤滑劑。 鍛造品係通常被多方面使用於飛機、汽車、電機器等 之各種零件者,由於要求軽量所以已由鐵漸行改為軽合金 ,例如鋁合金已漸被使用。鍛造作業中通常係在模型與材 料之間放入潤滑劑或潤滑油,防止二者熔粘在一起,更易 自模型剝離鍛造品。 锻造鋁合金用潤滑劑通常係使用添加有石墨之油溶性 潤滑劑、合成酯、聚矽氣油、石墨、賦加極壓劑、及界面 活性劑所成水溶性潤疳劑。 惟近年來由於各種零件之輕量化,配合鋁合鍛造技術 之進步,要求可在更佳之作業性下獲得高品質製品之潤滑 劑。而以往之潤滑劑已無法滿足如上述之要求。即,油性 潤滑劑時有冒煙、污染作業場所、箸火之危險等問題。水 溶性潤滑劑則為防止使用後之水質污染必須設置廢水處理 ,有耗資設備投資等各種經費之問題。為此乃極殷切地希 望開發新形態之鍛造鋁合金用潤滑劑。 本發明像有鑑於上述各問題而經再三研究,進行各種 条統性之實驗所得結果者,係以提供在锻造鋁合金作‘業中 ,欲在更佳作業性並且不破壞環境下獲得更高品質之鍛造 品時可用之鍛造鋁合金用潤滑劑為目的者。 本發明之锻造鋁合金用粉末潤滑劑偽將固體且做為潤 滑劑所使用之無機化合物所成粉末狀或顆粒狀的潤滑劑基 本紙張尺度逍用中國a家樣準(CHS)甲4規格(210x297公釐) (請先閲讀背面之注意事項再填寫本頁) 裝· -線· -3 - 五、發明説明(2 ) 材,與可使潤滑劑基材具有付著性之有機化合物予以混合 所成之潤滑劑,兩者均為具有粉末狀或顆粒狀形態,或具 有潤滑劑基材被有機化合物所被覆之形態做為其待徴。 本發明之最大持擞傜潤滑基材具有粉末狀或顆粒狀之 形態。 而對於無機化合物而言,有機化合物含有比率僳選自 0.1〜50重量%範圍較為有效。較0.1重量%少時 ,無機化合物無法獲得可充分附著於模型内面之效果, 5◦重量%以上時,會發生冒煙,形成重叠,有時無法自 模型剝離鍛造品,即降低潤滑效果,無法保有製品之尺寸 精密度。 ' 本發明中可用之潤滑劑基材係只要為固體可做為潤滑 劑之無機化合物即不予特別限制。通常使用氮化硼、氟化 物、滑石、雲母、金屬氧化物、氮化矽、硼化合物、硫化 合物、磷化合物為宜,惟其他以往做為潤滑劑被使用之公 « 經濟部中央標準A工消合作社印3i (請先閱讀背面之注意事項再填寫本頁) 知固體潤滑劑,例如石墨、二硫化鉬等亦可使用。而此等 無機化合物係以粉末狀或顆粒狀形態,僅使用其一種、或 組合二種以上使用。 又,本發明可用之有機化合物係只要對如上述之無機 化合物具有附著性、轉粘性之性質者即無特別限制。·通常 以金屬肥皂、高分子化合物,及藉由環猢精化合物使液體 狀或膏狀化合物成為粉末狀或顆粒狀者較適於使用。金屬 肥皂以羧酸架構上付加鈉、鈣、鋁、鋇、鋰、鉀、鎂、或 鈴者,又,高分子化合物係聚乙烯、聚丙烯、環氧樹脂、 本紙張尺度逍用中國國家標準(CNS)甲4規格(210父297公釐) -4 - Λ 6 Β6The Ministry of Economic Affairs Standard Standards 揓 Π 工 消 湃 會 cooperative grade Λ 6 Β6 V. Description of the invention (1) The present invention relates to the work of forging aluminum alloys in cold, warm or hot, which can be done by the general spray method or Electrostatic spraying method is used to spray powder lubricant for forging aluminum alloy on model or aluminum alloy. Forged products are generally used in various parts of airplanes, automobiles, electric machines, etc., because of the requirement for the amount of light, they have been gradually changed from iron to light alloys, such as aluminum alloys. In the forging operation, lubricants or lubricants are usually placed between the model and the material to prevent the two from melting and sticking together, making it easier to peel off the forged product from the model. Lubricants for forging aluminum alloys are usually water-soluble lumps made of graphite-added oil-soluble lubricants, synthetic esters, polysilicone oil, graphite, extreme pressure agents, and surfactants. However, in recent years, due to the lightweight of various parts and the advancement of aluminum alloy forging technology, it is required to obtain high-quality lubricants with better workability. In the past, lubricants could no longer meet the above requirements. That is, the oil-based lubricant has problems such as smoke, contamination of the work place, and the risk of fire. In order to prevent water pollution after use, water-soluble lubricants must be equipped with wastewater treatment, and there are various expenses such as costly equipment investment. Therefore, it is extremely eager to develop new forms of lubricants for forged aluminum alloys. In view of the above problems, the present invention has undergone repeated research and conducted various systematic experiments to provide results for the forging of aluminum alloys in order to achieve higher workability without destroying the environment. A lubricant for forged aluminum alloy that can be used for quality forged products. The powder lubricant for wrought aluminum alloy of the present invention uses a solid or inorganic compound used as a lubricant to form a powder or granular lubricant. The basic paper size is easy to use. China A Home Standard (CHS) A 4 specifications ( 210x297mm) (Please read the precautions on the back before filling in this page) Fifth, -Line · -3-V. Description of the invention (2) Material, mixed with organic compounds that can make the lubricant base material adhered The resulting lubricants are both in the form of powder or granules, or the form in which the lubricant base material is coated with an organic compound is taken as its standby. The largest lubricating base material of the present invention has a powdery or granular form. For inorganic compounds, the organic compound content ratio is preferably selected from the range of 0.1 to 50% by weight. When it is less than 0.1% by weight, the inorganic compound cannot obtain the effect of sufficiently adhering to the inner surface of the model. At 5% by weight or more, smoke occurs and overlaps, and sometimes the forged product cannot be peeled from the model, that is, the lubricating effect is reduced, and the Maintain the dimensional precision of products. The lubricant base material usable in the present invention is not particularly limited as long as it is a solid inorganic compound that can be used as a lubricant. Usually boron nitride, fluoride, talc, mica, metal oxides, silicon nitride, boron compounds, sulfur compounds, phosphorus compounds are suitable, but other companies that have been used as lubricants in the past Consumer Cooperative Printed 3i (Please read the precautions on the back before filling this page) Know that solid lubricants, such as graphite, molybdenum disulfide, etc. can also be used. However, these inorganic compounds are used in the form of powder or granules, and only one kind of them or a combination of two or more kinds is used. In addition, the organic compounds usable in the present invention are not particularly limited as long as the inorganic compounds as described above have the properties of adhesion and viscosity conversion. · Usually, metal soaps, polymer compounds, and liquid or paste compounds made of cyclospermium compounds into powders or granules are more suitable for use. The metal soap is added with sodium, calcium, aluminum, barium, lithium, potassium, magnesium, or bell on the carboxylic acid structure, and the polymer compound is polyethylene, polypropylene, epoxy resin, and the paper standard is used in accordance with Chinese national standards. (CNS) A 4 specifications (210 father 297 mm) -4-Λ 6 Β6
19873X 五、發明説明(3 ) (請先閲讀背面之注意事項再塡寫本頁) 矽樹脂、天然蟠類、酚樹脂、丙烯酸糸樹脂、醇酸樹脂、 胺基甲酸乙酯、苯乙烯樹脂、或氟樹脂,又,液體狀或膏 狀之化合物則可為合成樹脂類、天然油脂類、礦物油類、 聚矽氧油、聚苯醚、聚伸烷二醇、或乙烯一丙烯共聚物較 適於使用。此等有機化合物係以粉末狀或顆粒狀之形態與 潤滑劑基材混合,或以被加熱熔融之狀態被混合入潤滑劑 基質。因此本發明之潤滑劑係潤滑劑基材與有機化合物雙 方均呈粉末狀或顆粒狀之形態,或呈粉末狀或顆粒狀之潤 滑劑基材為被有機化合物所被覆之形態。又,有機化合物 係可以僅用上述化合物之一種,或組合二種以上使用。亦 可以組合使用金屬肥皂、與高分字化合物、粉末化之液體 狀或膏狀之化合物。 本發明之鍛造鋁合金用粉末潤滑劑係至少潤滑劑基材 為呈粉末狀或顆粒狀形態,所以即使鍛造作業中受到加熱 亦不易分解,極易自模型取出鍛造品,並且可防止氣體捲 入鍛造品内部,提高尺寸精密度或製品品質。 經濟部屮央標準AM工消费,合作社印奴 又,本發明之潤滑劑傺具有粉末狀或顆粒狀之形態, 不含水份,所以使用後不會如水溶性潤滑劑一樣污染水質 ,亦不會如油溶性潤滑劑一樣污染作業環境。因此不必為 廢水處理而花大筆經費,為防止璟境惡化而需一筆經費。 另外,由於本發明不含油性者,所以沒有冒煙、著火之危 險性,安全性亦無問題。 另外,本發明之潤滑劑傜至少潤滑劑基材為呈粉末狀 或顆粒狀形態,所以附著潤滑劑之模型内面部傺與材料( 本紙ifc尺度边用中國a家標準(CNS)〒4規格(210X297公¢) -5 - 198731 Λ6 __Β£ 五、發明説明(4 ) 鋁合金)之間至少會確實地隔著潤滑劑基材粉末與或顆粒 之粒徑。所以潤滑劑可以充分地附著於模型内面,以防止 材料與模型内面直接接觸,可防止塑性變形時的熔粘,更 可防止模型之摩損,提高作業性。 依本發明時可以使無機化合物所成潤滑劑基材與其與 有機化合物之混合物所成的鍛造鋁合金用粉末潤滑劑中的 至少潤滑劑基材為粉末狀或顆粒狀形態者,所以可降低塑 性變形時之鋁合金變形率,防止熔粘,得到高品質之鍛造 品,更可以充分防止在使用中及在使用後惡化環境。 經濟部屮央標準乃Π工消设合作社卬31 (請先閲讀背面之注意事項再填寫本頁) 尤其對無機化合物含有0.1〜50重量%範圍的有 機化合物時,可以獲得更佳品質乏鍛造品。另外,做為無 機化合物使用氮化硼、氟化物、滑石、雲母、金屬氧化物 、氮化矽、硼化合物、硫化合物、磷化合物,而有機化合 物可為使用羧酸架構上付加鈉、鈣、鋁、鋇、鋰、鉀、鎂 、或鋅之金靥肥皂,或聚乙烯、聚丙烯、環氣樹脂、矽樹 脂、天然蠟類、酚樹脂、丙烯酸糸樹脂、醇酸樹脂、胺基 甲酸乙酯、苯乙烯樹脂、或氣樹脂之高分子化合物或藉由 環糊精化合物使合成酯類、天然油脂類、礦物油類、聚矽 氣油、聚苯醚、聚伸烷二醇、或乙烯一丙烯共聚物等液體 或膏狀之化合物成為粉末狀或顆粒狀者,即更能發揮·上述 效果。而上述無機化合物、有機化合物中,可以分別使用 組合二種以上者,即能獲最適於锻造作業上使用之潤滑劑 〇 (實施例) 本紙尺度逍用中國a家標準(CNS)甲4規格(2丨0x297公及) -6 - 經濟部十央標準/i'JM工消设合作社印31 五、發明説明(5 ) 以下示本發明實施例,惟本發明並不限定於此。 首先獲得以下所示(A)〜(G)潤滑劑,使用此等 潤滑劑進行鍛造鋁合金之鍛造作業,依表1所示項目比較 檢討。另外,使用之合金偽J I S20 14高力合金。锻 造溫度傜390*0,潤滑劑傜以靜電噴霧法予以噴霧。本 發明例之(A)〜(D)混合物僳針對以粉末狀或顆粒狀 形態將有機化合物混合予無機化合物者,以加熱熔融狀態 混合有機化合物予無機化合物之雙方分別進行檢討,惟結 果均相同。又,(D)之有機化合物像使用以實驗性方法 使用環糊精化合物粉末化天然油脂者,而其他化合物則傜 市販者。 _ (A) 90份雲母(平均粘度6w)與10份聚乙烯 之混合物所成本發明之第1例 (B) 10份氮化硼、60份雲母、30份硬脂酸鈣 之混合物所成本發明之第2例 (C) 70份滑石、10份氮化矽、10份天然蠟、 1 0份硬脂酸鋅之混合物所成本發明之第3例 (D) 2 0份氮化硼、60份滑石、5份硼酸鈉、與 15份粉末化天然油脂之混合物所成本發明第4例 (E )僅使用氮化硼(比較例1 ) (F )由礦物油、天然油脂、石墨所成市販之鍛造用 潤滑劑(比較例2 ) (G)由羧酸鹽、合成蟠、極壓賦加劑、界面活性劑 所成市販鍛造用潤滑劑(比較例3) (請先閱讀背面之注意事項再填寫本頁) 裝< 訂. 線· 本紙5fc尺度边用中a B家標準(CNS)甲4規格(210x297公《:) -7 - 經濟部中央標準杓:^工消讣合作社印51 / i9的3上 Λ6 Β 6 五、發明説明(6 ) 〔表1〕 本 發明 比 較 例 (A) (B) (C) (D) (E) (F) (G) 對模型之附著性 Ο Ο Θ Ο X 〇 Δ 品 熔粘防止效果 Ο ◎ Ο Ο — 〇 △ 質 防止缺角之效果 0 Θ Ό © — 〇 X 影 防止裂痕效果 © Ο Ο © — 〇 X 逛 提高鍛造品表面 Θ 〇 Q 〇 — 〇 △ 因 之品質效果 子 防止油傷效果 Θ Ο Q Ο — X △ 防止發生冒煙、水蒸汽等 © ◎ Ο © — 〇 △ 致使惡化作業場環境 X :完全無,一:無法測定不能,△:小,〇:普通,〇:大 (請先閱讀背面之注意事項再填寫本頁) 本紙张尺度边用中國國家標準(CNS)甲4規格(210><297公垃) -8 -19873X V. Description of the invention (3) (Please read the precautions on the back before writing this page) Silicone resin, natural flats, phenol resin, acrylic resin, alkyd resin, urethane, styrene resin, Or fluororesin, and the liquid or paste compound can be synthetic resins, natural oils, mineral oils, silicone oil, polyphenylene oxide, polyalkylene glycol, or ethylene-propylene copolymer Suitable for use. These organic compounds are mixed with the lubricant base material in the form of powder or granules or mixed into the lubricant base in a state of being heated and melted. Therefore, both the lubricant base material and the organic compound of the present invention are in the form of powder or granules, or the lubricant base material in the form of powder or granules is coated with organic compounds. In addition, the organic compound may be used alone or in combination of two or more. It is also possible to use a combination of metal soap, a compound with a high-resolution character, and a powdered liquid or paste compound. The powder lubricant for forged aluminum alloy of the present invention has at least a lubricant base material in a powder or granular form, so it is not easy to decompose even if it is heated during the forging operation, it is very easy to take out the forged product from the model, and it can prevent the gas from getting involved Forged products inside, improve dimensional precision or product quality. The Ministry of Economic Affairs standard AM industrial consumption, cooperative cooperative Yinnu, and the lubricant of the present invention has a powder or granular form, does not contain moisture, so it will not pollute the water quality like a water-soluble lubricant after use, nor will it As the oil-soluble lubricant pollutes the working environment. Therefore, there is no need to spend a lot of money on wastewater treatment, and a sum of money is needed to prevent the deterioration of the environment. In addition, since the present invention does not contain oily substances, there is no danger of smoke or fire, and there is no problem in safety. In addition, at least the lubricant base material of the present invention is in the form of powder or granules, so the surface of the model and the material to which the lubricant is attached (this paper is based on the Chinese standard (CNS) 〒4 specifications (ifc scale) 210X297 public ¢) -5-198731 Λ6 __Β £ V. Description of the invention (4) Aluminum alloy) At least the particle size of the lubricant base powder and / or particles will be surely separated. Therefore, the lubricant can be sufficiently attached to the inner surface of the model to prevent the material from directly contacting the inner surface of the model, to prevent the melt adhesion during plastic deformation, to prevent the friction of the model and improve the workability. According to the present invention, at least the lubricant base material in the powdered lubricant for forged aluminum alloy formed of the lubricant base material made of inorganic compound and the mixture with the organic compound can be in powder or granular form, so the plasticity can be reduced The deformation rate of the aluminum alloy during deformation prevents fusion and high-quality forged products, and can fully prevent the deterioration of the environment during use and after use. The Ministry of Economy ’s standard is the Industrial and Commercial Cooperative Society 31 (please read the precautions on the back before filling in this page). Especially for inorganic compounds containing organic compounds in the range of 0.1 to 50% by weight, better quality forged products can be obtained . In addition, as inorganic compounds, boron nitride, fluoride, talc, mica, metal oxides, silicon nitride, boron compounds, sulfur compounds, phosphorus compounds, and organic compounds can be added with sodium, calcium, Aluminium, barium, lithium, potassium, magnesium, or zinc soaps of gold, or polyethylene, polypropylene, ring gas resins, silicone resins, natural waxes, phenol resins, acrylic resins, alkyd resins, urethane Polymer compounds of esters, styrene resins, or gas resins or cyclodextrin compounds are used to synthesize esters, natural oils, mineral oils, silicone oils, polyphenylene oxides, polyalkylene glycols, or ethylene If a liquid or paste-like compound such as a propylene copolymer becomes a powder or granule, the above effects can be more exerted. Among the above-mentioned inorganic compounds and organic compounds, two or more of them can be used in combination, respectively, to obtain the most suitable lubricant for forging operations. (Examples) This paper standard is used in China A Standard (CNS) A4 specifications ( 2 丨 0x297 Gong)) -6-Shiyang Standard of the Ministry of Economic Affairs / i'JM Industrial and Commercial Cooperative Printing Co., Ltd. 31 V. Description of the Invention (5) The following shows examples of the present invention, but the present invention is not limited thereto. First, obtain the lubricants (A) to (G) shown below. Use these lubricants to forge aluminum alloys. For comparison, review the items shown in Table 1. In addition, the alloy used is pseudo-J I S20 14 high-strength alloy. Forging temperature is 390 * 0, lubricant is sprayed by electrostatic spray method. The (A) to (D) mixtures of the examples of the present invention were reviewed for both the organic compound and the inorganic compound mixed in powder or granular form, and the organic compound and the inorganic compound were mixed in a heated and melted state, but the results were the same . In addition, the organic compound of (D) is like a person who uses a cyclodextrin compound to pulverize natural oils and fats in an experimental method, and other compounds are marketers. _ (A) A mixture of 90 parts mica (average viscosity 6w) and 10 parts polyethylene costs the first example of the invention (B) A mixture of 10 parts boron nitride, 60 parts mica and 30 parts calcium stearate costs the invention The second example (C) a mixture of 70 parts talc, 10 parts silicon nitride, 10 parts natural wax, and 10 parts zinc stearate is the third example of the invention (D) 20 parts boron nitride, 60 parts The mixture of talc, 5 parts of sodium borate, and 15 parts of powdered natural oil costs the fourth example of the invention (E). Only boron nitride is used (Comparative Example 1) (F). It is made of mineral oil, natural oil, and graphite. Forging lubricants (Comparative Example 2) (G) Commercially available forging lubricants (Comparative Example 3) made from carboxylates, synthetic flats, extreme pressure additives, and surfactants (Please read the notes on the back before (Fill in this page) Install & Order. Line · This paper is used in the 5fc scale side a B home standard (CNS) A 4 specifications (210x297 public ":) -7-Central Standards of the Ministry of Economic Affairs: ^ 工 消 讣 合 社 印 51 / Λ6 Β 6 on i9 3. Description of the invention (6) [Table 1] Comparative examples of the invention (A) (B) (C) (D) (E) (F) (G) Adhesion to the model Ο Ο Θ Ο X 〇Δ Product anti-sticking effect Ο ◎ Ο Ο — 〇 △ Quality prevention of corner loss 0 Θ Ό © — 〇X Shadow prevention effect © Ο Ο © — 〇X Go to improve the surface of forged products Θ 〇Q 〇- 〇 △ Because of Quality effect prevention oil damage effect Θ Ο Q Ο — X △ Prevents the occurrence of smoke, water vapor, etc. Ordinary, 〇: large (please read the precautions on the back before filling in this page) This paper uses the Chinese National Standard (CNS) A4 specifications (210 > < 297 public waste) -8-
Claims (1)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3176539A JPH0517795A (en) | 1991-07-17 | 1991-07-17 | Powdery lubricant for forging of aluminum alloy |
Publications (1)
Publication Number | Publication Date |
---|---|
TW198731B true TW198731B (en) | 1993-01-21 |
Family
ID=16015368
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW080109204A TW198731B (en) | 1991-07-17 | 1991-11-23 |
Country Status (6)
Country | Link |
---|---|
JP (1) | JPH0517795A (en) |
KR (1) | KR940010303B1 (en) |
CA (1) | CA2059901A1 (en) |
DE (1) | DE4212667A1 (en) |
GB (1) | GB2257712A (en) |
TW (1) | TW198731B (en) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2693470B1 (en) * | 1992-07-07 | 1994-09-23 | Roquette Freres | Compositions for aqueous machining fluids and aqueous machining fluids based on fatty substances and cyclodextrin. |
CA2116880A1 (en) * | 1993-03-23 | 1994-09-24 | Anthony P. Willoughby | Forging lubricant composition and process |
JP3826164B2 (en) * | 1993-12-24 | 2006-09-27 | ビーピー・ジャパン株式会社 | Lubricant for forming aluminum or aluminum alloy, and aluminum or aluminum alloy plate for forming |
US6455476B1 (en) | 1998-06-09 | 2002-09-24 | Henkel Corporation | Composition and process for lubricated plastic working of metals |
IN192718B (en) * | 1998-06-09 | 2004-05-15 | Nihon Parkerizing | |
US20050119133A1 (en) | 2002-03-25 | 2005-06-02 | Shinobu Komiyama | Metal soap-coated particle article made with the same process for production lubricating coating agent and lubricating film |
KR100679242B1 (en) * | 2005-04-22 | 2007-02-05 | 한국마그네슘기술연구조합 | A Lubricant and A making method for extruding magnesium alloy |
US8283296B2 (en) | 2006-10-11 | 2012-10-09 | Henkel Ag & Co., Kgaa | Lubricant for hot forging applications |
JP5297742B2 (en) * | 2008-09-26 | 2013-09-25 | 株式会社青木科学研究所 | Powder-containing oil-based lubricant for molds, electrostatic coating method using the same, and electrostatic coating apparatus |
US20130157191A1 (en) | 2010-09-14 | 2013-06-20 | Konica Minolat Business Technologies, Inc. | Toner for electrophotography and image-forming method |
EP2703454A1 (en) * | 2012-08-29 | 2014-03-05 | Pemco Brugge BVBA | Coating compositions |
EP2735592A1 (en) * | 2012-11-26 | 2014-05-28 | Hydro Aluminium Rolled Products GmbH | Coating of a metal sheet or strip |
CN103111567B (en) * | 2013-02-05 | 2015-02-25 | 上海交通大学 | Lubricant coating method |
JP6029526B2 (en) * | 2013-04-26 | 2016-11-24 | 株式会社神戸製鋼所 | Coating apparatus and coating method |
JP6244384B2 (en) * | 2013-06-07 | 2017-12-06 | ハイドロ アルミニウム ロールド プロダクツ ゲゼルシャフト ミット ベシュレンクテル ハフツングHydro Aluminium Rolled Products GmbH | Metal sheet or strip coating |
CN104450136A (en) * | 2014-11-05 | 2015-03-25 | 衡阳市金化科技有限公司 | Bentonite lubricant |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB970739A (en) * | 1962-02-02 | 1964-09-23 | Secr Aviation | An improved lubricant |
GB2003923B (en) * | 1977-09-07 | 1982-03-10 | Foseco Int | Metal working lubricants |
CA1126718A (en) * | 1978-02-07 | 1982-06-29 | Torao Nagura | Lubricant for plastic working |
JPS54118955A (en) * | 1978-03-07 | 1979-09-14 | Aichi Steel Works Ltd | Lubricant for plastic working |
US4281528A (en) * | 1978-07-27 | 1981-08-04 | Trw Inc. | Process for isothermally shaping a titanium-containing metal workpiece |
JPS5911399A (en) * | 1982-07-09 | 1984-01-20 | Nippon Steel Chem Co Ltd | High temperature-use lubricant composition |
DE3245827A1 (en) * | 1982-12-10 | 1984-06-28 | Kobe Steel, Ltd., Kobe, Hyogo | LUBRICANT FILM FOR PREVENTING EATING OF SLIDING METAL SURFACES |
EP0153039B1 (en) * | 1984-02-04 | 1988-08-17 | Dowa Mining Co., Ltd. | Lubricant for skis and the like |
JPH069730B2 (en) * | 1989-01-13 | 1994-02-09 | 花野商事株式会社 | Powder mold release agent for die casting |
JPH0350298A (en) * | 1989-06-16 | 1991-03-04 | Castrol Ind Inc | Carrier-free lubricant for forging, and use thereof |
JPH04236300A (en) * | 1991-01-17 | 1992-08-25 | Hanano Shoji Kk | Powdery lubricant for plunger device |
-
1991
- 1991-07-17 JP JP3176539A patent/JPH0517795A/en active Pending
- 1991-11-23 TW TW080109204A patent/TW198731B/zh active
- 1991-12-19 KR KR1019910023475A patent/KR940010303B1/en not_active IP Right Cessation
-
1992
- 1992-01-23 CA CA002059901A patent/CA2059901A1/en not_active Abandoned
- 1992-02-03 GB GB9202254A patent/GB2257712A/en not_active Withdrawn
- 1992-04-15 DE DE4212667A patent/DE4212667A1/en not_active Ceased
Also Published As
Publication number | Publication date |
---|---|
GB2257712A (en) | 1993-01-20 |
CA2059901A1 (en) | 1993-01-18 |
DE4212667A1 (en) | 1993-01-21 |
JPH0517795A (en) | 1993-01-26 |
KR940010303B1 (en) | 1994-10-22 |
GB9202254D0 (en) | 1992-03-18 |
KR930002489A (en) | 1993-02-23 |
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