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KR100256180B1 - Injection foaming product and manufacturing method thereof - Google Patents

Injection foaming product and manufacturing method thereof Download PDF

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Publication number
KR100256180B1
KR100256180B1 KR1019970043010A KR19970043010A KR100256180B1 KR 100256180 B1 KR100256180 B1 KR 100256180B1 KR 1019970043010 A KR1019970043010 A KR 1019970043010A KR 19970043010 A KR19970043010 A KR 19970043010A KR 100256180 B1 KR100256180 B1 KR 100256180B1
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KR
South Korea
Prior art keywords
cavity
foaming
main
foam
injection
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KR1019970043010A
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Korean (ko)
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KR19990019616A (en
Inventor
박수관
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박수관
주식회사영창신기술
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Priority to KR1019970043010A priority Critical patent/KR100256180B1/en
Priority to JP09369633A priority patent/JP3083800B2/en
Priority to DE19812694A priority patent/DE19812694A1/en
Priority to TW087104281A priority patent/TW424038B/en
Priority to IDP980420A priority patent/ID20771A/en
Priority to IT98TO000257A priority patent/ITTO980257A1/en
Priority to CA002233054A priority patent/CA2233054A1/en
Priority to CN98105889A priority patent/CN1211498A/en
Priority to ES009800657A priority patent/ES2164499B1/en
Priority to BR9800935-4A priority patent/BR9800935A/en
Publication of KR19990019616A publication Critical patent/KR19990019616A/en
Application granted granted Critical
Publication of KR100256180B1 publication Critical patent/KR100256180B1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D35/00Producing footwear
    • B29D35/12Producing parts thereof, e.g. soles, heels, uppers, by a moulding technique
    • B29D35/14Multilayered parts
    • B29D35/142Soles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/12Moulds or cores; Details thereof or accessories therefor with incorporated means for positioning inserts, e.g. labels
    • B29C33/14Moulds or cores; Details thereof or accessories therefor with incorporated means for positioning inserts, e.g. labels against the mould wall
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/02Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
    • B29C44/12Incorporating or moulding on preformed parts, e.g. inserts or reinforcements
    • B29C44/1228Joining preformed parts by the expanding material
    • B29C44/1233Joining preformed parts by the expanding material the preformed parts being supported during expanding
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0846Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0853Vinylacetate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04Polymers of ethylene
    • B29K2023/08Copolymers of ethylene
    • B29K2023/083EVA, i.e. ethylene vinyl acetate copolymer

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Molding Of Porous Articles (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Peptides Or Proteins (AREA)

Abstract

PURPOSE: An injection-foamed material and its preparation method are provided, which injection foamed one has at least one different natured material area, thereby to allow the design and appearance to be varied easily. CONSTITUTION: The method comprises the steps of preparing the main foaming material containing a resin and a foaming agent; molding the aid material inserted one which comprises the main foaming material and a cross-linkable resin and has the different nature from that of the main foaming material; forming the area for the aid material inserted one in the cavity of a foaming mold; inserting the solid aid material inserted one into the cavity; charging the liquid main foaming material into the cavity; and maturing it at specific temperature for specific period, opening the mold and foaming it. The main foaming material has the different color, foaming density or both from those of the aid material inserted one.

Description

이질재료영역을 갖는 사출발포물 및 그 제조방법{}Injection foam having heterogeneous material region and manufacturing method thereof

본 발명은 적어도 하나의 이질재료영역을 갖는 사출발포물 및 그 제조방법에 관한 것이다.The present invention relates to an injection foam having at least one foreign material region and a method of manufacturing the same.

사출발포기법은, 금형내에 형성되어 있는 소정형상의 캐비티내에 EVA 등의 수지재료와 발포제의 혼합물을 충전한 다음, 170도 내지 190도의 온도에서 6 내지 10분동안 숙성시킨 후 금형을 개방하면, 발포제 가스의 팽창에 의해 캐비티보다 약 30%이상 팽창된 제품 즉 사출발포물이 얻어지게 되는 공법을 말한다. 이러한 사출발포기법은, 최근에 개발된 발포기술로서, 아직 법용화의 단계에 이르지는 못하였지만, 다양한 형상과 물성의 발포물을 신속하고 용이하게 얻을 수 있다는 장점을 가지고 있으므로, 장래 그 적용범위가 폭넓게 확장될 것으로 예상된다.In the injection foaming method, a mixture of a resin material such as EVA and a foaming agent is filled into a cavity having a predetermined shape formed in the mold, and then aged for 6 to 10 minutes at a temperature of 170 to 190 degrees. It refers to a method in which a product, that is, an injection foam, which is expanded about 30% or more than a cavity by gas expansion is obtained. This injection foaming technique is a recently developed foaming technology, which has not yet reached the stage of legalization, but has the advantage of being able to obtain foams of various shapes and properties quickly and easily. It is expected to expand widely.

이러한 사출발포물은, 신발 특히 스포츠화의 미드솔(mid-sole)이나 아웃솔(out-sole)등과 같은 신발부품에 적극적으로 채용되고 있으며, 근래에는 미드솔과 아웃솔을 단일의 사출발포물로서 일체화한 제품이 개발되고 있다. 종래의 스포츠화에서는, 미국특허 US 4,245,406호에서 볼 수 있는 바와 같이, 폴리우레탄 등의 발포물로 만들어진 미드솔의 하부면에 고무로 된 아웃솔을 부착하여 신발의 밑창을 제조하였다. 그러나, 전술한 사출발포기법에 의하면, 이러한 미드솔과 아웃솔을 일체로 제조할 수 있으므로, 제품의 중량을 감소시킬 수 있고 제조비용을 현저히 절감할 수 있는 동시에 생산성도 현저히 높아질 수 있다는 장점이 있다.Such injection foams are actively employed in footwear, such as mid-soles or out-soles of sports shoes, and in recent years, products in which midsoles and outsoles are integrated as a single injection foam. Is being developed. In conventional sports shoes, as shown in US Pat. No. 4,245,406, the sole of a shoe was manufactured by attaching a rubber outsole to the bottom surface of a midsole made of foam such as polyurethane. However, according to the above-described injection foaming method, since the midsole and the outsole can be manufactured integrally, the weight of the product can be reduced, the manufacturing cost can be significantly reduced, and the productivity can be significantly increased.

그런데, 사출발포물은, 단일의 캐비티내에 유동성있는 재료를 주입하고 소정의 숙성시간동안의 가교과정을 거쳐야 하기 때문에, 불가피하게 단일의 재료에 의해 성형된다. 그래서, 제품은 전체적으로 그 색상이나 밀도 등의 물성이 전체적으로 균일하게 될 수 밖에 없다는 한계를 가지고 있다. 이러한 한계에 기인하여 다양한 창작적 색상디자인이 적용될 수 없으므로, 수요자의 다양한 취향에 적절히 대응할 수 없다는 문제가 있다. 또, 사출발포물은 그 자체가 발포물이기 때문에 다른 사출물이나 고무 등에 비해 내마모성이 비교적 낮다. 이를 보완하기 위해, 사출발포물의 적어도 일부영역을 상이한 밀도나 경도를 갖도록 성형할 수 있다면 바람직할 것이다.By the way, the injection foam is inevitably molded by a single material because it must inject a flowable material into a single cavity and undergo a crosslinking process for a predetermined aging time. Therefore, the product as a whole has a limitation that the physical properties such as color and density should be uniform throughout. Due to these limitations, various creative color designs cannot be applied, and thus there is a problem in that they cannot cope with various tastes of consumers. In addition, since the injection foam is itself a foam, the wear resistance is relatively lower than that of other injection molding products or rubber. To compensate for this, it would be desirable if at least a portion of the injection foam could be molded to have a different density or hardness.

따라서, 본 발명은, 전술한 종래기술의 문제점을 고려하여 안출된 것으로, 색상이나 밀도등이 상이한 이질재료영역을 갖는 사출발포물 및 그 제조방법을 제공하는 것을 목적으로 한다.Accordingly, the present invention has been made in view of the above-described problems of the prior art, and an object thereof is to provide an injection foam having a heterogeneous material region having a different color, density, or the like and a method of manufacturing the same.

도 1은 사출발포물의 일예인 신발용 아웃솔의 사시도,1 is a perspective view of an outsole for shoes as an example of the injection foam;

도 2는 도 1의 I-I선에 따른 단면도,2 is a cross-sectional view taken along the line I-I of FIG.

도 3은 본 발명에 따른 금형의 단면도,3 is a cross-sectional view of a mold according to the present invention;

도 4는 하부다이의 평면도,4 is a plan view of the lower die;

도 5 내지 도 7은 사출발포과정을 순차적으로 나타낸 금형의 단면도이다.5 to 7 are cross-sectional views of a mold sequentially showing the injection foaming process.

* 도면의 주요부분에 대한 부호의 설명 *Explanation of symbols on the main parts of the drawings

1 : 아웃솔 2 : 주재료영역1: Outsole 2: Main material area

3 : 제 1부재료영역 4 : 제 2부재료영역3: first submaterial region 4: second submaterial region

5 : 임계영역 10 : 금형5: critical area 10: mold

12 : 하부다이 13 : 캐비티12: lower die 13: cavity

14 : 상부다이 15 : 제 1부재료캐비티영역14: upper die 15: first sub-material cavity area

16 : 제 1격리리브 17 : 제 2부재료캐비티영역16: first isolation rib 17: second secondary material cavity area

18 : 제 2격리리브 20 : 주재료주입구18: 2nd isolation rib 20: main material inlet

21 : 주재료런너21: main material runner

상기 목적은, 본 발명에 따라, 수지재료와 발포제를 함유한 주발포재료를 마련하는 단계와, 상기 주발포재료와 가교반응가능한 수지재료를 포함하며 상기 주발포재료와 상이한 물성을 갖는 부재료삽입물을 성형하는 단계와, 발포성형용 금형의 캐비티내에 소정의 부재료캐비티영역을 형성하는 단계와, 상기 부재료캐비티영역내에 상기 부재료삽입물을 삽입하는 단계와, 상기 캐비티내에 액상의 주발포재료를 충전하는 단계와, 소정의 반응온도로 소정의 숙성시간동안 유지한 다음 상기 금형을 개방하여 발포시키는 단계를 포함하는 이질재료영역을 갖는 사출발포물의 제조방법에 의해 달성된다.The object of the present invention is to provide a main foam material containing a resin material and a blowing agent, and a material insert including a resin material capable of crosslinking reaction with the main foam material and having different physical properties from the main foam material. Molding, forming a predetermined material cavity area in the cavity of the foam molding die, inserting the material insert into the material cavity area, filling a liquid main foam material into the cavity; It is achieved by a method for producing an injection foam having a heterogeneous material region, which comprises maintaining at a predetermined reaction temperature for a predetermined aging time and then opening and foaming the mold.

여기서, 상기 주발포재료와 상기 부재료삽입물은 상호 가교반응성을 높이기 위해 동일한 수지재료 예를 들어 EVA를 주성분으로 하는 것이 바람직하며, 다만 그 색상과 발포밀도중 적어도 어느 하나를 상이하게 함으로써 이질재료로 구성할 수 있다.Here, the main foaming material and the subsidiary material insert are preferably made of the same resin material, for example, EVA in order to increase mutual crosslinking reactivity, but consist of heterogeneous materials by differentiating at least one of the color and the foam density. can do.

바람직한 실시예에서는, 부재료삽입물에 발포제를 함유시키고 그 발포제의 발포온도이하에서 성형하여 삽입함으로써, 주재료와 부재료가 일체로 발포되도록 할 수 있다.In a preferred embodiment, the main material and the subsidiary material can be integrally foamed by containing the blowing agent in the submaterial insert and molding and inserting it below the foaming temperature of the blowing agent.

한편, 본 발명의 다른 분야에 따르면, 전술한 제조방법에 의해 성형된 이질재료영역을 갖는 사출발포물이 제공된다.On the other hand, according to another field of the present invention, an injection foam having a heterogeneous material region molded by the above-described manufacturing method is provided.

이하에서 첨부도면을 참조하여 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

도 1은 이질영역을 갖는 사출발포물의 일예인 신발용 아웃솔의 사시도이고, 도 2는 도 1의 I-I선에 따른 단면도이다. 이들 도면에서 볼 수 있는 바와 같이, 아웃솔(1)은, 전체적으로 신발 특히 스포츠화의 밑창형태를 가지며, 종래 스포츠화에 있어서 상호 분리되어 있었던 발포물인 미드솔과 고무제인 아웃솔이 일체화되어 있는 형상을 가진다.1 is a perspective view of an outsole for shoes that is an example of an injection foam having a heterogeneous region, Figure 2 is a cross-sectional view taken along the line I-I of FIG. As can be seen from these figures, the outsole 1 has the shape of soles of shoes, in particular, sports shoes as a whole, and has a shape in which the midsole, which is a foam that has been separated from the conventional sports shoes, and the outsole made of rubber are integrated.

아웃솔(1)은, 거의 대부분의 영역을 점하는 주재료영역(2)과, 바닥면의 일부영역에 형성되어 있는 제 1부재료영역(3) 및 제 2부재료영역(4)을 가진다. 주재료영역(2)과 부재료영역(3, 4)의 수지재료로서는 각 영역의 수지재료가 상호 접촉하여 소정의 조건에서 반응할 때 상호 가교반응이 가능한 것으로 선택되며, 이들은 서로 동일한 것이 바람직하다. 주재료영역(2)와 부재료영역(3, 4)의 발포용 수지재료로서는, 폴리우레탄, 폴리스틸렌, EVA(Ethyl Vinyl Acetate), PVC, TPR(Thermoplastic Rubber) 등을 사용할 수 있으며, 가장 바람직한 것은 EVA이다.The outsole 1 has a main material region 2 covering almost most of the region, and a first submaterial region 3 and a second submaterial region 4 formed in a partial region of the bottom surface. The resin material of the main material region 2 and the submaterial regions 3 and 4 is selected to be capable of mutual crosslinking reaction when the resin materials in each region contact each other and react under predetermined conditions, and these are preferably the same as each other. Polyurethane, polystyrene, EVA (Ethyl Vinyl Acetate), PVC, TPR (Thermoplastic Rubber), and the like may be used as the foaming resin material for the main material region 2 and the subsidiary material regions 3 and 4, and EVA is most preferred. .

부재료영역(3, 4)은 발포금형내에 미리 성형되어 있는 고형체의 형태로 삽입되며, 주재료영역(2)은 유동성있는 액상상태로 충전되어, 소정의 온도조건에서 상당시간 숙성된 다음 함께 발포된다. 주재료영역(2)과 부재료영역(3, 4)은 상호 인접한 접경부인 임계영역(5)에서, 발포를 위한 소정의 온도조건하에서의 숙성될 때 상호 가교반응하여 일체로 결합된다.Subsidiary material regions 3 and 4 are inserted in the form of solids that have been preformed in the foam mold, and the main material region 2 is filled in a fluid liquid state and aged together for a predetermined time under predetermined temperature conditions and then foamed together. . The main material region 2 and the submaterial regions 3 and 4 are integrally joined by crosslinking reaction when aged under a predetermined temperature condition for foaming in the critical region 5, which is a border portion adjacent to each other.

주재료영역(2)과 부재료영역(3, 4)는, 해당 수지재료에 배합되는 발포제나 첨가제의 함량이나 종류를 달리 함으로써 완성제품에서의 발포밀도, 경도, 탄성도 혹은 색상이 상호 상이하도록 구성될 수 있다. 이에 의해, 내마모성이 요구되는 부분에 발포밀도나 경도가 높은 물성을 가진 부재료영역(3, 4)을 형성할 수 있으며, 경우에 따라서는 다양한 색상디자인의 적용 예를 들면 컬러심볼마크등의 형성이 가능하도록 상이한 색상을 갖는 부재료영역들을 형성하여 투톤컬러 혹은 다중톤컬러의 제품을 얻을 수 있다.The main material region 2 and the subsidiary material regions 3 and 4 may be configured so that the foam density, hardness, elasticity or color of the finished product is different by varying the content or type of blowing agent or additive blended with the resin material. Can be. As a result, it is possible to form submaterial areas 3 and 4 having high foaming density and high hardness in areas where wear resistance is required. In some cases, application of various color designs, for example, formation of color symbol marks, etc. It is possible to form subtone areas having different colors to obtain a two-tone color or a multitone color product.

도 3은 이러한 부재료영역을 갖는 아웃솔의 성형을 위한 금형의 단면도이다. 본 도면에서는 설명 및 도시의 편리를 위해 금형(10)내의 캐비티(13)가 도 1의 제품과는 다소 상이하게 간략화되어 있다.3 is a cross-sectional view of a mold for forming an outsole having such a material region. In this figure, the cavity 13 in the mold 10 is simplified somewhat differently from the product of FIG. 1 for convenience of explanation and illustration.

금형(10)는, 상면에 캐비티(13)가 형성되어 있는 하부다이(12), 및 캐비티(13)의 상부를 밀폐하는 상부다이(14)을 가진다. 이들 다이(12, 14)들은 도시않은 구동수단에 의해 상하방향으로 상대이동하여 상호 접촉 및 분리되며, 이에 의해 캐비티(13)를 폐쇄 및 개방한다.The metal mold | die 10 has the lower die 12 in which the cavity 13 is formed in the upper surface, and the upper die 14 which seals the upper part of the cavity 13. As shown in FIG. These dies 12 and 14 are moved relative to each other in a vertical direction by a driving means (not shown) to be in contact with and separated from each other, thereby closing and opening the cavity 13.

도 4는 하부다이(12)의 평면도로서, 도 3과 함께 참조하면, 하부다이(12)의 캐비티(13)내에는 아웃솔(1)의 부재료영역(3, 4)을 형성하기 위한 제 1부재료캐비티영역(15)과 제 2부재료캐비티영역(17)이 마련되어 있다. 이들 부재료캐비티영역(15, 17)은 캐비티(13)의 저면으로부터 소정 높이 돌출되도록 형성된 격리리브(16, 18)에 의해 나머지 주재료캐비티영역과 구획된다. 하부다이(12)에는 또한, 주재료주입구(20)로부터 이어지는 주재료런너(21)가 마련되어 있으며, 상부다이(14)에 형성된 연통로를 통해 캐비티(13)내부로 연결된다. 이에 의해 주재료주입구(20)로부터 공급되는 주발포재료는 주재료런너(21)를 통해 캐비티(13)에 공급되게 된다.4 is a plan view of the lower die 12. Referring to FIG. 3, the first sub-material for forming the submaterials 3 and 4 of the outsole 1 in the cavity 13 of the lower die 12 is shown. The cavity area 15 and the second sub material cavity area 17 are provided. These submaterial cavity regions 15 and 17 are partitioned from the remaining main material cavity regions by isolation ribs 16 and 18 formed to protrude a predetermined height from the bottom surface of the cavity 13. The lower die 12 is also provided with a main material runner 21 running from the main material inlet 20 and connected to the cavity 13 through a communication path formed in the upper die 14. As a result, the main foaming material supplied from the main material inlet 20 is supplied to the cavity 13 through the main material runner 21.

이하에서, 제 5도 내지 제 7도를 참조하여, 이질재료영역을 갖는 아웃솔의 제조공정을 순차적으로 설명한다.Hereinafter, referring to FIGS. 5 to 7, a manufacturing process of an outsole having a heterogeneous material region will be described in sequence.

먼저, 도 3과 같은 상태의 금형(10)에서, 도시않은 구동수단에 의해 상부다이(14)를 상승시켜 캐비티(13)를 개방하고, 개방된 캐비티(13)내의 부재료캐비티영역(15, 17)에 미리 성형되어 있는 부재료삽입물(3a, 4a)을 각각 삽입한다. 그런 다음, 상부다이(14)와 하부다이(12)를 상대이동시켜 도 5와 같이 캐비티(13)를 폐쇄한다. 캐비티(13)가 폐쇄되면, 주재료주입구(20)를 통해 주발포재료를 주입하며, 이에 의해 도 6에 도시된 바와 같이, 주발포재료가 캐비티(13)내에 충전된다.First, in the mold 10 as shown in FIG. 3, the upper die 14 is opened by the driving means (not shown) to open the cavity 13, and the material cavity regions 15 and 17 in the opened cavity 13 are first opened. ), The material inserts 3a and 4a which are previously molded are inserted. Then, the upper die 14 and the lower die 12 are moved relative to close the cavity 13 as shown in FIG. When the cavity 13 is closed, the main foaming material is injected through the main material inlet 20, whereby the main foaming material is filled in the cavity 13 as shown in FIG. 6.

여기서 주발포재료는 폴리우레탄, 폴리스틸렌, EVA, PVC, TPR 등의 수지재료를 주성분으로 하며 발포제를 함유하고, 유동가능한 액상의 상태로 캐비티(13)내에 사출주입된다. 부재료삽입물(3a, 4a)은 주발포재료와 가교반응가능한 재료 바람직하게는 동일한 수지재료를 주성분으로 하며, 사출, 압출등의 성형 방법에 의해 미리 성형된 고형체로서 부재료캐비티영역(15, 17)내에 삽입된다. 주발포재료와 부재료삽입물(3a, 4a)의 주성분을 이루는 수지재료로서는 실무에서 EVA가 가장 바람직한 것으로 확인된 바 있다. 여기서, 부재료삽입물(3a, 4a)도 발포제를 함유할 수 있다. 부재료삽입물(3a, 4a)이 발포제를 함유할 경우, 부재료삽입물(3a, 4a)은 발포제의 활성온도이하에서 성형되어 미발포상태로 캐비티(13)내에 삽입되며, 주발포재료의 발포과정에서 주발포재료와 함께 발포되게 된다. 주발포재료와 부재료삽입물(3a, 4a)은 발포제의 양이나 첨가제의 종류를 달리 하며, 이에 따라 발포성형의 완료후 상이한 밀도, 경도 혹은 색상을 나타낼 수 있다.The main foaming material is a resin material such as polyurethane, polystyrene, EVA, PVC, TPR and the like as a main component, and contains a blowing agent, and is injected into the cavity 13 in a flowable liquid state. The submaterial inserts 3a and 4a are made of a main foaming material and a material capable of crosslinking reaction, preferably the same resin material as the main component, and are preformed solids by a molding method such as injection and extrusion. Is inserted in. It has been found that EVA is most preferred in practice as the resin material constituting the main components of the main foam material and the submaterial inserts 3a and 4a. Here, the submaterial inserts 3a and 4a may also contain a blowing agent. When the submaterial inserts 3a and 4a contain a foaming agent, the submaterial inserts 3a and 4a are molded below the active temperature of the blowing agent and inserted into the cavity 13 in an unfoamed state, and the main foaming material is used in the foaming process. Foamed with the foamed material. The main foaming material and the submaterial inserts 3a and 4a vary in the amount of the blowing agent or the type of the additive, and thus may exhibit different density, hardness or color after completion of the foam molding.

도 6에서와 같이 주발포재료가 충전된 상태에서, 금형(10)은 캐비티(13)를 예를 들어 EVA의 경우 약 170 내지 190도의 온도로 약 6 내지 10분간의 숙성시간동안 유지한다. 이러한 온도조건에서의 숙성시간동안 각 발포재료는 자체적으로 활발한 가교반응을 진행하는 한편, 주발포재료와 부재료삽입물(3a, 4a)이 상호 접촉한 영역에서 부재료삽입물(3a, 4a)의 표면이 활성화되어 양 재료가 상호 가교반응하여 일체화된다.In the state in which the main foaming material is filled as shown in FIG. 6, the mold 10 maintains the cavity 13 for a aging time of about 6 to 10 minutes at a temperature of about 170 to 190 degrees, for example, in the case of EVA. During the aging time under these temperature conditions, each foam material undergoes an active crosslinking reaction on its own, while the surface of the material inserts 3a and 4a is activated in the region where the main foam material and the material inserts 3a and 4a are in contact with each other. Both materials are crosslinked with each other to be integrated.

충분한 숙성시간이 지나면, 도시않은 구동수단에 의해 상부다이(14)을 상향이동시킨다. 이때, 캐비티(13)가 개방되면서 발포가스의 팽창에 의해 캐비티(13)내에서 충분한 가교과정을 겪은 발포재료는 도 7에 도시된 바와 같이 급격히 팽창하면서 캐비티(13)로부터 이탈된다. 캐비티(13)로부터 이탈된 제품인 아웃솔(1)은 부재료삽입물(3a, 4a)에 의해 주재료영역(2)내에 섬형상으로 형성되는 부재료영역(3, 4)을 가지며, 이후의 트리밍등과 같은 후가공절차를 거쳐 완성품으로 출하되게 된다. 부재료영역(3, 4)은 부재료삽입물(3a, 4a)의 조성에 따라 주재료영역(2)과 상이한 색상이나 경도를 가진다.After sufficient maturation time has elapsed, the upper die 14 is moved upward by a driving means (not shown). At this time, the foamed material which has undergone sufficient crosslinking in the cavity 13 by expanding the foaming gas while the cavity 13 is opened is expelled from the cavity 13 while rapidly expanding as shown in FIG. 7. The outsole 1, which is a product separated from the cavity 13, has submaterial materials 3 and 4 formed in an island shape in the main material area 2 by submaterial inserts 3a and 4a, and is subsequently processed such as trimming thereafter. It will be shipped to the finished product through the procedure. The submaterial regions 3 and 4 have a different color or hardness than the main material region 2 depending on the composition of the submaterial inserts 3a and 4a.

이상 설명한 바와 같이, 단일의 금형내에서 이질영역을 갖는 아웃솔을 용이하게 제조할 수 있다. 이러한 제조방법은, 아웃솔 뿐만아니라, 다양한 형상이나 기능을 갖는 사출발포제품에 폭넓게 적용할 수 있음은 물론이다.As described above, an outsole having heterogeneous regions can be easily manufactured in a single mold. Such a manufacturing method can be widely applied not only to the outsole, but also to injection-foaming products having various shapes and functions.

이상과 같이, 본 발명에 따르면, 물성이나 형태 혹은 색상이 상이한 이질재료영역을 가지고 폭넓은 디자인의 적용이 가능한 사출발포제품을 저렴하고 용이하게 얻을 수 있다.As described above, according to the present invention, an injection-foaming product having a heterogeneous material region having different physical properties, shapes, or colors, and which can be applied to a wide range of designs, can be obtained at low cost and easily.

Claims (5)

(정정)(correction) 이질재료영역을 갖는 사출발포물의 제조방법에 있어서,In the method for producing an injection foam having a heterogeneous material region, 수지재료와 발포제를 함유한 주발포재료를 마련하는 단계와,Preparing a main foaming material containing a resin material and a blowing agent; 상기 주발포재료와 가교반응가능한 수지재료를 포함하며 상기 주발포재료와 상이한 물성을 갖는 부재료삽입물을 성형하는 단계와,Molding a material insert comprising a resin material capable of crosslinking and reacting with the main foam material and having different physical properties from the main foam material; 발포성형용 금형의 캐비티내에 소정의 부재료캐비티영역을 형성하는 단계와,Forming a predetermined material cavity area in the cavity of the foam molding die; 상기 부재료캐비티영역내에 상기 고형의 부재료삽입물을 삽입하는 단계와,Inserting the solid submaterial insert into the submaterial cavity region; 상기 캐비티내에 액상의 주발포재료를 충전하는 단계와,Filling the liquid main foam material into the cavity; 소정의 반응온도로 소정의 숙성시간동안 유지한 다음 상기 금형을 개방하여 발포시키는 단계를 포함하는 것을 특징으로 하는 이질재료영역을 갖는 사출발포물의 제조방법.A method of manufacturing an injection foam having a heterogeneous material region, the method comprising maintaining the mold at a predetermined reaction temperature for a predetermined aging time and then foaming the mold by opening the mold. 제 1항에 있어서,The method of claim 1, 상기 주발포재료와 상기 부재료삽입물은 동일한 수지재료를 주성분으로 하며, 색상과 발포밀도중 적어도 어느 하나가 상이한 것을 특징으로 하는 이질재료영역을 갖는 사출발포물의 제조방법.And the main foam material and the submaterial insert are composed of the same resin material as a main component, and at least one of a color and a foaming density is different. 제 2항에 있어서,The method of claim 2, 상기 공동의 수지재료는 EVA인 것을 특징으로 하는 이질재료영역을 갖는 사출발포물의 제조방법.And the resin material of the cavity is EVA. 제 3항에 있어서,The method of claim 3, 상기 부재료삽입물은 발포제를 함유하며, 상기 발포제의 발포온도이하에서 성형된 것을 특징으로 하는 이질재료영역을 갖는 사출발포물의 제조방법.And wherein the submaterial insert contains a blowing agent and is molded at a foaming temperature of the blowing agent at or below. 발포사출물에 있어서,In the foam injection, 제 1항 내지 제 4항중 어느 한 항에 따른 제조방법에 의해 성형된 이질재료영역을 갖는 사출발포물.An injection foam having a heterogeneous material region molded by the manufacturing method according to any one of claims 1 to 4.
KR1019970043010A 1997-08-29 1997-08-29 Injection foaming product and manufacturing method thereof KR100256180B1 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
KR1019970043010A KR100256180B1 (en) 1997-08-29 1997-08-29 Injection foaming product and manufacturing method thereof
JP09369633A JP3083800B2 (en) 1997-08-29 1997-12-29 Injection foam having foreign material region and method for producing the same
TW087104281A TW424038B (en) 1997-08-29 1998-03-23 Injection-foamed product having a different material portion and a manufacturing method thereof
DE19812694A DE19812694A1 (en) 1997-08-29 1998-03-23 Molding an injection foamed product with material sections having different properties
IDP980420A ID20771A (en) 1997-08-29 1998-03-24 DAMAGED PRODUCTS AND INSTRUCTION METHODS
IT98TO000257A ITTO980257A1 (en) 1997-08-29 1998-03-24 INJECTION EXPANDED PRODUCT AND PROCEDURE FOR ITS MANUFACTURE.
CA002233054A CA2233054A1 (en) 1997-08-29 1998-03-24 Injection-foamed product and manufacturing method thereof
CN98105889A CN1211498A (en) 1997-08-29 1998-03-26 Injection-foamed product and manufacturing method thereof
ES009800657A ES2164499B1 (en) 1997-08-29 1998-03-27 CELLULAR PRODUCT BY INJECTION AND MANUFACTURING METHOD OF THE SAME.
BR9800935-4A BR9800935A (en) 1997-08-29 1998-03-31 Foamed product by injection and manufacturing method

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KR1019970043010A KR100256180B1 (en) 1997-08-29 1997-08-29 Injection foaming product and manufacturing method thereof

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ES2361315B1 (en) * 2009-06-18 2012-04-20 Vulcanizados Argus, S.L METHOD OF MANUFACTURE OF A BASE-FLOOR ASSEMBLY FOR FOOTWEAR AND BASE-FLOOR ASSEMBLY MANUFACTURED WITH SUCH METHOD.
CN102173074B (en) * 2011-01-21 2016-06-08 许建华 A kind of production method of sole
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US10226906B2 (en) * 2014-04-14 2019-03-12 Nike, Inc. Method of manufacturing sole assembly formed of multiple preforms
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CN105291351A (en) * 2015-11-14 2016-02-03 重庆跃发日用品有限公司 Arranging structure for hard spheres, for massaging slipper sole, in manufacturing die
CN105291350A (en) * 2015-11-14 2016-02-03 重庆跃发日用品有限公司 Arranging method for arranging hard balls in protrusions of massaging slipper sole
CN105291377A (en) * 2015-11-14 2016-02-03 重庆跃发日用品有限公司 Manufacturing die of massaging slipper soles
CN110216851B (en) * 2018-03-02 2021-12-31 彰洋材料股份有限公司 Variable-pressure injection mold, injection shoe material and manufacturing method thereof
IT201900012519A1 (en) * 2019-07-22 2021-01-22 Nea Srl "Mold for the application of a leather template in the tread of an elastomeric hull of an après-ski and its manufacturing process"

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US8506860B2 (en) 2006-06-21 2013-08-13 Jang Won Park Method for manufacturing crosslinked foam
KR20160131095A (en) * 2014-04-14 2016-11-15 나이키 이노베이트 씨.브이. Sole assembly formed from multiple preforms and method and mold for manufacturing same
KR101896168B1 (en) 2014-04-14 2018-09-07 나이키 이노베이트 씨.브이. Sole assembly formed from multiple preforms and method and mold for manufacturing same
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ID20771A (en) 1999-03-04
ES2164499B1 (en) 2003-05-16
JPH1177745A (en) 1999-03-23
DE19812694A1 (en) 1999-03-04
BR9800935A (en) 2000-05-23
CA2233054A1 (en) 1999-02-28
CN1211498A (en) 1999-03-24
ES2164499A1 (en) 2002-02-16
JP3083800B2 (en) 2000-09-04
TW424038B (en) 2001-03-01
ITTO980257A1 (en) 1999-09-24
KR19990019616A (en) 1999-03-15

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