JP6267514B2 - 高性能チャンネルを有する半導体デバイス - Google Patents
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- 239000004065 semiconductor Substances 0.000 title claims description 37
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 190
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 189
- 239000000758 substrate Substances 0.000 claims description 94
- 238000009792 diffusion process Methods 0.000 claims description 79
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- 238000004519 manufacturing process Methods 0.000 claims description 42
- 229910021478 group 5 element Inorganic materials 0.000 claims description 29
- 239000002019 doping agent Substances 0.000 claims description 19
- 229910052698 phosphorus Inorganic materials 0.000 claims description 17
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 16
- 239000011574 phosphorus Substances 0.000 claims description 16
- 238000000137 annealing Methods 0.000 claims description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 239000012212 insulator Substances 0.000 claims description 7
- 229910044991 metal oxide Inorganic materials 0.000 claims description 7
- 238000005530 etching Methods 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 3
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- 229910052751 metal Inorganic materials 0.000 description 14
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- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 10
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 7
- 229920005591 polysilicon Polymers 0.000 description 7
- 229910052785 arsenic Inorganic materials 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 238000005468 ion implantation Methods 0.000 description 4
- -1 silicon carbide (SiC) metal oxide Chemical class 0.000 description 4
- 229910052787 antimony Inorganic materials 0.000 description 3
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 3
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- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- 239000003989 dielectric material Substances 0.000 description 2
- 230000005669 field effect Effects 0.000 description 2
- 238000004518 low pressure chemical vapour deposition Methods 0.000 description 2
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- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 2
- 235000012431 wafers Nutrition 0.000 description 2
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- 108090000699 N-Type Calcium Channels Proteins 0.000 description 1
- 102000004129 N-Type Calcium Channels Human genes 0.000 description 1
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- 230000015556 catabolic process Effects 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
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- 238000007796 conventional method Methods 0.000 description 1
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- 239000007789 gas Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- RLOWWWKZYUNIDI-UHFFFAOYSA-N phosphinic chloride Chemical group ClP=O RLOWWWKZYUNIDI-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
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- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/06—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
- H01L29/10—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions with semiconductor regions connected to an electrode not carrying current to be rectified, amplified or switched and such electrode being part of a semiconductor device which comprises three or more electrodes
- H01L29/107—Substrate region of field-effect devices
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/22—Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities
- H01L21/225—Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities using diffusion into or out of a solid from or into a solid phase, e.g. a doped oxide layer
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- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/12—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/16—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic Table
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- H01L29/66007—Multistep manufacturing processes
- H01L29/66053—Multistep manufacturing processes of devices having a semiconductor body comprising crystalline silicon carbide
- H01L29/66068—Multistep manufacturing processes of devices having a semiconductor body comprising crystalline silicon carbide the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
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- H01L29/66568—Lateral single gate silicon transistors
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Description
Claims (20)
- 第1導電型の炭化ケイ素(SiC)基板に半導体デバイスを作る方法であって、
第2導電型である第1ウェルを前記SiC基板内に設けるステップと、
前記第2導電型である第2ウェルを前記SiC基板内に設けるステップと、
前記SiC基板上の第1ウェルと第2ウェルとの間に、所定の厚さの絶縁層を設けるステップと、
表面拡散チャネルを形成するために、前記絶縁層を通じて前記SiC基板の表面内へと1000オングストローム未満の深さまで所定のドーパントを拡散するステップであって、前記所定のドーパントが前記絶縁層を通じて前記SiC基板の表面に拡散されるときに、前記所定のドーパントは前記SiC基板の前記第1ウェルと前記第2ウェルとの間に前記第2導電型の前記表面拡散チャンネルを形成し、前記表面拡散チャンネルを形成するために前記絶縁層を通して前記SiC基板の表面内へと前記所定のドーパントを拡散する前記ステップは、前記所定のドーパントが豊富な環境において、第1の所定の温度で、第1の所定の時間の間、前記SiC基板上に形成された前記絶縁層を含む前記SiC基板に対してアニールを行うステップを含み、
前記第1の所定の温度および前記第1の所定の時間は、前記絶縁層の所定の厚さに従って制御されて、前記所定のドーパントが前記SiC基板の表面内へ望ましい深さおよび望ましいドーピング濃度で拡散するようにされ、前記望ましい深さおよび前記望ましいドーピング濃度は、前記半導体デバイスが、常時オフの挙動を維持しつつも、前記表面拡散チャンネルの無い半導体デバイスよりもキャリアの移動度を増加させる、ステップと、
を含む、方法。 - 請求項1に記載の方法であって、ゼロ・ボルトの制御電圧が前記半導体デバイスの制御接点へ印加されたときに伝導される電流を前記半導体デバイスの定格電流の1/10000以下とすることにより、前記半導体デバイスが常時オフの挙動を示す、方法。
- 請求項1に記載の方法であって、前記表面拡散チャンネルを形成するために前記絶縁層を通して前記SiC基板の表面内へと前記所定のドーパントを拡散する前記ステップは、
前記SiC基板上に形成された前記絶縁層を含む前記SiC基板を、前記所定のドーパントが豊富な前記環境から取り出すステップと、
前記第1の所定の温度よりも高い第2の所定の温度で、第2の所定の時間の間、前記SiC基板上に形成された前記絶縁層を含む前記SiC基板に対してアニールを行うステップと
をさらに備える、方法。 - 請求項1に記載の方法であって、前記半導体デバイスはnチャンネル半導体デバイスであり、前記表面拡散チャンネルを形成するために前記SiC基板の表面内へと拡散される前記所定のドーパントはV族元素である、方法。
- 請求項1に記載の方法であって、前記所定のドーパントはリンである、方法。
- 請求項5に記載の方法であって、前記表面拡散チャンネルを形成するために前記絶縁層を通して前記SiC基板の表面内へと前記所定のドーパントを拡散する前記ステップは、リンが豊富な環境で、前記SiC基板上に形成された前記絶縁層を含む前記SiC基板に対してアニールを行うステップを含む、方法。
- 請求項6に記載の方法であって、前記リンが豊富な環境はP2O5環境である、方法。
- 請求項4に記載の方法であって、
第2のV族元素を前記絶縁層ヘ加えるステップと、
前記SiC基板の前記第1ウェルと前記第2ウェルとの間の表面に制御接点絶縁体を形成するように、前記絶縁層に対してエッチングを行うステップと
を更に含む方法。 - 請求項8に記載の方法であって、前記表面拡散チャンネルを形成するために前記SiC基板の表面内へと拡散される前記所定のドーパントはリンであり、前記第2のV族元素はリン以外のV族元素である、方法。
- 請求項9に記載の方法であって、前記第2のV族元素は窒素であり、第2のV族元素を前記絶縁層ヘ加える前記ステップは、前記SiC基板の表面に形成された前記絶縁層を含む前記SiC基板に対して、窒素の豊富な環境でアニールを行うステップを含む、方法。
- 請求項4に記載の方法であって、
前記表面拡散チャンネルを形成するために前記絶縁層を通して前記SiC基板の表面内へと前記所定のドーパントを拡散した後に、前記絶縁層を取り除くステップと、
前記SiC基板の表面に新たな絶縁層を設けるステップと、
前記SiC基板の前記第1ウェルと前記第2ウェルとの間の表面に制御接点絶縁体を形成するように、前記新たな絶縁層に対してエッチングを行うステップとを含む、方法。 - 請求項11に記載の方法であって、前記所定のドーパントはリンである、方法。
- 請求項4に記載の方法であって、
前記表面拡散チャンネルを形成するために前記絶縁層を通して前記SiC基板の表面内へと前記所定のドーパントを拡散した後に、前記絶縁層を取り除くステップと、
前記SiC基板の表面に新たな絶縁層を設けるステップと、
前記新たな絶縁層へ第2のV族元素を加えるステップと、
前記SiC基板の前記第1ウェルと前記第2ウェルとの間の表面に制御接点絶縁体を形成するように、前記新たな絶縁層に対してエッチングを行うステップと
を更に含む方法。 - 請求項13に記載の方法であって、前記表面拡散チャンネルを形成するために前記SiC基板の表面内へと拡散される前記所定のドーパントはリンであり、前記第2のV族元素はリン以外のV族元素である、方法。
- 請求項14に記載の方法であって、前記第2のV族元素は窒素であり、前記新たな絶縁層へ第2のV族元素を加える前記ステップは、前記SiC基板の表面に形成された前記新たな絶縁層を含む前記SiC基板に対して、窒素の豊富な環境でアニールを行うステップを含む、方法。
- 請求項1に記載の方法であって、前記表面拡散チャンネルのドースは5×1011/cm2ないし5×1013/cm2の範囲およびこの範囲を含む範囲である、方法。
- 請求項1に記載の方法であって、前記表面拡散チャンネルのドーピング濃度は少なくとも5×1017/cm3である、方法。
- 請求項1に記載の方法であって、前記半導体デバイスはnチャンネル半導体デバイスであり、前記SiC基板の表面内へ拡散される前記所定のドーパントはリンであり、
前記絶縁層の下の前記SiC基板の前記第1ウェルと前記第2ウェルとの間に前記表面拡散チャンネルを形成するために前記絶縁層を通して前記SiC基板の表面内へ前記リンを拡散させる前に、リン以外の第2のV族元素を前記絶縁層へ加えるステップ
を更に含む方法。 - 請求項18に記載の方法であって、前記第2のV族元素は窒素である、方法。
- 請求項1に記載の方法であって、前記半導体デバイスは金属酸化物半導体(MOS)デバイスである、方法。
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US13/039,441 US9478616B2 (en) | 2011-03-03 | 2011-03-03 | Semiconductor device having high performance channel |
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PCT/US2012/020494 WO2012118566A1 (en) | 2011-03-03 | 2012-01-06 | Semiconductor device having high performance channel |
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US9117817B2 (en) | 2012-09-14 | 2015-08-25 | Auburn University | Semiconductor devices including polar insulation layer capped by non-polar insulation layer |
JP5646570B2 (ja) * | 2012-09-26 | 2014-12-24 | 株式会社東芝 | 半導体装置及びその製造方法 |
US9111919B2 (en) | 2013-10-03 | 2015-08-18 | Cree, Inc. | Field effect device with enhanced gate dielectric structure |
JP6158153B2 (ja) * | 2014-09-19 | 2017-07-05 | 株式会社東芝 | 半導体装置及びその製造方法 |
US10910481B2 (en) | 2014-11-05 | 2021-02-02 | Cree, Inc. | Semiconductor device with improved insulated gate |
KR102465353B1 (ko) | 2015-12-02 | 2022-11-10 | 삼성전자주식회사 | 전계 효과 트랜지스터 및 이를 포함하는 반도체 소자 |
US10515969B2 (en) * | 2016-11-17 | 2019-12-24 | Taiwan Semiconductor Manufacturing Co., Ltd. | Semiconductor device and manufacturing method thereof |
JP7547795B2 (ja) | 2020-06-04 | 2024-09-10 | 富士電機株式会社 | 炭化珪素半導体装置および炭化珪素半導体装置の製造方法 |
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US20120223330A1 (en) | 2012-09-06 |
US9478616B2 (en) | 2016-10-25 |
TWI502741B (zh) | 2015-10-01 |
TW201238051A (en) | 2012-09-16 |
WO2012118566A1 (en) | 2012-09-07 |
JP2014510401A (ja) | 2014-04-24 |
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