JP2013100386A - 粘着剤組成物、粘着剤層、粘着剤層付偏光板および画像形成装置 - Google Patents
粘着剤組成物、粘着剤層、粘着剤層付偏光板および画像形成装置 Download PDFInfo
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- JP2013100386A JP2013100386A JP2011243549A JP2011243549A JP2013100386A JP 2013100386 A JP2013100386 A JP 2013100386A JP 2011243549 A JP2011243549 A JP 2011243549A JP 2011243549 A JP2011243549 A JP 2011243549A JP 2013100386 A JP2013100386 A JP 2013100386A
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- 229910052749 magnesium Inorganic materials 0.000 description 1
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- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
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- KBJFYLLAMSZSOG-UHFFFAOYSA-N n-(3-trimethoxysilylpropyl)aniline Chemical compound CO[Si](OC)(OC)CCCNC1=CC=CC=C1 KBJFYLLAMSZSOG-UHFFFAOYSA-N 0.000 description 1
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- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- XESFGOBWYAMCMB-UHFFFAOYSA-N potassium;bis(1,1,2,2,3,3,4,4,4-nonafluorobutylsulfonyl)azanide Chemical compound [K+].FC(F)(F)C(F)(F)C(F)(F)C(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F XESFGOBWYAMCMB-UHFFFAOYSA-N 0.000 description 1
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- AAYRWMCIKCRHIN-UHFFFAOYSA-N propane-1-sulfonic acid;prop-2-enamide Chemical compound NC(=O)C=C.CCCS(O)(=O)=O AAYRWMCIKCRHIN-UHFFFAOYSA-N 0.000 description 1
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
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- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
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- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- RKYSDIOEHLMYRS-UHFFFAOYSA-N triethoxy(hex-5-enyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCCC=C RKYSDIOEHLMYRS-UHFFFAOYSA-N 0.000 description 1
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 1
- JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
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- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
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- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/288—Compounds containing at least one heteroatom other than oxygen or nitrogen
- C08G18/289—Compounds containing at least one heteroatom other than oxygen or nitrogen containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
- C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/71—Monoisocyanates or monoisothiocyanates
- C08G18/711—Monoisocyanates or monoisothiocyanates containing oxygen in addition to isocyanate oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/062—Copolymers with monomers not covered by C09J133/06
- C09J133/066—Copolymers with monomers not covered by C09J133/06 containing -OH groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
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Abstract
【解決手段】(メタ)アクリル系ポリマー(A)、ならびにアニオン成分およびカチオン成分を有するイオン性化合物(B)を含有する粘着剤組成物であって、
前記アニオン成分が、下記一般式(1):
(CnF2n+1SO2)2N− (1)
(一般式(1)中、nは3〜10の整数)および下記一般式(2):
CF2(CmF2mSO2)2N− (2)
(一般式(2)中、mは2〜10の整数)で表される少なくとも1種のアニオン成分であることを特徴とする粘着剤組成物。
【選択図】なし
Description
前記アニオン成分が、下記一般式(1):
(CnF2n+1SO2)2N− (1)
(一般式(1)中、nは3〜10の整数)および下記一般式(2):
CF2(CmF2mSO2)2N− (2)
(一般式(2)中、mは2〜10の整数)で表される少なくとも1種のアニオン成分であることを特徴とする粘着剤組成物、に関する。
本発明においては、アニオン成分が、下記一般式(1):
(CnF2n+1SO2)2N− (1)
(一般式(1)中、nは3〜10の整数)および下記一般式(2):
CF2(CmF2mSO2)2N− (2)
(一般式(2)中、mは2〜10の整数)で表される少なくとも1種のアニオン成分である点が特徴である。
イオン性化合物(B)のカチオン成分としては、リチウム、ナトリウム、カリウムのアルカリ金属イオンが挙げられ、上記のアニオン成分と共に、イオン性化合物(B)としてのアルカリ金属塩を構成する。アルカリ金属イオンのなかでも、カリウムイオンを有するイオン性化合物(B)を含有する粘着剤組成物から形成された粘着剤層では、初期の表面抵抗値が上昇する傾向にある。その一方で、リチウムイオンを有するイオン性化合物(B)を含有する場合、粘着剤層の初期の表面抵抗値および加湿後の表面抵抗値の上昇を抑制できる。
(式中、Rは、置換基を有していてもよい、炭素数1〜20の1価の有機基であり、Mは水酸基又は加水分解性基であり、aは0〜2の整数である。但し、Rが複数存在するとき複数のRは互いに同一であっても異なっていてもよく、Mが複数存在するとき複数のMは互いに同一であっても異なっていてもよい。)で表される反応性シリル基を有する。
一般式(4):RaM3−aSi−X−Y−(AO)n−Z
(式中、Rは、置換基を有していてもよい、炭素数1〜20の1価の有機基であり、Mは水酸基又は加水分解性基であり、aは0〜2の整数である。但し、Rが複数存在するとき複数のRは互いに同一であっても異なっていてもよく、Mが複数存在するとき複数のMは互いに同一であっても異なっていてもよい。AOは、直鎖または分岐鎖の炭素数1〜10のオキシアルキレン基を示し、nは1〜1700であり、オキシアルキレン基の平均付加モル数を示す。Xは、炭素数1〜20の直鎖または分岐鎖のアルキレン基を示す。Yは、エーテル結合、エステル結合、ウレタン結合、またはカーボネート結合を示す。
Zは、水素原子、1価の炭素数1〜10の炭化水素基、
一般式(4A):−Y1−X−SiRaM3−a
(式中、R、M、X、aは、前記と同じ。Y1は単結合、−CO−結合、−CONH−結合、または−COO−結合を示す。)、または、
一般式(4B):−Q{−(OA)n−Y−X−SiRaM3−a}m
(式中、R、M、X、Y、aは、前記と同じ。OAは前記のAOに同じで、nは前記と同じ。Qは、2価以上の炭素数1〜10の炭化水素基であり、mは当該炭化水素基の価数と同じ。)で表される基である。)で表される化合物が挙げられる。
更に具体的には、次のような方法により、薄型偏光膜を製造することができる。
上記の薄型偏光膜の製造方法は、上記工程以外に、その他の工程を含み得る。その他の工程としては、例えば、不溶化工程、架橋工程、乾燥(水分率の調節)工程等が挙げられる。その他の工程は、任意の適切なタイミングで行い得る。
上記不溶化工程は、代表的には、ホウ酸水溶液にPVA系樹脂層を浸漬させることにより行う。不溶化処理を施すことにより、PVA系樹脂層に耐水性を付与することができる。当該ホウ酸水溶液の濃度は、水100重量部に対して、好ましくは1重量部〜4重量部である。不溶化浴(ホウ酸水溶液)の液温は、好ましくは20℃〜50℃である。好ましくは、不溶化工程は、積層体作製後、染色工程や水中延伸工程の前に行う。
上記架橋工程は、代表的には、ホウ酸水溶液にPVA系樹脂層を浸漬させることにより行う。架橋処理を施すことにより、PVA系樹脂層に耐水性を付与することができる。当該ホウ酸水溶液の濃度は、水100重量部に対して、好ましくは1重量部〜4重量部である。また、上記染色工程後に架橋工程を行う場合、さらに、ヨウ化物を配合することが好ましい。ヨウ化物を配合することにより、PVA系樹脂層に吸着させたヨウ素の溶出を抑制することができる。ヨウ化物の配合量は、水100重量部に対して、好ましくは1重量部〜5重量部である。ヨウ化物の具体例は、上述のとおりである。架橋浴(ホウ酸水溶液)の液温は、好ましくは20℃〜50℃である。好ましくは、架橋工程は上記第2のホウ酸水中延伸工程の前に行う。好ましい実施形態においては、染色工程、架橋工程および第2のホウ酸水中延伸工程をこの順で行う。
(メタ)アクリル系ポリマー(A)の重量平均分子量は、GPC(ゲル・パーミエーション・クロマトグラフィー)により測定した。
・分析装置:東ソー社製、HLC−8120GPC
・カラム:東ソー社製、G7000HXL+GMHXL+GMHXL
・カラムサイズ:各7.8mmφ×30cm 計90cm
・カラム温度:40℃
・流量:0.8ml/min
・注入量:100μl
・溶離液:テトラヒドロフラン
・検出器:示差屈折計(RI)
・標準試料:ポリスチレン
厚さ80μmのポリビニルアルコールフィルムを、速度比の異なるロール間において、30℃、0.3%濃度のヨウ素溶液中で1分間染色しながら、3倍まで延伸した。その後、60℃、4%濃度のホウ酸、10%濃度のヨウ化カリウムを含む水溶液中に0.5分間浸漬しながら総合延伸倍率が6倍になるように延伸した。次いで、30℃、1.5%濃度のヨウ化カリウムを含む水溶液中に10秒間浸漬することで洗浄した後、50℃で4分間乾燥を行い、厚さ20μmの偏光子を得た。当該偏光子の両面に、けん化処理した厚さ40μmのトリアセチルセルロースフィルムを、それぞれ、ポリビニルアルコール系接着剤により貼り合せて偏光板を作成した。以下、これをTAC系偏光板(1)という。
薄型偏光膜を作製するため、まず、非晶性PET基材に9μm厚のPVA層が製膜された積層体を延伸温度130℃の空中補助延伸によって延伸積層体を生成し、次に、延伸積層体を染色によって着色積層体を生成し、さらに着色積層体を延伸温度65度のホウ酸水中延伸によって総延伸倍率が5.94倍になるように非晶性PET基材と一体に延伸された4μm厚のPVA層を含む光学フィルム積層体を生成した。このような2段延伸によって非晶性PET基材に製膜されたPVA層のPVA分子が高次に配向され、染色によって吸着されたヨウ素がポリヨウ素イオン錯体として一方向に高次に配向された高機能偏光膜を構成する、厚さ4μmのPVA層を含む光学フィルム積層体を生成することができた。更に、当該光学フィルム積層体の偏光膜の表面にポリビニルアルコール系接着剤を塗布しながら、けん化処理した40μm厚のトリアセチルセルロースフィルムを貼合せたのち、非晶性PET基材を剥離した後、他の片面に厚さ33μmのノルボルネン系フィルムを、それぞれ、ポリビニルアルコール系接着剤により貼り合せて、薄型偏光膜を用いた偏光板を作製した。以下、これを薄型偏光板(2)という。
<アクリル系ポリマー(A−1)の調製>
冷却管、窒素導入管、温度計及び撹拌装置を備えた反応容器に、アクリル酸ブチル95部、アクリル酸4−ヒドロキシブチル5部、及び開始剤として、AIBNをモノマー(固形分)100部に対して1部を酢酸エチルと共に加えて窒素ガス気流下、60℃で7時間反応させた後、その反応液に酢酸エチルを加えて、重量平均分子量100万のアクリル系ポリマー(A−1)を含有する溶液を得た(固形分濃度30重量%)。
<アクリル系ポリマー(A−2)の調製>
製造例1において、モノマー混合物として、ブチルアクリレート95部、アクリル酸5部を含有するモノマー混合物を用いたこと以外は、製造例1と同様にして、重量平均分子量200万のアクリル系ポリマー(A−2)の溶液を調製した。
<アクリル系ポリマー(A−3)の調製>
製造例1において、モノマー混合物として、ブチルアクリレート90部、アクリル酸10部を含有するモノマー混合物を用いたこと以外は、製造例1と同様にして、重量平均分子量180万のアクリル系ポリマー(A−3)の溶液を調製した。
(粘着剤組成物の調製)
製造例1で得られたアクリル系ポリマー(A−1)の固形分100部あたり0.1部のトリメチロールプロパンキシリレンジイソシアネート(三井化学(株)製:タケネートD110N)と、ジベンゾイルパーオキサイド0.3部と、0.1部のγ−グリシドキシプロピルメトキシシラン(信越化学工業(株)製:KBM−403)と、シクロ−ヘキサフルオロプロパン―1、3―ビス(スルホニル)イミドリチウム(三菱マテリアル電子化成製:EF−N305)0.2部を配合して、アクリル系粘着剤溶液を得た。
前記アクリル系粘着剤溶液をシリコーン系剥離剤で処理されたポリエチレンテレフタレートフィルム(基材)の表面に、ファウンテンコータで均一に塗工し、155℃の空気循環式恒温オーブンで2分間乾燥し、基材の表面に厚さ20μmの粘着剤層を形成した。次いで、TAC系偏光板(1)に、粘着剤層を形成したセパレータを移着させ、粘着剤層付偏光板を作製した。
実施例1において、粘着剤組成物の調製にあたり、各成分の使用量を表1に示すように変えたこと、粘着剤層付偏光板の作製にあたり偏光板の種類を表1に示すように変えたこと以外は、実施例1と同様にして、粘着剤層付偏光板を作製した。
粘着剤層付偏光板のセパレータフィルムを剥がした後、粘着剤表面の表面抵抗値(Ω/□)を三菱化学アナリテック社製MCP−HT450を用いて測定した。
作製された粘着剤層付偏光板を100mm×100mmの大きさに切断し、液晶パネルに貼り付けた。このパネルを10000cdの輝度を持つバックライト上に置き、静電気発生装置であるESD(SANKI社製,ESD−8012A)を用いて5kvの静電気を発生させることで液晶の配向乱れを起こした。その配向不良による表示不良の回復時間(秒)を、瞬間マルチ測光検出器(大塚電子社製,MCPD−3000)を用いて測定し、下記基準で評価した。
◎:表示不良が1秒未満で消失した。
○:表示不良が1秒以上10秒未満で消失した。
×:表示不良が10秒以上で消失した。
実施例、比較例で得られた粘着剤層付偏光板を60℃/95%RHの恒温恒湿機に投入し、48時間後取り出したのち、60℃で2時間乾燥したのちセパレータフィルムを剥がし、粘着剤表面の表面抵抗値を(株)三菱化学アナリテック製MCP−HT450を用いて測定した。
実施例、比較例で得られた粘着剤層付偏光板のセパレータフィルムを剥がし、無アルカリガラスに貼り合わせ、50℃、5atm、15分間のオートクレーブ処理を行った後、80℃の加熱オーブンおよび60℃/90%RHの恒温恒湿機に投入した。500h後の偏光板の剥がれの有無を確認し、全く剥がれが認められなかったものを◎、目視では確認できない程度の剥がれを○、目視で確認できる小さな剥がれを△、明らかな剥がれが認められたものを×とした。
粘着剤層付偏光板のセパレータフィルムを剥がし厚さ0.7mmの無アルカリガラス(コーニング社製,1737)にラミネーターを用いて貼着した。次いで、50℃、0.5MPaで、15分間のオートクレーブ処理を行って、上記粘着剤層付偏光板を完全に無アクリルガラスに密着させた。次いで、60℃/95%RHの恒温恒湿機に500時間投入した。投入前と投入後の偏光板の偏光度を、日本分光(株)製のV7100を用いて測定し、変化量ΔP=(投入前の偏光度)−(投入後の偏光度)、を求めた。
架橋剤(C)における、「C−1」は三井化学ポリウレタン社製のイソシアネート架橋剤(商品名「タケネートD110N」,トリメチロールプロパンキシリレンジイソシアネート)、「C−2」は(商品名「コロネート L」、日本ポリウレタン社製)、「C−3」は日本油脂社製のベンゾイルパーオキサイド(ナイパーBMT)、を示す。
シランカップリング剤(D)における「D−1」は信越化学工業社製のKBM403を示す。
ポリエーテル化合物(E)における「E−1」は、(商品名「サイリルSAT10」、カネカ社製、「E−2」は、(商品名「SIB1824.82」、GELEST社製)を示す。
Claims (16)
- (メタ)アクリル系ポリマー(A)、ならびにアニオン成分およびカチオン成分を有するイオン性化合物(B)を含有する粘着剤組成物であって、
前記アニオン成分が、下記一般式(1):
(CnF2n+1SO2)2N− (1)
(一般式(1)中、nは3〜10の整数)および下記一般式(2):
CF2(CmF2mSO2)2N− (2)
(一般式(2)中、mは2〜10の整数)で表される少なくとも1種のアニオン成分であることを特徴とする粘着剤組成物。 - 前記イオン性化合物(B)が有するカチオン成分が、アルカリ金属カチオンおよび有機カチオンの少なくとも1種である請求項1に記載の粘着剤組成物。
- 前記イオン性化合物(B)が有するカチオン成分が、リチウムカチオンである請求項1または2に記載の粘着剤組成物。
- 前記イオン性化合物(B)が有するアニオン成分が、ビス(ヘプタフルオロプロパンスルホニル)イミドアニオン、ビス(ノナフルオロブタンスルホニル)イミドアニオン、およびシクロ−ヘキサフルオロプロパン−1,3−ビス(スルホニル)イミドアニオンの少なくとも1種である請求項1〜3のいずれかに記載の粘着剤組成物。
- 前記(メタ)アクリル系ポリマー(A)100重量部に対して、前記イオン性化合物(B)を0.001〜10重量部含有する請求項1〜4のいずれかに記載の粘着剤組成物。
- 前記(メタ)アクリル系ポリマー(A)が、モノマー単位として、アルキル(メタ)アクリレートおよびカルボキシル基含有モノマーを含有する請求項1〜5のいずれかに記載の粘着剤組成物。
- さらに、架橋剤(C)を含有する請求項1〜6のいずれかに記載の粘着剤組成物。
- 前記(メタ)アクリル系ポリマー(A)100重量部に対して、前記架橋剤(C)を0.01〜20重量部含有する請求項7に記載の粘着剤組成物。
- 前記架橋剤(C)が、イソシアネート系化合物および過酸化物の少なくとも1種である請求項7または8に記載の粘着剤組成物。
- 前記(メタ)アクリル系ポリマー(A)100重量部に対して、さらに、シランカップリング剤(D)を0.001〜5重量部含有する請求項1〜9のいずれかに記載の粘着剤組成物。
- 前記(メタ)アクリル系ポリマー(A)100重量部に対して、さらにポリエーテル変性シリコーン(E)を0.001〜10重量部含有する請求項1〜10のいずれかに記載の粘着剤組成物。
- 前記(メタ)アクリル系ポリマー(A)の重量平均分子量が、50万〜300万である請求項1〜11のいずれかに記載の粘着剤組成物。
- 請求項1〜12のいずれかに記載の粘着剤組成物から形成されたものであることを特徴とする粘着剤層。
- 少なくとも偏光板と、請求項13に記載の粘着剤層とを有することを特徴とする粘着剤層付偏光板。
- 前記偏光板と前記粘着剤層との間に、易接着層を有する請求項14に記載の粘着剤層付偏光板。
- 請求項14または15に記載の粘着剤層付偏光板を少なくとも1つ用いたことを特徴とする画像表示装置。
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US14/355,236 US9676970B2 (en) | 2011-11-07 | 2012-11-02 | Adhesive agent composition, adhesive agent layer, polarizing plate provided with adhesive agent layer, and image formation device |
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JP7119972B2 (ja) | 2017-12-27 | 2022-08-17 | 三菱ケミカル株式会社 | 粘着剤組成物及びそれを用いてなる粘着剤、偏光板用粘着剤、ならびに画像表示装置 |
JP2020100841A (ja) * | 2020-03-12 | 2020-07-02 | 藤森工業株式会社 | 粘着剤組成物、及び表面保護フィルム |
WO2023190078A1 (ja) * | 2022-03-29 | 2023-10-05 | 日東電工株式会社 | 光学用粘着シート |
WO2023190079A1 (ja) * | 2022-03-29 | 2023-10-05 | 日東電工株式会社 | 光学用粘着シート |
JP7586970B2 (ja) | 2023-07-05 | 2024-11-19 | Zacros株式会社 | 粘着フィルム、及び表面保護フィルム |
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KR20140089507A (ko) | 2014-07-15 |
US9676970B2 (en) | 2017-06-13 |
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TW201335303A (zh) | 2013-09-01 |
TWI563044B (ja) | 2016-12-21 |
KR102353402B1 (ko) | 2022-01-19 |
US20140308514A1 (en) | 2014-10-16 |
WO2013069576A1 (ja) | 2013-05-16 |
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KR20200010570A (ko) | 2020-01-30 |
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