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IT1256259B - Composti mettallocenici aventi leganti di tipo fluorenilico - Google Patents

Composti mettallocenici aventi leganti di tipo fluorenilico

Info

Publication number
IT1256259B
IT1256259B ITMI922988A ITMI922988A IT1256259B IT 1256259 B IT1256259 B IT 1256259B IT MI922988 A ITMI922988 A IT MI922988A IT MI922988 A ITMI922988 A IT MI922988A IT 1256259 B IT1256259 B IT 1256259B
Authority
IT
Italy
Prior art keywords
mettallocenic
fluorenylic
binders
compounds
alchylic
Prior art date
Application number
ITMI922988A
Other languages
English (en)
Inventor
Luigi Resconi
Original Assignee
Montecatini Tecnologie Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montecatini Tecnologie Srl filed Critical Montecatini Tecnologie Srl
Publication of ITMI922988A0 publication Critical patent/ITMI922988A0/it
Priority to ITMI922988A priority Critical patent/IT1256259B/it
Priority to EP93120798A priority patent/EP0604908B1/en
Priority to DE69330780T priority patent/DE69330780T2/de
Priority to ES93120798T priority patent/ES2162802T3/es
Priority to JP5338090A priority patent/JPH06256369A/ja
Priority to FI935913A priority patent/FI935913A/fi
Priority to RU93057745/04A priority patent/RU2169152C2/ru
Priority to KR1019930031557A priority patent/KR940014423A/ko
Priority to CA002112598A priority patent/CA2112598A1/en
Publication of ITMI922988A1 publication Critical patent/ITMI922988A1/it
Application granted granted Critical
Publication of IT1256259B publication Critical patent/IT1256259B/it

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

META I LO CERI Di FORMU I A (I):METALLOCENI DI FORMULA (I): (FORMULA I) IN CUI I SOSTITUENTI R1 SONO, AD ESEMPIO, ATOMI DI IDROGENO O GRUPPI ALCHILICI, M E' Ti, Zr O Hf, I SOSTITUENTI R2 SONO, AD ESEMPIO, ALOGENI O GRUPPI ALCHILICI, IL GRUPPO R3 E', AD ESEMPIO, UN RADICALE DIALCHILSILANDILICO, SONO UTILI QUALI COMPONENTI CATALITICI PER LA POLIMERIZZAZIONE DI OLEFINE.
ITMI922988A 1992-12-30 1992-12-30 Composti mettallocenici aventi leganti di tipo fluorenilico IT1256259B (it)

Priority Applications (9)

Application Number Priority Date Filing Date Title
ITMI922988A IT1256259B (it) 1992-12-30 1992-12-30 Composti mettallocenici aventi leganti di tipo fluorenilico
EP93120798A EP0604908B1 (en) 1992-12-30 1993-12-23 Process for the polymerisation of alpha-olefins using metallocene compounds having ligands of fluorenylic type
DE69330780T DE69330780T2 (de) 1992-12-30 1993-12-23 Verfahren zur Polymerisierung von Alpha-Olefinen mittels Metalloceneverbindungen mit Liganden des Typs Fluorenyl
ES93120798T ES2162802T3 (es) 1992-12-30 1993-12-23 Procedimiento para la polimerizacion de alfa-olefinas utilizando compuestos de metaloceno que tienen ligandos de tipo fluorenilico.
JP5338090A JPH06256369A (ja) 1992-12-30 1993-12-28 フルオレンタイプのリガンドを有するメタロセン化合物
FI935913A FI935913A (fi) 1992-12-30 1993-12-29 Metalloseeniyhdisteitä, joissa on fluorenyylityyppisiä lignandeja
RU93057745/04A RU2169152C2 (ru) 1992-12-30 1993-12-29 Металлоцены с лигандами флуоренильного типа, способ их получения, промежуточное соединение для их получения, катализатор полимеризации олефинов, содержащий эти металлоцены, способ полимеризации олефинов
KR1019930031557A KR940014423A (ko) 1992-12-30 1993-12-30 플루오레닐형 리간드를 갖는 메탈로센 화합물
CA002112598A CA2112598A1 (en) 1992-12-30 1993-12-30 Metallocene compounds having ligands of fluorenylic type

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI922988A IT1256259B (it) 1992-12-30 1992-12-30 Composti mettallocenici aventi leganti di tipo fluorenilico

Publications (3)

Publication Number Publication Date
ITMI922988A0 ITMI922988A0 (it) 1992-12-30
ITMI922988A1 ITMI922988A1 (it) 1994-06-30
IT1256259B true IT1256259B (it) 1995-11-29

Family

ID=11364558

Family Applications (1)

Application Number Title Priority Date Filing Date
ITMI922988A IT1256259B (it) 1992-12-30 1992-12-30 Composti mettallocenici aventi leganti di tipo fluorenilico

Country Status (9)

Country Link
EP (1) EP0604908B1 (it)
JP (1) JPH06256369A (it)
KR (1) KR940014423A (it)
CA (1) CA2112598A1 (it)
DE (1) DE69330780T2 (it)
ES (1) ES2162802T3 (it)
FI (1) FI935913A (it)
IT (1) IT1256259B (it)
RU (1) RU2169152C2 (it)

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US5504169A (en) * 1989-09-13 1996-04-02 Exxon Chemical Patents Inc. Process for producing amorphous poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5466766A (en) * 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
US5571880A (en) * 1991-05-09 1996-11-05 Phillips Petroleum Company Organometallic fluorenyl compounds and use thereof in an alpha-olefin polymerization process
US5631335A (en) * 1991-05-09 1997-05-20 Phillips Petroleum Company Process of polymerizing olefins using diphenylsilyl or dimethyl tin bridged 1-methyl fluorenyl metallocenes
US5710224A (en) * 1991-07-23 1998-01-20 Phillips Petroleum Company Method for producing polymer of ethylene
IT1273420B (it) * 1994-04-06 1997-07-08 Spherilene Srl Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
IT1273662B (it) * 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propiline'
US5770755A (en) * 1994-11-15 1998-06-23 Phillips Petroleum Company Process to prepare polymeric metallocenes
WO1996019488A1 (en) * 1994-12-21 1996-06-27 Exxon Chemical Patents Inc. A method of preparing high purity racemic metallocene alkyls and use thereof
IT1272924B (it) * 1995-01-23 1997-07-01 Spherilene Srl Procedimento per la preparazione di composti ciclopentadienilici e composti cosi' ottenibili
IT1275856B1 (it) 1995-03-03 1997-10-24 Spherilene Srl Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione
IT1275857B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Copolimeri atattici del propilene con l'etilene
IT1275408B (it) 1995-05-30 1997-08-05 Spherilene Spa Composti metallocenici bis-indenilici pontanti procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
AT403376B (de) * 1995-07-03 1998-01-26 Danubia Petrochem Polymere Metallocene mit silylsubstituierten brücken und deren einsatz für die olefinpolymerisation
IT1282683B1 (it) * 1996-02-23 1998-03-31 Montell North America Inc Mescole di bitume e di polimeri olefinici atti alla modifica dei bitumi
US6329541B1 (en) 1997-01-08 2001-12-11 Phillips Petroleum Company Organo omega-alkenyl cyclopentacarbyl silane-bridged metallocene compounds
US5854363A (en) * 1997-01-08 1998-12-29 Phillips Petroleum Company (Omega-alkenyl) (cyclopentacarbyl) metallocene compounds
US5856547A (en) * 1997-01-08 1999-01-05 Phillips Petroleum Company Organo omega-alkenyl cyclopentacarbyl silane compounds
US6265512B1 (en) 1997-10-23 2001-07-24 3M Innovative Company Elastic polypropylenes and catalysts for their manufacture
PL334470A1 (en) 1997-11-12 2000-02-28 Montell Technology Company Bv Metalocenes and olefins polymerisation catalysts
CN1243763C (zh) * 1998-01-14 2006-03-01 蒙特尔技术有限公司 茂金属化合物的制备方法
KR19990067851A (ko) 1998-01-14 1999-08-25 고오사이 아끼오 올레핀 중합체, 올레핀 중합 촉매 및 올레핀 중합체의 제조 방법
JP4592848B2 (ja) * 1998-10-21 2010-12-08 三井化学株式会社 軟質透明性シンジオタクティックポリプロピレン組成物
CN1162454C (zh) 2000-03-22 2004-08-18 巴塞尔技术有限公司 全同立构丙烯聚合物和全同立构规整度降低的软丙烯聚合物的热塑性组合物及其制备方法
FR2813079B1 (fr) 2000-08-18 2003-07-25 Atofina Ligands avec au moins un substituant fluorosilicone pour la preparation de metallocenes
WO2003057705A1 (en) * 2002-01-08 2003-07-17 Basell Polyolefine Gmbh Preparation of silicon-bridged metallocene compounds
EP1735355B1 (en) * 2004-03-12 2010-09-29 Basell Polyolefine GmbH Process for polymerizing 1-hexene or higher alpha-olefins
US7943716B2 (en) 2004-03-12 2011-05-17 Basell Polyolefine Gmbh Process for polymerizing 1-hexene or higher alpha-olefins
EP1753792B1 (en) 2004-05-04 2009-10-14 Basell Polyolefine GmbH Process for the preparation of atactic 1-butene polymers
ATE388994T1 (de) 2004-07-22 2008-03-15 Basell Polyolefine Gmbh 1-butenpolymerzusammensetzung
WO2006008212A1 (en) 2004-07-22 2006-01-26 Basell Polyolefine Gmbh Process for producing fractionable 1-butene polymers
WO2008025710A1 (en) 2006-08-30 2008-03-06 Basell Polyolefine Gmbh 1-butene propylene copolymer compositions
WO2008025721A1 (en) 2006-08-30 2008-03-06 Basell Polyolefine Gmbh 1-butene propylene copolymer compositions
KR101154507B1 (ko) 2009-07-31 2012-06-13 주식회사 엘지화학 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하여 제조된 올레핀계 중합체
US8691916B2 (en) 2012-05-07 2014-04-08 Dow Global Technologies Llc Retortable easy opening seals for film extrusion
WO2015158790A2 (en) * 2014-04-17 2015-10-22 Borealis Ag Improved catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
KR101666170B1 (ko) 2014-06-18 2016-10-13 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 폴리올레핀의 제조방법
WO2019139355A1 (ko) * 2018-01-11 2019-07-18 주식회사 엘지화학 혼성 담지 메탈로센 촉매를 이용한 폴리올레핀의 제조방법
KR102363189B1 (ko) 2018-01-11 2022-02-15 주식회사 엘지화학 혼성 담지 메탈로센 촉매를 이용한 폴리올레핀의 제조 방법
CN113880881B (zh) * 2021-10-20 2023-11-17 中化泉州石化有限公司 一种刚性有机膦配体的合成及其在乙烯齐聚中的应用
CN115109189B (zh) * 2022-06-15 2024-01-30 宁夏清研高分子新材料有限公司 一种环烯烃共聚物材料的制备方法、催化剂体系及其应用

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JPH01249782A (ja) * 1988-03-30 1989-10-05 Mitsubishi Metal Corp 高活性触媒用有機珪素化合物のカリウム塩とその製法
US5191132A (en) * 1991-05-09 1993-03-02 Phillips Petroleum Company Cyclopentadiene type compounds and method for making
US5436305A (en) * 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
CA2067525C (en) * 1991-05-09 1998-09-15 Helmut G. Alt Organometallic fluorenyl compounds, preparation and use
NL9101502A (nl) * 1991-09-06 1993-04-01 Dsm Nv Werkwijze voor het bereiden van een gebrugde metalloceenverbinding alsmede een katalysatorcomponent en een werkwijze voor de polymerisatie van een olefinen.

Also Published As

Publication number Publication date
DE69330780D1 (de) 2001-10-25
JPH06256369A (ja) 1994-09-13
FI935913A (fi) 1994-07-01
KR940014423A (ko) 1994-07-18
ITMI922988A0 (it) 1992-12-30
RU2169152C2 (ru) 2001-06-20
ITMI922988A1 (it) 1994-06-30
EP0604908B1 (en) 2001-09-19
EP0604908A2 (en) 1994-07-06
FI935913A0 (fi) 1993-12-29
CA2112598A1 (en) 1994-07-01
DE69330780T2 (de) 2002-07-04
ES2162802T3 (es) 2002-01-16
EP0604908A3 (en) 1994-08-24

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