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IT1273420B - Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine - Google Patents

Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine

Info

Publication number
IT1273420B
IT1273420B ITMI940645A ITMI940645A IT1273420B IT 1273420 B IT1273420 B IT 1273420B IT MI940645 A ITMI940645 A IT MI940645A IT MI940645 A ITMI940645 A IT MI940645A IT 1273420 B IT1273420 B IT 1273420B
Authority
IT
Italy
Prior art keywords
olefins
catalysts
polymerization
procedure
preparation
Prior art date
Application number
ITMI940645A
Other languages
English (en)
Inventor
Edward Bishop
Robert Jones
Krishna Raman
Vu Ahn Dang
Lin-Chen Yu
Luigi Resconi
Original Assignee
Spherilene Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Spherilene Srl filed Critical Spherilene Srl
Publication of ITMI940645A0 publication Critical patent/ITMI940645A0/it
Priority to ITMI940645A priority Critical patent/IT1273420B/it
Priority to JP52605095A priority patent/JP3804969B2/ja
Priority to EP95913890A priority patent/EP0702687B1/en
Priority to ES95913890T priority patent/ES2167424T3/es
Priority to PCT/EP1995/001200 priority patent/WO1995027717A1/en
Priority to CA002164599A priority patent/CA2164599A1/en
Priority to DE69524333T priority patent/DE69524333T2/de
Priority to KR1019950705519A priority patent/KR960702842A/ko
Priority to CN95190451A priority patent/CN1128537A/zh
Priority to US08/417,735 priority patent/US6211108B1/en
Publication of ITMI940645A1 publication Critical patent/ITMI940645A1/it
Priority to FI955822A priority patent/FI955822A/fi
Application granted granted Critical
Publication of IT1273420B publication Critical patent/IT1273420B/it
Priority to US09/823,393 priority patent/US7094847B2/en
Priority to US11/478,214 priority patent/US20060252895A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/613—Unsaturated compounds containing a keto groups being part of a ring polycyclic
    • C07C49/617—Unsaturated compounds containing a keto groups being part of a ring polycyclic a keto group being part of a condensed ring system
    • C07C49/643—Unsaturated compounds containing a keto groups being part of a ring polycyclic a keto group being part of a condensed ring system having three rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
    • C07C49/665—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system
    • C07C49/675—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system having three rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/0805—Compounds with Si-C or Si-Si linkages comprising only Si, C or H atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
ITMI940645A 1994-04-06 1994-04-06 Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine IT1273420B (it)

Priority Applications (13)

Application Number Priority Date Filing Date Title
ITMI940645A IT1273420B (it) 1994-04-06 1994-04-06 Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
DE69524333T DE69524333T2 (de) 1994-04-06 1995-03-31 Metallocen verbindungen und ihre verwendung in katalysatoren für die polymerisation von olefinen
CN95190451A CN1128537A (zh) 1994-04-06 1995-03-31 金属茂化合物及其在用于烯烃聚合的催化剂中的应用
ES95913890T ES2167424T3 (es) 1994-04-06 1995-03-31 Compuestos de metaloceno y su empleo en catalizadores para la polimerizacion de olefinas.
PCT/EP1995/001200 WO1995027717A1 (en) 1994-04-06 1995-03-31 Metallocene compounds and use thereof in catalysts for the polymerization of olefins
CA002164599A CA2164599A1 (en) 1994-04-06 1995-03-31 Metallocene compounds and use thereof in catalysts for the polymerization of olefins
JP52605095A JP3804969B2 (ja) 1994-04-06 1995-03-31 メタロセン化合物及びオレフィンの重合用触媒への使用
KR1019950705519A KR960702842A (ko) 1994-04-06 1995-03-31 올레핀 중합용 메탈로센 화합물 및 그의 촉매로서의 용도(metallocene compounds and use thereof in catalysts for the polymerization of olefins)
EP95913890A EP0702687B1 (en) 1994-04-06 1995-03-31 Metallocene compounds and use thereof in catalysts for the polymerization of olefins
US08/417,735 US6211108B1 (en) 1994-04-06 1995-04-05 Metallocene compounds and use thereof in catalysts for the polymerization of olefins
FI955822A FI955822A (fi) 1994-04-06 1995-12-04 Metalloseeniyhdisteitä ja niiden käyttö katalyytteihin olefiinien polymeroinnissa
US09/823,393 US7094847B2 (en) 1994-04-06 2001-03-30 Metallocene compounds and use thereof in catalysts for the polymerization of olefins
US11/478,214 US20060252895A1 (en) 1994-04-06 2006-06-29 Metallocene compounds and use thereof in catalysts for the polymerization of olefins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI940645A IT1273420B (it) 1994-04-06 1994-04-06 Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine

Publications (3)

Publication Number Publication Date
ITMI940645A0 ITMI940645A0 (it) 1994-04-06
ITMI940645A1 ITMI940645A1 (it) 1995-10-06
IT1273420B true IT1273420B (it) 1997-07-08

Family

ID=11368482

Family Applications (1)

Application Number Title Priority Date Filing Date
ITMI940645A IT1273420B (it) 1994-04-06 1994-04-06 Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine

Country Status (11)

Country Link
US (3) US6211108B1 (it)
EP (1) EP0702687B1 (it)
JP (1) JP3804969B2 (it)
KR (1) KR960702842A (it)
CN (1) CN1128537A (it)
CA (1) CA2164599A1 (it)
DE (1) DE69524333T2 (it)
ES (1) ES2167424T3 (it)
FI (1) FI955822A (it)
IT (1) IT1273420B (it)
WO (1) WO1995027717A1 (it)

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US10882932B2 (en) 2016-10-05 2021-01-05 Exxonmobil Chemical Patents Inc. Sterically hindered metallocenes, synthesis and use
US10968290B2 (en) 2017-03-28 2021-04-06 Exxonmobil Chemical Patents Inc. Metallocene-catalyzed polyalpha-olefins
US11021553B2 (en) 2018-02-12 2021-06-01 Exxonmobil Chemical Patents Inc. Metallocene dimer selective catalysts and processes to produce poly alpha-olefin dimers
US11078308B2 (en) 2018-02-12 2021-08-03 Exxonmobil Chemical Patents Inc. Processes to produce poly alpha-olefin trimers
US11084894B2 (en) 2018-02-12 2021-08-10 Exxonmobil Chemical Patents Inc. Catalyst systems and processes for poly alpha-olefin having high vinylidene content
CN113015755B (zh) 2018-09-17 2023-09-08 埃克森美孚化学专利公司 金属茂二聚物选择性催化剂和聚α-烯烃二聚物的制备方法
CN111484573A (zh) * 2019-06-04 2020-08-04 安徽敦茂新材料科技有限公司 一种烯烃聚合催化剂的合成方法
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Also Published As

Publication number Publication date
ES2167424T3 (es) 2002-05-16
US20010012877A1 (en) 2001-08-09
US7094847B2 (en) 2006-08-22
KR960702842A (ko) 1996-05-23
US6211108B1 (en) 2001-04-03
EP0702687A1 (en) 1996-03-27
WO1995027717A1 (en) 1995-10-19
DE69524333D1 (de) 2002-01-17
FI955822A0 (fi) 1995-12-04
EP0702687B1 (en) 2001-12-05
US20060252895A1 (en) 2006-11-09
JP3804969B2 (ja) 2006-08-02
DE69524333T2 (de) 2002-08-08
FI955822A (fi) 1996-01-18
CA2164599A1 (en) 1995-10-19
CN1128537A (zh) 1996-08-07
ITMI940645A1 (it) 1995-10-06
ITMI940645A0 (it) 1994-04-06
JPH09501184A (ja) 1997-02-04

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