ES2118718T3 - Copolimeros olefinas y su produccion. - Google Patents
Copolimeros olefinas y su produccion.Info
- Publication number
- ES2118718T3 ES2118718T3 ES90900353T ES90900353T ES2118718T3 ES 2118718 T3 ES2118718 T3 ES 2118718T3 ES 90900353 T ES90900353 T ES 90900353T ES 90900353 T ES90900353 T ES 90900353T ES 2118718 T3 ES2118718 T3 ES 2118718T3
- Authority
- ES
- Spain
- Prior art keywords
- molecular weight
- production
- derived
- load
- ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/08—Butenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Insulating Materials (AREA)
Abstract
ESTA INVENCION SUMINISTRA UN COPOLIMERO DE ETILENO CON UNA ESTRECHA DISTRIBUCION DE SU PESO ATOMICO Y UN EXCELENTE FLUJO, QUE ESTA COMPUESTO DE UNIDADES ESTRUCTURALES: (A) DERIVADAS DE ETILENO Y UNIDADES ESTRUCTURALES Y (B) DERIVADAS DE UN C SUB 3 A C SUB 20 (ALFA)-OLEFINAS, TENIENDO, DICHO COPOLIMERO (A) UNA DENSIDAD DE 0,85 A 0,92 G/CM ELEVADO 3, (B) UNA VISCOSIDAD LIMITANTE [(MU)] DETERMINADA EN DECALINA A 135 DL/G, (C) UNA PROPORCION PESO-PESO MOLECULAR PROMEDIO (MW) A NUMERO-PESO MOLECULAR PROMEDIO (MN), DETERMINADO POR GPC DE 1,2 A 4, (D) UNA PROPORCION DE MFR SUB 10, BAJO UNA CARGA DE 10-KG AL MFR SUB 2 BAJO UNA CARGA DE 2,16 KG DE 8 A 50, A 190 COMPONENTE METALICO DE TRANSICION COMPUESTO DE HAFNIUM TENIENDO COMO LIGANDO UN COMPUESTO MULTIDENTADO EN EL QUE, AL MENOS, DOS GRUPOS SELECCIONADOS ENTRE GRUPOS CICLOALCADIENIL O GRUPOS SUSTITUIDOS DEL ANTERIOR ESTAN LIGADOS ENTRE SI VIA GRUPOS ALQUILENO BAJO, O PRODUCTOS TRATADOS DEL ANTERIOR. (B) COMPUESTO ORGANOMETALICO COPOLIMERO DE OLEFINA COMPUESTO OXI-ORGANOALUMINICO.
Applications Claiming Priority (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP0-328732 | 1988-12-26 | ||
JP32873188A JP2685261B2 (ja) | 1988-12-26 | 1988-12-26 | プロピレン系ランダム共重合体およびその製造方法 |
JP0-328734 | 1988-12-26 | ||
JP63328732A JP2685262B2 (ja) | 1988-12-26 | 1988-12-26 | ヒートシール剤 |
JP0-328731 | 1988-12-26 | ||
JP32873488A JP2685263B2 (ja) | 1988-12-26 | 1988-12-26 | プロピレン系ランダム共重合体およびその製造方法 |
JP1-114596 | 1989-01-24 | ||
JP1459689 | 1989-01-24 | ||
JP1-189044 | 1989-07-21 | ||
JP1189044A JP2571280B2 (ja) | 1989-01-24 | 1989-07-21 | エチレン系共重合体およびその製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2118718T3 true ES2118718T3 (es) | 1998-10-01 |
ES2118718T5 ES2118718T5 (es) | 2009-11-05 |
Family
ID=27519622
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES90900353T Expired - Lifetime ES2118718T5 (es) | 1988-12-26 | 1989-12-21 | Copolimeros de olefinas y su produccion. |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0495099B2 (es) |
AT (1) | ATE166890T1 (es) |
DE (3) | DE68928696T2 (es) |
ES (1) | ES2118718T5 (es) |
WO (1) | WO1990007526A1 (es) |
Families Citing this family (122)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8914703D0 (en) * | 1989-06-27 | 1989-08-16 | Dow Europ Sa | Bioriented film |
US5272236A (en) * | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
JP3402473B2 (ja) * | 1991-08-20 | 2003-05-06 | 日本ポリケム株式会社 | オレフィン重合用触媒 |
US5525695A (en) * | 1991-10-15 | 1996-06-11 | The Dow Chemical Company | Elastic linear interpolymers |
US5562958A (en) * | 1991-10-15 | 1996-10-08 | The Dow Chemical Company | Packaging and wrapping film |
US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
EP0538749B1 (en) * | 1991-10-21 | 1995-01-11 | Mitsubishi Petrochemical Co., Ltd. | Propylene copolymer composition |
ES2109473T3 (es) * | 1991-12-13 | 1998-01-16 | Exxon Chemical Patents Inc | Copolimeros de etileno/alfa-olefinas superiores. |
JPH05310847A (ja) * | 1992-05-08 | 1993-11-22 | Nippon Oil Co Ltd | エチレン・α−オレフィン共重合体 |
EP0597502B1 (en) | 1992-11-13 | 2005-03-16 | Cryovac, Inc. | Heat shrinkable films containing single site catalyzed copolymers |
CA2103379C (en) * | 1992-11-19 | 2000-05-23 | Toshiyuki Tsutsui | Catalyst for olefin polymerization, process for olefin polymerization using the same, ethylene/.alpha.-olefin copolymer, graft modified ethylene/.alpha.-olefin copolymer, and ethylene copolymer composition |
US6001941A (en) * | 1992-11-19 | 1999-12-14 | Mitsui Chemicals, Inc. | Ethylene α-olefin copolymer obtained by copolymerizing ethylene with an α-olefin |
US5604043A (en) * | 1993-09-20 | 1997-02-18 | W.R. Grace & Co.-Conn. | Heat shrinkable films containing single site catalyzed copolymers having long chain branching |
CA2085813C (en) * | 1992-12-18 | 2001-06-12 | Bankim B. Desai | Formulation of high abuse, high shrink barrier bags for meat packaging |
GB9226616D0 (en) * | 1992-12-21 | 1993-02-17 | Printed Forms Equip | Pressure sealing machine and method |
JP3344015B2 (ja) * | 1993-08-23 | 2002-11-11 | 住友化学工業株式会社 | エチレン−αオレフィン共重合体及び該共重合体から成形されてなる成形体 |
DE69425900T2 (de) * | 1993-10-26 | 2001-02-01 | Idemitsu Kosan Co. Ltd., Tokio/Tokyo | Verzweigtes ethylen makromonomer und daraus hergestelltes polymer |
KR100332506B1 (ko) * | 1993-11-29 | 2002-10-09 | 미쓰이 가가쿠 가부시키가이샤 | 프로필렌엘라스토머 |
EP0669348B1 (en) | 1994-02-25 | 1998-06-10 | Sumitomo Chemical Company Limited | Propylene random copolymer and film laminate thereof |
JPH10502975A (ja) * | 1994-05-24 | 1998-03-17 | エクソン・ケミカル・パテンツ・インク | 低融点プロピレンポリマーを含む繊維及び布 |
US5571619A (en) * | 1994-05-24 | 1996-11-05 | Exxon Chemical Patents, Inc. | Fibers and oriented films of polypropylene higher α-olefin copolymers |
ES2158107T3 (es) * | 1994-05-24 | 2001-09-01 | Exxonmobil Chem Patents Inc | Resina termosellable de copolimero de propileno mejorada y articulos obtenidos a partir de la misma. |
DE69511352T2 (de) * | 1994-10-03 | 2000-03-30 | Sumitomo Chemical Co., Ltd. | Verfahren zur Herstellung eines Copolymerkautschuks |
US5834077A (en) * | 1994-10-04 | 1998-11-10 | W. R. Grace & Co.-Conn. | High shrink multilayer film which maintains optics upon shrinking |
US5837335A (en) * | 1994-10-04 | 1998-11-17 | Cryovac, Inc. | High shrink multilayer film which maintains optics upon shrinking |
US6287613B1 (en) | 1994-12-12 | 2001-09-11 | Cryovac Inc | Patch bag comprising homogeneous ethylene/alpha-olefin copolymer |
IT1272923B (it) * | 1995-01-23 | 1997-07-01 | Spherilene Srl | Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
TW401445B (en) † | 1995-07-13 | 2000-08-11 | Mitsui Petrochemical Ind | Polyamide resin composition |
US5648308A (en) * | 1995-08-10 | 1997-07-15 | Albemarle Corporation | Process for upgrading metallocene catalysts |
DE19533337A1 (de) * | 1995-09-11 | 1997-03-13 | Basf Ag | Propen/But-1-en-Copolymere |
DE19533336A1 (de) * | 1995-09-11 | 1997-03-13 | Basf Ag | Verfahren zur Herstellung von Propen/But-1-en-Copolymeren |
DE69631600T2 (de) * | 1995-09-18 | 2004-12-23 | Exxonmobil Chemical Patents Inc., Baytown | Polypropylene zusammensetzung mit hohe barrierewirkung und ihre verwendung als verpackungen |
US5741563A (en) * | 1995-09-18 | 1998-04-21 | Exxon Chemical Patents Inc. | Shrink films from propylene polymers |
WO1997012919A1 (en) * | 1995-10-06 | 1997-04-10 | The Dow Chemical Company | Branched block ethylene polymers, their preparation and compositions comprising the same |
US6114477A (en) * | 1996-02-09 | 2000-09-05 | Exxon Chemical Patents Inc. | Polymerization process |
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-
1989
- 1989-12-21 AT AT90900353T patent/ATE166890T1/de not_active IP Right Cessation
- 1989-12-21 ES ES90900353T patent/ES2118718T5/es not_active Expired - Lifetime
- 1989-12-21 DE DE68928696T patent/DE68928696T2/de not_active Expired - Lifetime
- 1989-12-21 WO PCT/JP1989/001281 patent/WO1990007526A1/ja active IP Right Grant
- 1989-12-21 DE DE68929006T patent/DE68929006T2/de not_active Expired - Lifetime
- 1989-12-21 DE DE68929210T patent/DE68929210T2/de not_active Expired - Lifetime
- 1989-12-21 EP EP90900353A patent/EP0495099B2/en not_active Expired - Lifetime
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DE68929210D1 (de) | 2000-06-15 |
ES2118718T5 (es) | 2009-11-05 |
ATE166890T1 (de) | 1998-06-15 |
EP0495099A1 (en) | 1992-07-22 |
EP0495099B2 (en) | 2009-06-10 |
DE68929006T2 (de) | 1999-10-07 |
WO1990007526A1 (en) | 1990-07-12 |
DE68928696T2 (de) | 1998-12-03 |
DE68929006D1 (de) | 1999-07-01 |
DE68928696D1 (de) | 1998-07-09 |
EP0495099B1 (en) | 1998-06-03 |
DE68929210T2 (de) | 2001-01-04 |
EP0495099A4 (en) | 1993-01-13 |
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