ES2002301A6 - Procedimiento para la oxidacion electroquimica de una alquilpiridina - Google Patents
Procedimiento para la oxidacion electroquimica de una alquilpiridinaInfo
- Publication number
- ES2002301A6 ES2002301A6 ES8601756A ES8601756A ES2002301A6 ES 2002301 A6 ES2002301 A6 ES 2002301A6 ES 8601756 A ES8601756 A ES 8601756A ES 8601756 A ES8601756 A ES 8601756A ES 2002301 A6 ES2002301 A6 ES 2002301A6
- Authority
- ES
- Spain
- Prior art keywords
- anolyte
- exchange membrane
- electrochemical oxidation
- alkylpyridines
- ion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
- C07D213/803—Processes of preparation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/23—Oxidation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Pyridine Compounds (AREA)
Abstract
PROCEDIMIENTO PARA LA OXIDACION ELECTROQUIMICA DE UNA ALQUILPIRIDINA DE FORMULA EN QUE R REPRESENTA ALQUILO CON 1-6 ATOMOS DE CARBONO Y X ES 1, 2 O 3, EN UN MEDIO ACIDO, EN UN ANODO QUE CONTIENE PLOMO DE UNA PILA ELECTROLITICA CON COMPARTIMIENTOS DE ANODO Y CATODO, SEPARADOS POR UNA MEMBRANA DE INTERCAMBIO DE IONES, EN DONDE, EN CALIDAD DE MEMBRANA DE INTERCAMBIO DE IONES, SE UTILIZA UNA MEMBRANA DE INTERCAMBIO DE ANIONES Y, EN CALIDAD DE CATOLITO, SE UTILIZA UNA SOLUCION ACUOSA DEL MISMO ACIDO QUE EL UTILIZADO EN EL ANOLITO, CUYA SOLUCION ESTA DILUIDA CON RESPECTO A ESTE ANOLITO, Y, SUBSIGUIENTEMENTE, EL PRODUCTO DE REACCION SE RECUPERA A PARTIR DEL ANOLITO.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL8502485A NL8502485A (nl) | 1985-09-11 | 1985-09-11 | Werkwijze voor de elektrochemische oxidatie van alkylpyridines. |
NL8502486A NL8502486A (nl) | 1985-09-11 | 1985-09-11 | Werkwijze voor de elektrochemische oxidatie van alkylpyridines. |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2002301A6 true ES2002301A6 (es) | 1988-08-01 |
Family
ID=26646072
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES8601756A Expired ES2002301A6 (es) | 1985-09-11 | 1986-09-10 | Procedimiento para la oxidacion electroquimica de una alquilpiridina |
Country Status (4)
Country | Link |
---|---|
US (1) | US4693793A (es) |
EP (1) | EP0217439B1 (es) |
DE (1) | DE3667802D1 (es) |
ES (1) | ES2002301A6 (es) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5074974A (en) * | 1990-06-08 | 1991-12-24 | Reilly Industries, Inc. | Electrochemical synthesis and simultaneous purification process |
US5002641A (en) * | 1990-06-28 | 1991-03-26 | Reilly Industries, Inc. | Electrochemical synthesis of niacin and other N-heterocyclic compounds |
ES2066534T3 (es) * | 1991-09-19 | 1995-03-01 | Hoechst Ag | Procedimiento para la oxidacion de derivados de hidroximetilpiridina en derivados de acido piridincarboxilico. |
CN111792706A (zh) * | 2020-08-27 | 2020-10-20 | 南京师范大学 | 有阳离子交换膜的电化学氧化处理反应器及用于处理吡啶废水的方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2512483A (en) * | 1942-03-20 | 1950-06-20 | Merck & Co Inc | Electrolytic oxidation of quinoline to quinolinic acid |
US4482439A (en) * | 1984-04-05 | 1984-11-13 | Reilly Tar & Chemical Corp. | Electrochemical oxidation of pyridine bases |
-
1986
- 1986-09-08 DE DE8686201531T patent/DE3667802D1/de not_active Expired - Lifetime
- 1986-09-08 EP EP86201531A patent/EP0217439B1/en not_active Expired
- 1986-09-10 US US06/905,398 patent/US4693793A/en not_active Expired - Fee Related
- 1986-09-10 ES ES8601756A patent/ES2002301A6/es not_active Expired
Also Published As
Publication number | Publication date |
---|---|
EP0217439B1 (en) | 1989-12-27 |
DE3667802D1 (de) | 1990-02-01 |
EP0217439A1 (en) | 1987-04-08 |
US4693793A (en) | 1987-09-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 20000208 |