ES2058888T3 - Procedimientos que utilizan composiciones de catalizador de fluoruro de aluminio para preparar haloetanos que contienen fluor. - Google Patents
Procedimientos que utilizan composiciones de catalizador de fluoruro de aluminio para preparar haloetanos que contienen fluor.Info
- Publication number
- ES2058888T3 ES2058888T3 ES90901439T ES90901439T ES2058888T3 ES 2058888 T3 ES2058888 T3 ES 2058888T3 ES 90901439 T ES90901439 T ES 90901439T ES 90901439 T ES90901439 T ES 90901439T ES 2058888 T3 ES2058888 T3 ES 2058888T3
- Authority
- ES
- Spain
- Prior art keywords
- aluminum fluoride
- haloethanes
- procedures
- catalyst compositions
- fluoride catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 title abstract 3
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 title abstract 2
- 239000000376 reactant Substances 0.000 abstract 2
- 229920006395 saturated elastomer Polymers 0.000 abstract 2
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 abstract 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 239000008246 gaseous mixture Substances 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
- 230000001131 transforming effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
- C07C17/358—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction by isomerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
SE REVELA UN PROCESO PARA TRANSFORMAR UN REACTANTE SATURADO (P.EJ.1,1,2TICLORO -1,2,2-TRIFLUOROETANO) EN UN PRODUCTO SATURADO (P. EJ. 1,1 DO EN CONTACTO UNA MEZCLA GASEOSA QUE CONTENGA ESTE REACTANTE CON UN CATALIZADOR DE FLUORURO DE ALUMINIO A TEMPERATURA ELEVADA, QUE ESTA CARACTERIZADO POR UTILIZAR UNA COMPOSICION CATALITICA QUE CONSISTE ESENCIALMENTE EN UN FLUORURO DE ALUMINIO PREPARADO POR LA REACCION DE HIDROXIDO DE ALUMINIO Y HF. TAMBIEN SE REVELA UN PROCESO PARA LA PRODUCCION DE 2-CLORO-1, 1, 1, 2-TETRAFLUOROETANO Y/O 1, 1, 1, 2-TETRAFLUOROETANO MEDIANTE LA HIDRODESCLORINACION DE 1, 1 -DICLORO-1, 2, 2, 2-TETRAFLUOROETANO PRODUCIDO POR ESTA TRANSFORMACION.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/291,100 US4902838A (en) | 1988-12-28 | 1988-12-28 | Isomerization of saturated fluorohydrocarbons |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2058888T3 true ES2058888T3 (es) | 1994-11-01 |
Family
ID=23118840
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES90901439T Expired - Lifetime ES2058888T3 (es) | 1988-12-28 | 1989-12-21 | Procedimientos que utilizan composiciones de catalizador de fluoruro de aluminio para preparar haloetanos que contienen fluor. |
ES90901441T Expired - Lifetime ES2057526T3 (es) | 1988-12-28 | 1989-12-21 | Catalizadores de fluoruro de aluminio y su uso en un procedimiento de clorofluoracion para la preparacion de 1,1-dicloro-1,2,2,2-tetrafluoroetano. |
ES89313599T Expired - Lifetime ES2055114T3 (es) | 1988-12-28 | 1989-12-27 | Isomerizacion de hidrocarburos fluorados saturados. |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES90901441T Expired - Lifetime ES2057526T3 (es) | 1988-12-28 | 1989-12-21 | Catalizadores de fluoruro de aluminio y su uso en un procedimiento de clorofluoracion para la preparacion de 1,1-dicloro-1,2,2,2-tetrafluoroetano. |
ES89313599T Expired - Lifetime ES2055114T3 (es) | 1988-12-28 | 1989-12-27 | Isomerizacion de hidrocarburos fluorados saturados. |
Country Status (15)
Country | Link |
---|---|
US (1) | US4902838A (es) |
EP (3) | EP0451199B1 (es) |
JP (3) | JPH04502471A (es) |
CN (1) | CN1020589C (es) |
AR (1) | AR248265A1 (es) |
AT (3) | ATE111881T1 (es) |
AU (3) | AU628912B2 (es) |
BR (3) | BR8907859A (es) |
CA (1) | CA2006212A1 (es) |
DE (3) | DE68916974T2 (es) |
ES (3) | ES2058888T3 (es) |
MX (1) | MX166485B (es) |
RU (1) | RU1811523C (es) |
WO (2) | WO1990007481A1 (es) |
ZA (1) | ZA899915B (es) |
Families Citing this family (74)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8824571D0 (en) * | 1988-10-20 | 1988-11-23 | Ici Plc | Chemical process |
US4902838A (en) * | 1988-12-28 | 1990-02-20 | E. I. Du Pont De Nemours And Company | Isomerization of saturated fluorohydrocarbons |
CA2012792A1 (en) * | 1989-06-14 | 1990-12-14 | Robert C. Zawalski | Process for preparing chlorofluorocarbons via an in situ generated activated aluminum trihalide catalyst and products resulting therefrom |
US5157171A (en) * | 1989-10-16 | 1992-10-20 | E. I. Du Pont De Nemours And Company | Process for chlorofluoropropanes |
JPH03284637A (ja) * | 1990-03-31 | 1991-12-16 | Du Pont Mitsui Fluorochem Co Ltd | ハイドロクロロフルオロカーボンの異性化方法 |
US5030372A (en) * | 1990-07-31 | 1991-07-09 | E. I. Du Pont De Nemours And Company | Catalytic equilibration to improve the relative yield of selected halocarbons |
US5250213A (en) * | 1991-05-06 | 1993-10-05 | E. I. Du Pont De Nemours And Company | 1,1,1,2,2,3,3,4,4,5,6-undecafluorohexane and use thereof in compositions and processes for cleaning |
US5243108A (en) * | 1991-06-03 | 1993-09-07 | E. I. Du Pont De Nemours And Company | Aluminum fluoride catalyst compositions and use thereof in a chlorofluorination process for preparing 1,1-dichloro-1,2,2,2-tetrafluoroethane |
US5243106A (en) * | 1991-06-03 | 1993-09-07 | E. I. Du Pont De Nemours And Company | Processes using aluminum fluoride catalyst compositions for preparing 1,1-dichloro-1,2,2,2-tetrafluoroethane |
US5268122A (en) * | 1991-08-28 | 1993-12-07 | E. I. Du Pont De Nemours And Company | Gem-dihydropolyfluoroalkanes and monohydropolyfluoroalkenes, processes for their production, and use of gem-dihydropolyfluoroalkanes in cleaning compositions |
IT1251957B (it) * | 1991-10-18 | 1995-05-27 | Ausimont Spa | Procedimento per isomerizzare 1,1,2-trifluoro-1,2-dicloroetano a 1,1,1- trifluoro-2,2,-dicloroetano |
US5345017A (en) * | 1992-12-08 | 1994-09-06 | E. I. Du Pont De Nemours And Company | Process for reducing the fluorine content of halocarbons |
US5523498A (en) * | 1992-12-08 | 1996-06-04 | E. I. Du Pont De Nemours And Company | Process for reducing the fluorine content of hydrofluorocarbons and hydrohalofluorocarbons |
US5866730A (en) * | 1993-04-02 | 1999-02-02 | E. I. Du Pont De Nemours And Company | Process for enriching 1,2-dichloro-1,1,2,2-tetrafluoroethane from a mixture of dichlorotetrafluoroethane isomers |
US5274190A (en) * | 1993-05-24 | 1993-12-28 | E. I. Du Pont De Nemours And Company | Process for the manufacture of linear hydrofluorocarbons containing end group hydrogen substituents |
US5396000A (en) * | 1993-05-24 | 1995-03-07 | E. I. Du Pont De Nemours And Company | Process for the manufacture of 1,1,1,2,3,-pentafluoropropane |
US5274189A (en) * | 1993-05-24 | 1993-12-28 | E. I. Du Pont De Nemours And Company | Process for the manufacture of linear hydrofluorocarbons containing end group hydrogen substituents |
GB9324814D0 (en) * | 1993-12-03 | 1994-01-19 | Ici Plc | Production of 1,1,1,2-tetrafluoroethane |
US5563304A (en) | 1994-05-26 | 1996-10-08 | E. I. Du Pont De Nemours And Company | Production of 1,2-dihydro and 2,2-dihydro hexafluoropropanes and azeotropes thereof with HF |
US5559069A (en) * | 1994-05-26 | 1996-09-24 | E. I. Du Pont De Nemours And Company | Catalysts for halogenated hydrocarbon processing, their precursors and their preparation and use |
US5847242A (en) * | 1995-05-19 | 1998-12-08 | E. I. Du Pont De Nemours And Company | Catalysts for halogenated hydrocarbon processing, their precursors and their preparation and use |
US5919994A (en) * | 1995-11-29 | 1999-07-06 | E. I. Du Pont De Nemours And Company | Catalytic halogenated hydrocarbon processing and ruthenium catalysts for use therein |
FR2758556B1 (fr) * | 1997-01-17 | 1999-02-19 | Atochem Elf Sa | Isomerisation d'hydrofluorocarbures |
FR2759093B1 (fr) | 1997-02-05 | 1999-03-05 | Ceca Sa | Polymethylenepolyamine dipropionamides comme inhibiteurs non ecotoxiques de la corrosion carbonique du fer |
US6365544B2 (en) | 1998-05-22 | 2002-04-02 | Conoco Inc. | Fischer-Tropsch processes and catalysts using fluorided alumina supports |
US6333294B1 (en) | 1998-05-22 | 2001-12-25 | Conoco Inc. | Fischer-tropsch processes and catalysts with promoters |
US6472574B2 (en) | 1999-12-10 | 2002-10-29 | E. I. Du Pont Nemours And Company | Production of 1,2-dihydro and 2,2-dihydro hexafluoropropanes and azeotropes thereof with HF |
US6333440B1 (en) | 2000-04-07 | 2001-12-25 | E. I. Du Pont De Nemours And Company | Process for perfluorocyclobutane purification |
US7897823B2 (en) * | 2004-10-29 | 2011-03-01 | E. I. Du Pont De Nemours And Company | Process for production of azeotrope compositions comprising hydrofluoroolefin and hydrogen fluoride and uses of said azeotrope compositions in separation processes |
US7476771B2 (en) | 2005-11-01 | 2009-01-13 | E.I. Du Pont De Nemours + Company | Azeotrope compositions comprising 2,3,3,3-tetrafluoropropene and hydrogen fluoride and uses thereof |
ES2392591T3 (es) * | 2006-03-31 | 2012-12-12 | E.I. Du Pont De Nemours And Company | Coproducción de hidrofluoroolefinas |
CN101479217B (zh) | 2006-06-27 | 2013-02-06 | 纳幕尔杜邦公司 | 四氟丙烯生产方法 |
EP2059492A1 (en) * | 2006-09-05 | 2009-05-20 | E.I. Du Pont De Nemours And Company | 1,2,3,3,3-pentafluoropropene production processes |
TW200920721A (en) * | 2007-07-13 | 2009-05-16 | Solvay Fluor Gmbh | Preparation of halogen and hydrogen containing alkenes over metal fluoride catalysts |
FR2929272B1 (fr) * | 2008-03-28 | 2010-04-09 | Arkema France | Procede pour la preparation du 2,3,3,3-tetrafluoro-1-propene |
MX355723B (es) | 2008-05-07 | 2018-04-27 | Du Pont | Composiciones que comprenden 1,1,1,2,3-pentafluoropropano o 2,3,3,3-tetrafluoropropeno. |
EP2516367B1 (en) | 2009-12-23 | 2015-10-07 | Arkema France | Catalytic gas phase fluorination of 243db to 1234yf |
CN102686543B (zh) | 2009-12-23 | 2015-04-15 | 阿克马法国公司 | 1230xa到1234yf的催化气相氟化 |
WO2011077191A1 (en) * | 2009-12-23 | 2011-06-30 | Arkema France | Catalytic gas phase fluorination of 1230xa to 1234yf |
CN102686542A (zh) | 2009-12-23 | 2012-09-19 | 阿克马法国公司 | 1233xf到1234yf的催化气相氟化 |
US9120716B2 (en) | 2010-10-22 | 2015-09-01 | Arkema France | Process for the preparation of 2,3,3,3 tetrafluoropropene |
WO2012052798A1 (en) | 2010-10-22 | 2012-04-26 | Arkema France | Process for the manufacture of 2-chloro-3,3,3-trifluropropene by gas phase fluorination of pentachloropropane |
WO2012098420A1 (en) | 2011-01-21 | 2012-07-26 | Arkema France | Process for the manufacture of 2,3,3,3- tetrafluoropropene by gas phase fluorination of pentachloropropane |
PL2665692T3 (pl) | 2011-01-21 | 2019-04-30 | Arkema France | Katalityczne fluorowanie w fazie gazowej |
JP6165061B2 (ja) | 2011-01-21 | 2017-07-19 | アルケマ フランス | 気相触媒フッ素化 |
EP3296281B1 (en) | 2011-12-14 | 2022-08-03 | Arkema France | Process for the preparation of 2,3,3,3-tetrafluoropropene |
FR2986525B1 (fr) | 2012-02-03 | 2014-02-14 | Arkema France | Procede de production de 2,3,3,3-tetrafluoropropene |
US8822739B2 (en) | 2012-03-22 | 2014-09-02 | E I Du Pont De Nemours And Company | Catalytic isomerization of 2,3,3,3-tetrafluoropropene |
CN102994052B (zh) * | 2012-11-30 | 2015-09-09 | 徐超 | 一种空调用制冷剂 |
FR3012137B1 (fr) | 2013-10-17 | 2016-09-16 | Arkema France | Procede de production de composes fluores |
FR3013606B1 (fr) * | 2013-11-28 | 2015-11-13 | Arkema France | Procede de purification d'acide chlorhydrique |
FR3023286B1 (fr) | 2014-07-02 | 2018-02-16 | Arkema France | Procede de fabrication de tetrafluoropropene |
FR3027303B1 (fr) | 2014-10-16 | 2016-10-07 | Arkema France | Compositions a base de 1,1,1,2,3-pentachloropropane |
FR3027304B1 (fr) | 2014-10-16 | 2018-02-23 | Arkema France | Compositions a base de 1,1,1,3,3-pentachloropropane |
WO2016092340A1 (en) | 2014-12-11 | 2016-06-16 | Arkema France | Process for the preparation of 1-chloro-2,2-difluoroethane |
FR3046160B1 (fr) | 2015-12-23 | 2019-12-13 | Arkema France | Procede de preparation du 2,3,3,3-tetrafluoro-1-propene et recyclage du 2-chloro-3,3,3-trifluoropropene exempt d'impuretes. |
FR3046162B1 (fr) | 2015-12-23 | 2019-12-13 | Arkema France | Procede de production et de purification du 2,3,3,3-tetrafluoro-1-propene. |
FR3046161B1 (fr) | 2015-12-23 | 2019-12-13 | Arkema France | Procede de production et de purification du 2,3,3,3-tetrafluoro-1-propene. |
FR3046165B1 (fr) | 2015-12-23 | 2019-12-13 | Arkema France | Procede de production et de purification du 2,3,3,3-tetrafluoro-1-propene |
FR3048429B1 (fr) | 2016-03-04 | 2019-09-27 | Arkema France | Composition azeotropique ou quasi-azeotropique comprenant de la trifluoropropyne |
KR20190008221A (ko) | 2016-04-13 | 2019-01-23 | 아르끄마 프랑스 | 2,3,3,3-테트라플루오로프로펜의 제조 방법 |
FR3051468B1 (fr) | 2016-05-19 | 2019-07-26 | Arkema France | Procede de fabrication de tetrafluoropropene. |
FR3051469B1 (fr) | 2016-05-19 | 2018-05-11 | Arkema France | Procede de fabrication de tetrafluoropropene. |
CN109843838A (zh) * | 2016-11-01 | 2019-06-04 | Agc株式会社 | 有机化合物的异构化方法以及有机化合物的异构体的制造方法 |
FR3064626B1 (fr) | 2017-03-28 | 2020-02-21 | Arkema France | Procede de production du 2,3,3,3-tetrafluoropropene. |
FR3064627B1 (fr) | 2017-03-28 | 2020-02-21 | Arkema France | Procede de production du 2,3,3,3-tetrafluoropropene. |
FR3064622B1 (fr) | 2017-03-28 | 2019-03-22 | Arkema France | Procede de recuperation d'acide fluorhydrique |
FR3064629B1 (fr) | 2017-03-28 | 2019-04-05 | Arkema France | Procede de production et de purification du 2,3,3,3-tetrafluoro-1-propene |
FR3064628B1 (fr) | 2017-03-28 | 2019-04-05 | Arkema France | Procede de production et de purification du 2,3,3,3-tetrafluoropropene |
FR3065726B1 (fr) | 2017-04-28 | 2019-04-19 | Arkema France | Procede de production et de purification du 2,3,3,3-tetrafluoropropene. |
FR3065725B1 (fr) | 2017-04-28 | 2020-01-24 | Arkema France | Procede de purification du 1,1,1,2,2-pentafluoropropane. |
FR3078700B1 (fr) | 2018-03-07 | 2020-07-10 | Arkema France | Procede de production du 2,3,3,3-tetrafluoropropene |
FR3078699B1 (fr) | 2018-03-07 | 2020-02-21 | Arkema France | Procede de production du 2,3,3,3-tetrafluoropropene |
FR3078698B1 (fr) | 2018-03-07 | 2020-02-21 | Arkema France | Procede de production du 2-chloro-3,3,3-trifluoropropene |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2598411A (en) * | 1948-11-23 | 1952-05-27 | Atomic Energy Commission | Rearrangement of saturated halocarbons |
US2748177A (en) * | 1951-08-03 | 1956-05-29 | Allied Chem & Dye Corp | Fluorination |
NL98595C (es) * | 1957-07-18 | |||
NL263002A (es) * | 1960-03-30 | 1900-01-01 | ||
FR1453510A (fr) * | 1965-08-13 | 1966-06-03 | Electro Chimie Soc D | Purification du dichlorotétrafluoroéthane |
DE1668346C3 (de) * | 1967-12-06 | 1973-10-25 | Kali-Chemie Ag, 3000 Hannover | Verfahren zur Herstellung von 1,1,1 Trifluortnchlorathan durch Um lagerung |
NO125478B (es) * | 1968-07-25 | 1972-09-18 | Montedison Spa | |
DK138673B (da) * | 1968-10-10 | 1978-10-16 | Montedison Spa | Katalysator til fremstilling af chlorfluorerede ethaner. |
DE2245372A1 (de) * | 1972-09-15 | 1974-03-21 | Biocontrol Arzneimittel Gmbh | Verfahren zur herstellung von monotopischen di- und trifluorpolyhalogenaethanen |
JPS53121710A (en) * | 1977-03-30 | 1978-10-24 | Daikin Ind Ltd | Preparation of isomerized chlorofluorohydrocarbon containing hydrogne |
GB1578933A (en) * | 1977-05-24 | 1980-11-12 | Ici Ltd | Manufacture of halogenated hydrocarbons |
FR2498591A1 (fr) * | 1980-12-31 | 1982-07-30 | Ugine Kuhlmann | Procede continu de preparation en phase gazeuse du trichlorotrifluorethane, du dichlorotetrafluorethane et du monochloropentafluorethane en proportions controlees |
JPH0788326B2 (ja) * | 1987-11-26 | 1995-09-27 | 旭硝子株式会社 | 1,1−ジクロロ−1,2,2,2−テトラフルオロエタンの製造方法 |
IN170774B (es) * | 1988-05-23 | 1992-05-16 | Du Pont | |
US4902838A (en) * | 1988-12-28 | 1990-02-20 | E. I. Du Pont De Nemours And Company | Isomerization of saturated fluorohydrocarbons |
-
1988
- 1988-12-28 US US07/291,100 patent/US4902838A/en not_active Expired - Fee Related
-
1989
- 1989-12-20 CA CA002006212A patent/CA2006212A1/en not_active Abandoned
- 1989-12-21 BR BR898907859A patent/BR8907859A/pt not_active Application Discontinuation
- 1989-12-21 JP JP90502247A patent/JPH04502471A/ja active Pending
- 1989-12-21 WO PCT/US1989/005732 patent/WO1990007481A1/en active IP Right Grant
- 1989-12-21 BR BR898907858A patent/BR8907858A/pt not_active Application Discontinuation
- 1989-12-21 AU AU48405/90A patent/AU628912B2/en not_active Ceased
- 1989-12-21 DE DE68916974T patent/DE68916974T2/de not_active Expired - Fee Related
- 1989-12-21 DE DE68918463T patent/DE68918463T2/de not_active Expired - Fee Related
- 1989-12-21 WO PCT/US1989/005738 patent/WO1990007482A1/en active IP Right Grant
- 1989-12-21 EP EP90901439A patent/EP0451199B1/en not_active Expired - Lifetime
- 1989-12-21 EP EP90901441A patent/EP0452363B1/en not_active Expired - Lifetime
- 1989-12-21 AT AT90901439T patent/ATE111881T1/de active
- 1989-12-21 ES ES90901439T patent/ES2058888T3/es not_active Expired - Lifetime
- 1989-12-21 AT AT90901441T patent/ATE108759T1/de not_active IP Right Cessation
- 1989-12-21 ES ES90901441T patent/ES2057526T3/es not_active Expired - Lifetime
- 1989-12-21 JP JP2501665A patent/JPH04502464A/ja active Pending
- 1989-12-21 AU AU48236/90A patent/AU634514B2/en not_active Expired - Fee Related
- 1989-12-27 RU SU894742723A patent/RU1811523C/ru active
- 1989-12-27 EP EP89313599A patent/EP0376686B1/en not_active Expired - Lifetime
- 1989-12-27 MX MX018912A patent/MX166485B/es unknown
- 1989-12-27 ZA ZA899915A patent/ZA899915B/xx unknown
- 1989-12-27 BR BR898906778A patent/BR8906778A/pt not_active Application Discontinuation
- 1989-12-27 AR AR89315830A patent/AR248265A1/es active
- 1989-12-27 ES ES89313599T patent/ES2055114T3/es not_active Expired - Lifetime
- 1989-12-27 AT AT89313599T patent/ATE89255T1/de not_active IP Right Cessation
- 1989-12-27 JP JP1345115A patent/JP2669701B2/ja not_active Expired - Lifetime
- 1989-12-27 DE DE89313599T patent/DE68906524T2/de not_active Expired - Fee Related
- 1989-12-28 AU AU47315/89A patent/AU621439B2/en not_active Ceased
- 1989-12-28 CN CN89109827A patent/CN1020589C/zh not_active Expired - Fee Related
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