EP0635071A1 - Verfahren und vorrichtung zur vermeidung von kontamination des abstichstahles durch vorlaufschlacke bei einem kippbaren konverter. - Google Patents
Verfahren und vorrichtung zur vermeidung von kontamination des abstichstahles durch vorlaufschlacke bei einem kippbaren konverter.Info
- Publication number
- EP0635071A1 EP0635071A1 EP93907776A EP93907776A EP0635071A1 EP 0635071 A1 EP0635071 A1 EP 0635071A1 EP 93907776 A EP93907776 A EP 93907776A EP 93907776 A EP93907776 A EP 93907776A EP 0635071 A1 EP0635071 A1 EP 0635071A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- plug
- converter
- tap hole
- tapping
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 19
- 239000010959 steel Substances 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims abstract description 16
- 239000002893 slag Substances 0.000 title abstract description 20
- 238000010079 rubber tapping Methods 0.000 title abstract description 19
- 230000008569 process Effects 0.000 title abstract description 6
- 238000011109 contamination Methods 0.000 title abstract description 4
- 239000011230 binding agent Substances 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 21
- 239000004033 plastic Substances 0.000 claims abstract description 9
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000007789 sealing Methods 0.000 claims description 26
- 239000004014 plasticizer Substances 0.000 claims description 17
- 239000011819 refractory material Substances 0.000 claims description 9
- 210000000078 claw Anatomy 0.000 claims description 8
- 239000004927 clay Substances 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- 239000001913 cellulose Substances 0.000 claims description 5
- 229920002678 cellulose Polymers 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- 150000004760 silicates Chemical class 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 230000007704 transition Effects 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 239000002480 mineral oil Substances 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 239000003921 oil Substances 0.000 claims description 2
- 238000007664 blowing Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000009970 fire resistant effect Effects 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000002028 premature Effects 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000010310 metallurgical process Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009993 protective function Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012384 transportation and delivery Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
- C21C5/42—Constructional features of converters
- C21C5/46—Details or accessories
- C21C5/4653—Tapholes; Opening or plugging thereof
Definitions
- the invention relates to a device for closing the tap hole of a tiltable converter with a sealing plug which consists of a heat-resistant mass, a front plate facing towards the inside of the converter, which melts when liquid steel strikes it, and a setting device via which the plug can be inserted into the tap hole and is deformable against the wall thereof.
- the invention also relates to a method for operating a converter and thereby for the uniform and slag-free discharge of the liquid steel, a plug consisting of plastic material being inserted as deep as possible into the tap hole connecting the inner wall and outer wall and being fixed there.
- tiltable converters At a suitable point in the converter wall above the bath level, tiltable converters have an outlet opening or a tap hole for transferring the liquid steel into the tap pan. For emptying, the converter is tilted into such a position that the steel flows through the tap hole into the downstream pan. Since specifically lighter slag of different viscosities always floats on the molten metal, it necessarily reaches the tap hole during the tipping process and thus more or less large amounts of feed slag into the tapping pan. For numerous subsequent metallurgical processes, the presence of slag which is rich in oxygen and often enriched with phosphorus or sulfur is a considerable disadvantage. There is therefore a requirement to transfer the converter steel into the tapping pan with as little slag as possible. As is known, this is achieved in that the tap hole of the converter is temporarily closed
- Spare sheet becomes.
- a number of systems which should only release the tap hole when the slag has been led past the tap during the tipping process.
- slide systems are known as a closure mechanism, but they cannot prevent feed slag from getting into the tapping channel because they are flush with the outer wall of the converter.
- plugs made of different materials or material combinations have previously been arranged outside in the tap hole or driven into the tap hole (AT-PS-355 070, AT-PS-257 665).
- Combinations of fibrous materials with solids, plastic clay materials, wooden plugs and pitch plugs are also known for the outer placement, and combinations of sheet metal with a refractory material coating and possibly additional clay material coating and claws for fixing in the tap hole (EP-A-0 315 311, US-A-4 877 221, WO 90/06377, US-A-4 399 986 and EP-A-0 260 735).
- the known plugs Due to the technically required conical or funnel-like shape of the tap holes and the progressive wear of the refractory materials in this area, the known plugs cause uncontrollable and consequently disadvantageous behavior due to premature failure of the protective function against preliminary slag contamination. As a result, larger quantities of preliminary slag are often transferred to the pan despite the appropriate safeguards.
- a considerable risk to the operating team is associated with the use of these sealing plugs.
- the invention is therefore based on the object of specifying an easy-to-use closure device which compensates for the changes in the tap hole and a method which reliably prevents the transfer of large amounts of converter feed slag into the pan.
- the object is achieved in that the sealing plug has a cylindrical, highly plastic core, that the cylinder cover surfaces are covered by the face plate and a base plate, that the face plate is displaceably connected to the setting device against the base plate and is formed into a funnel channel, which pierces the sealing plug or core and is shaped to receive a pulling claw acting on the end plate.
- the converter can be tilted, the end plate and also the funnel channel now melting when the molten steel is touched, and the steel can flow through the funnel channel in a precisely targeted manner into the pan. Since the remaining part of the sealing plug, with the exception of the edges, is not sintered, it is discharged or rinsed out quickly and without problems, the small amount of plug material for the further processing of the steel not being a hindrance.
- the different operating modes and operating conditions of a converter have no negative influence on the full functional and protective effect of the converter even after the sealing plug has remained in the tapping tube for several hours.
- the permanent and temporary binders contained in the refractory material of the sealing plug also prevent premature decomposition of the residual mass.
- the cap formed towards the inside of the converter is stable enough to safely guide the slag over the rack when the converter is tilted. It only breaks when the ferrostatic pressure is applied.
- An advantageously uniform mass for the sealing plug is that in which the cylindrical core consists of refractory material with a grain size of less than 3 mm, binding agent and plasticizer and plasticizer.
- the cylindrical core can consist of raw materials based on silicon, aluminum, magnesium oxide or silicate in a suitable composition. However, a mixture of is preferred as the refractory material
- plasticizer 0.5 to 3% by weight plasticizer
- This fire-resistant material has a bulk density of 0.8 to 0.9 kg / dm 3 and is therefore much lighter than conventional materials used for this purpose. It is advantageous if silicates are used as permanent binders, cellulose material as temporary binders, polyelectrolytic alcohol as plasticizers and as a liquefied fatty acid. This creates a material that ensures that the stopper is effectively fixed in the tap hole during deformation without any continuous sintering. The residual mass is protected against disintegration even when exposed to appropriate heat.
- the end plate used is made of heat-resistant material and is funnel-shaped and convex in the direction of the smaller opening, the smaller opening opening into the funnel channel.
- This funnel channel is extended through the stopper and is used to guide the setting tool for squeezing the sealing plug and to center the emerging pouring stream at the moment of tapping to avoid a shower effect on the flowing steel.
- the funnel channel can have different diameters. In the embodiment according to the invention, the diameters are 25-38 mm.
- the cross section of the funnel channel can deviate from the circular shape.
- the funnel channel is designed to merge beyond the base plate into the setting tool in order to make it easier to insert the claw.
- the invention further provides that the setting tool has an adjustable lock which specifies the thickness of the remaining plug, in order in this way to ensure the exact setting of the sealing plug in the transition zone to the converter interior.
- a method is used to operate a converter of the high * safety standard, in which the stopper is inserted into the tap hole up to the inner wall of the converter and then from the bottom side and at the same time is deformed through a center hole from the top side until it lies tight against the hole wall.
- a particularly effective method is that in which the stopper is positioned in the transition zone to the converter interior with the aid of a seating device which grips it from the underside and the top, and is placed by squeezing while keeping the center hole open.
- the stopper can be loaded evenly from both sides, so that the uniform abutment on the inner wall of the tapping tube already mentioned above is ensured.
- the plastic material of the stopper is made of 20 to 40% by weight of insulating clay silicate, 20 to 40% by weight of binder clay, 0 to 30% by weight of water, 5 to 20% by weight.
- % Mineral oil 0.1 to 3% by weight plasticizer (polyelectrolytic alcohol), 0.1 to 2% by weight plasticizer (fatty acid), 0.1 to 2% by weight temporary binder (cellulose) and 0.1 to 5% by weight of permanent binders (silicates) mixed together, formed into a cylindrical body and then pierced with the funnel channel of a funnel-shaped squeeze plate and then placed on the setting device and inserted and fixed in the tap hole becomes.
- FIG. 1 perspective side view of a
- Fig. 2 section through a converter in the tap hole with inserted plug (a seated device)
- Fig. 3 section through a converter in the tap hole with inserted and squeezed sealing plug.
- the slag feed stopper generally designated (1) in the figures, has a cylindrical shape.
- the cross section of this sealing plug (8) can deviate from the circular shape.
- the sealing plug (8) consists of a fire-resistant material and has a funnel-shaped baffle plate (2) on the inside of the converter, which has an elongated funnel channel (5) guided through the sealing plug (8).
- the refractory material of the sealing plug consists of 35% by weight of alumina silicate, 35% by weight of binder clay, 20% by weight of water, 6.5% by weight of mineral oil, 0.2% by weight of plasticizer, 0.3% by weight of plasticizer, 0.5% by weight of temporary binder and 2.5% by weight of permanent binder.
- FIG. 2 shows how the plug (8) is inserted into the tap hole (10) with the aid of the setting tool.
- the base plate (4) of the setting tool which is matched to the diameter of the tap hole (10), lies on the side (7) opposite the crushing plate or end plate (2).
- a claw (6) is guided according to FIG. 2 through the funnel channel (5) to above the funnel and initially has the task of holding the sealing plug (8) until it is finally positioned in the tap hole (10).
- the sealing plug (8) is inserted with the aid of the setting device into the tap hole (10) to such an extent that it has a squish plate surface, i.e. that is, the surface of the end plate (2) is almost flush with the inside of the converter (9).
- the pulling claw (6) is pulled onto the end plate (2) via the lever system of the setting tool, whereby pressure is exerted on the plug material, which deforms until the diameter of the tap hole (10) is completely filled.
- a crushed plug (8) in the tap hole (10) is shown.
- the thickness of the stopper bottom or remaining stopper (12) in FIG. 3 is always maintained for each tapping diameter of a converter with the aid of the setting device, so that a reproducible opening behavior is ensured.
- Stopper material not required to fill the tapping diameter is attached to the tapping wall with the help of the baffle plate or end plate (2). Fig. 3 pressed.
- the end plate (2) melts and sinters with the refractory material to form a solid cap (see FIG. 3).
- This cap keeps the blowing pressure and the occurring Vibrations and shocks stood.
- the remaining refractory, insulating material solidifies to such an extent that it remains stable in the tap hole (8). Sintering with the wall of the tap hole (8) does not take place.
- the sintered cap is so stable that, when the converter is tilted, it reliably guides the forward slag over the tap hole (8) and only breaks in under the ferrostatic pressure. Remaining plug material is discharged through the flowing steel within a few seconds.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Carbon Steel Or Casting Steel Manufacturing (AREA)
- Furnace Charging Or Discharging (AREA)
- Ceramic Products (AREA)
- Furnace Details (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Description
Claims
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19924211593 DE4211593C2 (de) | 1992-04-07 | 1992-04-07 | Vorrichtung zum Verschließen des Abstichloches eines kippbaren Konverters |
DE4211593 | 1992-04-07 | ||
DE9213704U DE9213704U1 (de) | 1992-10-10 | 1992-10-10 | Konverter mit plastischem Schlackenvorlaufstopfen |
DE9213704U | 1992-10-10 | ||
DE9215646U | 1992-11-17 | ||
DE9215646U DE9215646U1 (de) | 1992-04-07 | 1992-11-17 | Vorrichtung zur Vermeidung von Kontamination des Abstichstahles durch Vorlaufschlacke bei einem kippbaren Konverter |
PCT/DE1993/000311 WO1993020246A1 (de) | 1992-04-07 | 1993-04-01 | Verfahren und vorrichtung zur vermeidung von kontamination des abstichstahles durch vorlaufschlacke bei einem kippbaren konverter |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0635071A1 true EP0635071A1 (de) | 1995-01-25 |
EP0635071B1 EP0635071B1 (de) | 1996-02-28 |
Family
ID=27203617
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP93907776A Expired - Lifetime EP0635071B1 (de) | 1992-04-07 | 1993-04-01 | Verfahren und vorrichtung zur vermeidung von kontamination des abstichstahles durch vorlaufschlacke bei einem kippbaren konverter |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0635071B1 (de) |
JP (1) | JP3252909B2 (de) |
AT (1) | ATE134708T1 (de) |
AU (1) | AU671447B2 (de) |
BR (1) | BR9306202A (de) |
DE (1) | DE59301739D1 (de) |
ES (1) | ES2085154T3 (de) |
HU (1) | HU217016B (de) |
PL (1) | PL172861B1 (de) |
WO (1) | WO1993020246A1 (de) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008039142A1 (de) | 2008-08-21 | 2010-02-25 | Stilkerieg, Berthold, Dipl.-Ing. | Verschlussstopfen für kippbare Konverter |
DE102013002623A1 (de) | 2013-02-18 | 2014-08-21 | Veronica Stilkerieg | Stopfen für das zeitweise Verschließen des Konverterabstichloches |
DE102020102105A1 (de) | 2020-01-29 | 2021-07-29 | Veronica Stilkerieg | Verschlussstopfen für Konverterabstichlöcher |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19848004B4 (de) * | 1998-10-17 | 2006-10-12 | Stilkerieg, Berthold, Dipl.-Ing. | Vorrichtung zur Vermeidung von Kontamination des Abstichstahles durch Vorlaufschlacke bei einem kippbaren Konverter mit verbesserter Materialzusammensetzung |
DE102005015469A1 (de) * | 2005-04-04 | 2006-10-05 | Stilkerieg, Berthold, Dipl.-Ing. | Vorrichtung zum zeitweisen Verschließen des Konverterabstichloches mit verbesserten Stopfeneigenschaften |
JP4989422B2 (ja) * | 2007-10-30 | 2012-08-01 | ニコー物産株式会社 | スラグ流出防止用プラグ |
CN107324822A (zh) * | 2017-07-15 | 2017-11-07 | 山西建龙实业有限公司 | 一种钢渣与渣盆分离剂 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT257665B (de) | 1964-08-03 | 1967-10-25 | Voest Ag | Vorrichtung zum Verschließen des Abstiches bei Aufblasetiegeln oder sonstigen metallurgischen Öfen |
LU71494A1 (de) * | 1974-12-16 | 1976-11-11 | ||
DE2549728C2 (de) | 1975-11-06 | 1977-10-06 | Stahlwerke Peine-Salzgitter Ag, 3150 Peine | Vorrichtung zum Verschließen des Abstichloches eines Konverters |
US4399986A (en) | 1981-12-14 | 1983-08-23 | Collins William J | Device for plugging a taphole in a furnace |
NL8602255A (nl) | 1986-09-08 | 1988-04-05 | Hoogovens Groep Bv | Stop voor een convertertapgat. |
US4828226A (en) | 1987-10-16 | 1989-05-09 | Foseco International Limited | Tap hole plugs for metallurgical vessels |
DE8805975U1 (de) | 1988-05-05 | 1988-06-23 | Wertz, Heinz, 4000 Düsseldorf | Verschlußvorrichtung für das Abstichloch eines kippbaren Abstichkonverters |
EP0446252B1 (de) | 1988-12-01 | 1994-03-16 | Goricon Metallurgical Services Limited | Gefässe zur stahlherstellung |
US4877221A (en) | 1988-12-05 | 1989-10-31 | Tri-Star Manufacturing & Service, Inc. | Expandable tap hole plug |
-
1993
- 1993-04-01 WO PCT/DE1993/000311 patent/WO1993020246A1/de active IP Right Grant
- 1993-04-01 ES ES93907776T patent/ES2085154T3/es not_active Expired - Lifetime
- 1993-04-01 AU AU38871/93A patent/AU671447B2/en not_active Ceased
- 1993-04-01 AT AT93907776T patent/ATE134708T1/de active
- 1993-04-01 PL PL93305073A patent/PL172861B1/pl not_active IP Right Cessation
- 1993-04-01 DE DE59301739T patent/DE59301739D1/de not_active Expired - Lifetime
- 1993-04-01 JP JP50797893A patent/JP3252909B2/ja not_active Expired - Fee Related
- 1993-04-01 BR BR9306202A patent/BR9306202A/pt not_active IP Right Cessation
- 1993-04-01 EP EP93907776A patent/EP0635071B1/de not_active Expired - Lifetime
- 1993-04-01 HU HU9402881A patent/HU217016B/hu not_active IP Right Cessation
Non-Patent Citations (1)
Title |
---|
See references of WO9320246A1 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008039142A1 (de) | 2008-08-21 | 2010-02-25 | Stilkerieg, Berthold, Dipl.-Ing. | Verschlussstopfen für kippbare Konverter |
DE102013002623A1 (de) | 2013-02-18 | 2014-08-21 | Veronica Stilkerieg | Stopfen für das zeitweise Verschließen des Konverterabstichloches |
DE102020102105A1 (de) | 2020-01-29 | 2021-07-29 | Veronica Stilkerieg | Verschlussstopfen für Konverterabstichlöcher |
EP3859257A1 (de) | 2020-01-29 | 2021-08-04 | Veronica Stilkerieg | Verschlussstopfen für konverterabstichlöcher |
Also Published As
Publication number | Publication date |
---|---|
AU671447B2 (en) | 1996-08-29 |
JP3252909B2 (ja) | 2002-02-04 |
ES2085154T3 (es) | 1996-05-16 |
JPH07508070A (ja) | 1995-09-07 |
WO1993020246A1 (de) | 1993-10-14 |
ATE134708T1 (de) | 1996-03-15 |
DE59301739D1 (de) | 1996-04-04 |
HUT67839A (en) | 1995-05-29 |
AU3887193A (en) | 1993-11-08 |
BR9306202A (pt) | 1998-06-23 |
EP0635071B1 (de) | 1996-02-28 |
PL172861B1 (pl) | 1997-12-31 |
HU217016B (hu) | 1999-11-29 |
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