CN117815842B - System and method based on compressed air energy storage coupled with direct air carbon capture - Google Patents
System and method based on compressed air energy storage coupled with direct air carbon capture Download PDFInfo
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- B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
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Abstract
Description
技术领域Technical Field
本申请涉及碳回收技术领域,尤其涉及基于压缩空气储能耦合直接空气碳捕集的系统及方法。The present application relates to the field of carbon recovery technology, and in particular to a system and method based on compressed air energy storage coupled with direct air carbon capture.
背景技术Background technique
目前主要的碳捕集技术分为燃烧前捕集、富氧燃烧捕集和燃烧后捕集。燃烧前捕集是将燃料中的含碳组分转化为水煤气,进而将二氧化碳从中分离,该方式多用于整体煤气化联合循环电站;富氧燃烧捕集则是将纯氧从空气中分离并通入燃烧系统,辅以烟气循环,该技术捕集的二氧化碳纯度高,但系统总投资较高;燃烧后捕集则是从烟气中分离二氧化碳,该技术能耗较高。此外,以上几种二氧化碳捕集方式都是应对工业集中源排放二氧化碳的集中捕集技术,但实际上,全球每年约有30-50%的二氧化碳来自交通运输业、居民建筑热能、小型工厂等分布式排放源。直接空气捕集(Direct air capture,DAC)二氧化碳技术是一种重要的CCUS技术,该技术可以从环境空气中去除二氧化碳,DAC工艺一般由空气捕集模块、吸收剂或吸附剂再生模块、二氧化碳储存模块三部分组成。在空气捕集模块,大多先通过引风机等设备对空气中二氧化碳进行捕集,再通过固体吸附材料或液体吸收材料吸收二氧化碳;吸收剂或吸附剂再生模块主要通过高温脱附等方法对材料进行再生;二氧化碳储存模块主要通过压缩机将收集的二氧化碳送入储罐中贮存。At present, the main carbon capture technologies are divided into pre-combustion capture, oxygen-enriched combustion capture and post-combustion capture. Pre-combustion capture is to convert the carbon-containing components in the fuel into water gas, and then separate the carbon dioxide from it. This method is mostly used in integrated coal gasification combined cycle power plants; oxygen-enriched combustion capture is to separate pure oxygen from the air and pass it into the combustion system, assisted by flue gas circulation. The carbon dioxide captured by this technology is of high purity, but the total investment of the system is relatively high; post-combustion capture is to separate carbon dioxide from flue gas, and this technology has high energy consumption. In addition, the above carbon dioxide capture methods are all centralized capture technologies for industrial concentrated source carbon dioxide emissions, but in fact, about 30-50% of the world's carbon dioxide comes from distributed emission sources such as transportation, residential building heat, and small factories each year. Direct air capture (DAC) carbon dioxide technology is an important CCUS technology that can remove carbon dioxide from ambient air. The DAC process generally consists of three parts: air capture module, absorbent or adsorbent regeneration module, and carbon dioxide storage module. In the air capture module, carbon dioxide in the air is mostly captured first through induced draft fans and other equipment, and then absorbed by solid adsorbent materials or liquid absorption materials; the absorbent or adsorbent regeneration module mainly regenerates the material through high-temperature desorption and other methods; the carbon dioxide storage module mainly uses a compressor to send the collected carbon dioxide into a storage tank for storage.
现有的二氧化碳捕集分离方法包括溶液吸收法、固体吸附法、膜分离法等,其中吸收法应用最广,但吸收介质再生能耗较高。而吸附法由于其较好的环保性、经济性受到人们的关注。传统的二氧化碳吸附装置多采用固定床、转环或流化床形式,捕集对象多为二氧化碳浓度为10%-30%的化石燃料燃烧后气体。捕集装置的循环运行方法包括变压吸附、变温吸附、变湿吸附等。相关的技术中采用薄层移动床和球形固态胺吸附剂,其中球型固态胺吸附剂需要在其中上下转移,系统磨损较大,以及相关技术中还公开了使用3D打印技术成型的转轮为整体式结构,性能虽好,但是成本极高;此外一些方案中需要温控装置加热吸脱附床层才能使二氧化碳脱附,加热能耗大且脱附效率低,另外,加热后空气的温度较高,对温室大棚中作物的生长造成影响;以及此采用了湿法再生吸附材料,但是对于固定床形式的捕集装置的吸附材料重新吸收捕碳时,湿度较大的吸附材料对二氧化碳的捕捉效率低且存在二氧化碳气体通过吸附材料时阻力较大,进一步降低了碳捕集效率,因此如何提供一种高效率,经济运行性高且能实现连续捕集二氧化碳的直接空气碳捕集的系统是本领域技术人员亟需解决的。Existing carbon dioxide capture and separation methods include solution absorption, solid adsorption, membrane separation, etc. Among them, the absorption method is the most widely used, but the energy consumption of the absorption medium regeneration is relatively high. The adsorption method has attracted people's attention due to its better environmental protection and economy. Traditional carbon dioxide adsorption devices mostly adopt fixed bed, rotating ring or fluidized bed forms, and the capture objects are mostly fossil fuel combustion gases with a carbon dioxide concentration of 10%-30%. The cyclic operation methods of the capture device include pressure swing adsorption, temperature swing adsorption, humidity swing adsorption, etc. The related technology adopts a thin layer moving bed and a spherical solid amine adsorbent, wherein the spherical solid amine adsorbent needs to be transferred up and down therein, resulting in greater wear on the system, and the related technology also discloses that the rotor formed using 3D printing technology is an integral structure, which has good performance but extremely high cost; in addition, some schemes require a temperature control device to heat the adsorption and desorption bed layer to desorb carbon dioxide, which consumes a lot of heating energy and has low desorption efficiency. In addition, the temperature of the heated air is high, which affects the growth of crops in the greenhouse; and this adopts a wet regeneration adsorption material, but when the adsorption material of the fixed bed capture device reabsorbs carbon, the adsorption material with higher humidity has low capture efficiency of carbon dioxide and there is greater resistance when carbon dioxide gas passes through the adsorption material, further reducing the carbon capture efficiency. Therefore, how to provide a high-efficiency, economically operable direct air carbon capture system that can achieve continuous capture of carbon dioxide is an urgent problem to be solved by technical personnel in this field.
发明内容Summary of the invention
本申请旨在至少在一定程度上解决相关技术中的技术问题之一。The present application aims to solve one of the technical problems in the related art at least to some extent.
为此,本申请的目的在于提出基于压缩空气储能耦合直接空气碳捕集的系统及方法,其中利用脱附液对湿法再生吸附材料解析再生后,通过自转转轴转动脱甩湿法再生吸附材料中的脱附液,降低湿法再生吸附材料的湿度,从而在湿法再生吸附材料循环过程中提高碳捕集效率和捕碳量。同时利用压缩空气提高了单位流量中通入碳捕集组件的压缩空气气流中的二氧化碳浓度,提高了直接空气碳捕集的效率和捕碳总量,且不断地将压缩空气进行吸附,实现连续捕集压缩空气中的二氧化碳。To this end, the purpose of this application is to propose a system and method based on compressed air energy storage coupled with direct air carbon capture, wherein after the wet regeneration adsorption material is analyzed and regenerated by the desorption liquid, the desorption liquid in the wet regeneration adsorption material is rotated and removed by the self-rotating shaft to reduce the humidity of the wet regeneration adsorption material, thereby improving the carbon capture efficiency and carbon capture amount during the wet regeneration adsorption material cycle. At the same time, compressed air is used to increase the carbon dioxide concentration in the compressed air flow passing into the carbon capture component per unit flow, thereby improving the efficiency and total carbon capture of direct air carbon capture, and continuously adsorbing the compressed air to achieve continuous capture of carbon dioxide in the compressed air.
根据本申请的第一个方面提出了基于压缩空气储能耦合直接空气碳捕集的系统,包括:According to a first aspect of the present application, a system based on compressed air energy storage coupled with direct air carbon capture is proposed, comprising:
碳捕集组件,其包括壳体以及填充在所述壳体内的湿法再生吸附材料;所述壳体内设置沿其轴线方向延伸的自转转轴,所述自转转轴转动时带动所述壳体转动;A carbon capture assembly comprises a shell and a wet regeneration adsorption material filled in the shell; a self-rotating shaft extending along its axial direction is arranged in the shell, and the shell is driven to rotate when the self-rotating shaft rotates;
所述壳体与空气压缩释能组件中的压缩空气连通,用以将压缩空气内的二氧化碳经过所述湿法再生吸附材料捕集;所述壳体上开设进液口,用以通入脱附液没入所述湿法再生吸附材料,并将所述湿法再生吸附材料吸附的二氧化碳洗脱至脱附液内;当所述壳体内的脱附液输出后,利用所述壳体转动脱甩脱附液后再进行下次二氧化碳吸附捕集。The shell is connected to the compressed air in the air compression energy release component to capture the carbon dioxide in the compressed air through the wet regeneration adsorption material; a liquid inlet is provided on the shell to allow desorption liquid to be introduced into the wet regeneration adsorption material and to elute the carbon dioxide adsorbed by the wet regeneration adsorption material into the desorption liquid; after the desorption liquid in the shell is output, the shell is rotated to remove the desorption liquid before the next carbon dioxide adsorption capture is carried out.
在一些实施例中,所述空气压缩释能组件包括空气压缩组件,其与存储压缩空气的气室连接,用以向所述气室输入压缩空气;所述气室的输出端与所述壳体连接。In some embodiments, the air compression energy release component includes an air compression component, which is connected to an air chamber storing compressed air to input compressed air into the air chamber; the output end of the air chamber is connected to the shell.
在一些实施例中,所述空气压缩释能组件包括空气膨胀组件,所述空气膨胀组件的进口连接所述气室的出口用于将压缩空气膨胀做功;所述空气膨胀组件的气体出口连通所述壳体。In some embodiments, the air compression energy release component includes an air expansion component, the inlet of the air expansion component is connected to the outlet of the air chamber for expanding the compressed air to perform work; the gas outlet of the air expansion component is connected to the shell.
在一些实施例中,所述空气膨胀组件包括多级串联的空气膨胀机;所述空气膨胀机与所述自转转轴同轴连接,在所述空气膨胀机运行时带动所述自转转轴转动。In some embodiments, the air expansion assembly includes a multi-stage series-connected air expander; the air expander is coaxially connected to the self-rotating shaft, and drives the self-rotating shaft to rotate when the air expander is in operation.
在一些实施例中,所述自转转轴为中空结构,其与所述气室的出口连通;所述自转转轴连通多个气体喷射器。In some embodiments, the self-rotating shaft is a hollow structure, which is connected to the outlet of the air chamber; the self-rotating shaft is connected to a plurality of gas injectors.
在一些实施例中,所述碳捕集组件还包括储液件和光能生物培养单元;所述储液件中存储有脱附液,其出液口连接所述壳体上的进液口;所述壳体的出液口连接所述光能生物培养单元,脱附液对所述湿法再生吸附材料洗脱解析再生后排入所述光能生物培养单元。In some embodiments, the carbon capture assembly further includes a liquid storage component and a photo-energy biological cultivation unit; the liquid storage component stores a desorption liquid, and its liquid outlet is connected to a liquid inlet on the shell; the liquid outlet of the shell is connected to the photo-energy biological cultivation unit, and the desorption liquid is discharged into the photo-energy biological cultivation unit after eluting, analyzing and regenerating the wet-regeneration adsorption material.
在一些实施例中,所述碳捕集组件还包括采集仪,用于检测所述壳体内二氧化碳的浓度,在所述壳体内二氧化碳的浓度高于预设值时,所述储液件向所述壳体内通入脱附液。In some embodiments, the carbon capture assembly further includes a collector for detecting the concentration of carbon dioxide in the shell. When the concentration of carbon dioxide in the shell is higher than a preset value, the liquid storage component introduces a desorption liquid into the shell.
在一些实施例中,还包括换热器单元;其与所述空气压缩释能组件换热连接,用于在不同工况下,存储所述空气压缩释能组件中的热量或向所述空气压缩释能组件释热。In some embodiments, a heat exchanger unit is also included; it is connected to the air compression energy release component for heat exchange, and is used to store heat in the air compression energy release component or release heat to the air compression energy release component under different working conditions.
在一些实施例中,所述碳捕集组件与所述换热器单元换热连接;用于对所述壳体输出的脱附液换热;和/或所述换热器单元与所述储液件连通。In some embodiments, the carbon capture assembly is connected to the heat exchanger unit for heat exchange with the desorption liquid output from the shell; and/or the heat exchanger unit is connected to the liquid storage member.
根据本申请的第二个方面,提出了一种直接空气碳捕集的方法,该方法采用上述任意一项实施例所述的系统进行直接空气碳捕集,包括如下过程:According to a second aspect of the present application, a method for direct air carbon capture is provided. The method uses the system described in any one of the above embodiments to perform direct air carbon capture, and includes the following process:
用电低谷期,空气压缩释能组件将产生的压缩空气存储至气室;所述气室中的压缩空气调压调温后通入壳体;自转转轴转动带动所述壳体旋转吸附压缩空气中的二氧化碳;在所述壳体内二氧化碳的浓度高于预设值时,向所述壳体内通入脱附液,使得所述湿法再生吸附材料浸没在脱附液中设定时间,后将所述壳体中的脱附液排出并利用所述自转转轴转动脱甩所述壳体中的脱附液;再次向所述壳体内通入压缩空气进行直接空气碳捕集,循环往复。During the period of low electricity consumption, the air compression energy release component stores the generated compressed air in the air chamber; the compressed air in the air chamber is pressure- and temperature-regulated and then introduced into the shell; the rotation of the self-rotating shaft drives the shell to rotate and adsorb carbon dioxide in the compressed air; when the concentration of carbon dioxide in the shell is higher than a preset value, desorption liquid is introduced into the shell, so that the wet regeneration adsorption material is immersed in the desorption liquid for a set time, and then the desorption liquid in the shell is discharged and the self-rotating shaft is used to rotate to remove the desorption liquid in the shell; compressed air is introduced into the shell again for direct air carbon capture, and the cycle is repeated.
在一些实施例中,用电高峰期,所述气室中的压缩空气膨胀做功,并将输出的高温气体在脱甩湿法再生吸附材料时,通入所述壳体内加速所述湿法再生吸附材料干燥。In some embodiments, during peak hours of electricity consumption, the compressed air in the air chamber expands to do work, and the output high-temperature gas is passed into the shell to accelerate the drying of the wet regeneration adsorption material when the wet regeneration adsorption material is removed.
本申请附加的方面和优点将在下面的描述中部分给出,部分将从下面的描述中变得明显,或通过本申请的实践了解到。Additional aspects and advantages of the present application will be given in part in the description below, and in part will become apparent from the description below, or will be learned through the practice of the present application.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
本申请上述的和/或附加的方面和优点从下面结合附图对实施例的描述中将变得明显和容易理解,其中:The above and/or additional aspects and advantages of the present application will become apparent and easily understood from the following description of the embodiments in conjunction with the accompanying drawings, in which:
图1是本申请一实施例提出的基于压缩空气储能耦合空气碳捕集系统的结构框图;FIG1 is a structural block diagram of a compressed air energy storage coupled air carbon capture system proposed in one embodiment of the present application;
图2是本申请一实施例提出的碳捕集组件的结构示意图;FIG2 is a schematic structural diagram of a carbon capture assembly proposed in one embodiment of the present application;
图3是本申请另一实施例提出的基于压缩空气储能耦合空气碳捕集系统的结构框图;FIG3 is a structural block diagram of a compressed air energy storage coupled air carbon capture system proposed in another embodiment of the present application;
图4是本申请一实施例提出的基于压缩空气储能耦合空气碳捕集系统的结构框图;FIG4 is a structural block diagram of a compressed air energy storage coupled air carbon capture system proposed in one embodiment of the present application;
图5是本申请另一实施例提出的基于压缩空气储能耦合空气碳捕集系统的结构框图;FIG5 is a structural block diagram of a compressed air energy storage coupled air carbon capture system proposed in another embodiment of the present application;
图6是本申请一实施例提出的基于压缩空气储能耦合空气碳捕集系统的结构框图;FIG6 is a structural block diagram of a compressed air energy storage coupled air carbon capture system proposed in one embodiment of the present application;
图7是本申请另一实施例提出的碳捕集组件的结构示意图;FIG7 is a schematic structural diagram of a carbon capture assembly proposed in another embodiment of the present application;
图8是本申请一实施例提出的基于压缩空气储能耦合空气碳捕集系统的结构框图;FIG8 is a structural block diagram of a compressed air energy storage coupled air carbon capture system proposed in one embodiment of the present application;
图中,1、碳捕集组件;11、壳体;15、自转转轴;17、电机;18、进液口;19、出液口;20、气体喷射器;2、气室;3、空气压缩组件;4、储液件;5、光能生物培养单元;6、空气膨胀组件;7、采集仪;8、换热器单元。In the figure, 1. carbon capture component; 11. shell; 15. rotating shaft; 17. motor; 18. liquid inlet; 19. liquid outlet; 20. gas injector; 2. air chamber; 3. air compression component; 4. liquid storage component; 5. photobiological cultivation unit; 6. air expansion component; 7. collector; 8. heat exchanger unit.
具体实施方式Detailed ways
下面详细描述本申请的实施例,所述实施例的示例在附图中示出,其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的,仅用于解释本申请,而不能理解为对本申请的限制。相反,本申请的实施例包括落入所附加权利要求书的精神和内涵范围内的所有变化、修改和等同物。Embodiments of the present application are described in detail below, and examples of the embodiments are shown in the accompanying drawings, wherein the same or similar reference numerals throughout represent the same or similar elements or elements with the same or similar functions. The embodiments described below with reference to the accompanying drawings are exemplary and are only used to explain the present application, and cannot be construed as limiting the present application. On the contrary, the embodiments of the present application include all changes, modifications and equivalents that fall within the spirit and connotation of the appended claims.
如图1,根据本申请的第一个方面提出了基于压缩空气储能耦合直接空气碳捕集的系统,包括:碳捕集组件1和空气压缩释能组件;其中碳捕集组件1包括壳体11以及设置在壳体11内的湿法再生吸附材料;壳体11内设置沿其轴线方向延伸的自转转轴15;自转转轴15转动时带动壳体11转动。As shown in Figure 1, according to the first aspect of the present application, a system based on compressed air energy storage coupled with direct air carbon capture is proposed, including: a carbon capture component 1 and an air compression energy release component; wherein the carbon capture component 1 includes a shell 11 and a wet regeneration adsorption material arranged in the shell 11; a self-rotating shaft 15 extending along its axial direction is arranged in the shell 11; when the self-rotating shaft 15 rotates, it drives the shell 11 to rotate.
换言之;碳捕集组件1包括壳体11;其中可知的壳体11为具有一定耐腐蚀,耐高温的型材形成的空心结构,此外本实施例中,在壳体11内设置沿其轴线方向延伸的自转转轴15,可通过自驱动沿壳体11的轴线转动,其中自转转轴15与壳体11连接,在自转转轴15转动时可带动壳体11转动;用于均匀吸附混合气中的二氧化碳气体。In other words; the carbon capture assembly 1 includes a shell 11; it can be seen that the shell 11 is a hollow structure formed by a profile with certain corrosion resistance and high temperature resistance. In addition, in this embodiment, a self-rotating shaft 15 extending along the axial direction of the shell 11 is provided in the shell 11, which can be rotated along the axis of the shell 11 by self-drive, wherein the self-rotating shaft 15 is connected to the shell 11, and when the self-rotating shaft 15 rotates, the shell 11 can be driven to rotate; it is used to uniformly adsorb carbon dioxide gas in the mixed gas.
示例的如图2所示,自转转轴15的一端伸入壳体11内并与壳体11连接;自转转轴15通过设置在自转转轴15上的电机17驱动,其中电机17位于壳体11外,位于壳体11内的自转转轴15上,在气流经过壳体11内时,可旋转壳体11,使壳体11的湿法再生吸附材料与气流接触均匀,以利于湿法再生吸附材料吸收气流中的二氧化碳。As shown in the example of Figure 2, one end of the self-rotating shaft 15 extends into the shell 11 and is connected to the shell 11; the self-rotating shaft 15 is driven by a motor 17 arranged on the self-rotating shaft 15, wherein the motor 17 is located outside the shell 11, and is located on the self-rotating shaft 15 inside the shell 11. When the airflow passes through the shell 11, the shell 11 can be rotated so that the wet regeneration adsorption material of the shell 11 is in uniform contact with the airflow, so as to facilitate the wet regeneration adsorption material to absorb carbon dioxide in the airflow.
壳体与空气压缩释能组件中的压缩空气连通,用以将压缩空气内的二氧化碳经过湿法再生吸附材料捕集;壳体上开设进液口,用以通入脱附液没入湿法再生吸附材料,并将湿法再生吸附材料吸附的二氧化碳洗脱至脱附液内;当壳体内的脱附液输出后,利用壳体转动脱甩脱附液后再进行下次二氧化碳吸附捕集。The shell is connected to the compressed air in the air compression energy release component to capture the carbon dioxide in the compressed air through the wet regeneration adsorption material; a liquid inlet is provided on the shell to allow the desorption liquid to be immersed in the wet regeneration adsorption material and to elute the carbon dioxide adsorbed by the wet regeneration adsorption material into the desorption liquid; after the desorption liquid in the shell is output, the shell is rotated to remove the desorption liquid before the next carbon dioxide adsorption capture is carried out.
其中,壳体11上具有进气口,空气压缩释能组件中的压缩空气连通壳体11,并将压缩空气在合适的温度和气压下通入壳体11内,被其中的湿法再生吸附材料捕集其中的二氧化碳。The shell 11 has an air inlet, and the compressed air in the air compression energy release component is connected to the shell 11. The compressed air is introduced into the shell 11 at a suitable temperature and air pressure, and the carbon dioxide therein is captured by the wet regeneration adsorption material therein.
此外壳体11上开设进液口18和出液口19,本实施例中的湿法再生吸附材料吸附饱和时,可利用脱附液从进液口18输入,并将湿法再生吸附材料全部浸没入脱附液内,利用脱附液对二氧化碳进行洗脱,例如脱附液可为氨基酸钾盐或碱金属盐溶液吸收剂,例如氨基酸盐为脯氨酸钾、赖氨酸钾、甘氨酸钾、丙氨酸钾、缬氨酸钾、亮氨酸钾、异亮氨酸钾、甲硫氨酸钾的一种或多种混合;碱金属盐为氢氧化钾、氢氧化钠的一种或两种混合。二氧化碳与脱附液反应并溶解在脱附液内,完成湿法再生吸附材料解析再生后,将脱附液排出,并贮存调解后应用。在脱附液排空后,利用自转转轴15的转动,可将壳体11进行转动,实现湿法再生吸附材料中的脱附液离心脱甩出壳体11,大幅度降低湿法再生吸附材料中的湿度。相较于相关技术中,利用脱附液对湿法再生吸附材料解析再生后,直接通入气流进行再次碳捕集时,湿度较大的吸附材料对二氧化碳的捕捉效率低且存在二氧化碳气体通过吸附材料时阻力较大,碳捕集效率降低,本申请可在湿法再生吸附材料再次进行碳捕集前,降低湿法再生吸附材料的湿度,从而提高碳捕集效率和捕碳量。In addition, the shell 11 is provided with a liquid inlet 18 and a liquid outlet 19. When the wet regeneration adsorption material in this embodiment is saturated with adsorption, a desorption liquid can be input from the liquid inlet 18, and the wet regeneration adsorption material is completely immersed in the desorption liquid, and the carbon dioxide is eluted by the desorption liquid. For example, the desorption liquid can be an amino acid potassium salt or an alkali metal salt solution absorbent, for example, the amino acid salt is a mixture of one or more of proline potassium, lysine potassium, glycine potassium, alanine potassium, valine potassium, leucine potassium, isoleucine potassium, and methionine potassium; the alkali metal salt is a mixture of one or two of potassium hydroxide and sodium hydroxide. Carbon dioxide reacts with the desorption liquid and dissolves in the desorption liquid. After the wet regeneration adsorption material is analyzed and regenerated, the desorption liquid is discharged and stored for use after adjustment. After the desorption liquid is emptied, the shell 11 can be rotated by rotating the self-rotating shaft 15, so that the desorption liquid in the wet regeneration adsorption material is centrifugally removed from the shell 11, greatly reducing the humidity in the wet regeneration adsorption material. Compared with the related art, after the wet-regenerated adsorbent material is analyzed and regenerated by using a desorption liquid, when an airflow is directly introduced for carbon capture again, the adsorbent material with higher humidity has low efficiency in capturing carbon dioxide and there is greater resistance when carbon dioxide gas passes through the adsorbent material, thereby reducing the carbon capture efficiency. The present application can reduce the humidity of the wet-regenerated adsorbent material before the wet-regenerated adsorbent material is used for carbon capture again, thereby improving the carbon capture efficiency and carbon capture amount.
同时,本申请中利用碳捕集组件1与空气压缩释能组件耦合,在谷电期,利用空气压缩释能组件压缩空气,产生的高压的压缩空气提高了单位流量中通入碳捕集组件1的压缩空气气流中的二氧化碳浓度,提高了直接空气碳捕集的效率和捕碳总量,将二者结合具有方案合理,绿色节能以及较高的经济运行性,且的特点。在一些实施例中,可将碳捕集组件1设置为多个,多个碳捕集组件1并联,例如图3所示碳捕集组件1布置设有三个,三个碳捕集组件1同轴驱动;在本示例中可先对第一个碳捕集组件1进行二氧化碳吸附,其完成后再控制第二个碳捕集组件1进行二氧化碳吸附;与此同时,控制第一个碳捕集组件1进行湿法再生吸附材料解析再生;第二个碳捕集组件1进行二氧化碳吸附完成后再控制第三个碳捕集组件1进行二氧化碳吸附;与此同时,控制第二个碳捕集组件1进行湿法再生吸附材料解析再生;如此使三个碳捕集组件1循环往复工作,不断地将压缩空气进行吸附,实现连续捕集压缩空气中的二氧化碳。At the same time, the carbon capture assembly 1 is coupled with the air compression energy release assembly in the present application. During the valley period, the air compression energy release assembly is used to compress the air. The high-pressure compressed air generated increases the carbon dioxide concentration in the compressed air flow entering the carbon capture assembly 1 per unit flow, and increases the efficiency and total carbon capture of direct air carbon capture. The combination of the two has the characteristics of reasonable scheme, green energy saving, and high economic operation. In some embodiments, the carbon capture assembly 1 can be set to multiple, and multiple carbon capture assemblies 1 are connected in parallel. For example, as shown in FIG3, the carbon capture assembly 1 is arranged with three, and the three carbon capture assemblies 1 are coaxially driven; in this example, the first carbon capture assembly 1 can be first subjected to carbon dioxide adsorption, and after completion, the second carbon capture assembly 1 is controlled to adsorb carbon dioxide; at the same time, the first carbon capture assembly 1 is controlled to perform wet regeneration adsorption material analysis regeneration; after the second carbon capture assembly 1 is subjected to carbon dioxide adsorption, the third carbon capture assembly 1 is controlled to adsorb carbon dioxide; at the same time, the second carbon capture assembly 1 is controlled to perform wet regeneration adsorption material analysis regeneration; in this way, the three carbon capture assemblies 1 work in a reciprocating manner, and the compressed air is continuously adsorbed to achieve continuous capture of carbon dioxide in the compressed air.
在一些实施例中,其中空气压缩释能组件包括空气压缩组件3,其与用于存储压缩空气的气室2输入端连通;气室2的输出端与壳体11连通。In some embodiments, the air compression energy release assembly includes an air compression assembly 3 , which is connected to an input end of an air chamber 2 for storing compressed air; and an output end of the air chamber 2 is connected to a housing 11 .
其中,空气压缩释能组件包括空气压缩组件3和气室2;其中空气压缩组件3的输入端通入空气,经过压缩后输出高压的压缩空气,通过空气压缩组件3的输出端连接气室2的输入端;将压缩空气存储在气室2。示例的,空气压缩组件3包括多级串联的空气压缩机;空气压缩机的进口输入空气,经将进入的空气进行压缩形成压缩空气,此为本领域常规技术不再赘述。本实施例中将气室2中存储的压缩空气经过调温调压后,可通入碳捕集组件1进行二氧化碳碳捕集。The air compression energy release component includes an air compression component 3 and an air chamber 2; air is introduced into the input end of the air compression component 3, and high-pressure compressed air is output after compression, and the output end of the air compression component 3 is connected to the input end of the air chamber 2; the compressed air is stored in the air chamber 2. For example, the air compression component 3 includes a multi-stage series air compressor; the air compressor inputs air at the inlet, and the incoming air is compressed to form compressed air. This is a conventional technology in the field and will not be described in detail. In this embodiment, the compressed air stored in the air chamber 2 can be introduced into the carbon capture component 1 for carbon capture of carbon dioxide after temperature and pressure adjustment.
此外,在一些实施例中,基于压缩空气储能耦合直接空气碳捕集的系统还包括换热器单元8如图5所示,其中该换热器单元8与空气压缩组件3换热连接。例如换热器单元8包括换热器和储热件;其中储热件中存储有冷却介质,利用冷却介质对压缩空气换热,回收压缩空气中的热量。具体的空气换热器单元8包括多级空气换热器时,其中空气压缩机与空气换热器的数量相同,且两者配对使用一一对应,在空气进行压缩的过程中将产生空气压缩热,利用一级空气压缩机对应一级空气换热器,及时利用空气换热器将压缩空气中的热量回收。In addition, in some embodiments, the system based on compressed air energy storage coupled with direct air carbon capture also includes a heat exchanger unit 8 as shown in FIG5, wherein the heat exchanger unit 8 is connected to the air compression component 3 for heat exchange. For example, the heat exchanger unit 8 includes a heat exchanger and a heat storage component; wherein the heat storage component stores a cooling medium, and the cooling medium is used to exchange heat with the compressed air to recover the heat in the compressed air. When the specific air heat exchanger unit 8 includes a multi-stage air heat exchanger, the number of air compressors and air heat exchangers is the same, and the two are paired and used one-to-one. Air compression heat will be generated during the air compression process. A first-stage air compressor corresponds to a first-stage air heat exchanger, and the air heat exchanger is used in time to recover the heat in the compressed air.
在一些实施例中,空气压缩释能组件包括空气膨胀组件6,空气膨胀组件6的进口连接气室2的出口用于将压缩空气膨胀做功;空气膨胀组件6的气体出口连通壳体11。In some embodiments, the air compression energy release assembly includes an air expansion assembly 6 , the inlet of the air expansion assembly 6 is connected to the outlet of the air chamber 2 for expanding the compressed air to perform work; the gas outlet of the air expansion assembly 6 is connected to the shell 11 .
其中,空气压缩释能组件包括空气膨胀组件6如图4所示,其中空气膨胀组件6包括多级串联的空气膨胀机,空气膨胀机的进口连接气室2,气室2将压缩空气输出进行膨胀做功,而做功后的气体可通入壳体11。示例的,用电低谷期时;空气压缩组件3产生的压缩空气存储至气室2;气室2中的压缩空气调压调温后通入壳体11;自转转轴15转动带动壳体11旋转吸附压缩空气中的二氧化碳;在壳体11内二氧化碳的浓度高于预设值时,向壳体11内通入脱附液使得湿法再生吸附材料洗脱解析再生后,脱附液排出壳体11;自转转轴15转动脱甩吸附网盘16中的脱附液。用电高峰期时;气室2中的压缩空气进入空气膨胀组件6中做功,并将做功后的气体通入壳体11中,进行碳捕集,其中碳捕集过程与前述相同不再赘述。Among them, the air compression energy release component includes an air expansion component 6 as shown in Figure 4, wherein the air expansion component 6 includes a multi-stage series air expander, the inlet of the air expander is connected to the air chamber 2, the air chamber 2 outputs the compressed air to expand and do work, and the gas after the work can be passed into the shell 11. For example, during the low electricity consumption period; the compressed air generated by the air compression component 3 is stored in the air chamber 2; the compressed air in the air chamber 2 is passed into the shell 11 after adjusting the pressure and temperature; the self-rotating shaft 15 rotates to drive the shell 11 to rotate and adsorb carbon dioxide in the compressed air; when the concentration of carbon dioxide in the shell 11 is higher than the preset value, the desorption liquid is passed into the shell 11 so that the wet regeneration adsorption material is eluted and analyzed for regeneration, and the desorption liquid is discharged from the shell 11; the self-rotating shaft 15 rotates to remove the desorption liquid in the adsorption net disk 16. During the peak electricity consumption period; the compressed air in the air chamber 2 enters the air expansion component 6 to do work, and the gas after the work is passed into the shell 11 for carbon capture, wherein the carbon capture process is the same as the above and will not be repeated.
此外,在一些实施例中,换热器单元8与空气膨胀组件6换热连接如图5所示;换热器单元8包括多级空气再热器,其中空气膨胀机与空气再热器的数量相同,且两者配对使用一一对应,用于对气室2输出的压缩空气进行加热后进入空气膨胀机做功发电。In addition, in some embodiments, the heat exchanger unit 8 is connected to the air expansion component 6 for heat exchange as shown in Figure 5; the heat exchanger unit 8 includes a multi-stage air reheater, wherein the number of air expanders and air reheaters is the same, and the two are paired and used one-to-one, and are used to heat the compressed air output from the air chamber 2 and then enter the air expander to generate power.
在一些实施例中,空气膨胀机与自转转轴15同轴连接,在空气膨胀机运行时带动自转转轴15转动。具体的,空气膨胀机可与自转转轴15同轴连接;在空气膨胀机运行时,可关闭驱动自转转轴15的电机17,利用空气膨胀机带动自转转轴15转动。In some embodiments, the air expander is coaxially connected to the self-rotating shaft 15, and drives the self-rotating shaft 15 to rotate when the air expander is running. Specifically, the air expander can be coaxially connected to the self-rotating shaft 15; when the air expander is running, the motor 17 driving the self-rotating shaft 15 can be turned off, and the air expander can be used to drive the self-rotating shaft 15 to rotate.
在一些实施例中,自转转轴15为中空结构,其与气室2的出口连通;自转转轴15上连通多个间隔设置的气体喷射器20。In some embodiments, the self-rotating shaft 15 is a hollow structure, which is connected to the outlet of the air chamber 2; the self-rotating shaft 15 is connected to a plurality of gas injectors 20 arranged at intervals.
其中,上述实施例中,压缩空气均进入壳体11内,然后再与湿法再生吸附材料接触,其中虽然自转转轴15可在此过程中转动,带动壳体11增加与气流的接触面积,实现较好的碳捕集效果;但是碳捕集速度较慢,时间较长;因此在本实施例中,利用将自转转轴15设置为中空结构如图7,其中通入气室2输出的压缩空气,并利用气体喷射器20将压缩空气喷出,以使得湿法再生吸附材料较快的饱和,完成碳捕集和增加捕集效率。示例的,自转转轴15为中空管结构,其伸入壳体11内,自转转轴15连通有气体喷射器20,在自转转轴15内通入压缩空气后,压缩空气经过气体喷射器20均匀分散到周侧,并由湿法再生吸附材料捕集其中的二氧化碳。Among them, in the above embodiments, the compressed air all enters the shell 11, and then contacts the wet regeneration adsorption material. Although the self-rotating shaft 15 can rotate in this process, driving the shell 11 to increase the contact area with the airflow, achieving a better carbon capture effect; but the carbon capture speed is slow and the time is long; therefore, in this embodiment, the self-rotating shaft 15 is set as a hollow structure as shown in Figure 7, wherein the compressed air output by the air chamber 2 is introduced, and the compressed air is ejected by the gas injector 20, so that the wet regeneration adsorption material is saturated faster, the carbon capture is completed and the capture efficiency is increased. For example, the self-rotating shaft 15 is a hollow tube structure, which extends into the shell 11, and the self-rotating shaft 15 is connected to the gas injector 20. After the compressed air is introduced into the self-rotating shaft 15, the compressed air is evenly dispersed to the surrounding side through the gas injector 20, and the carbon dioxide therein is captured by the wet regeneration adsorption material.
具体的,本实施例中的基于压缩空气储能耦合直接空气碳捕集的系统如图6所示,其进行空气碳捕集的方法为:用电低谷期时;空气压缩组件3产生的压缩空气存储至气室2;气室2中的压缩空气调压调温后通入壳体11和自转转轴15内;并进行压缩空气中二氧化碳的捕集和湿法再生吸附材料的解析再生。用电高峰期时;气室2中的压缩空气进入空气膨胀组件6中做功,并将做功后的气体通入壳体11中;同时气室2中的压缩空气调压调温后通入自转转轴15内进行碳捕集,其中碳捕集过程与前述相同不再赘述。需要说明的,在本实施例中解析再生的湿法再生吸附材料在进行循环使用前,利用空气膨胀组件6运行并带动自转转轴15转动,用于脱甩壳体11中的脱附液;同时将做功后的气体通入壳体11中,用于快速干燥湿法再生吸附材料。Specifically, the system based on compressed air energy storage coupled with direct air carbon capture in this embodiment is shown in FIG6 , and the method for air carbon capture is as follows: during the off-peak period of electricity consumption; the compressed air generated by the air compression component 3 is stored in the air chamber 2; the compressed air in the air chamber 2 is pressure-regulated and temperature-regulated and then introduced into the shell 11 and the self-rotating shaft 15; and the carbon dioxide in the compressed air is captured and the wet regeneration adsorption material is analyzed and regenerated. During the peak period of electricity consumption; the compressed air in the air chamber 2 enters the air expansion component 6 to do work, and the gas after the work is introduced into the shell 11; at the same time, the compressed air in the air chamber 2 is pressure-regulated and temperature-regulated and then introduced into the self-rotating shaft 15 for carbon capture, wherein the carbon capture process is the same as the above and will not be repeated. It should be noted that in this embodiment, the wet regeneration adsorption material for analysis and regeneration is operated by the air expansion component 6 and drives the self-rotating shaft 15 to rotate before recycling, which is used to remove the desorption liquid in the shell 11; at the same time, the gas after the work is introduced into the shell 11, which is used to quickly dry the wet regeneration adsorption material.
在一些实施例中,碳捕集组件1还包括储液件4和光能生物培养单元5;储液件4中存储有脱附液,其出液口19连接壳体11上的进液口18;壳体11的出液口19连接光能生物培养单元5,脱附液对湿法再生吸附材料洗脱解析再生后排入光能生物培养单元5。In some embodiments, the carbon capture assembly 1 further includes a liquid storage component 4 and a photo-energy biological cultivation unit 5; the liquid storage component 4 stores desorption liquid, and its liquid outlet 19 is connected to the liquid inlet 18 on the shell 11; the liquid outlet 19 of the shell 11 is connected to the photo-energy biological cultivation unit 5, and the desorption liquid is discharged into the photo-energy biological cultivation unit 5 after eluting and analyzing the wet-regeneration adsorption material for regeneration.
其中,碳捕集组件1还包括储液件4和光能生物培养单元5如图3-图6,其中储液件4中存储有脱附液,其出液口19连接壳体11上的进液口18;壳体11上的进液口18连接光能生物培养单元5;其中光能生物为利用氮磷钾等元素进行培养的光合作用的生物,如藻类等。其中脱附液可为氨基酸钾盐或碱金属盐溶液吸收剂,其中可与二氧化碳反应生成碳酸氢根离子,根据光能微生物的不同,可调节从壳体11排出的脱附液的离子浓度,pH值等,直接用于光能生物的培养。The carbon capture assembly 1 further includes a liquid storage part 4 and a light-energy biological cultivation unit 5 as shown in Fig. 3-Fig. 6, wherein the liquid storage part 4 stores a desorption liquid, and its liquid outlet 19 is connected to the liquid inlet 18 on the shell 11; the liquid inlet 18 on the shell 11 is connected to the light-energy biological cultivation unit 5; wherein the light-energy organism is a photosynthetic organism cultivated using elements such as nitrogen, phosphorus and potassium, such as algae. The desorption liquid can be an amino acid potassium salt or an alkali metal salt solution absorbent, which can react with carbon dioxide to generate bicarbonate ions. According to different light-energy microorganisms, the ion concentration, pH value, etc. of the desorption liquid discharged from the shell 11 can be adjusted, and it can be directly used for the cultivation of light-energy organisms.
在一些实施例中,换热器单元8与碳捕集组件1换热连接,例如图8所示换热器单元8包括换热器,可与壳体11输出的脱附液换热,用于加热脱附液;或者换热器中的换热介质与脱附液相同;通过换热器单元8与储液件4连通用于向储液件4中补充脱附液,提高脱附液的脱附能力。In some embodiments, the heat exchanger unit 8 is connected to the carbon capture assembly 1 for heat exchange. For example, the heat exchanger unit 8 shown in Figure 8 includes a heat exchanger that can exchange heat with the desorption liquid output by the shell 11 to heat the desorption liquid; or the heat exchange medium in the heat exchanger is the same as the desorption liquid; the heat exchanger unit 8 is connected to the liquid storage component 4 to replenish the desorption liquid into the liquid storage component 4 to improve the desorption capacity of the desorption liquid.
在一些实施例中,碳捕集组件1还包括采集仪7,其用于检测壳体11内二氧化碳的浓度,在壳体11内二氧化碳的浓度高于预设值时,向壳体11内通入脱附液。In some embodiments, the carbon capture assembly 1 further includes a collector 7 for detecting the concentration of carbon dioxide in the shell 11 , and when the concentration of carbon dioxide in the shell 11 is higher than a preset value, a desorption liquid is introduced into the shell 11 .
其中碳捕集组件1还包括采集仪7如图8所示,其中采集仪7为二氧化碳浓度检测仪,其设置可采集在壳体11出液口19处的二氧化碳的浓度,并根据不同湿法再生吸附材料的吸附性能设置预设值,当壳体11内二氧化碳的浓度高于预设值时说明湿法再生吸附材料趋近饱和,可向壳体11内通入脱附液。The carbon capture assembly 1 also includes a collector 7 as shown in FIG. 8 , wherein the collector 7 is a carbon dioxide concentration detector, which can collect the concentration of carbon dioxide at the liquid outlet 19 of the shell 11 and set a preset value according to the adsorption performance of different wet regeneration adsorption materials. When the concentration of carbon dioxide in the shell 11 is higher than the preset value, it indicates that the wet regeneration adsorption material is close to saturation, and a desorption liquid can be introduced into the shell 11.
根据本申请的第二个方面,还提出了一种直接空气碳捕集的方法,该方法采用上述任意一项实施例的系统进行直接空气碳捕集,包括如下过程:According to a second aspect of the present application, a method for direct air carbon capture is also proposed. The method uses the system of any one of the above embodiments to perform direct air carbon capture, and includes the following process:
用电低谷期,空气压缩释能组件将产生的压缩空气存储至气室2;气室2中的压缩空气调压调温后通入壳体;自转转轴15转动带动壳体旋转吸附压缩空气中的二氧化碳;在壳体内二氧化碳的浓度高于预设值时,向壳体内通入脱附液,使得湿法再生吸附材料浸没在脱附液中设定时间,后将壳体中的脱附液排出并利用自转转轴15转动脱甩壳体中的脱附液;再次向壳体内通入压缩空气进行直接空气碳捕集,循环往复。During the period of low electricity consumption, the air compression energy release component stores the generated compressed air in the air chamber 2; the compressed air in the air chamber 2 is pressure- and temperature-regulated and then introduced into the shell; the rotation of the self-rotating shaft 15 drives the shell to rotate and adsorb carbon dioxide in the compressed air; when the concentration of carbon dioxide in the shell is higher than the preset value, desorption liquid is introduced into the shell, so that the wet regeneration adsorption material is immersed in the desorption liquid for a set time, and then the desorption liquid in the shell is discharged and the self-rotating shaft 15 is used to rotate and remove the desorption liquid in the shell; compressed air is introduced into the shell again for direct air carbon capture, and the cycle is repeated.
其中,以图8中的基于压缩空气储能耦合直接空气碳捕集的系统为示例,其直接空气碳捕集的方法为:用电低谷期时;空气压缩组件3产生的压缩空气与换热器单元8换热后存储至气室2;气室2中的压缩空气调压调温后通入壳体11和自转转轴15内;自转转轴15转动带动壳体11旋转吸附压缩空气中的二氧化碳;在壳体11内二氧化碳的浓度高于预设值时,向壳体11内通入脱附液使得湿法再生吸附材料洗脱解析再生后,脱附液排出壳体11;自转转轴15自驱动转动脱甩壳体11中的脱附液。用电高峰期时;气室2中的压缩空气进入空气膨胀组件6中做功,同时利用空气膨胀机运行带动自转转轴15转动,并将做功后的气体通入壳体11中;气室2中的压缩空气调压调温后通入自转转轴15内,并利用气体喷射器20将气体喷出,进行气流中的二氧化碳捕集,其中碳捕集过程与前述相同不再赘述。Among them, taking the system based on compressed air energy storage coupled with direct air carbon capture in Figure 8 as an example, its direct air carbon capture method is: during the low electricity consumption period; the compressed air generated by the air compression component 3 is stored in the air chamber 2 after heat exchange with the heat exchanger unit 8; the compressed air in the air chamber 2 is pressure- and temperature-regulated and then passed into the shell 11 and the self-rotating shaft 15; the rotation of the self-rotating shaft 15 drives the shell 11 to rotate and adsorb carbon dioxide in the compressed air; when the concentration of carbon dioxide in the shell 11 is higher than the preset value, desorption liquid is introduced into the shell 11 to make the wet regeneration adsorption material elute and analyze and regenerate, and then the desorption liquid is discharged from the shell 11; the self-rotating shaft 15 is self-driven to rotate to remove the desorption liquid in the shell 11. During the peak period of electricity consumption, the compressed air in the air chamber 2 enters the air expansion component 6 to do work, and at the same time, the air expander is used to drive the rotating shaft 15 to rotate, and the gas after doing work is passed into the shell 11; the compressed air in the air chamber 2 is adjusted in pressure and temperature and then passed into the rotating shaft 15, and the gas is ejected by the gas injector 20 to capture carbon dioxide in the airflow, wherein the carbon capture process is the same as mentioned above and will not be repeated.
在本实施例中解析再生的湿法再生吸附材料在进行循环使用前,利用空气膨胀组件6运行并带动自转转轴15转动,用于脱甩壳体11中的脱附液;同时将做功后的气体通入壳体11中,用于快速干燥湿法再生吸附材料。In this embodiment, before the wet regeneration adsorption material is recycled, the air expansion component 6 is operated to drive the rotating shaft 15 to rotate, so as to remove the desorption liquid in the shell 11; at the same time, the gas after work is introduced into the shell 11 to quickly dry the wet regeneration adsorption material.
需要说明的是,在本申请的描述中,术语“第一”、“第二”等仅用于描述目的,而不能理解为指示或暗示相对重要性。此外,在本申请的描述中,除非另有说明,“多个”的含义是两个或两个以上。It should be noted that, in the description of this application, the terms "first", "second", etc. are only used for descriptive purposes and cannot be understood as indicating or implying relative importance. In addition, in the description of this application, unless otherwise specified, the meaning of "plurality" is two or more.
流程图中或在此以其他方式描述的任何过程或方法描述可以被理解为,表示包括一个或更多个用于实现特定逻辑功能或过程的步骤的可执行指令的代码的模块、片段或部分,并且本申请的优选实施方式的范围包括另外的实现,其中可以不按所示出或讨论的顺序,包括根据所涉及的功能按基本同时的方式或按相反的顺序,来执行功能,这应被本申请的实施例所属技术领域的技术人员所理解。Any process or method description in a flowchart or otherwise described herein may be understood to represent a module, segment or portion of code that includes one or more executable instructions for implementing the steps of a specific logical function or process, and the scope of the preferred embodiments of the present application includes alternative implementations in which functions may not be performed in the order shown or discussed, including performing functions in a substantially simultaneous manner or in the reverse order depending on the functions involved, which should be understood by technicians in the technical field to which the embodiments of the present application belong.
在本说明书的描述中,参考术语“一个实施例”、“一些实施例”、“示例”、“具体示例”、或“一些示例”等的描述意指结合该实施例或示例描述的具体特征、结构、材料或者特点包含于本申请的至少一个实施例或示例中。在本说明书中,对上述术语的示意性表述不一定指的是相同的实施例或示例。而且,描述的具体特征、结构、材料或者特点可以在任何的一个或多个实施例或示例中以合适的方式结合。In the description of this specification, the description with reference to the terms "one embodiment", "some embodiments", "example", "specific example", or "some examples" means that the specific features, structures, materials or characteristics described in conjunction with the embodiment or example are included in at least one embodiment or example of the present application. In this specification, the schematic representation of the above terms does not necessarily refer to the same embodiment or example. Moreover, the specific features, structures, materials or characteristics described may be combined in any one or more embodiments or examples in a suitable manner.
尽管上面已经示出和描述了本申请的实施例,可以理解的是,上述实施例是示例性的,不能理解为对本申请的限制,本领域的普通技术人员在本申请的范围内可以对上述实施例进行变化、修改、替换和变型。Although the embodiments of the present application have been shown and described above, it can be understood that the above embodiments are exemplary and cannot be understood as limitations on the present application. Ordinary technicians in the field can change, modify, replace and modify the above embodiments within the scope of the present application.
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Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101186357A (en) * | 2007-12-18 | 2008-05-28 | 南京大学 | Resin-based nanometer hydrated iron oxide method for deep purification of heavy metal slightly polluted water |
WO2015060723A1 (en) * | 2013-10-22 | 2015-04-30 | Statoil Petroleum As | System and process for absorption and desorption of co2 |
CN109737432A (en) * | 2018-12-06 | 2019-05-10 | 无锡中天固废处置有限公司 | Utilize the processing system and method for dangerous waste incinerator processing low-concentration organic exhaust gas |
CN114452768A (en) * | 2022-03-03 | 2022-05-10 | 霖和气候科技(北京)有限公司 | CO based on wet-process regenerated adsorption material2Direct air capture system and method |
CN114558414A (en) * | 2022-03-09 | 2022-05-31 | 霖和气候科技(北京)有限公司 | Method for decarbonizing concentrated carbon dioxide emission source based on wet-process regeneration carbon dioxide capture material |
CN116889790A (en) * | 2023-07-31 | 2023-10-17 | 西安热工研究院有限公司 | Variable-humidity adsorption direct air carbon trapping coupling microalgae carbon fixing system and method |
CN117018805A (en) * | 2023-07-31 | 2023-11-10 | 西安热工研究院有限公司 | Energy-saving direct air carbon trapping system and method for coupling compressed air energy storage |
CN117138549A (en) * | 2023-10-09 | 2023-12-01 | 西安热工研究院有限公司 | A system and method for air carbon capture concrete maintenance and carbon sequestration |
CN117138550A (en) * | 2023-10-09 | 2023-12-01 | 西安热工研究院有限公司 | Wet-method-desorbed air carbon capturing microalgae carbon fixing system and method |
CN117282222A (en) * | 2023-09-18 | 2023-12-26 | 西安热工研究院有限公司 | Device and method for continuously capturing carbon in air |
-
2024
- 2024-03-04 CN CN202410239823.3A patent/CN117815842B/en active Active
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101186357A (en) * | 2007-12-18 | 2008-05-28 | 南京大学 | Resin-based nanometer hydrated iron oxide method for deep purification of heavy metal slightly polluted water |
WO2015060723A1 (en) * | 2013-10-22 | 2015-04-30 | Statoil Petroleum As | System and process for absorption and desorption of co2 |
CN109737432A (en) * | 2018-12-06 | 2019-05-10 | 无锡中天固废处置有限公司 | Utilize the processing system and method for dangerous waste incinerator processing low-concentration organic exhaust gas |
CN114452768A (en) * | 2022-03-03 | 2022-05-10 | 霖和气候科技(北京)有限公司 | CO based on wet-process regenerated adsorption material2Direct air capture system and method |
CN114558414A (en) * | 2022-03-09 | 2022-05-31 | 霖和气候科技(北京)有限公司 | Method for decarbonizing concentrated carbon dioxide emission source based on wet-process regeneration carbon dioxide capture material |
CN116889790A (en) * | 2023-07-31 | 2023-10-17 | 西安热工研究院有限公司 | Variable-humidity adsorption direct air carbon trapping coupling microalgae carbon fixing system and method |
CN117018805A (en) * | 2023-07-31 | 2023-11-10 | 西安热工研究院有限公司 | Energy-saving direct air carbon trapping system and method for coupling compressed air energy storage |
CN117282222A (en) * | 2023-09-18 | 2023-12-26 | 西安热工研究院有限公司 | Device and method for continuously capturing carbon in air |
CN117138549A (en) * | 2023-10-09 | 2023-12-01 | 西安热工研究院有限公司 | A system and method for air carbon capture concrete maintenance and carbon sequestration |
CN117138550A (en) * | 2023-10-09 | 2023-12-01 | 西安热工研究院有限公司 | Wet-method-desorbed air carbon capturing microalgae carbon fixing system and method |
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