CN115162464A - Carbon dioxide and fresh water capturing system and capturing method thereof - Google Patents
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 102
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 51
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 48
- 239000013505 freshwater Substances 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims abstract description 12
- 238000001179 sorption measurement Methods 0.000 claims abstract description 115
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 71
- 230000008929 regeneration Effects 0.000 claims abstract description 66
- 238000011069 regeneration method Methods 0.000 claims abstract description 66
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 50
- 239000003570 air Substances 0.000 claims abstract description 46
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000012080 ambient air Substances 0.000 claims abstract description 5
- 239000003463 adsorbent Substances 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 8
- 239000012621 metal-organic framework Substances 0.000 claims description 6
- 239000011148 porous material Substances 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000000017 hydrogel Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 238000009423 ventilation Methods 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 12
- 238000005516 engineering process Methods 0.000 description 5
- 238000010586 diagram Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
- 159000000002 lithium salts Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- 241000282414 Homo sapiens Species 0.000 description 1
- 239000013178 MIL-101(Cr) Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
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- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
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- 239000002861 polymer material Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
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- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03B—INSTALLATIONS OR METHODS FOR OBTAINING, COLLECTING, OR DISTRIBUTING WATER
- E03B3/00—Methods or installations for obtaining or collecting drinking water or tap water
- E03B3/28—Methods or installations for obtaining or collecting drinking water or tap water from humid air
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D5/00—Condensation of vapours; Recovering volatile solvents by condensation
- B01D5/0057—Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/50—Carbon dioxide
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
- B01D2259/4009—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas
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Abstract
本发明提供一种二氧化碳和淡水的捕集系统及其捕集方法,系统包括吸附风机、水吸附转轮、第一冷凝器、碳吸附转轮、空气加热器、第一再生风机、第二再生风机、第二冷凝器、储水罐和储气瓶,水吸附转轮和碳吸附转轮内部皆分为吸附区和再生区,本发明环境空气依次通过吸附风机、水吸附转轮吸附区、第一冷凝器、碳吸附转轮吸附区、空气加热器、第一再生风机、碳吸附转轮再生区、第二再生风机和水吸附转轮再生区,最终形成高碳蒸汽,高碳蒸汽通过冷凝器冷凝,水和二氧化碳分别进入储水罐和储气瓶内存储,本发明首次提出一套系统直接对空气进行水和二氧化碳的双捕集,实现了不间断式的捕集和再生过程,且系统结构简单、使用方便。
The invention provides a carbon dioxide and fresh water capture system and its capture method. The system includes an adsorption fan, a water adsorption rotor, a first condenser, a carbon adsorption rotor, an air heater, a first regeneration fan, and a second regeneration fan. The fan, the second condenser, the water storage tank and the gas cylinder, the water adsorption runner and the carbon adsorption runner are divided into an adsorption area and a regeneration area. The ambient air in the present invention passes through the adsorption fan, the water adsorption runner adsorption area, The first condenser, the carbon adsorption rotor adsorption zone, the air heater, the first regeneration fan, the carbon adsorption rotor regeneration zone, the second regeneration fan and the water adsorption rotor regeneration zone finally form high-carbon steam, and the high-carbon steam passes through the The condenser is condensed, and the water and carbon dioxide are stored in the water storage tank and the gas storage cylinder respectively. The present invention proposes a system for the first time to directly capture the air for both water and carbon dioxide, thereby realizing an uninterrupted capture and regeneration process. And the system structure is simple and easy to use.
Description
技术领域technical field
本发明属于二氧化碳和水的捕集技术领域,尤其涉及一种二氧化碳和淡水的捕集系统及其捕集方法。The invention belongs to the technical field of capturing carbon dioxide and water, and particularly relates to a capturing system for carbon dioxide and fresh water and a capturing method thereof.
背景技术Background technique
近年来,化石燃料的大量燃烧使空气中二氧化碳浓度不断升高,导致全球变暖问题日益严重。除了减少二氧化碳的排放,碳捕集也是实现“碳达峰”、“碳中和”目标的关键。传统的碳捕集模式,例如从燃煤电厂进行燃烧前捕集和燃烧后捕集可以减缓大气二氧化碳浓度的升高,但是只有直接从空气中捕集二氧化碳才是真正能显著降低空气中二氧化碳浓度的“负碳技术”。In recent years, the massive burning of fossil fuels has increased the concentration of carbon dioxide in the air, leading to an increasingly serious global warming problem. In addition to reducing carbon dioxide emissions, carbon capture is also key to achieving "carbon peaking" and "carbon neutrality" goals. Traditional carbon capture models, such as pre-combustion and post-combustion capture from coal-fired power plants, can slow the rise in atmospheric CO2 concentrations, but only capturing CO2 directly from the air can actually significantly reduce airborne CO2 concentrations "Negative Carbon Technology".
由于淡水资源有限与人口激增之间的矛盾,水资源短缺一直是人类面临的严重危机。而空气集水技术能够直接从空气中捕获淡水,对地理水资源的依赖度小,是一项有前途的技术。Due to the contradiction between the limited freshwater resources and the population explosion, water shortage has always been a serious crisis facing human beings. The air-harvesting technology, which can directly capture fresh water from the air, has little dependence on geographical water resources, and is a promising technology.
发明内容SUMMARY OF THE INVENTION
针对二氧化碳捕集技术和空气取水的缺陷,本发明提供一种吸附转轮式直接空气二氧化碳和淡水联合捕集系统及其方法,以实现对空气中二氧化碳和淡水的全天候快速捕集。In view of the defects of carbon dioxide capture technology and air water intake, the present invention provides an adsorption runner type direct air carbon dioxide and fresh water combined capture system and method thereof, so as to realize all-weather fast capture of carbon dioxide and fresh water in the air.
本发明的技术方案如下:The technical scheme of the present invention is as follows:
一种二氧化碳和淡水的捕集系统,包括风机、冷凝器、转轮、空气加热器、储水罐和储气瓶,所述风机包括吸附风机和再生风机,所述再生风机包括第一再生风机和第二再生风机;所述冷凝器包括第一冷凝器和第二冷凝器;所述转轮包括水吸附转轮和碳吸附转轮,所述水吸附转轮和所述碳吸附转轮皆设置有用于提供动力的电动机,且所述水吸附转轮和所述碳吸附转轮的内部皆包括吸附区和再生区;A carbon dioxide and fresh water capture system, including a fan, a condenser, a runner, an air heater, a water storage tank and a gas cylinder, the fan includes an adsorption fan and a regeneration fan, and the regeneration fan includes a first regeneration fan and a second regeneration fan; the condenser includes a first condenser and a second condenser; the runner includes a water adsorption runner and a carbon adsorption runner, and both the water adsorption runner and the carbon adsorption runner are an electric motor for providing power is provided, and the inside of the water adsorption runner and the carbon adsorption runner both include an adsorption zone and a regeneration zone;
所述吸附风机、水吸附转轮的吸附区、第一冷凝器、碳吸附转轮的吸附区、空气加热器、第一再生风机、碳吸附转轮的再生区、第二再生风机、水吸附转轮的再生区和第二冷凝器依次风路设置,所述第二冷凝器通过管道分别连接所述储水罐和所述储气瓶。The adsorption fan, the adsorption zone of the water adsorption rotor, the first condenser, the adsorption zone of the carbon adsorption rotor, the air heater, the first regeneration fan, the regeneration zone of the carbon adsorption rotor, the second regeneration fan, the water adsorption The regeneration area of the runner and the second condenser are arranged in sequence in the air passage, and the second condenser is respectively connected to the water storage tank and the gas storage bottle through pipes.
进一步地,所述水吸附转轮内的吸附区和再生区皆设有水吸附剂,所述碳吸附转轮内的吸附区和再生区皆设有二氧化碳吸附剂。Further, both the adsorption zone and the regeneration zone in the water adsorption runner are provided with a water adsorbent, and both the adsorption zone and the regeneration zone in the carbon adsorption runner are provided with a carbon dioxide adsorbent.
进一步地,所述水吸附剂为盐基复合材料、多孔材料、水凝胶、金属有机框架材料中的一种或多种混合。Further, the water adsorbent is a mixture of one or more of salt-based composite materials, porous materials, hydrogels, and metal-organic framework materials.
进一步地,所述二氧化碳吸附剂为胺多功能化的多孔材料、胺功能化的树脂和金属有机框架材料中的一种或多种混合。Further, the carbon dioxide adsorbent is a mixture of one or more of amine-functionalized porous materials, amine-functionalized resins and metal organic framework materials.
进一步地,所述水吸附转轮和碳吸附转轮中吸附区与再生区的面积比为1:1—3:1。Further, the area ratio of the adsorption zone to the regeneration zone in the water adsorption rotor and the carbon adsorption rotor is 1:1-3:1.
一种二氧化碳和淡水捕集系统的捕集方法,包括如下步骤:A capture method for a carbon dioxide and fresh water capture system, comprising the following steps:
S1:接通电源,电动机、风机和空气加热机器开始运行;S1: Turn on the power, the motor, fan and air heating machine start to run;
S2:环境空气依次通过吸附风机送风、水吸附转轮的吸附区进行水吸附、第一冷凝器进行降温、碳吸附转轮的吸附区进行碳吸附、空气加热器进行升温、第一再生风机送风,碳吸附转轮的再生区进行碳再生、第二再生风机送风、水吸附转轮的再生区进行水再生并形成高碳蒸汽、第二冷凝器对高碳蒸汽进行冷凝,冷凝后的水和二氧化碳分别进入储水罐和储气瓶进行存储。S2: The ambient air is supplied by the adsorption fan in sequence, the adsorption area of the water adsorption runner performs water adsorption, the first condenser performs cooling, the adsorption area of the carbon adsorption runner performs carbon adsorption, the air heater performs heating, and the first regeneration fan Air supply, carbon regeneration in the regeneration area of the carbon adsorption runner, air supply by the second regeneration fan, water regeneration in the regeneration area of the water adsorption runner to form high-carbon steam, and the second condenser condenses the high-carbon steam. The water and carbon dioxide enter the water storage tank and the gas storage cylinder respectively for storage.
与现有技术相比,本发明的有益效果主要体现在:Compared with the prior art, the beneficial effects of the present invention are mainly reflected in:
1、本发明的吸附转轮式直接空气二氧化碳和淡水联合捕集系统,利用转轮直接对空气中的二氧化碳和水分进行捕集,并利用高温空气对吸附剂进行负压再生,相比于传统的固定床式捕集装置,本装置的灵活性高、气流压降小、再生气体的温度梯级利用,可以有效提高能源利用效率。1. The adsorption runner type direct air carbon dioxide and fresh water combined capture system of the present invention uses the runner to directly capture carbon dioxide and moisture in the air, and uses high-temperature air to regenerate the adsorbent under negative pressure. The fixed bed type trapping device has high flexibility, small gas flow pressure drop, and temperature cascade utilization of regeneration gas, which can effectively improve energy utilization efficiency.
2、本发明首次提出一套系统直接对空气进行水和二氧化碳的双捕集,实现了不间断式的捕集和再生过程,且系统结构简单、使用方便;相比传统单一二氧化碳捕集或空气取水装置,本装置利用变温吸附原理,实现了从空气中直接进行的快速二氧化碳和水分联合捕集,极大扩展了两种技术的使用边界,同时,使用高温空气进行吸附剂的再生,再生的混合气可使用冷凝的方式使水与二氧化碳分离从而得到纯度较高的二氧化碳气体和相对纯净的淡水,从而使二者被利用或封存,实现物质和能量互补的全场景的低能耗驱动的高效淡水和二氧化碳获取。2. The present invention proposes for the first time a system to directly capture water and carbon dioxide in the air, which realizes an uninterrupted capture and regeneration process, and the system has a simple structure and is easy to use; compared with the traditional single carbon dioxide capture or air Water intake device, this device uses the principle of temperature swing adsorption to realize the rapid combined capture of carbon dioxide and moisture directly from the air, which greatly expands the use boundary of the two technologies. The mixed gas can be condensed to separate water and carbon dioxide to obtain high-purity carbon dioxide gas and relatively pure fresh water, so that the two can be used or stored to achieve low-energy consumption driven high-efficiency fresh water in the whole scene with complementary materials and energy. and carbon dioxide acquisition.
3、本发明使用具有良好吸附动力学性能的吸附材料,转轮以适宜的转速转动,经过吸附区的吸附剂能在到达再吸附饱和的状态,经过再生区的吸附剂能在回到吸附区以前完成再生活化,因此能满足转轮式连续捕集的要求。3. The present invention uses the adsorption material with good adsorption kinetic performance, the rotor rotates at a suitable speed, the adsorbent passing through the adsorption zone can reach the state of re-adsorption saturation, and the adsorbent passing through the regeneration zone can return to the adsorption zone. The regeneration and activation have been completed before, so it can meet the requirements of runner-type continuous capture.
附图说明Description of drawings
图1为本发明一种二氧化碳和淡水的捕集系统的结构图;Fig. 1 is the structure diagram of a kind of carbon dioxide and fresh water capture system of the present invention;
图2为本发明转轮结构图。Fig. 2 is the structure diagram of the runner of the present invention.
其中,1、吸附风机;2、水吸附转轮;3、第一冷凝器;4、碳吸附转轮;5、空气加热器;6、第一再生风机;7第二再生风机;8、第二冷凝器;9、储水罐;10、储气瓶;11、电动机;12、吸附区;13、再生区。Among them, 1, adsorption fan; 2, water adsorption rotor; 3, first condenser; 4, carbon adsorption rotor; 5, air heater; 6, first regeneration fan; 7, second regeneration fan; 8, first 2. Condenser; 9. Water storage tank; 10. Gas storage cylinder; 11. Electric motor; 12. Adsorption zone; 13. Regeneration zone.
具体实施方式Detailed ways
下面将结合示意图对本发明一种二氧化碳和淡水的捕集系统及其捕集方法进行更详细的描述,其中表示了本发明的优选实施例,应该理解本领域技术人员可以修改在此描述的本发明,而仍然实现本发明的有利效果,因此,下列描述应当被理解为对于本领域技术人员的广泛知道,而并不作为对本发明的限制。A carbon dioxide and fresh water capture system and a capture method thereof of the present invention will be described in more detail below in conjunction with schematic diagrams, wherein preferred embodiments of the present invention are shown, and it should be understood that those skilled in the art can modify the present invention described herein , and still achieve the advantageous effects of the present invention, therefore, the following description should be construed as widely known to those skilled in the art, rather than as a limitation of the present invention.
参考图1和图2,一种二氧化碳和淡水的捕集系统,包括吸附风机1、水吸附转轮2、第一冷凝器3、碳吸附转轮4、空气加热器5、第一再生风机6、第二再生风机7、第二冷凝器8、储水罐9和储气瓶10,其中,水吸附转轮2和碳吸附转轮4都配套设置有电动机11,电动机11驱动水吸附转轮2和碳吸附转轮4进行旋转,旋转可为匀速旋转,也可为变速旋转。水吸附转轮2和碳吸附转轮4的内部都分为吸附区11和再生区12,吸附区11和再生区12的面积占比为1:1—3:1。Referring to Figures 1 and 2, a carbon dioxide and fresh water capture system includes an adsorption fan 1, a
空气加热器5用于加热碳吸附转轮4通入的空气,其热量来源为电能、太阳能、地热能和工业余热中的一种或多种。The
水吸附转轮2的吸附区和再生区都设置有水吸附剂,水吸附剂为盐基复合材料、多孔材料、水凝胶、金属有机框架材料中的一种或多种,比如浸渍锂盐的硅胶、浸渍锂盐的活性炭纤维毡、PAM水凝胶、海藻酸钠复合凝胶和MIL-101(Cr)。Both the adsorption zone and the regeneration zone of the
碳吸附转轮4的吸附区和再生区都设置有二氧化碳吸附剂,二氧化碳吸附剂为胺多功能化的多孔材料、胺功能化的树脂和金属有机框架材料中的一种或多种,比如聚乙烯亚胺浸渍的硅胶和聚乙烯亚胺浸渍的活性炭纤维毡。Both the adsorption zone and the regeneration zone of the
本发明一种二氧化碳和淡水的捕集系统,吸附风机1、水吸附转轮2、第一冷凝器3、碳吸附转轮4、空气加热器5、第一再生风机6、第二再生风机7和第二冷凝器8之间通过工业通风管道相连接,第二冷凝器8通过ppr热塑管分别连接储水罐7和储气瓶10。The present invention is a carbon dioxide and fresh water capture system, an adsorption fan 1, a
本发明一种二氧化碳和淡水的捕集系统的运行方法包括如下步骤:The operation method of a carbon dioxide and fresh water capture system of the present invention comprises the following steps:
给装置输入电能时,电动机11、风机、空气加热器5开始运行,环境空气被吸附风机1送至所述水吸附转轮2的吸附区,使得环境空气中的水被水吸附剂吸附,空气中的湿度降低,处理后的空气被送至第一冷凝器3。经过第一冷凝器的低温低湿空气,送至碳吸附转轮4的吸附区,使得空气中的碳被二氧化碳吸附剂吸附,处理后的空气被送至空气加热器5。When electrical energy is input to the device, the
在再生过程中,从空气加热器5出来的高温空气,被第一再生风机6引风流过碳吸附转轮4的再生区,加热二氧化碳吸附剂使其解吸出二氧化碳进行再生。处理后的空气被第二再生风机7引风流过水吸附转轮2的再生区,加热水吸附剂使其解吸出水进行再生。之后高碳蒸汽在第二冷凝器8冷凝后流入储水罐9,而二氧化碳被收集存储到储气瓶10。During the regeneration process, the high-temperature air from the
在本发明一种二氧化碳和淡水的捕集系统的运行过程中,水吸附转轮2和碳吸附转轮4工作状况的判断标准是输出给环境的空气中水分和二氧化碳浓度是否低于所要求的值,以及一定时间后储水罐9和储气瓶10中是否收集到水和二氧化碳。During the operation of the carbon dioxide and fresh water capture system of the present invention, the criterion for judging the working conditions of the
上述仅为本发明的优选实施例而已,并不对本发明起到任何限制作用。任何所属技术领域的技术人员,在不脱离本发明的技术方案的范围内,对本发明揭露的技术方案和技术内容做任何形式的等同替换或修改等变动,均属未脱离本发明的技术方案的内容,仍属于本发明的保护范围之内。The above are only preferred embodiments of the present invention, and do not have any limiting effect on the present invention. Any person skilled in the art, within the scope of not departing from the technical solution of the present invention, makes any form of equivalent replacement or modification to the technical solution and technical content disclosed in the present invention, and does not depart from the technical solution of the present invention. content still falls within the protection scope of the present invention.
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