CN103952094B - A kind of paper-plastic package heat-seal adhesive and preparation method thereof - Google Patents
A kind of paper-plastic package heat-seal adhesive and preparation method thereof Download PDFInfo
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- CN103952094B CN103952094B CN201410110235.6A CN201410110235A CN103952094B CN 103952094 B CN103952094 B CN 103952094B CN 201410110235 A CN201410110235 A CN 201410110235A CN 103952094 B CN103952094 B CN 103952094B
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Abstract
A kind of paper-plastic package heat-seal adhesive and preparation method thereof, is characterized in that being made up of the raw material of following weight part: E-12 epoxy resin 12-14, terpine resin 6-8, EVA resin 14-17, ethyl acetate 12-13, N-BUTYL ACETATE 20-23, tributyl citrate 4-6, phenyl-trichloro-silicane 3-4, MALEIC ANHYDRIDE 6-9, propylene glycol 4-6, titanate coupling agent TMC-TTS1-2, cyclohexanone peroxide 1-2,2-amino-2-methyl-1-propanol 7-9, vinyl triamine 3-4, tackifying assistant 4-5.It is reasonable that the present invention packs hot glue formula, and bonding strength is high, color inhibition, water-fast.
Description
Technical field
The present invention relates to a kind of heat-seal adhesive, more particularly, is a kind of paper-plastic package heat-seal adhesive and preparation method thereof.
Background technology
Packaging industry is on a grand scale in China, and during packaging, paper bonding, the bonding of paper paper, ironshaper bonding, all need for packing glue, the problems such as existing packaging heat-seal adhesive exists poisonous dissolvent residual more, and bonding strength is not high.The harmless bonding needs of present packaging can not be met.
Summary of the invention
The object of this invention is to provide a kind of paper-plastic package heat-seal adhesive and preparation method thereof.
The technical solution adopted in the present invention is:
A kind of paper-plastic package heat-seal adhesive, is characterized in that being made up of the raw material of following weight part:
E-12 epoxy resin 12-14, terpine resin 6-8, EVA resin 14-17, ethyl acetate 12-13, N-BUTYL ACETATE 20-23, tributyl citrate 4-6, phenyl-trichloro-silicane 3-4, MALEIC ANHYDRIDE 6-9, propylene glycol 4-6, titanate coupling agent TMC-TTS1-2, cyclohexanone peroxide 1-2,2-amino-2-methyl-1-propanol 7-9, vinyl triamine 3-4, tackifying assistant 4-5.
Described tackifying assistant is obtained by the raw material of following weight part: thermoplastic acrylic resin 3-4, Silane coupling agent KH550 1-2,582-2 aminoresin 3-4, polyisobutene 2-3, N-BUTYL ACETATE 6-8, cobalt naphthenate 0.1-0.2, biscyclo pentadienyl iron 0.4-0.6;
Preparation method is: join in N-BUTYL ACETATE by thermoplastic acrylic resin, 582-2 aminoresin, so enter to add Silane coupling agent KH550, be heated to 90-100 DEG C, stirring reaction 30-40 minute, then polyisobutene, biscyclo pentadienyl iron, cobalt naphthenate is added, stirring reaction 20-40 minute and get final product.
The preparation method of described paper-plastic package heat-seal adhesive, is characterized in that comprising the following steps:
Tributyl citrate, phenyl-trichloro-silicane, MALEIC ANHYDRIDE, propylene glycol, titanate coupling agent TMC-TTS are joined in N-BUTYL ACETATE, add cyclohexanone peroxide, stirring reaction 1-3 hour, continue to be heated to 80-90 DEG C, add 2-amino-2-methyl-1-propanol, tackifying assistant, stirring reaction 1-2 hour, then add other surplus stock, stirring reaction 2-3 hour and get final product.
It is reasonable that the present invention packs hot glue formula, and bonding strength is high, color inhibition, water-fast.
Embodiment
A kind of paper-plastic package heat-seal adhesive, be made up of the raw material of following weight part (kilogram):
E-12 epoxy resin 14, terpine resin 8, EVA resin 17, ethyl acetate 13, N-BUTYL ACETATE 23, tributyl citrate 4, phenyl-trichloro-silicane 4, MALEIC ANHYDRIDE 9, propylene glycol 6, titanate coupling agent TMC-TTS2, cyclohexanone peroxide 2,2-amino-2-methyl-1-propanol 9, vinyl triamine 4, tackifying assistant 5.
Described tackifying assistant is obtained by the raw material of following weight part (kilogram):
Thermoplastic acrylic resin 4, Silane coupling agent KH550 2,582-2 aminoresin 4, polyisobutene 3, N-BUTYL ACETATE 8, cobalt naphthenate 0.2, biscyclo pentadienyl iron 0.6;
Preparation method is: join in N-BUTYL ACETATE by thermoplastic acrylic resin, 582-2 aminoresin, so enter to add Silane coupling agent KH550, be heated to 90-100 DEG C, stirring reaction 30-40 minute, then polyisobutene, biscyclo pentadienyl iron, cobalt naphthenate is added, stirring reaction 20-40 minute and get final product.
The preparation method of paper-plastic package heat-seal adhesive, comprises the following steps:
Tributyl citrate, phenyl-trichloro-silicane, MALEIC ANHYDRIDE, propylene glycol, titanate coupling agent TMC-TTS are joined in N-BUTYL ACETATE, add cyclohexanone peroxide, stirring reaction 1-3 hour, continue to be heated to 80-90 DEG C, add 2-amino-2-methyl-1-propanol, tackifying assistant, stirring reaction 1-2 hour, then add other surplus stock, stirring reaction 2-3 hour and get final product.
The present invention is used for the bonding of paper and plastics film, after 5 hours, adhesive shear strength reaches 12Mpa.
Claims (1)
1. a paper-plastic package heat-seal adhesive, is characterized in that being made up of the raw material of following weight part: E-12 epoxy resin 12-14, terpine resin 6-8, EVA resin 14-17, ethyl acetate 12-13, N-BUTYL ACETATE 20-23, tributyl citrate 4-6, phenyl-trichloro-silicane 3-4, MALEIC ANHYDRIDE 6-9, propylene glycol 4-6, titanate coupling agent TMC-TTS1-2, cyclohexanone peroxide 1-2,2-amino-2-methyl-1-propanol 7-9, diethylenetriamine 3-4, tackifying assistant 4-5;
Described tackifying assistant is obtained by the raw material of following weight part: thermoplastic acrylic resin 3-4, Silane coupling agent KH550 1-2,582-2 aminoresin 3-4, polyisobutene 2-3, N-BUTYL ACETATE 6-8, cobalt naphthenate 0.1-0.2, biscyclo pentadienyl iron 0.4-0.6; The preparation method of described tackifying assistant is: join in N-BUTYL ACETATE by thermoplastic acrylic resin, 582-2 aminoresin, so enter to add Silane coupling agent KH550, be heated to 90-100 DEG C, stirring reaction 30-40 minute, then polyisobutene, biscyclo pentadienyl iron, cobalt naphthenate is added, stirring reaction 20-40 minute and get final product;
The preparation method of described paper-plastic package heat-seal adhesive, comprise the following steps: tributyl citrate, phenyl-trichloro-silicane, MALEIC ANHYDRIDE, propylene glycol, titanate coupling agent TMC-TTS are joined in N-BUTYL ACETATE, add cyclohexanone peroxide, stirring reaction 1-3 hour, continue to be heated to 80-90 DEG C, add 2-amino-2-methyl-1-propanol, tackifying assistant, stirring reaction 1-2 hour, add other surplus stock again, stirring reaction 2-3 hour and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410110235.6A CN103952094B (en) | 2014-03-24 | 2014-03-24 | A kind of paper-plastic package heat-seal adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410110235.6A CN103952094B (en) | 2014-03-24 | 2014-03-24 | A kind of paper-plastic package heat-seal adhesive and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103952094A CN103952094A (en) | 2014-07-30 |
| CN103952094B true CN103952094B (en) | 2016-04-06 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410110235.6A Expired - Fee Related CN103952094B (en) | 2014-03-24 | 2014-03-24 | A kind of paper-plastic package heat-seal adhesive and preparation method thereof |
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| CN (1) | CN103952094B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009516064A (en) * | 2005-11-18 | 2009-04-16 | ゼネラル・エレクトリック・カンパニイ | Polymer blend method, polymer composition, and polymer article |
| CN103468157A (en) * | 2013-09-04 | 2013-12-25 | 杨学荣 | Formaldehyde-free wood adhesive film |
| CN103571375A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Epoxy resin hot melt adhesive |
| CN103571392A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Anti-corrosion hot melt adhesive for automotive upholstery |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040197571A1 (en) * | 2003-04-03 | 2004-10-07 | Yuji Hiroshige | Thermosetting composition, and sealing article and sealing structure using the same |
| JP4900975B2 (en) * | 2005-06-24 | 2012-03-21 | エクソンモービル・ケミカル・パテンツ・インク | Functionalized propylene copolymer adhesive composition |
-
2014
- 2014-03-24 CN CN201410110235.6A patent/CN103952094B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009516064A (en) * | 2005-11-18 | 2009-04-16 | ゼネラル・エレクトリック・カンパニイ | Polymer blend method, polymer composition, and polymer article |
| CN103468157A (en) * | 2013-09-04 | 2013-12-25 | 杨学荣 | Formaldehyde-free wood adhesive film |
| CN103571375A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Epoxy resin hot melt adhesive |
| CN103571392A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Anti-corrosion hot melt adhesive for automotive upholstery |
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| CN103952094A (en) | 2014-07-30 |
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Gao Xintao Inventor before: Hu Wenjin |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180504 Address after: 253200 north side of Shengli Road East of West Ring Road, Xiajin, Dezhou, Shandong Patentee after: Shandong Hongfei Package Co., Ltd. Address before: 244131 Anhui Tongling suburb Anqing copper mine sixteenth middle school Patentee before: Tongling Songma Food Packing Machinery Manufacturing Co., Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160406 Termination date: 20190324 |