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CN109468070A - A kind of carton aldehyde-free cement and preparation method thereof - Google Patents

A kind of carton aldehyde-free cement and preparation method thereof Download PDF

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Publication number
CN109468070A
CN109468070A CN201811437538.3A CN201811437538A CN109468070A CN 109468070 A CN109468070 A CN 109468070A CN 201811437538 A CN201811437538 A CN 201811437538A CN 109468070 A CN109468070 A CN 109468070A
Authority
CN
China
Prior art keywords
parts
pure
aldehyde
carton
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201811437538.3A
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Chinese (zh)
Inventor
王智峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guizhou Zhongwang Packaging Co Ltd
Original Assignee
Guizhou Zhongwang Packaging Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guizhou Zhongwang Packaging Co Ltd filed Critical Guizhou Zhongwang Packaging Co Ltd
Priority to CN201811437538.3A priority Critical patent/CN109468070A/en
Publication of CN109468070A publication Critical patent/CN109468070A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of carton aldehyde-free cements and preparation method thereof, 43-53 parts of the starch comprising parts by weight, 24-28 parts of propylene glycol, 21-25 parts of talcum powder, 17-20 parts of pentaerythrite, 13-15 parts of ethyl acetate, 10-14 parts of pure-acrylic emulsion, 9-11 parts of methyl methacrylate, 8-10 parts of pure acrylic latex, 6-8 parts of sodium metasilicate, 13-19 parts of water.Carton aldehyde-free cement obtained by the present invention, no aldehyde, safety and environmental protection, and adhesive strength is higher, stability is good.

Description

A kind of carton aldehyde-free cement and preparation method thereof
Technical field
The present invention relates to adhesive area, especially a kind of carton aldehyde-free cement and preparation method thereof.
Background technique
Carton, be it is most widely used in current packing articles, can classify according to materials, be divided into corrugated case, Single cardboard box, two ply board case etc., and can according to require formulate different model.With the tide of shopping online, packaging Carton carries at one of indispensable object of logistics links and contains, protects product, beautiful substantial responsibility.
And cardboard is carried out gluing by the adhesive that is made by of carton.Adhesive, also known as " bonding agent ", " bonding Agent " is a kind of substance for playing attached article by surface bonding by adhesion strength and cohesive force.So carton quality by The influence of adhesive quality.Existing adhesive bonding, contains aldehyde, and intensity is low, stability is poor.
Summary of the invention
The object of the present invention is to provide a kind of carton aldehyde-free cement and preparation method thereof, obtained adhesive, Without aldehyde, safety and environmental protection, and adhesive strength are higher, stability is good.
Technical solution of the present invention: a kind of carton aldehyde-free cement, 43-53 parts of the starch comprising parts by weight, propylene glycol 24-28 parts, 21-25 parts of talcum powder, 17-20 parts of pentaerythrite, 13-15 parts of ethyl acetate, 10-14 parts of pure-acrylic emulsion, methyl-prop 9-11 parts of e pioic acid methyl ester, 8-10 parts of pure acrylic latex, 6-8 parts of sodium metasilicate, 13-19 parts of water.
Preferably, carton aldehyde-free cement above-mentioned, 48-52 parts of the starch comprising parts by weight, 25-27 parts of propylene glycol, 22-24 parts of talcum powder, 18-19 parts of pentaerythrite, 13-15 parts of ethyl acetate, 12-13 parts of pure-acrylic emulsion, methyl methacrylate 10-11 parts, 9-10 parts of pure acrylic latex, 6-7 parts of sodium metasilicate, 15-17 parts of water.
Preferably, carton aldehyde-free cement above-mentioned, 48 parts of the starch comprising parts by weight, 26 parts of propylene glycol, talcum powder 23 parts, 18 parts of pentaerythrite, 14 parts of ethyl acetate, 12 parts of pure-acrylic emulsion, 10 parts of methyl methacrylate, pure acrylic latex 9 Part, 7 parts of sodium metasilicate, 16 parts of water.
The preparation method of carton aldehyde-free cement above-mentioned, step include:
A: the starch of the parts by weight is mixed with water, is then heated to 80-90 DEG C, and is passed through nitrogen and is bubbled 45- 55min obtains A product;
B: propylene glycol, talcum powder, pentaerythrite, ethyl acetate, pure-acrylic emulsion, the first of the parts by weight are added in the A product Base methyl acrylate, pure acrylic latex, sodium metasilicate, are heated to 75-85 DEG C, be uniformly mixed to get.
Compared with prior art, the present invention is closed by materials such as combination starch, propylene glycol, talcum powder, pentaerythrites The adjustment of reason ratio and preparation method adjustment, make obtained adhesive without aldehyde, safety and environmental protection, and adhesive strength is higher, steady It is qualitative good.
Specific embodiment
For a better understanding of the present invention, below by embodiment, the present invention is further described, and embodiment is served only for explaining The present invention will not constitute any restriction to the present invention.
Embodiment 1:
A kind of carton aldehyde-free cement, 43 parts of the starch comprising parts by weight, 24 parts of propylene glycol, 21 parts of talcum powder, pentaerythrite 17 parts, 13 parts of ethyl acetate, 10 parts of pure-acrylic emulsion, 9 parts of methyl methacrylate, 8 parts of pure acrylic latex, 6 parts of sodium metasilicate, 13 parts of water.
The preparation method of above-mentioned carton aldehyde-free cement, step include:
A: the starch of the parts by weight is mixed with water, is then heated to 80 DEG C, and is passed through nitrogen and is bubbled 45min, and A is obtained Product;
B: propylene glycol, talcum powder, pentaerythrite, ethyl acetate, pure-acrylic emulsion, the first of the parts by weight are added in the A product Base methyl acrylate, pure acrylic latex, sodium metasilicate are heated to 75 DEG C, be uniformly mixed to get.
Embodiment 2:
A kind of carton aldehyde-free cement, 53 parts of the starch comprising parts by weight, 28 parts of propylene glycol, 25 parts of talcum powder, pentaerythrite 20 parts, 15 parts of ethyl acetate, 14 parts of pure-acrylic emulsion, 11 parts of methyl methacrylate, 10 parts of pure acrylic latex, sodium metasilicate 8 Part, 19 parts of water.
The preparation method of above-mentioned carton aldehyde-free cement, step include:
A: the starch of the parts by weight is mixed with water, is then heated to 90 DEG C, and is passed through nitrogen and is bubbled 55min, and A is obtained Product;
B: propylene glycol, talcum powder, pentaerythrite, ethyl acetate, pure-acrylic emulsion, the first of the parts by weight are added in the A product Base methyl acrylate, pure acrylic latex, sodium metasilicate are heated to 85 DEG C, be uniformly mixed to get.
Embodiment 3:
A kind of carton aldehyde-free cement, 48 parts of the starch comprising parts by weight, 25 parts of propylene glycol, 22 parts of talcum powder, pentaerythrite 18 parts, 13 parts of ethyl acetate, 12 parts of pure-acrylic emulsion, 10 parts of methyl methacrylate, 9 parts of pure acrylic latex, sodium metasilicate 6 Part, 15 parts of water.
The preparation method of above-mentioned carton aldehyde-free cement, step include:
A: the starch of the parts by weight is mixed with water, is then heated to 83 DEG C, and is passed through nitrogen and is bubbled 47min, and A is obtained Product;
B: propylene glycol, talcum powder, pentaerythrite, ethyl acetate, pure-acrylic emulsion, the first of the parts by weight are added in the A product Base methyl acrylate, pure acrylic latex, sodium metasilicate are heated to 78 DEG C, be uniformly mixed to get.
Embodiment 4:
A kind of carton aldehyde-free cement, 52 parts of the starch comprising parts by weight, 27 parts of propylene glycol, 24 parts of talcum powder, pentaerythrite 19 parts, 15 parts of ethyl acetate, 13 parts of pure-acrylic emulsion, 11 parts of methyl methacrylate, 10 parts of pure acrylic latex, sodium metasilicate 7 Part, 17 parts of water.
The preparation method of above-mentioned carton aldehyde-free cement, step include:
A: the starch of the parts by weight is mixed with water, is then heated to 87 DEG C, and is passed through nitrogen and is bubbled 51min, and A is obtained Product;
B: propylene glycol, talcum powder, pentaerythrite, ethyl acetate, pure-acrylic emulsion, the first of the parts by weight are added in the A product Base methyl acrylate, pure acrylic latex, sodium metasilicate are heated to 82 DEG C, be uniformly mixed to get.
Embodiment 5:
A kind of carton aldehyde-free cement, 48 parts of the starch comprising parts by weight, 26 parts of propylene glycol, 23 parts of talcum powder, pentaerythrite 18 parts, 14 parts of ethyl acetate, 12 parts of pure-acrylic emulsion, 10 parts of methyl methacrylate, 9 parts of pure acrylic latex, sodium metasilicate 7 Part, 16 parts of water.
The preparation method of above-mentioned carton aldehyde-free cement, step include:
A: the starch of the parts by weight is mixed with water, is then heated to 85 DEG C, and is passed through nitrogen and is bubbled 50min, and A is obtained Product;
B: propylene glycol, talcum powder, pentaerythrite, ethyl acetate, pure-acrylic emulsion, the first of the parts by weight are added in the A product Base methyl acrylate, pure acrylic latex, sodium metasilicate are heated to 80 DEG C, be uniformly mixed to get.

Claims (4)

1. a kind of carton aldehyde-free cement, it is characterised in that: 43-53 parts of the starch comprising parts by weight, 24-28 parts of propylene glycol, 21-25 parts of talcum powder, 17-20 parts of pentaerythrite, 13-15 parts of ethyl acetate, 10-14 parts of pure-acrylic emulsion, methyl methacrylate 9-11 parts, 8-10 parts of pure acrylic latex, 6-8 parts of sodium metasilicate, 13-19 parts of water.
2. carton aldehyde-free cement according to claim 1, it is characterised in that: 48-52 parts of the starch comprising parts by weight, 25-27 parts of propylene glycol, 22-24 parts of talcum powder, 18-19 parts of pentaerythrite, 13-15 parts of ethyl acetate, 12-13 parts of pure-acrylic emulsion, 10-11 parts of methyl methacrylate, 9-10 parts of pure acrylic latex, 6-7 parts of sodium metasilicate, 15-17 parts of water.
3. carton aldehyde-free cement according to claim 1, it is characterised in that: 48 parts of the starch comprising parts by weight, third 26 parts of glycol, 23 parts of talcum powder, 18 parts of pentaerythrite, 14 parts of ethyl acetate, 12 parts of pure-acrylic emulsion, methyl methacrylate 10 Part, 9 parts of pure acrylic latex, 7 parts of sodium metasilicate, 16 parts of water.
4. the preparation method of carton aldehyde-free cement described in any one of -3 according to claim 1, it is characterised in that: step Suddenly include:
A: the starch of the parts by weight is mixed with water, is then heated to 80-90 DEG C, and is passed through nitrogen and is bubbled 45- 55min obtains A product;
B: propylene glycol, talcum powder, pentaerythrite, ethyl acetate, pure-acrylic emulsion, the first of the parts by weight are added in the A product Base methyl acrylate, pure acrylic latex, sodium metasilicate, are heated to 75-85 DEG C, be uniformly mixed to get.
CN201811437538.3A 2018-11-28 2018-11-28 A kind of carton aldehyde-free cement and preparation method thereof Withdrawn CN109468070A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811437538.3A CN109468070A (en) 2018-11-28 2018-11-28 A kind of carton aldehyde-free cement and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811437538.3A CN109468070A (en) 2018-11-28 2018-11-28 A kind of carton aldehyde-free cement and preparation method thereof

Publications (1)

Publication Number Publication Date
CN109468070A true CN109468070A (en) 2019-03-15

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CN (1) CN109468070A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103360988A (en) * 2013-07-05 2013-10-23 全椒海丰印刷包装有限公司 Carton environment-friendly formaldehyde-free adhesive and preparation method thereof
CN103666326A (en) * 2013-11-29 2014-03-26 汤颖锴 Quick-drying carton adhesive
CN104327787A (en) * 2014-11-11 2015-02-04 句容市茂源织造厂 Carton processing adhesive
CN106336850A (en) * 2016-06-17 2017-01-18 临泉县亚泰包装有限公司 Environmentally-friendly non-formaldehyde carton adhesive and preparation method thereof
CN108753203A (en) * 2018-07-16 2018-11-06 苏州震嵘包装有限公司 A kind of Carton environment-friendlyformaldehyde-free formaldehyde-free adhesive

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103360988A (en) * 2013-07-05 2013-10-23 全椒海丰印刷包装有限公司 Carton environment-friendly formaldehyde-free adhesive and preparation method thereof
CN103666326A (en) * 2013-11-29 2014-03-26 汤颖锴 Quick-drying carton adhesive
CN104327787A (en) * 2014-11-11 2015-02-04 句容市茂源织造厂 Carton processing adhesive
CN106336850A (en) * 2016-06-17 2017-01-18 临泉县亚泰包装有限公司 Environmentally-friendly non-formaldehyde carton adhesive and preparation method thereof
CN108753203A (en) * 2018-07-16 2018-11-06 苏州震嵘包装有限公司 A kind of Carton environment-friendlyformaldehyde-free formaldehyde-free adhesive

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Application publication date: 20190315