CN109468070A - A kind of carton aldehyde-free cement and preparation method thereof - Google Patents
A kind of carton aldehyde-free cement and preparation method thereof Download PDFInfo
- Publication number
- CN109468070A CN109468070A CN201811437538.3A CN201811437538A CN109468070A CN 109468070 A CN109468070 A CN 109468070A CN 201811437538 A CN201811437538 A CN 201811437538A CN 109468070 A CN109468070 A CN 109468070A
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- Prior art keywords
- parts
- pure
- aldehyde
- carton
- weight
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a kind of carton aldehyde-free cements and preparation method thereof, 43-53 parts of the starch comprising parts by weight, 24-28 parts of propylene glycol, 21-25 parts of talcum powder, 17-20 parts of pentaerythrite, 13-15 parts of ethyl acetate, 10-14 parts of pure-acrylic emulsion, 9-11 parts of methyl methacrylate, 8-10 parts of pure acrylic latex, 6-8 parts of sodium metasilicate, 13-19 parts of water.Carton aldehyde-free cement obtained by the present invention, no aldehyde, safety and environmental protection, and adhesive strength is higher, stability is good.
Description
Technical field
The present invention relates to adhesive area, especially a kind of carton aldehyde-free cement and preparation method thereof.
Background technique
Carton, be it is most widely used in current packing articles, can classify according to materials, be divided into corrugated case,
Single cardboard box, two ply board case etc., and can according to require formulate different model.With the tide of shopping online, packaging
Carton carries at one of indispensable object of logistics links and contains, protects product, beautiful substantial responsibility.
And cardboard is carried out gluing by the adhesive that is made by of carton.Adhesive, also known as " bonding agent ", " bonding
Agent " is a kind of substance for playing attached article by surface bonding by adhesion strength and cohesive force.So carton quality by
The influence of adhesive quality.Existing adhesive bonding, contains aldehyde, and intensity is low, stability is poor.
Summary of the invention
The object of the present invention is to provide a kind of carton aldehyde-free cement and preparation method thereof, obtained adhesive,
Without aldehyde, safety and environmental protection, and adhesive strength are higher, stability is good.
Technical solution of the present invention: a kind of carton aldehyde-free cement, 43-53 parts of the starch comprising parts by weight, propylene glycol
24-28 parts, 21-25 parts of talcum powder, 17-20 parts of pentaerythrite, 13-15 parts of ethyl acetate, 10-14 parts of pure-acrylic emulsion, methyl-prop
9-11 parts of e pioic acid methyl ester, 8-10 parts of pure acrylic latex, 6-8 parts of sodium metasilicate, 13-19 parts of water.
Preferably, carton aldehyde-free cement above-mentioned, 48-52 parts of the starch comprising parts by weight, 25-27 parts of propylene glycol,
22-24 parts of talcum powder, 18-19 parts of pentaerythrite, 13-15 parts of ethyl acetate, 12-13 parts of pure-acrylic emulsion, methyl methacrylate
10-11 parts, 9-10 parts of pure acrylic latex, 6-7 parts of sodium metasilicate, 15-17 parts of water.
Preferably, carton aldehyde-free cement above-mentioned, 48 parts of the starch comprising parts by weight, 26 parts of propylene glycol, talcum powder
23 parts, 18 parts of pentaerythrite, 14 parts of ethyl acetate, 12 parts of pure-acrylic emulsion, 10 parts of methyl methacrylate, pure acrylic latex 9
Part, 7 parts of sodium metasilicate, 16 parts of water.
The preparation method of carton aldehyde-free cement above-mentioned, step include:
A: the starch of the parts by weight is mixed with water, is then heated to 80-90 DEG C, and is passed through nitrogen and is bubbled 45-
55min obtains A product;
B: propylene glycol, talcum powder, pentaerythrite, ethyl acetate, pure-acrylic emulsion, the first of the parts by weight are added in the A product
Base methyl acrylate, pure acrylic latex, sodium metasilicate, are heated to 75-85 DEG C, be uniformly mixed to get.
Compared with prior art, the present invention is closed by materials such as combination starch, propylene glycol, talcum powder, pentaerythrites
The adjustment of reason ratio and preparation method adjustment, make obtained adhesive without aldehyde, safety and environmental protection, and adhesive strength is higher, steady
It is qualitative good.
Specific embodiment
For a better understanding of the present invention, below by embodiment, the present invention is further described, and embodiment is served only for explaining
The present invention will not constitute any restriction to the present invention.
Embodiment 1:
A kind of carton aldehyde-free cement, 43 parts of the starch comprising parts by weight, 24 parts of propylene glycol, 21 parts of talcum powder, pentaerythrite
17 parts, 13 parts of ethyl acetate, 10 parts of pure-acrylic emulsion, 9 parts of methyl methacrylate, 8 parts of pure acrylic latex, 6 parts of sodium metasilicate,
13 parts of water.
The preparation method of above-mentioned carton aldehyde-free cement, step include:
A: the starch of the parts by weight is mixed with water, is then heated to 80 DEG C, and is passed through nitrogen and is bubbled 45min, and A is obtained
Product;
B: propylene glycol, talcum powder, pentaerythrite, ethyl acetate, pure-acrylic emulsion, the first of the parts by weight are added in the A product
Base methyl acrylate, pure acrylic latex, sodium metasilicate are heated to 75 DEG C, be uniformly mixed to get.
Embodiment 2:
A kind of carton aldehyde-free cement, 53 parts of the starch comprising parts by weight, 28 parts of propylene glycol, 25 parts of talcum powder, pentaerythrite
20 parts, 15 parts of ethyl acetate, 14 parts of pure-acrylic emulsion, 11 parts of methyl methacrylate, 10 parts of pure acrylic latex, sodium metasilicate 8
Part, 19 parts of water.
The preparation method of above-mentioned carton aldehyde-free cement, step include:
A: the starch of the parts by weight is mixed with water, is then heated to 90 DEG C, and is passed through nitrogen and is bubbled 55min, and A is obtained
Product;
B: propylene glycol, talcum powder, pentaerythrite, ethyl acetate, pure-acrylic emulsion, the first of the parts by weight are added in the A product
Base methyl acrylate, pure acrylic latex, sodium metasilicate are heated to 85 DEG C, be uniformly mixed to get.
Embodiment 3:
A kind of carton aldehyde-free cement, 48 parts of the starch comprising parts by weight, 25 parts of propylene glycol, 22 parts of talcum powder, pentaerythrite
18 parts, 13 parts of ethyl acetate, 12 parts of pure-acrylic emulsion, 10 parts of methyl methacrylate, 9 parts of pure acrylic latex, sodium metasilicate 6
Part, 15 parts of water.
The preparation method of above-mentioned carton aldehyde-free cement, step include:
A: the starch of the parts by weight is mixed with water, is then heated to 83 DEG C, and is passed through nitrogen and is bubbled 47min, and A is obtained
Product;
B: propylene glycol, talcum powder, pentaerythrite, ethyl acetate, pure-acrylic emulsion, the first of the parts by weight are added in the A product
Base methyl acrylate, pure acrylic latex, sodium metasilicate are heated to 78 DEG C, be uniformly mixed to get.
Embodiment 4:
A kind of carton aldehyde-free cement, 52 parts of the starch comprising parts by weight, 27 parts of propylene glycol, 24 parts of talcum powder, pentaerythrite
19 parts, 15 parts of ethyl acetate, 13 parts of pure-acrylic emulsion, 11 parts of methyl methacrylate, 10 parts of pure acrylic latex, sodium metasilicate 7
Part, 17 parts of water.
The preparation method of above-mentioned carton aldehyde-free cement, step include:
A: the starch of the parts by weight is mixed with water, is then heated to 87 DEG C, and is passed through nitrogen and is bubbled 51min, and A is obtained
Product;
B: propylene glycol, talcum powder, pentaerythrite, ethyl acetate, pure-acrylic emulsion, the first of the parts by weight are added in the A product
Base methyl acrylate, pure acrylic latex, sodium metasilicate are heated to 82 DEG C, be uniformly mixed to get.
Embodiment 5:
A kind of carton aldehyde-free cement, 48 parts of the starch comprising parts by weight, 26 parts of propylene glycol, 23 parts of talcum powder, pentaerythrite
18 parts, 14 parts of ethyl acetate, 12 parts of pure-acrylic emulsion, 10 parts of methyl methacrylate, 9 parts of pure acrylic latex, sodium metasilicate 7
Part, 16 parts of water.
The preparation method of above-mentioned carton aldehyde-free cement, step include:
A: the starch of the parts by weight is mixed with water, is then heated to 85 DEG C, and is passed through nitrogen and is bubbled 50min, and A is obtained
Product;
B: propylene glycol, talcum powder, pentaerythrite, ethyl acetate, pure-acrylic emulsion, the first of the parts by weight are added in the A product
Base methyl acrylate, pure acrylic latex, sodium metasilicate are heated to 80 DEG C, be uniformly mixed to get.
Claims (4)
1. a kind of carton aldehyde-free cement, it is characterised in that: 43-53 parts of the starch comprising parts by weight, 24-28 parts of propylene glycol,
21-25 parts of talcum powder, 17-20 parts of pentaerythrite, 13-15 parts of ethyl acetate, 10-14 parts of pure-acrylic emulsion, methyl methacrylate
9-11 parts, 8-10 parts of pure acrylic latex, 6-8 parts of sodium metasilicate, 13-19 parts of water.
2. carton aldehyde-free cement according to claim 1, it is characterised in that: 48-52 parts of the starch comprising parts by weight,
25-27 parts of propylene glycol, 22-24 parts of talcum powder, 18-19 parts of pentaerythrite, 13-15 parts of ethyl acetate, 12-13 parts of pure-acrylic emulsion,
10-11 parts of methyl methacrylate, 9-10 parts of pure acrylic latex, 6-7 parts of sodium metasilicate, 15-17 parts of water.
3. carton aldehyde-free cement according to claim 1, it is characterised in that: 48 parts of the starch comprising parts by weight, third
26 parts of glycol, 23 parts of talcum powder, 18 parts of pentaerythrite, 14 parts of ethyl acetate, 12 parts of pure-acrylic emulsion, methyl methacrylate 10
Part, 9 parts of pure acrylic latex, 7 parts of sodium metasilicate, 16 parts of water.
4. the preparation method of carton aldehyde-free cement described in any one of -3 according to claim 1, it is characterised in that: step
Suddenly include:
A: the starch of the parts by weight is mixed with water, is then heated to 80-90 DEG C, and is passed through nitrogen and is bubbled 45-
55min obtains A product;
B: propylene glycol, talcum powder, pentaerythrite, ethyl acetate, pure-acrylic emulsion, the first of the parts by weight are added in the A product
Base methyl acrylate, pure acrylic latex, sodium metasilicate, are heated to 75-85 DEG C, be uniformly mixed to get.
Priority Applications (1)
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CN201811437538.3A CN109468070A (en) | 2018-11-28 | 2018-11-28 | A kind of carton aldehyde-free cement and preparation method thereof |
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CN201811437538.3A CN109468070A (en) | 2018-11-28 | 2018-11-28 | A kind of carton aldehyde-free cement and preparation method thereof |
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CN109468070A true CN109468070A (en) | 2019-03-15 |
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CN201811437538.3A Withdrawn CN109468070A (en) | 2018-11-28 | 2018-11-28 | A kind of carton aldehyde-free cement and preparation method thereof |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103360988A (en) * | 2013-07-05 | 2013-10-23 | 全椒海丰印刷包装有限公司 | Carton environment-friendly formaldehyde-free adhesive and preparation method thereof |
CN103666326A (en) * | 2013-11-29 | 2014-03-26 | 汤颖锴 | Quick-drying carton adhesive |
CN104327787A (en) * | 2014-11-11 | 2015-02-04 | 句容市茂源织造厂 | Carton processing adhesive |
CN106336850A (en) * | 2016-06-17 | 2017-01-18 | 临泉县亚泰包装有限公司 | Environmentally-friendly non-formaldehyde carton adhesive and preparation method thereof |
CN108753203A (en) * | 2018-07-16 | 2018-11-06 | 苏州震嵘包装有限公司 | A kind of Carton environment-friendlyformaldehyde-free formaldehyde-free adhesive |
-
2018
- 2018-11-28 CN CN201811437538.3A patent/CN109468070A/en not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103360988A (en) * | 2013-07-05 | 2013-10-23 | 全椒海丰印刷包装有限公司 | Carton environment-friendly formaldehyde-free adhesive and preparation method thereof |
CN103666326A (en) * | 2013-11-29 | 2014-03-26 | 汤颖锴 | Quick-drying carton adhesive |
CN104327787A (en) * | 2014-11-11 | 2015-02-04 | 句容市茂源织造厂 | Carton processing adhesive |
CN106336850A (en) * | 2016-06-17 | 2017-01-18 | 临泉县亚泰包装有限公司 | Environmentally-friendly non-formaldehyde carton adhesive and preparation method thereof |
CN108753203A (en) * | 2018-07-16 | 2018-11-06 | 苏州震嵘包装有限公司 | A kind of Carton environment-friendlyformaldehyde-free formaldehyde-free adhesive |
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Application publication date: 20190315 |