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CN102191694B - Environmentally-friendly machine-printed rubber adhesive used for embossing on textile coating as well as preparation method and application thereof - Google Patents

Environmentally-friendly machine-printed rubber adhesive used for embossing on textile coating as well as preparation method and application thereof Download PDF

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Publication number
CN102191694B
CN102191694B CN2011100682740A CN201110068274A CN102191694B CN 102191694 B CN102191694 B CN 102191694B CN 2011100682740 A CN2011100682740 A CN 2011100682740A CN 201110068274 A CN201110068274 A CN 201110068274A CN 102191694 B CN102191694 B CN 102191694B
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machine
parts
stamp
rubber cement
textile coating
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CN102191694A (en
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张琴
吴敏
林秋汶
黎永铭
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Guangzhou Huigu New Materials Technology Co ltd
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HUIGU CHEMCIAL CO Ltd GUANGZHOU
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Abstract

The invention discloses an environmentally-friendly machine-printed rubber adhesive used for embossing on a textile coating as well as a preparation method and application thereof. The preparation method of the machine-printed rubber adhesive comprises the following steps: (1) adding 2-10 parts of water and 0.5-2 parts of wet dispersing agent into 60-75 parts of binding agent, and evenly stirring; (2) keeping stirring, adding 0-18 parts of titanium dioxide and 3-5 parts of delustering agent into an emulsion, and stirring for 5-15 minutes; (3) adding 0.2-0.5 part of defoaming agent, stirring for 3-5 minutes, adding 6-8 parts of anti net clogging agent after the mixture is completely defoamed, and stirring for 1-3 minutes; (4) adding 1-3 parts of thickening agent, and continuing to stir for 5-10 minutes; and (5) discharging after the obtained product is ground for 1-2 times, thus obtaining the machine-printed rubber adhesive used for embossing on the textile coating. The machine-printed rubber adhesive disclosed by the invention has the characteristics of safety, environmental friendliness, good embossing effect, soft embossed coating after being completely dried and good fastness and small possibility of clogging the net when embossing is continuously carried out on a full-automatic embossing machine.

Description

Environment-friendly type textile coating stamp is with machine seal rubber cement and preparation method thereof and application
Technical field
The present invention relates to the serigraphy field, be specifically related to a kind of environment-friendly type textile coating stamp with machine seal rubber cement and preparation method thereof and application.
Background technology
The textile coating stamp is to utilize silk screen printing technology, is film forming matter with macromolecular compound (adhesive), will not have compatibility and reactive pigment to stick to the printing technology that obtains required colour image on the fabric to fabric.Because the printing image clear-cut, chromatogram is complete, colorant match is easy, to the fiber non-selectivity; Be fit to various fabrics and BLENDED FABRIC; Simultaneously its operation simple, need not to evaporate and wash, meet the environmental requirement of energy-saving and emission-reduction, COAT PRINTING obtains industry approval and application more and more widely.
At present, the printing in textiles coating in the industry mainly divides the impression of the hand rubber cement of heat-set ink, water-based and machine to print three kinds of rubber cements.Though heat-set ink is applicable to impression of the hand and machine stamp; But; Because not environmental protection of traditional heat-set ink; Novel green thermosetting ink at present its technology is still immature, and the existing product type is single and cost an arm and a leg on the market, and the main raw material produced as printing in textiles with the water-based stamp rubber cement of environmental protection is still selected by current domestic most stamp enterprise.And common impression of the hand rubber cement is owing to exist in the printing process moisture evaporation fast; Very easily rapid draing when the China ink layer is very thin; Especially in hot day or high-temperature work environment, there is the problem that is prone to the plug net, thereby can't directly applies in the machine stamp, be only applicable to traditional long table manual work and run the format printing.By contrast; The mode of production of the machine seal machine stamp that rubber cement was suitable for has the efficient height, precision is high, printing quality is stable, occupation of land is than advantages such as manual machine are little, save labour turnover; Therefore, the textile coating stamp will increase along with the expansion in stamp market with the market demand of machine seal rubber cement.
But; Opposed with this trend; Machine seal rubber cement on the current domestic market; Its quality and performance be all not as American-European, Japanese like product, in order to take into account properties of product and production cost, has many domestic stamps enterprise more to be ready to select to use the machine seal rubber cement of external as Japan and carry out the machine stamp again after homemade impression of the hand rubber cement mixes.Simultaneously, at present domestic also still the nonwoven webs COAT PRINTING with the related patent U.S. Patent No. report of machine seal rubber cement aspect.
Summary of the invention
The shortcoming that primary and foremost purpose of the present invention is to overcome prior art provides a kind of environmental protection, the difficult machine seal rubber cement of netting, can be used for the textile coating stamp of filling in not enough.
Another object of the present invention is to provide the preparation method of above-mentioned machine seal rubber cement.
A purpose more of the present invention is to provide the application of above-mentioned machine seal rubber cement.
The object of the invention is realized through following technical proposals:
A kind of environment-friendly type textile coating stamp prints rubber cement with machine, is prepared by the composition of following weight portion:
Figure BDA0000051329800000021
Said adhesive is a kind of in 55~60% polyacrylate dispersion or the aqueous polyurethane emulsion for not containing polyethenoxy ether class (APEO) material, formaldehydeless release, solid content;
The preferred deionized water of said water, its effect are to regulate the final finished product solid content of contrivance;
Said titanium white powder is a kind of in rutile type titanium white or the anatase thpe white powder;
Said delustering agent is a kind of in micro mist wax, micron order aeroge or the micron order precipitated silica;
Said wetting dispersing agent is a kind of in PPG, polyacrylate (like the Dispers 735W of TEGO), polyacrylamide, polyacrylate (like the Dispers 715W of TEGO) or the long chain type derivative of fatty acid (the Dispers 740W of TEGO);
Said antifoaming agent is a kind of in fatty acid metal soap, fatty acid ester, fatty acid amide, dimethyl silicone polymer or the polyether-modified polysiloxanes (like the BYK-321 of German Bi Ke);
Said antifouling net agent is a kind of in ethylene glycol, propylene glycol, butanediol, sorbierite, glycerine, urea, polyethylene glycol or the polypropylene glycol;
Said thickener is more than one mixtures in polyacrylate (like the Viscalex HV-30 of Ciba), modified polypropene hydrochlorate (like the Acrysol ASE-60 of Rohm&haas) or the hydrophobically modified ethyoxyl polyurethane (like the Acrysol RM-895 of Rohm&haas).
Above-mentioned environment-friendly type textile coating stamp may further comprise the steps with the preparation method of machine seal rubber cement:
(1) in 60~75 parts of adhesives, adds 2~10 parts of water and 0.5~2 part of wetting dispersing agent, stir;
(2) keeping under the state that stirs 0~18 part of titanium white powder and 3~5 parts of delustering agents (transparent rubber cement only has delustering agent) slowly being sneaked in the emulsion pick up speed stirring 5~15 minutes;
(3) reduce mixing speed and add 0.2~0.5 part of antifoaming agent, stirred 3~5 minutes; After treating that froth breaking fully, add 6~8 parts of antifouling net agent, stirred 1~3 minute;
(4) according to the viscosity requirement of rubber cement, add 1~3 part of thickener, continue to stir 5~10 minutes;
(5) grind 1~2 time after discharging, promptly make and be used for the textile coating stamp and print rubber cement with machine;
Said umber is a weight portion.
Environment-friendly type textile coating stamp of the present invention is white in color/the oyster white pastel with machine seal rubber cement, brookfield viscosity 150000-220000cPs, pH value 6.5-7.5 (according to GB/T 7573-2009 test); Content of formaldehyde is lower than 20ppm (according to ISO 14184-1 test); Stamp was not filled in net at least 4 hours continuously on full-automatic decorating machine, was applicable to the realization of the various graphical effects of textile coating stamp on the material fabrics such as cotton, terylene, but through 1-2 minute bone dry of 140 ℃ of bakings; Clear, soft, the good springiness of gained coating flower shape; COLOR FASTNESS (according to GB/T 5713-1997 test color fastness to water, according to GB/T 3922-1995 test acid and alkali-resistance PERSPIRATION COLOR FASTNESS, is tested anti-dried wet friction COLOR FASTNESS according to GB/T 3920-2008) more than the 3-4 level; 60 ℃ of washing 400-800min flower types keep clear, do not come off, ftracture.
Above-mentioned environment-friendly type textile coating stamp can be used on continuous stamp on the full-automatic decorating machine with machine seal rubber cement.
The present invention has following advantage and effect with respect to prior art
The environment-friendly type textile coating stamp that the present invention prepares prints rubber cement with machine; Than traditional heat-set ink and impression of the hand rubber cement, good with safety and environmental protection, printing quality, on full-automatic decorating machine, be difficult for the characteristics that printing coating is soft, fastness is good behind plug net, the bone dry continuously during stamp.
The specific embodiment
Below in conjunction with embodiment the present invention is described in further detail, but embodiment of the present invention is not limited thereto.
Embodiment 1
The composition of machine seal rubber cement is as follows: (by weight)
Figure BDA0000051329800000031
The preparation method of above-mentioned machine seal PVA glue: in 65 parts of solid contents are 55% polyacrylate dispersion; Add 2 parts of deionized waters and 2 parts of polyacrylate (the Dispers 735W of TEGO); Stir; And under keeping stirring, 18 parts of rutile type titanium whites and 5 parts of micro mist waxes are slowly sneaked in the emulsion back high-speed stirred 10 minutes; Reduce mixing speed, slowly splash into 0.2 part of fatty acid ester and continue and slowly stirred 4 minutes; Add 6 parts of sorbierites, continue to stir 3 minutes; According to the viscosity requirement of rubber cement, add 2 parts of polyacrylates (the Viscalex HV-30 of Ciba), continue to stir 5 minutes; Discharging after using three-roller to grind 1~2 time promptly makes and is used for the textile coating stamp and prints PVA glue with machine.
Machine that present embodiment the prepares seal PVA glue outward appearance pastel that is white in color; Brookfield viscosity 180000-220000cPs, pH value 6.5-7.5 (according to GB/T 7573-2009 test), content of formaldehyde are lower than 20ppm (according to ISO 14184-1 test); Stamp was not filled in net at least in 4 hours continuously on full-automatic decorating machine; But through 1-2 minute bone dry of 140 ℃ of bakings, clear, soft, the good springiness of gained coating flower shape on material fabrics such as cotton, terylene, COLOR FASTNESS (is tested color fastness to water according to GB/T 5713-1997 more than the 3-4 level; According to GB/T3922-1995 test acid and alkali-resistance PERSPIRATION COLOR FASTNESS; Test anti-dried wet friction COLOR FASTNESS according to GB/T 3920-2008), 60 ℃ of washing 800min flower types keep clear, do not come off, ftracture.
Embodiment 2
The composition of machine seal rubber cement is as follows: (by weight)
Figure BDA0000051329800000041
The preparation method of above-mentioned machine seal PVA glue: in 60 parts of solid contents are 60% aqueous polyurethane emulsion; Add 8 parts of deionized waters and 1.5 parts of long chain type derivative of fatty acid (the Dispers 740W of TEGO); Stir; And under keeping stirring, 10 parts of anatase thpe white powders and 3 parts of micron order aeroges are slowly sneaked in the emulsion back high-speed stirred 15 minutes; Reduce mixing speed, slowly splash into 0.5 part of dimethyl silicone polymer and continue and slowly stirred 5 minutes; Add 8 parts of glycerine, continue to stir 1 minute; According to the viscosity requirement of rubber cement, add 0.5 part of polyacrylate (the Viscalex HV-30 of Ciba) and 0.5 part of hydrophobically modified ethyoxyl polyurethane, continue to stir 10 minutes; Discharging after using three-roller to grind 1~2 time promptly makes and is used for the textile coating stamp and prints PVA glue with machine.
Machine that present embodiment the prepares seal PVA glue outward appearance pastel that is white in color; Brookfield viscosity 180000-220000cPs, pH value 6.5-7.5 (according to GB/T 7573-2009 test), content of formaldehyde are lower than 20ppm (according to ISO 14184-1 test); Stamp was not filled in net at least in 4 hours continuously on full-automatic decorating machine; But through 1-2 minute bone dry of 140 ℃ of bakings, clear, soft, the good springiness of gained coating flower shape on material fabrics such as cotton, terylene, COLOR FASTNESS (is tested color fastness to water according to GB/T 5713-1997 more than the 3-4 level; According to GB/T3922-1995 test acid and alkali-resistance PERSPIRATION COLOR FASTNESS; Test anti-dried wet friction COLOR FASTNESS according to GB/T 3920-2008), 60 ℃ of washing 400min flower types keep clear, do not come off, ftracture.
Embodiment 3
The composition of machine seal rubber cement is as follows: (by weight)
Figure BDA0000051329800000051
The preparation method of above-mentioned machine printthrough gelatine size: in 75 parts of solid contents are 55% polyacrylate dispersion; Add 10 parts of deionized waters and 0.5 part of long chain type derivative of fatty acid (the Dispers 740W of TEGO); Stir; And under keeping stirring, 5 parts of micron order precipitated silicas are slowly sneaked in the emulsion back high-speed stirred 5 minutes; Reduce mixing speed, slowly splash into 0.4 part of fatty acid amide and continue and slowly stirred 3 minutes; Add 6 parts of polypropylene glycols, continue to stir 2 minutes; According to the viscosity requirement of rubber cement, add 3 parts of polyacrylates (the Viscalex HV-30 of Ciba), continue to stir 8 minutes; Discharging after using three-roller to grind 1 time promptly makes and is used for the textile coating stamp with machine printthrough gelatine size.
The machine printthrough gelatine size outward appearance that present embodiment the prepares translucent pastel that is creamy white, brookfield viscosity 150000-180000cPs, pH value 6.5-7.5 (according to GB/T 7573-2009 test); Content of formaldehyde is lower than 20ppm (according to ISO 14184-1 test); Can be separately or with uses that proportion of machine seal PVA glue, look kind, stamp was not filled in net at least in 4 hours continuously on full-automatic decorating machine, but toasted 1-2 minute bone dry through 140 ℃; Clear, soft, the good springiness of gained coating flower shape on material fabrics such as cotton, terylene; COLOR FASTNESS (according to GB/T 5713-1997 test color fastness to water, according to GB/T 3922-1995 test acid and alkali-resistance PERSPIRATION COLOR FASTNESS, is tested anti-dried wet friction COLOR FASTNESS according to GB/T 3920-2008) more than the 3-4 level; 60 ℃ of washing 800min flower types keep clear, do not come off, ftracture.
The foregoing description is a preferred implementation of the present invention; But embodiment of the present invention is not restricted to the described embodiments; Other any do not deviate from change, the modification done under spirit of the present invention and the principle, substitutes, combination, simplify; All should be the substitute mode of equivalence, be included within protection scope of the present invention.

Claims (10)

1. an environment-friendly type textile coating stamp prints rubber cement with machine, it is characterized in that it being that composition by following weight portion prepares:
Adhesive: 60~75 parts
Water: 2~10 parts
Titanium white powder: 0~18 part
Delustering agent: 3~5 parts
Wetting dispersing agent: 0.5~2 part
Antifoaming agent: 0.2~0.5 part
Antifouling net agent: 6~8 parts
Thickener: 1~3 part.
2. print rubber cement according to the said environment-friendly type textile coating of claim 1 stamp with machine, it is characterized in that: said adhesive is a kind of in polyacrylate dispersion or the aqueous polyurethane emulsion of solid content 55~60%.
3. print rubber cement according to the said environment-friendly type textile coating of claim 1 stamp with machine, it is characterized in that: said titanium white powder is a kind of in rutile type titanium white or the anatase thpe white powder.
4. print rubber cement according to the said environment-friendly type textile coating of claim 1 stamp with machine, it is characterized in that: said delustering agent is a kind of in micro mist wax, micron order aeroge or the micron order precipitated silica.
5. print rubber cement according to the said environment-friendly type textile coating of claim 1 stamp with machine, it is characterized in that: said wetting dispersing agent is a kind of in PPG, polyacrylate, polyacrylamide, polyacrylate or the long chain type derivative of fatty acid.
6. print rubber cement according to the said environment-friendly type textile coating of claim 1 stamp with machine, it is characterized in that: said antifoaming agent is a kind of in fatty acid metal soap, fatty acid ester, fatty acid amide, dimethyl silicone polymer or the polyether-modified polysiloxanes.
7. print rubber cement according to the said environment-friendly type textile coating of claim 1 stamp with machine, it is characterized in that: said antifouling net agent is a kind of in ethylene glycol, propylene glycol, butanediol, sorbierite, glycerine, urea, polyethylene glycol or the polypropylene glycol.
8. print rubber cement according to the said environment-friendly type textile coating of claim 1 stamp with machine, it is characterized in that: said thickener is more than one mixtures in polyacrylate, modified polypropene hydrochlorate or the hydrophobically modified ethyoxyl polyurethane.
9. the said environment-friendly type textile coating of claim 1 stamp is characterized in that may further comprise the steps with the preparation method of machine seal rubber cement:
(1) in 60~75 parts of adhesives, adds 2~10 parts of water and 0.5~2 part of wetting dispersing agent, stir;
(2) keep stirring, 0~18 part of titanium white powder and 3~5 parts of delustering agents are sneaked in the emulsion, stirred 5~15 minutes;
(3) add 0.2~0.5 part of antifoaming agent, stirred 3~5 minutes; After treating that froth breaking fully, add 6~8 parts of antifouling net agent, stirred 1~3 minute;
(4) add 1~3 part of thickener, continue to stir 5~10 minutes;
(5) grind 1~2 time after discharging, promptly make and be used for the textile coating stamp and print rubber cement with machine;
Said umber is a weight portion.
10. the described environment-friendly type textile coating of claim 1 stamp is with the application of machine seal rubber cement in the continuous stamp of full-automatic decorating machine.
CN2011100682740A 2011-03-22 2011-03-22 Environmentally-friendly machine-printed rubber adhesive used for embossing on textile coating as well as preparation method and application thereof Active CN102191694B (en)

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Patentee before: Guangzhou Huigu New Materials Technology Co.,Ltd.

Country or region before: China

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