CN101608078B - Decorative paper water-based gravure printing ink composition - Google Patents
Decorative paper water-based gravure printing ink composition Download PDFInfo
- Publication number
- CN101608078B CN101608078B CN 200910069857 CN200910069857A CN101608078B CN 101608078 B CN101608078 B CN 101608078B CN 200910069857 CN200910069857 CN 200910069857 CN 200910069857 A CN200910069857 A CN 200910069857A CN 101608078 B CN101608078 B CN 101608078B
- Authority
- CN
- China
- Prior art keywords
- pigment
- pigment red
- red
- yellow
- pigment yellow
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention provides a decorative paper gravure printing ink composition which comprises the components in parts by weight: component A: 10-50 parts of at least one organic pigment and/or inorganic pigment, component B: 10-40 parts of at least one acrylic resin or the solution thereof, component C: 0.5-1 part of at least one wetting agent, component D: 0-10 parts of water-soluble supporting substance, component E: 0-5 parts of additive and component F: 100 parts of water. A method for preparing the composition comprises: the components are mixed for pulping according to the parts by weight and ground by a bead mill to have the grain diameter of 0.5-2mum under the cooling condition; then, the concentration of the final pigment is adjusted by softened water, and the ink is obtained by separating grinding medium and water-based color paste.
Description
Technical field
The present invention relates to decorative paper intaglio printing dye technology Application Areas, particularly a kind of decorative paper water-based gravure printing ink composition.
Background technology
Global forest reserves scarcity has promoted the mass production of wood-base fibre and particle panel material, and the surface decoration problem has become to solve the task of top priority that wood-based plate replaces solid wood to use.Therefore, the decorative paper production technology has had and has developed rapidly, the sign and the trend of development also occurred in China.This paper is specious, and texture is true to nature, and gloss is soft, and sense of touch is warm, and wear-resisting, resistant, flexible and high resilience is fit to various moulding is for bigger space has been opened up in furniture design, wood-based plate utilization.Because it has finish surface, thereby has simplified the furniture production technique, has improved production efficiency, reduced produce and use in the noxious volatilization, be the finishing material of a large amount of uses of upholstery and decorative craft of building, be the ideal substitute of natural veneer.
Along with the raising of living standards of the people, the increase of living space must cause the increase of upholstery material requirement.It is powerful that the development of demand is decorated in present domestic PLASTIC LAMINATED, floor, furniture and indoor and outdoor etc.Especially develop rapidly a large amount of outlets over past ten years.Be used to make the printing ink of starting material-veneer decorative paper use of decorative sheets such as PLASTIC LAMINATED, floor, furniture, require printing ink that good preservation stability is arranged; The printing characteristics of decorative paper are on decorative paper, to adopt the mode of intaglio printing painted, and ink should have excellent printability, good sticking power, dried fastness and sharpness; Decorative paper after the printing should have good dipping (unfading in melamine resin) to fit property; Satisfy overlaying condition, have high thermostability (200 ℃) and good anti-ultraviolet, light permanency (7-8 level).But traditional wash has high waterproof, film-forming properties is good, has changed decorative paper high-hydroscopicity and ventilation property, so be not suitable for the printing color of decorative paper.
Domestic, early stage, adopt the printing of textile coating printing paste, be equipped with tackiness agent to increase fastness.Fastness improves, and prints out diatom, pressing plate haftplatte, heat-resisting, sun-proof (weathering resistance) deficiency; In recent years; Progress along with synthetic water-base resin; Very much progress is arranged in the decorative paper printing, and the requirement of still can not satisfy sharpness, sticking power that decorative paper is printed on printing suitability, printing, soaking on the performances such as melamine-formaldehyde resin adhesive perviousness, pressing plate thermotolerance, uvioresistant and sun-proof differs greatly with the German Hartmann ink of external highest level, the gravure printing ink of Spain's sky fragrant plant ink like product level.
1. the FAQs of printability aspect: dark earlier back is shallow in (1) printing process, and behind the 500-1000m, color shoals; (2) go out cutter line, printing lifts, printing in the printing process and do that fastness is not enough, the colour reproduction circulation ratio is bad;
2. soak the FAQs of melamine glue: impregnation, the color drift miscible of fading with glue; Impregnation speed car 10-40m.;
3. pressing plate thermotolerance effect: 200 ℃ of variable colors in following 3 minutes, colour-darkening;
4. weathering resistance effect: 4-6 level;
5. sheet material is processed crisp limit.
For a long time, print the main dependence on import ink of high-grade decorative paper and exported product, reduced the competitive power of products export on the mountain, world market.Along with social progress, market requires increasingly high to decorative paper printing class and printing quality, and print product requirement decorative pattern is meticulous, have ornamental accordingly, the painted aesthetic consciousness that meets people, and durable in use, environmental protection is reliable; Development and exploitation decorative paper dedicated high performance aqueous intaglio printing China ink help improving the quality of China's decorative sheet product, change the situation that China produces the used gravure printing ink dependence on import of high-grade decorative paper.
Summary of the invention
The purpose of this invention is to provide a kind of decorative paper gravure printing ink composition; Said composition at printing suitability, sticking power, soak that obviously to be superior to existing decorative paper water-based gravure printing on the performances such as melamine-formaldehyde resin adhesive perviousness, pressing plate thermotolerance, uvioresistant and sun-proof black, can satisfy the decorating printing requirement.
Particularly, the invention provides a kind of decorative paper gravure printing ink composition, component and parts by weight thereof that said composition comprises are following:
At least a pigment dyestuff of A and/or mineral dye 10-50 part
At least a vinyl resin of B or acrylic resin soln 10-40 part
At least a wetting agent 0.5-1 of C part
D hydrotrophy material 0-10 part
E additive 0-5 part
F water is mended to 100 parts
In the above-mentioned compsn, pigment dyestuff is CI. Pigment Yellow 73 18, CI. Pigment Yellow 73 24, CI. Pigment Yellow 73 55, CI. Pigment Yellow 73 62, CI. Pigment Yellow 73 75, CI. pigment yellow 81, CI. pigment yellow 83, CI. Pigment Yellow 73 95, CI. Pigment Yellow 73 97, CI. Pigment Yellow 73 110, CI. pigment Yellow 12 0, CI. pigment yellow 13 8, CI. pigment yellow 13 9, CI. pigment yellow 147, CI. Pigment Yellow 73 150, CI. pigment yellow 154, CI. pigment yellow 17 5, CI. Pigment Yellow 73 180, CI. Pigment Yellow 73 181, CI. Pigment Yellow 73 194, CI. pigment orange 34, CI. pigment orange 36, CI. pigment orange, CI. pigment Red 89, CI. pigment red 122, CI. Pigment red 144, CI. pigment red 149, CI. Pigment red 166, CI. Pigment red 168, CI. Pigment red CI. Pigment red 170, CI. Pigment red 171, CI. Pigment red 175, CI. Pigment red 176, CI. Pigment red 177, CI. Pigment red 178, CI. Pigment red 179, CI. Pigment red 185, CI. Pigment red 187, CI. Pigment red 194, CI. Pigment red 202, CI. Pigment red 206, CI. Pigment Red 207, CI. Pigment red 208, CI. Pigment red 254, CI. Pigment red 255, CI. Pigment red 272, CI. pigment violet 19, the blue 15:0 of CI. pigment, the blue 15:1 of CI. pigment, the blue 15:2 of CI. pigment, the blue 15:3 of CI. pigment or the blue 15:4 of CI. pigment etc.Mineral dye is oxide compound or carbon black of white titanium pigment, iron etc.
Wherein at least a vinyl resin of B component or its solution, particularly, wherein vinyl resin can be thermoplastic acrylic resin or thermosetting acrylic resin, preferably, acrylic resin soln is the ammonia soln of vinyl resin.The example of vinyl resin; For example; Vinyl resin is water soluble acrylic acid solid resin village minister J678 (market is on sale), Korea S Han Hua water soluble acrylic acid solid resin S20 (market is on sale) etc., and these products join in the compsn of the present invention can both solve technical problem of the present invention.Preferred this acrylic resin soln is the ammonia soln of the 20-40 weight % of vinyl resin.
Component C wetting agent is preferably sulfo-succinic acid half ester sodium salt, the tetramethyl decynediol of AEO, fatty acid alkoxylates.
Component D hydrotrophy material is selected from one or more in terepthaloyl moietie, Ucar 35, glycerine, glycol ether, triglycol, polyoxyethylene glycol, ethanol, Virahol, ethylene glycol ethyl ether, butyl glycol ether, propylene glycol monomethyl ether, the Ucar 35 butyl ether;
Component E additive be selected from antisettling agent, sanitas/sterilant, inhibitor, air release agent/or skimmer, filler etc. in one or more.
Antisettling agent, sanitas, inhibitor, air release agent and/or skimmer etc.; Auxiliary agent commonly used in the dispersible pigment color paste preparation; For example; Sanitas is promise moral
C15 coating sterilant sanitas, sterilant mould inhibitor DC-2011 etc.; Inhibitor such as Ug-150 inhibitor, skimmer are Dormant oils class, lower alcohols etc., like FEB-100 skimmer etc.
Component F water is preferably zero(ppm) water, softening water, also available tap water.
The preparation of above-mentioned ink composition can use conventional blending means to carry out, and just above-mentioned raw materials is mixed, and grinds and has just obtained ink composition.
The preparation of above-mentioned ink composition also can prepare through following method:
By the parts by weight of said components each component is mixed making beating, under cooling conditions, being ground to particle diameter through ball mill is 0.5-2um, regulates final pigment concentration with softening water then, separate grinding medium and aqueous color paste obtain ink.
Particularly; The working method of ink composition be with powder pigment or pigment filter cake in softening water with vinyl resin or its solution and other additive furnishing pasty states; Or other suitable device homogenizing, use ball mill or other suitable dispersing apparatus dispersion grinding subsequently, wherein grind quartz silica bead or the Zirconium oxide bead that uses size d=1mm; Under cooling, carry out; Until reaching required colour intensity, regulate final pigment concentration with softening water, separate grinding medium and aqueous color paste and get ink.
The ink composition that method for preparing obtains is under 25 ℃ temperature condition, and viscosity T4# is 20-30s, and PH is 8-9, and said composition can be mixed the acquisition required color arbitrarily with pigment.
Above-mentioned decorative paper gravure printing ink composition of the present invention has following beneficial effect:
Ink composition of the present invention can print 10 tons of about 100000m and not have colour-change; Do not have in the printing and print out bad phenomenon such as cutter line, lifts; The attachment fastness of compsn meets the requirements, the colour reproduction favorable reproducibility.Have good effect aspect the melamine glue soaking, as impregnation do not fade, no color drift; Impregnation speed is applicable to that 10-60m impregnation speed is good.And the pressing plate thermotolerance reaches 200 ℃ of following 3 minutes nondiscolorations, colors and increases gorgeous.Weathering resistance reaches 7 grades.The not crisp limit of sheet material processing.
Embodiment
Following embodiment just to the explanation and the explanation of technical scheme of the present invention, does not form any restriction to protection scope of the present invention.Raw material among the following embodiment all can be bought from market and obtain the purchase information of arbitrary raw material below can obtaining through the internet.
Embodiment 1
Take by weighing the raw materials mix making beating of following weight, under cooling conditions, being ground to particle diameter through ball mill is 0.5um, regulates pigment concentration with softening water then, separate grinding medium and aqueous color paste obtain ink.
This ink composition is bright-colored, tinctorial yield is high, stable storing, non-foam.Implement printing and have excellent printability, good fastness, impregnation permeates.
Embodiment 2
Take by weighing the raw materials mix making beating of following weight, under cooling conditions, being ground to particle diameter through ball mill is 0.5um, regulates pigment concentration with softening water then, separate grinding medium and aqueous color paste obtain ink.
| A, CI. pigment Blue 15: 3 | 25Kg |
| The 20 weight % ammonia solns of B, Korea S Han Hua water soluble acrylic acid solid resin S20 | 30Kg |
| C, AEO | 0.5Kg |
| E, sterilant mould inhibitor DC-2011 | 0.2Kg |
| F, water | 44.3Kg |
This ink composition is implemented printing back impregnation and is permeated.The printing rate of drying is fast, and the impregnation seepage velocity is fast.
Embodiment 3
Take by weighing the raw materials mix making beating of following weight, under cooling conditions, being ground to particle diameter through ball mill is 0.5um, regulates pigment concentration with softening water then, separate grinding medium and aqueous color paste obtain ink.
| A, carbon black | 20Kg |
| The 40 weight % ammonia solns of B, water soluble acrylic acid solid resin village minister J678 | 35Kg |
| C, tetramethyl decynediol | 0.7Kg |
| D, butyl glycol ether | 4.5Kg |
| F, water | 39.8Kg |
This ink composition has tinctorial yield, the non-foam of embodiment 1, implements printing and has excellent printability, good fastness, and impregnation permeates.
But arbitrary proportion mixes the adjustment required color between the color of above-mentioned ink composition of the present invention, and dispersible pigment color paste can be with removing light dilution agent to any concentration, convenient in application.
Ink composition of the present invention is described through concrete embodiment.Those skilled in the art can use for reference links such as content appropriate change raw material of the present invention, processing condition and realize corresponding other purpose; Its relevant change does not all break away from content of the present invention; All similar replacements and change will become apparent to those skilled in the art that all to be regarded as and are included within the scope of the present invention.
Claims (7)
1. decorative paper gravure printing ink composition, component and parts by weight thereof that said composition comprises are following:
At least a pigment dyestuff of A and/or mineral dye 10-50 part
At least a vinyl resin of B or acrylic resin soln 10-40 part
At least a wetting agent 0.5-1 of C part
D hydrotrophy material 0-10 part
E additive 0-5 part
F water is mended to 100 parts,
Wherein component C wetting agent is a tetramethyl decynediol, and wherein vinyl resin is water soluble acrylic acid solid resin village minister J678 or Korea S Han Hua water soluble acrylic acid solid resin S20.
2. compsn according to claim 1; Wherein pigment dyestuff is CI. Pigment Yellow 73 18, CI. Pigment Yellow 73 24, CI. Pigment Yellow 73 55, CI. Pigment Yellow 73 62, CI. Pigment Yellow 73 75, CI. pigment yellow 81, CI. pigment yellow 83, CI. Pigment Yellow 73 95, CI. Pigment Yellow 73 97, CI. Pigment Yellow 73 110, CI. pigment Yellow 12 0, CI. pigment yellow 13 8, CI. pigment yellow 13 9, CI. pigment yellow 147, CI. Pigment Yellow 73 150, CI. pigment yellow 154, CI. pigment yellow 17 5, CI. Pigment Yellow 73 180, CI. Pigment Yellow 73 181, CI. Pigment Yellow 73 194, CI. pigment orange 34, CI. pigment orange 36, CI. pigment orange, CI. pigment Red 89, CI. pigment red 122, CI. Pigment red 144, CI. pigment red 149, CI. Pigment red 166, CI. Pigment red 168, CI. Pigment red CI. Pigment red 170, CI. Pigment red 171, CI. Pigment red 175, CI. Pigment red 176, CI. Pigment red 177, CI. Pigment red 178, CI. Pigment red 179, CI. Pigment red 185, CI. Pigment red 187, CI. Pigment red 194, CI. Pigment red 202, CI. Pigment red 206, CI. Pigment Red 207, CI. Pigment red 208, CI. Pigment red 254, CI. Pigment red 255, CI. Pigment red 272, CI. pigment violet 19, the blue 15:0 of CI. pigment, the blue 15:1 of CI. pigment, the blue 15:2 of CI. pigment, the blue 15:3 of CI. pigment or the blue 15:4 of CI. pigment, and mineral dye is the oxide compound or the carbon black of white titanium pigment, iron.
3. compsn according to claim 1, wherein acrylic resin soln is the ammonia soln of vinyl resin.
4. compsn according to claim 1, wherein acrylic resin soln is the ammonia soln of the 20-40 weight % of vinyl resin.
5. compsn according to claim 1, wherein component D hydrotrophy material is selected from one or more in terepthaloyl moietie, Ucar 35, glycerine, glycol ether, triglycol, polyoxyethylene glycol, ethanol, Virahol, ethylene glycol ethyl ether, butyl glycol ether, propylene glycol monomethyl ether, the Ucar 35 butyl ether.
6. compsn according to claim 1, wherein component E additive is selected from antisettling agent, sanitas, inhibitor, air release agent and/or skimmer, one or more in the filler.
7. compsn according to claim 1, the preparation of said composition prepares through following method:
By the parts by weight of said components each component is mixed making beating, under cooling conditions, being ground to particle diameter through ball mill is 0.5-2um, regulates final pigment concentration with softening water then, separate grinding medium and aqueous color paste obtain ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910069857 CN101608078B (en) | 2009-07-23 | 2009-07-23 | Decorative paper water-based gravure printing ink composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910069857 CN101608078B (en) | 2009-07-23 | 2009-07-23 | Decorative paper water-based gravure printing ink composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101608078A CN101608078A (en) | 2009-12-23 |
| CN101608078B true CN101608078B (en) | 2012-09-19 |
Family
ID=41481989
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200910069857 Expired - Fee Related CN101608078B (en) | 2009-07-23 | 2009-07-23 | Decorative paper water-based gravure printing ink composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101608078B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101955709B (en) * | 2010-09-17 | 2016-01-20 | 天津市海山化工科技开发有限公司 | A kind of water-containing coating paste and composition |
| CN102268840B (en) * | 2011-07-15 | 2013-06-19 | 浙江帝龙新材料股份有限公司 | Decorative paper used for floor or furniture |
| CN102936450B (en) * | 2012-11-21 | 2014-10-29 | 广州酷漫居动漫科技有限公司 | UV (ultraviolet) ink bridging agent and application thereof |
| CN103146257B (en) * | 2013-03-20 | 2014-08-27 | 哈尔滨绿科科技有限公司 | Special water-based ink for printing polyvinyl chloride (PVC) foam wallpaper and preparation method thereof |
| CN104263074B (en) * | 2014-10-13 | 2016-08-17 | 北京印刷学院 | Pure water type cork paper gravure white ink and preparation method thereof |
| CN104877434A (en) * | 2015-06-02 | 2015-09-02 | 青岛伟健金属饰品有限公司 | Fading-free ink |
| CN106905764A (en) * | 2017-04-20 | 2017-06-30 | 孔硕硕 | A kind of preparation method of Neutral writing ink and obtained ink |
| CN110294963B (en) * | 2019-08-12 | 2022-02-08 | 厦门欧化实业有限公司 | Water-based UV treatment-free surface printing ink and processing method and processing equipment thereof |
| CN115449258A (en) * | 2022-09-16 | 2022-12-09 | 昆山大世界油墨涂料有限公司 | Decorative paper ink with high color spreading effect and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101275043A (en) * | 2007-03-28 | 2008-10-01 | 樊官保 | Environment-friendly water-soluble plate engraving ink |
| CN101381535A (en) * | 2008-10-27 | 2009-03-11 | 浙江盛龙装饰材料有限公司 | Aqueous ink special for decorating paper and production method thereof |
-
2009
- 2009-07-23 CN CN 200910069857 patent/CN101608078B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101275043A (en) * | 2007-03-28 | 2008-10-01 | 樊官保 | Environment-friendly water-soluble plate engraving ink |
| CN101381535A (en) * | 2008-10-27 | 2009-03-11 | 浙江盛龙装饰材料有限公司 | Aqueous ink special for decorating paper and production method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 周霞，武兵.《印刷油墨对颜料的要求》.《印刷油墨的配方设计与生产工艺》.化学工业出版社,2004,138-168. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101608078A (en) | 2009-12-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101608078B (en) | Decorative paper water-based gravure printing ink composition | |
| CN102191694B (en) | Environmentally-friendly machine-printed rubber adhesive used for embossing on textile coating as well as preparation method and application thereof | |
| CN101492577A (en) | Process for producing watersoluble stone design imitating color slice and use scheme | |
| CN101386726B (en) | Water-borne colorant for coloring of waterborne wood coatings and producing method thereof | |
| CN101579880B (en) | Manufacturing technique of dyeing bamboo filament plate | |
| CN103183995B (en) | Water-based paint compositions | |
| CN103360851A (en) | Development method of novel water-based timber rubbling coloring agent | |
| CN102174747B (en) | Environment-friendly textile printing pearlescent adhesive cement and preparation method and application thereof | |
| CN105658437A (en) | Inkjet printing methods for manufacturing of decorative surfaces | |
| CN101468480A (en) | Construction technique of fiber drawing archaized decoration coated by nitro lacquer for house | |
| CN102796420A (en) | Water-based ink color painting pigment with shading effect used on rice paper | |
| CN103696273B (en) | A kind of leather manufacture method of the dyeing based on water-based resin and dyeing leather | |
| CN106314002A (en) | Ceramic overglazed pearlescent relief pigment, ceramic overglazed pearlescent relief color decal paper and manufacturing method thereof | |
| CN105482531A (en) | Solid instant transparent watercolor and preparation method thereof | |
| CN102587616B (en) | Energy-saving and environment-friendly floor with low energy consumption and preparation method and using method of floor | |
| CN101500799A (en) | Floor panel made of MDF or HDF | |
| CN111254721A (en) | Novel pyrograph printing ink and preparation method and application thereof | |
| CN102093780B (en) | Non-woven fabric environmental-protection water-based ink and preparation method thereof | |
| CN108978296A (en) | A kind of high quality recycled paper processing method | |
| CN104403414A (en) | Water-soluble woven bag printing ink with high abrasion resistance and making method thereof | |
| CN103224738B (en) | Aqueous, environmental protective edge band ink and preparation method thereof | |
| CN101705630B (en) | Color paste of printing coating for textile fabrics | |
| CN106168006A (en) | The technique that a kind of water color ink manufactures wallpaper | |
| CN101463216B (en) | Foaming pigment and its production method | |
| CN107839398A (en) | A kind of jade carving vessel fill out lacquer craftwork |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120919 Termination date: 20190723 |