CN101302881B - External heat insulation decorative processing method and structural body - Google Patents
External heat insulation decorative processing method and structural body Download PDFInfo
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- CN101302881B CN101302881B CN2008100967194A CN200810096719A CN101302881B CN 101302881 B CN101302881 B CN 101302881B CN 2008100967194 A CN2008100967194 A CN 2008100967194A CN 200810096719 A CN200810096719 A CN 200810096719A CN 101302881 B CN101302881 B CN 101302881B
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Abstract
The invention relates to an external heat insulating decorative processing structure which is structure on the outer wall of buildings, comprising: an external heat insulating structure base material which is formed by wall material and heat insulating material layer laminated on the wall material; a lower coating layer and decorative coating layer laminated on the external heat insulating base material, and the decorative coating layer is divided into multiple regions by seams. The invention is processed by the external heat insulating structure base material on the outer wall of the building, thereby improving beauty of the wall processing surface.
Description
Technical field
The present invention relates to have concurrently the external heat insulation decorative processing method and the metope structure body of high thermal insulation and aesthetic property.
Background technology
In the last few years, at commercial facility, the apartment, in vogue in the buildings such as only dwelling house by carrying out high heat insulationization and high sealabilityization, to save cold air and heating installation expense, realize the saving of the energy and resource.
Usually, in the building of not implementing Design on thermal insulation, winter is when supplying heating installation, and position such as indoor hot gas can be from the roof, floor, window and wall is dispersed into outdoor; Summer, outdoor hot gas can invade indoor from these positions when supplying cold air.In these thermal loss about 1/3rd can be said so and be caused by metope.Therefore, in order to realize the saving of resource, the high heat-proof quality of the exterior wall of indoor and the outer isolation in room is absolutely necessary.In recent years, the multiple scheme that the metope structure of heat-barrier material is set at exterior wall surface has been proposed.For example, outside the building on the surface of wall, the insulation material layer based on polystyrene foam and phenol formaldehyde foam etc. is set, is provided with the metope structure of filming thereon and knows (for example patent documentation 1 etc.) for the crowd of people institute.
But this metope structure nearly all is solid color now, lacks design property.
Patent documentation 1, the spy opens the 2002-235386 communique
Summary of the invention
At the problems referred to above, the objective of the invention is: outside the building on the wall heat-barrier material is set, when reaching high heat insulationization, improves the aesthetic property of metope.
The inventor in order to reach above-mentioned purpose, has carried out conscientious research, by the outer heat insulating base on the materials for wall of skin face is provided with the ornamental material layer that is coated with specific form, has finally finished the present invention.
That is, the present invention has following feature.
1, a kind of external heat insulation decorative processing structure body is the structure on the materials for wall of skin face, and it comprises:
Outer heat insulating base, it is that the lamination insulation material layer constitutes on materials for wall, or according to demand on this insulation material layer the lamination strengthening layer obtain, described strengthening layer is made of polymer water mud layer and/or reticulate body;
Under be coated with material layer and the ornamental material layer that is coated with, lamination is on outer heat insulating base, and the described ornamental material layer that is coated with is divided into a plurality of zones by seam; Described be coated with down following in the material layer be coated with material with synthetic resin as in conjunction with material, the skin of described synthetic resin is-20～100 ℃ carbonyl acrolein resin for the glass transition temperature, internal layer comprises sandwich construction type synthetic resin emulsion, and this sandwich construction type synthetic resin emulsion comprises the silicones that derives from cyclic siloxane compound and glass transition temperature and is-80～20 ℃ acrolein resin.
2, a kind of external heat insulation decorative processing method, it comprises the steps:
A, outside the building the lamination insulation material layer obtains outer heat insulating base on the materials for wall of metope, be coated with the material layer to being coated with material under this outer heat insulating base coating to form down, wherein said outer heat insulating base also comprises the strengthening layer of lamination on insulation material layer according to demand, and described strengthening layer is made up of polymer water mud layer and/or reticulate body; Described be coated with down following in the material layer be coated with material with synthetic resin as in conjunction with material, the skin of described synthetic resin is-20～100 ℃ carbonyl acrolein resin for the glass transition temperature, internal layer comprises sandwich construction type synthetic resin emulsion, and this sandwich construction type synthetic resin emulsion comprises the silicones that derives from cyclic siloxane compound and glass transition temperature and is-80～20 ℃ acrolein resin;
B, paste the seam material on the surface that this time is coated with the material layer;
C, the ornamental material that is coated with of surface applied that obtains at step B;
D, part or all of seam material removed.
The invention effect
When external heat insulation decorative processing structure body of the present invention has good thermal insulation, also has good aesthetic property.
Below, describe implementing better embodiment of the present invention.
Description of drawings
Fig. 1 is the sectional view of an embodiment of structure of the present invention.
Description of reference numerals
A: outer heat insulating base 3: strengthening layer
B: seam 4: be coated with the material layer down
1: materials for wall 5: decorate and be coated with the material layer
2: insulation material layer
The specific embodiment
The present invention is the structure on the materials for wall of skin face, and it comprises:
Outer heat insulating base, it is that the lamination insulation material layer constitutes on materials for wall, or according to demand on this insulation material layer the lamination strengthening layer obtain, described strengthening layer is made of polymer water mud layer and/or reticulate body;
Under be coated with material layer and the ornamental material layer that is coated with, lamination is on outer heat insulating base, and the described ornamental material layer that is coated with is divided into a plurality of zones by seam.
This structure can form by following step.
(A) coating of the outer heat insulating base on the materials for wall of skin face is coated with material down to form down the step that is coated with the material layer (hereinafter referred to as step (A).)
(B) be coated with the step of pasting the seam material on the surface of material layer (hereinafter referred to as step (B) in this time.)
(C) on the surface that obtains by (B) the coating ornamental step that is coated with material (hereinafter referred to as step (C).)
(D) remove part or all step of seam material (hereinafter referred to as step (D).)
Below, the present invention will be described based on above-mentioned steps.
The materials for wall that constitutes the skin face can be for for example: concrete, lightweight concrete, mortar, light weight mortar, gypsum plank, cement board, extrusion forming board, pearlite board, slabstone, PC plate, ALC plate, fibre reinforced cement panel, metal wallboard, ceramic wallboard, ceramic wafer, calcium silicate board, plastic plate, hard wood cement board, plywood, brick, ceramic tile etc.On their surface, can implement any surfacing (for example: sealing (sealer), surface coating (surfacer), filling (filler) etc.).
Insulation material layer makes skin wear thermal insulation.
Insulation material layer can use the various materials with heat-proof quality, but preferably adopts foaming organic resin heat-barrier materials such as polystyrene foam, polyurethane foam, phenol formaldehyde foam, polyethylene.This foaming organic resin heat-barrier material has the low and good heat-proof quality of pyroconductivity.Tabular foaming organic resin heat-barrier material can use adhesives and metal parts etc. to be fixed in base material.In the present invention, also can form insulation material layer by the material of foam-in-place type.In addition, can also form insulation material layer by the mixing thing of foaming shot-like particle of organic resin and cement etc.The thickness of insulation material layer is not done special qualification, but is generally about 5～150mm.
On insulation material layer, the strengthening layer of being made up of polymer water mud layer and/or reticulate body can be set as required.This strengthening layer has improved intensity, durability, breakage-proof of metope structure body etc.When the heat insulation material that uses was the tabular heat insulation material of foaming organic resin, strengthening layer was essential.
The polymer water mud layer can adopt, for example: cement such as hydraulic lime, portland cement, blast-furance cement, silicon-dioxide cement, flyash cement and alumina cement; Resins such as vinyl, vinyl acetate base resin, mylar, alkyd resins, ethlyene dichloride base resin, epoxy resin, acrolein resin, carbamate resins, silicones, methacrylaldehyde silicones, fluororesin, cellulose and polyvinyl alcohol; Fine aggregates such as silica sand; And the constituent that can contain various additives as required obtains.
Reticulate body is the net structure that fiber and metal fine form; This fiber for example is: paper pulp (pulp) fiber, polyester fiber, polypropylene fibre, aromatic polyamide fibre, vinal, styroflex, polyarylate fiber, pbo fiber, nylon fiber, methacrylaldehyde fiber, ethlyene dichloride base fiber, cellulose fibre, asbestos, glass fiber, silicon dioxide fibre, silica-alumina fiber, carbon fiber and silicon carbide fibre etc.; This metal fine for example is: metal fines such as iron, copper.
The present invention is preferably in the polymer water mud layer and imbeds reticulate body.
Among the present invention, adopt common method on insulation material layer, to form the strengthening layer of forming by polymer water mud layer and/or reticulate body, and obtain outer heat insulating base through suitably maintaining.
Under be coated with material and have the sorting table surface state, improve the effect of ornamental processability that is coated with material etc.Under be coated with material will be as inorganic based material such as cement, gypsum, water glass, silica gel as in conjunction with material, perhaps with various synthetic resin as in conjunction with material.
Under be coated with material and preferably have elasticity.Be coated with material under this elasticity and have the breakage that prevents on the machined surface, peel off and effect such as expansion.
Described synthetic resin can for, for example water-soluble resin, water-dispersed resin, the solvable type resin of solvent, solvent-free shape resin, non-aqueous dispersion shape resin etc. perhaps also can be their compound.Preferably use water-soluble resin and/or water-dispersed resin among the present invention.
Be specially vinyl, vinyl acetate base resin, mylar, alkyd resins, ethlyene dichloride base resin, epoxy resin, acrolein resin, carbamate resins, silicones, methacrylaldehyde silicones, fluororesin, cellulose, polyvinyl alcohol etc.
The skin of synthetic resin can for, for example the glass transition temperature is-20～100 ℃ a carbonyl acrolein resin, internal layer comprises sandwich construction type synthetic resin emulsion, this sandwich construction type synthetic resin emulsion comprises the silicones that derives from cyclic siloxane compound and glass transition temperature and is-80～20 ℃ acrolein resin, this synthetic resin has the seal of guaranteeing outer heat insulating base, prevent timeliness breakage, peel off, effect such as expansion.
To under be coated with material and carry out can using coloring pigment suitably to mix colours when painted.At this moment, be set at and the ornamental approximate form and aspect of material (look altogether) that are coated with of aftermentioned, just can not produce inharmonic sensation if will be coated with the tone of material down.In addition, be set at and the ornamental different form and aspect of material that are coated with of aftermentioned, can make seam look and the ornamental contrast that is coated with material clearly if will be coated with the tone of material down.In this case, can suitably select the tone that is coated with material down according to required seam look.
Coloring pigment for example can use, titanium oxide, zinc oxide, carbon black, lamp black carbon black, bone carbon black, blacklead, black iron oxide, copper-chrome black, cobalt black, copper ferromanganese are black, di-iron trioxide, yellow lead, permanent bordeaux, forever consolidate pink, anthraquinone, perylene is red, quinacridone is red, yellow iron oxide, titan yellow, permanent yellow, benzimidazolone Huang, chrome green, cobalt green, phthalocyanine green, ultramarine, dark purple, cobalt blue, phthalocyanine blue, quinacridone violet and permanent violet etc.
In addition, except synthetic resin, coloring pigment, being coated with material can also comprise the composition that can be used for being coated with usually material down.This composition for example can use gather materials, solid pigment, fiber, thickener, membrane producing promoter, poising agent, plasticizer, antifreezing agent, pH are adjusted agent, anticorrisive agent, anti-microbial inoculum, anti-algae agent, antiseptic, dispersing agent, defoamer, ultra-violet absorber, antioxidant, catalyst, bridging agent etc.
The method that is coated with material for coating down is not particularly limited, and can adopt known coating process.Coating process for example can be coated with etc. for spraying, roller coat, brushing, trowel.It is relevant with the form that is coated with material down to be coated with the coating amount of material down, is generally 0.1～3kg/m
2About.During application can with mixing diluents such as water with suitable adjusting viscosity.The drying that is coated with material down can be carried out usually at normal temperatures.
Step (B) is characterised in that pastes the seam material on the surface that is coated with the material layer down.
The seam material can be seam rod, seam band or embedded seam material etc.
The material of this seam material is not particularly limited, but can be carbolic acid resin, melamine resin, mylar, epoxy resin, polyurethane resin, ethlyene dichloride base resin, AS resin, ABS resin, polyvinyl resin, polyacrolein resin, polystyrene resin, EVA (ethene-vinyl acetate base copolymer) resin, polycarbonate resin, rubber etc.
This seam material be pasted on down be not particularly limited the lip-deep opportunity that is coated with the material layer, but be preferably under carry out after being coated with the material drying.Perhaps, when carrying out the stickup of seam material, can use solid, adhesive etc. as required.Further, can on the seam material, lay release liner or anti-fouling material etc.
The position of stickup seam material and spacing etc. can be determined according to desirable joint pattern.For example, can equidistantly paste, or random stickup.Pattern also can be pictorial pattern that is designed to animals and plants, implements, literal etc. etc. except ceramic tile style pattern, brick style pattern, geometrical pattern, globule pattern, candy strip, grid pattern, vortex pattern and badge pattern.In order to show these patterns, can make the seam material of linearity carry out multiple combination, also can carry out corresponding burrowing to plane cardboard to form pattern form.
Seam material width is generally about 0.5～100mm, can suitably set in its scope.The height of seam material is generally about 0.5～10mm.
Among the present invention, a part of descending to be coated with the material layer can be cut the back and on this cutting tip, paste the seam material.But in this case, note not switching to base material.
Step (C) is characterised in that the ornamental material that is coated with of coating on the surface that is obtained by step (B).By this step, can make the surface have the multicolor patterns of aesthetic property and/or relief pattern etc.
In addition, said here multicolor patterns is under the state that can debate knowledge, at least the pattern that mixes of the above color of dichromatism.In addition, relief pattern is the picture on surface with about 0.2～5mm left and right sides difference of height.
The ornamental instantiation that is coated with material is coated with material for using the processing of (1) stone material style, the multicolor pattern paint of (2) JISK5667, and the thin deposited processing of (3) JISA6909 is coated with material or thick deposited processing Tu Cai etc., also can use the above-mentioned two or more ornamental material that is coated with.
(1) processing of stone material style is coated with material
The processing of stone material style is coated with material can form multicolor patterns according to coloured color of gathering materials, and with synthetic resin emulsion and coloured gathering materials as necessary constituent.Wherein, synthetic resin emulsion can be for for example, vinyl acetate base resin, epoxy resin, silicones, acrolein resin, carbamate resins, methacrylaldehyde carbamate resins, methacrylaldehyde silicones, fluororesin etc., or be the compound of these resins.
Colouredly gather materials that to be generally particle directly be gathering materials of 0.05～5mm.Described coloured gathering materials can be used natural aggregates such as crushed material from natural stone, natural stone, and manually gathered materials more than select at least a painted gather materials etc.Particularly, for example, marble, imperial shadow stone, serpentinite, granite, fluorite, gypsum rubrum, feldspar, limestone, silica, silica sand, rubble, mica, siliceous shale and their crushed material, pottery chinaware crushed material, ceramic powder minces, glass dust minces, glass bead, resin-oatmeal minces, resin beads, micelle, clipped wire etc.In addition, can also use crushed materials such as shell, coral, timber, carbon and activated carbon.Further, surfacing is carried out by pigment, dyestuff and glaze etc. in their surface, also can carry out painted covering.Can make two or more this gathering materials carry out appropriate combination, to show various multicolor patterns.
Coloured gathering materials mixes with certain proportion.This ratio is, with respect to synthetic resin emulsion solid portion 100 weight portions, will mix 100～4000 weight portions usually, is preferably to mix 150～3000 weight portions, more preferably for mixing 200～2000 weight portions.If the mixed proportion of gathering materials helps the property conceived in this scope, prevent aspects such as crack breakage.
The processing of stone material style is coated with in the material, can mix above-mentioned composition in addition.This composition can be for for example, and coloring pigment, solid pigment, fiber, membrane producing promoter, plasticizer, antifreezing agent, anticorrisive agent, anti-microbial inoculum, antiseptic, defoamer, pigment dispersing agent, thickener, poising agent, wetting agent, pH adjust agent, delustering agent, ultra-violet absorber, antioxidant, catalyst, bridging agent.
Stone material style processing is coated with the coating process of material can be for for example, and spraying, roller coat, trowel are coated with, brushing etc.One or more the material that is coated with can be carried out overlapping coating.Be coated with in the material in this stone material style processing, adjust application utensil and application condition etc., obtain various relief patterns by suitable selection.In addition, behind dried coating film, can handle protuberance cutting such as polish.
The coating amount that the processing of stone material style is coated with material is generally 1～10kg/m
2About.Mixing diluents such as water can be coated with the viscosity of material during application with suitable adjusting.Dilution ratio is generally about 0～10 percentage by weight.The processing of stone material style is coated with the drying of material and can carries out at normal temperatures usually.
(2) multicolor pattern paint
Multicolor pattern paint is outstanding turbid in dispersion medium and form by the look grain more than the aqueous or gelatinous dichromatism.It can be divided into oil-in-water type (O/W type), water-in-oil type (w/o type), oily oil-in (O/O type) and this several types of water-in-water type (W/W type).Wherein, about the multicolor pattern paint of oil-in-water type (O/W type) and water-in-water type (W/W type), any one dispersion medium all is a water-based, is very desirable at aspects such as environment.
Look grain in the multicolor pattern paint is by pigmented finiss is formed with granular being scattered in the dispersion medium.This pigmented finiss comprises resin and colorant, and can also comprise various additives etc. as required.
As long as the resin in the pigmented finiss can play the vehicle effect, can use known resin without particular limitation.This resin can be for for example, resins such as methacrylaldehyde, carbamate, vinyl acetate base, methacrylaldehyde vinyl acetate base, methacrylaldehyde carbamate, methacrylaldehyde silicon, fluorine, polyvinyl ethanol, biogum, galactomannans (galactomannan) inductor, alginic acid inductor, cellulose inductor.The form of these resins can be in the solvable type resin of solvent, non-water-dispersion type resin, water-soluble resin, the water-dispersed resin etc. any one.In addition, these resins also can have by the functional group of hardener and sclerosis catalyst bridge formation.
In addition, when above-mentioned resin is solvable type resin of solvent and/or non-water-dispersion type resin, can obtain the solvent-borne type pigmented finiss, it is scattered in the multicolor pattern paint that then forms oil-in-water type (O/W type) in the water-based dispersion medium.In addition, when above-mentioned resin is water-soluble resin and/or water-dispersed resin, can obtain the water-based pigmented finiss, it is scattered in the multicolor pattern paint that then forms water-in-water type (W/W type) in the water-based dispersion medium.
Colorant in the pigmented finiss generally can cooperate with coating.Coloring pigment of in the explanation that is coated with material down, being given an example etc. for example.
In the pigmented finiss, can suitably use known coating additive.This additive can be for for example, and viscosity is adjusted agent, bridging agent, catalyst, filler, fiber-like, pigment dispersing agent, membrane producing promoter, antifreezing agent, dry agent, plasticizer, delustering agent, defoamer, ultra-violet absorber, antioxidant, light stabilizer, anti-microbial inoculum and the anticorrisive agent etc. adjusted.
Pigmented finiss is not particularly limited with the method for granular dispersion, can adopts known method.Particularly, can adopt method of pigmented finiss being scattered in the water-based dispersion medium that includes dispersion stabilizer etc. etc.
Dispersion stabilizer is to make pigmented finiss be stable at granular composition, can select according to kind of pigmented finiss etc.The object lesson of dispersion stabilizer as: the one-tenth as the bridging agent of pigmented finiss grades.This composition can be for for example, epoxies, isocyanic acid salt, amine, alkoxy silane (alkoxysilane) class, organic titanate (titanate) class, aluminium chelating class, magnesium salts, calcium salt class, barium salt class, aluminium salt, sodium salt class, sylvite class, borate family, phosphoric acid salt etc.In addition, dispersion stabilizer can use polyvinyl ethanol, polyacrylic acid, polyethylene oxide, methylcellulose, ethyl cellulose, hydroxyethylcellulose, carbonyl methyl cellulose, casein, cellulose acetate phthalate, bentonite, gel, Sodium Alginate, acacia gum, pectin, xanthans, starch etc.
The particle footpath and the shape of look grain can suitably be set.Particularly, the shape of the stirrer paddle during according to manufacturing, the size and location of the stirrer paddle of agitation tank, the rotary speed of stirrer paddle, the viscosity of pigmented finiss, the adding method of dispersion stabilizer and concentration, and the viscosity of water-based dispersion medium etc. can suitably be selected and adjust.
The particle footpath of look grain does not limit especially, (preferably is about 0.1～5mm) but be generally 0.01～10mm.
The coating process of multicolor pattern paint for example can adopt, spraying, roller coat, brushing.Use multicolor pattern paint show relief pattern time, according under be coated with material and form desirable relief pattern after, can carry out the application of multicolor pattern paint, the method that for example can adopt the spy to open to put down in writing in the flat 8-173899 communique etc.
The coating amount of multicolor pattern paint is generally 0.2～1kg/m
2About.Mixing diluents such as water suitably can be regulated viscosity during coating.Dilution ratio is generally about 0～10 weight %.The drying of multicolor pattern paint is carried out usually at normal temperatures.
In addition, before the application multicolor pattern paint, application substrate in advance is coated with material.Be coated with material by application substrate in advance, can make the ornamental material that is coated with obtain certain thickness, in addition, can also produce concavo-convex.
(3) thin deposited processing is coated with material, and thick deposited processing is coated with material
In JISA6909, stipulate thin apply processing be coated with material and thick deposited processing be coated with material can by with synthetic resin emulsion as binding material, evenly mix coloring pigment, solid pigment, gather materials, and other mixed agent (dispersing agent, thickener, defoamer, anticorrisive agent etc.) obtain.
Wherein, synthetic resin emulsion can be for for example, vinyl acetate base resin, epoxy resin, silicones, acrolein resin, carbamate resins, acrylic-amino formic acid esters resin, propylene silicones, fluororesin etc., perhaps compound of these resins etc.
Coloring pigment can use and be coated with given example etc. in the material under aforementioned.By being used in combination in these coloring pigments one or more, can show desirable color.The blending ratio of coloring pigment is with respect to synthetic resin emulsion solid constituent 100 weight portions, to be generally the coloring pigment that mixes about 1～300 weight portion (preferably being 2～200 weight portions).
Solid pigment is the composition of filming and forming that helps thick film mainly as extender.The object lesson of solid pigment is as, powdered whiting, slight property calcium carbonate, china clay, clay, potter's clay, ceramic clay, kieselguhr, moisture micro mist silicic acid, French chalk, blanc fixe, barium sulfate, settleability barium sulfate, brium carbonate, magnesium carbonate, silicon dioxide powder and water alumina etc.The particle footpath of solid pigment is usually less than 50 μ m (preferably being that 0.5 μ m is above less than 50 μ m).The mixed proportion of solid pigment is with respect to the solid portion of 100 weight portion synthetic resin emulsion, will mix the solid pigment about 10～1000 weight portions (preferably being 20～500 weight portions) usually.
Gather materials and for example can use, gypsum rubrum, feldspar, limestone, silica, silica sand, rubble, mica, siliceous shale, and their crushed material, glass bead, resin beads, resin-oatmeal minces, micelle and clipped wire etc.The particle that gathers materials directly is generally 0.05～5mm.The mixed proportion of gathering materials is that the solid portion of relative 100 weight portion synthetic resin emulsion will mix gathering materials about 10～2000 weight portions (preferably being 30～1500 weight portions) usually.
In this application that is coated with material, kind and using method thereof by suitable selection application utensil can obtain various relief patterns, sand wall shape for example, and shaddock skin shape, fiber wall shape, wavy, the plaster shape, concavo-convex, month planar, comb draws shape, worm food shape etc.The application utensil for example can use, spray sundries, roller, trowel etc.At this moment, before being coated with the material drying, can also use pattern roller, trowel, brush, comb, scraper etc. to handle, to form various relief patterns to being coated with face.In addition, also can be combined to form multicolor patterns to the two or more material that is coated with of different color.
Though coating amount depends on the kind of formed pattern etc., is generally 0.3～10kg/m
2About.Thinners such as water can be mixed during application, suitably regulate being coated with material viscosity.Dilution ratio is generally about 0～10 weight %.Drying is carried out usually at normal temperatures.
Step (D) is characterised in that removes the seam material.
For the opportunity of removing the seam material, as long as can form desirable decoration seam, unhardened or sclerosis that decoration is coated with material etc. does not limit especially.
In addition, when the seam material was seam rod, seam band etc., it was whole preferably to remove the seam material; When the seam material is embedded seam material, a part of preferably removing the seam material.
Among the present invention, form joint pattern, and compare, can obtain stable performance at aspects such as preventing breakage by cutting the method etc. that a part of getting base material forms seam by above method.
Further, among the present invention, remove the seam material after, can apply clear dope as required.In addition, can also carry out hydrophilicity-imparting treatment and preventing hydration processing etc.Wherein, clear dope can use for example various coating such as acrolein resin system, carbamate resins system, methacrylaldehyde silicones system, fluororesin.This clear dope can be implemented painted under the prerequisite of not overslaugh effect of the present invention.In waterproofing work, can use with alkoxysilane compound containing trialkylsilyl group in molecular structure and silicones etc. to be waterproof agent of main component etc.
Among the present invention, except method based on above-mentioned steps, can also adopt outside on the heat insulating base coating be coated with down material, ornamental be coated with material after, in the ornamental method that is coated with formation seam on the material layer etc.But, in this case, note not switching to base material.In this method, can carry out appropriate colouring on the formed seam.In this case, the seam look preferably with under be coated with the material layer and have same color.
Embodiment
Embodiment shown below is illustrated more clearly in feature of the present invention.
(being coated with the manufacturing of material 1 down)
Adopt common method evenly to be mixed and made into down the following resin 1 of 65 weight portions, membrane producing promoter 6.5 weight portions, thickener 2.5 weight portions, 14 parts by weight of titanium oxide, 60 weight % dispersion liquids, 1 weight portion yellow iron oxide, 60 weight % dispersion liquids, 4.2 weight portion black iron oxides, 50 weight % dispersion liquids, 6 weight parts waters and 0.8 weight portion defoamer and be coated with material 1.
Resin 1: sandwich construction type synthetic resin emulsion
Outer: acrolein resin (Tg5 ℃, constituent: methyl methacrylate, n-butylacrylic acid methyl esters, n-butylacrylic acid ester, 2-ethylhexyl acrylate, methacrylate),
Internal layer: silicones (constituent: pregnancy basic ring siloxanes at the tenth of the twelve Earthly Branches, octamethylcy-clotetrasiloxane, decamethylcyclopentaandoxane), acrolein resin is (Tg-35 ℃, constituent: n-butylacrylic acid methyl esters, n-butylacrylic acid ester, 2-ethylhexyl acrylate), the weight ratio of silicones and internal layer acrolein resin is 18: 82, weight ratio outer and internal layer is 45: 55, solid constituent is 50 weight %, and the carbonyl monomer is 3 weight % (in the solid constituent).
(being coated with the manufacturing of material 2 down)
Be coated with material 2 under the following resin 2 of 65 weight portions, membrane producing promoter 6.5 weight portions, thickener 2.5 weight portions, 14 parts by weight of titanium oxide, 60 weight % dispersion liquids, 1 weight portion yellow iron oxide, 60 weight % dispersion liquids, 4.2 weight portion black iron oxides, 50 weight % dispersion liquids, water 6 weight portions and defoamer 0.8 weight portion adopted common method evenly to mix to make.
Resin 2: sandwich construction type synthetic resin emulsion
Outer: acrolein resin (Tg5 ℃, constituent: t-butylacrylic acid methyl esters, n-butylacrylic acid methyl esters, n-butylacrylic acid ester, 2-ethylhexyl acrylate, methacrylate)
Internal layer: silicones (constituent: pregnancy basic ring siloxanes at the tenth of the twelve Earthly Branches, octamethylcy-clotetrasiloxane, decamethylcyclopentaandoxane), acrolein resin is (Tg-35 ℃, constituent: n-butylacrylic acid methyl esters, n-butylacrylic acid ester, the 2-ethylhexyl acrylate), the weight ratio of silicones and internal layer acrolein resin is 18: 82
Weight ratio outer and internal layer is 45: 55, and solid constituent is 50 weight %, carbonyl monomer 3 weight % (in the solid constituent)
(being coated with the manufacturing of material 3 down)
Be coated with material 3 under the following resin 3 of 65 weight portions, membrane producing promoter 6.5 weight portions, thickener 2.5 weight portions, 14 parts by weight of titanium oxide, 60 weight % dispersion liquids, 1 weight portion yellow iron oxide, 60 weight % dispersion liquids, 4.2 weight portion black iron oxides, 50 weight % dispersion liquids, water 6 weight portions and defoamer 0.8 weight portion adopted common method evenly to mix to make.
Resin 3: sandwich construction type synthetic resin emulsion
Outer: acrolein resin (Tg5 ℃, constituent: t-butylacrylic acid methyl esters, n-butylacrylic acid methyl esters, n-butylacrylic acid ester, 2-ethylhexyl acrylate, methacrylate);
Internal layer: acrolein resin (Tg-35 ℃, constituent; N-butylacrylic acid methyl esters, n-butylacrylic acid ester, 2-ethylhexyl acrylate);
Weight ratio outer and internal layer is that 50: 50, solid constituent are that 50 weight %, carbonyl monomer are 3 weight % (in the solid constituent)
(being coated with the manufacturing of material 4 down)
Be coated with material 4 under the following resin 4 of 65 weight portions, membrane producing promoter 6.5 weight portions, thickener 2.5 weight portions, 14 parts by weight of titanium oxide, 60 weight % dispersion liquids, 1 weight portion yellow iron oxide, 60 weight % dispersion liquids, 4.2 weight portion black iron oxides, 50 weight % dispersion liquids, water 6 weight portions and defoamer 0.8 weight portion adopted common method evenly to mix to make.
Resin 4: acrolein resin emulsion [Tg-10 ℃, constituent: t-butylacrylic acid methyl esters, n-butylacrylic acid methyl esters, n-butylacrylic acid ester, the 2-ethylhexyl acrylate, methacrylate, solid constituent 50 weight %, carbonyl contain monomer 3 weight % (in the solid constituent)]
(manufacturing of multicolor pattern paint 1)
Black particles dispersion liquid 1
At first, in container, the resin 5 of following 85.0 weight portions is feeded, when stirring, membrane producing promoter 8.3 weight portions, water 5.7 weight portions, gelatinizing agent (aluminum sulfate) 0.5 weight portion, defoamer 0.5 weight portion evenly mixed make water-based dispersion medium 1 with the rotary speed of stirrer paddle 1800rpm.
Then, in another container, the resin 5 of 40.0 weight portions is feeded, when stirrer paddle stirs with the rotary speed of 1800rpm, membrane producing promoter 4.0 weight portions and black iron oxide 50 weight % dispersion liquids 12.0 weight portions, glue are formed material (the carbonyl methyl cellulose 2 weight % aqueous solution) 43.5 weight portions and defoamer 0.5 weight portion evenly mix and make black water coating 1.
To above-mentioned water-based dispersion medium 1 (100 weight portion), add the black water coating 1 of 100 weight portions, by disperseing (the rotary speed of stirrer paddle: 600rpm), obtain being dispersed with the black particles dispersion liquid 1 of the black particles of the about 2mm of particle diameter.
Brown particle dispersion 1
The resin 5 of charging 40.0 weight portions in container, when stirrer paddle stirs with the rotary speed of 1800rpm, membrane producing promoter 4.0 weight portions, titanium oxide 60 weight % dispersion liquids 3.5 weight portions, yellow iron oxide 60 weight % dispersion liquids 11.5 weight portions, black iron oxide 50 weight % dispersion liquid 0.2 weight portions and red oxide 60 weight % dispersion liquids 1.5 weight portions, glue are formed material (the carbonyl methyl cellulose 2 weight % aqueous solution) 43.5 weight portions and defoamer 0.5 weight portion evenly mix and make brown water paint 1.The aberration of this brown water paint 1 and above-mentioned black water coating 1 is 40.
To above-mentioned water-based dispersion medium 1 (100 weight portion), add the brown water paint 1 of 100 weight portions, by disperseing (the rotary speed of stirrer paddle: 1600rpm), obtain being dispersed with the brown particle dispersion 1 of the brown particle of the about 1mm of particle diameter.
Black particles dispersion liquid 1 that will obtain by above method and brown particle dispersion 1 mix with 2: 8 weight rate, to obtain multicolor pattern paint 1.
Resin 5: acrolein resin emulsion (methyl methacrylate-cyclohexyl methyl acrylate-butylacrylic acid ester-acrylic acid copolymer, the glass transition temperature: 35 ℃, solid constituent: 50 weight %)
(processing of stone material style is coated with the manufacturing of material 1)
Brown=2: 8), membrane producing promoter 18 weight portions, thickener 5 weight portions, defoamer 3 weight portions evenly mix to make the processing of stone material style with common method and resin 5 and be coated with material 1 preparing the resin 5 of 200 weight portions, directly is the painted aggregate mix (black: of 0.1～2mm with the particle of 380 weight portions.
(thin applying processed the manufacturing that is coated with material 1)
Prepare the resin 5 of 200 weight portions, silica sand (averaged particles is 500 μ m directly) 100 weight portions, kieselguhr (averaged particles footpath 40 μ mm) 200 weight portions, calcium carbonate (averaged particles footpath 40 μ m) 300 weight portions, titanium oxide 20 weight portions are coated with material 1 with the thin deposited processing that common method and resin 5 evenly mix to make the limestone style.
(experimental example 1)
On slabstone, paste tabular poly-stupid vinyl foam formation insulation material layer, and then to apply coating amount thereon be 0.5kg/m
2Mud, this mud is made up of active phenol A type epoxy resin 20 weight portions, amine hardener 20 weight portions, portland cement 100 weight portions, French chalk 80 weight portions, titanium oxide 80 weight portions, water 30 weight portions, additive 1 weight portion.Further, lamination glass mesh thereon, and then to apply coating amount thereon be 0.5kg/m
2This mud to form strengthening layer, with this as the base material of wanting application.
Whole spraying coating amounts to this base material are 0.3kg/m
2The following material 1 that is coated with, carry out 2 hours maintenance backs, bar-shaped seam material (joint gap 10mm, height 5mm, polyethylene system) pasted into clathrate by adhesive, to be coated with material spraying coating amount be 0.4kg/m as ornamental then
2Multicolor pattern paint 1, remove bar-shaped seam material, maintain and obtain the metope structure body after 7 days.In addition, above step is all carried out under standard state (23 ℃ of temperature, relative humidity 50%).
Resulting surface shows the good aesthetic property of the colorful sense with black and brown in the grid pattern based on the grey seam.
(experimental example 2)
Except by under be coated with material 1 and replace being coated with down the material 2, employing method similarly to Example 1 obtains the metope structure body.Resulting surface in the grid pattern based on the grey seam, has the colorful sense of black and brown, and shows good aesthetic property.
(experimental example 3)
Except with under be coated with material 3 and replace being coated with down the material 1, employing method similarly to Example 1 obtains the metope structure body.Resulting surface in the grid pattern based on the grey seam, has the colorful sense of black and brown, and shows good aesthetic property.
(experimental example 4)
Except with under be coated with material 4 and replace being coated with down the material 1, employing method similarly to Example 1 obtains the metope structure body.Resulting surface has the colorful sense of black and brown in the grid pattern based on the grey seam, and shows good aesthetic property.
(experimental example 5)
The base material that example 1 is by experiment obtained whole will be coated with material 2 down with coating amount 0.3kg/m
2Spray, after the maintenance in two hours, it is clathrate that bar-shaped seam material (seam width of cloth 10mm, height 10mm, polyethylene system) is pasted by adhesive, then, as the ornamental material that is coated with, the processing of stone material style is coated with material 1 with coating amount 1.0kg/m
2Spray, remove bar-shaped seam material, carry out maintenance in seven days and obtain the metope structure body.In addition, above step is all carried out under standard state (23 ℃ of temperature, relative humidity 50%).
Resulting surface in the grid pattern based on the grey seam, has the design of stone material style, shows good aesthetic property.
(experimental example 6)
Whole to the base material that obtains in the experimental example 1 are with coating amount 0.3kg/m
2After spraying is coated with down the maintenance of 2, two hour time of material, embedded seam material (seam width of cloth 10mm, height 2mm, polypropylene system, form and aspect: black) pasted by adhesive is clathrate, then,, will approach to apply to process and be coated with material 1 with coating amount 1.5kg/m as the ornamental material that is coated with
2Carry out application by trowel, remove the part of embedded seam material, maintained with seven day time, obtain the metope structure body.In addition, above step is all carried out under standard state (23 ℃ of temperature, relative humidity 50%).
Resulting surface in the grid pattern based on the black seam, has the design of limestone style, shows good aesthetic property.
With the part of the metope structure body made in the experimental example 1～6 take out as test body (60 * 40mm), carry out following experiment.
The weatherability experiment
In the weatherability experiment, use acceleration weatherability experimental machine [metal weather (Metal Weather)] (DAIPLA WINTES corporate system) to penetrate 4 hours with illumination, dewfall 4 hours (8 hours altogether) is carried out 80 cycles altogether for one-period.(A＞B＞C) carry out at 80 all after dates observation appearance of films, is designated " A " unusually to what can not discern, and the variable color that can identify, expand, peel off etc. is designated " C " by three phases in assessment.Experimental result is as shown in table 1.
The mimetism experiment
In mimetism experiment, with each experiment body (300 * 150mm) with 18 hours →-20 ℃ 3 hours → 80 ℃ of water logging bubbles (23 ℃) 3 hours as circulation once carry out cold and hot experiment repeatedly amount to circulate for ten times after, the state of observation experiment surface.(A＞B＞C) carry out is designated " A " unusually to what can not discern, and the expansion that can identify, peel off etc. is designated " C " by three phases in assessment.Experimental result is as shown in table 1.
The seal experiment
In seal experiment, each experiment body was soaked in 50 ℃ warm water after 6 times, go into to test film (the ornamental material portion that is coated with) of body central portion with the cutter crosscut, partly paste belt body in this crosscut and assess seal by peeling off.(A＞B＞C) carry out is designated [A] unusually to what can not discern, and peeling off of can identifying is designated [C] by three phases in assessment.Experimental result is as shown in table 1.
(table 1)
| ? | Experimental example 1 | Experimental example 2 | Experimental example 3 | Experimental example 4 | Experimental example 5 | Experimental example 6 |
| Weatherability | A | A | C | C | A | A |
| Mimetism | A | A | B | B | A | A |
| Seal | B | A | C | C | A | A |
Claims (4)
1. an external heat insulation decorative processing structure body is the structure on the skin face, and it comprises:
Outer heat insulating base, insulation material layer on materials for wall constitutes by materials for wall and lamination for it;
Under be coated with material layer and the ornamental material layer that is coated with, lamination is on outer heat insulating base, and the described ornamental material layer that is coated with is divided into a plurality of zones by seam; Described be coated with down following in the material layer be coated with material with synthetic resin as in conjunction with material, the skin of described synthetic resin is-20～100 ℃ carbonyl acrolein resin for the glass transition temperature, internal layer comprises sandwich construction type synthetic resin emulsion, and this sandwich construction type synthetic resin emulsion comprises the silicones that derives from cyclic siloxane compound and glass transition temperature and is-80～20 ℃ acrolein resin.
2. external heat insulation decorative processing structure body according to claim 1 is characterized in that described outer heat insulating base also comprises strengthening layer, and this strengthening layer lamination is on this insulation material layer, and this strengthening layer is made of polymer water mud layer and/or reticulate body.
3. external heat insulation decorative processing method, it comprises the steps:
A, outside the building the lamination insulation material layer obtains outer heat insulating base on the materials for wall of metope, is coated with the material layer to being coated with material under this outer heat insulating base coating to form down; Be coated with under described material with synthetic resin as in conjunction with material, the skin of described synthetic resin is-20～100 ℃ carbonyl acrolein resin for the glass transition temperature, internal layer comprises sandwich construction type synthetic resin emulsion, and this sandwich construction type synthetic resin emulsion comprises the silicones that derives from cyclic siloxane compound and glass transition temperature and is-80～20 ℃ acrolein resin;
B, paste the seam material on the surface that this time is coated with the material layer;
C, the ornamental material that is coated with of surface applied that obtains at step B;
D, part or all of seam material removed.
4. external heat insulation decorative processing method according to claim 3, it is characterized in that obtaining in the described steps A method of outer heat insulating base, more be included in the step of lamination strengthening layer on the heat-barrier material, this strengthening layer is made up of polymer water mud layer and/or reticulate body.
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| JP2007126769 | 2007-05-11 | ||
| JP2007-126769 | 2007-05-11 |
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| CN2008100967194A Expired - Fee Related CN101302881B (en) | 2007-05-11 | 2008-05-05 | External heat insulation decorative processing method and structural body |
| CNU200820112531XU Expired - Lifetime CN201198641Y (en) | 2007-05-11 | 2008-05-05 | External heat insulation decorative machining structure body |
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Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW201120289A (en) * | 2009-12-04 | 2011-06-16 | wei-zhi Huang | Waterproof and thermal insulated construction method of plastering. |
| TW201132838A (en) * | 2010-03-29 | 2011-10-01 | wei-zhi Huang | Mudwork waterproof and thermal insulation construction method (III) |
| CN103291026A (en) * | 2013-06-28 | 2013-09-11 | 广西防城港美好涂料有限公司 | Pattern textured coating wall body and construction method thereof |
| CN104234248B (en) * | 2014-09-04 | 2016-06-29 | 中利建设集团有限公司 | A kind of external heat insulating wall |
| JP6392741B2 (en) * | 2015-12-10 | 2018-09-19 | 株式会社ヤブ原 | Outside insulation method |
| CN106393870A (en) * | 2016-11-10 | 2017-02-15 | 包俊鸿 | Reinforced wall coating and processing method thereof |
| CN108118556A (en) * | 2017-04-27 | 2018-06-05 | 钟建军 | A kind of diatom ooze bionical building decorative wall paper surface material |
| CN111491799B (en) * | 2017-11-28 | 2023-05-12 | 陶氏环球技术有限责任公司 | Polyurethane-based heat insulation board |
| CN109138307A (en) * | 2018-10-16 | 2019-01-04 | 严园妹 | A kind of anti-hollowing wall of environmental protection and its construction method |
| JP7521739B2 (en) | 2019-07-31 | 2024-07-24 | 旭化成建材株式会社 | Thermal insulation methods for buildings, thermal insulation structures for buildings, adhesives, and surface protection materials |
| CN112521104B (en) * | 2020-12-24 | 2021-12-03 | 陕西省建筑科学研究院有限公司 | Cement mortar for geogrid reinforced masonry structure |
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| JP4711615B2 (en) * | 2002-12-27 | 2011-06-29 | エスケー化研株式会社 | Water-based coating composition and method for coating inorganic substrate |
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| JP4895564B2 (en) * | 2005-09-29 | 2012-03-14 | エスケー化研株式会社 | Joint formation method |
| JP2008007738A (en) * | 2005-09-29 | 2008-01-17 | Sk Kaken Co Ltd | Water paint composition and its coating method |
| JP4696000B2 (en) * | 2005-09-30 | 2011-06-08 | エスケー化研株式会社 | Wall structure |
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- 2008-05-05 CN CN2008100967194A patent/CN101302881B/en not_active Expired - Fee Related
- 2008-05-05 CN CNU200820112531XU patent/CN201198641Y/en not_active Expired - Lifetime
- 2008-05-08 JP JP2008122771A patent/JP5491003B2/en active Active
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| EP0086452A3 (en) * | 1982-02-12 | 1984-02-22 | Faster Gmbh & Co. Kg Befestigungstechnik | Method of fixing an insulating slab to be plastered to a building surface |
| DE19756131A1 (en) * | 1997-12-17 | 1999-06-24 | Pro Therm Gmbh & Co Kg | Heat insulating plate of three layers including projecting fabric layer |
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Also Published As
| Publication number | Publication date |
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| JP2008308981A (en) | 2008-12-25 |
| CN201198641Y (en) | 2009-02-25 |
| JP5491003B2 (en) | 2014-05-14 |
| CN101302881A (en) | 2008-11-12 |
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