CN106947318B - Preparation and application of dye-doped nanometer microsphere structure color-generating ink for textile digital jet printing - Google Patents
Preparation and application of dye-doped nanometer microsphere structure color-generating ink for textile digital jet printing Download PDFInfo
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- CN106947318B CN106947318B CN201710073370.1A CN201710073370A CN106947318B CN 106947318 B CN106947318 B CN 106947318B CN 201710073370 A CN201710073370 A CN 201710073370A CN 106947318 B CN106947318 B CN 106947318B
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- 239000004005 microsphere Substances 0.000 title claims abstract description 83
- 238000007639 printing Methods 0.000 title claims abstract description 42
- 239000004753 textile Substances 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000002612 dispersion medium Substances 0.000 claims abstract description 7
- 239000003906 humectant Substances 0.000 claims abstract description 7
- 239000004094 surface-active agent Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 239000000049 pigment Substances 0.000 claims abstract description 6
- 230000001105 regulatory effect Effects 0.000 claims abstract description 4
- 239000004744 fabric Substances 0.000 claims description 27
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 9
- 229910021641 deionized water Inorganic materials 0.000 claims description 9
- 238000001338 self-assembly Methods 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 8
- 239000011259 mixed solution Substances 0.000 claims description 8
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- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
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- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 229940015975 1,2-hexanediol Drugs 0.000 claims description 3
- JQXYBDVZAUEPDL-UHFFFAOYSA-N 2-methylidene-5-phenylpent-4-enoic acid Chemical compound OC(=O)C(=C)CC=CC1=CC=CC=C1 JQXYBDVZAUEPDL-UHFFFAOYSA-N 0.000 claims description 3
- GNYFFELFTGPXKK-UHFFFAOYSA-N 2-methylidene-5-phenylpent-4-enoic acid;methyl 2-methylprop-2-enoate Chemical compound COC(=O)C(C)=C.OC(=O)C(=C)CC=CC1=CC=CC=C1 GNYFFELFTGPXKK-UHFFFAOYSA-N 0.000 claims description 3
- FEIQOMCWGDNMHM-UHFFFAOYSA-N 5-phenylpenta-2,4-dienoic acid Chemical compound OC(=O)C=CC=CC1=CC=CC=C1 FEIQOMCWGDNMHM-UHFFFAOYSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 3
- 238000005485 electric heating Methods 0.000 claims description 3
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 claims description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 3
- 229920005862 polyol Polymers 0.000 claims description 3
- 150000003077 polyols Chemical class 0.000 claims description 3
- 229960004063 propylene glycol Drugs 0.000 claims description 3
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 3
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 3
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- 229940043375 1,5-pentanediol Drugs 0.000 claims description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 claims description 2
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 230000001276 controlling effect Effects 0.000 claims description 2
- 229940093476 ethylene glycol Drugs 0.000 claims description 2
- PCMWAHMJVPFNEV-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;5-phenylpenta-2,4-dienoic acid Chemical compound COC(=O)C(C)=C.OC(=O)C=CC=CC1=CC=CC=C1 PCMWAHMJVPFNEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000005543 nano-size silicon particle Substances 0.000 claims description 2
- 235000013772 propylene glycol Nutrition 0.000 claims description 2
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims description 2
- 230000002940 repellent Effects 0.000 claims description 2
- 239000005871 repellent Substances 0.000 claims description 2
- 239000000661 sodium alginate Substances 0.000 claims description 2
- 235000010413 sodium alginate Nutrition 0.000 claims description 2
- 229940005550 sodium alginate Drugs 0.000 claims description 2
- 229960002920 sorbitol Drugs 0.000 claims description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004038 photonic crystal Substances 0.000 abstract description 10
- 239000007787 solid Substances 0.000 abstract description 3
- 239000007921 spray Substances 0.000 abstract description 3
- 230000001360 synchronised effect Effects 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 10
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- 239000000377 silicon dioxide Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- -1 polyoxyethylene Polymers 0.000 description 2
- 101001018064 Homo sapiens Lysosomal-trafficking regulator Proteins 0.000 description 1
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- 235000010703 Modiola caroliniana Nutrition 0.000 description 1
- 244000038561 Modiola caroliniana Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
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- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
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- 238000009826 distribution Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002077 nanosphere Substances 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/39—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67383—Inorganic compounds containing silicon
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Coloring (AREA)
Abstract
The invention discloses a preparation method and application of dye-doped nanometer microsphere structure color-generating ink for textile digital jet printing, which is mainly obtained by uniformly dispersing a mixture of the following components in parts by weight: 1.0-5.0 parts of monodisperse nano microspheres (calculated by solid content), 0.1-1.5 parts of commercial grade dye, 0.1-1.0 part of humectant, 0.1-1.0 part of viscosity regulator, 0.1-1.0 part of pH regulator (pH 7-8 regulated), 0.1-3.0 parts of surfactant and 100 parts of dispersion medium. The dye-doped nano microsphere ink is specially developed for adapting to the color generation performance of a textile digital jet printing structure, and can realize synchronous generation of pigment color background and structural color on the textile. In order to meet the requirement of textile flexibility, the invention constructs the ultrathin structural color photonic crystal film by digital spray printing according to needs, and the hand feeling of the textile is hardly influenced.
Description
Technical Field
The invention relates to a digital jet printing technology of textiles, in particular to a preparation method of dye-doped nanometer microsphere structure color-generating ink and a method for constructing photonic crystal structure color generation by utilizing the dye-doped nanometer microsphere structure color-generating ink to perform digital jet printing on textiles.
Background
Photonic Crystals (PCs) belong to photon forbidden band materials and are a structural color generation mode commonly existing in nature. When the visible light wave band (380-780nm) falls into the specific forbidden band of the photonic crystal, the photonic crystal can selectively reflect the light forbidden to propagate in the forbidden band, the reflected light forms coherent diffraction on the surface of the photonic crystal with the periodically arranged structure, and human eyes can see gorgeous structural color. The way of constructing structure photon crystals on textiles by adopting microsphere dipping self-assembly technologies such as gravity settling and vertical settling is frequently reported, but the problems of long assembly time, material waste, incapability of positioning, assembly and coloring according to requirements and the like exist, and fabrics used for self-assembly in the report are required to be dyed into black in advance, so that the process flow and time are obviously further increased.
The invention prepares the dye-doped nano microsphere ink, uniformly disperses the dye among nano microsphere liquid, and applies the dye on the textile in a digital jet printing mode according to the needs. Under certain conditions, the nano-microspheres can be self-assembled on the textile, and the dye can be dyed and fixed, namely the textile can be used for constructing the structural color of the photonic crystal while coloring the pigment, and the textile is not required to be dyed with the ground color in advance. When the visible light wave band falls into the photon forbidden band, the un-forbidden light will be partially or completely absorbed by the dye on the textile, and the reflected light can still form diffraction on the surface of the colloid microballoon which is periodically arranged to present colorful structural color.
The invention provides a preparation method of dye-doped nano microsphere ink and application of the dye-doped nano microsphere ink to the technical field of textile structure color generation in a digital jet printing mode.
Disclosure of Invention
The invention aims to provide preparation and application of dye-doped nanometer microsphere structure chromogenic ink for digital jet printing of textiles.
In order to solve the technical problems, the following technical scheme is adopted:
a dye-doped nanometer microsphere structure color-generating ink for textile digital jet printing is characterized in that: the dye-doped nano microspheric ink is obtained by uniformly dispersing a mixture of the following components in parts by weight: 1.0-5.0 parts of monodisperse nano microspheres (calculated by solid content), 0.1-1.5 parts of commercial grade dye, 0.1-1.0 part of humectant, 0.1-1.0 part of viscosity regulator, 0.1-1.0 part of pH regulator (regulating pH7-8), 0.1-3.0 parts of surfactant and 100 parts of dispersion medium.
Preferably, the monodisperse nano-microsphere is nano polystyrene (PSt) colloidal microsphere, nano polymethyl methacrylate (PMMA) colloidal microsphere, nano poly (styrene-methacrylic acid) (P (St-MAA)) colloidal microsphere, nano poly (styrene-acrylic acid) (P (St-AA)) colloidal microsphere, nano poly (styrene-methacrylic acid-methyl methacrylate) (P (St-MAA-MMA)) colloidal microsphere, nano poly (styrene-acrylic acid-methyl methacrylate) (P (St-MAA-MMA)) colloidal microsphere and nano silicon dioxide (SiO) (SiO (MMA)) -colloidal microsphere2) Any one of colloidal microspheres.
Preferably, the particle size range of the monodisperse nano microsphere is 180-380 nm.
Preferably, the monodisperse nano microsphere has good sphericity and a monodisperse index (PDI) of not more than 0.08.
Preferably, the dye is a commercial grade reactive dye or a commercial grade acid dye.
Preferably, the humectant is any one of glycerol, diethylene glycol, triethylene glycol, ethylene glycol, 1, 2-hexanediol, 1, 2-propanediol, sorbitol, 1, 5-pentanediol, and 2-pyrrolidone.
Preferably, the viscosity modifier is any one of polyvinylpyrrolidone, glycerol polyoxyethylene ether, polyether polyol and sodium carboxymethylcellulose.
Preferably, the surfactant is any one of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, sodium stearate and alkylphenol polyoxyethylene.
Preferably, the pH regulator is any one of sodium carbonate, sodium bicarbonate, sodium hydroxide, triethanolamine, and disodium hydrogen phosphate.
The dye-doped nanometer microsphere structure color-generating ink for digital jet printing of textiles according to claim 1, which is characterized in that: the dispersion medium is deionized water or a mixed solution of deionized water and ethanol with different volume ratios (such as 10:1, 7:1, 5:1, 3:1, 1:2, 1:4, 1:7 and 1: 10).
A preparation method of dye-doped nanometer microsphere structure color-generating ink for textile digital jet printing is characterized by comprising the following specific processes: accurately weighing the nano microsphere dispersion liquid according to the proportion, sequentially adding commercial dye, humectant, viscosity regulator, surfactant and dispersion medium to prepare a mixed solution, regulating the pH of the system to be 7-8 by using the pH regulator, and dispersing the mixed solution in an ultrasonic disperser for more than 15min to obtain the uniformly dispersed dye-doped nano microsphere ink.
The application of dye-doped nanometer microsphere structure color-generating ink for textile digital jet printing in textile digital jet printing is characterized by comprising the following steps of:
a. adding the dye-doped nano microsphere ink into an ink container of a digital control ink jet system for simulating digital jet printing, controlling the size of jet droplets through the selection of the size of a nozzle and the adjustment of jet pressure, setting a precise control jet printing position through a three-dimensional numerical control program, and carrying out jet printing on the surface of the pretreated fabric to be printed by using the dye-doped nano microsphere ink according to a designed pattern;
b. placing the sprayed and printed fabric in an electric heating constant-temperature oven, and treating for 10-20min under the conditions that the temperature in the oven is kept at 60-70 ℃ and air blast is accompanied, so that the colloid microspheres finish a self-assembly process on the surface of the fabric to generate structural color;
c. and (3) placing the dried fabric into a cylindrical steamer, and steaming for 1-5min under the conditions that the steamer is supersaturated with steam and the temperature is 100-105 ℃ to generate the pigment base color.
Preferably, the fabric to be printed is a real silk fabric or a cotton fabric, and has no background color requirement.
Preferably, the pretreatment of the fabric to be printed is water repellent finishing of sodium alginate/waterproof agent.
Due to the adoption of the technical scheme, the method has the following beneficial effects:
compared with the prior art, the invention has the advantages that: the dye and the nano microspheres are used as main ink components, and the dye-doped nano microsphere ink is applied to the textile in a digital jet printing mode, so that the base color of the dye pigment and the structural color of the photonic crystal are synchronously constructed, the color generation effect positioned as required is realized, the step of dyeing the textile in advance is omitted, and the practical application of the bionic structure color generation to the textile is facilitated.
The formula of the dye-doped nano microsphere ink is specially developed for adapting to the color generation performance of a digital printing structure of a textile. In order to meet the requirement of textile flexibility, the ultra-thin photonic crystal structure film is constructed by digital spraying according to needs, and the hand feeling of the textile is hardly influenced. It should be noted that the different nanospheres have different charging properties, and therefore other components in the ink system need to be optimized and adjusted accordingly, but similar to the concept of the present invention, they are within the protection scope of the present invention.
Drawings
The invention will be further described with reference to the accompanying drawings in which:
FIG. 1 is a schematic view of the operation flow of digital jet printing according to the present invention;
FIG. 2 is a schematic diagram of an analog digital inkjet printing according to the present invention;
FIG. 3 shows the jet printing color-developing effect (mauve) of reactive dye doped with nano microspheric ink on real silk fabric;
FIG. 4 shows the reactive dye doped with nano microspheric ink, which is printed on a real silk fabric in a jet printing manner to generate color (orange);
FIG. 5 shows the color-developing effect (brilliant yellow) of the reactive dye doped with the nano-microsphere ink on the real silk fabric;
FIG. 6 is a jet printing color-developing effect (light green) of reactive dye doped with nano microspheric ink on real silk fabric;
FIG. 7 is a jet printing color-developing effect (blue) of reactive dye doped with nano microspheric ink on real silk fabric;
FIG. 8 shows the color-developing effect of reactive dye doped with nano microspheric ink in jet printing on silk fabric (cyan).
Detailed Description
The solution of the invention is illustrated below by means of non-limiting examples;
in the following experimental examples, reagents, materials and equipment used were either commercially available or prepared by conventional methods or commonly used in the industry, unless otherwise specified.
Wherein, analog digital injection system: a digital liquid dispensing system, model D-585, manufactured by Nordson Asymtek, USA, was used.
Example 1:
(1) accurately weighing 3.0 parts (by solid content) of nano poly (styrene-methacrylic acid) (P (St-MAA)) colloidal microsphere emulsion (the particle size is 246nm, the monodispersion index is 0.02) and 130.1 parts of C.I. active black, adding 0.5 part of glycerol, 0.5 part of polyvinylpyrrolidone, 0.5 part of sodium dodecyl sulfate and 100 parts of deionized water, then adding 0.3 part of sodium carbonate solution to adjust the pH value to be 7-8, mixing the components, and then placing the mixture in an ultrasonic disperser to disperse for 15min to obtain the uniformly dispersed dye-doped nano microspheric ink.
(2) Loading dye-doped colloid microspheric ink to a digital liquid distribution system, setting spray printing parameters, and spray printing the dye-doped colloid microspheric ink on the surface of the pretreated real silk fabric according to the designed pattern positioning and requirements;
(3) placing the fabric with the jet printing dye doped with the nano microsphere ink in an electric heating constant temperature oven, and treating for 10-20min at the temperature of 60-70 ℃ under the condition of air blast to enable the colloidal microspheres to complete a self-assembly process on the surface of the fabric to generate structural color;
(4) steaming conditions are as follows: and (3) placing the dried fabric into a cylindrical steamer, and steaming for 1-5min under the conditions that the steamer is supersaturated with steam and the temperature is 100-105 ℃ to generate pigment color.
Example 2:
accurately weighing 5.0 parts of nano poly (styrene-acrylic acid) (P (St-AA)) colloidal microsphere emulsion (the particle size is 345nm and the monodispersion index is 0.05) and 80.5 parts of C.I. active black, adding 1.0 part of ethylene glycol, 0.1 part of glycerol polyoxyethylene ether, 1.0 part of sodium dodecyl sulfate and 100 parts of deionized water, then adding 1.0 part of sodium bicarbonate solution to adjust the pH value to be 7-8, mixing the components, and then placing the mixture in an ultrasonic disperser to disperse for 15min to obtain the uniformly dispersed dye-doped colloidal microsphere ink.
The digital jet printing, self-assembly conditions and method and steaming conditions were the same as those of (2), (3) and (4) in example 1.
Example 3:
accurately weighing 4.0 parts of nano polystyrene (PSt) colloidal microsphere emulsion (the particle size is 200nm, the monodispersion index is 0.02), 30.5 parts of C.I. active yellow, adding 0.1 part of 1, 2-hexanediol, 0.8 part of polyether polyol, 0.8 part of sodium dodecyl benzene sulfonate and 100 parts of deionized water, then adding 0.3 part of sodium carbonate solution to adjust the pH value to 7-8, mixing the components, and then placing the mixture in an ultrasonic disperser for dispersing for 15min to obtain the uniformly dispersed dye-doped colloidal microsphere ink.
The digital jet printing, self-assembly conditions and method and steaming conditions were the same as those of (2), (3) and (4) in example 1.
Example 4:
3.0 parts of nano poly (styrene-methacrylic acid-methyl methacrylate) (P (St-MAA-MMA)) colloidal microsphere emulsion (with the particle size of 286nm and the monodispersion index of 0.03) and 241.5 parts of C.I. active red are accurately weighed, 1.0 part of 1, 2-propylene glycol, 1.0 part of polyvinylpyrrolidone, 1.0 part of sodium stearate and 100 parts of deionized water/ethanol mixed solution (the volume ratio of the two is 7:1) are added, then 0.5 part of disodium hydrogen phosphate solution is added to adjust the pH value to be 7-8, all the components are mixed and then placed in an ultrasonic disperser to be dispersed for 15min, and the uniformly dispersed dye-doped colloidal microsphere ink is obtained.
The digital jet printing, self-assembly conditions and method and steaming conditions were the same as those of (2), (3) and (4) in example 1.
Example 5:
accurately weighing silicon dioxide (SiO)2)1.0 portion of colloid microsphere emulsion (the grain diameter is 265nm, the monodispersion index is 0.03), 1090.5 portions of C.I. acid black, 1.0 portion of sorbitol and sodium carboxymethylcellulose are added0.8 part of dye-doped colloid microspheric ink, 0.1 part of alkylphenol ethoxylates and 100 parts of deionized water/ethanol mixed solution (the volume ratio of the two is 10:1), then 0.1 part of sodium hydroxide solution is added to adjust the pH value to 7-8, and the components are mixed and then placed in an ultrasonic disperser to be dispersed for 15min to obtain the uniformly dispersed dye-doped colloid microspheric ink.
The digital jet printing, self-assembly conditions and method and steaming conditions were the same as those of (2), (3) and (4) in example 1.
In order to make the technical solutions and features of the present invention more clearly understood and readily appreciated by those of ordinary skill in the art, the above-described embodiments are merely illustrative of the present invention and are not intended to limit the present invention. Any simple changes, equivalent substitutions or modifications made on the basis of the present invention to solve the same technical problems and achieve the same technical effects are all covered in the protection scope of the present invention.
Claims (5)
1. A dye-doped nanometer microsphere structure color-generating ink for textile digital jet printing is characterized in that: the dye-doped nano microspheric ink is obtained by uniformly dispersing a mixture of the following components in parts by weight: 1.0-5.0 parts of monodisperse nano microsphere emulsion; 0.1-1.5 parts of commercial grade dye, 0.1-1.0 part of humectant, 0.1-1.0 part of viscosity regulator, 0.1-1.0 part of pH regulator, 0.1-3.0 parts of surfactant and 100 parts of dispersion medium; wherein the humectant is any one of glycerol, diethylene glycol, triethylene glycol, ethylene glycol, 1, 2-hexanediol, 1, 2-propanediol, sorbitol, 1, 5-pentanediol and 2-pyrrolidone; the viscosity regulator is any one of polyvinylpyrrolidone, glycerol polyoxyethylene ether, polyether polyol and sodium carboxymethylcellulose;
wherein the monodisperse nano-microsphere is any one of a nano polystyrene colloidal microsphere, a nano polymethyl methacrylate colloidal microsphere, a nano poly (styrene-methacrylic acid) colloidal microsphere, a nano poly (styrene-acrylic acid) colloidal microsphere, a nano poly (styrene-methacrylic acid-methyl methacrylate) colloidal microsphere, a nano poly (styrene-acrylic acid-methyl methacrylate) colloidal microsphere and a nano silicon dioxide colloidal microsphere;
the particle size range of the monodisperse nano microsphere is 180-380nm, the sphericity of the monodisperse nano microsphere is good, and the monodisperse index of the monodisperse nano microsphere is not more than 0.08.
2. The dye-doped nanometer microsphere structure color-generating ink for digital jet printing of textiles according to claim 1, which is characterized in that: any one of the surfactants of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, sodium stearate and alkylphenol polyoxyethylene ether; the pH regulator is any one of sodium carbonate, sodium bicarbonate, sodium hydroxide, triethanolamine and disodium hydrogen phosphate.
3. The dye-doped nanometer microsphere structure color-generating ink for digital jet printing of textiles according to claim 1, which is characterized in that: the dispersion medium is any one of deionized water and mixed solution of deionized water/ethanol with different volume ratios.
4. The preparation method of the dye-doped nanometer microsphere structure color-generating ink for digital jet printing of textiles according to claim 1, which is characterized by comprising the following specific steps: accurately weighing the monodisperse nano microsphere emulsion according to the proportion, sequentially adding commercial dye, humectant, viscosity regulator, surfactant and dispersion medium to prepare a mixed solution, regulating the pH of the system to be 7-8 by using the pH regulator, and dispersing the mixed solution in an ultrasonic disperser for more than 15min to obtain the uniformly dispersed dye-doped nano microsphere ink.
5. The application of the dye-doped nanometer microsphere structure color-generating ink for textile digital jet printing in textile digital jet printing according to claim 1 is characterized by comprising the following steps:
a. adding the dye-doped nanometer microsphere structure color-generating ink into an ink container of a digital control ink jet system for simulating digital jet printing, controlling the size of jet liquid drops through the selection of the size of a nozzle and the adjustment of jet pressure, setting a precise control jet printing position through a three-dimensional numerical control program, and carrying out jet printing on the surface of the pretreated fabric to be printed by using the dye-doped nanometer microsphere structure color-generating ink according to a designed pattern; the fabric to be printed is a real silk fabric and a cotton fabric, and has no ground color requirement, and the pretreatment of the fabric to be printed is water repellent finishing of sodium alginate/waterproof agent;
b. placing the sprayed and printed fabric in an electric heating constant-temperature oven, and treating for 10-20min under the conditions that the temperature in the oven is kept at 60-70 ℃ and air blast is accompanied, so that the monodisperse nano microsphere emulsion is subjected to a self-assembly process on the surface of the fabric to generate structural color;
c. and (3) placing the dried fabric into a cylindrical steamer, and steaming for 1-5min under the conditions that the steamer is supersaturated with steam and the temperature is 100-105 ℃ to generate the pigment base color.
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| CN108442138B (en) * | 2018-02-08 | 2020-10-02 | 浙江理工大学 | Preparation method of surface adsorption dye type nano microsphere structure color-generating ink for textile digital jet printing self-assembly |
| CN108532285A (en) * | 2018-04-26 | 2018-09-14 | 天津日津科技股份有限公司 | A kind of intelligent sound box cloth and preparation method with nanometer layer |
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| CN111379174A (en) * | 2018-12-27 | 2020-07-07 | 浙江理工大学 | Structural color-generating finishing liquid for preparing high-stability photonic crystal and application |
| CN110283495A (en) * | 2019-03-29 | 2019-09-27 | 浙江理工大学 | A kind of microballoon ink and its preparation method and application to add lustre to for textile constructions |
| CN110791981A (en) * | 2019-10-12 | 2020-02-14 | 浙江理工大学 | Preparation method of photonic crystal structure chromogenic fabric based on deep-implantation self-assembly effect |
| CN111254726A (en) * | 2020-02-27 | 2020-06-09 | 浙江理工大学 | Structural color-producing textile with asymmetric wetting characteristic and preparation method and application thereof |
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