CN106350291A - 一种内衣裤洗涤用洗衣凝珠及其制备方法 - Google Patents
一种内衣裤洗涤用洗衣凝珠及其制备方法 Download PDFInfo
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- CN106350291A CN106350291A CN201610713273.XA CN201610713273A CN106350291A CN 106350291 A CN106350291 A CN 106350291A CN 201610713273 A CN201610713273 A CN 201610713273A CN 106350291 A CN106350291 A CN 106350291A
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- laundry
- pearl
- washing
- alcohol
- condensate beads
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Classifications
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- C—CHEMISTRY; METALLURGY
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
- C11D3/2013—Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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Abstract
本发明涉及洗涤剂领域,特别是涉及一种内衣裤洗涤用洗衣凝珠及其制备方法。一种内衣裤洗涤用洗衣凝珠,由水溶膜及其内的清洗液构成,清洗液按由以下的组分制备得到:丙二醇、山梨醇、甘油、十二烷基苯磺酸、乙醇胺、非离子表面活性剂、椰子油酸、马来酸/丙烯酸共聚物、螯合剂、乙醇、杀菌剂、季铵盐有机硅氧烷、去离子水、香精、苦味剂、酶。本发明的产品降低阴离子表面活性剂添加量,减少对皮肤的刺激,对常见致病菌有较强的杀灭作用。添加柔顺成分,衣物洗后不干结、硬挺,提高舒适度。
Description
技术领域
本发明涉及洗涤剂领域,特别是涉及一种内衣裤洗涤用洗衣凝珠及其制备方法。
背景技术
传统的洗衣液主要活性物质为直链十二烷基苯磺酸盐和其他助洗剂;直链十二烷基苯磺酸盐来源于石化产品,属于不可再生原料,且该原料不耐硬水,在自来水环境下去污力大大降低,不利于洗涤;其他助剂,4A沸石、如三聚磷酸钠含有磷、不利于环境保护;铝,纯碱、烧碱碱性较高,易使衣物褪色,损伤衣物;芒硝属于填充物,无效循环利用,会给运营带来不必要的浪费。此外,普通液体洗涤剂利用常规表面活性剂和碱性助剂,仅具有洗涤清洁作用,柔顺效果欠佳。
中国发明专利申请(申请号CN201510437124.0申请日2015.07.23)公开了一种多功能洗衣凝珠,其重量百分比组分包括:C14-16烯烃磺酸钠30-35%、脂肪醇聚氧乙烯醚(9EO)15-20%、十二烷基苯磺酸10-12%、阳离子烷基多糖苷5-8%、乙二胺四乙酸二钠0.01-0.03%、D-泛醇1-2%、苯氧乙醇0.3-0.7%、香精0.1-0.3%、三氯生0.05-0.1%、蛋白酶0.01-0.03%、余量为去离子水。该产品具有洗涤、护理、杀菌、消臭、愉悦身心多重功效,节能减排,使用方便。
中国发明专利申请(申请号CN201510436322.5申请日2015.07.23)公开了一种精油洗衣凝珠,其重量百分比组分包括:20~25%的C14-16烯烃磺酸钠、15~20%的脂肪醇聚氧乙烯醚(9EO)、10~12%的脂肪醇聚氧乙烯醚硫酸钠、8~10%的月桂醇硫酸酯三乙醇胺盐、2~4%的聚乙二醇、1~3%的阳离子烷基多糖苷、1~2%的D-泛醇、0.3~0.7%的苯氧乙醇、0.05~0.01%的乙二胺四乙酸二钠、0.5~1%的茉莉精油、0.05~0.1%的三氯生、0.1~0.2%的蛋白酶、0.002~0.005%的红33色素,余量为去离子水。该产品具有洗涤、护理、杀菌、消臭、愉悦身心多重功效,使用方便。
中国发明专利申请(申请号CN201610216176.X申请日2016.04.09)公开了一种柔顺洗衣凝珠及其制备方法,该洗衣凝珠包括25~35%异构C13脂肪醇聚氧乙烯醚、10~20%脂肪醇聚氧乙烯醚(9EO)、10~20%脂肪醇聚氧乙烯醚硫酸钠、5~10%脂肪醇聚氧乙烯醚(7EO)、1.5~2.5%洗涤增效剂WR、1.5~2.5%异构醇聚氧乙烯醚、0.8~1.5%阳离子柔顺剂、0.02~0.05%杀菌剂、0.5~1.0%微胶囊香精、0.01-0.03%碱性蛋白酶和20~38%溶剂(丙二醇),该产品具有较强的赋香性、使用安全方便、洗涤能力和柔顺效果较好等特点。
上述的各种洗衣凝珠具有不同配方,同时也具有不同的功能和效果,随着洗衣凝珠的推广,消费者对洗衣凝珠有不同的需求,因此有必要对细分的产品进行开发生产。
发明内容
本发明的第一个目的是提供一种内衣裤洗涤用洗衣凝珠,该洗衣凝珠对常见致病菌有较强的杀灭作用,衣物洗后不干结、硬挺,提高舒适度。本发明的第二个目的是提供上述的洗衣凝珠的制备方法。
为了实现上述的第一个目的,本发明采用了以下的技术方案:
一种内衣裤洗涤用洗衣凝珠,由水溶膜及其内的清洗液构成,清洗液按质量百分比计由以下的组分制备得到:
丙二醇 8-20%
山梨醇 2-9%
甘油 2-5%
十二烷基苯磺酸 10-40%
乙醇胺 3-10%
非离子表面活性剂 10-40%
椰子油酸 5-15%
马来酸/丙烯酸共聚物 0.5-2%
螯合剂 0.5-2%
乙醇 0.5-3%
杀菌剂 0.2-1%
季铵盐有机硅氧烷 0.4-1.0%
去离子水 3-20%
香精 0.7-2%
厌恶剂 0.0001-0.02%
酶 0.05-2%。
作为优选,该清洗液珠按质量百分比计由以下的组分制备得到:
丙二醇 10-20%
山梨醇 2-7%
甘油 3-4%
十二烷基苯磺酸 15-35%
乙醇胺 4-8%
非离子表面活性剂 15-35%
椰子油酸 8-12%
马来酸/丙烯酸共聚物 0.8-1.5%
螯合剂 0.8-1.5%
乙醇 0.8-2.5%
杀菌剂 0.2-1%
季铵盐有机硅氧烷 0.4-1.0%
去离子水 5-15%
香精 0.8-1.5%
厌恶剂 0.0001-0.02%
酶 0.1-1.5%。
作为优选,所述的丙二醇含量12-19%,且山梨醇含量在2-5%时。产品保湿能力最好,丙二醇含量增加,水溶膜容易变干、变脆。
作为优选,清洗液的水含量在8-18%时,产品外观和稳定性最佳。含水量小,水溶膜容易变干、变脆,含水量大,产品较软,容易破裂。
作为优选,乙醇含量0.6-2%时,对产品增溶及对气味的影响最佳,含量小,产品容易浑浊,含量多,会影响最终产品的味道。
作为优选,所述的非离子表面活性剂包括烷基酚的聚氧乙烯醚、脂肪醇聚氧乙烯醚、脂肪酸甲酯聚氧乙烯醚和净洗剂6501中的一种或多种。作为优选,所述的脂肪醇聚氧乙烯醚选用月桂醇聚氧乙烯醚、12-14碳伯醇聚氧乙烯醚、12-14碳仲醇聚氧乙烯醚、支链化13碳格尔伯特醇聚氧乙烯醚、支链化10碳格尔伯特醇聚氧乙烯醚、直链的10碳醇聚氧乙烯醚、直链的8碳辛醇聚氧乙烯醚、直链的8碳异辛醇聚氧乙烯醚中的一种或多种。
作为优选,所述的非离子表面活性剂中AEO-7:AEO-9=1.7:1-2.3:1或AEO-9:AEO-3=1:1.2–1:2;所述的非离子表面活性剂:十二烷基苯磺酸=2:8-3:7。上述的配方活性物带来的去污能力最强。
乙醇胺用于生成十二烷基苯磺酸乙醇胺和椰子油酸乙醇胺。作为优选,所述的乙醇胺选用单乙醇胺、三乙醇胺、二乙醇胺中的一种或多种混合。中和十二烷基苯磺酸时,最优选择原料排序为:单乙醇胺、三乙醇胺、二乙醇胺。
作为优选,所述的防腐剂选用苯甲酸、苯甲酸钠、山梨酸、山梨酸钾、丙酸钙中的一种或多种混合。
作为优选,所述的厌恶剂选用糖精苄铵酰胺和苯甲地钠铵中的一种或两种混合。
作为优选,所述的酶选用蛋白酶、脂肪酶、淀粉酶、纤维素酶中的一种或多种混合。
作为优选,所述的杀菌剂采用玉洁新与其他复配。
为了实现上述的第二个目的,本发明采用了以下的技术方案:
一种制备上述任意一个技术方案所述的洗衣凝珠的方法,该方法包括以下的步骤:
1)按丙二醇、山梨醇、甘油、十二烷基苯磺酸、单乙醇胺、非离子表面活性剂、椰子油酸、马来酸/丙烯酸共聚物、螯合剂顺序依次加入原料,温度低于50℃时,加入乙醇、杀菌剂、季铵盐有机硅氧烷、去离子水、香精、厌恶剂和酶混合;
2)液体合格后,进行水溶膜包装。
作为优选,所述的水溶膜可选材料聚乙烯醇、聚乙烯醇缩乙醛、聚乙烯吡咯烷酮、聚丙烯酸、马来酸/丙烯酸共聚物、淀粉、明胶、黄原胶、瓜尔胶、羟丙基甲基纤维素,以及以上成分的均聚、共聚物和改性成分中的一种或多种混合。
本发明由于采用了上述的技术方案,与普通水基体系洗衣液比较,可以使活性物含量显著增加(含量可达80%以上),做到真正意义的超浓缩,减少包装用量、贮存空间和运输成本。本发明的产品降低阴离子表面活性剂添加量,减少对皮肤的刺激,对常见致病菌有较强的杀灭作用。添加柔顺成分,衣物洗后不干结、硬挺,提高舒适度。
具体实施方式
实施例1
一种内衣裤洗涤用洗衣凝珠,由水溶膜及其内的清洗液构成,清洗液按质量百分比计由以下的组分制备得到:
上述的洗衣凝珠的方法,该方法包括以下的步骤:
1)按丙二醇、山梨醇、甘油、十二烷基苯磺酸、单乙醇胺、非离子表面活性剂、椰子油酸、马来酸/丙烯酸共聚物、螯合剂顺序依次加入原料,温度低于50℃时,加入乙醇、杀菌剂、季铵盐有机硅氧烷、去离子水、香精、厌恶剂和酶混合;
2)液体合格后,进行水溶膜包装。包装方式可选用水封或热封。水溶膜可选材料聚乙烯醇、聚乙烯醇缩乙醛、聚乙烯吡咯烷酮、聚丙烯酸、马来酸/丙烯酸共聚物、淀粉、明胶、黄原胶、瓜尔胶、羟丙基甲基纤维素,以及以上成分的均聚、共聚物和改性成分。膜的组成可以是以上的单一成分,也可以是多种成分的混合。
本发明定量包装,使用方便,不会使液体沾到手上;减少使用中的浪费;浓缩配方在家庭中占用较小空间。包装使用水溶膜,在温度0-70℃时,4分钟内会全部溶于水中,无论机洗、手洗,都很方便。
实施例2
一种内衣裤洗涤用洗衣凝珠,由水溶膜及其内的清洗液构成,清洗液按质量百分比计由以下的组分制备得到:
上述的洗衣凝珠的方法,该方法包括以下的步骤:
1)按丙二醇、山梨醇、甘油、十二烷基苯磺酸、单乙醇胺、非离子表面活性剂、椰子油酸、马来酸/丙烯酸共聚物、螯合剂顺序依次加入原料,温度低于50℃时,加入乙醇、杀菌剂、季铵盐有机硅氧烷、去离子水、香精、厌恶剂和酶混合;
2)液体合格后,进行水溶膜包装。包装方式可选用水封或热封。水溶膜可选材料聚乙烯醇、聚乙烯醇缩乙醛、聚乙烯吡咯烷酮、聚丙烯酸、马来酸/丙烯酸共聚物、淀粉、明胶、黄原胶、瓜尔胶、羟丙基甲基纤维素,以及以上成分的均聚、共聚物和改性成分。膜的组成可以是以上的单一成分,也可以是多种成分的混合。
实施例3
一种内衣裤洗涤用洗衣凝珠,由水溶膜及其内的清洗液构成,清洗液按质量百分比计由以下的组分制备得到:
上述的洗衣凝珠的方法,该方法包括以下的步骤:
1)按丙二醇、山梨醇、甘油、十二烷基苯磺酸、单乙醇胺、非离子表面活性剂、椰子油酸、马来酸/丙烯酸共聚物、螯合剂顺序依次加入原料,温度低于50℃时,加入乙醇、杀菌剂、季铵盐有机硅氧烷、去离子水、香精、厌恶剂和酶混合;
2)液体合格后,进行水溶膜包装。包装方式可选用水封或热封。水溶膜可选材料聚乙烯醇、聚乙烯醇缩乙醛、聚乙烯吡咯烷酮、聚丙烯酸、马来酸/丙烯酸共聚物、淀粉、明胶、黄原胶、瓜尔胶、羟丙基甲基纤维素,以及以上成分的均聚、共聚物和改性成分。膜的组成可以是以上的单一成分,也可以是多种成分的混合。
Claims (10)
1.一种内衣裤洗涤用洗衣凝珠,由水溶膜及其内的清洗液构成,其特征在于清洗液按质量百分比计由以下的组分制备得到:
丙二醇 8-20%
山梨醇 2-9%
甘油 2-5%
十二烷基苯磺酸 10-30%
乙醇胺 3-10%
非离子表面活性剂 10-40%
椰子油酸 5-15%
马来酸/丙烯酸共聚物 0.5-2%
螯合剂 0.5-2%
乙醇 0.5-3%
杀菌剂 0.2-1%
季铵盐有机硅氧烷 0.4-1.0%
去离子水 3-20%
香精 0.7-2%
厌恶剂 0.0001-0.02%
酶 0.05-2%。
2.根据权利要求1所述的一种内衣裤洗涤用洗衣凝珠,其特征在于清洗液按质量百分比计由以下的组分制备得到:
丙二醇 10-15%
山梨醇 3-7%
甘油 3-4%
十二烷基苯磺酸 15-35%
乙醇胺 4-8%
非离子表面活性剂 15-35%
椰子油酸 8-12%
马来酸/丙烯酸共聚物 0.8-1.5%
螯合剂 0.8-1.5%
乙醇 0.8-2.5%
杀菌剂 0.2-1%
季铵盐有机硅氧烷 0.4-1.0%
去离子水 5-15%
香精 0.8-1.5%
厌恶剂 0.0001-0.02%
酶 0.1-1.5%。
3.根据权利要求1或2所述的一种内衣裤洗涤用洗衣凝珠,其特征在于丙二醇含量为12-19%,且山梨醇含量为2-5%。
4.根据权利要求1所述的一种内衣裤洗涤用洗衣凝珠,其特征在于非离子表面活性剂包括烷基酚的聚氧乙烯醚、脂肪醇聚氧乙烯醚、脂肪酸甲酯聚氧乙烯醚和净洗剂6501中的一种或多种;优选,脂肪醇聚氧乙烯醚选用月桂醇聚氧乙烯醚、12-14碳伯醇聚氧乙烯醚、12-14碳仲醇聚氧乙烯醚、支链化13碳格尔伯特醇聚氧乙烯醚、支链化10碳格尔伯特醇聚氧乙烯醚、直链的10碳醇聚氧乙烯醚、直链的8碳辛醇聚氧乙烯醚、直链的8碳异辛醇聚氧乙烯醚中的一种或多种。
5.根据权利要求1所述的一种内衣裤洗涤用洗衣凝珠,其特征在于非离子表面活性剂中AEO-7:AEO-9=1.7:1-2.3:1或AEO-9:AEO-3=1:1.2–1:2;所述的非离子表面活性剂:十二烷基苯磺酸=2:8-3:7。
6.根据权利要求1所述的一种内衣裤洗涤用洗衣凝珠,其特征在于乙醇胺选用单乙醇胺、
三乙醇胺、二乙醇胺中的一种或多种混合。
7.根据权利要求1所述的一种内衣裤洗涤用洗衣凝珠,其特征在于厌恶剂选用糖精苄铵酰胺和苯甲地钠铵中的一种或两种混合;酶选用蛋白酶、脂肪酶、淀粉酶、纤维素酶中的一种或多种混合。
8.根据权利要求1所述的一种内衣裤洗涤用洗衣凝珠,其特征在于杀菌剂采用玉洁新与其他复配。
9.一种制备权利要求1~8任意一项权利要求所述的洗衣凝珠的方法,其特征在于该方法包括以下的步骤:
1)按丙二醇、山梨醇、甘油、十二烷基苯磺酸、单乙醇胺、非离子表面活性剂、椰子油酸、马来酸/丙烯酸共聚物、螯合剂顺序依次加入原料,温度低于50℃时,加入乙醇、杀菌剂、季铵盐有机硅氧烷、去离子水、香精、厌恶剂和酶混合;
2)液体合格后,进行水溶膜包装。
10.根据权利要求9所述的洗衣凝珠的制备方法,其特征在于水溶膜可选材料聚乙烯醇、聚乙烯醇缩乙醛、聚乙烯吡咯烷酮、聚丙烯酸、马来酸/丙烯酸共聚物、淀粉、明胶、黄原胶、瓜尔胶、羟丙基甲基纤维素,以及以上成分的均聚、共聚物和改性成分中的一种或多种混合。
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CN113388458A (zh) * | 2021-06-08 | 2021-09-14 | 森川喀左生态科技发展有限公司 | 一种内衣专用酸性洗衣液 |
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