Nothing Special   »   [go: up one dir, main page]

BR9402019A - Processo para preparar um metaloceno ligado em forma de sanduíche e processo para a polimerização de uma olefina - Google Patents

Processo para preparar um metaloceno ligado em forma de sanduíche e processo para a polimerização de uma olefina

Info

Publication number
BR9402019A
BR9402019A BR9402019A BR9402019A BR9402019A BR 9402019 A BR9402019 A BR 9402019A BR 9402019 A BR9402019 A BR 9402019A BR 9402019 A BR9402019 A BR 9402019A BR 9402019 A BR9402019 A BR 9402019A
Authority
BR
Brazil
Prior art keywords
olefin
polymerization
preparing
bound metallocene
sandwich bound
Prior art date
Application number
BR9402019A
Other languages
English (en)
Inventor
Suriac J Palackal
Konstantinos Patsidis
Tara G Hill
Gil R Hawley
Peter P Chu
M Bruce Welch
Rolf L Geerts
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=22057254&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BR9402019(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Publication of BR9402019A publication Critical patent/BR9402019A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1608—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/54—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings
    • C07C13/547—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings at least one ring not being six-membered, the other rings being at the most six-membered
    • C07C13/567—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings at least one ring not being six-membered, the other rings being at the most six-membered with a fluorene or hydrogenated fluorene ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C22/00—Cyclic compounds containing halogen atoms bound to an acyclic carbon atom
    • C07C22/02—Cyclic compounds containing halogen atoms bound to an acyclic carbon atom having unsaturation in the rings
    • C07C22/04—Cyclic compounds containing halogen atoms bound to an acyclic carbon atom having unsaturation in the rings containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/703—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups
    • C07C49/747—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/373—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of functional groups containing oxygen only in doubly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
    • C07C63/33—Polycyclic acids
    • C07C63/331—Polycyclic acids with all carboxyl groups bound to non-condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
    • C07C63/33—Polycyclic acids
    • C07C63/49—Polycyclic acids containing rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C65/32—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing keto groups
    • C07C65/34—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing keto groups polycyclic
    • C07C65/36—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing keto groups polycyclic containing rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/0805—Compounds with Si-C or Si-Si linkages comprising only Si, C or H atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/22—Tin compounds
    • C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/02—Ortho- or ortho- and peri-condensed systems
    • C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
    • C07C2603/06—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members
    • C07C2603/10—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings
    • C07C2603/12—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings only one five-membered ring
    • C07C2603/18—Fluorenes; Hydrogenated fluorenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
BR9402019A 1993-05-20 1994-05-19 Processo para preparar um metaloceno ligado em forma de sanduíche e processo para a polimerização de uma olefina BR9402019A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/064,630 US5401817A (en) 1991-05-09 1993-05-20 Olefin polymerization using silyl-bridged metallocenes

Publications (1)

Publication Number Publication Date
BR9402019A true BR9402019A (pt) 1995-03-07

Family

ID=22057254

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9402019A BR9402019A (pt) 1993-05-20 1994-05-19 Processo para preparar um metaloceno ligado em forma de sanduíche e processo para a polimerização de uma olefina

Country Status (10)

Country Link
US (3) US5401817A (pt)
EP (2) EP0875517A1 (pt)
JP (1) JPH07138275A (pt)
KR (1) KR100352920B1 (pt)
BR (1) BR9402019A (pt)
CA (1) CA2117031C (pt)
DE (1) DE69416721T2 (pt)
ES (1) ES2128457T5 (pt)
FI (1) FI942333A (pt)
NO (1) NO941887L (pt)

Families Citing this family (84)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5466766A (en) * 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
CA2067525C (en) * 1991-05-09 1998-09-15 Helmut G. Alt Organometallic fluorenyl compounds, preparation and use
US5710222A (en) * 1992-06-22 1998-01-20 Fina Technology, Inc. Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems
KR0151873B1 (ko) * 1994-10-13 1998-10-15 김영욱 메탈로센 화합물, 이의 제조방법 및 이를 촉매로 이용한 고분자의 제조방법
DE69500763T2 (de) * 1994-10-13 1998-03-26 Japan Polyolefins Co Ltd Katalysatorkomponent zur Olefinpolymerisation, dieses enthaltenden Katalysator und Verfahren zur Olefinpolymerisation in Gegenwart dieses Katalysators
US6639030B2 (en) * 1994-10-25 2003-10-28 Tosoh Corporation Process for production of olefin polymer
US5770755A (en) * 1994-11-15 1998-06-23 Phillips Petroleum Company Process to prepare polymeric metallocenes
IT1275856B1 (it) 1995-03-03 1997-10-24 Spherilene Srl Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione
US6225426B1 (en) * 1996-04-10 2001-05-01 Uniroyal Chemical Company, Inc. Process for producing polyolefin elastomer employing a metallocene catalyst
US5945365A (en) * 1996-05-20 1999-08-31 Fina Technology, Inc. Stereorigid bis-fluorenyl metallocenes
US6313242B1 (en) 1996-05-20 2001-11-06 Fina Technology, Inc. Stereorigid bis-fluorenyl metallocenes
US6630550B1 (en) 1996-07-11 2003-10-07 Fina Research, S.A. Olefin polymerization catalyst
EP0818475A1 (en) * 1996-07-11 1998-01-14 Fina Research S.A. Syndiotactic/atactic block polyolefins, catalysts and processes for producing the same
EP1083188A1 (en) * 1999-09-10 2001-03-14 Fina Research S.A. Catalyst and process for the preparation of syndiotactic / atactic block polyolefins
DE19637669A1 (de) 1996-09-16 1998-03-19 Hoechst Ag Verfahren zur Herstellung einer methylenverbrückten Biscyclopentadienylverbindung
US6177377B1 (en) * 1996-12-18 2001-01-23 Amherst Polymer Technology, Inc. Polymer blends and process for preparation
US5886202A (en) * 1997-01-08 1999-03-23 Jung; Michael Bridged fluorenyl/indenyl metallocenes and the use thereof
CA2277292A1 (en) 1997-01-08 1998-07-16 Laura M. Babcock Solid acids as catalysts for the preparation of hydrocarbon resins
US6265512B1 (en) 1997-10-23 2001-07-24 3M Innovative Company Elastic polypropylenes and catalysts for their manufacture
EP0931814A1 (en) 1998-01-21 1999-07-28 Fina Research S.A. Polyolefins and uses thereof
DK0980375T3 (da) * 1998-01-30 2006-03-13 Boulder Scient Co Syntese af silylerede og N-silylerede forbindelser
US6677013B1 (en) 1998-04-17 2004-01-13 Pechiney Emballage Flexible Europe Transparent multilayer polypropylene container with barrier protection
EP1082355B1 (en) 1998-05-18 2008-10-15 Chevron Phillips Chemical Company Lp Catalyst composition for polymerizing monomers
US6225427B1 (en) 1998-10-15 2001-05-01 Uniroyal Chemical Company, Inc. Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst
US6528670B1 (en) 1998-10-23 2003-03-04 Exxonmobil Chemical Patents Inc. Bridged metallocenes for olefin copolymerization
EP1026199A1 (en) * 1999-02-03 2000-08-09 Fina Research S.A. Polyolefins and uses thereof
US6515086B1 (en) * 1999-02-19 2003-02-04 Fina Research, S.A. Polyolefin production
DE50006923D1 (de) * 1999-04-22 2004-08-05 Basell Polyolefine Gmbh Verfahren zur Herstellung von silylverbrückten Fluorenyl-Cyclopentadienyl-Liganden und silylverbrückten Fluorenyl-Cyclopentadienyl-Metallocenen
EP1074557A3 (de) * 1999-07-31 2003-02-26 Basell Polyolefine GmbH Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen
EP1242179B1 (en) 1999-12-16 2013-05-15 Chevron Phillips Chemical Company LP Organometal compound catalyst
US7041617B2 (en) 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
EP1263764B1 (en) * 2000-02-08 2004-04-14 ExxonMobil Chemical Patents Inc. Method of preparing group 14 bridged biscyclopentadienyl ligands
ATE297420T1 (de) * 2000-08-07 2005-06-15 Total Petrochemicals Res Feluy Polyolefinherstellung
EP1458549A4 (en) 2001-10-24 2008-12-10 Pechiney Emballage Flexible Eu POLYPROPYLENE CONTAINER AND MANUFACTURING METHOD THEREFOR
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7524910B2 (en) 2002-10-15 2009-04-28 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7696280B2 (en) 2004-04-30 2010-04-13 Chevron Phillips Chemical Company, Lp HDPE resins for use in pressure pipe and related applications
US7294599B2 (en) 2004-06-25 2007-11-13 Chevron Phillips Chemical Co. Acidic activator-supports and catalysts for olefin polymerization
US7163906B2 (en) * 2004-11-04 2007-01-16 Chevron Phillips Chemical Company, Llp Organochromium/metallocene combination catalysts for producing bimodal resins
US7514509B2 (en) * 2005-12-16 2009-04-07 Fina Technology, Inc. Catalyst compositions and methods of forming isotactic polyproyplene
US7517939B2 (en) 2006-02-02 2009-04-14 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching
US7619047B2 (en) * 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
US7601255B2 (en) 2006-09-06 2009-10-13 Chemtura Corporation Process for removal of residual catalyst components
WO2008059974A1 (fr) * 2006-11-17 2008-05-22 Mitsui Chemicals, Inc. Procédé pour produire un polypropylène syndiotactique
US7897539B2 (en) * 2007-05-16 2011-03-01 Chevron Phillips Chemical Company Lp Methods of preparing a polymerization catalyst
US7572948B2 (en) * 2007-05-16 2009-08-11 Chevron Phillips Chemical Company, Lp Fulvene purification
US8058200B2 (en) * 2007-05-17 2011-11-15 Chevron Phillips Chemical Company, L.P. Catalysts for olefin polymerization
US7799721B2 (en) 2007-09-28 2010-09-21 Chevron Phillips Chemical Company Lp Polymerization catalysts for producing polymers with high comonomer incorporation
US8119553B2 (en) 2007-09-28 2012-02-21 Chevron Phillips Chemical Company Lp Polymerization catalysts for producing polymers with low melt elasticity
US8114946B2 (en) 2008-12-18 2012-02-14 Chevron Phillips Chemical Company Lp Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches
KR101673043B1 (ko) 2009-06-16 2016-11-04 셰브론 필립스 케미컬 컴퍼니 엘피 메탈로센-ｓｓａ 촉매시스템을 이용한 알파 올레핀 올리고머화 및 윤활제 블렌드 제조를 위한 생성된 폴리알파올레핀의 용도
US8067652B2 (en) 2009-08-13 2011-11-29 Chemtura Corporation Processes for controlling the viscosity of polyalphaolefins
US8476394B2 (en) 2010-09-03 2013-07-02 Chevron Philips Chemical Company Lp Polymer resins having improved barrier properties and methods of making same
US8440772B2 (en) 2011-04-28 2013-05-14 Chevron Phillips Chemical Company Lp Methods for terminating olefin polymerizations
US8487053B2 (en) 2011-11-30 2013-07-16 Chevron Phillips Chemical Company Lp Methods for removing polymer skins from reactor walls
US8501882B2 (en) 2011-12-19 2013-08-06 Chevron Phillips Chemical Company Lp Use of hydrogen and an organozinc compound for polymerization and polymer property control
US8703883B2 (en) 2012-02-20 2014-04-22 Chevron Phillips Chemical Company Lp Systems and methods for real-time catalyst particle size control in a polymerization reactor
US10273315B2 (en) 2012-06-20 2019-04-30 Chevron Phillips Chemical Company Lp Methods for terminating olefin polymerizations
US8916494B2 (en) 2012-08-27 2014-12-23 Chevron Phillips Chemical Company Lp Vapor phase preparation of fluorided solid oxides
US8940842B2 (en) 2012-09-24 2015-01-27 Chevron Phillips Chemical Company Lp Methods for controlling dual catalyst olefin polymerizations
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8815357B1 (en) 2013-02-27 2014-08-26 Chevron Phillips Chemical Company Lp Polymer resins with improved processability and melt fracture characteristics
US9181369B2 (en) 2013-03-11 2015-11-10 Chevron Phillips Chemical Company Lp Polymer films having improved heat sealing properties
US10654948B2 (en) 2013-03-13 2020-05-19 Chevron Phillips Chemical Company Lp Radically coupled resins and methods of making and using same
US10577440B2 (en) 2013-03-13 2020-03-03 Chevron Phillips Chemical Company Lp Radically coupled resins and methods of making and using same
US9828451B2 (en) 2014-10-24 2017-11-28 Chevron Phillips Chemical Company Lp Polymers with improved processability for pipe applications
EP3294450A4 (en) 2015-05-11 2019-02-27 W.R. Grace & Co.-Conn. PROCESS FOR PRODUCING MODIFIED CLAY, MODIFIED CLAY PRODUCED AND USE THEREOF
RU2736492C2 (ru) 2015-05-11 2020-11-17 У.Р. Грейс Энд Ко.-Конн. Способ производства модифицированной глины, металлоценового катализатора полимеризации на подложке, производимого катализатора и их применение
US9708426B2 (en) 2015-06-01 2017-07-18 Chevron Phillips Chemical Company Lp Liquid-solid sampling system for a loop slurry reactor
WO2017078974A1 (en) 2015-11-05 2017-05-11 Chevron Phillips Chemical Company Lp Radically coupled resins and methods of making and using same
US9645131B1 (en) 2015-12-04 2017-05-09 Chevron Phillips Chemical Company Lp Polymer compositions having improved processability and methods of making and using same
US9645066B1 (en) 2015-12-04 2017-05-09 Chevron Phillips Chemical Company Lp Polymer compositions having improved processability and methods of making and using same
US10005861B2 (en) 2016-06-09 2018-06-26 Chevron Phillips Chemical Company Lp Methods for increasing polymer production rates with halogenated hydrocarbon compounds
US10550252B2 (en) 2017-04-20 2020-02-04 Chevron Phillips Chemical Company Lp Bimodal PE resins with improved melt strength
US10774161B2 (en) 2019-01-31 2020-09-15 Chevron Phillips Chemical Company Lp Systems and methods for polyethylene recovery with low volatile content
WO2021154204A1 (en) 2020-01-27 2021-08-05 Formosa Plastics Corporation, U.S.A. Process for preparing catalysts and catalyst compositions
US11339229B2 (en) 2020-01-27 2022-05-24 Formosa Plastics Corporation, U.S.A. Process for preparing catalysts and catalyst compositions
US12077616B2 (en) 2021-12-15 2024-09-03 Chevron Phillips Chemical Company Lp Production of polyethylene and ethylene oligomers from ethanol and the use of biomass and waste streams as feedstocks to produce the ethanol
US11845814B2 (en) 2022-02-01 2023-12-19 Chevron Phillips Chemical Company Lp Ethylene polymerization processes and reactor systems for the production of multimodal polymers using combinations of a loop reactor and a fluidized bed reactor
US20230331875A1 (en) 2022-04-19 2023-10-19 Chevron Phillips Chemical Company Lp Loop slurry periodogram control to prevent reactor fouling and reactor shutdowns
WO2023239560A1 (en) 2022-06-09 2023-12-14 Formosa Plastics Corporaton, U.S.A. Clay composite support-activators and catalyst compositions

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3364190A (en) * 1964-04-27 1968-01-16 Standard Oil Co Process for polymerizing propylene to syndiotactic polypropylene
US3426069A (en) * 1967-09-11 1969-02-04 Union Carbide Corp Bis(9-(substituted alkyl)fluoren-9-yl)alkanes
US4808561A (en) * 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4794096A (en) * 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
US4931417A (en) * 1987-11-09 1990-06-05 Chisso Corporation Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US5120867A (en) * 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
KR100197327B1 (ko) * 1988-07-15 1999-06-15 치어즈 엠. 노우드 신디오택틱 폴리프로필렌
DE3840772A1 (de) * 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
IT8919252A0 (it) * 1989-01-31 1989-01-31 Ilano Catalizzatori per la polimerizzazione di olefine.
IT1228916B (it) * 1989-02-28 1991-07-09 Himont Inc Polimeri a struttura sindiotattica delle alfa olefine
DE3907965A1 (de) † 1989-03-11 1990-09-13 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen polyolefins
DE3907964A1 (de) * 1989-03-11 1990-09-13 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen polyolefins
DE3922546A1 (de) * 1989-07-08 1991-01-17 Hoechst Ag Verfahren zur herstellung von cycloolefinpolymeren
JP3020250B2 (ja) * 1990-04-09 2000-03-15 三井化学株式会社 シンジオタクチックポリプロピレンの製造方法
JP2927885B2 (ja) * 1990-05-24 1999-07-28 三井化学株式会社 シンジオタクチックポリα―オレフィンの製造方法
ES2090209T3 (es) * 1990-11-12 1996-10-16 Hoechst Ag Metalocenos con ligandos basados en derivados de indenilo sustituidos en posicion 2, procedimiento para su preparacion y su empleo como catalizadores.
ES2071888T3 (es) * 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
US5252677A (en) * 1990-11-20 1993-10-12 Mitsubishi Petrochemical Company Limited Functionalized olefin polymers
AU9159191A (en) * 1990-12-28 1992-08-17 Exxon Chemical Patents Inc. Syndiotactic polypropylene
JP3048653B2 (ja) * 1991-02-07 2000-06-05 三菱化学株式会社 α‐オレフィン重合体の製造
DE59209354D1 (de) * 1991-03-09 1998-07-09 Targor Gmbh Verfahren zur Herstellung chemisch einheitlicher Cycloolefincopolymere
JP3193066B2 (ja) * 1991-05-02 2001-07-30 三菱化学株式会社 プロピレンランダム共重合体の製造法
US5391789A (en) * 1991-08-08 1995-02-21 Hoechst Aktiengesellschaft Bridged, chiral metallocenes, processes for their preparation and their use as catalysts
DE69300609T2 (de) * 1992-04-01 1996-06-13 Mitsui Toatsu Chemicals Syndiotaktischen Polypropylen, Wachs, Verfahren zur Herstellung derselbe und ihre Anwendung in eine Wärmefixiertonerzusammensetzung für geheizte Walze.
US5710222A (en) * 1992-06-22 1998-01-20 Fina Technology, Inc. Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems

Also Published As

Publication number Publication date
EP0628577A2 (en) 1994-12-14
CA2117031C (en) 1998-09-15
FI942333A (fi) 1994-11-21
CA2117031A1 (en) 1994-11-21
EP0628577B2 (en) 2002-10-09
NO941887L (no) 1994-11-21
DE69416721D1 (de) 1999-04-08
US5401817A (en) 1995-03-28
US5627118A (en) 1997-05-06
US5459218A (en) 1995-10-17
NO941887D0 (no) 1994-05-19
ES2128457T3 (es) 1999-05-16
DE69416721T2 (de) 1999-07-22
JPH07138275A (ja) 1995-05-30
EP0628577A3 (en) 1995-10-25
FI942333A0 (fi) 1994-05-19
EP0875517A1 (en) 1998-11-04
EP0628577B1 (en) 1999-03-03
ES2128457T5 (es) 2003-02-16
KR100352920B1 (ko) 2002-09-16

Similar Documents

Publication Publication Date Title
BR9402019A (pt) Processo para preparar um metaloceno ligado em forma de sanduíche e processo para a polimerização de uma olefina
BR9502665A (pt) Processo para preparação de um metaloceno não ligado processo para polimerização de uma olefina e metaloceno não-ligado
BR9502044A (pt) Processo para preparar um sistema catalisador contendo metaloceno e processo para polimerizar uma olefina
BR9405911A (pt) Processo para a preparaçao de uma composiçao de copolímero em bloco e composiçao de copolímero em bloco
BR9708187A (pt) Processo e aparelhagem para a polimerização de monômeros de olefina
BR9407041A (pt) Processo para reciclar plásticos
BR8902263A (pt) Veiculo de transicao e processo para a instalacao do mesmo
BR9505754A (pt) Processo para a preparação de copolímeros de poliéster
BR9602920A (pt) Processo para a polimerização de etileno com alfa-olefinas C 3 - C 10
BR9708878A (pt) Processos para produção de um laminado retroreflexivo e com cantos de cubo brilhantes e de um produto retrorreflecivo
FI942744A (fi) Metalloseeneja ja siihen liittyviä menetelmiä
BR9612069A (pt) Processo para preparar um laminado laminado e calçado
BR9405706A (pt) Processo e aparelho para preparo de chips de lanche isentos de gordura
BR9406429A (pt) Processo para produção de um laminado e aparelho para produção de um material laminado
BR9612065A (pt) Estrutura de laminado sintético e processo para fabricar a mesma
BR9306003A (pt) Processo para a polimerização ou copolimerização de etileno e/ou uma ou mais alfa-olefinas
BR9708971A (pt) Processo para a polimerização de alfa-olefinas
BR9505055A (pt) Processo para a preparação de polímeros de olefina uso de umcompost e poliolefina estabilizada
BR9406237A (pt) Processo para produção de um laminado e aparelho para produção de um material laminado
BR9103639A (pt) Catalisadores e processo para a polemiracao de alfa-olefinas
BR9404712A (pt) Processo e dispositivo para corte com tesoura de material em forma de seção
BR9405272A (pt) Processo para a polimerização de cloreto de vinila
DE69402778D1 (de) Alkylierungsverfahren
BR9510397A (pt) Composição polimerizável e processo para a polimerização de olefinas cíclicas
BR9505924A (pt) Processo para a polimerização de etileno com propileno e eventualmente outro dieno

Legal Events

Date Code Title Description
FA10 Dismissal: dismissal - article 33 of industrial property law
HKFN Application deemed withdrawn (deleted)
FA7 Application withdrawn (art. 18 par. 1 of law 5772/71) - being contrary to morals, good customs and public security, order and health