BR112014011773A2 - processo para a produção de polidienos - Google Patents
processo para a produção de polidienosInfo
- Publication number
- BR112014011773A2 BR112014011773A2 BR112014011773A BR112014011773A BR112014011773A2 BR 112014011773 A2 BR112014011773 A2 BR 112014011773A2 BR 112014011773 A BR112014011773 A BR 112014011773A BR 112014011773 A BR112014011773 A BR 112014011773A BR 112014011773 A2 BR112014011773 A2 BR 112014011773A2
- Authority
- BR
- Brazil
- Prior art keywords
- polydienes
- production
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
- C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
- C08F2/40—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161560941P | 2011-11-17 | 2011-11-17 | |
| US61/560,941 | 2011-11-17 | ||
| PCT/US2012/065808 WO2013075085A1 (en) | 2011-11-17 | 2012-11-19 | Process for producing polydienes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112014011773A2 true BR112014011773A2 (pt) | 2017-05-09 |
| BR112014011773B1 BR112014011773B1 (pt) | 2020-10-13 |
Family
ID=47291259
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112014011773-0A BR112014011773B1 (pt) | 2011-11-17 | 2012-11-19 | processo para a produção de polidienos |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9505859B2 (pt) |
| EP (1) | EP2780381B1 (pt) |
| JP (1) | JP6196982B2 (pt) |
| KR (1) | KR101963474B1 (pt) |
| CN (1) | CN104039843B (pt) |
| BR (1) | BR112014011773B1 (pt) |
| RU (1) | RU2605552C2 (pt) |
| WO (1) | WO2013075085A1 (pt) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015084922A1 (en) | 2013-12-03 | 2015-06-11 | Bridgestone Corporation | Process for preparing blends of cis-1,4-polybutadiene and syndiotactic 1,2-polybutadiene |
| EP3250616B1 (en) * | 2015-01-28 | 2019-01-23 | Bridgestone Corporation | Aged lanthanide-based catalyst systems and their use in the preparation of cis-1,4-polydienes |
| US11584808B2 (en) | 2019-12-30 | 2023-02-21 | Bridgestone Corporation | Polymerization catalyst composition and method of employing same |
| KR20220041760A (ko) * | 2020-09-25 | 2022-04-01 | 주식회사 엘지화학 | 네오디뮴 촉매화 공액디엔계 중합체 및 이를 포함하는 고무 조성물 |
Family Cites Families (77)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3297667A (en) | 1963-02-28 | 1967-01-10 | Union Carbide Corp | Production of cis-1, 4-polydienes by polymerization of 1, 3-dienes |
| BE787691A (fr) | 1971-08-17 | 1973-02-19 | Degussa | Composes organosiliciques contenant du soufre |
| US3873489A (en) | 1971-08-17 | 1975-03-25 | Degussa | Rubber compositions containing silica and an organosilane |
| US3978103A (en) | 1971-08-17 | 1976-08-31 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Sulfur containing organosilicon compounds |
| US3770710A (en) | 1971-08-23 | 1973-11-06 | Firestone Tire & Rubber Co | Bulk polymerization of diolefins |
| US3794604A (en) | 1971-09-24 | 1974-02-26 | Goodyear Tire & Rubber | Diolefin polymerization catalyst composition |
| SU580840A3 (ru) | 1974-02-07 | 1977-11-15 | Дегусса (Фирма) | Способ получени серосодержащих кремнийорганических соединений |
| US4002594A (en) | 1975-07-08 | 1977-01-11 | Ppg Industries, Inc. | Scorch retardants for rubber reinforced with siliceous pigment and mercapto-type coupling agent |
| DE2830080A1 (de) | 1978-07-08 | 1980-01-17 | Bayer Ag | Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien |
| CA1223396A (en) | 1981-06-29 | 1987-06-23 | Tooru Shibata | Process for producing conjugated diene polymer |
| US4473661A (en) * | 1982-07-01 | 1984-09-25 | The Firestone Tire & Rubber Company | Polymerization catalyst system containing organolithium, dialkyl magnesium and/or trialkyl aluminum, and a phosphine oxide |
| US4575538A (en) * | 1984-12-20 | 1986-03-11 | Phillips Petroleum Company | Olefin polymerization |
| IT1191612B (it) | 1985-05-15 | 1988-03-23 | Enichem Elastomers | Procedimento migliorato per la polimerizzazione o copolimerizzazione del butadiene |
| IT1191614B (it) | 1985-05-15 | 1988-03-23 | Enichem Elastomers | Procedimento migliorato per la polimerizzazione o copolimerizzazione del butadiene |
| IT1186730B (it) | 1985-06-05 | 1987-12-16 | Enichem Elastomers | Procedimento per la polimerizzazione di isoprene |
| US5064910A (en) | 1986-09-05 | 1991-11-12 | Japan Synthetic Rubber Co., Ltd. | Preparation of conjugated diene polymers modified with an organo-tin or germanium halide |
| US4906706A (en) | 1986-09-05 | 1990-03-06 | Japan Synthetic Rubber Co., Ltd. | Modified conjugated diene polymer and process for production thereof |
| IT1230756B (it) | 1989-02-17 | 1991-10-29 | Enichem Elastomers | Metodo per la preparazione di polibutadiene a lavorabilita' migliorata. |
| FR2673187B1 (fr) | 1991-02-25 | 1994-07-01 | Michelin & Cie | Composition de caoutchouc et enveloppes de pneumatiques a base de ladite composition. |
| JP3211274B2 (ja) | 1991-08-27 | 2001-09-25 | 旭化成株式会社 | 共役ジエン系重合体の製造方法 |
| JP3230532B2 (ja) | 1991-08-28 | 2001-11-19 | 旭化成株式会社 | 共役ジエン系重合体の製造法 |
| EP0713885B1 (en) * | 1993-07-30 | 1998-05-20 | Nippon Zeon Co., Ltd. | Modified conjugated diene copolymer, process for producing the same, and composition thereof |
| DE4436059A1 (de) | 1994-10-10 | 1996-04-11 | Bayer Ag | Verfahren zur Herstellung von mittels Nd-Katalysatoren polymerisierten Dienkautschuken mit niedrigem cold-flow und geringem Eigengeruch |
| US5580919A (en) | 1995-03-14 | 1996-12-03 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition and use in tires |
| US5674932A (en) | 1995-03-14 | 1997-10-07 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition and use in tires |
| JP3555809B2 (ja) | 1995-06-19 | 2004-08-18 | 株式会社ブリヂストン | ラジアルタイヤ |
| AT405285B (de) | 1995-09-07 | 1999-06-25 | Semperit Ag | Kautschukmischung |
| US5583245A (en) | 1996-03-06 | 1996-12-10 | The Goodyear Tire & Rubber Company | Preparation of sulfur-containing organosilicon compounds |
| US5719207A (en) | 1996-03-18 | 1998-02-17 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition and tire with tread |
| US5696197A (en) | 1996-06-21 | 1997-12-09 | The Goodyear Tire & Rubber Company | Heterogeneous silica carbon black-filled rubber compound |
| JP3606411B2 (ja) | 1996-07-10 | 2005-01-05 | 株式会社ブリヂストン | タイヤ加硫成型用金型およびその製造方法 |
| JP3117645B2 (ja) | 1996-09-03 | 2000-12-18 | 株式会社ブリヂストン | 空気入りラジアルタイヤ |
| US5663396A (en) | 1996-10-31 | 1997-09-02 | The Goodyear Tire & Rubber Company | Preparation of sulfur-containing organosilicon compounds |
| US5684171A (en) | 1997-02-11 | 1997-11-04 | The Goodyear Tire & Rubber Company | Process for the preparation of organosilicon polysulfide compounds |
| US5684172A (en) | 1997-02-11 | 1997-11-04 | The Goodyear Tire & Rubber Company | Process for the preparation of organosilicon polysulfide compounds |
| DE69815172T2 (de) | 1997-03-05 | 2004-07-01 | Jsr Corp. | Verfahren zur Herstellung von konjugierten Dien-Polymeren |
| JP4489194B2 (ja) | 1997-03-05 | 2010-06-23 | Ｊｓｒ株式会社 | 共役ジエン系重合体の製造方法 |
| JP3724125B2 (ja) | 1997-07-15 | 2005-12-07 | Ｊｓｒ株式会社 | 共役ジエン系重合体の製造方法 |
| US6384117B1 (en) | 1997-07-11 | 2002-05-07 | Bridgestone Corporation | Processability of silica-filled rubber stocks |
| US6221943B1 (en) | 1997-07-11 | 2001-04-24 | Bridgestone Corporation | Processability of silica-filled rubber stocks |
| US6525118B2 (en) | 1997-07-11 | 2003-02-25 | Bridgestone Corporation | Processability of silica-filled rubber stocks with reduced hysteresis |
| EP0958298B2 (en) | 1997-08-21 | 2008-10-22 | Momentive Performance Materials Inc. | Blocked mercaptosilane coupling agents for filled rubbers |
| US5971046A (en) | 1997-09-17 | 1999-10-26 | Bridgestone/Firestone, Inc. | Method and apparatus for bonding an active tag to a patch and a tire |
| CA2372404C (en) | 1999-05-19 | 2010-04-27 | Bridgestone Corporation | Low molecular weight high-cis polybutadienes and their use in high molecular weight/low molecular weight high-cis polybutadiene blends |
| CA2424815C (en) | 1999-11-12 | 2009-12-29 | Bridgestone Corporation | Modified polymers prepared with lanthanide-based catalysts |
| EP1099711B1 (en) | 1999-11-12 | 2006-03-29 | JSR Corporation | Modified conjugated diene polymer, method of producing it and rubber composition comprising the same |
| US6977281B1 (en) | 1999-11-12 | 2005-12-20 | Bridgestone Corporation | Modified polymers prepared with lanthanide-based catalysts |
| FR2802542A1 (fr) | 1999-12-20 | 2001-06-22 | Michelin Soc Tech | Composition de caoutchouc vulcanisable pour la fabrication d'un pneumatique et pneumatique dont la bande de roulement comprend une telle composition |
| US6590017B1 (en) | 2000-05-15 | 2003-07-08 | Bridgestone Corporation | Processability of silica-reinforced rubber containing an amide compound |
| US6608145B1 (en) | 2000-10-13 | 2003-08-19 | Bridgestone Corporation | Silica-reinforced rubber compounded with an organosilane tetrasulfide silica coupling agent at high mixing temperature |
| JP4965055B2 (ja) | 2000-11-10 | 2012-07-04 | 株式会社ブリヂストン | 新規な官能化剤を用いて製造した官能化高シス−１，４−ポリブタジエン |
| JP4828085B2 (ja) | 2001-02-28 | 2011-11-30 | 株式会社ブリヂストン | 狭い分子量分布を示す共役ジエン重合体の連続製造方法およびそれから製造された製品 |
| TW575586B (en) | 2001-04-12 | 2004-02-11 | Ube Industries | Method of polymerizing ethylenically unsaturated monomer |
| US6579949B1 (en) | 2001-10-30 | 2003-06-17 | Bridgestone Corporation | Preparation of low hysteresis rubber by reacting a lithium polymer with a sulfur containing reagent |
| US6699813B2 (en) | 2001-11-07 | 2004-03-02 | Bridgestone Corporation | Lanthanide-based catalyst composition for the manufacture of polydienes |
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| US7008899B2 (en) | 2003-08-11 | 2006-03-07 | Bridgestone Corporation | Lanthanide-based catalyst composition for producing cis-1,4-polydienes |
| CN1528794A (zh) | 2003-09-25 | 2004-09-15 | 中国科学院长春应用化学研究所 | 稀土顺丁橡胶分子质量分布的调节方法 |
| US7094849B2 (en) * | 2003-12-15 | 2006-08-22 | Bridgestone Corporation | Bulk polymerization process for producing polydienes |
| EP1765889B1 (en) | 2004-03-02 | 2016-03-30 | Bridgestone Corporation | Bulk polymerization process |
| US7799725B2 (en) | 2004-11-01 | 2010-09-21 | Ube Industries, Ltd. | Catalyst for polymerization of conjugated diene and method of polymerization conjugated diene using the catalyst, rubber composition for tires, and rubber composition for golf balls |
| US7879952B2 (en) | 2005-12-28 | 2011-02-01 | Bridgestone Corporation | Functionalized polymers |
| FR2899903B1 (fr) | 2006-04-14 | 2012-01-06 | Michelin Soc Tech | Procede de preparation d'un elastomere dienique, tel qu'un polybutadiene. |
| US7671138B2 (en) | 2006-05-26 | 2010-03-02 | Bridgestone Corporation | Polymers functionized with hydrobenzamides |
| US7732534B2 (en) | 2006-08-28 | 2010-06-08 | Bridgestone Corporation | Polymers functionalized with nitro compounds |
| US8088868B2 (en) | 2006-12-19 | 2012-01-03 | Bridgestone Corporation | Polymers functionalized with protected oxime compounds |
| ZA200711158B (en) | 2006-12-28 | 2009-03-25 | Bridgestone Corp | A method for producing functionalized cis-1,4-polydienes having high cis-1,4-linkage content and high functionality |
| US7572867B2 (en) | 2007-05-01 | 2009-08-11 | Bridgestone Corporation | Polymerization process for producing polydienes |
| US7879958B2 (en) | 2007-08-07 | 2011-02-01 | Bridgestone Corporation | Polyhydroxy compounds as polymerization quenching agents |
| US8324329B2 (en) | 2007-08-07 | 2012-12-04 | Bridgestone Corporation | Process for producing functionalized polymers |
| US7825201B2 (en) * | 2007-12-31 | 2010-11-02 | Bridgestone Corporation | Process for producing polydienes |
| US7741418B2 (en) * | 2007-12-31 | 2010-06-22 | Bridgestone Corporation | Process for producing polydienes |
| JP5345835B2 (ja) | 2007-12-31 | 2013-11-20 | 株式会社ブリヂストン | ポリジエンの製造のためのバルク重合法 |
| US7807763B2 (en) * | 2008-04-07 | 2010-10-05 | Bridgestone Corporation | Method for bulk polymerization |
| CN101724115B (zh) * | 2009-12-21 | 2012-01-25 | 中国科学院长春应用化学研究所 | 用于制备聚异戊二烯的磺酸稀土催化剂及制法和应用 |
| CN101906110B (zh) * | 2010-08-18 | 2014-03-05 | 中国科学院长春应用化学研究所 | 苯二甲酸钕给电子体配合物及其制备方法和稀土催化剂 |
| CN101974023B (zh) * | 2010-09-21 | 2012-05-23 | 中国科学院长春应用化学研究所 | 稀土配合物、催化剂及其制备方法和聚丁二烯的制备方法 |
-
2012
- 2012-11-19 US US14/358,834 patent/US9505859B2/en active Active
- 2012-11-19 BR BR112014011773-0A patent/BR112014011773B1/pt not_active IP Right Cessation
- 2012-11-19 RU RU2014124345/04A patent/RU2605552C2/ru active
- 2012-11-19 CN CN201280066475.XA patent/CN104039843B/zh not_active Expired - Fee Related
- 2012-11-19 JP JP2014544776A patent/JP6196982B2/ja active Active
- 2012-11-19 WO PCT/US2012/065808 patent/WO2013075085A1/en active Application Filing
- 2012-11-19 EP EP12795698.5A patent/EP2780381B1/en not_active Not-in-force
- 2012-11-19 KR KR1020147015970A patent/KR101963474B1/ko active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| BR112014011773B1 (pt) | 2020-10-13 |
| US20140303327A1 (en) | 2014-10-09 |
| KR20140091594A (ko) | 2014-07-21 |
| JP6196982B2 (ja) | 2017-09-13 |
| RU2014124345A (ru) | 2015-12-27 |
| CN104039843B (zh) | 2016-05-18 |
| US9505859B2 (en) | 2016-11-29 |
| WO2013075085A1 (en) | 2013-05-23 |
| CN104039843A (zh) | 2014-09-10 |
| EP2780381A1 (en) | 2014-09-24 |
| JP2014534331A (ja) | 2014-12-18 |
| KR101963474B1 (ko) | 2019-03-28 |
| RU2605552C2 (ru) | 2016-12-20 |
| EP2780381B1 (en) | 2015-10-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
| B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 19/11/2012, OBSERVADAS AS CONDICOES LEGAIS. |
|
| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE A 10A ANUIDADE. |
|
| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2697 DE 13-09-2022 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |