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AR009034A1 - Complejos de metales que contienen ciclopentadienilo sustituido por heteroatomos en la posicion 2, sistemas catalizadores que incluyen dichoscomplejos; proceso para polimerizar olefinas aplicando dichos sistemas; productos de polimerizacion de olefinas obtenidas con dicho proceso; los - Google Patents

Complejos de metales que contienen ciclopentadienilo sustituido por heteroatomos en la posicion 2, sistemas catalizadores que incluyen dichoscomplejos; proceso para polimerizar olefinas aplicando dichos sistemas; productos de polimerizacion de olefinas obtenidas con dicho proceso; los

Info

Publication number
AR009034A1
AR009034A1 ARP970103616A ARP970103616A AR009034A1 AR 009034 A1 AR009034 A1 AR 009034A1 AR P970103616 A ARP970103616 A AR P970103616A AR P970103616 A ARP970103616 A AR P970103616A AR 009034 A1 AR009034 A1 AR 009034A1
Authority
AR
Argentina
Prior art keywords
olefins
complexes
systems
heteroatomes
applying
Prior art date
Application number
ARP970103616A
Other languages
English (en)
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of AR009034A1 publication Critical patent/AR009034A1/es

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Complejos de metales que tienen ciclopentadienilo que en la posicion 2 tienen heterátomo, de formula (I) donde Ra o Ro, T, M, Z, Xp, Xq tienen losvalores indicados en la descripcion. Dichos complejos son utiles como ligandos en la preparacion de sistemas catalíticos para la polimerizacion de olefinas, atemperaturas elevadas para producir polímeros de elevado peso molecular. También se proponen procesos de polimerizacion de olefinas con aplicacion delos sistemas mencionados y las poliolefinas resultantes y además los ligandos de ciclopentadienilo y el uso de los mismos en la preparacion de los complejosmencionados.
ARP970103616A 1996-08-08 1997-08-08 Complejos de metales que contienen ciclopentadienilo sustituido por heteroatomos en la posicion 2, sistemas catalizadores que incluyen dichoscomplejos; proceso para polimerizar olefinas aplicando dichos sistemas; productos de polimerizacion de olefinas obtenidas con dicho proceso; los AR009034A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US2376896P 1996-08-08 1996-08-08

Publications (1)

Publication Number Publication Date
AR009034A1 true AR009034A1 (es) 2000-03-08

Family

ID=21817090

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP970103616A AR009034A1 (es) 1996-08-08 1997-08-08 Complejos de metales que contienen ciclopentadienilo sustituido por heteroatomos en la posicion 2, sistemas catalizadores que incluyen dichoscomplejos; proceso para polimerizar olefinas aplicando dichos sistemas; productos de polimerizacion de olefinas obtenidas con dicho proceso; los

Country Status (21)

Country Link
EP (1) EP1021454A1 (es)
JP (1) JP2000516608A (es)
KR (1) KR20000029853A (es)
CN (1) CN1231668A (es)
AR (1) AR009034A1 (es)
AU (1) AU716659B2 (es)
BR (1) BR9711115A (es)
CA (1) CA2262377A1 (es)
CO (1) CO4870709A1 (es)
CZ (1) CZ42499A3 (es)
HU (1) HUP9904148A3 (es)
ID (1) ID18005A (es)
NO (1) NO990546L (es)
NZ (1) NZ333877A (es)
PL (1) PL331526A1 (es)
RU (1) RU2196776C2 (es)
SA (1) SA97180735B1 (es)
SK (1) SK15299A3 (es)
TR (1) TR199900589T2 (es)
WO (1) WO1998006728A1 (es)
ZA (2) ZA976998B (es)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI971565A (fi) * 1997-04-14 1998-10-15 Borealis As Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä
DE19809159A1 (de) * 1998-03-04 1999-09-09 Bayer Ag Metallorganische Verbindungen
US6326493B1 (en) * 1999-01-25 2001-12-04 Chisso Corporation Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers
DE60000831T2 (de) 1999-04-29 2003-08-28 Dow Global Technologies Inc Bis(n,n-dihydrocarbylamino)-substituierte cyclopentadiene und diese enthaltende metallkomplexe
EP1178997B1 (en) 1999-05-13 2003-03-05 Dow Global Technologies Inc. Di-and tri-heteroatom substituted indenyl metal complexes
DE60001557T2 (de) 1999-05-13 2004-01-08 Dow Global Technologies, Inc., Midland Metallkomplexe mit heteroatom-enthaltende brücke für olefinpolymerisationsverfahren
US6420299B1 (en) 1999-06-04 2002-07-16 Dow Global Technologies Inc. Boron-substituted cyclopentadienes and metal complexes thereof
US6825295B2 (en) 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
EP1253158A1 (en) * 1999-12-10 2002-10-30 Dow Global Technologies Inc. Substituted group 4 metal complexes, catalysts and olefin polymerization process
CN1495188A (zh) * 1999-12-10 2004-05-12 取代的第4族金属配合物，催化剂和烯烃聚合方法
EP1533324B1 (en) 2000-01-18 2009-05-06 Basell Polyolefine GmbH A ligand for a metallocene catalyst used to prepare propylene based polymers, and its preparation method
EP1248806A1 (en) * 2000-01-19 2002-10-16 Borealis Technology Oy Metallocene catalysts comprising monocyclic siloxy substituted cyclopentadienyl group(s) for the polymerisation of olefins
GB0001232D0 (en) * 2000-01-19 2000-03-08 Borealis Polymers Oy Polymerisation catalysts
JP4062929B2 (ja) 2002-02-08 2008-03-19 住友化学株式会社 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法
AU2003216476A1 (en) * 2002-03-14 2003-09-29 Dow Global Technologies Inc. Substituted indenyl metal complexes and polymerization process
US6927264B2 (en) 2003-05-28 2005-08-09 Dow Global Technologies Inc. Metal complexes and polymerization process using same
BRPI1015130B1 (pt) 2009-07-28 2019-11-26 Univation Tech Llc processo de polimerização usando um catalisador de geometria limitada suportado
EP2617752B1 (en) * 2010-09-15 2018-07-25 Nippon Shokubai Co., Ltd. Composition usable as thermal-latent polymerization initiator
CN102101897B (zh) * 2010-12-24 2013-02-06 上海化工研究院 侧链含杂环的茂金属催化剂及其在烯烃聚合中的应用
JP6355815B2 (ja) 2014-03-21 2018-07-11 エクソンモービル・ケミカル・パテンツ・インク エチレンプロピレンコポリマーを製造する方法
US10773246B2 (en) 2015-01-06 2020-09-15 Scg Chemicals Co., Ltd. SiO2-layered double hydroxide microspheres and methods of making them
KR102010630B1 (ko) * 2016-01-20 2019-08-13 한화토탈 주식회사 올레핀 중합촉매 및 이를 이용한 올레핀 중합방법
GB201608384D0 (en) 2016-05-12 2016-06-29 Scg Chemicals Co Ltd Unsymmetrical metallocene catalysts and uses thereof
EP3601378A1 (en) * 2017-03-23 2020-02-05 ExxonMobil Chemical Patents Inc. Catalyst systems and methods for preparing and using the same
KR102643986B1 (ko) 2017-09-29 2024-03-07 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 인덴계 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
KR102714698B1 (ko) 2019-02-28 2024-10-10 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
WO2020174346A1 (ko) 2019-02-28 2020-09-03 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
US12006378B2 (en) 2019-09-27 2024-06-11 Lg Chem, Ltd. Polyethylene and its chlorinated polyethylene

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
PL166690B1 (pl) * 1990-06-04 1995-06-30 Exxon Chemical Patents Inc Sposób wytwarzania polimerów olefin PL
DE59310131D1 (de) * 1992-08-03 2001-01-25 Targor Gmbh Verfahren zur Herstellung eines Olefinpolymers unter Verwendung spezieller Metallocene
DE4406964A1 (de) * 1994-03-03 1995-09-07 Basf Ag Geträgerte Metalloxenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem als Katalysatorsysteme
DE4406963A1 (de) * 1994-03-03 1995-09-07 Basf Ag Metallocenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem

Also Published As

Publication number Publication date
AU716659B2 (en) 2000-03-02
NO990546D0 (no) 1999-02-05
RU2196776C2 (ru) 2003-01-20
BR9711115A (pt) 1999-08-17
KR20000029853A (ko) 2000-05-25
JP2000516608A (ja) 2000-12-12
TR199900589T2 (xx) 1999-07-21
ID18005A (id) 1998-02-19
CO4870709A1 (es) 1999-12-27
CZ42499A3 (cs) 1999-07-14
WO1998006728A1 (en) 1998-02-19
EP1021454A1 (en) 2000-07-26
PL331526A1 (en) 1999-07-19
SA97180735B1 (ar) 2006-10-08
ZA976998B (en) 1999-02-08
CA2262377A1 (en) 1998-02-19
AU3964797A (en) 1998-03-06
NO990546L (no) 1999-03-29
NZ333877A (en) 2000-08-25
HUP9904148A2 (hu) 2000-03-28
SK15299A3 (en) 2000-03-13
HUP9904148A3 (en) 2003-03-28
CN1231668A (zh) 1999-10-13
ZA976999B (en) 1999-02-08

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