ZA976998B - 3-Heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process - Google Patents
3-Heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization processInfo
- Publication number
- ZA976998B ZA976998B ZA976998A ZA976998A ZA976998B ZA 976998 B ZA976998 B ZA 976998B ZA 976998 A ZA976998 A ZA 976998A ZA 976998 A ZA976998 A ZA 976998A ZA 976998 B ZA976998 B ZA 976998B
- Authority
- ZA
- South Africa
- Prior art keywords
- polymerization process
- metal complexes
- containing metal
- olefin polymerization
- substituted cyclopentadienyl
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 title 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 title 1
- 239000002184 metal Substances 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2376896P | 1996-08-08 | 1996-08-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA976998B true ZA976998B (en) | 1999-02-08 |
Family
ID=21817090
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA976999A ZA976999B (en) | 1996-08-08 | 1997-08-06 | 2-Heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process |
| ZA976998A ZA976998B (en) | 1996-08-08 | 1997-08-06 | 3-Heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA976999A ZA976999B (en) | 1996-08-08 | 1997-08-06 | 2-Heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process |
Country Status (21)
| Country | Link |
|---|---|
| EP (1) | EP1021454A1 (en) |
| JP (1) | JP2000516608A (en) |
| KR (1) | KR20000029853A (en) |
| CN (1) | CN1231668A (en) |
| AR (1) | AR009034A1 (en) |
| AU (1) | AU716659B2 (en) |
| BR (1) | BR9711115A (en) |
| CA (1) | CA2262377A1 (en) |
| CO (1) | CO4870709A1 (en) |
| CZ (1) | CZ42499A3 (en) |
| HU (1) | HUP9904148A3 (en) |
| ID (1) | ID18005A (en) |
| NO (1) | NO990546L (en) |
| NZ (1) | NZ333877A (en) |
| PL (1) | PL331526A1 (en) |
| RU (1) | RU2196776C2 (en) |
| SA (1) | SA97180735B1 (en) |
| SK (1) | SK15299A3 (en) |
| TR (1) | TR199900589T2 (en) |
| WO (1) | WO1998006728A1 (en) |
| ZA (2) | ZA976999B (en) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI971565A (en) * | 1997-04-14 | 1998-10-15 | Borealis As | Substituted metallocene compounds for catalyst systems intended for polymerization of olefins, intermediates and processes for their preparation |
| DE19809159A1 (en) * | 1998-03-04 | 1999-09-09 | Bayer Ag | Organometallic compounds |
| US6326493B1 (en) * | 1999-01-25 | 2001-12-04 | Chisso Corporation | Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers |
| US6617407B1 (en) | 1999-04-29 | 2003-09-09 | The Dow Chemical Company | Bis(n,n-dihydrocarbylamino)-substituted cyclopentadienes and metal complexes thereof |
| CA2368111A1 (en) | 1999-05-13 | 2000-11-23 | The Dow Chemical Company | Di- and tri-heteroatom substituted indenyl metal complexes |
| CA2368010A1 (en) | 1999-05-13 | 2000-11-23 | Dow Global Technologies Inc. | Metal complexes containing bridging heteroatom for olefin-polymerization process |
| EP1194431B1 (en) | 1999-06-04 | 2005-06-22 | Dow Global Technologies Inc. | Boron-substituted cyclopentadienes and metal complexes thereof |
| KR100738694B1 (en) * | 1999-12-10 | 2007-07-12 | 다우 글로벌 테크놀로지스 인크. | Substituted group 4 metal complexes, catalysts and olefin polymerization process |
| US6825295B2 (en) | 1999-12-10 | 2004-11-30 | Dow Global Technologies Inc. | Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process |
| EP1253158A1 (en) * | 1999-12-10 | 2002-10-30 | Dow Global Technologies Inc. | Substituted group 4 metal complexes, catalysts and olefin polymerization process |
| EP1533324B1 (en) | 2000-01-18 | 2009-05-06 | Basell Polyolefine GmbH | A ligand for a metallocene catalyst used to prepare propylene based polymers, and its preparation method |
| AU2001226937A1 (en) * | 2000-01-19 | 2001-07-31 | Borealis Technology Oy | Metallocene catalysts comprising monocyclic siloxy substituted cyclopentadienyl group(s) for the polymerisation of olefins |
| GB0001232D0 (en) * | 2000-01-19 | 2000-03-08 | Borealis Polymers Oy | Polymerisation catalysts |
| JP4062929B2 (en) | 2002-02-08 | 2008-03-19 | 住友化学株式会社 | Transition metal complex, ligand, catalyst for olefin polymerization, and method for producing olefin polymer |
| JP4624679B2 (en) * | 2002-03-14 | 2011-02-02 | ダウ グローバル テクノロジーズ インコーポレイティド | Substituted indenyl metal complex and polymerization method |
| US6927264B2 (en) | 2003-05-28 | 2005-08-09 | Dow Global Technologies Inc. | Metal complexes and polymerization process using same |
| WO2011017092A1 (en) | 2009-07-28 | 2011-02-10 | Univation Technologies, Llc | Polymerization process using a supported constrained geometry catalyst |
| WO2012036164A1 (en) * | 2010-09-15 | 2012-03-22 | 株式会社日本触媒 | Composition usable as heat-latent polymerization initiator |
| CN102101897B (en) * | 2010-12-24 | 2013-02-06 | 上海化工研究院 | Heterocyclic-side-chain-containing metallocene catalyst and application thereof in olefinic polymerization |
| US9382361B2 (en) | 2014-03-21 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Process to produce ethylene propylene copolymers |
| KR20170103887A (en) | 2015-01-06 | 2017-09-13 | 에스씨지 케미컬스 컴퍼니, 리미티드. | SiO2-layered double hydroxide microspheres and methods for their preparation |
| KR102010630B1 (en) * | 2016-01-20 | 2019-08-13 | 한화토탈 주식회사 | Catalyst for olefin polymerization and olefin polymerization method thereof |
| GB201608384D0 (en) | 2016-05-12 | 2016-06-29 | Scg Chemicals Co Ltd | Unsymmetrical metallocene catalysts and uses thereof |
| CN110612313A (en) * | 2017-03-23 | 2019-12-24 | 埃克森美孚化学专利公司 | Catalyst system and methods of making and using the same |
| KR102643986B1 (en) | 2017-09-29 | 2024-03-07 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | A novel indene-based transition metal complexes, catalysts composition containing the same, and methods for preparing ethylene homopolymers or copolymers of ethylene and α-olefins using the same |
| KR102714698B1 (en) | 2019-02-28 | 2024-10-10 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | Novel tetraaryl borate compounds, catalysts composition containing the same, and methods for preparing ethylene homopolymers or copolymers of ethylene and α-olefins using the same |
| WO2020174346A1 (en) | 2019-02-28 | 2020-09-03 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | NOVEL TETRAARYLBORATE COMPOUND, CATALYST COMPOSITION COMPRISING SAME, AND METHOD FOR PREPARING ETHYLENE HOMOPOLYMERS OR COPOLYMERS OF ETHYLENE AND α-OLEFIN BY USING SAME |
| US12006378B2 (en) | 2019-09-27 | 2024-06-11 | Lg Chem, Ltd. | Polyethylene and its chlorinated polyethylene |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5096867A (en) * | 1990-06-04 | 1992-03-17 | Exxon Chemical Patents Inc. | Monocyclopentadienyl transition metal olefin polymerization catalysts |
| NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| ATE198207T1 (en) * | 1992-08-03 | 2001-01-15 | Targor Gmbh | METHOD FOR PRODUCING AN OLEFIN POLYMER USING SPECIAL METALLOCENES |
| DE4406963A1 (en) * | 1994-03-03 | 1995-09-07 | Basf Ag | Metallocene complexes with heterofunctional groups on the cyclopentadienyl system |
| DE4406964A1 (en) * | 1994-03-03 | 1995-09-07 | Basf Ag | Supported metal oxide complexes with heterofunctional groups on the cyclopentadienyl system as catalyst systems |
-
1997
- 1997-07-28 TR TR1999/00589T patent/TR199900589T2/en unknown
- 1997-07-28 PL PL97331526A patent/PL331526A1/en unknown
- 1997-07-28 NZ NZ333877A patent/NZ333877A/en unknown
- 1997-07-28 EP EP97937033A patent/EP1021454A1/en not_active Withdrawn
- 1997-07-28 WO PCT/US1997/013171 patent/WO1998006728A1/en not_active Application Discontinuation
- 1997-07-28 RU RU99104650/04A patent/RU2196776C2/en not_active IP Right Cessation
- 1997-07-28 KR KR1019997001015A patent/KR20000029853A/en not_active Application Discontinuation
- 1997-07-28 CZ CZ99424A patent/CZ42499A3/en unknown
- 1997-07-28 HU HU9904148A patent/HUP9904148A3/en unknown
- 1997-07-28 CN CN97198208A patent/CN1231668A/en active Pending
- 1997-07-28 AU AU39647/97A patent/AU716659B2/en not_active Ceased
- 1997-07-28 CA CA002262377A patent/CA2262377A1/en not_active Abandoned
- 1997-07-28 JP JP10509760A patent/JP2000516608A/en active Pending
- 1997-07-28 SK SK152-99A patent/SK15299A3/en not_active Application Discontinuation
- 1997-07-28 BR BR9711115A patent/BR9711115A/en not_active IP Right Cessation
- 1997-08-06 ZA ZA976999A patent/ZA976999B/en unknown
- 1997-08-06 ZA ZA976998A patent/ZA976998B/en unknown
- 1997-08-07 ID IDP972749A patent/ID18005A/en unknown
- 1997-08-08 CO CO97045592A patent/CO4870709A1/en unknown
- 1997-08-08 AR ARP970103616A patent/AR009034A1/en not_active Application Discontinuation
- 1997-12-24 SA SA97180735A patent/SA97180735B1/en unknown
-
1999
- 1999-02-05 NO NO990546A patent/NO990546L/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| BR9711115A (en) | 1999-08-17 |
| RU2196776C2 (en) | 2003-01-20 |
| NO990546L (en) | 1999-03-29 |
| CA2262377A1 (en) | 1998-02-19 |
| SK15299A3 (en) | 2000-03-13 |
| AR009034A1 (en) | 2000-03-08 |
| CZ42499A3 (en) | 1999-07-14 |
| HUP9904148A3 (en) | 2003-03-28 |
| CO4870709A1 (en) | 1999-12-27 |
| NO990546D0 (en) | 1999-02-05 |
| NZ333877A (en) | 2000-08-25 |
| ID18005A (en) | 1998-02-19 |
| ZA976999B (en) | 1999-02-08 |
| JP2000516608A (en) | 2000-12-12 |
| EP1021454A1 (en) | 2000-07-26 |
| AU3964797A (en) | 1998-03-06 |
| PL331526A1 (en) | 1999-07-19 |
| WO1998006728A1 (en) | 1998-02-19 |
| AU716659B2 (en) | 2000-03-02 |
| KR20000029853A (en) | 2000-05-25 |
| CN1231668A (en) | 1999-10-13 |
| HUP9904148A2 (en) | 2000-03-28 |
| TR199900589T2 (en) | 1999-07-21 |
| SA97180735B1 (en) | 2006-10-08 |
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