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1.2 Relevant identified uses of the substance or mixture and uses advised against
Uses advised against: This product is not recommended for any industrial, professional or consumer
use other than the Intended Uses above.
Company/undertaking identification
Supplier/Manufacturer:
e-mail: mail@marichem-marigases.com
Emergency Information:
Inside U.S. and Canada: (800)-424-9300 (CHEMTREC)
Outside U.S. and Canada: 1-703-527-3887 (CHEMTREC)
National Emergency Centre (Greece): ++30 210 7793777
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2. HAZARDS IDENTIFICATION
The product does not require a hazard warning label in accordance with GHS criteria.
The preparation is not classified as dangerous according to Directive 1999/45/EC and its
amendments.
3. COMPOSITION/INFORMATION ON INGREDIENTS
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.
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On skin contact:
Wash thoroughly with soap and water.
On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: No significant symptoms are expected due to the non-classification of the product.
Hazards: No hazard is expected under intended use and appropriate handling.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions) - no known specific
antidote.
5. FIRE-FIGHTING MEASURES
Further information:
Contaminated extinguishing water must be disposed of in accordance with official regulations. Keep
containers cool by spraying with water if exposed to fire. Foam should be applied in large quantities
as it is broken down to some extent by the product.
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7. HANDLING AND STORAGE
57-55-6: Propane-1,2-diol
PNEC
freshwater: 19 mg/l
marine water: 1.9 mg/l
intermittent release: 190 mg/l
STP: 4168 mg/l
sediment (freshwater): 70.2 mg/kg
sediment (marine water): 7.02 mg/kg
soil: 2.74 mg/kg
oral (secondary poisoning):
No PNEC oral derived, as accumulation in organisms is not to be expected.
DNEL
worker:
Long-term exposure- systemic effects, dermal: 65 mg/kg
worker:
Long-term exposure- systemic effects, Inhalation: 310 mg/m3
consumer:
Long-term exposure- systemic effects, dermal: 15 mg/kg
consumer:
Long-term exposure- systemic effects, Inhalation: 37.2 mg/m3
consumer:
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Long-term exposure- systemic effects, oral: 1.67 mg/kg
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Gas filter for gases/vapours of organic
compounds (boiling point >65 °C, e. g. EN 14387 Type A)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
butyl rubber (butyl) - 0.7 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).
9.1.1. Appearance
Color: Pale
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Solubility in water: Soluble
Temperature of loading cargo: Temperature of loading cargo must not exceed 1400C
10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals: No corrosive effect on metal.
Formation of flammable gases:
Remarks: Forms no flammable gases in the presence of water.
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11. TOXICOLOGICAL INFORMATION
Acute toxicity
Experimental/calculated data:
LD50 rat (oral): > 5,000 mg/kg
Irritation
Experimental/calculated data:
Skin corrosion/irritation rabbit: non-irritant (BASF-Test)
Serious eye damage/irritation rabbit: non-irritant (Draize test)
Respiratory/Skin sensitization
Assessment of sensitization:
The substance did not cause skin sensitization in humans.
Assessment of mutagenicity:
The substance was not mutagenic in bacteria. The substance was not mutagenic in mammalian cell
culture.
Carcinogenicity
Assessment of carcinogenicity:
No data available concerning carcinogenic effects. The chemical structure does not suggest a
specific alert for such an effect.
Developmental toxicity
Assessment of teratogenicity:
No indications of a developmental toxic / teratogenic effect were seen in animal studies.
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Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Aspiration hazard
Not applicable.
12.1 Toxicity
Toxicity to fish:
LC50 (96 h) > 1,000 mg/l, Poecilia reticulata (OECD 203; ISO 7346; 84/449/EEC, C.1, static)
The details of the toxic effect relate to the nominal concentration.
Aquatic invertebrates:
LC50 (48 h) 1,919 mg/l, Daphnia magna (OPP 72-2 (EPA-guideline), static)
Literature data. The details of the toxic effect relate to the nominal concentration.
Aquatic plants:
EC50 (96 h) > 969 mg/l (growth rate), Pseudokirchneriella subcapitata (OECD Guideline 201, static)
Literature data. The statement of the toxic effect relates to the analytically determined concentration.
Terrestrial plants:
EC50 500 g/l, (OECD Guideline 227)
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Assessment biodegradation and elimination (H2O):
Readily biodegradable (according to OECD criteria). Easily eliminated from water.
Elimination information:
96 % DOC reduction (28 d) (OECD 301F; ISO 9408; 92/69/EEC, C.4-D) (aerobic, activated sludge,
domestic).
94 % DOC reduction (13 d) (OECD Guideline 302 B) (aerobic, activated sludge, industrial)
According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): The product does not fulfill the criteria for
PBT (Persistent/bioaccumulative/toxic) and vPvB (very persistent/very bioaccumulative). Self
classification.
The substance is not listed in Regulation (EC) 1005/2009 on substances that deplete the ozone
layer.
The product is not harmful to the marine environment as per paragraphs 1.7.4 and 1.7.5. of
Resolution MEPC. 219 (63) /Annex 24 - 2012 adoption of IMO’s MARPOL Annex V.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for
recycling after being thoroughly cleaned.
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14. TRANSPORT INFORMATION
14.1 Not classified as dangerous material for the transportation according to ADR/RID, IMDG,
ICAO/IATA and US DOT transportation codes.
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture.
If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.
A CSA has been carried out for the raw materials in this product, from the raw materials
manufacturers (when needed to be carried out).
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European
Agreement concerning the International Carriage of Dangerous Goods by Road).
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de
fer (Regulations Concerning the International Transport of Dangerous Goods by Rail).
IMDG: International Maritime Code for Dangerous Goods.
IATA: International Air Transport Association.
ICAO: International Civil Aviation Organization.
bw: Body weight.
Carc.: Carcinogenicity.
CAS number: Chemical Abstracts Service number.
CLP: Classification Labelling Packaging Regulation.
CSA: Chemical Safety Assessment.
CSR: Chemical Safety Report.
DNEL: Derived No Effect Level.
dw: Dry weight.
EC number: EINECS and ELINCS number.
EC: European Commission.
EC50: Half maximal effective concentration.
EINECS: European Inventory of Existing Commercial Chemical Substances.
ELINCS: European List of Notified Chemical Substances.
EmS: Emergency Schedule.
ERC: Environmental Release Category.
ES: Exposure scenario.
food: oral feed.
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GHS: Globally Harmonized System of Classification and Labelling of Chemicals.
Irrit.: Irritation.
LC50: Lethal concentration, 50 %.
LD50: Median Lethal dose.
LOAEC: Lowest Observed Adverse Effect Concentration.
LOAEL: Lowest Observed Adverse Effect Level.
MK value: Maximum Concentration value.
NCO: An international corporation that provides customer service contracting.
NOAEC: No Observed Adverse Effect Concentration.
NOAEL: No Observed Adverse Effect Level.
NOEC: No Observed Effect Concentration.
OECD: Organisation for Economic Cooperation and Development.
PBT: Persistent, Bioaccumulative and Toxic.
PNEC: Predicted No Effect Concentration.
PROC: Process category.
REACH: The Registration, Evaluation, Authorisation and Restriction of Chemicals.
Resp.: Respiratory.
Sens.: Sensitization.
STEL value: Short Term Exposure Limit value.
STOT RE: Specific target organ toxicity — repeated exposure.
STOT SE: Specific target organ toxicity — single exposure.
STOT: Specific Target Organ Toxicity.
STP: Sewage Treatment Plant.
SU: Sector of use.
Tox.: Toxicity.
TWA value: Time Weighted Average value.
vPvB: Very Persistent and Very Bioaccumulative.
All information, instructions and statements contained in this Material Safety Data Sheet are
compiled in accordance with European Directives, corresponding national legislation and on the
basis of information given by our suppliers.
The information disclosed in this Material Safety Data Sheet (which supersedes all previous
versions) is believed to be correct, at the date of issue, to the best of our current knowledge and
experience. It only relates to the specific product designated herein and it may not be valid when said
product is used in combination with any other products or in any processed form, unless specified in
the text. This document aims to provide the necessary health and safety information of the product
and is not to be considered a warranty or quality specification. It is the responsibility of the recipient
of this Material Safety Data Sheet to ensure that information given here is read and understood by all
who use, handle, dispose of or in any way come in contact with the product.
Also, it is the responsibility of the user to comply with local legislation relating to safety, health,
environment and waste management. Data and information provided concerning the product are
informative, exclusively presented to the customer.
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