Carbon Clean LT

CARBONCLEAN LT
Wilhelmsen Ships Service AS

Part Number: 575696 (25 liter) Issue Date: 07/06/2021
Version No: 12.20.22.11 Print Date: 17/09/2021
Safety Data Sheet (Conforms to Regulation (EU) No 2020/878) L.REACH.NOR.EN
SECTION 1 Identification of the substance / mixture and of the company / undertaking
1.1. Product Identifier

Product name CARBONCLEAN LT
Chemical Name Not Applicable

Synonyms Not Available
Chemical formula Not Applicable
Other means of
575696 (25 liter), 575696
identification
1.2. Relevant identified uses of the substance or mixture and uses advised against
Chemical Product
PC35 Washing and cleaning products (including solventbased products)
Category
Sectors of Use SU3 Industrial uses: Uses of substances as such or in preparations* at industrial sites
Carbonclean LT includes a chemical, quaternary alkyl methyl amine ethoxylate methyl chloride (CAS No 1554325-20-0), that is
subject to a Significant New Use Rule (SNUR) at 40 CFR $721.10859. The SNUR for this substance requires that you report to
Relevant identified uses the EPA any predictable or purposeful release of a process stream containing the substance as defined in 40 CFR $721.90(a)(4),
(b)(4)and (c)(4) with N=29, through a Significant New Use Notice (SNUN). The calculation for the surface water concentrations is
found in 40 CFR $721.91
Uses advised against Not Applicable
1.3. Details of the supplier of the safety data sheet

Outback (M)SDS portal:
Wilhelmsen Ships Service AS*
Registered company name Wilhelmsen Ships Service AS http://jr.chemwatch.net/outb/account
Central Warehouse
/autologin?login=wilhelmsen
--------Use our Outback portal to obtain our
(M)SDSs in other languages and/or
Strandveien 20 Lysaker 1366 format.--------- For questions relating to our Willem Barentszstraat 50 Rotterdam
Address
Norway SDSs please use Email: Netherlands
WSS.GLOBAL.SDSINFO@wilhelmsen.com
--------- Norway
Telephone +47 67 58 40 00 Not Available +31 10 4877 777

Fax Not Available Not Available Not Available
Website http://www.wilhelmsen.com/ http://www.wilhelmsen.com http://www.wilhelmsen.com
Email wss.norway.cs@wilhelmsen.com wss.global.sdsinfo@wilhelmsen.com wss.rotterdam@wilhelmsen.com
Registered company name Wilhelmsen Ships Service AS* Central Warehouse

Address Willem Barentszstraat 50 Rotterdam Netherlands
Telephone +31 10 4877 777
Catalogue Number: 575696 (25 liter) Page 2 of 14 Issue Date: 07/06/2021
CARBONCLEAN LT
Fax Not Available

Website http://www.wilhelmsen.com
Email wss.rotterdam@wilhelmsen.com
1.4. Emergency telephone number

Association / Organisation Giftinformasjonssentralen - 24 timer 24hrs - Chemtrec Dutch nat. poison centre
Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers
Other emergency
+31-10-4877700 +1 800 424 9300 + 31 10 4877700
telephone numbers
Association / Organisation Dutch nat. poison centre
Emergency telephone
+ 31 30 274 88 88
numbers
Other emergency
+ 31-10-4877700
telephone numbers
SECTION 2 Hazards identification
2.1. Classification of the substance or mixture
Considered a hazardous mixture according to Reg. (EC) No 1272/2008 and their amendments. Not classified as Dangerous Goods for
transport purposes.
Classification according to
regulation (EC) No
H373 - Specific Target Organ Toxicity - Repeated Exposure Category 2, H318 - Serious Eye Damage/Eye Irritation Category 1
1272/2008 [CLP] and
amendments [1]
Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI
2.2. Label elements
Hazard pictogram(s)
Signal word Danger
Hazard statement(s)
H373 May cause damage to organs through prolonged or repeated exposure. (Respiratory system) (Inhalation)
H318 Causes serious eye damage.
Supplementary statement(s)
Not Applicable
CLP classification (additional)

Not Applicable
Precautionary statement(s) Prevention

P260 Do not breathe mist/vapours/spray.
P280 Wear protective gloves, protective clothing, eye protection and face protection.
Precautionary statement(s) Response

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor/physician/first aider.
Precautionary statement(s) Storage

CARBONCLEAN LT
Not Applicable
Precautionary statement(s) Disposal

P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.
2.3. Other hazards

Ingestion may produce health damage*.
May produce skin discomfort*.
2-(2-butoxyethoxy)ethanol Listed in the Europe Regulation (EC) No 1907/2006 - Annex XVII (Restrictions may apply)
SECTION 3 Composition / information on ingredients
3.1.Substances
See 'Composition on ingredients' in Section 3.2
3.2.Mixtures
1.CAS No
2.EC No Classification according to regulation (EC) Nanoform Particle
%[weight] Name
3.Index No No 1272/2008 [CLP] and amendments Characteristics
4.REACH No
1.112-34-5*
2.203-961-6 Serious Eye Damage/Eye Irritation Category 2;
5-10 2-(2-butoxyethoxy)ethanol * Not Available
3.603-096-00-8 H319 [1]
4.01-2119475104-44-XXXX
1.160875-66-1*
2.Not Available Serious Eye Damage/Eye Irritation Category 1,
5-10 fatty alcohol ethoxylates Not Available
3.Not Available Acute Toxicity (Oral) Category 4; H318, H302 [1]
4.Not Available
1.68439-46-3*
2.Not Available
Serious Eye Damage/Eye Irritation Category 2;
3.Not Available 10-30 primary c9-c11 alcoholethoxylate Not Available
H319 [1]
4.01-2119980051-45-
XXXX|01-2119979533-26-XXXX
Specific Target Organ Toxicity - Repeated

1.Not Available
Hydrocarbons, C10-C13, Exposure Category 1, Aspiration Hazard
2.919-164-8
5-10 n-alkanes, isoalkanes, cyclics, Category 1, Hazardous to the Aquatic Not Available
3.Not Available
aromatics (2-25%)- Environment Long-Term Hazard Category 3;
4.01-21194739 77-17-0004
H372, H304, H412, EUH066 [1]
1.1554325-20-0* Acute Toxicity (Oral) Category 4, Skin

2.Not Available Quaternary C12-C14 Corrosion/Irritation Category 2, Serious Eye
1-5 Not Available
3.Not Available Alkylaminetoxilate chloride Damage/Eye Irritation Category 1; H302, H315,
4.Not Available H318 [1]
Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from
C&L; * EU IOELVs available; [e] Substance identified as having endocrine disrupting properties
SECTION 4 First aid measures
4.1. Description of first aid measures

If this product comes in contact with the eyes:
Immediately hold eyelids apart and flush the eye continuously with running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally
Eye Contact lifting the upper and lower lids.
Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
Transport to hospital or doctor without delay.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin contact occurs:

Immediately remove all contaminated clothing, including footwear.
Skin Contact
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Inhalation
Other measures are usually unnecessary.
CARBONCLEAN LT
If swallowed do NOT induce vomiting.

If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and
prevent aspiration.
Ingestion Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
See Section 11
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5 Firefighting measures
5.1. Extinguishing media

Water spray or fog.
Foam.
Dry chemical powder.
5.2. Special hazards arising from the substrate or mixture

Fire Incompatibility None known.
5.3. Advice for firefighters

Alert Fire Brigade and tell them location and nature of hazard.
Fire Fighting Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or water course.
Combustible.
Slight fire hazard when exposed to heat or flame.
Fire/Explosion Hazard Heating may cause expansion or decomposition leading to violent rupture of containers.
May emit poisonous fumes.
May emit corrosive fumes.
SECTION 6 Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures

See section 8
6.2. Environmental precautions

See section 12
6.3. Methods and material for containment and cleaning up

Remove all ignition sources.
Minor Spills Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Moderate hazard.
Major Spills Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
6.4. Reference to other sections

Personal Protective Equipment advice is contained in Section 8 of the SDS.
SECTION 7 Handling and storage
7.1. Precautions for safe handling

Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Safe handling
Use in a well-ventilated area.
DO NOT allow clothing wet with material to stay in contact with skin
CARBONCLEAN LT
Fire and explosion

See section 5
protection
Store in original containers.
Other information Keep containers securely sealed.
No smoking, naked lights or ignition sources.
7.2. Conditions for safe storage, including any incompatibilities

Metal can or drum
Suitable container Packaging as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Storage incompatibility None known
+ x + x + + +
X — Must not be stored together

0 — May be stored together with specific preventions
+ — May be stored together
Note: Depending on other risk factors, compatibility assessment based on the table above may not be relevant to storage situations, particularly where large volumes
of dangerous goods are stored and handled. Reference should be made to the Safety Data Sheets for each substance or article and risks assessed accordingly.
7.3. Specific end use(s)

See section 1.2
SECTION 8 Exposure controls / personal protection
8.1. Control parameters

DNELs PNECs
Ingredient
Exposure Pattern Worker Compartment
Dermal 83 mg/kg bw/day (Systemic, Chronic)

1.1 mg/L (Water (Fresh))
Inhalation 67.5 mg/m³ (Systemic, Chronic)
0.11 mg/L (Water - Intermittent release)
Inhalation 67.5 mg/m³ (Local, Chronic)
11 mg/L (Water (Marine))
Inhalation 101.2 mg/m³ (Local, Acute)
4.4 mg/kg sediment dw (Sediment (Fresh Water))
2-(2-butoxyethoxy)ethanol Dermal 50 mg/kg bw/day (Systemic, Chronic) *
0.44 mg/kg sediment dw (Sediment (Marine))
Inhalation 40.5 mg/m³ (Systemic, Chronic) *
0.32 mg/kg soil dw (Soil)
Oral 5 mg/kg bw/day (Systemic, Chronic) *
200 mg/L (STP)
Inhalation 40.5 mg/m³ (Local, Chronic) *
56 mg/kg food (Oral)
Inhalation 60.7 mg/m³ (Local, Acute) *
0.104 mg/L (Water (Fresh))
Dermal 2 080 mg/kg bw/day (Systemic, Chronic) 0.104 mg/L (Water - Intermittent release)
Inhalation 294 mg/m³ (Systemic, Chronic) 0.014 mg/L (Water (Marine))
primary c9-c11
Dermal 1 250 mg/kg bw/day (Systemic, Chronic) * 13.7 mg/kg sediment dw (Sediment (Fresh Water))
alcoholethoxylate
Inhalation 87 mg/m³ (Systemic, Chronic) * 13.7 mg/kg sediment dw (Sediment (Marine))
Oral 25 mg/kg bw/day (Systemic, Chronic) * 1 mg/kg soil dw (Soil)
1.4 mg/L (STP)
* Values for General Population
Occupational Exposure Limits (OEL)
INGREDIENT DATA
Source Ingredient Material name TWA STEL Peak Notes
EU Consolidated List of
Indicative Occupational 2-(2-Butoxyethoxy) 10 ppm / 67.5 101.2 mg/m3 / Not Not
2-(2-butoxyethoxy)ethanol
Exposure Limit Values ethanol mg/m3 15 ppm Available Available
(IOELVs)
Norway regulations on action
rvalues o a nd limitf values
physical and chemical
10 ppm / 68 Not
factors in the work 2-(2-butoxyethoxy)ethanol 2-2(butoksyetoksy)etanol Not Available E
mg/m3 Available
environment and infection
risk groups for biological
factors
CARBONCLEAN LT
Emergency Limits
Ingredient TEEL-1 TEEL-2 TEEL-3
2-(2-butoxyethoxy)ethanol 30 ppm 33 ppm 200 ppm
Ingredient Original IDLH Revised IDLH
2-(2-butoxyethoxy)ethanol Not Available Not Available
fatty alcohol ethoxylates Not Available Not Available
primary c9-c11
Not Available Not Available
alcoholethoxylate
Hydrocarbons, C10-C13,
n-alkanes, isoalkanes, Not Available Not Available
cyclics, aromatics (2-25%)-
Quaternary C12-C14
Alkylaminetoxilate chloride
Occupational Exposure Banding
Ingredient Occupational Exposure Band Rating Occupational Exposure Band Limit

fatty alcohol ethoxylates E ≤ 0.1 ppm
primary c9-c11
E ≤ 0.1 ppm
alcoholethoxylate
Quaternary C12-C14
E ≤ 0.01 mg/m³
Notes: Occupational exposure banding is a process of assigning chemicals into specific categories or bands based on a chemical's
potency and the adverse health outcomes associated with exposure. The output of this process is an occupational exposure
band (OEB), which corresponds to a range of exposure concentrations that are expected to protect worker health.
MATERIAL DATA
Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historically occupational exposure standards for
these irritants have been based on observation of workers' responses to various airborne concentrations. Present day expectations require that nearly every
individual should be protected against even minor sensory irritation and exposure standards are established using uncertainty factors or safety factors of 5 to 10 or
more.
8.2. Exposure controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed
engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to
8.2.1. Appropriate
provide this high level of protection.
engineering controls
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
8.2.2. Personal protection
Safety glasses with side shields.

Eye and face protection Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants.
Skin protection See Hand protection below

Wear chemical protective gloves, e.g. PVC.
Wear safety footwear or safety gumboots, e.g. Rubber
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from
Hands/feet protection manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material
can not be calculated in advance and has therefore to be checked prior to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be
observed when making a final choice.
Body protection See Other protection below

Overalls.
Other protection P.V.C apron.
Barrier cream.
8.2.3. Environmental exposure controls

See section 12
CARBONCLEAN LT
SECTION 9 Physical and chemical properties
9.1. Information on basic physical and chemical properties

Appearance Yellow
Relative density (Water =

Physical state Liquid 0.950 - 0.960
1)
Partition coefficient
Odour Not Available Not Available
n-octanol / water
Auto-ignition temperature
Odour threshold Not Available Not Available
(°C)
Decomposition
pH (as supplied) Not Available Not Available
temperature
Melting point / freezing
Not Available Viscosity (cSt) Not Available
point (°C)
Initial boiling point and
>100 Molecular weight (g/mol) Not Available
boiling range (°C)
Flash point (°C) >61 Taste Not Available
Evaporation rate Not Available BuAC = 1 Explosive properties Not Available

Flammability Combustible. Oxidising properties Not Available
Surface Tension (dyn/cm
Upper Explosive Limit (%) Not Applicable Not Available
or mN/m)
Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available

Solubility in water Miscible pH as a solution (%) Not Applicable
Vapour density (Air = 1) Not Available VOC g/L Not Available
Nanoform Particle
Nanoform Solubility Not Available Not Available
Characteristics
Particle Size Not Available
9.2. Other information

Not Available
SECTION 10 Stability and reactivity
10.1.Reactivity See section 7.2
Unstable in the presence of incompatible materials.

10.2. Chemical stability Product is considered stable.
Hazardous polymerisation will not occur.
10.3. Possibility of
See section 7.2
hazardous reactions
10.4. Conditions to avoid See section 7.2
10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3
decomposition products
SECTION 11 Toxicological information
11.1. Information on toxicological effects

The material is not thought to produce either adverse health effects or irritation of the respiratory tract following inhalation (as
classified by EC Directives using animal models). Nevertheless, adverse systemic effects have been produced following
Inhaled
exposure of animals by at least one other route and good hygiene practice requires that exposure be kept to a minimum and that
suitable control measures be used in an occupational setting.
Ingestion Accidental ingestion of the material may be damaging to the health of the individual.
Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce
health damage following entry through wounds, lesions or abrasions.
Skin Contact
Repeated exposure may cause skin cracking, flaking or drying following normal handling and use.
CARBONCLEAN LT
Limited evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a
substantial number of individuals following direct contact, and/or produces significant inflammation when applied to the healthy
intact skin of animals, for up to four hours, such inflammation being present twenty-four hours or more after the end of the
exposure period. Skin irritation may also be present after prolonged or repeated exposure; this may result in a form of contact
dermatitis (nonallergic). The dermatitis is often characterised by skin redness (erythema) and swelling (oedema) which may
progress to blistering (vesiculation), scaling and thickening of the epidermis.
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with
harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
When applied to the eye(s) of animals, the material produces severe ocular lesions which are present twenty-four hours or more
Eye
after instillation.
Long-term exposure to the product is not thought to produce chronic effects adverse to health (as classified by EC Directives
Chronic using animal models); nevertheless exposure by all routes should be minimised as a matter of course.
Prolonged or repeated skin contact may cause drying with cracking, irritation and possible dermatitis following.
TOXICITY IRRITATION
CARBONCLEAN LT
TOXICITY IRRITATION
2-(2-butoxyethoxy)ethanol Dermal (rabbit) LD50: 4120 mg/kg[2] Eye (rabbit): 20 mg/24h moderate
Oral(Rat) LD50; 5660 mg/kg[2] Eye (rabbit): 5 mg - SEVERE
TOXICITY IRRITATION
fatty alcohol ethoxylates
TOXICITY IRRITATION
Dermal (rabbit) LD50: >2000 mg/kg[2] Eye (human): SEVERE
primary c9-c11 Dermal (rabbit) LD50: >5000 mg/kg *[2] Eye: adverse effect observed (irritating)[1]
alcoholethoxylate Oral(Rat) LD50; 1378 mg/kg[2] Skin: no adverse effect observed (not irritating)[1]
Oral(Rat) LD50; 1400 mg/kg *[2] Skin: SEVERE
Oral(Rat) LD50; 2700 mg/kg *[2]
TOXICITY IRRITATION
Hydrocarbons, C10-C13, Dermal (Other) LD50: >3400 mg/kg[2] Not Available
n-alkanes, isoalkanes,
cyclics, aromatics (2-25%)- Inhalation(Rat) LC50; 13,1 mg/kg[2]
Oral(Rat) LD50; >15000 mg/kg[2]
Quaternary C12-C14 TOXICITY IRRITATION

Alkylaminetoxilate chloride Oral(Rat) LD50; >300 mg/kg[2] Not Available
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS.
Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances
For diethylene glycol monoalkyl ethers and their acetates:

This category includes diethylene glycol ethyl ether (DGEE), diethylene glycol propyl ether (DGPE) diethylene glycol butyl ether
(DGBE) and diethylene glycol hexyl ether (DGHE) and their acetates.
2-(2-butoxyethoxy)ethanol Acute toxicity: There are adequate oral, inhalation and/or dermal toxicity studies on the category members. Oral LD50 values in
rats for all category members are all > 3000 mg/kg bw, with values generally decreasing with increasing molecular weight. Four
to eight hour acute inhalation toxicity studies were conducted for all category members except DGPE in rats at the highest
vapour concentrations achievable.
Human beings have regular contact with alcohol ethoxylates through a variety of industrial and consumer products such as
soaps, detergents, and other cleaning products . Exposure to these chemicals can occur through ingestion, inhalation, or contact
with the skin or eyes. Studies of acute toxicity show that volumes well above a reasonable intake level would have to occur to
produce any toxic response.
Alcohol ethoxylates are according to CESIO (2000) classified as Irritant or Harmful depending on the number of EO-units:
EO < 5 gives Irritant (Xi) with R38 (Irritating to skin) and R41 (Risk of serious damage to eyes)
primary c9-c11
EO > 5-15 gives Harmful (Xn) with R22 (Harmful if swallowed) - R38/41
alcoholethoxylate
EO > 15-20 gives Harmful (Xn) with R22-41
>20 EO is not classified (CESIO 2000)
Oxo-AE, C13 EO10 and C13 EO15, are Irritating (Xi) with R36/38 (Irritating to eyes and skin) .
AE are not included in Annex 1 of the list of dangerous substances of the Council Directive 67/548/EEC
In general, alcohol ethoxylates (AE) are readily absorbed through the skin of guinea pigs and rats and through the
CARBONCLEAN LT
gastrointestinal mucosa of rats. AE are quickly eliminated from the body through the urine, faeces, and expired air (CO2).Orally
dosed AE was absorbed rapidly and extensively in rats, and more than 75% of the dose was absorbed. When applied to the skin
of humans, the doses were absorbed slowly and incompletely (50% absorbed in 72 hours).
The material may produce severe skin irritation after prolonged or repeated exposure, and may produce a contact dermatitis
(nonallergic). This form of dermatitis is often characterised by skin redness (erythema) thickening of the epidermis.
Histologically there may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the epidermis.
Prolonged contact is unlikely, given the severity of response, but repeated exposures may produce severe ulceration.
Dermal (rabbit): 4000 mg/kg * Somnolence, ataxia, diarrhoea recorded.
& primary c9-c11 The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to
alcoholethoxylate irritants may produce conjunctivitis.
Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity
Serious Eye
STOT - Single Exposure
Damage/Irritation
Respiratory or Skin
STOT - Repeated Exposure
sensitisation
Mutagenicity Aspiration Hazard
Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification
11.2.1. Endocrine Disruption Properties

Not Available
SECTION 12 Ecological information
12.1. Toxicity
Endpoint Test Duration (hr) Species Value Source

CARBONCLEAN LT Not Not Not
Available Available Available

LC50 96h Fish 1300mg/l 2
EC50 72h Algae or other aquatic plants 1101mg/l 2
EC50 48h Crustacea >100mg/l 1
NOEC(ECx) 96h Algae or other aquatic plants >=100mg/l 1
EC50 96h Algae or other aquatic plants >100mg/l 1

fatty alcohol ethoxylates Not Not Not

NOEC(ECx) 720h Fish 0.11-0.28mg/l 2
primary c9-c11
LC50 96h Fish 5-7mg/l 2
alcoholethoxylate
EC50 48h Crustacea 2.5mg/l 2
EC50 96h Algae or other aquatic plants 1.4mg/l 2

EC50 48 Crustacea Daphnia magna 100mg/L 8
n-alkanes, isoalkanes,
cyclics, aromatics (2-25%)- Fish Oncorhynchus mykiss (Rainbow
LC50 96 10-100mg/L 8
trout)

Quaternary C12-C14
Not Not Not
Alkylaminetoxilate chloride Not Available Not Available
Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity
3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5.
CARBONCLEAN LT
ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8.
Vendor Data
Harmful to aquatic organisms.

DO NOT discharge into sewer or waterways.
12.2. Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air
2-(2-butoxyethoxy)ethanol LOW LOW
12.3. Bioaccumulative potential

Ingredient Bioaccumulation
2-(2-butoxyethoxy)ethanol LOW (BCF = 0.46)
12.4. Mobility in soil

Ingredient Mobility
2-(2-butoxyethoxy)ethanol LOW (KOC = 10)
12.5. Results of PBT and vPvB assessment

P B T
Relevant available data Not Available Not Available Not Available

PBT
vPvB
PBT Criteria fulfilled? No

vPvB No
12.6. Endocrine Disruption Properties

Not Available
12.7. Other adverse effects

Not Available
SECTION 13 Disposal considerations
13.1. Waste treatment methods

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws
operating in their area. In some areas, certain wastes must be tracked.
DO NOT allow wash water from cleaning or process equipment to enter drains.
Product / Packaging It may be necessary to collect all wash water for treatment before disposal.
disposal In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
Recycle wherever possible or consult manufacturer for recycling options.
Consult State Land Waste Management Authority for disposal.
Bury residue in an authorised landfill.
Waste treatment options Not Available
Sewage disposal options Not Available
SECTION 14 Transport information
Labels Required
Marine Pollutant NO
Land transport (ADR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

14.1. UN number Not Applicable
14.2. UN proper shipping

Not Applicable
name
CARBONCLEAN LT
14.3. Transport hazard Class Not Applicable

class(es) Subrisk Not Applicable
14.4. Packing group Not Applicable

14.5. Environmental
Not Applicable
hazard
Hazard identification (Kemler) Not Applicable

Classification code Not Applicable
14.6. Special precautions Hazard Label Not Applicable

for user Special provisions Not Applicable
Limited quantity Not Applicable

Tunnel Restriction Code Not Applicable
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Not Applicable
name
ICAO/IATA Class Not Applicable

14.3. Transport hazard
ICAO / IATA Subrisk Not Applicable
class(es)
ERG Code Not Applicable
14.5. Environmental
Not Applicable
hazard
Special provisions Not Applicable
Cargo Only Packing Instructions Not Applicable

Cargo Only Maximum Qty / Pack Not Applicable
14.6. Special precautions
Passenger and Cargo Packing Instructions Not Applicable
for user
Passenger and Cargo Maximum Qty / Pack Not Applicable
Passenger and Cargo Limited Quantity Packing Instructions Not Applicable
Passenger and Cargo Limited Maximum Qty / Pack Not Applicable
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Not Applicable
name
14.3. Transport hazard IMDG Class Not Applicable

class(es) IMDG Subrisk Not Applicable

14.5. Environmental
Not Applicable
hazard
EMS Number Not Applicable

for user
Limited Quantities Not Applicable
Inland waterways transport (ADN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Not Applicable
name
14.3. Transport hazard

Not Applicable Not Applicable
class(es)

CARBONCLEAN LT
14.5. Environmental
Not Applicable
hazard
Classification code Not Applicable

Limited quantity Not Applicable
for user
Equipment required Not Applicable
Fire cones number Not Applicable
14.7. Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable
14.8. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group
2-(2-butoxyethoxy)ethanol Not Available
fatty alcohol ethoxylates Not Available

primary c9-c11
Not Available
alcoholethoxylate
n-alkanes, isoalkanes, Not Available
Quaternary C12-C14
Not Available
14.9. Transport in bulk in accordance with the ICG Code

Product name Ship Type
2-(2-butoxyethoxy)ethanol Not Available
fatty alcohol ethoxylates Not Available

primary c9-c11
Not Available
alcoholethoxylate
n-alkanes, isoalkanes, Not Available
Quaternary C12-C14
Not Available
SECTION 15 Regulatory information
15.1. Safety, health and environmental regulations / legislation specific for the substance or mixture
2-(2-butoxyethoxy)ethanol is found on the following regulatory lists
EU Consolidated List of Indicative Occupational Exposure Limit Values European Union - European Inventory of Existing Commercial Chemical
(IOELVs) Substances (EINECS)
EU REACH Regulation (EC) No 1907/2006 - Annex XVII - Restrictions on the European Union (EU) Regulation (EC) No 1272/2008 on Classification,
manufacture, placing on the market and use of certain dangerous substances, Labelling and Packaging of Substances and Mixtures - Annex VI
mixtures and articles dNorway regulations on n action values and limit
a values for physical
Europe EC Inventory chemical factors in the work environment and infection risk groups for
biological factors
fatty alcohol ethoxylates is found on the following regulatory lists
Not Applicable
primary c9-c11 alcoholethoxylate is found on the following regulatory lists
Not Applicable
Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, aromatics (2-25%)- is found on the following regulatory lists
Not Applicable
Quaternary C12-C14 Alkylaminetoxilate chloride is found on the following regulatory lists

Not Applicable
CARBONCLEAN LT
This safety data sheet is in compliance with the following EU legislation and its adaptations - as far as applicable - : Directives 98/24/EC, - 92/85/EEC, - 94/33/EC,
- 2008/98/EC, - 2010/75/EU; Commission Regulation (EU) 2020/878; Regulation (EC) No 1272/2008 as updated through ATPs.
15.2. Chemical safety assessment

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
National Inventory Status

National Inventory Status
Australia - AIIC / Australia
No (Quaternary C12-C14 Alkylaminetoxilate chloride)
Non-Industrial Use
Canada - DSL No (fatty alcohol ethoxylates; Quaternary C12-C14 Alkylaminetoxilate chloride)
No (2-(2-butoxyethoxy)ethanol; fatty alcohol ethoxylates; primary c9-c11 alcoholethoxylate; Quaternary C12-C14

Canada - NDSL
Alkylaminetoxilate chloride)
China - IECSC No (Quaternary C12-C14 Alkylaminetoxilate chloride)

Europe - EINEC / ELINCS /
No (fatty alcohol ethoxylates; primary c9-c11 alcoholethoxylate; Quaternary C12-C14 Alkylaminetoxilate chloride)
NLP
Japan - ENCS No (Quaternary C12-C14 Alkylaminetoxilate chloride)
Korea - KECI No (Quaternary C12-C14 Alkylaminetoxilate chloride)
New Zealand - NZIoC No (Quaternary C12-C14 Alkylaminetoxilate chloride)

Philippines - PICCS No (fatty alcohol ethoxylates; Quaternary C12-C14 Alkylaminetoxilate chloride)
USA - TSCA No (Quaternary C12-C14 Alkylaminetoxilate chloride)

Taiwan - TCSI No (Quaternary C12-C14 Alkylaminetoxilate chloride)
Mexico - INSQ No (fatty alcohol ethoxylates; Quaternary C12-C14 Alkylaminetoxilate chloride)

Vietnam - NCI No (Quaternary C12-C14 Alkylaminetoxilate chloride)
Russia - FBEPH No (fatty alcohol ethoxylates; primary c9-c11 alcoholethoxylate; Quaternary C12-C14 Alkylaminetoxilate chloride)
Yes = All CAS declared ingredients are on the inventory

Legend: No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require
registration.
SECTION 16 Other information
Revision Date 07/06/2021

Initial Date 08/03/2018
CONTACT POINT
- For quotations contact your local Customer Services - http://wssdirectory.wilhelmsen.com/#/customerservices - - Responsible for safety data sheet Wilhelmsen
Ships Service AS - Prepared by: Product HSE Manager, - Email: Email: WSS.GLOBAL.SDSINFO@wilhelmsen.com - Telephone: Tel.: +31 10 4877775
Full text Risk and Hazard codes

H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.
H319 Causes serious eye irritation.
H372 Causes damage to organs through prolonged or repeated exposure.

H412 Harmful to aquatic life with long lasting effects.
SDS Version Summary

Version Date of Update Sections Updated
11.20.10.4 07/06/2021 Acute Health (skin), Chronic Health, Classification, Ingredients, Physical Properties, Use
11.20.11.4 07/06/2021 Regulation Change
11.20.11.5 09/06/2021 Template Change

11.20.11.6 11/06/2021 Template Change
11.20.11.7 15/06/2021 Template Change

11.20.12.8 05/07/2021 Template Change

CARBONCLEAN LT
Version Date of Update Sections Updated


11.20.16.9 01/08/2021 Template Change

11.20.20.10 29/08/2021 Template Change

11.20.21.11 16/09/2021 Template Change
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch
Classification committee using available literature references.
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks
in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available
engineering controls must be considered.
Carbonclean LT includes a chemical, quarternary alkyl methyl amine ethoxylate methyl chloride (CAS No. 1554325-20-0), that is subject to a Significant New Use
Rule (SNUR) at 40 CFR §721.10859. The SNUR for this substance requires that you report to the EPA any predictable or purposeful release of a process stream
containing the substance as defined in 40 CFR §721.90 (a)(4), (b)(4), and (c)(4), with N = 29, through a Significant New Use Notice (SNUN). The calculation for
the surface water concentrations is found in 40 CFR §721.91.
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CARBONCLEAN LT

Wilhelmsen Ships Service AS

SECTION 1 Identification of the substance / mixture and of the company / undertaking

1.1. Product Identifier

Chemical Name Not Applicable

Uses advised against Not Applicable

1.3. Details of the supplier of the safety data sheet

Telephone +47 67 58 40 00 Not Available +31 10 4877 777

Registered company name Wilhelmsen Ships Service AS* Central Warehouse

Fax Not Available

1.4. Emergency telephone number

Association / Organisation Dutch nat. poison centre

SECTION 2 Hazards identification

2.1. Classification of the substance or mixture

2.2. Label elements

Signal word Danger

H318 Causes serious eye damage.

CLP classification (additional)

Precautionary statement(s) Prevention

Precautionary statement(s) Response

Precautionary statement(s) Storage

Precautionary statement(s) Disposal

2.3. Other hazards

May produce skin discomfort*.

SECTION 3 Composition / information on ingredients

Specific Target Organ Toxicity - Repeated

1.1554325-20-0* Acute Toxicity (Oral) Category 4, Skin

SECTION 4 First aid measures

4.1. Description of first aid measures

If skin contact occurs:

If swallowed do NOT induce vomiting.

SECTION 5 Firefighting measures

5.1. Extinguishing media

5.2. Special hazards arising from the substrate or mixture

5.3. Advice for firefighters

SECTION 6 Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

SECTION 7 Handling and storage

7.1. Precautions for safe handling

Fire and explosion

7.2. Conditions for safe storage, including any incompatibilities

X — Must not be stored together

7.3. Specific end use(s)

SECTION 8 Exposure controls / personal protection

8.1. Control parameters

Dermal 83 mg/kg bw/day (Systemic, Chronic)

* Values for General Population

Occupational Exposure Limits (OEL)

Source Ingredient Material name TWA STEL Peak Notes

Ingredient TEEL-1 TEEL-2 TEEL-3

2-(2-butoxyethoxy)ethanol 30 ppm 33 ppm 200 ppm

Ingredient Original IDLH Revised IDLH

2-(2-butoxyethoxy)ethanol Not Available Not Available

fatty alcohol ethoxylates Not Available Not Available

Occupational Exposure Banding

Ingredient Occupational Exposure Band Rating Occupational Exposure Band Limit