SAFETY DATA SHEET

DULUX WASH & WEAR (MATT)

Section 1. Identification
Product name : DULUX WASH & WEAR (MATT)

Product use : Waterborne coating for interior use.

Supplier's details : Akzo Nobel Paints (Singapore) Pte Ltd

3 Changi Business Park Vista
#06-01, Singapore 486051
Tel.: 65-62650677
Fax : 65-62654775
Internet: www.dulux.com.sg

email address : customer.care.sg@akzonobel.com

Emergency telephone : Customer Care Tel.: (65) 6265 0677

number (8.30 am to 5.00 pm, Mon to Fri)

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Version : 0.01 Date of issue/Date of revision : 28-9-2022

Date of previous issue : No previous validation

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Section 2. Hazards identification

Classification of the : Not classified.
substance or mixture

GHS label elements, including precautionary statements

Signal word : No signal word.
Hazard statements : No known significant effects or critical hazards.
Precautionary statements
General : P102 - Keep out of reach of children.
P101 - If medical advice is needed, have product container or label at hand.
Prevention : P262 - Do not get in eyes, on skin, or on clothing.
Response : P312 - Call a doctor if you feel unwell.
Storage : Not applicable.
Disposal : P501 - Dispose of contents and container in accordance with all local, regional,
national or international regulations.
Hazardous ingredients : 1-isopropyl-2,2-dimethyltrimethylene diisobutyrate
silver chloride

Other hazards which do not : None known.

result in classification

Section 3. Composition/information on ingredients

Substance/mixture : Mixture

Ingredient name % CAS number

1-isopropyl-2,2-dimethyltrimethylene diisobutyrate 1 - < 2.5 6846-50-0
silver chloride 0-<1 7783-90-6
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Get medical attention if irritation
occurs.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical attention if symptoms occur.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur.
Ingestion : Wash out mouth with water. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Do not induce vomiting
unless directed to do so by medical personnel. Get medical attention if symptoms
occur.

Most important symptoms/effects, acute and delayed

Potential acute health effects

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Section 4. First aid measures

Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.

See toxicological information (Section 11)

Section 5. Firefighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst.
from the chemical
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Put on appropriate personal
protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

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Section 6. Accidental release measures

Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and material for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop
up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry
material and place in an appropriate waste disposal container. Dispose of via a
licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent
treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8).
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8.2 for additional
information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected
including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible
incompatibilities materials (see Section 10) and food and drink. Keep container tightly closed and
sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabelled containers.
Use appropriate containment to avoid environmental contamination. See Section 10
for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
None.

Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne
controls contaminants.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.

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 DULUX WASH & WEAR (MATT)

Section 8. Exposure controls/personal protection

Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: safety glasses with
side-shields.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary.
Gloves : When prolonged or frequently repeated contact may occur, a glove with a protection
class of 6 (breakthrough time >480 minutes according to EN374) is recommended.
Recommended gloves: Viton ® or Nitrile, thickness ≥ 0.38 mm.
When only brief contact is expected, a glove with protection class of 2 or higher
(breakthrough time >30 minutes according to EN374) is recommended.
Recommended gloves: Nitrile, thickness ≥ 0.12 mm.
Gloves should be replaced regularly and if there is any sign of damage to the glove
material.

The performance or effectiveness of the glove may be reduced by physical/chemical

damage and poor maintenance.
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Colour : Various: See label.
Odour : Not available.
Odour threshold : Not available.
pH : Not available.
Melting point : Not available.
Initial boiling point and : 100°C
boiling range
Flash point : Not applicable.
Burning time : Not applicable.
Burning rate : Not applicable.
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapour pressure : Not available.
Vapour density : Not available.
Relative density : 1.364

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Section 9. Physical and chemical properties

Solubility : Easily soluble in the following materials: cold water.
Solubility in water : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
SADT : Not available.
Viscosity : Kinematic (room temperature): 5.48 cm2/s

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : No specific data.

Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.
SADT : Not available.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Not available.
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
1-isopropyl- Skin - Mild irritant Guinea pig - 5 gm -
2,2-dimethyltrimethylene
diisobutyrate
Skin - Mild irritant Human - 504 hours 1 -
%I
Sensitisation
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Not available.

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Section 11. Toxicological information

Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.

Specific target organ toxicity (repeated exposure)

Not available.
Aspiration hazard
Not available.

Information on likely routes : Not available.

of exposure
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Delayed and immediate effects as well as chronic effects from short and long-term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
N/A

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Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
silver chloride Acute EC50 0.00022 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Chronic EC10 0.00016 mg/l Algae - Nostuc moscorum 15 days

Persistence/degradability
Not available.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
1-isopropyl- - 5340 high
2,2-dimethyltrimethylene
diisobutyrate
silver chloride - 70 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible. This material and
its container must be disposed of in a safe way. Empty containers or liners may
retain some product residues. Avoid dispersal of spilt material and runoff and
contact with soil, waterways, drains and sewers.

Section 14. Transport information

Information pertaining to IATA and ADN is considered not relevant since the
material is not packaged in the correct approved packaging required of these
methods of transport.
ADR IMDG

14.1 UN number UN3082 Not regulated.

14.2 UN proper ENVIRONMENTALLY HAZARDOUS Not applicable.

shipping name SUBSTANCE, LIQUID, N.O.S. (OIT)

14.3 Transport
hazard class(es)
Class 9 Not applicable.

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 DULUX WASH & WEAR (MATT)

Information pertaining to IATA and ADN is considered not relevant since the
material is not packaged in the correct approved packaging required of these
methods of transport.
Subsidiary class - -

14.4 Packing group III Not applicable.

14.5
Environmental
hazards
Marine pollutant Yes. No.

Marine pollutant Not available.

substances
14.6 Special Transport within user’s premises: always
precautions for transport in closed containers that are upright
user and secure. Ensure that persons transporting
the product know what to do in the event of an
accident or spillage.
HI/Kemler number 90

Emergency F-A, S-F

schedules (EmS)

Transport in bulk according : Not applicable.

to IMO instruments

Additional This product is not regulated as a dangerous -

information good when transported in sizes of ≤5 L or ≤5 kg,
provided the packagings meet the general
provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to
4.1.1.8.

Section 15. Regulatory information

Safety, health and : SS586: Specification for hazard communication for hazardous chemicals and
environmental regulations dangerous goods.
specific for the product
Singapore - hazardous chemicals under government control
None.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.

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 DULUX WASH & WEAR (MATT)

Section 15. Regulatory information

UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.

Section 16. Other information

Product code : 571676
History
Date of printing : 28-9-2022
Date of issue/Date of : 28-9-2022
revision
Date of previous issue : No previous validation
Version : 0.01
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Procedure used to derive the classification
Classification Justification
Not classified.
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader
IMPORTANT NOTE The information in this data sheet is not intended to be exhaustive and is based on the
present state of our knowledge and on current laws: any person using the product for any purpose other than
that specifically recommended in the technical data sheet without first obtaining written confirmation from us
as to the suitability of the product for the intended purpose does so at his own risk. It is always the
responsibility of the user to take all necessary steps to fulfill the demands set out in the local rules and
legislation. Always read the Material Data Sheet and the Technical Data Sheet for this product if available. All
advice we give or any statement made about the product by us (whether in this data sheet or otherwise) is
correct to the best of our knowledge but we have no control over the quality or the condition of the substrate
or the many factors affecting the use and application of the product. Therefore, unless we specifically agree in
writing otherwise, we do not accept any liability whatsoever for the performance of the product or for any loss
or damage arising out of the use of the product. All products supplied and technical advice given are subject
to our standard terms and conditions of sale. You should request a copy of this document and review it
carefully. The information contained in this data sheet is subject to modification from time to time in the light
of experience and our policy of continuous development. It is the user's responsibility to verify that this data
sheet is current prior to using the product.

Brand names mentioned in this data sheet are trademarks of or are licensed to AkzoNobel.

Head Office
AkzoNobel Decorative Coatings BV, Christian Neefestraat 2, 1077 WW Amsterdam, The Netherlands

Version : 0.01 Date of issue/Date of revision : 28-9-2022

Date of previous issue : No previous validation