Product Name: MARINE USED LUBRICATING OIL FOR ANALYSIS

Revision Date: 30 Apr 2010

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MATERIAL SAFETY DATA SHEET

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

PRODUCT
Product Name: MARINE USED LUBRICATING OIL FOR ANALYSIS
Product Description: Hydrocarbons and Additives
Product Code: 361014-03
Intended Use: Recovery/by-product

COMPANY IDENTIFICATION
Supplier: EXXON MOBIL CORPORATION
3225 GALLOWS ROAD
FAIRFAX, VA. 22037 USA
24 Hour Health Emergency 609-737-4411
Transportation Emergency Phone 800-424-9300
ExxonMobil Transportation No. 281-834-3296
Product Technical Information 800-662-4525 / 800-947-9147
MSDS Internet Address http://www.exxon.com, http://www.mobil.com

SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS

Reportable Hazardous Substance(s) or Complex Substance(s)

Name CAS# Concentration*
CARBON BLACK 1333-86-4 0.1 - 1%
**LUBRICATING OILS, USED** 92045-40-4 90 - 100%
PHOSPHORODITHOIC ACID, O,O-DI C1-14-ALKYL 68649-42-3 1 - 5%
ESTERS, ZINC SALTS (2:1) (ZDDP)

* All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume.

SECTION 3 HAZARDS IDENTIFICATION

This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).

POTENTIAL HEALTH EFFECTS

Under conditions of poor personal hygiene and prolonged repeated contact, some polycyclic aromatic
compounds (PACs) have been suspected as a cause of skin cancer in humans. Excessive exposure may
result in eye, skin, or respiratory irritation.

ENVIRONMENTAL HAZARDS
May cause long-term adverse effects in the aquatic environment.

NFPA Hazard ID: Health: 1 Flammability: 1 Reactivity: 0

HMIS Hazard ID: Health: 1* Flammability: 1 Reactivity: 0

NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert
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advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary
from person to person.

SECTION 4 FIRST AID MEASURES

INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use
adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use
mouth-to-mouth resuscitation.

SKIN CONTACT
Remove contaminated clothing. Dry wipe exposed skin and cleanse with waterless hand cleaner and follow by
washing thoroughly with soap and water. For those providing assistance, avoid further skin contact to yourself
or others. Wear impervious gloves. Launder contaminated clothing separately before reuse. Discard
contaminated articles that cannot be laundered.

EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.

INGESTION
First aid is normally not required. Seek medical attention if discomfort occurs.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.

Inappropriate Extinguishing Media: Straight Streams of Water

FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams,
sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed
spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel.

Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulfur oxides, Incomplete combustion
products, Oxides of carbon, Metal Oxides

FLAMMABILITY PROPERTIES
Flash Point [Method]: >93C (200F) [ ASTM D-93]
Flammable Limits (Approximate volume % in air): LEL: 0.6 UEL: 7.0
Autoignition Temperature: N/D

SECTION 6 ACCIDENTAL RELEASE MEASURES

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NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations. US regulations require reporting releases of this material to the environment which exceed the
applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The
National Response Center can be reached at (800)424-8802.

SPILL MANAGEMENT
Land Spill: Stop leak if you can do it without risk. Small Spills: Absorb with earth, sand or other non-
combustible material and transfer to containers for later disposal. If liquid is too viscous for pumping, scrape it
up with shovels into a suitable container for recycle or disposal.

Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other
shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist
before using dispersants.

Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.

ENVIRONMENTAL PRECAUTIONS
Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
sewers, basements or confined areas.

SECTION 7 HANDLING AND STORAGE

HANDLING
Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. The composition of
used motor oil is variable, depending on the source of the used oil and segregation practices. Procedures
should be established to minimize contamination by ensuring segregation of used oil from other materials, such
as ethylene glycol and halogenated solvents, used in the same work area. Properly segregated used motor oil
can be expected to contain low levels of lead from leaded gasoline and aromatic hydrocarbons from oil
oxidation and fuel combustion by-products. Material can accumulate static charges which may cause an
electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any
flammable vapors from liquids or residues that may be present (e.g., during switch-loading operations). Use
proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from
static accumulation. Consult local applicable standards for guidance. Additional references include American
Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or
National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404
(Electrostatics - Code of practice for the avoidance of hazards due to static electricity).

Static Accumulator: This material is a static accumulator.

STORAGE
The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store
in open or unlabelled containers.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE LIMIT VALUES

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Exposure limits/standards (Note: Exposure limits are not additive)

Substance Name Form Limit / Standard NOTE Source

CARBON BLACK TWA 3.5 mg/m3 N/A OSHA Z1
CARBON BLACK TWA 3.5 mg/m3 N/A ACGIH

Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols
can occur, the following are recommended: 5 mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL, 5 mg/m³ - OSHA PEL.

NOTE: Limits/standards shown for guidance only. Follow applicable regulations.

ENGINEERING CONTROLS

The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.

PERSONAL PROTECTION

Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.

Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a

level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation.

For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.

Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:
Chemical resistant gloves are recommended. If contact with forearms is likely wear gauntlet style
gloves.

Eye Protection: If contact is likely, safety glasses with side shields are recommended.

Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
Chemical resistant clothing, including apron and sleeves, when handling bulk quantities is
recommended.

Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
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handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.

ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Typical physical and chemical properties are given below.

GENERAL INFORMATION
Physical State: Liquid
Color: Dark Brown
Odor: Characteristic
Odor Threshold: N/D

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION

Relative Density (at 15 C): 0.9
Flash Point [Method]: >93C (200F) [ ASTM D-93]
Flammable Limits (Approximate volume % in air): LEL: 0.6 UEL: 7.0
Autoignition Temperature: N/D
Boiling Point / Range: N/D
Vapor Density (Air = 1): > 2 at 101 kPa
Vapor Pressure: < 0.133 kPa (1 mm Hg) at 20 C
Evaporation Rate (n-butyl acetate = 1): N/D
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): N/D
Solubility in Water: Negligible
Viscosity: N/D
Oxidizing Properties: See Hazards Identification Section.

OTHER INFORMATION
Freezing Point: N/D
Melting Point: N/A

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Material is stable under normal conditions.

CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition.

MATERIALS TO AVOID: Strong oxidizers

HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.

HAZARDOUS POLYMERIZATION: Will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

ACUTE TOXICITY
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Route of Exposure Conclusion / Remarks
Inhalation
Toxicity: No end point data. Not determined.
Irritation: No end point data. Elevated temperatures or mechanical action may form vapors,
mist, or fumes which may be irritating to the eyes, nose, throat, or
lungs. Based on assessment of the components.

Ingestion
Toxicity (Rat): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials.

Skin
Toxicity (Rabbit): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials.
Irritation (Rabbit): No end point data. Negligible irritation to skin at ambient temperatures. Based on test
data for structurally similar materials.

Eye
Irritation (Rabbit): No end point data. May cause mild, short-lasting discomfort to eyes. Based on test
data for structurally similar materials.

CHRONIC/OTHER EFFECTS
For the product itself:
The toxicological properties of this material have not been fully assessed. This material must be used by or
under the supervision of a technically qualified person.
Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any
carcinogenic effects in chronic mouse skin painting studies.

Contains:
Carbon black: Certain carbon blacks have proved carcinogenic in animal studies. Inhalation animal studies of
high concentrations resulted in chronic inflammation, lung fibrosis and lung tumors. Epidemiology studies of
workers include findings of bronchitis, pneumonia, emphysema and excess cancer. Substances bound in a
polymer or other matrix should present little or no hazard.

Additional information is available by request.

The following ingredients are cited on the lists below:

Chemical Name CAS Number List Citations

CARBON BLACK 1333-86-4 5

--REGULATORY LISTS SEARCHED--

1 = NTP CARC 3 = IARC 1 5 = IARC 2B
2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC

SECTION 12 ECOLOGICAL INFORMATION

The information given is based on data available for the material, the components of the material, and similar materials.

ECOTOXICITY
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Material -- May cause long-term adverse effects in the aquatic environment.

PERSISTENCE AND DEGRADABILITY

Biodegradation:
Base oil component -- Expected to be inherently biodegradable

SECTION 13 DISPOSAL CONSIDERATIONS

Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.

DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclos ed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products.

REGULATORY DISPOSAL INFORMATION

RCRA Information: Disposal of unused product may be subject to RCRA regulations (40 CFR 261). Disposal
of the used product may also be regulated due to ignitability, corrosivity, reactivity or toxicity as determined by
the Toxicity Characteristic Leaching Procedure (TCLP). Potential RCRA characteristics:
TCLP (LEAD, BENZENE, CHROMIUM)

Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and
can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be
completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken
for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with
governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.

SECTION 14 TRANSPORT INFORMATION

LAND (DOT): Not Regulated for Land Transport

LAND (TDG): Not Regulated for Land Transport

SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code

AIR (IATA): Not Regulated for Air Transport

SECTION 15 REGULATORY INFORMATION

OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not classified
as hazardous in accordance with OSHA 29 CFR 1910.1200.

NATIONAL CHEMICAL INVENTORY LISTING: AICS, EINECS, ENCS

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EPCRA: This material contains no extremely hazardous substances.

Chemical Name CAS Number Typical Value Component TPQ Product TPQ
PHOSPHORUS 7723-14-0 0.108 %weight 100 LBS 92592.59 LBS

SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.

SARA (313) TOXIC RELEASE INVENTORY:

Chemical Name CAS Number Typical Value

PHOSPHORODITHOIC ACID, 68649-42-3 1 - 5%
O,O-DI C1-14-ALKYL ESTERS,
ZINC SALTS (2:1) (ZDDP)

The following ingredients are cited on the lists below:

Chemical Name CAS Number List Citations

**CALCIUM** 7440-70-2 17, 19
CARBON BLACK 1333-86-4 1, 4, 10, 13, 16, 17, 18, 19
**COPPER** 7440-50-8 15
PHOSPHORODITHOIC ACID, 68649-42-3 13, 15, 17
O,O-DI C1-14-ALKYL ESTERS,
ZINC SALTS (2:1) (ZDDP)
PHOSPHORUS 7723-14-0 1, 4
TOLUENE 108-88-3 15
XYLENES 1330-20-7 5, 15
ZINC 7440-66-6 15

--REGULATORY LISTS SEARCHED--

1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK
2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK
3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK
4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK
5 = TSCA 4 10 = CA P65 CARC 15 = MI 293

Code key: CARC=Carcinogen; REPRO=Reproductive

SECTION 16 OTHER INFORMATION

N/D = Not determined, N/A = Not applicable

THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:

Revision Changes:
Section 06: Notification Procedures - Header was modified.
Section 10 Stability and Reactivity - Header was modified.
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Section 13: Disposal Recommendations - Note was modified.
Section 13: Empty Container Warning was modified.
Section 08: Personal Protection was modified.
Section 08: Hand Protection was modified.
Section 09: Vapor Pressure was modified.
Section 07: Handling and Storage - Handling was modified.
Section 07: Handling and Storage - Storage Phrases was modified.
Section 05: Hazardous Combustion Products was modified.
Section 06: Accidental Release - Spill Management - Land was modified.
Section 06: Accidental Release - Spill Management - Water was modified.
Section 09: Relative Density - Header was modified.
Section 09: Flash Point C(F) was modified.
Section 08: Skin and Body Protection was modified.
Section 14: Sea (IMDG) - Header was modified.
Section 14: Air (IATA) - Header was modified.
Section 14: LAND (TDG) - Header was modified.
Section 14: LAND (DOT) - Header was modified.
Composition: Component table was modified.
Section 15: List Citations Table was modified.
Section 15: List Citation Table - Header was modified.
Section 14: LAND (DOT) - Default was modified.
Section 14: LAND (TDG) Default was modified.
Section 14: Sea (IMDG) - Default was modified.
Section 14: Air (IATA) - Default was modified.
Section 15: National Chemical Inventory Listing was modified.
Section 08: Exposure limits/standards was modified.
Section 06: Notification Procedures was modified.
Section 08: Exposure Limits Table was modified.
Section 09: Oxidizing Properties was modified.
Section 08: OEL Table - Notation Column - Header was modified.
Section 08: Exposure Limit Values - Header was modified.
Section 01: Company Contact Methods Sorted by Priority was modified.
Hazard Identification: OSHA - May be Hazardous Statement was modified.
Section 15: Community RTK - CAS - Header was added.
Section 15: Community RTK - Component TPQ - Header was added.
Section 15: Community RTK - Chemical Name - Header was added.
Section 15: Community RTK - Product RQ - Header was added.
Section 15: Community RTK Table was added.
Section 15: Community RTK - Typical Value - Header was added.
Section 08: OEL Table - Substance Name Column - Header was added.
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This warning is given to comply with California Health and Safety Code 25249.6 and does not constitute an admission
or a waiver of rights. This product contains a chemical known to the State of California to cause cancer.
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The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-
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publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for
convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.

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Internal Use Only

MHC: 0, 0, 0, 0, 0, 1 PPEC: D

DGN: 7010270 (1008267) (NA Core)

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Copyright 2002 Exxon Mobil Corporation, All rights reserved