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Example Solutions

Natural Gas Analysis

The Problem
For over 150 years, natural gas has been sold and holds a position of major significance in the world’s energy resources.
The Calorific Value of the Natural Gas is of vital importance, as this displays the ‘heating value’ and hence the relative
quality. The Calorific Value is used by the supplier, to produce a constant quality of gas as well as the customer, to
ensure the gas is of the correct composition prior to use.

The rapid and accurate analysis of the Natural Gas is therefore of critical importance; firstly at the development stage
for assessing the quality of new finds and secondly at the production stage for QA purposes.
The principle parameters affecting its economic value being Calorific Value, Compressibility, Specific Gravity, Density
and Wobbe Index.

The Solution
Ellutia offers a range of Natural Gas Analysers. The example below is based around a specially modified 200 Series
Gas Chromatograph.

Valves: Three Electrically Operated Switching Valves


Columns: Three Stainless Steel Columns and One Capillary Column
GC: Ellutia 200 Series GC
Detectors: Thermal Conductivity Detector (TCD)
Flame Ionisation Detector (FID)

This system quantifies CO2, O2, N2 and Methane on the TCD and from C2-C10 on the FID, with C6 and above being
grouped for calculation if required.

Clarity data station software automatically reports Component Concentration, Calorific Value, Compressibility, Specific
Gravity, Density and Wobbe Index in compliance with:

ISO 6976-95 Calculation of Calorific Values, Density, Relative Density and Wobbe Index from Composition.

ASTM D3588-98 Standard Practice for Calculating Heat Value, Compressibility Factor, and Relative Density of Gaseous
Fuels, Ideal & Real Heating Values in BTU’s

GPA 2172-09 Calculation of Gross Heating Value, Relative Density and Compressibility Factor for Natural Gas Mixtures
from Compositional Analysis.
System Sample in Helium In Splitter Vent H2 in
Carrier
EPPC
Split/Splitless Air in
Control
Injector

1
CV1 & 6 2 NV4
MEA 1 He in
5 3 Injector oven
4 TCD reference
FID
Analysis A
SL1

Sample Out SL2


Stripper B Detector
1 Oven
2
10
Stripper 3
9
Vent NV2 CV2 &
4
8 MEA2
5
7 6

TCD
NV1 Analysis B

He
Carrier in
Bypass B

1
6 2
CV3 & Column Oven
NV3
MEA3 5 3
4

Results Calibration Standard


Component Amount Fraction / (%mol/mol)
Comparison of the Superior Calorific Value Oxygen 0.0524 ±0.0027
calculated on an Ellutia Natural Gas Analyser
Nitrogen 1.519 ±0.013
and of the manufacturers specification.
Carbon Dioxide 0.705 ±0.006
Methane 93.782 ±0.1
Calculated Values Ethane 3.242 ±0.019
Mean Molecular Weight 17.11 Propane 0.498 ±0.04
Relative Density 0.59 Iso-Butane 0.1015 ±0.0013
Density 0.73 kg/m 3
n-Butane 0.1010 ±0.0013

Superior Calorific Value 38.3 MJ/m3 CV (Superior @ 15˚C/15˚C) 38.3 ±0.04


Inferior Calorific Value 34.53 MJ/m 3
Calculated by ISO6976:1995(E) including amendment No.1 - May 1998.
The expanded uncertainty is based on a standard uncertainty multiplied by a
Wobbe Index 49.79 MJ/m3
coverage factor K=2, providing a level of confidence of approximately 95%.

UK Tel: 01353 669916 Fax: 01353 669917


USA Tel: 843 559 4889 Fax: 843 559 4889
Germany Tel: 0561 400 0430 Fax: 0561 400 0429
Email: info@ellutia.com Website: http://www.ellutia.com

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