WO2016001129A1 - Improved insecticidal compositions - Google Patents

Abstract

The invention relates to compositions containing the compounds of formula (l) and at least one activity enhancer selected from penetration enhancers and ammonium or phosphonium salts of formula (II) in which D, n, R⁸, R⁹, R¹⁰, R¹¹ and R¹² are as defined in the description.

Description

 Improved insecticidal compositions

The present invention relates to insecticidal compositions comprising the compound of formula (I)

and at least one effect enhancer, preferably selected from ammonium salts, phosphonium salts and penetration promoters.

It is known from EP 0 268 915 A2, JP1993078323 A and WO 2012/029672 A1 that the compound of the formula (I) has a biological activity and that it can be used for controlling insects. The effectiveness of this compound is good, but not always completely satisfactory, especially at low application rates and concentrations.

However, since the ecological and economic demands on modern plant treatment products are constantly increasing, for example as regards selectivity and application rate, and in addition, e.g. Problems with resistance can occur, there is the constant task of developing new plant treatment products that have advantages over the known at least in some areas.

The object of the present invention is therefore to provide an insecticidal composition which contains the compound of the formula (I) and which has an improved action or a broader spectrum of activity than the known compositions.

WO 95/017817 describes that the effect of certain agrochemical active ingredients can be increased by the addition of surfactants (detergents) which contain various nitrogen-containing compounds, such as quaternary ammonium salts, betaines and amines. WO 95/017817 is concerned with providing optimized performance enhancers and describes that compositions comprising at least one nitrogen-containing salt and a chelating agent are particularly advantageous. The nitrogen-containing salt is preferably a nitrogen-containing detergent.

The use of salts containing nitrogen or phosphorous with longer alkyl and / or aryl substituents are also disclosed in EP-A-0 453 086, EP-A-0 664 081, FR-A-2 600 494, US 4,844,734B, US 5,462,912B , US 5,538,937B, US 20003 / 0224939A, US 2005 / 0009880A and / or US 2005 / 0096386A described. These salts have a permeabilizing effect or increase the solubility of the active ingredient; or they act as detergents.

US Pat. No. 2,848,476 B proposes to use salts of sulfonic acids for enhancing the activity (increasing the activity). The effect enhancement can be attributed to the fact that the acids used themselves have a paralyzing effect on insects.

The use of inorganic ammonium salts as formulation auxiliaries and enhancers in combination with certain herbicides is also known. WO 92/16108 describes the use of ammonium sulfate as a formulation adjuvant in a granular formulation containing insecticidally active phosphoramidothioates. WO 92/16108 describes that a certain amount of ammonium sulfate is necessary to ensure the chemical stability of granules containing phosphoramidothioates. US 6,645,914 B and EP-A-0 036 106 describe the increase in activity for the herbicides glyphosate and phosphinothricin by adding ammonium sulfate.

However, it is also known that a general occurrence of an effect enhancement can not be predicted by addition of known activity enhancers to agrochemical active substances or active ingredient classes.

It has now been found that the effect of the compound of the formula (I) can be increased by the addition of at least one activity enhancer selected from among ammonium and / or phosphonium salts and penetration promoters.

The subject matter of the present invention is thus a composition containing the compound of the formula (I)

and at least one activity improver selected from penetration promoters (in particular alkanol alkoxylates of the formula (III) as defined below and / or mineral or vegetable oils and their modifications) and ammonium or phosphonium salts of the formula (II)

11 I + nn-

RDR ⁹ 12

 R

_R 10

 n

(Π) in which

D is nitrogen or phosphorus; preferably D is nitrogen; n is 1, 2, 3 or 4; preferably n stands for 1 or 2;

R ⁸ , R ⁹ , R ¹⁰ and R ¹¹ independently of one another represent hydrogen or in each case optionally substituted C 1 -C 8 -alkyl or mono- or polyunsaturated, optionally substituted C 2 -C 8 -alkenyl, where the substituents are selected from halogen, nitro and cyano can; preferably, R ^8, R ^9, R ¹⁰ and R ¹¹ are independently hydrogen or optionally substituted C i-alkyl, wherein the substituents are selected from halogen, nitro and cyano; particularly preferably R ^8, R ^9, R ¹⁰ and R ^{11 are} independently hydrogen, methyl, ethyl, n-propyl, z o-propyl, n-butyl, z ^'o-butyl, eoButyl or tert-butyl; most preferably R ⁸ , R ⁹ , R ¹⁰ and R ¹¹ are each independently hydrogen, methyl or ethyl;

R ^{12 is} an inorganic or organic anion; R ¹² is preferably hydrogencarbonate, tetraborate, fluoride, bromide, iodide, chloride, monohydrogenphosphate, dihydrogenphosphate, hydrogensulphate, tartrate, sulphate, nitrate, thiosulphate, thiocyanate, formate, lactate, acetate, propionate, butyrate, pentanoate, citrate or oxalate; R ¹² furthermore preferably represents carbonate, pentaborate, sulfite, benzoate, hydrogen oxalate, hydrogen citrate, methyl sulfate or tetrafluoroborate; R ¹² particularly preferably represents lactate, sulfate, nitrate, thiosulphate, thiocyanate, citrate, oxalate, formate, monohydrogenphosphate or dihydrogenphosphate; R ¹² particularly preferably represents monohydrogenphosphate, dihydrogenphosphate or sulphate.

Examples of the abovementioned ammonium salts of the formula (II) are ammonium sulfate, ammonium lactate, ammonium nitrate, ammonium thiosulphate, ammonium thiocyanate, ammonium citrate, ammonium oxalate, ammonium formate, ammonium hydrogenphosphate,

Ammonium dihydrogen phosphate, ammonium carbonate, ammonium benzoate, ammonium sulfite, ammonium benzoate, ammonium hydrogen oxalate, ammonium hydrogen citrate, ammonium acetate, tetramethylammonium sulfate, tetramethylammonium lactate, tetramethylammonium nitrate,

Tetramethylammonium thiosulphate, tetramethylammonium thiocyanate, tetramethylammonium citrate, tetramethylammonium oxalate, tetramethylammonium formate, tetramethylammonium hydrogenphosphate, tetramethylammonium dihydrogenphosphate, tetraethylammonium sulfate, tetraethylammonium lactate, tetraethylammonium nitrate,

Tetraethylammonium thiosulfate, tetraethylammonium thiocyanate, tetraethylammonium citrate, tetraethylammonium oxalate, tetraethylammonium formate, tetraethylammonium hydrogenphosphate and tetraethylammonium dihydrogenphosphate. The present invention also provides for the use of the effect enhancers according to the invention, ie the ammonium and / or phosphonium salts according to the invention optionally in combination with the penetration promoters according to the invention, for enhancing the effect (increasing the activity) of the compound of the formula (I).

The enhancers may be added to the use solution containing the compound of formula (I) (tank mix / tank mix application) or incorporated into a formulation comprising the compound of formula (I) (formulated product).

The invention thus also relates to formulated insecticidal compositions and ready-to-use crop protection agents (for example spray liquors). Finally, the invention also relates to the use of the compositions according to the invention and agents for combating insect pests (plant pests) which occur in agriculture.

The compound of the formula (I) can be used in the compositions of the invention in a wide concentration range. The concentration of the compound of the formula (I) in the composition is usually 0.1-50% by weight.

The ammonium or phosphonium salts of the formula (II) according to the invention can be used in the compositions according to the invention in a wide concentration range.

The ammonium or phosphonium salts according to the invention are added in the composition in such a concentration that in the ready-to-use plant protection product (in the spray mixture or tank mix / tank mix application) in a concentration of 0.5 to 80 mmol / l, preferably 0.75 to 37.5 mmol / l, particularly preferably 1.5 to 25 mmol / l.

In the case of a formulated product, the ammonium and / or phosphonium salt concentration in the formulation is chosen such that it is in the aforementioned ranges after dilution of the formulation to the desired drug concentration. The concentration of the salt in the formulation is usually 1-50% by weight.

In a preferred embodiment, the composition according to the invention contains as an effect enhancer an inventive ammonium and / or phosphonium salt and a penetration promoter according to the invention (in particular alkanol alkoxylates of the formula (III) as defined herein and / or mineral or vegetable oils and their modifications).

It has been found that the combination of ammonium and phosphonium salts according to the invention and a penetration promoter according to the invention, the effect of the compound of formula (I) is so greatly increased that it is still effective even at such low concentrations, in which no addition of the combination Effect is more noticeable. Penetration promoters according to the invention are substances which are usually used to improve the penetration of agrochemical active substances into plants by penetrating from the corresponding application form (in particular aqueous spray mixture) and / or from the spray coating into the cuticle of the plant and thereby increasing the mobility of the material (mobility ) of active ingredients in the cuticle. The method described in the literature can be used to determine this property (Baur et al., 1997, Pesticide Science 51, 131-152).

Suitable penetration enhancers are also substances which promote the solubility of the compound of the formula (I) in the spray coating. These include, for example, mineral or vegetable oils (vegetable oils, vegetable oil). Suitable oils are all commonly used in agrochemical means mineral or vegetable - optionally modified - oils in question. Examples include sunflower oil, rapeseed oil, olive oil, castor oil, rapeseed oil, corn oil, cottonseed oil and soybean oil and their esters (preferably methyl or ethyl esters). Preferred oils are rapeseed oil, sunflower oil and their methyl or ethyl esters (e.g., rapeseed oil methyl ester).

Suitable penetration enhancers are also alkanol alkoxylates of the formula (III)

R-O- (AO) _v -R '(III) in which

R is straight-chain or branched C 1 -C 20 -alkyl; R is preferably butyl, where -butyl, n-pentyl, z-pentyl, neopentyl, n-hexyl, iso-hexyl, n-octyl, z o-octyl, 2-ethyl-hexyl, nonyl, where-nonyl, Decyl, n-dodecyl, z o -dodecyl, lauryl, myristyl, z o -tridecyl, trimethyl-nonyl, palmityl, stearyl or eicosyl;

R 'is hydrogen, methyl, ethyl, n -propyl, z o -propyl, n -butyl, z o -butyl, tert -butyl, n -pentyl or n -hexyl;

AO is an ethylene oxide radical, a propylene oxide radical, a butylene oxide radical or mixtures of ethylene oxide and propylene oxide radicals or butylene oxide radicals; and v is a number from 2 to 30.

Suitable penetration promoters are, in particular, alkanol alkoxylates of the formula (IIIa), (IIIb) or (IIIc) R-O - (- EO-) _n -R'R-0 - (- EO-) _p - (- PO-) _q -R'R-0 - (- PO-) _r - (- EO-) _s -R '

(Ill-a) (Ill-b) (III-c) in which R and R 'are as defined above, EO is a group -CH 2 -CH 2 -O-; n is a number from 2 to 20; CH-CH-O-

 OH

PO stands for ³ ; p, q, r, and s each independently represent a number from 1 to 10. Further suitable penetration promoters are in particular alkanol alkoxylates of the formula (III-d)

R-0 - (- EO-) _p - (- BO-) _Q -R '(Ill-d) in which

R and R 'have the meanings given above; EO is CH ₂ -CH ₂ -O-;

- CH5-CH5-CH-O

 I

PH

BO stands for ³ ; p and q, each independently, represent a number from 1 to 10. Further suitable penetration promoters are in particular alkanol alkoxylates of the formula (III-e)

R-0 - (- BO-) _r - (- EO-) _S -R '(III-e) in which

R and R 'have the meanings given above; - CH5-CH5-CH-O

 P I H

BO stands for ³ ;

EO is CH ₂ -CH ₂ -O-; each of r and s independently represents a number from 1 to 10. Further suitable penetration promoters are in particular alkanol alkoxylates of the formula (III-f)

CH ₃ - (CH 2) _t -CH2-0 - (- CH 2 -CH ₂ -0-) _u -R '(III-f) in which

R 'has the meaning given above; t is a number from 8 to 13; preferably t is a number from 9 to 12; and u is a number from 6 to 17; preferably u is a number from 7 to 9. Preference is given to an alkanol alkoxylate of the formula (III-f-1)

CH ₃ - (CH 2) _t -CH2-0 - (- CH 2 -CH ₂ -0-) _u -H (III-f-1) in which t stands for an average value of 10.5; and u stands for an average of 8.4.

An example of an alkanol alkoxylate of the formula (III-c) is a 2-ethylhexyl alkoxylate of the formula (III-c-1)

CH ₃ - CH ₂ CHj CH ₂ - CH CHj O (PO) - (EO) ₆ -H

 (III-c-1)

C ₂ H ₅

 CH-CH-0

 CH

in which EO is -CH ₂ -CH ₂ -O-; PO stands for ³ ; and the numbers 8 and 6 represent averages.

An example of an alkanol alkoxylate of the formula (III-d) is a compound of the formula (III-d-1)

CH ₃ - (CH 2) io-O - (- EO-) ₆ - (- BO-) 2-CH ₃ (III-d-1) - CH CH-CH-O- in which EO is CH ₂ -CH ₂ -0- stands; BO stands for ³ ; and the numbers 10, 6 and 2 represent averages.

The alkanol alkoxylates are generally defined by the above formulas. These substances are mixtures of substances of the specified type with different chain lengths. For the indices, therefore, average values are calculated, which can also differ from whole numbers.

The alkanol alkoxylates of the formulas given are known and are partly available commercially or can be prepared by known methods (compare WO 98/035553, WO00 / 35278 and EP-A 0 681 865).

The concentration of penetration promoter can be varied within a wide range in the compositions according to the invention.

In the case of a formulated crop protection agent, it is generally from 1 to 95% by weight, preferably from 1 to 55% by weight, more preferably from 15 to 40% by weight. In the ready-to-use agents (e.g., spray liquors), the concentration is generally between 0.1 and 10 g / l, preferably between 0.5 and 5 g / l.

Combinations of active ingredient, salt and penetration promoter highlighted in accordance with the invention are listed in the following table: "Penetration promoter according to the test" means that any compound which is suitable for use in the test for penetration of the cuticle according to Baur et al., 1997, Pesticide Science 51, 131 152 acts as a penetration promoter.

 # Active ingredient salt penetration enhancer

 1 (I) ammonium sulfate according to test

 2 (I) Ammonium lactate according to test

 3 (I) Ammonium nitrate according to test

 4 (I) Ammonium thiosulfate according to test

 5 (I) Ammonium thiocyanate according to test

 6 (I) ammonium citrate according to test

 7 (I) ammonium oxalate according to test

 8 (I) ammonium formate according to test

 9 (I) Ammonium hydrogen phosphate according to test

 10 (I) Ammonium dihydrogen phosphate according to test

 11 (I) ammonium carbonate according to test

 12 (I) ammonium benzoate according to test

 13 (I) Ammonium sulfite according to test

 14 (I) Ammonium benzoate according to test

 15 (I) Ammonium hydrogenoxalate according to test

 16 (I) Ammonium hydrogen citrate according to test

 17 (I) Ammonium acetate according to test

 18 (I) tetramethylammonium sulfate according to test

 19 (I) tetramethylammonium lactate according to test

 20 (I) tetramethylammonium nitrate according to test

 21 (I) Tetramethylammonium thiosulfate according to test

 22 (I) tetramethylammonium thiocyanate according to test

23 (I) tetramethylammonium citrate according to test # Active ingredient salt penetration enhancer

24 (I) tetramethylammonium oxalate according to test

 25 (I) tetramethylammonium formate according to test

 26 (I) tetramethylammonium hydrogen phosphate according to test

 27 (I) tetramethylammonium dihydrogen phosphate according to test

 28 (I) Tetraethylammonium sulfate according to test

 29 (I) Tetraethylammonium lactate according to test

 30 (I) Tetraethylammonium nitrate according to test

 31 (I) Tetraethylammonium thiosulfate according to test

 32 (I) Tetraethylammonium thiocyanate according to test

 33 (I) Tetraethylammonium citrate according to test

 34 (I) tetraethylammonium oxalate according to test

 35 (I) Tetraethylammonium formate according to test

 36 (I) Tetraethylammonium hydrogen phosphate according to test

 37 (I) Tetraethylammonium dihydrogen phosphate according to test

The compositions according to the invention may also contain further components, for example surfactants (nonionic or anionic) or dispersing aids or emulsifiers.

Suitable nonionic surfactants or dispersing agents are all substances of this type which can usually be used in agrochemical compositions. Preference is given to polyethylene oxide-polypropylene oxide block copolymers, polyethylene glycol ethers of linear alcohols, reaction products of fatty acids with ethylene oxide and / or propylene oxide, furthermore polyvinyl alcohol, polyvinylpyrrolidone, copolymers of polyvinyl alcohol and polyvinylpyrrolidone and copolymers of (meth) acrylic acid and (meth) acrylic acid esters, furthermore Alkylethoxylates and alkylarylethoxylates, which may optionally be phosphated and optionally neutralized with bases, wherein sorbitol ethoxylates may be mentioned by way of example, as well as polyoxyalkyleneamine derivatives.

Suitable anionic surfactants are all substances of this type conventionally usable in agrochemical compositions. Preference is given to alkali metal and alkaline earth metal salts of alkylsulfonic acids or alkylarylsulfonic acids.

Another preferred group of anionic surfactants or dispersing agents are salts of polystyrenesulfonic acids which are sparingly soluble in vegetable oil, salts of polyvinylsulfonic acids, salts of naphthalenesulfonic acid-formaldehyde condensation products, salts of condensation products of naphthalenesulfonic acid, phenolsulfonic acid and formaldehyde and salts of lignosulfonic acid.

Suitable additives which may be present in the formulations according to the invention are emulsifiers, foam-inhibiting agents, preservatives, antioxidants, dyes and inert fillers. Preferred emulsifiers are ethoxylated nonylphenols, reaction products of alkylphenols with ethylene oxide and / or propylene oxide, ethoxylated arylalkylphenols, furthermore ethoxylated and propoxylated arylalkylphenols, and sulfated or phosphated arylalkyl ethoxylates or ethoxypropoxylates, sorbitan derivatives such as polyethylene oxide sorbitan fatty acid esters and sorbitan - fatty acid esters, are exemplified.

The composition according to the invention may contain, in addition to the compound of formula (I), other active substances, including synergists, and fertilizers. Synergists are compounds that increase the effect of the active ingredients without the added synergist itself having to be active. Suitable active ingredients include insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth regulators, herbicides, safeners and messengers (= semiochemicals, for example pheromones, allomones, or kairomones).

Suitable active ingredients are, for example, the following insecticides, acaricides or nematicides:

(Inl) acetylcholinesterase (AChE) inhibitors such as carbamates, e.g. Alanycarb, Aldicarb, Bendiocarb, Benfuracarb, Butocarboxime, Butoxycarboxime, Carbaryl, Carbofuran, Carbosulfan, Ethiofencarb, Fenobucarb, Formetanate, Furathiocarb, Isoprocarb, Methiocarb, Methomyl, Metolcarb, Oxamyl, Pirimicarb, Propoxur, Thiodicarb, Thiofanox, Triazamate, Trimethacarb, XMC and xylylcarb; or organophosphates, e.g. Acephates, azamethiphos, azinphos (-methyl, -ethyl), cadusafos, chloroethoxyfos, chlorfenvinphos, chlormephos, chlorpyrifos (-methyl), coumaphos, cyanophos, demeton-S-methyl, diazinon, dichlorvos / DDVP, dicrotophos, dimethoates, dimethyvinphos , Disulfoton, EPN, Ethion, Ethoprophos, Famphur, Fenamiphos, Fenitrothion, Fenthion, Fosthiazate, Heptenophos, Isofenphos, Isopropyl O- (methoxyaminothio-phosphoryl) salicylate, Isoxathione, Malathion, Mecarbam, Methamidophos, Methidathione, Mevinphos, Monocrotophos, Naled, Omethoate , Oxydemeton-methyl, Parathion (-methyl), Phenthoate, Phorate, Phosalone, Phosmet, Phosphamidon, Phoxim, Pirimiphos (-methyl), Profenofos, Propetamphos, Prothiofos, Pyraclofos, Pyridaphenthion, Quinalphos, Sulfotep, Tebupirimfos, Temephos, Terbufos, Tetrachlorvinphos , Thiometone, triazophos, triclorfone and vamidothion.

(In2) GABA-controlled chloride channel antagonists, such as organochlorines, e.g. Chlordane and endosulfan (alpha); or fiproles (phenylpyrazoles), e.g. Ethiprole, Fipronil, Pyrafluprole and Pyriprole.

(In3) Sodium Channel Modulators / Voltage-Dependent Sodium Channel Blockers, Such as Pyrethroids, eg Acrinathrin, Allethrin (d-cis-trans, d-trans), Bifenthrin, Bioallethrin, Bioallethrin-S-cyclopentenyl, Bioresmethrin, Cycloprothrin, Cyfluthrin (beta), cyhalothrin (gamma, lambda), cypermethrin (alpha, beta, theta, zeta), cyphenothrin [(lR) trans isomers], deltamethrin, dimefluthrin, empenthrin [(EZ) - (lR) -isomers], esfenvalerates, etofenprox, fenpropathrin, fenvalerates, flucythrinates, Flumethrin, fluvalinate (tau-), halfenprox, imiprothrin, metofluthrin, permethrin, phenothrin [(1R) - trans isomer], prallethrin, profuthrin, pyrethrin (pyrethrum), resmethrin, RU 15525, silafluofen, tefluthrin, tetramethrin [(1R) Isomers], tralomethrin, transfluthrin and ZXI 8901; or DDT; or methoxychlor.

(In4) nicotinergic acetylcholine receptor agonists such as neonicotinoids, e.g. Acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, sulfoxaflor, thiacloprid, thiamethoxam; or nicotine.

(In5) allosteric acetylcholine receptor modulators (agonists), such as spinosyns, e.g. Spinetoram and spinosad.

(In6) chloride channel activators, such as avermectins / milbemycins, e.g. Abamectin, Emamectin benzoate, Lepimectin and Milbemectin.

(In7) juvenile hormone analogs, e.g. Hydroprene, kinoprene, methoprene; or fenoxycarb; Pyritexyfen.

(In8) agents with unknown or nonspecific modes of action, such as fumigants, e.g. Methyl bromide and other alkyl halides; or chloropicrin; sulfuryl fluoride; Borax; Tartar emetic.

(In 9) Selective feeding inhibitors, e.g. pymetrozine; or flonicamide.

(In10) mite growth inhibitors, e.g. Clofentezine, diflovidazine, hexythiazox, etoxazole.

(Inl l) Insect intestinal membrane microbial disruptors such as Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies tenebrionis, and BT plant proteins, e.g. CrylAb, CrylAc, CrylFa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34 / 35Abl.

(Inl2) inhibitors of oxidative phosphorylation, ATP disruptors, such as diafenthiuron; or organotin compounds, e.g. Azocyclotine, cyhexatin, fenbutatin oxide; or propargite; Tetradifon.

(In13) Decoupling of oxidative phosphorylation by interruption of the H proton gradient, such as chlorfenapyr and DNOC.

(Inl4) Nicotinergic acetylcholine receptor antagonists, such as Bensultap, Cartap (hydrochloride), thiocylam, and thiosultap (-sodium). (115) Type 0 inhibitors of chitin biosynthesis, such as benzoylureas, eg, bistrifluron, chlorofluorazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron and triflumuron.

(Inl 6) inhibitors of chitin biosynthesis, type 1, such as Bupro fezin. (Inl7) Moulting agents, such as Cyromazine.

(Inl 8) ecdysone agonists / disruptors, such as diacylhydrazines, e.g. Chromafenozide, Halofenozide, Methoxyfenozide and Tebufenozide.

(Inl 9) Octopaminergic agonists, such as amitraz.

(In20) complex III electron transport inhibitors such as hydramethylnone; acequinocyl; Fluacrypyrim.

(In21) complex I electron transport inhibitors, for example from the group of the METI acaricides, e.g. Fenazaquin, Fenpyroximate, Pyrimidifen, Pyridaben, Tebufenpyrad, Tolfenpyrad; or Rotenone (Derris).

(In22) voltage dependent sodium channel blockers, e.g. indoxacarb; Metaflumizone.

(In23) inhibitors of acetyl-CoA carboxylase, such as tetronic acid derivatives, e.g. Spirodiclofen and spiromesifen; or tetramic acid derivatives, e.g. Spirotetramat.

(In24) complex IV electron transport inhibitors such as phosphines, e.g. Aluminum phosphide, calcium phosphide, phosphine, zinc phosphide; or cyanide.

(In 25) Complex II electron transport inhibitors, such as cyenopyrafen.

(In28) ryanodine receptor effectors such as diamides, e.g. Flubendiamide, chlorantraniliprole (Rynaxypyr), cyantraniliprole (Cyazypyr) and 3-bromo-N- {2-bromo-4-chloro-6 - [(1-cyclopropylethyl) carbamoyl] phenyl} -1- (3-chloropyridin-2-yl ) - 1 H -pyrazole-5-carboxamide (known from WO2005 / 077934) or methyl 2- [3,5-dibromo-2 - ({[3-bromo-1- (3-chloropyridin-2-yl) -] 1H-pyrazol-5-yl] carbonyl} amino) benzoyl] -1,2-dimethylhydrazinecarboxylate (known from WO2007 / 043677).

(In29) Other drugs with unknown mechanism of action, such as azadirachtin, amidoflumet, benzoximate, bifenazate, quinomethionate, cryolites, cyflumetofen, dicofol, fluensulfone (5-chloro-2 - [(3,4,4-trifluorobut-3-ene-1 -yl) sulfonyl] -l, 3-thiazoles), flufenerim, pyralidyl and pyrifluquinazone; furthermore preparations based on Bacillus firmus (1-1582, BioNeem, Votivo) and the following known active compounds 4- {[(6-bromopyrid-3-yl) methyl] (2-fluoroethyl) amino} furan 2 (5H) -one (known from WO 2007/115644), 4- {[(6-fluoropyrid-3-yl) methyl] (2,2-difluoroethyl) amino} furan-2 (5H) -one (known from WO 2007/115644), 4- {[(2-chloro-1,3-thiazol-5-yl) methyl] (2-fluoroethyl) amino} furan-2 (5H) -one (known from WO 2007/115644) , 4- {[(6-Chloropyrid-3-yl) methyl] (2-fluoroethyl) amino} furan-2 (5H) -one (known from WO 2007/115644), 4- {[(6-chloropyrid-3 - yl) methyl] (2,2-difluoroethyl) amino} furan-2 (5H) -one (known from WO 2007/115644), 4- {[(6-chloro-5-fluoropyrid-3-yl) methyl] (methyl) amino} furan-2 (5H) -one (known from WO 2007/115643), 4- {[(5,6-dichloro-3-yl) methyl] (2-fluoroethyl) amino} furan 2 (5H) -one (known from WO 2007/115646), 4- {[(6-chloro-5-fluoro-3-ylid-3-yl) methyl] (cyclopropyl) amino} furan-2 (5H) -one ( known from WO 2007/115643), 4- {[(6-chloropyrid-3-yl) methyl] (cyclopropyl) amino} furan-2 (5H) -one (known from EP-A-0 539 588), 4- {[(6-chloropyrid-3-yl) methyl] (methyl) amino} furan-2 (5H) -one (known from EP-A-0 539 588), {[1- (6-chloropyridin-3-yl ) ethyl] (methyl) oxido-λ ⁴ -sulfanylidene} cyano mid (known from WO2007 / 149134) and its diastereomers {[(1R) -1- (6-chloropyridin-3-yl) ethyl] (methyl) oxido ^ ⁴ -sulfanylidene} cyanamide (A) and {[(l S ) -l- (6-chloropyridin-3-yl) ethyl] (methyl) oxido-λ ⁴ -sulfanyliden} cyanamide (B) (also known from WO2007 / 149134) and sulfoxaflor (also known from WO2007 / 149134) and its diastereomers [(R) -methyl (oxido) {(IR) -l- [6- (trifluoromethyl) pyridin-3-yl] ethyl} -λ ⁴ -sulfanylidene] cyanoamide (AI) and [(S) -methyl ( oxido) {(1S) -1- [6- (trifluoromethyl) pyridin-3-yl] ethyl} -λ ⁴ -sulfanylidenecyanamide (A2), referred to as diastereomeric gamma A (known from WO 2010/074747, WO 2010 / No. 074751), [(R) -methyl (oxido) {(1S) -1- [6- (trifluoromethyl) pyridin-3-yl] ethyl} -λ ⁴ -sulfanylidene] cyanamide (B1) and [(S ) -Methyl (oxido) {(IR) -l- [6- (trifluoromethyl) pyridin-3-yl] ethyl} -λ ⁴ -sulfanylidenjcyanamid (B2), referred to as Diastereomerengrappe B (also known from WO 2010/074747 , WO 2010/074751) and 1 l - (4-chloro-2,6-dimethylphenyl) -12-hydroxy-l, 4-diox a-9-azadirolo [4.2.4.2] tetradec-1-en-10-one (known from WO 2006/089633), 3- (4'-fluoro-2,4-dimethylbiphenyl-3-yl) - 4-hydroxy-8-oxa-1-azaspiro [4.5] dec-3-en-2-one (known from WO 2008/067911), 1- [2-fluoro-4-methyl-5 - [(2,2 , 2-trifluoroethyl) sulfinyl] phenyl] -3- (trifluoromethyl) -1H-l, 2,4-triazole-5-amine (known from WO 2006/043635), [(3S, 4aR, 12R, 12aS, 12bS) 3 - [(Cyclopropylcarbonyl) oxy] -6,12-dihydroxy-4,12b-dimethyl-1-oxo-9- (pyridin-3-yl) -l, 3,4,4a, 5,6,6a , 12,12a, 12b-decahydro-2H, 1H-benzo [f-pyrano [4,3-b] chromen-4-yl] -methylcyclopropanecarboxylate (known from WO 2006/129714), 2-cyano-3- (difluoromethoxy) - N, N-dimethylbenzenesulfonamide (known from WO2006 / 056433), 2-cyano-3- (difluoromethoxy) -N-methylbenzenesulfonamide (known from WO2006 / 100288), 2-cyano-3- (difluoromethoxy) -N-ethylbenzenesulfonamide (known from US Pat WO2005 / 035486), 4- (difluoromethoxy) -N-ethyl-N-methyl-1,2-benzothiazol-3-amine-1, 1-dioxide (known from WO2007 / 057407) and N- [1- (2, 3-dimethylphenyl) -2- (3,5-dimethylphenyl) ethyl] -4,5-dihydro-1,3-d -thiazol-2-amine (known from WO2008 / 104503).

Suitable active ingredients are, for example, the following fungicides:

(Fl) inhibitors of ergosterol biosynthesis, such as aldimorph, azaconazole, bitertanol, bromuconazole, cyproconazole, diclobutrazole, difenoconazole, diniconazole, diniconazole-M, dodemorph, Dodemorph Acetate, Epoxiconazole, Etaconazole, Fenarimol, Fenbuconazole, Fenhexamid, Fenpropidin, Fenpropimorph, Fluquinconazole, Flurprimidol, Flusilazole, Flutriafol, Furconazole, Furconazole Cis, Hexaconazole, Imazalil, Imazalil Sulfate, Imibenconazole, Ipconazole, Metconazole, Myclobutanil, Naftifine, Nuarimol, Oxpoconazole, Paclobutrazole, Pefurazoate, Penconazole, Piperaline, Prochlorazole, Propiconazole, Prothioconazole, Pyributicarb, Pyrifenox, Quinconazole, Simeconazole, Spiroxamine, Tebuconazole, Terbinafine, Tetraconazole, Triadimefon, Triadimenol, Tridemorph, Triflumizole, Triforine, Triticonazole, Uniconazole, Uniconazole-p, Viniconazole, voriconazole, 1- (4-chlorophenyl) -2- (1H-l, 2,4-triazol-1-yl) cycloheptanol, methyl 1 - (2,2-dimethyl-2,3-dihydro-1H 1-yl) -1H-imidazole-5-carboxylate, N '- {5- (difluoromethyl) -2-methyl-4- [3- (trimethylsilyl) propoxy] phenyl} -N-ethyl-N- methylimidoformamide, N-ethyl-N-methyl-N '- {2-methyl-5- (trifluoromethyl) -4- [3- (trimethylsilyl) propoxy] phenyl} imidoformamide, and O- [1- (4-meth oxyphenoxy) -3,3-dimethylbutan-2-yl] -1H-imidazole-1-carbothioate.

(F2) inhibitors of respiration (respiratory chain inhibitors), such as bixafen, boscalid, carboxin, diflumetorim, fenfuram, fluopyram, flutolanil, fluxapyroxad, furametpyr, furmecyclox, isopyrazam mixture of the syn-epimeric racemate 1RS, 4SR, 9RS and the anti- more highly enriched racemates 1RS, 4SR, 9SR, isopyrazam (anti-epimeric racemate), isopyrazam (anti-epimeric enantiomer 1R, 4S, 9S), isopyrazam (anti-epimeric enantiomer 1S, 4R, 9R), isopyrazam (syn-epimeric racemate 1RS , 4SR, 9RS), isopyrazam (syn-epimeric enantiomer 1R, 4S, 9R), isopyrazam (syn-epimeric enantiomer 1S, 4R, 9S), mepronil, oxycarboxine, penflufen, penthiopyrad, sedaxanes, thifluzamide, 1-methyl-N [2- (1,2,2-tetrafluoroethoxy) phenyl] -3- (trifluoromethyl) -1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -1-methyl-N- [2- (1, l, 2,2-tetrafluoroethoxy) phenyl] -1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -N- [4-fluoro-2- (1,1,2,3,3,3-hexafluoropropoxy) phenyl] ] -1-methyl-1H-pyrazole-4-carboxamide and N- [1- (2,4-dichlorophenyl) -1-methoxy-2-propyl] -3 - (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide.

(F3) inhibitors of respiration (respiratory chain inhibitors) at the complex III of the respiratory chain, such as ametoctradine, amisulbrom, azoxystrobin, cyazofamide, dimoxystrobin, enestroburin, famoxadone, fenamidone, fluoxastrobin, kresoxim-methyl, metominostrobin, orysastrobin, picoxystrobin, pyraclostrobin, pyrametostrobin , Pyraoxystrobin, pyribencarb, trifloxystrobin, (2E) -2- (2- {[6- (3-chloro-2-methylphenoxy) -5-fluoropyrimidin-4-yl] oxy} phenyl) -2- (methoxyimino) -N -methyl-ethanamide, (2E) -2- (methoxyimino) -N-methyl-2- (2- {[({(L (e) -l- [3- (trifluoromethyl) -phenyl] ethylidene} amino) oxy] methyl} phenyl) ethanamide, (2E) -2- (methoxyimino) -N-methyl-2- {2 - [(E) - ({1 - [3

(trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} ethanamide, (2E) -2- {2- [({[(IE) -1- (3 - {[(E) -1-fluoro-2-phenylethenyl ] oxy} phenyl) ethylidene] amino} oxy) methyl] phenyl} -2- (methoxyimino) -N-methylethane amide, (2E) -2- {2 - [({[(2E, 3E) -4- ( 2,6-dichlorophenyl) but-3-en-2-ylidene] amino} oxy) methyl] phenyl} -2- (methoxyimino) -N-methylethaneamide, 2-chloro-N- (1,1,3-trimethyl- 2,3-dihydro-1H-inden-4-yl) pyridine-3-carboxamide, 5-methoxy-2-methyl-4- (2- {[({(1E) -l- [3- (trifluoromethyl) phenyl] ] ethylidene} amino) oxy] methyl} phenyl) -2,4-dihydro-3H-l, 2,4-triazol-3-one, methyl (2E) -2- {2 - [({cyclopropyl) pyl [(4-methoxyphenyl) imino] methyl} sulfanyl) methyl] phenyl} -3-methoxyprop-2-enoate, N- (3-ethyl) 3,5,5-trimethylcyclohexyl) -3- (formylamino) -2-hydroxybenzamide, 2- {2 - [(2,5-dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide and (2R) -2- {2 - [(2,5-dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide.

(F4) inhibitors of mitosis and cell division, such as benomyl, carbendazim, chlorfenazole, diethofencarb, ethaboxam, fluopicolide, fuberidazole, pencycuron, thiabendazole, thiophanate-methyl, thiophanate, zoxamide, 5-chloro-7- (4-methylpiperidine-1 - yl) -6- (2,4,6-trifluorophenyl) [l, 2,4] triazolo [l, 5-ajpyrimidine and 3-chloro-5- (6-chloropyridin-3-yl) -6-methyl-4 - (2,4,6-trifluorophenyl) pyridazine.

(F5) Compounds with multisite activity, such as Bordeaux mixture, captafol, captan, chlorothalonil, copper preparations such as copper hydroxide, copper naphthenate, copper oxide, copper oxychloride, copper sulfate, dichlofluanid, dithianon, dodine, dodine free base, Ferbam, Fluorofolpet, Folpet, guazatine, guazatin acetate , Iminoctadine, iminoctadinal besylate, iminoctadine triacetate, mancopper, mancozeb, maneb, metiram, zinc metiram, copper oxine, propamidine, propineb, sulfur and sulfur preparations such as calcium polysulfide, thiram, tolylfluanid, zineb and ziram.

(F6) resistance inducers, such as acibenzolar-S-methyl, isotianil, probenazole and tiadinil.

(F7) inhibitors of amino acid and protein biosynthesis, such as andoprim, blasticidin-S, cyprodinil, kasugamycin, kasugamycin hydrochloride hydrate, mepanipyrim and pyrimethanil.

(F8) inhibitors of ATP production, such as, for example, fentin acetate, fentin chloride, fentin hydroxide and silthiofam.

(F9) inhibitors of cell wall synthesis, such as benthiavalicarb, dimethomorph, flumorph, iprovalicarb, mandipropamide, polyoxins, polyoxorim, validamycin A, and valifenalate.

(F10) inhibitors of lipid and membrane synthesis, such as biphenyl, chloroneb, dicloran, edifenphos, etridiazole, iodocarb, Iprobenfos, isoprothiolane, propamocarb, propamocarb hydrochloride, prothiocarb, pyrazophos, quintozene, tecnazene, and tolclofos-methyl.

(Fl 1) inhibitors of melanin biosynthesis, such as carpropamide, diclocymet, fenoxanil, fthalide, pyroquilone and tricyclazole.

(Fl 2) Inhibitors of nucleic acid synthesis, such as benalaxyl, benalaxyl-M (kiralaxyl), bupirimate, clozylacon, dimethirimol, ethirimol, furalaxyl, hymexazole, metalaxyl, metalaxyl-M (mefenoxam), ofurace, oxadixyl, oxolinic acid.

(Fl 3) Signal transduction inhibitors, such as, for example, chlozolinate, fenpiclonil, fludioxonil, iprodione, procymidone, quinoxyfen and vinclozolin. (Fl4) decouplers such as binapacryl, dinocap, ferimzone, fluazinam and meptyldinocap.

(Fl 5) Further compounds, such as, for example, benthiazole, Bethoxazine, Capsimycin, Carvone, Chinomethionat, Chlazafenone, Cufraneb, Cyflufenamid, Cymoxanil, Cyprosulfamide, Dazomet, Debacarb, Dichlorophene, Diclomezine, Difenzoquat, Difenzoquat methylsulphate, Diphenylamine, Ecomat, Fenpyrazamine, Flumetover, Fluoromide, flusulfamide, flutianil, fosetyl-aluminum, fosetyl-calcium, fosetyl-sodium, hexachlorobenzene, irumamycin, methasulfocarb, methylisothiocyanate, metrafenone, mildiomycin, natamycin, nickel dimethyldithiocarbamate, nitrothal-isopropyl, octhilinone, oxamocarb, oxyfenthiine, pentachlorophenol and its salts, Phenothrin, phosphoric acid and its salts, propamocarb-fosetylate, propanosine sodium, proquinazide, pyrrolnitrin, tebufloquine, tecloftalam, tolnifanide, triazoxide, trichlamide, zarilamide, 1- (4- {4 - [(5R) -5- (2,6 -Difluorophenyl) -4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidine-1-yl) -2- [5-methyl-3 - (trifluoromethyl) 1-H-pyrazol-1-yl] ethanone, 1- (4- {4 - [(5 S) -5- (2,6-) Difluorophenyl) -4,5-dihydro-l, 2-oxazol-3-yl] -l, 3-thiazol-2-yl} piperidin-1-yl) -2- [5-methyl-3- (trifluoromethyl) - lH-pyrazol-1-yl] ethanone, 1- (4- {4- [5- (2,6-difluorophenyl) -4,5-dihydro-1,2-oxazol-3-yl] -l, 3 thiazol-2-yl} piperidin-1-yl) -2- [5-methyl-3- (trifluoromethyl) -1-H-pyrazol-1-yl] ethanone, 1- (4-methoxyphenoxy) -3,3-dimethylbutane -2-yl-1H-imidazole-1-carboxylate, 2,3,5,6-tetrachloro-4- (methylsulfonyl) pyridine, 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidine-4 (3H) -one, 2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -1- (4- {4 - [(5R) -5-phenyl-4,5-dihydro -l, 2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) ethanone, 2- [5-methyl-3 - (trifluoromethyl) -1H-pyrazole-1 - yl] -

1- (4- {4 - [(5 S) -5-phenyl-4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) ethanone, 2- [5-methyl-3- (trifluoromethyl) -1 H -pyrazol-1-yl] -1- {4- [4- (5-phenyl-4,5-dihydro-1,2-oxazole) 3-yl) -1,3-thiazole

2-yl] piperidin-1-yl} ethanone, 2-butoxy-6-iodo-3-propyl-4H-chromen-4-one, 2-chloro-5- [2-chloro-L- (2,6- difluoro-4-methoxyphenyl) -4-methyl-1H-imidazol-5-yl] pyridine, 2-phenylphenol and its salts, 3,4,5-trichloropyridine-2,6-dicarbonitrile, 3- [5- (4- Chlorophenyl) -2,3-dimethyl-1,2-oxazolidin-3-yl] pyridine, 3-chloro-5- (4-chlorophenyl) -4- (2,6-difluorophenyl) -6-methylpyridazine, 4- ( 4-chlorophenyl) -5- (2,6-difluorophenyl) -3,6-dimethylpyridazine, 5-amino-1, 3,4-thiadiazole-2-thiol, 5-chloro-N'-phenyl-N ' - (prop-2-yn-1-yl) thiophene-2-sulfonohydrazide, 5-methyl-6-octyl [l, 2,4] triazolo [l, 5-a] pyrimidin-7-amine, ethyl (2Z ) -3-amino-2-cyano-3-phenylprop-2-enoate, N- (4-chlorobenzyl) -3- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] propanamide, N - [(4-chlorophenyl) (cyano) methyl] -3- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] propanamide, N - [(5-bromo-3-chloropyridine) 2-yl) methyl] -2,4-dichloropyridine-3-carboxamide, N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl] -2,4-dichloropyridine-3-carboxamide, N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl] -2-fluoro-4-iodopyridine 3-carboxamide, N - {(E) - [(Cyclopropylmethoxy) imino] [6- (difluoromethoxy) -2,3-difluorophenyl] methyl} -2-phenylacetamide, N - {(Z) - [(Cyclopropylmethoxy) imino ] [6- (difluoromethoxy) -2,3-difluorophenyl] methyl} -2-phenylacetamide, N-methyl-2- (1 - {[5-methyl-3 - (trifluoromethyl) -1 H -pyrazol-1-yl ] acetyl} piperidin-4-yl) -N- (1,2,3,4-tetrahydronaphthalen-1-yl) -1,3-thiazole-4-carboxamide, N-methyl-2- (1 - {[5 -methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] acetyl} piperidin-4-yl) - N - [(1 R) -1,3,3,4-tetrahydronaphthalen-1-yl] -1 , 3-thiazole-4 carboxamide, N-methyl-2- (1 - {[5-methyl-3 - (trifluoromethyl) -1-H-pyrazol-1-yl] -acetyl} -piperidin-4-yl) -N- [(1S) -1, 2,3,4-tetrahydronaphthalene-1-yl] -1,3-thiazole-4-carboxamide, pentyl {6- [({[(1-methyl-1H-tetrazol-5-yl) (phenyl) -methylidene ] amino} oxy) methyl] pyridin-2-yl} carbamate, phenazine-1-carboxylic acid, quinolin-8-ol and quinoline-8-olsulfate (2: 1).

(F16) Further compounds, such as, for example, 1-methyl-3- (trifluoromethyl) -N- [2'- (trifluoromethyl) biphenyl-2-yl] -1H-pyrazole-4-carboxamide, N- (4'-chlorobiphenyl- 2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, N- (2 ', 4'-dichlorobiphenyl-2-yl) -3- (difluoromethyl) -1-methyl- 1 H-pyrazole-4-carboxamide, 3- (difluoromethyl) -1-methyl-N- [4 '- (trifluoromethyl) biphenyl-2-yl] -1H-pyrazole-4-carboxamide, N- (2', 5 '-Difluorobiphenyl-2-yl) -1-methyl-3- (trifluoromethyl) -1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -1-methyl-N- [4' - (prop-1-amine) 1 -yl) biphenyl-2-yl] -1-H-pyrazole-4-carboxamide, 5-fluoro-1,3-dimethyl-N- [4 '- (prop-1-yn-1-yl) biphenyl-2 -yl] - 1 H -pyrazole-4-carboxamide, 2-chloro-N- [4 '- (prop-1-yn-1-yl) biphenyl-2-yl] pyridine-3-carboxamide, 3- (difluoromethyl ) -N- [4 '- (3,3-dimethylbut-1-yn-1-yl) biphenyl-2-yl] -1-methyl-1H-pyrazole-4-carboxamide, N- [4' - (3 , 3-dimethylbut-1-yn-1-yl) biphenyl-2-yl] -5-fluoro-1, 3-dimethyl-1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -N- (4 ' -ethynyl-biphenyl-2-yl) - 1 -m ethyl 1H-pyrazole-4-carboxamide, N- (4'-ethynyl-biphenyl-2-yl) -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, 2-chloro-N- ( 4'-ethynyl-biphenyl-2-yl) pyridine-3-carboxamide, 2-chloro-N- [4 '- (3,3-dimethylbut-1-yn-1-yl) -biphenyl-2-yl] pyridine 3-carboxamide, 4- (difluoromethyl) -2-methyl-N- [4 '- (trifluoromethyl) biphenyl-2-yl] -1,3-thiazole-5-carboxamide, 5-fluoro-N- [4'- (3-hydroxy-3-methylbut-1-yn-1-yl) biphenyl-2-yl] -1,3-dimethyl-1H-pyrazole-4-carboxamide, 2-chloro-N- [4 '- (3 -hydroxy-3-methylbut-1-yn-1-yl) biphenyl-2-yl] pyridine-3-carboxamide, 3- (difluoromethyl) -N- [4 '- (3-methoxy-3-methylbut-1 - in 1 -yl) biphenyl-2-yl] -1-methyl-1H-pyrazole-4-carboxamide, 5-fluoro-N- [4 '- (3-methoxy-3-methylbut-1-in-1 -yl) biphenyl-2-yl] -l, 3-dimethyl-1H-pyrazole-4-carboxamide, 2-chloro-N- [4 '- (3-methoxy-3-methylbut-1-yn-1-yl ) biphenyl-2-yl] pyridine-3-carboxamide, (5-bromo-2-methoxy-4-methylpyridin-3-yl) (2,3,4-trimethoxy-6-methylphenyl) methanone and N- [2- (4- {[3- (4-chlorophenyl) prop-2-yn-1-yl] oxy} -3-methoxyphenyl) ethyl] -N2- (methylsulfonyl) valinamide.

If chemically useful, the aforementioned active ingredients can form salts with suitable bases or acids. The active substances mentioned here with their "common name" are known and described, for example, in the Pesticide Handbook ("The Pesticide Manual" 14th Ed., British Crop Protection Council 2006) or searchable on the Internet (eg http://www.alanwood.net/pesticides ).

According to the invention, all plants and parts of plants can be treated. In this context, plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants). Crop plants can be plants that can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including by Plant variety rights protectable or non-protectable plant varieties. Plant parts are to be understood as meaning all aboveground parts and organs of the plants, such as shoots, leaves and flowers, examples of which include leaves, needles, stems, stems, flowers, fruiting bodies and fruits. The plant parts also include crops and vegetative propagating material, such as cuttings.

The treatment according to the invention of the plants and plant parts with the composition according to the invention is carried out directly or by acting on their environment, habitat or storage space according to the usual treatment methods, e.g. by dipping, spraying, evaporating, misting, spreading and painting.

In particular, the composition according to the invention is suitable for the treatment of above-ground parts of plants. Preference is given to mention the combinations according to the invention mentioned above as being preferred or particularly preferred. Thus, a large part of the damage caused by pests damage to crops by the infestation of aboveground plant parts

The control of plant pests by the treatment of Oberiridisches plant parts has long been known and is the subject of constant improvement. Nevertheless, there are a number of problems in the treatment of Upper-Irish parts of plants that can not always be satisfactorily resolved. Thus, it is desirable to develop methods for protecting the above-ground parts of plants, which reduce the additional application of pesticides after the emergence of the plants. It is also desirable to optimize the amount of active ingredient used to the effect that the above-ground parts of plants are best protected against infestation by pests, but without damaging the plant itself by the active ingredient used. In particular, methods for treating upper-iridian plant parts should also include the intrinsic, insecticidal properties of transgenic plants in order to achieve optimum protection of the above-ground parts of plants with a minimum of pesticides.

The present invention therefore also relates in particular to a method of protecting plants from the infestation of plant pests by treating the above-ground parts of plants with the composition according to the invention.

The invention also relates to the use of the composition according to the invention for controlling plant pests by applying the composition to conventional or transgenic plants. Furthermore, the invention relates to aboveground plant parts which have been treated with the composition according to the invention for protection against plant pests. In particular, plant pests are insects, arachnids, helminths, nematodes and molluscs found in agriculture, horticulture, forests, gardens and recreational facilities. The compositions according to the invention are active against normally sensitive and resistant species as well as against all or individual stages of development. Plant pests include:

Pests from the strain: Arthropoda, especially from the class of arachnids, e.g. Acarus spp., Aceria kuko, Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Amphitetranychus viennensis, Argas spp., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Centruroides spp., Chorioptes spp., Dermanyssus gallinae , Dermatophagoides pteronyssius, Dermatophagoides farinae, Dermacentor spp., Eotetranychus spp., Epitrimerus pyri, Eutetranychus spp., Eriophyes spp., Halotydeus destructor, Hemitarsonemus spp., Hyalomma spp., Ixodes spp., Latrodectus spp., Loxosceles spp., Metatetranychus Spp., Nuphersa spp., Oligonychus spp., Ornithodorus spp., Ornithonyssus spp., Panonychus spp., Phyllocoptruta oleivora, Platytetranychus multidigituli, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus , Stenotarsonemus spp., Tarsonemus spp., Tetranychus spp., Vaejovis spp., Vasates lycopersici.

From the genus of Chilopoda, e.g. Geophilus spp., Scutigera spp. from the order or class of collembola e.g. Onychiurus armatus, Sminthurus viridis; from the class of diplopoda e.g. Blaniulus guttulatus; from the class of Insecta, e.g. from the order of the Blattodea e.g. Blattella asahinai, Blattella germanica, Blatta orientalis, Leucophaea maderae (Rhypaobia maderae), Panchlora spp., Parcoblatta spp., Periplaneta spp., Supella longipalpa, Loboptera decipiens, Neostylopyga rhombifolia, Pycnoscelus surinamensis;

From the order of the Coleoptera eg Acalymma vittatum, Acanthoscelides obtectus, Adoretus spp., Aethina tumida, Agelastica alni, Agriotes spp., Alphitobius diaperinus, Amphimallon solstitialis, Anobium punctatum, Anoplophora spp., Anthonomus spp., Anthrenus spp., Apion spp. , Apogonia spp., Atomaria spp., Attagenus spp., Baris caerulescens, Bruchidius obtectus, Bruchus spp., Cassida spp., Cerotoma trifurcata, Ceutorrhynchus spp., Chaetocnema spp., Cleonus mendicus, Conoderus spp., Cosmopolites spp., Costelytra zealandica, Ctenicera spp., Curculio spp., Cryptolestes ferruginus, Cryptorhynchus lapathi, Cylindrocopturus spp., Dermestes spp., Diabrotica spp., Dichocrocis spp., Dicladispa armigera, Diloboderus spp., Epicaerus spp., Epilachna spp., Epitrix spp. , Faustinus spp., Gibbium psylloides, Gnathocerus cornutus, Hellula and alis, Heteronychus arator, Heteronyx spp., Hylamorpha elegans, Hylotrupes bajulus, Hypera postica, Hypomeces squamosus, Hypothenemus spp., Lachnosterna consanguinea, Lasioderma serricorne, Latheticus oryzae, Lathridius spp., Lema spp., Leptinotarsa decemlineata, Leucoptera spp., Lissorhoptrus oryzophilus, Listronotus (= Hyperodes) spp., Lixus spp., Luperodes spp., Luperomorpha xanthodera, Lyctus spp., Megascelis spp., Melanotus spp., Meligethes aeneus, Melolontha spp., Migdolus spp., Monochamus spp., Naupactus xanthographus, Necrobia spp., Neogalerucella spp., Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamensis, Oryzaphagus oryzae, Otiorrhynchus spp., Oulema spp., Oulema melanopus, Oulema oryzae, Oxycetonia jucunda, Phaedon cochleariae, Phyllophaga spp., Phyllophaga helleri, Phyllotreta spp., Popillia japonica, Premnotrypes spp., Prostephanus trancatus, Psylliodes spp., Ptinus spp., Rhizobius ventralis, Rhizopertha dominica, Rhynchophorus spp., Rhynchophoras ferragineus, Rhynchophoras palmarum, Sinoxylon perforans, Sitophilus spp., Sitophilus oryzae, Sphenophorus spp., Stegobium paniceum, Starchus spp., Symphyletes spp. , Tanymecus spp., Tenebrio molitor, Tenebrioides mauretanicus, Tribolium spp., Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus spp.

From the order of the Dermaptera, e.g. Anisolabis maritime, Forficula auricularia, Labidura riparia;

From the order of Diptera e.g. Aedes spp., Agromyza spp., Anastrepha spp., Anopheles spp., Asphondylia spp., Bactrocera spp., Bibio hortulanus, Calliphora erythrocephala, Calliphora vicina, Ceratitis spp., Ceratitis capitata, Chironomus spp., Chrysomyia spp., Chrysops spp , Chrysozona pluvialis, Cochliomyia spp., Contarinia spp., Cordylobia anthropophaga, Cricotopus sylvestris, Culex spp., Culicoides spp., Culiseta spp., Cuterebra spp., Dacus oleae, Dasyneura spp., Delia spp., Dermatobia hominis, Drosophila Spp., Drosophila suzukii, Echinocnemus spp., Euleia heraclei, Fannia spp., Gasterophilus spp., Glossina spp., Haematopota spp., Hydrellia spp., Hydrellia griseola, Hylemya spp., Hyppobosca spp., Hypoderma spp., Liriomyza spp Lucilla spp., Lutzomyia spp., Mansonia spp., Musca spp., Oestrus spp., Oscinella frit, Paratanytarsus spp., Paralauterborniella subcincta, Pegomyia spp., Phlebotomus spp., Phorbia spp., Phormia spp., Piophila casei , Platyparea poeciloptera, Prodiplosis spp., Psila rosae, Rhagoletis spp., Sa rcophaga spp., Simulium spp, Stomoxys spp., Tabanus spp., Tetanops spp., Tipula spp., Toxotrypana curvicauda.

From the subordination of Heteroptera e.g. Aelia spp., Anasa tristis, Antestiopsis spp., Boisea spp., Blissus spp., Calocoris spp., Campylomma livida, Cavelerius spp., Cimex spp., Collaria spp., Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocoris hewetti, Dysdercus spp., Euschistus spp., Eurydema spp., Eurygaster spp., Halyomorpha halys, Heliopeltis spp., Horcias nobilellus, Leptocorisa spp., Leptocorisa varicornis, Leptoglossus occidentalis, Leptoglossus phyllopus, Lygocoris spp., Lygus spp., Macropes excavatus, Megacopta cribraria, Miridae, Monaionion atratum, Nezara spp., Nysius spp., Oebalus spp., Pentomidae, Piesma quadrata, Piezodorus spp., Psallus spp., Pseudacysta persea, Rhodnius spp., Sahlbergella singularis, Scaptocoris castanea, Scotinophora spp. Stephanitis nashi, Tibraca spp., Triatoma spp.

From the order of Hemiptera, for example, Acizzia acaciaebaileyanae, Acizzia dodonaeae, Acizzia uncatoides, Acrida turrita, Acyrthosipon spp., Acrogonia spp., Aeneolamia spp., Agonoscena spp., Aleurocanthus spp., Aleyrodes spp., Aleyrodes proletella, Aleurolobus barodensis, Aleurothrixus spp., Aleurothrixus floccosus, Allocaridara malayensis, Amrasca spp., Anuraphis cardui, Aonidiella spp., Aphanostigma piri, Aphis spp., Arboridia apicalis, Arytainilla spp., Aspidiella spp , Aspidiotus spp., Atanus spp., Aulacorthum solani, Bemisia spp., Bemisia tabaci, Blastopsylla occidentalis, Boreioglycaspis melaleucae, Brachycaudus helichrysii, Brachycolus spp., Brevicoryne brassicae, Cacopsylla spp., Calligypona marginata, Capulinia spp., Carneocephala fulgida, Ceratovacuna lanigera, Cercopidae, Ceroplastes spp., Chaetosiphon fragaefolii, Chionaspis tegalensis, Chlorita onukii, Chondracris rosea, Chromaphis juglandicola, Chrysomphalus aonidum, Chrysomphalus ficus, Cicadulina mbila, Coccomytilus halli, Coccus spp., Cryptomyzus ribis, Cryptoneossa spp. , Ctenarytaina spp., Dalbulus spp., Dialeurodes chittendeni, Dialeurodes spp., Dialeurodes citri, Diaphorina spp., Diaphorina citri, Diaspis spp., Diuraphis spp., Drosicha spp., Dysaphis spp., Dysmicoccus spp., Empoasca spp., Eriosoma spp., Erythroneura spp., Eucalyptolyma spp., Euphyllura spp., Euscelis bilobatus, Ferrisia spp., Fiorinia spp., Furcaspis oceanica, Geococcus coffeae, Glycaspis spp., Heteropsylla cubana, Heteropsylla spinulosa, Homalodisca coagulata, Hyalopterus arundinis, Hyalopterus pruni, Icerya spp., Idiocerus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., Lepidosaphes spp., Lipaphis erysimi, Lopholeucaspis japonica , Lycorma delicatula, Macrosiphum spp., Macrosteles facifrons, Mahanarva spp., Melanaphis sacchari, Metcalfiella spp., Metealfa pruinosa, Metopolophium dirhodum, Monellia costalis, Monelliopsis pecanis, Myzus spp., Nasonovia ribisnigri, Neomaskellia spp., Nephotettix spp., Nettigoniclla spectra, Nilaparvata lugens, Oncometopia spp., Orthezia praelonga, Oxya chinensis, Pachypsylla spp., Parabemisia myricae, Paratrioza spp., Parlatoria spp., Pemphigus spp., Peregrinus maidis, Perkinsiell a spp., Phenacoccus spp., Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp., Pinnaspis aspidistrae, Planococcus spp., Prosopidopsylla flava, Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus spp., Psyllopsis spp., Psylla spp., Pteromalus spp. Pulvinaria spp., Pyrilla spp., Quadraspidiotus spp., Quesada gigas, Rastrococcus spp., Rhopalosiphum spp., Saissetia spp., Scaphoides titanus, Schizaphis graminum, Selenaspidus articulatus, Sitobion avenae, Sogata spp., Sogatella fureifera, Sogatodes spp. Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonocephela spp., Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp., Trialeurodes spp., Trialeurodes vaporariorum, Trioza spp., Typhlocyba spp., Unaspis spp., Viteus vitifolii, Zygina spp.

From the order of Hymenoptera e.g. Acromyrmex spp., Athalia spp., Atta spp., Camponotus spp., Dolichovespula spp., Diprion spp., Hoplocampa spp., Lasius spp., Linepithema (Iridiomyrmex) humile, Monomorium pharaonis, Paratrechina spp., Paravespula spp., Plagiolepis Spp., Sirex spp., Solenopsis invicta, Tapinoma spp., Technomyrmex albipes, Urocerus spp., Vespa spp., Wasmannia auropunetata, Xeris spp.

From the order of the Isopoda eg Armadillidium vulgare, Oniscus asellus, Porcellio scaber. From the order of the Isoptera eg Coptotermes spp., Cornitermes cumulans, Cryptotermes spp., Incisitermes spp., Kalotermes spp., Microtermes obesi, Nasutitermes spp., Odontotermes spp., Porotermes spp., Reticulitermes spp.

From the order of Lepidoptera e.g. Achroia grisella, Acronica major, Adoxophyes spp., Aedia leucomelas, Agrotis spp., Alabama spp., Amyelois transitella, Anarsia spp., Anticarsia spp., Argyroploce spp., Autographa spp., Barathra brassicae, Blastodacna atra, Borbo cinnara, Bucculatrix thurberiella, Bupalus piniarius, Busseola spp., Cacoecia spp., Caloptilia theivora, Capua reticulana, Carpocapsa pomonella, Carposina niponensis, Cheimatobia brumata, Chilo spp., Choreutis pariana, Choristoneura spp., Chrysodixis chalcites, Clysia ambiguella, Cnaphalocerus spp., Cnaphalocrocis medinalis, Cnephasia spp., Conopomorpha spp., Conotrachelus spp., Copitarsia spp., Cydia spp., Dalaca noctuides, Diaphania spp., Diacraea saccharalis, Diparopsis spp., Earias spp., Ecdytolopha aurantium, Elasmopalpus lignosellus, Eidana saccharina, Ephestia spp., Epinotia spp., Epiphyas postvittana, Erannis spp., Erschoviella musculana, Etiella spp., Eudocima spp., Eulia spp., Eupoecilia ambiguella, Euproctis spp., Euxoa spp., Feltia spp., Galleria mellonella, Gracillaria spp., Grapholitha spp., Hedylepta spp., Helicoverpa spp., Heliothis spp., Hofmannophila pseudospretella, Homoeosoma spp., Homona spp., Hyponomeuta padella, Kakivoria flavofasciata, Lampides spp., Laphygma spp., Laspeyresia molesta, Leucinodes orbonalis, Leucoptera spp., Lithocolletis spp., Lithophane antennata, Lobesia spp., Loxagrotis albicosta, Lymantria spp., Lyonetia spp., Malacosoma neustria, Maruca spp., Maruca testulalis, Mamestra brassicae, Melanitis leda, Mocis spp., Monopis obviella, Mythimna separata, Nemapogon cloacellus, Nymphula spp., Oiketicus spp., Omphisa spp., Operophtera spp., Oria spp., Orthaga spp., Ostrinia spp., Panolis flammea, Parnara spp., Pectinophora spp., Perileucoptera spp. , Phthorimaea spp., Phyllocnistis citrella, Phyllonorycter spp., Pieris spp., Platynota stultana, Plodia interpunctella, Plusia spp., Plutella xylostella, Prays spp., Prodenia spp., Protoparce spp., Pseudaletia spp., Pseudaletia unipuncta, Pseudoplusia includens . Pyrausta nubilalis, Rachiplusia nu, Schoenobius spp., Scirpophaga spp., Scirpophaga innotata, Scotia segetum, Sesamia spp., Sesamia inferens, Sparganothis spp., Spodoptera spp., Spodoptera praefica, Stathmopoda spp., Stenoma spp., Stomopteryx subsecivella, Synanthedon Spp., Tecia solanivora, Thaumetopoea spp., Thermesia gemmatalis, Tinea cloacella, Tinea pellionella, Tineola bisselliella, Tortrix spp., Trichophaga tapetzella, Trichoplusia spp., Tryporyza incertulas, Tuta absoluta, Virachola spp.

From the order of Orthoptera or Saltatoria e.g. Acheta domesticus, Dichroplus spp., Gryllotalpa spp., Hieroglyphus spp., Locusta spp., Melanoplus spp., Paratlanticus ussuriensis, Schistocerca gregaria.

From the order of Phthiraptera eg Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Phylloxera vastatrix, Phtirus pubis, Trichodectes spp. From the order of Siphonaptera eg Ceratophyllus spp., Ctenocephalides spp., Pulex irritans Tunga penetrans, Xenopsylla cheopis.

From the order of Symphyla e.g. Scutigerella spp ..

From the order of Thysanoptera e.g. Anaphothrips obscurus, Baliothrips biformis, Chaetanaphothrips leeuweni, Drepanothris reuteri, Enneothrips flavens, Frankliniella spp., Haplothrips spp., Heliothrips spp., Hercinothrips femoralis, Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniothrips cardamoni, Thrips spp.

From the order of Zygentoma (= Thysanura) Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus, Thermobia domestica. from the class of Symphyla e.g. Scutigerella spp .;

Pests from the strain: Mollusca, especially from the bivalve class, e.g. Dreissena spp.

From the class Gastropoda, e.g. Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Pomacea spp., Succinea spp.

Plant pests from the strain: Nematoda, i. plant parasitic nematodes, in particular Aglenchus spp., Anguina spp., Aphelenchoides spp., Belonolaimus spp., Bursaphelenchus spp., Cacopaurus spp., Criconemella spp., Criconemoides spp., Ditylenchus spp., Dolichodorus spp., Globodera spp. Helicotylenchus spp., Hemicriconemoides spp., Hemicycliophora spp., Heterodera spp., Hoplolaimus spp., Longidorus spp., Meloidogyne spp., Meloinema spp., Nacobbus spp., Neotylenchus spp., Paralongidorus spp., Paraphelenchus spp., Paratrichodorus spp , Pratylenchus spp., Pseudohalenchus spp., Psilenchus spp., Punctodera spp., Quinisulcius spp., Radopholus similis, Rotylenchulus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp., Tylenchulus spp., Tylenchulus semipenetrans, Tylenchorhynchus spp., Xiphinema spp.

Furthermore, the order of the coccidia, for example Eimeria spp., Can be determined from the subregion of the protozoa. fight.

One of the advantages of the present invention is that, due to the systemic properties of the composition according to the invention, it is also possible to combat translaminar pests when treating aboveground plant parts. A further advantage consists in the synergistic increase in the insecticidal activity of the composition according to the invention over the individual insecticide, which exceeds the expected effectiveness of the two individually applied active ingredients. This allows optimization of the amount of active ingredients used. Likewise, it is to be regarded as advantageous that the composition of the invention can also be used on transgenic plants, wherein the plants resulting from this seed are capable of expressing a protein directed against pests. By treating such plants with the agents according to the invention, certain pests can already be controlled by the expression of the insecticidal protein, for example, and in addition can be protected from damage by the agents according to the invention.

The composition of the invention is suitable for the protection of Oberiridisches plant parts of any plant variety, as already mentioned above, which is used in agriculture, in the greenhouse, in forests or in horticulture. In particular, these are corn, peanut, canola, rapeseed, poppy, soybeans, cotton, turnip (eg sugar beet and fodder beet), rice, millet, wheat, barley, oats, rye, sunflower, tobacco, potatoes or vegetables (eg tomatoes , Cabbage). The compositions according to the invention are likewise suitable for the treatment of fruit plants and vegetables as already mentioned above. Special importance is attached to the treatment of maize, soya, cotton, wheat and canola or rapeseed.

Transgenic plants usually contain at least one heterologous gene which controls the expression of a polypeptide having in particular insecticidal properties. The heterologous genes in transgenic plants can be derived from microorganisms such as Bacillus, Rhizobium, Pseudomonas, Serratia, Trichoderma, Clavibacter, Glomus or Gliocladium. The present invention is particularly useful for the treatment of transgenic plants containing at least one heterologous gene derived from Bacillus sp. and whose gene product shows activity against corn borer and / or corn rootworm. Most preferably, this is a heterologous gene derived from Bacillus thuringiensis.

As already mentioned above, according to the invention all plants and their uppermost parts can be treated. In a preferred embodiment, wild-type or plant species and plant varieties obtained by conventional biological breeding methods, such as crossing or protoplast fusion, and parts thereof are treated (conventional plants). In a further preferred embodiment, transgenic plants and plant cultivars which have been obtained by genetic engineering methods, if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated.

Plant varieties are understood as meaning plants having new traits which have been bred by conventional breeding, by mutagenesis or by recombinant DNA techniques. These can be varieties, biotypes and genotypes.

The preferred plants or plant varieties to be treated according to the invention to be treated include all plants produced by the genetic engineering modification received genetic material which gives these plants special beneficial properties ("traits"). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to bottoms salt, increased flowering, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products. Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants against certain herbicidal active substances. Examples of transgenic plants are the important crops such as cereals (wheat, rice), corn, soy, potato, sugar beets, tomatoes, peas and other vegetables, cotton, tobacco, oilseed rape, and fruit plants (with the fruits apples, pears, citrus fruits and Grapes), with special emphasis on maize, soya, potato, cotton, tobacco and oilseed rape. Traits which are particularly emphasized are the increased defense of the plants against insects, arachnids, nematodes and snails by toxins formed in the plants, in particular those produced by the genetic material from Bacillus thuringiensis (eg by the genes CrylA (a) , CrylA (b), CrylA (c), CryllA, CrylllA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CrylF and combinations thereof) in the plants (hereinafter "Bt plants"). Traits also highlight the increased resistance of plants to fungi, bacteria and viruses by systemic acquired resistance (SAR), systemin, phytoalexins, elicitors and resistance genes and correspondingly expressed proteins and toxins. Traits which are furthermore particularly emphasized are the increased tolerance of the plants to certain herbicidally active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene). The genes which confer the desired properties ("traits") can also occur in combinations with one another in the transgenic plants. Examples of "Bt plants" are maize varieties, cotton varieties, soya bean varieties and potato varieties which are sold under the trade names YIELD GARD ^® (for example maize, cotton, soya beans), KnockOut ^® (for example maize), StarLink ^® (for example maize), Bollgard ^® ( cotton), NuCOTN ^® (cotton) and NewLeaf ^® (potato). Examples of herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties may be mentioned, under the trade names Roundup Ready ^® (tolerance to glyphosate, for example maize, cotton, soya bean), Liberty Link ^® (tolerance to phosphinotricin, for example oilseed rape), IMI ^® (tolerance against imidazolinone) and ^STS® (tolerance to sulfonylureas eg corn). As herbicide-resistant (conventionally grown on herbicide tolerance) plants are also sold under the name Clearfield ^® varieties (eg corn). Of course, these statements also apply to future or future marketed plant varieties with these or future developed genetic traits. Depending on the plant species or plant cultivars, their location and growth conditions (soils, climate, vegetation period, diet), treatment with the composition according to the invention may also result in superadditive ("synergistic") effects. Thus, for example, reduced application rates and / or extensions of the spectrum of action and / or an increase in the effect of the substances and agents usable in the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering power facilitated harvest, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or machinability of the harvested products, which exceed the actual expected effects.

The invention is further illustrated by the following examples, without thereby limiting. In the following examples, the abbreviations have the following meanings: RME = rapeseed oil methyl ester; AMS = ammonium sulfate; EW = oil-in-water emulsion; ppm = parts per million; ^d = days

Example 1:

Foliar application Nilaparvata lugens / rice

Solvent: 7 parts by weight of dimethylformamide

 Emulsifier: alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and filled with water containing an emulsifier concentration of 1000 ppm until reaching the desired concentration. To prepare further test concentrations, dilute with emulsifier-containing water. When necessary addition of ammonium salts and / or penetration promoters (rapeseed oil methyl ester = RME), these are pipetted in a concentration of 1000 ppm after dilution of the finished preparation solution.

Rice plants (Oryza sativa, var. Balilla) are treated by spraying with the preparation of active compound in the desired concentration and then populated with larvae of the rice leafhopper {Nilaparvata lugens).

After the desired time the kill is determined in%. 100% means that all cicadas have been killed; 0% means that no cicadas have been killed.

In addition, the phytoprotective effect is scored. At 100% effect no damage by feeding is to be seen, with 0% effect the damage at the treated leaves corresponds to the untreated control. In this test, the compound of formula (I) in combination with RME (rapeseed oil methyl ester) or / and AMS (ammonium sulfate) showed improved efficacy compared to the single application:

Table A-1: Nilaparvata lugens test

Active substance Concentration in 2 ai / ha Kill2% after 2 ^

Untreated control 0

 RME control 0

 Compound of formula (I) 16 50

 Compound of formula (I) + 16 80

 RME

Table A-2: Nilaparvata lugens test

Active substance concentration in 2 ai / ha kill2 in% after 21 ^d

Untreated control 0

 RME / AMS control 0

 Compound of formula (I) 4 45

 Compound of formula (I) + 4 100

 RME

 Compound of formula (I) + 4 100

 AMS

 Compound of formula (I) + 4 100

 RME + AMS

Table A-3: Nilaparvata lugens - feeding protection

Active ingredient concentration in 2 ai / ha feeding protection in% after 21 ^d

Untreated control 0

 RME / AMS control 0

 Compound of formula (I) 4 33

 1.33 0

0.44 0 Compound of formula (I) + 4 100

RME 1.33 47

 0.44 13

 Compound of formula (I) + 4 100

 AMS 1.33 0

 0.44 0

 Compound of formula (I) + 4 100

 RME + AMS 1.33 58

 0.44 42

Example 2:

Foliar application Aphis gossypii / cotton

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and filled with water containing an emulsifier concentration of 1000 ppm until reaching the desired concentration. To prepare further test concentrations, dilute with emulsifier-containing water. When necessary addition of ammonium salts or / and penetration promoters (rapeseed oil methyl ester = RME), these are pipetted in a concentration of 1000 ppm after dilution of the finished preparation solution.

Single-leaved cotton plants (Gossypium hirsutum) heavily infested with the cotton aphid {Aphis gossypii) are treated by spraying with the preparation of active compound at the desired concentration.

After the desired time the kill is determined in%. 100% means that all animals have been killed; 0% means that no animals were killed.

In this test, the compound of formula (I) in combination with RME (rapeseed oil methyl ester) showed improved efficacy compared to the single application: Table Bl: Aphis gossypii test

 * Found. = found insecticidal activity, ex. = calculated effect according to the Colby formula

Example 3:

Nezara viridula test

Solvent: 7 parts by weight of dimethylformamide

 Emulsifier: alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and filled with water containing an emulsifier concentration of 1000 ppm until reaching the desired concentration. To prepare further test concentrations, dilute with emulsifier-containing water. When necessary addition of ammonium salts and / or penetration promoters (rapeseed oil methyl ester), these are pipetted in a concentration of 1000 ppm after dilution of the finished preparation solution. Cotton plants (Gossypium hirsutum) are treated by spraying with the preparation of active compound in the desired concentration and then populated with larvae of the green rice bug (Nezara viridula).

 After the desired time, mortality is determined in%. 100% means that all bugs have been killed; 0% means that no bugs have been killed. Existing control mortality is calculated using the Schneider-Orelli formula.

Schneider - Orelli - Formula for offsetting control mortality in%

% Mortality treated plant -% mortality control plant

CCM% = () x 100

 100% mortality control plant

CCM = corrected control mortality

In addition, the phytoprotective effect is scored. At 100% effect no damage by feeding is to be seen, with 0% effect the damage at the treated leaves corresponds to the untreated control.

In this test, the compound of formula (I) in combination with AMS (ammonium sulfate) showed improved efficacy compared to the single application: see table

Table C-1: Nezara viridula - Test - Mortality

 * found effect; "calculated effect by offsetting the untreated control according to Schneider

Orelli Table C-2: Nezara viridula test protection

Active substance Concentration in 2 ai / ha Meal protection in% after 2 ^

Untreated control 0

 Compound of formula (I) 1.33 89

 0.44 0

 Compound of formula (I) + 1.33 100

 AMS

 0.44 36

Table C-3: Nezara viridula test protection

Active substance concentration in 2 ai / ha feeding protection in% after 3 ^

Untreated control 0

 Compound of formula (I) 0.44 6

 Compound of formula (I) + 0.44 36

 AMS

Claims

claims

1. Compositions containing the compound of the formula (I)

 and at least one activity improver selected from among penetration-enhancing and ammonium and phosphorus salts of the formula (II)

 in which

D is nitrogen or phosphorus; n for 1,

2, 3 or 4;

R ⁸ , R ⁹ , R ¹⁰ and R ¹¹ independently of one another represent hydrogen or in each case optionally substituted C 1 -C ⁸ -alkyl or mono- or polyunsaturated, optionally substituted C 2 -C ⁸ -alkenyl, where the substituents are selected from halogen, nitro and cyano can;

R is inorganic or organic anion.

Composition according to Claim 1, comprising a penetration promoter selected from a mineral or vegetable oil and modifications thereof and / or an alkanol alkoxylate of the formula (III)

R-O- (AO) _v -R '(III) in which

R is straight-chain or branched C 1 -C 20 -alkyl;

R 'is hydrogen, methyl, ethyl, n -propyl, z o -propyl, n -butyl, iso -butyl, tert -butyl, n -pentyl or n -hexyl; AO is an ethylene oxide radical, a propylene oxide radical, a butylene oxide radical or mixtures of ethylene oxide and propylene oxide radicals or butylene oxide radicals; and v is a number from 2 to 30.

A composition according to claim 2, wherein the penetration promoter is a vegetable oil selected from rapeseed oil, sunflower oil and their methyl or ethyl esters.

4. The composition according to any one of claims 1 to 3, containing an ammonium salt of the formula (II), in which

D is nitrogen; n is 1 or 2;

R ⁸ , R ⁹ , R ¹⁰ and R ¹¹ are each independently hydrogen or each optionally substituted Ci-C i-alkyl, wherein the substituents of halogen, nitro and cyano are selected; and

R ^{12 is} hydrogencarbonate, tetraborate, fluoride, bromide, iodide, chloride, monohydrogenphosphate, dihydrogenphosphate, hydrogensulfate, tartrate, sulphate, nitrate, thiosulphate, thiocyanate, formate, lactate, acetate, propionate, butyrate, pentanoate, citrate or oxalate.

5. A composition according to any one of claims 1 to 4, containing an ammonium salt selected from the following salts:

Ammonium sulfate, ammonium lactate, ammonium nitrate, ammonium thiosulfate, ammonium thiocyanate, ammonium citrate, ammonium oxalate, ammonium formate, ammonium hydrogen phosphate, ammonium dihydrogen phosphate, ammonium carbonate, ammonium benzoate, ammonium sulfite, ammonium benzoate, ammonium hydrogen oxalate, ammonium hydrogen citrate, ammonium acetate, tetramethylammonium sulfate, tetramethylammonium nitrate, tetramethylammonium nitrate, tetramethylammonium thiosulfate,

Tetramethylammonium thiocyanate, tetramethylammonium citrate, tetramethylammonium oxalate, tetramethylammonium formate, tetramethylammonium hydrogenphosphate, tetramethylammonium dihydrogenphosphate, tetraethylammonium sulfate, tetraethylammonium lactate, tetraethylammonium nitrate, tetraethylammonium thiosulfate, tetraethylammonium thiocyanate, tetraethylammonium citrate, tetraethylammonium oxalate, Tetraethylammonium formate, tetraethylammonium hydrogenphosphate, tetraethylammonium dihydrogenphosphate.

6. Use of the composition as defined in any one of claims 1 to 5, for controlling plant pests.

7. Use according to claim 6, in which the composition is applied to aerial plant parts of conventional or transgenic plants.

8. Use according to claim 6, in which the composition is present as a spray mixture or as a tank mixture.