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WO2016001119A1 - Insecticide and fungicide active ingredient combinations - Google Patents

Insecticide and fungicide active ingredient combinations Download PDF

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Publication number
WO2016001119A1
WO2016001119A1 PCT/EP2015/064663 EP2015064663W WO2016001119A1 WO 2016001119 A1 WO2016001119 A1 WO 2016001119A1 EP 2015064663 W EP2015064663 W EP 2015064663W WO 2016001119 A1 WO2016001119 A1 WO 2016001119A1
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WO
WIPO (PCT)
Prior art keywords
spp
methyl
species
carboxamide
pyrazole
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PCT/EP2015/064663
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German (de)
French (fr)
Inventor
Peter Jeschke
Wolfgang Thielert
Holger Weckwert
Marita JOHN
Original Assignee
Bayer Cropscience Aktiengesellschaft
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Publication of WO2016001119A1 publication Critical patent/WO2016001119A1/en

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings

Definitions

  • This application relates to mixtures of the compound of formula (I) explained below with at least one further active ingredient which is preferably a fungicide or an antimicrobially active compound.
  • These mixtures are suitable for controlling animal and microbial pests and as a plant tonic.
  • the compound of the formula (I) is known from EP 0 268 915 A2, JP1993078323 A and WO 2012/029672 Al, where its use for controlling animal pests is described.
  • Single drug combinations containing the compound of formula (I) have become known, see WO 2013/129688 Al.
  • acaricidal and / or insecticidal and / or nematicidal and / or fungicidal or antimicrobial efficacy and / or range of action and / or the plant tolerance of this compound and of the known active compound combinations, in particular to crop plants, is not always sufficient.
  • active substance combinations mixtures of active substances containing the compound of the formula (I) and one or more compounds from the groups (Fl) to (F-14) described below and / or one or more compounds of further than preferred mentioned Groups of mixing partners are synergistically effective and are suitable for controlling animal and microbial pests and as a plant tonic.
  • the active compound combinations according to the invention contain the compound of the formula (I)
  • the active compound combinations according to the invention preferably contain the compound of the formula (I) and the mixing partner (s) in synergistically effective amounts.
  • the active compound combinations according to the invention additionally contain one or more compounds from the groups (F-1) to (F-14) described below and / or one or more compounds of groups of mixing partners which are more preferred than those mentioned.
  • inhibitors of nucleic acid synthesis such as benalaxyl, benalaxyl-M (kiralaxyl), bupirimate, clozylacone, dimethirimol, ethirimol, furalaxyl, hymexazole, metalaxyl, metalaxyl-M (mefenoxam), ofurace, oxadixyl, oxolinic acid and octhilinone, (F-2) inhibitors of mitosis and cell division, such as benomyl, carbendazim, chlorfenazole, diethofencarb, ethaboxam, fuberidazole, pencycuron, thiabendazole, thiophanate, thiophanate-methyl, zoxamide, fluopicolide, 5-chloro-7- (4-methylpiperidine) l-yl) -6- (2,4,6-trifluorophenyl) [l,
  • (F-5) inhibitors of ATP production such as, for example, fentin acetate, fentin chloride, fentin hydroxide and silthiofam,
  • (F-6) inhibitors of amino acid and protein biosynthesis such as andoprim, blasticidin-S, cyprodinil, kasugamycin, kasugamycin hydrochloride hydrate, mepanipyrim and pyrimethanil
  • (F-7) signal transduction inhibitors such as fenpiclonil, fludioxonil, fluxapyroxad and quinoxyfen, 3- (5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl) quinoline, oxytetracycline, streptomycin,
  • Inhibitors of lipid and membrane synthesis such as biphenyl, chlozolinate, edifenphos, etridiazole, iodocarb, Iprobenfos, iprodione, isoprothiolane, procymidone, propamocarb, propamocarb hydrochloride, pyrazophos, tolclofos-methyl and vinclozolin, chloroneb, dicloran , Prothiocarb, Quintozen, Tecnazene,
  • (F-9) inhibitors of ergosterol biosynthesis such as aldimorph, azaconazole, bitertanol, bromuconazole, cyproconazole, diclobutrazole, difenoconazole, diniconazole, diniconazole-M, dodemorph, dodemorph acetate, epoxiconazole, etaconazole, fenarimol, fenbuconazole, fenhexamide, fenpropidin, Fenpropimorph, fluquinconazole, flurprimidol, flusilazole, flutriafol, furconazole, furconazole cis, hexaconazole, imazalil, imazalil sulfate, imibenconazole, ipconazole, metconazole, myclobutanil, naftifine, nuarimol, oxpoconazole, paclobutrazole
  • (F-10) inhibitors of cell wall synthesis such as benthiavalicarb, dimethomorph, flumorph, iprovalicarb, mandipropamide, polyoxins, polyoxorim, validamycin A valefenalate and polyoxin B
  • (Fl l) inhibitors of melanin biosynthesis such as carpropamide, diclocymet, fenoxanil, Fthalide, pyroquilon tricyclazole, and 2,2,2-trifluoroethyl ⁇ 3-methyl-1 - [(4-methylbenzoyl) amino] butan-2-yl carbamate
  • (F-12) resistance inducers such as acibenzolar-S-methyl, probenazole and tiadinil, isotianil, laminarin, (F-13) compounds having multisite activity such as Bordeaux mixture, captafol, captan, chlorothalonil, copper naphthenate, copper oxide, copper oxychloride, Copper Preparations such as Copper Hydroxide, Copper Sulfate, Dichlofluanid, Dithianone, Dodine and its Free Base, Ferbam, Fluorofolpet, Folpet, Guazatin, Guazatin Acetate, Iminoctadine, Iminoctadinal Besilate, Iminoctadine Triacetate, Mancopper, Mancozeb, Maneb, Metiram, Zinc Metiram, Copper Oxine, Propamidine, Propineb , Sulfur and sulfur preparations such as calcium polysulfide, thiram, tolylfluanid, zineb and ziram,
  • Preferred compounds from these groups are furthermore:
  • Azoxystrobin Boscalid, Penflufen, Bixafen, Fluopyram, Carpropamid, Spiroxamine, Fluxapyroxad, Carbendazim, Carboxin, Fenamidon, Fludioxonil, Fluopicolide, Fluoxastrobin, Fluquinconazole, Flutriafol, Ipconazole, Iprodione, Isotianil, Mefenoxam, Metalaxyl, Metominostrobin, Pencycuron, Prochloraz, Prothioconazole, Pyraclostrobin, Pyrimethanil, Sedaxane, Silthiopham, Tebuconazole, Thiram, Tolylfluanid, Triadimenol, Triazoxide, Trifloxystrobin, Triflumuron and Triticonazole.
  • the compounds fluopyram, fosetyl-aluminum, propamocarb hydrochloride, propamocarb fosetylate, isotianil, fluopicolide, isotianil, prothioconazole, penflufen, tebuconazole, triadimenol, pyrimethanil, fenamidone, metalaxyl, dimethomorph, cyazofamide and azoxystrobin are another preferred group of mixing partners.
  • Particularly preferred are those drug combinations in which the compound of formula (I) is combined with the mixing partners indicated in Table A.
  • the preferred, particularly preferred and most preferred mixing ratios given in the table are weight ratios. The ratio is to be understood as the compound of formula (I) Mixing partner no. 1 to 5.
  • Each of the drug combinations (mixtures) Nos. 1 to 5 is a preferred embodiment of the present invention.
  • Further preferred mixing ratios in which the compound of the formula (I) is combined with the mixing partners indicated in Table A are 2000: 1 to 1: 2000, 1000: 1 to 1: 1000, 750: 1 to 1: 750, 500 : 1 to 1: 500, 250: 1 to 1: 250, 200: 1 to 1: 200, 100: 1 to 1: 100, 95: 1 to 1:95, 90: 1 to 1:90, 85: 1 to 1:85, 80: 1 to 1:80, 75: 1 to 1:75, 70: 1 to 1:70, 65: 1 to 1:65, 60: 1 to 1:60, 55: 1 to 1 : 55, 45: 1 to 1:45, 40: 1 to 1:40, 35: 1 to 1:35, 30: 1 to 1:30, 20: 1 to 1:20, 15: 1 to 1:15, 10: 1 to 1:10, 9: 1 to 1: 9, 8: 1 to 1: 8, 7: 1 to 1: 7, 6: 1 to 1: 64: 1 to 1: 4, 3: 1 to 1: 3, 2: 1
  • the antimicrobial action or the fungicidal action and / or acaricidal and / or insecticidal and / or nematicidal action and / or the plant-strengthening and / or yield-increasing action of the active compound combinations according to the invention is substantially higher than the sum of the effects of the individual active substances. There is an unpredictable true synergistic Effect before and not just an effect supplement.
  • the active compound combinations according to the invention can contain one or more further active compounds from the groups (1-1) to (1-29) mentioned below.
  • (1-1) Acetylcholinesterase (AChE) inhibitors such as carbamates, e.g.
  • GABA-controlled chloride channel antagonists such as cyclodiene organochlorines, e.g. Chlordanes and endosulfan or phenylpyrazoles (fiproles), e.g. Ethiprole and fipronil.
  • Sodium channel modulators / voltage dependent sodium channel blockers such as pyrethroids, e.g. Acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha- Cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [(lR) trans isomers], deltamethrin, empenthrin [(EZ) (lR) isomers
  • Nicotinergic acetylcholine receptor (nAChR) agonists such as neonicotinoids, eg acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam or nicotine or sulfoxaflor or flupyradifurone.
  • Nicotinergic acetylcholine receptor (nAChR) allosteric activators such as spinosines, eg spinetoram and spinosad.
  • chloride channel activators such as avermectins / milbemycins, e.g. Abamectin, Emamectin benzoate, Lepimectin and Milbemectin.
  • Juvenile hormone mimics such as juvenile hormone analogs, e.g. Hydroprene, Kinoprene and Methoprene or Fenoxycarb or Pyriproxyfen.
  • Agents with unknown or nonspecific modes of action such as alkyl halides, e.g. Methyl bromide and other alkyl halides; or chloropicrin or sulfuryl fluoride or borax or tartar emetic.
  • Selective feeding inhibitors e.g. Pymetrozine or flonicamide.
  • Insect intestinal membrane microbial disruptors e.g. Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies tenebrionis and BT plant proteins: CrylAb, CrylAc, CrylFa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34 / 35Abl.
  • Bacillus thuringiensis subspecies israelensis Bacillus sphaericus
  • Bacillus thuringiensis subspecies aizawai Bacillus thuringiensis subspecies kurstaki
  • Bacillus thuringiensis subspecies tenebrionis and BT plant proteins CrylAb, CrylAc, CrylFa, Cry2Ab, mCry
  • Inhibitors of oxidative phosphorylation, ATP disruptors such as diafenthiuron or organotin compounds, e.g. Azocyclotin, Cyhexatin and Fenbutatin-oxide or Propargite or Tetradifon.
  • Nicotinergic acetylcholine receptor antagonists such as Bensultap, Cartap hydrochloride, Thiocyclam, and Thiosultap Sodium.
  • Type 0 inhibitors of chitin biosynthesis such as bistrifluron, chlorofluorazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron and triflumuron.
  • Ecdysone receptor agonists such as chromafenozides, halofenozides, methoxyfenozides, and tebufenozides.
  • Octopaminergic agonists such as amitraz.
  • (1-20) complex III electron transport inhibitors such as hydramethylnone or acequinocyl or fluacrypyrim.
  • METI acaricides e.g. Fenazaquin, Fenpyroximate, Pyrimidifen, Pyridaben, Tebufenpyrad and Tolfenpyrad or Rotenone (Derris).
  • inhibitors of acetyl-CoA carboxylase such as tetronic and tetramic acid derivatives, e.g. Spirodiclofen, spiromesifen and spirotetramat.
  • Complex IV electron transport inhibitors such as phosphines, e.g. Aluminum phosphide, calcium phosphide, phosphine and zinc phosphide or cyanide.
  • ryanodine receptor effectors such as diamides, e.g. Chlorantraniliprole, Cyantraniliprole and Flubendiamide,
  • Preferred compounds from these groups are:
  • the compounds of the formula (I) can be mixed with the following herbicides.
  • Fruit / Vegetable Herbicides Atrazine, Bromacil, Diuron, Glyphosate, Linuron, Metribuzin, Simazine, Trifluralin, Fluazifop, Glufosinate, Halosulfuron Gowan, Paraquat, Propyzamide, Sethoxydim, Butafenacil, Halosulfuron, Indaziflam; Cereal Herbicides: Isoproturon, Bromoxynil, Ioxynil, Phenoxies, Chlorsulfuron, Clodinafop, Diclofop, Diflufenican, Fenoxaprop, Florasulam, Fluroxypyr, Metsulfuron, Triasulfuron, Flucarbazone, Iodosulfuron, Propoxycarbazone, Picolinafen, Mesosulfuron, Beflubutamide, Pinoxaden, Amidosulfuron, Thifensulfuron, Tribenuron, Flupyrsul
  • Corn herbicides atrazines, alachlor, bromoxynil, acetochlor, dicamba, clopyralid, (S) -dimethenamid, glufosinate, glyphosate, isoxaflutole, (S) -metolachlor, mesotrione, nicosulfuron, primisulfuron, rimsulfuron, sulcotrione, foramsulfuron, toramezone, tembotrione, saflufenacil, Thiencarbazone, flufenacet, pyroxasulfone; Rice herbicides: Butachlor, Propanil, Azimsulfuron, Bensulfuron, Cyhalofop, Daimuron, Fentrazamide, Imazosulfuron, Mefenacet, Oxaziclomefone, Pyrazosulfuron, Pyributicarb, Quinclorac, Thiobencarb, Indanofan
  • Soy herbicides alachlor, bentazone, trifluralin, chlorimuron-ethyl, cloransulam-methyl, fenoxaprop, fomesafen, fluazifop, glyphosate, imazamox, imazaquin, imazethapyr, (S) -metolachlor, metribuzin, pendimethalin, tepraloxydim, glufosinate;
  • Sugar beet herbicides Chloridazon, Desmedipham, Ethofumesate, Phenmedipham, Triallate, Clopyralid, Fluazifop, Lenacil, Metamitron, Quinmerac, Cycloxydim, Triflusulfuron, Tepraloxydim, Quizalofop;
  • Rape herbicides Clopyralid, Diclofop, Fluazifop, Glufosinate, Glyphosate, Metazachlor, Trifluralin Ethametsulfuron, Quinmerac, Quizalofop, Clethodim, Tepraloxydim;
  • mixtures of the active compound combinations according to the invention with glyphosate Particular preference is given to mixtures of the active compound combinations according to the invention with glyphosate. Further preferred are in particular mixtures of the active ingredient combinations according to the invention with glufosinate.
  • the active compound combinations according to the invention are suitable for good plant tolerance, favorable toxicity to warm-blooded animals and good environmental compatibility for the protection of plants and plant organs, for increasing crop yields, improving the quality of the crop and for controlling animal pests, in particular insects, arachnids, helminths, nematodes and molluscs found in agriculture, horticulture, livestock, forests, gardens and recreational facilities, in supplies and materials, and in the hygiene sector. They can preferably be used as crop protection agents. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
  • the above mentioned pests include:
  • Pests of the genus Arthropoda in particular of the class Arachnida eg Acarus spp., Aceria kuko, Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Amphitetranychus viennensis, Argas spp., Boophilus spp., Brevipalpus spp.
  • Apogonia spp. Atomaria spp., Attagenus spp., Baris caerulescens, Bruchidius obtectus, Bruchus spp., Cassida spp., Cerotoma trifurcata, Ceutorrhynchus spp., Chaetocnema spp., Cleonus mendicus, Conoderus spp., Cosmopolites spp., Costelytra zealandica, Ctenicera spp., Curculio spp., Cryptolestes ferruginus, Cryptorhynchus lapathi, Cylindrocopturus spp., Dermestes spp., Diabrotica spp., Dichocrocis spp., Dicladispa armigera, Diloboderus spp., Epicaerus spp., Epilachna spp., Epitrix spp.
  • hypoderma spp. Liriomyza spp., Lucilla spp., Lutzomyia spp., Mansonia spp., Musca spp., Oestrus spp., Oscinella frit, Paratanytarsus spp., Paralauterborniella subcincta, Pegomyia spp., Phlebotomus spp., Phorbia spp.
  • Pulvinaria spp. Pyrilla spp., Quadraspidiotus spp., Quesada gigas, Rastrococcus spp., Rhopalosiphum spp., Saissetia spp., Scaphoid titanus, Schizaphis graminum, Selenaspidus articulatus, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp.
  • Stictocephala festina Siphoninus phillyreae, Tenalaphara malayensis, Tetragonocephela spp., Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp., Trialeurodes vaporariorum, Trioza spp., Typhlocyba spp., Unaspis spp., Viteus vitifolii, Zygina spp .; from the order of the Hymenoptera eg Acromyrmex spp., Athalia spp., Atta spp., Camponotus spp., Dolichovespula spp., Diprion spp., Hoplocampa spp., Lasius spp., Linepithema (Iridiomyrmex) humile, Monomorium pharaonis, Paratrechina spp.
  • Paravespula spp. Paravespula spp., Plagiolepis spp., Sirex spp., Solenopsis invicta, Tapinoma spp., Technomyrmex albipes, Urocerus spp., Vespa spp., Wasmannia auropunctata, Xeris spp.,; from the order of Isopoda, for example, Armadillidium vulgare, Oniscus asellus, Porcellio scaber; from the order of the Isoptera eg Coptotermes spp., Cornitermes cumulans, Cryptotermes spp., Incisitermes spp., Kalotermes spp., Microtermes obesi, Nasutitermes spp., Odontotermes spp., Porotermes spp., Reticulitermes spp .; from the order of Lepidoptera eg Achroia grisella, Acronica major
  • Pseudaletia spp., Pseudaletia Unipuncta, Pseudoplusia includens, Pyrausta nubilalis, Rachiplusia nu, Schoenobius spp., Scirpophaga spp., Scirpophaga innotata, Ontario segetum, Sesamia spp., Sesamia inferens, Sparganothis spp., Spodoptera spp., Spodoptera praefica, Stathmopoda spp., Stenoma spp.
  • Stomopteryx subsecivella Synanthedon spp., Tecia solanivora, Thaumetopoea spp., Thermesia gemmatalis, Tinea cloacella, Tinea pellionella, Tineola bisselliella, Tortrix spp., Trichophaga tapetzella, Trichoplusia spp., Tryporyza incertulas, Tuta absoluta, Virachola spp .; from the order of Orthoptera or Saltatoria eg Acheta domesticus, Dichroplus spp., Gryllotalpa spp., Hieroglyphus spp., Locusta spp., Melanoplus spp., Paratlanticus ussuriensis, Schistocerca gregaria; from the order of Phthiraptera eg Damalinia spp., Haematopinus spp., Linognathus spp., Ped
  • Pests of the Mollusca strain in particular of the bivalve class, e.g. Dreissena spp., As well as from the class Gastropoda e.g. Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Pomacea spp., Succinea spp .;
  • Gastropoda e.g. Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Pomacea spp., Succinea spp .;
  • Animal parasites from the strains of Plathelminthes and Nematoda e.g. Aelurostrongylus spp., Amidostomum spp., Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Angiostrongylus spp., Anisakis spp., Anoplocephala spp., Ascaris spp., Ascaridia spp., Baylisascaris spp., Brugia malayi, Brugia timori , Bunostomum spp., Capillaria spp., Chabertia spp., Clonorchis spp., Cooperia spp., Crenosoma spp., Cyathostoma spp., Dicrocoelium spp., Dictyocaulus fil
  • Plant pests of the Nematoda strain ie plant parasitic nematodes, in particular Aglenchus spp., Anguina spp., Aphelenchoides spp., Belonolaimus spp., Bursaphelenchus spp., Cacopaurus spp., Criconemella spp., Criconemoides spp., Ditylenchus spp., Dolichodorus spp ., Globodera spp., Helicotylenchus spp., Hemicriconemoides spp., Hemicycliophora spp., Heterodera spp., Hoplolaimus spp., Longidorus spp., Meloidogyne spp., Meloinema spp., Nacobbus spp., Neotylenchus spp., Paralongidorus spp., Paraphele
  • the order of coccidia can be determined, e.g. Eimeria spp. fight.
  • the active compound combinations according to the invention in particular those mentioned in Table A, have an increased microbicidal activity and can be used for controlling unwanted microorganisms, such as fungi and bacteria, in crop protection and in the protection of materials.
  • Fungicides can be used for the control of Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes.
  • Bactericides can be used in crop protection for controlling Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae and Streptomycetaceae.
  • Podosphaera species such as Podosphaera leucotricha
  • Sphaerotheca species such as Sphaerotheca fuliginea
  • Uncinula species such as Uncinula necator
  • Gymnosporangium species such as Gymnosporangium sabinae
  • Hemileia species such as Hemileia vastatrix
  • Phakopsora species such as Phakopsora pachyrhizi and Phakopsora meibomiae
  • Puccinia species such as Puccinia recondita
  • Uromyces species such as Uromyces appendiculatus
  • Bremia species such as Bremia lactucae
  • Peronospora species such as Peronospora pisi or P. brassicae;
  • Phytophthora species such as Phytophthora infestans
  • Plasmopara species such as Plasmopara viticola
  • Pseudoperonospora species such as Pseudoperonospora humuli or
  • Pythium species such as Pythium ultimum
  • Alternaria species such as Alternaria solani;
  • Cercospora species such as Cercospora beticola
  • Cladosporium species such as Cladosporium cucumerinum
  • Cochliobolus species such as Cochliobolus sativus
  • Colletotrichum species such as Colletotrichum lindemuthanium
  • Cycloconium species such as cycloconium oleaginum
  • Elsinoe species such as Elsinoe fawcettii
  • Gloeosporium species such as, for example, Gloeosporium laeticolor
  • Glomerella species such as Glomerella cingulata
  • Guignardia species such as Guignardia bidwelli
  • Leptosphaeria species such as Leptosphaeria maculans
  • Magnaporthe species such as Magnaporthe grisea
  • Mycosphaerella species such as Mycosphaerella graminicola and Mycosphaerella fijiensis;
  • Phaeosphaeria species such as Phaeosphaeria nodorum
  • Pyrenophora species such as, for example, Pyrenophora teres
  • Ramularia species such as Ramularia collo-cygni
  • Rhynchosporium species such as Rhynchosporium secalis
  • Septoria species such as Septoria apii
  • Typhula species such as Typhula incarnata
  • Venturia species such as Venturia inaequalis
  • Corticium species such as Corticium graminearum
  • Fusarium species such as Fusarium oxysporum
  • Gaeumannomyces species such as Gaeumannomyces graminis
  • Rhizoctonia species such as Rhizoctonia solani
  • Tapesia species such as Tapesia acuformis
  • Thielaviopsis species such as Thielaviopsis basicola
  • Ear and panicle diseases caused by e.g.
  • Alternaria species such as Alternaria spp .
  • Aspergillus species such as Aspergillus flavus
  • Cladosporium species such as Cladosporium cladosporioides
  • Claviceps species such as Claviceps purpurea
  • Fusarium species such as Fusarium culmorum
  • Gibberella species such as Gibberella zeae
  • Monographella species such as Monographella nivalis
  • Sphacelotheca species such as Sphacelotheca reiliana
  • Tilletia species such as Tilletia caries
  • Urocystis species such as Urocystis occulta
  • Ustilago species such as Ustilago nuda
  • Aspergillus species such as Aspergillus flavus
  • Botrytis species such as Botrytis cinerea
  • Penicillium species such as Penicillium expansum and Penicillium purpurogenum
  • Sclerotinia species such as Sclerotinia sclerotiorum
  • Verticilium species such as Verticilium alboatrum
  • Phytophthora species such as Phytophthora cactorum
  • Pythium species such as Pythium ultimum
  • Rhizoctonia species such as Rhizoctonia solani
  • Sclerotium species such as Sclerotium rolfsii
  • Nectria species such as Nectria galligena
  • Monilinia species such as Monilinia laxa; Deformations of leaves, flowers and fruits, caused by eg.
  • Taphrina species such as Taphrina deformans
  • Esca species such as Phaeomoniella chlamydospora and Phaeoacremonium aleophilum and Fomitiporia mediterranea;
  • Botrytis species such as Botrytis cinerea
  • Rhizoctonia species such as Rhizoctonia solani
  • Helminthosporium species such as Helminthosporium solani
  • Xanthomonas species such as Xanthomonas campestris pv. Oryzae;
  • Pseudomonas species such as Pseudomonas syringae pv. Lachrymans;
  • Erwinia species such as Erwinia amylovora
  • the following diseases of soybean beans can be controlled:
  • Alternaria leaf spot (Alternaria spec. Atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var. Truncatum), Brown spot (Septoria glycines), Cercospora leaf spot and blight (Cercospora kikuchii), Choanephora leaf blight (Choanephora infundibulifera trispora (Syn.)) , Dactuliophora leaf spot (Dactuliophora glycines), Downy Mildew (Peronospora manshurica), Drechslera blight (Drechslera glycini), Frogeye leaf spot (Cercospora sojina), Leptosphaerulina leaf spot (Leptosphaerulina trifolii), Phyllostica leaf spot (Phyllosticta sojaecola), Pod and Stem Blight (Phomopsis sojae), Powdery Milde
  • the present invention further relates to formulations and application forms prepared therefrom as crop protection agents and / or pesticides such.
  • B. drench, drip and spray comprising at least one of the active compound combinations according to the invention.
  • the use forms contain other crop protection agents and / or pesticides and / or the effect of improving adjuvants such as penetration enhancers, eg.
  • vegetative oils such as rapeseed oil, sunflower oil, mineral oils such as paraffin oils, alkyl esters of vegetable fatty acids such as rapeseed oil or soybean oil or alkanol alkoxylates and / or spreading agents such as alkyl siloxanes and / or salts z.
  • organic or inorganic ammonium or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate and / or retention-promoting agents such.
  • dioctylsulfosuccinate or hydroxypropyl guar polymers and / or humectants such as dioctylsulfosuccinate or hydroxypropyl guar polymers and / or humectants such.
  • glycerol and / or fertilizers such as ammonium, potassium or phosphorus-containing fertilizer.
  • Typical formulations are, for example, water-soluble liquids (SL), emulsion concentrates (EC), emulsions in water (EW), suspension concentrates (SC, SE, FS, OD), water-dispersible granules (WG), granules (GR) and capsule concentrates (CS). ;
  • SL water-soluble liquids
  • EC emulsion concentrates
  • EW emulsions in water
  • SC suspension concentrates
  • SC SE, SE, FS, OD
  • WG water-dispersible granules
  • GR granules
  • capsule concentrates CS
  • the formulations contain, in addition to one or more active compounds according to the invention, further agrochemical active substances.
  • auxiliaries such as extenders, solvents, spontaneity promoters, carriers, emulsifiers, dispersants, antifreeze agents, biocides, thickeners and / or further auxiliaries, such as adjuvants.
  • An adjuvant in this context is a component that enhances the biological effect of the formulation without the component itself having a biological effect. Examples of adjuvants are agents that promote retention, spreading behavior, adherence to the leaf surface, or penetration.
  • formulations are prepared in a known manner, e.g. by mixing the active ingredients with excipients such as extenders, solvents and / or solid carriers and / or other excipients such as surfactants.
  • excipients such as extenders, solvents and / or solid carriers and / or other excipients such as surfactants.
  • the preparation of the formulations is carried out either in suitable systems or before or during use.
  • excipients there may be used those substances which are suitable for conferring special properties, such as certain physical, technical and / or biological properties, to the formulation of the active substance or to the forms of use prepared from these formulations (for example usable plant protection agents such as spray or seed dressing).
  • polar and non-polar organic chemical liquids e.g. from the classes of aromatic and non-aromatic hydrocarbons (such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes), alcohols and polyols (which may also be substituted, etherified and / or esterified), ketones (such as acetone, cyclohexanone), Esters (including fats and oils) and (poly) ethers, simple and substituted amines, amides, lactams (such as N-alkylpyrrolidones) and lactones, sulfones and sulfoxides (such as dimethylsulfoxide).
  • aromatic and non-aromatic hydrocarbons such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes
  • alcohols and polyols which may also be substituted, etherified and / or esterified
  • ketones such as
  • Suitable liquid solvents are essentially: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g.
  • Petroleum fractions mineral and vegetable oils, alcohols, such as butanol or glycol, and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide and dimethyl sulfoxide, and water.
  • suitable solvents are, for example, aromatic hydrocarbons, e.g. Xylene, toluene or alkylnaphthalenes, chlorinated aromatic or aliphatic hydrocarbons, e.g.
  • Chlorobenzene chloroethylene, or methylene chloride
  • aliphatic hydrocarbons e.g. Cyclohexane, paraffins, petroleum fractions, mineral and vegetable oils
  • alcohols e.g. Methanol, ethanol, iso-propanol, butanol or glycol and their ethers and esters
  • ketones such as e.g. Acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone
  • strong polar solvents such as dimethyl sulfoxide, and water.
  • Suitable carriers are in particular: for example, ammonium salts and ground natural minerals, such as kaolins, clays, talc cumin, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and ground synthetic minerals such as fumed silica, alumina and natural or synthetic silicates, resins, waxes and / or solid fertilizers. Mixtures of such carriers can also be used.
  • Suitable carriers for granules are: eg broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, paper, coconut shells, corn cobs and tobacco stems.
  • liquefied gaseous diluents or solvents can be used.
  • Examples of emulsifying and / or foaming agents, dispersants or wetting agents having ionic or non-ionic properties or mixtures of these surfactants are salts of polyacrylic acid, salts of lignosulphonic acid, salts of phenolsulphonic acid or naphthalenesulphonic acid, polycondensates of ethylene oxide with fatty alcohols or with fatty acids or with fatty amines, with substituted phenols (preferably alkylphenols or arylphenols), salts of sulphosuccinic acid esters, taurine derivatives (preferably alkyl taurates), phosphoric acid esters of polyethoxylated alcohols or phenols, fatty acid esters of polyols, and derivatives of the compounds containing sulphates, sulphonates and phosphates, eg Alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates, protein hydro
  • dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes, and nutrient and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • inorganic pigments e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes
  • nutrient and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • Stabilizers such as cold stabilizers, preservatives, antioxidants, light stabilizers or other chemical and / or physical stability-improving agents may also be present. It may also contain foam-forming agents or defoamers. Further, the formulations and applications derived therefrom may also contain, as additional auxiliaries, adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins, and synthetic phospholipids. Other auxiliaries may be mineral and vegetable oils. Optionally, further auxiliaries may be present in the formulations and in the use forms derived therefrom.
  • adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins, and synthetic phospholipids.
  • Such additives are, for example, fragrances, protective colloids, binders, adhesives, thickeners, thixotropic substances, penetration promoters, retention promoters, stabilizers, sequestrants, complexing agents, humectants, spreading agents.
  • the active ingredients can be combined with any solid or liquid additive commonly used for formulation purposes.
  • Suitable penetration promoters in the present context are all those substances which are usually used to improve the penetration of agrochemical active substances into plants.
  • Penetration promoters are in this context defined by the fact that they can penetrate from the (usually aqueous) application broth and / or from the spray coating into the cuticle of the plant and thereby increase the material mobility (mobility) of the active ingredients in the cuticle. The method described in the literature (Baur et al., 1997, Pesticide Science 51, 131-152) can be used to determine this property.
  • Examples include alcohol alkoxylates such as coconut oil ethoxylate (10) or Isotridecylethoxylat (12), fatty acid esters such as rapeseed oil or soybean oil, fatty amine alkoxylates such as Tallowamine ethoxylate (15) or ammonium and / or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate.
  • alcohol alkoxylates such as coconut oil ethoxylate (10) or Isotridecylethoxylat (12)
  • fatty acid esters such as rapeseed oil or soybean oil
  • fatty amine alkoxylates such as Tallowamine ethoxylate (15) or ammonium and / or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate.
  • plants and parts of plants can be treated.
  • plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants).
  • Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights.
  • the plants which can be treated with the active compound combinations according to the invention include, for.
  • turf vines, cereals, for example wheat, barley, rye, oats, rice, corn and millet, triticale
  • Beets for example sugar beets and fodder beets
  • Fruits such as pome fruit, stone fruit and soft fruit, such as apples, pears, plums, peaches, almonds, cherries and berries, eg.
  • Plant parts are to be understood as meaning all aboveground and underground parts and organs of the plants, such as shoot, leaf, flower and root, by way of example, leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds and roots, tubers and rhizomes .
  • the plant parts also include crops as well as vegetative and generative propagation material, for example cuttings, tubers, rhiomes, offshoots and seeds.
  • the treatment according to the invention of the plants and plant parts with the active compound combinations takes place directly or by acting on their environment, habitat or storage space according to the usual treatment methods, e.g. by dipping, spraying, spraying, sprinkling, vaporizing, atomizing, casting, atomizing, sprinkling, foaming, brushing, spreading, injecting, pouring, drip irrigation and propagating material, in particular at Seeds, further by dry pickling, wet pickling, slurry pickling, encrusting, single or multi-layer wrapping.
  • a preferred direct treatment of the plants is foliar application, i. the active compound combinations according to the invention are applied to the foliage, wherein the treatment frequency and the application rate can be matched to the infestation pressure of the respective pest.
  • the active compound combinations according to the invention also enter the plants via the root system.
  • the treatment of the plants is then carried out by the action of the active compound combinations according to the invention on the habitat of the plant.
  • This may be, for example, by drenching, mixing into the soil or the nutrient solution, i. the location of the plant (e.g., soil or hydroponic systems) is impregnated with a liquid form of the active compound combinations of the invention, or by the soil application, i.
  • the active compound combinations according to the invention are introduced in solid form (for example in the form of granules) into the location of the plants. In water rice crops this may also be by metering the invention in a solid application form (e.g., as granules) into a flooded paddy field.
  • the present invention therefore also relates in particular to a method for protecting seed and germinating plants from the infestation of pests by treating the seed with the active compound combinations according to the invention.
  • the method according to the invention for the protection of seeds and germinating plants from attack by pests comprises a method, in the seed is treated simultaneously in one operation with an active substance of formula I and mixing partners. It also includes a method in which the seed is treated at different times with an active ingredient of formula I and mixing partners.
  • the invention also relates to the use of the active compound combinations according to the invention for the treatment of seed for the protection of the seed and the resulting plant from animal pests.
  • the invention relates to seed which has been treated for protection against animal pests with the active compound combinations according to the invention.
  • the invention also relates to seed which has been treated at the same time with the active ingredient of formula (I) and mixing partner.
  • the invention further relates to seed which has been treated at different times with the active ingredient of the formula (I) and mixing partner.
  • the individual active ingredients of the agent according to the invention may be present in different layers on the seed.
  • the layers containing the active ingredient of the formula (I) and mixing partner may optionally be separated by an intermediate layer.
  • the invention also relates to seed in which the active ingredient of the formula (I) and mixing partner are applied as part of a coating or as a further layer or further layers in addition to a coating.
  • the invention relates to seed which, after treatment with the active compound combinations according to the invention, is subjected to a film coating process in order to avoid dust abrasion on the seed.
  • One of the advantages of the present invention is that because of the particular systemic properties of the compositions of the invention, treatment of the seeds with these agents not only protects the seed itself but also the resulting plants after emergence from animal pests. In this way, the immediate treatment of the culture at the time of sowing or shortly afterwards can be omitted.
  • a further advantage is the fact that germination and emergence of the treated seed can be promoted by treating the seed with the active compound combinations according to the invention.
  • active compound combinations according to the invention can be used in particular also in transgenic seed.
  • wild-type or plant species obtained by conventional biological breeding methods such as cross-breeding or protoplast fusion, and plant varieties and their parts are treated.
  • Traditional propagation and breeding methods may be supported or supplemented by one or more biotechnological methods, such as the use of double haploids, random and directed mutagenesis, molecular or genetic markers, or bioengineering methods and genetic engineering methods.
  • transgenic plants and plant cultivars which have been obtained by genetic engineering methods, if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated.
  • heterologous gene essentially means a gene that is provided or assembled outside the plant or plant cell and that when introduced into the nuclear genome, the chloroplast genome or the mitochondrial genome, provides the transformed plant with new or improved agronomic or other features in that it expresses a protein or polypeptide of interest, or that it downregulates or shuts down another gene present in the plant or other genes present in the plant (eg, by antisense technology, cosuppression technology , RNA interference technology (RNAi technology) or microRNA technology (miRNA technology)).
  • RNAi technology RNA interference technology
  • miRNA technology microRNA technology
  • Plants or plant varieties belong to all plants which received genetic material through the genetic engineering modification, which gives these plants particularly advantageous valuable properties ("traits").
  • traits are better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to bottoms salt, increased flowering, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products.
  • Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants against certain herbicidal active substances.
  • transgenic plants include the important crops such as cereals (wheat, rice), corn, soy, potato, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soy, potato, cotton and rapeseed should be highlighted.
  • Traits which are particularly emphasized are the increased defense of the plants against insects by toxins which are formed in the plants, in particular those which are produced by the genetic material from Bacillus thuringiensis (for example by the genes CrylA (a), CrylA (b), CrylA (c), CryllA, CrylllA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CrylF and combinations thereof) are produced in the plants (hereinafter "Bt plants”).
  • trasits which are furthermore particularly emphasized are the increased tolerance of the plants to certain herbicidal active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene).
  • herbicidal active compounds for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene).
  • the genes which confer the desired properties can also occur in combinations with one another in the transgenic plants.
  • Bt plants are maize varieties, cotton varieties, soya bean varieties and potato varieties which are sold under the trade names YIELD GARD ® (for example maize, cotton, soya beans), KnockOut ® (for example maize), StarLink ® (for example maize), Bollgard ® ( cotton), NuCOTN ® (cotton) and NewLeaf ® (potato).
  • herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties which are resistant under the trade names Roundup Ready ® (tolerance to glyphosate, for example maize, cotton, soya bean), Liberty Link ® (tolerance to phosphinotricin, for example oilseed rape), IMI ® (tolerance imidazolinones) and STS ® (tolerance to sulphonylureas, for example maize).
  • Herbicide-resistant (conventionally grown on herbicide tolerance) plants are also the varieties marketed under the name Clearfield ® (eg corn) mentioned. Of course, these statements also apply to future or future marketed plant varieties with these or future developed genetic traits.
  • the listed plants can be treated particularly advantageously according to the invention with the active substance mixtures according to the invention.
  • the preferred ranges given above for the active substance combinations also apply to the treatment of these plants.
  • Particularly emphasized is the Plant treatment with the active compound combinations specifically mentioned in the present text.
  • a synergistic effect is always present when the effect of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.
  • X means the degree of killing, expressed in% of the untreated control, when using the active substance A at a rate of m g / ha or in a concentration of m ppm,
  • Y means the degree of killing, expressed in% of the untreated control, when using the active ingredient B in an application rate of n g / ha or in a concentration of n ppm
  • E is the killing degree, expressed in% of the untreated control, when using the active compounds A and B in application rates of m and n g / ha or in a concentration of m and n ppm, then is
  • Emulsifier alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and filled with water containing an emulsifier concentration of 1000 ppm until reaching the desired concentration. Further test concentrations are obtained by dilution with emulsifier-containing water.
  • Chinese cabbage leaf discs (Brassica pekinensis) infested with all stages of the green peach aphid ⁇ Myzus persicae) are sprayed with an active compound preparation of the desired concentration.
  • the effect is determined in%. 100% means that all aphids have been killed and 0% means that no aphids have been killed.
  • the determined kill values are calculated according to the Colby formula (see page 1).
  • Emulsifier alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and filled with water containing an emulsifier concentration of 1000 ppm until reaching the desired concentration. Further test concentrations are obtained by dilution with emulsifier-containing water.
  • Chinese cabbage leaf discs (Brassica pekinensis) are sprayed with a preparation of active compound of the desired concentration and, after drying, are populated with larvae of the horseradish leaf beetle (Phaedon cochleariae).
  • the effect is determined in%. 100% means that all beetle larvae have been killed and 0% means that no beetle larvae have been killed.
  • the determined kill values are calculated according to the Colby formula (see page 1).

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Abstract

The invention relates to active ingredient combinations that contain the known compound of formula (I) and one or more other fungicides and are suitable for controlling animal and microbial pests.

Description

Insektizide und fungizide Wirkstoffkombinationen  Insecticidal and fungicidal combinations of active substances
Diese Anmeldung betrifft Mischungen der Verbindung der unten erläuterten Formel (I) mit mindestens einem weiteren Wirkstoff, welcher bevorzugt ein Fungizid bzw. eine antimikrobiell wirksame Verbindung ist. Diese Mischungen (Wirkstoffkombinationen) eignen sich zur Bekämpfung tierischer und mikrobieller Schädlinge sowie als Pflanzenstärkungsmittel. Die Verbindung der Formel (I) ist aus EP 0 268 915 A2, JP1993078323 A und WO 2012/029672 AI bekannt, dort wird ihre Verwendung zur Bekämpfung tierischer Schädlinge beschrieben. Einzelne Wirkstoffkombinationen enthaltend die Verbindung der Formel (I) sind bekannt geworden, siehe WO 2013/129688 AI . Die akarizide und / oder Insektizide und / oder nematizide und / oder fungizide bzw. antimikrobielle Wirksamkeit und / oder Wirkungsbreite und / oder die Pflanzenverträglichkeit dieser Verbindung und der bekannten Wirkstoffkombinationen, insbesondere gegenüber Kulturpflanzen, ist jedoch nicht immer ausreichend. This application relates to mixtures of the compound of formula (I) explained below with at least one further active ingredient which is preferably a fungicide or an antimicrobially active compound. These mixtures (drug combinations) are suitable for controlling animal and microbial pests and as a plant tonic. The compound of the formula (I) is known from EP 0 268 915 A2, JP1993078323 A and WO 2012/029672 Al, where its use for controlling animal pests is described. Single drug combinations containing the compound of formula (I) have become known, see WO 2013/129688 Al. However, the acaricidal and / or insecticidal and / or nematicidal and / or fungicidal or antimicrobial efficacy and / or range of action and / or the plant tolerance of this compound and of the known active compound combinations, in particular to crop plants, is not always sufficient.
Es wurde nun gefunden, dass Wirkstoffkombinationen (Wirkstoffmischungen) enthaltend die Verbindung der Formel (I) und eine oder mehrere Verbindungen aus den weiter unten beschriebenen Gruppen (F-l) bis (F-14) und/oder eine oder mehrere Verbindungen aus weiter als bevorzugt genannten Gruppen von Mischpartnern synergistisch wirksam sind und sich zur Bekämpfung tierischer und mikrobieller Schädlinge sowie als Pflanzenstärkungsmittel eignen. It has now been found that active substance combinations (mixtures of active substances) containing the compound of the formula (I) and one or more compounds from the groups (Fl) to (F-14) described below and / or one or more compounds of further than preferred mentioned Groups of mixing partners are synergistically effective and are suitable for controlling animal and microbial pests and as a plant tonic.
Die erfindungsgemäßen Wirkstoffkombinationen enthalten die Verbindung der Formel (I) The active compound combinations according to the invention contain the compound of the formula (I)
Figure imgf000002_0001
Figure imgf000002_0001
Vorzugsweise enthalten die erfindungsgemäßen Wirkstoffkombinationen die Verbindung der Formel (I) und den oder die Mischpartner in synergistisch wirksamen Mengen. The active compound combinations according to the invention preferably contain the compound of the formula (I) and the mixing partner (s) in synergistically effective amounts.
Die erfindungsgemäßen Wirkstoffkombinationen enthalten darüber hinaus eine oder mehrere Verbindungen aus den im Folgenden beschriebenen Gruppen (F-l) bis (F-14) und/oder eine oder mehrere Verbindungen aus weiter als bevorzugt genannten Gruppen von Mischpartnern. The active compound combinations according to the invention additionally contain one or more compounds from the groups (F-1) to (F-14) described below and / or one or more compounds of groups of mixing partners which are more preferred than those mentioned.
(F-l) Inhibitoren der Nukleinsäuresynthese, wie beispielsweise Benalaxyl, Benalaxyl-M (Kiralaxyl), Bupirimat, Clozylacon, Dimethirimol, Ethirimol, Furalaxyl, Hymexazol, Metalaxyl, Metalaxyl-M (Mefenoxam), Ofurace, Oxadixyl, Oxolinsäure und Octhilinone, (F-2) Inhibitoren der Mitose und Zellteilung, wie beispielsweise Benomyl, Carbendazim, Chlorfenazol, Diethofencarb, Ethaboxam, Fuberidazol, Pencycuron, Thiabendazol, Thiophanat, Thiophanat-Methyl, Zoxamid, Fluopicolid, 5-Chlor-7-(4-methylpiperidin-l-yl)-6-(2,4,6-trifluorphenyl)[l,2,4]triazolo[l,5- ajpyrimidin, (F-3) Inhibitoren der Respiration (Atmungsketten-Inhibitoren), wie beispielsweise Diflumetorim als Inhibitor am Komplex I der Atmungskette; Bixafen, Boscalid, Carboxin, Fenfuram, Flutolanil, Fluopyram, Furametpyr, Furmecyclox, Isopyrazam (Mischung aus dem yn-epimeren Razemat \RS,4SR,9RS und dem αηίζ'-epimeren Razemat \RS,4SR,9SR), Isopyrazam (yyn-epimeres Razemat \RS,4SR,9RS), Isopyrazam (yyn-epimeres Enantiomer 1R,4S,9R), Isopyrazam (yyn-epimeres Enantiomer \S,4R,9S), Isopyrazam (αηίζ'-epimeres Razemat \RS,4SR,9SR), Isopyrazam (αηίζ'-epimeres Enantiomer \R,4S,9S), Isopyrazam (αηίζ'-epimeres Enantiomer \S,4R,9R), (B) inhibitors of nucleic acid synthesis, such as benalaxyl, benalaxyl-M (kiralaxyl), bupirimate, clozylacone, dimethirimol, ethirimol, furalaxyl, hymexazole, metalaxyl, metalaxyl-M (mefenoxam), ofurace, oxadixyl, oxolinic acid and octhilinone, (F-2) inhibitors of mitosis and cell division, such as benomyl, carbendazim, chlorfenazole, diethofencarb, ethaboxam, fuberidazole, pencycuron, thiabendazole, thiophanate, thiophanate-methyl, zoxamide, fluopicolide, 5-chloro-7- (4-methylpiperidine) l-yl) -6- (2,4,6-trifluorophenyl) [l, 2,4] triazolo [l, 5-ajpyrimidine, (F-3) inhibitors of respiration (respiratory chain inhibitors), such as diflumetorim as an inhibitor at complex I of the respiratory chain; Bixafen, boscalid, carboxin, fenfuram, flutolanil, fluopyram, furametpyr, furmecyclox, isopyrazam (mixture of the yn-epimeric racemate \ RS, 4SR, 9RS and the αηίζ ' epimeric racemate \ RS, 4SR, 9SR), isopyrazam (yyne) epimeric racemate \ RS, 4SR, 9RS), isopyrazam (yyn-epimeric enantiomer 1R, 4S, 9R), isopyrazam (yyn-epimeric enantiomer \ S, 4R, 9S), isopyrazam (αηίζ ' epimeric racemate \ RS, 4SR, 9SR ), Isopyrazam (αηίζ ' epimeric enantiomer \ R, 4S, 9S), isopyrazam (αηίζ ' epimeric enantiomer \ S, 4R, 9R),
Mepronil, Oxycarboxin, Penflufen, Penthiopyrad, Sedaxane, Thifluzamid, 3 -(Difluormethyl)- 1-methyl- N- [2-( 1 , 1 ,2,2-tetrafluorethoxy)phenyl] - 1 H-pyrazol-4-carboxamid, 3 -(Difluormethyl)- 1 -methyl-N- [2- (l,l,2,2-tetrafluorethoxy)phenyl]-lH-pyrazol-4-carboxamid, 3-(Difluormethyl)-l-methyl-N-[2-(l , 1,2,2- tetrafluorethoxy)phenyl]-lH-pyrazol-4-carboxamid, Benzovindiflupyr, Benodanil, 2-Chlor-N-(l ,l,3- trimethyl-2,3-dihydro-lH-inden-4-yl)pyridin-3-carboxamid, Isofetamid, N-[l-(2,4-Dichlorphenyl)-l- methoxypropan-2-yl]-3-(difluormethyl)-l-methyl-lH-pyrazol-4-carboxamid, 5,8-Difluor-N-[2-(2-fluor- 4- {[4-(trifluormethyl)pyridin-2-yl]oxy}phenyl)ethyl]quinazolin-4-amin, Benzovindiflupyr, N-[(l S,4R)- 9-(dichlormethylen)- 1 ,2,3 ,4-tetrahydro- 1 ,4-methanonaphthalen-5-yl] -3 -(difluormethyl)- 1 -methyl- 1 H- pyrazol-4-carboxamid, N-[(lR,4S)-9-(dichlormethylen)-l,2,3,4-tetrahydro-l,4-methanonaphthalen-5- yl] -3 -(difluormethyl)- 1 -methyl- 1 H-pyrazol-4-carboxamid, 3 -(Difluormethyl)- 1 -methyl-N-( 1 ,1,3- trimethyl-2,3-dihydro-lH-inden-4-yl)-lH-pyrazol-4-carboxamid, l,3,5-Trimethyl-N-(l ,l,3-trimethyl- 2,3 -dihydro- 1 H-inden-4-yl)- 1 H-pyrazol-4-carboxamid, 1 -Methyl-3 -(trifluormethyl)-N-( 1 , 1 ,3 -trimethyl- 2,3 -dihydro- 1 H-inden-4-yl)- 1 H-pyrazol-4-carboxamid, 1 -Methyl-3 -(trifluormethyl)-N- [(3R)- 1 , 1 ,3 - trimethyl-2,3 -dihydro- 1 H-inden-4-yl] - 1 H-pyrazol-4-carboxamid, 1 -Methyl-3 -(trifluormethyl)-N- [(3 S)- 1 , 1 ,3 -trimethyl-2,3 -dihydro- 1 H-inden-4-yl] - 1 H-pyrazole-4-carboxamid, 3 -(Difluormethyl)- 1 -methyl-N- [(3 S)- 1 , 1 ,3 -trimethyl-2,3 -dihydro- 1 H-inden-4-yl] - 1 H-pyrazol-4-carboxamid, 3 -(Difluormethyl)- 1 - methyl-N-[(3R)-l,l,3-trimethyl-2,3-dihydro-lH-inden-4-yl]-lH-pyrazole-4-carboxamid, 1,3,5- Trimethyl-N-[(3R)-l,l,3-trimethyl-2,3-dihydro-lH-inden-4-yl]-lH-pyrazol-4-carboxamid, 1,3,5- Trimethyl-N- [(3 S)- 1 , 1 ,3 -trimethyl-2,3 -dihydro- 1 H-inden-4-yl] - 1 H-pyrazole-4-carboxamid, als Inhibitoren am Komplex II der Atmungskette ; Amisulbrom, Azoxystrobin, Cyazofamid, Dimoxystrobin, Enestroburin, Famoxadon, Fenamidon, Fluoxastrobin, Kresoxim-Methyl, Metominostrobin, Orysastrobin, Picoxystrobin, Pyraclostrobin, Pyraoxystrobin, Pyrametostrobin, Pyribencarb, Trifloxystrobin, Ametoctradin, Coumethoxystrobin, Coumoxystrobin, Enoxastrobin, Flufenoxystrobin, Triclopyricarb, (2E)-2-(2- {[6-(3-chlor-2-methylphenoxy)-5-fluorpyrimidin-4- yl]oxy}phenyl)-2-(methoxyimino)-N-methylacetamid, (2E)-2-(methoxyimino)-N-methyl-2-(2- {[( {(lE)- l-[3-(trifluormethyl)phenyl]ethyliden}amino)oxy]methyl}phenyl)acetamid, (2E)-2-(methoxyimino)-N- methyl-2- {2- [(E)-( { 1 - [3 -(trifluormethyl)phenyl] ethoxy } imino)methyl]phenyl} acetamid, (2E)-2- {2-Mepronil, oxycarboxine, penflufen, penthiopyrad, sedaxanes, thifluzamide, 3- (difluoromethyl) -1-methyl-N- [2- (1, 1, 2,2-tetrafluoroethoxy) phenyl] -1 H -pyrazole-4-carboxamide, 3 - (Difluoromethyl) -1-methyl-N- [2- (1,1,2,2-tetrafluoroethoxy) phenyl] -1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -l-methyl-N- [ 2- (l, 1,2,2-tetrafluoroethoxy) phenyl] -1H-pyrazole-4-carboxamide, benzovindiflupyr, benodanil, 2-chloro-N- (1,1,3-trimethyl-2,3-dihydro-1H -inden-4-yl) pyridine-3-carboxamide, isofetamide, N- [1- (2,4-dichlorophenyl) -1-methoxypropan-2-yl] -3- (difluoromethyl) -1-methyl-1H-pyrazole 4-carboxamide, 5,8-difluoro-N- [2- (2-fluoro-4- {[4- (trifluoromethyl) pyridin-2-yl] oxy} phenyl) ethyl] quinazolin-4-amine, benzovindiflupyr, N - [(1S, 4R) -9- (dichloromethylene) -1,2,3,4-tetrahydro-1,4-methanonaphthalene-5-yl] -3- (difluoromethyl) -1-methyl-1H- pyrazole-4-carboxamide, N - [(1R, 4S) -9- (dichloromethylene) -l, 2,3,4-tetrahydro-1,4-methanonaphthalene-5-yl] -3- (difluoromethyl) -1 - methyl-1H-pyrazole-4-carboxamide, 3 - (difluoromethyl) -1 -methyl-N- (1, 1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1H-pyrazole-4-carboxamide, 1,3,5-trimethyl-N- (1, 1, 3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1 H -pyrazole-4-carboxamide, 1-methyl-3 - (trifluoromethyl) -N- (1, 1, 3 - trimethyl-2,3-dihydro-1H-inden-4-yl) -1-H-pyrazole-4-carboxamide, 1-methyl-3 - (trifluoromethyl) -N- [(3R) - 1, 1, 3 - trimethyl-2,3-dihydro-1H-inden-4-yl] -1-H-pyrazole-4-carboxamide, 1-methyl-3 - (trifluoromethyl) -N- [(3S)-1, 1, 3 -trimethyl-2,3-dihydro-1H-inden-4-yl] - 1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -1-methyl-N- [(3S) -1, 1, 3-trimethyl-2,3-dihydro-1H-inden-4-yl] - 1H-pyrazole-4-carboxamide, 3 - (difluoromethyl) -1-methyl-N - [(3R) -l, l, 3-trimethyl-2,3-dihydro-1H-inden-4-yl] -LH-pyrazole-4-carboxamide, 1,3,5-trimethyl-N - [(3R) -l, l, 3-trimethyl- 2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, 1,3,5-trimethyl-N- [(3S) -1,3,3-trimethyl-2,3 -dihydro-1H-inden-4-yl] - 1H-pyrazole-4-carboxamide, as inhibitors of complex II of the respiratory chain e; Amisulbrom, Azoxystrobin, Cyazofamide, Dimoxystrobin, Enestroburin, Famoxadone, Fenamidon, Fluoxastrobin, Kresoxim-Methyl, Metominostrobin, Orysastrobin, Picoxystrobin, Pyraclostrobin, Pyraoxystrobin, Pyrametostrobin, Pyribencarb, Trifloxystrobin, Ametoctradin, Coumethoxystrobin, Coumoxystrobin, Enoxastrobin, Flufenoxystrobin, Triclopyricarb, (2E ) -2- (2- {[6- (3-chloro-2-methylphenoxy) -5-fluoropyrimidin-4-yl] oxy} phenyl) -2- (methoxyimino) -N-methylacetamide, (2E) -2- (methoxyimino) -N-methyl-2- (2- {[({(IE) - 1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) acetamide, (2E) -2- (methoxyimino) -N-methyl-2- {2- [(E) - ({1 - [3 - (trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} acetamide, (2E) -2- {2-
[( { [( 1 E)- 1 -(3 - { [(E)- 1 -fluor-2-phenylvinyl] oxy } phenyl)ethyliden] amino} oxy) methyljphenyl} -2-[({[(1E) -1- (3 - {[(E) -1-fluoro-2-phenylvinyl] oxy} phenyl) ethylidene] amino} oxy) methyl] phenyl} -2-
(methoxyimino)-N-methylacetamid, Fenaminostrobin, 5-Methoxy-2-methyl-4-(2- {[( {(lE)-l-[3- (trifluormethyl)phenyl]ethyliden}amino)oxy]methyl}phenyl)-2,4-dihydro-3H-l,2,4-triazol-3-one, Methyl(2E)-2- {2-[({cyclopropyl[(4-methoxyphenyl)imino]methyl}sulfanyl)methyl]phenyl} -3- methoxyacrylate, N-(3-ethyl-3,5,5-rrimethylcyclohexyl)-3-formamido-2-hydroxybenzamid, 2- {2-[(2,5-(methoxyimino) -N-methylacetamide, fenaminostrobin, 5-methoxy-2-methyl-4- (2- {[({(L (e) -l- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl ) -2,4-dihydro-3H-l, 2,4-triazol-3-one, methyl (2E) -2- {2 - [({cyclopropyl [(4-methoxyphenyl) imino] methyl} sulfanyl) methyl] phenyl} -3-methoxyacrylate, N- (3-ethyl-3,5,5-trimethylcyclohexyl) -3-formamido-2-hydroxybenzamide, 2- {2 - [(2,5-)
Dimethylphenoxy)methyl]phenyl} -2-methoxy-N-methylacetamid, 2- {2-[(2,5-dimethylphenoxy) methyl]phenyl} -2-methoxy-N-methylacetamid als Inhibitoren am Komplex III der Atmungskette, (F-4) Entkoppler, wie beispielsweise Binapacryl, Dinocap, Fluazinam und Meptyldinocap, Ferimzon, Dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide, 2- {2 - [(2,5-dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide as inhibitors of the complex III of the respiratory chain, (F 4) decouplers such as binapacryl, dinocap, fluazinam and meptyldinocap, ferimzone,
(F-5) Inhibitoren der ATP Produktion, wie beispielsweise Fentin Acetat, Fentin Chlorid, Fentin Hydroxid und Silthiofam, (F-5) inhibitors of ATP production, such as, for example, fentin acetate, fentin chloride, fentin hydroxide and silthiofam,
(F-6) Inhibitoren der Aminosäure- und Protein-Biosynthese, wie beispielsweise Andoprim, Blasticidin- S, Cyprodinil, Kasugamycin, Kasugamycin Hydrochlorid Hydrat, Mepanipyrim und Pyrimethanil, (F-7) Inhibitoren der Signaltransduktion, wie beispielsweise Fenpiclonil, Fludioxonil, Fluxapyroxad und Quinoxyfen, 3-(5-Fluor-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-l-yl)quinolin, Oxytetracyclin, Streptomycin, (F-6) inhibitors of amino acid and protein biosynthesis, such as andoprim, blasticidin-S, cyprodinil, kasugamycin, kasugamycin hydrochloride hydrate, mepanipyrim and pyrimethanil, (F-7) signal transduction inhibitors, such as fenpiclonil, fludioxonil, fluxapyroxad and quinoxyfen, 3- (5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl) quinoline, oxytetracycline, streptomycin,
(F-8) Inhibitoren der Lipid- und Membran-Synthese, wie beispielsweise Biphenyl, Chlozolinat, Edifenphos, Etridiazol, Iodocarb, Iprobenfos, Iprodion, Isoprothiolan, Procymidon, Propamocarb, Propamocarb Hydrochlorid, Pyrazophos, Tolclofos-Methyl und Vinclozolin, Chloroneb, Dicloran, Prothiocarb, Quintozen, Tecnazene, (F-8) Inhibitors of lipid and membrane synthesis, such as biphenyl, chlozolinate, edifenphos, etridiazole, iodocarb, Iprobenfos, iprodione, isoprothiolane, procymidone, propamocarb, propamocarb hydrochloride, pyrazophos, tolclofos-methyl and vinclozolin, chloroneb, dicloran , Prothiocarb, Quintozen, Tecnazene,
(F-9) Inhibitoren der Ergosterol-Biosynthese, wie beispielsweise Aldimorph, Azaconazol, Bitertanol, Bromuconazol, Cyproconazol, Diclobutrazol, Difenoconazol, Diniconazol, Diniconazol-M, Dodemorph, Dodemorph Acetat, Epoxiconazol, Etaconazol, Fenarimol, Fenbuconazol, Fenhexamid, Fenpropidin, Fenpropimorph, Fluquinconazol, Flurprimidol, Flusilazol, Flutriafol, Furconazol, Furconazol-Cis, Hexaconazol, Imazalil, Imazalil Sulfat, Imibenconazol, Ipconazol, Metconazol, Myclobutanil, Naftifin, Nuarimol, Oxpoconazol, Paclobutrazol, Pefurazoat, Penconazol, Piperalin, Prochloraz, Propiconazol, Prothioconazol, Pyributicarb, Pyrifenox, Quinconazol, Simeconazol, Spiroxamin, Tebuconazol, Terbinafin, Tetraconazol, Triadimefon, Triadimenol, Tridemorph, Triflumizol, Triforin, Triticonazol, Uniconazol, Viniconazol und Voriconazol, Uniconazole-P, l-(4-chlorphenyl)-2-(lH-l,2,4-triazol-l- yl)cycloheptanol, Methyl 1 -(2,2-dimethyl-2,3-dihydro- 1 H-inden- 1 -yl)-l H-imidazol-5-carboxylat, N'- {5- (Difluormethyl)-2-methyl-4-[3-(trimethylsilyl)propoxy]phenyl}-N-ethyl-N-methylimidoformamid, N- Ethyl-N-methyl-N'- {2-methyl-5-(trifluormethyl)-4-[3-(trimethylsilyl)propoxy]phenyl}imidoformamid, 0-[l -(4-methoxyphenoxy)-3,3-dimethylbutan-2-yl] lH-imidazol-l -carbothioat, Pyrisoxazol, (F-9) inhibitors of ergosterol biosynthesis, such as aldimorph, azaconazole, bitertanol, bromuconazole, cyproconazole, diclobutrazole, difenoconazole, diniconazole, diniconazole-M, dodemorph, dodemorph acetate, epoxiconazole, etaconazole, fenarimol, fenbuconazole, fenhexamide, fenpropidin, Fenpropimorph, fluquinconazole, flurprimidol, flusilazole, flutriafol, furconazole, furconazole cis, hexaconazole, imazalil, imazalil sulfate, imibenconazole, ipconazole, metconazole, myclobutanil, naftifine, nuarimol, oxpoconazole, paclobutrazole, pefurazoate, penconazole, piperaline, prochloraz, propiconazole, prothioconazole , Pyributicarb, Pyrifenox, Quinconazole, Simeconazole, Spiroxamine, Tebuconazole, Terbinafine, Tetraconazole, Triadimefon, Triadimenol, Tridemorph, Triflumizol, Triforin, Triticonazole, Uniconazole, Viniconazole and Voriconazole, Uniconazole-P, 1- (4-chlorophenyl) -2- ( lH-l, 2,4-triazol-1-yl) cycloheptanol, methyl 1 - (2,2-dimethyl-2,3-dihydro-1H-inden-1-yl) -1H-imidazole-5-carboxylate , N'- {5- (difluoromethyl l) -2-methyl-4- [3- (trimethylsilyl) propoxy] phenyl} -N-ethyl-N-methylimidoformamide, N-ethyl-N-methyl-N '- {2-methyl-5- (trifluoromethyl) - 4- [3- (trimethylsilyl) propoxy] phenyl} imidoformamid, 0- [1- (4-methoxyphenoxy) -3,3-dimethylbutan-2-yl] -1H-imidazole-1-carbothioate, pyrisoxazole,
(F-10) Inhibitoren der Zellwandsynthese, wie beispielsweise Benthiavalicarb, Dimethomorph, Flumorph, Iprovalicarb, Mandipropamid, Polyoxins, Polyoxorim, Validamycin A Valefenalat und Polyoxin B, (F-l l) Inhibitoren der Melanin-Biosynthese, wie beispielsweise Carpropamid, Diclocymet, Fenoxanil, Fthalid, Pyroquilon Tricyclazol, und 2,2,2-Trifluorethyl {3-methyl-l -[(4-methylbenzoyl)amino]butan-2- yljcarbamat, (F-10) inhibitors of cell wall synthesis, such as benthiavalicarb, dimethomorph, flumorph, iprovalicarb, mandipropamide, polyoxins, polyoxorim, validamycin A valefenalate and polyoxin B, (Fl l) inhibitors of melanin biosynthesis, such as carpropamide, diclocymet, fenoxanil, Fthalide, pyroquilon tricyclazole, and 2,2,2-trifluoroethyl {3-methyl-1 - [(4-methylbenzoyl) amino] butan-2-yl carbamate,
(F-12) Resistenzinduktoren, wie beispielsweise Acibenzolar-S-Methyl, Probenazol und Tiadinil, Isotianil, Laminarin, (F-13) Verbindungen mit Multisite- Aktivität, wie beispielsweise Bordeauxmischung, Captafol, Captan, Chlorothalonil, Kupfernaphthenat, Kupferoxid, Kupferoxychlorid, Kupferzubereitungen, wie Kupferhydroxid, Kupfersulfat, Dichlofluanid, Dithianon, Dodine und dessen freie Base, Ferbam, Fluorofolpet, Folpet, Guazatin, Guazatinacetat, Iminoctadin, Iminoctadinalbesilat, Iminoctadintriacetat, Mankupfer, Mancozeb, Maneb, Metiram, Zinkmetiram, Kupfer-Oxin, Propamidin, Propineb, Schwefel und Schwefelzubereitungen wie beispielsweise Calciumpolysulfid, Thiram, Tolylfluanid, Zineb und Ziram, Anilazin, (F-12) resistance inducers such as acibenzolar-S-methyl, probenazole and tiadinil, isotianil, laminarin, (F-13) compounds having multisite activity such as Bordeaux mixture, captafol, captan, chlorothalonil, copper naphthenate, copper oxide, copper oxychloride, Copper Preparations such as Copper Hydroxide, Copper Sulfate, Dichlofluanid, Dithianone, Dodine and its Free Base, Ferbam, Fluorofolpet, Folpet, Guazatin, Guazatin Acetate, Iminoctadine, Iminoctadinal Besilate, Iminoctadine Triacetate, Mancopper, Mancozeb, Maneb, Metiram, Zinc Metiram, Copper Oxine, Propamidine, Propineb , Sulfur and sulfur preparations such as calcium polysulfide, thiram, tolylfluanid, zineb and ziram, anilazine,
(F-14) Weitere Verbindungen, wie beispielsweise 2,3-Dibutyl-6-chlorthieno[2,3-d]pyrimidin-4(3H)-on, (2Z)-3 -Amino-2-cyano-3 -phenylprop-2-ensäureethylester, N- [2-( 1 ,3 -Dimethylbutyl)phenyl] -5 -fluor- 1 ,3- dimethyl- lH-pyrazol-4-carboxamid, 3-(Difluormethyl)- 1 -methyl-N-(3 ',4',5'-trifluorbiphenyl-2-yl)- 1H- pyrazol-4-carboxamid, 3-(Difluormethyl)-N-[4-fluor-2-(l , 1 ,2,3,3, 3-hexafluorpropoxy)phenyl]-l -me- thyl-lH-pyrazol-4-carboxamid, (2£')-2-(2- {[6-(3-Chlor-2-methylphenoxy)-5-fluorpyrimidin-4- yl]oxy}phenyl)-2-(methoxyimino)-N-methylethanamid, (2£')-2- {2-[( {[(2£',3£')-4-(2,6-Dichlor- phenyl)but-3-en-2-yliden]amino} oxy)methyl]phenyl} -2-(methoxyimino)-N-methylethanamid, N-(3- Ethyl-3,5,5-trimethylcyclohexyl)-3-(formylamino)-2-hydroxybenzamid, 5-Methoxy-2-methyl-4-(2- { [( {( 1 - [3 -(trifluormethyl)phenyl] ethyliden} amino)oxy]methyl} phenyl)-2,4-dihydro-3H- 1 ,2,4- triazol-3-οη, (2£')-2-(Methoxyimino)-N-methyl-2-(2- {[( {(l£')-l -[3-(trifluormethyl)phenyl]ethyl- iden} amino)oxy]methyl}phenyl)ethanamid, (2£')-2-(Methoxyimino)-N-methyl-2- {2-[E-( { 1 -[3-(F-14) Other compounds such as 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidin-4 (3H) -one, (2Z) -3-amino-2-cyano-3-phenylprop 2-enoic acid ethyl ester, N- [2- (1, 3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -1-methyl-N- (3 ', 4', 5'-trifluorobiphenyl-2-yl) -1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -N- [4-fluoro-2- (1,1,2,3,3 , 3-hexafluoropropoxy) phenyl] -1-methyl-1H-pyrazole-4-carboxamide, (2'-1 ' ) -2- [2- {[6- (3-chloro-2-methylphenoxy) -5-fluoropyrimidine 4-yl] oxy} phenyl) -2- (methoxyimino) -N-methylethaneamide, (2'l ' ) -2- {2 - [({[(2 £ ' , 3 £ ' ) -4- (2, 6-dichlorophenyl) but-3-en-2-ylidene] amino} oxy) methyl] phenyl} -2- (methoxyimino) -N-methylethaneamide, N- (3-ethyl-3,5,5-trimethylcyclohexyl) -3- (formylamino) -2-hydroxybenzamide, 5-methoxy-2-methyl-4- (2- {[({(1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) - 2,4-dihydro-3H-1, 2,4-triazol-3-one, (2'-1 ' ) -2- (methoxyimino) -N-methyl-2- (2- {[({(l £ '' ) -l - [3- (trifluoromethyl) phe nyl] ethylidene} amino) oxy] methyl} phenyl) ethanamide, (2'- ' ) -2- (methoxyimino) -N-methyl-2- {2- [E- ({1 - [3-
(trifluormethyl)phenyl]ethoxy} imino)methyl]phenyl} ethanamid, (2E)-2- {2- [( { [( E)- 1 -(3 - { [(E)- 1 -Fluor- 2-phenylethenyl] oxy } phenyl)ethyliden] amino } oxy)methyl]phenyl} -2-(methoxyimino)-N-methyl- ethanamid, 1 -(2,2-Dimethyl-2,3-dihydro- 1 Η-inden- 1 -yl)- lH-imidazol-5-carbonsaeuremethylester, N'- {5-(Difluormethyl)-2-methyl-4-[3-(trimethylsilyl)propoxy]phenyl} -N-ethyl-N-methylimidoformamid, 0- { l -[(4-Methoxyphenoxy)methyl]-2,2-dimethylpropyl} lH-imidazol-l -carbothioat, N-[2-(4- {[3-(4- Chlorphenyl)prop-2-yn-l -yl]oxy} -3-methoxyphenyl)ethyl]-N2-(methylsulfonyl)valinamid, 5-Amino- 1 ,3,4-thiadiazol-2-thiol, Propamocarb-Fosetyl, 1 -[(4-Methoxyphenoxy)methyl]-2,2-dimethylpropyl 1H- imidazol-l-carboxylat, 2,3,5, 6-Tetrachlor-4-(methylsulfonyl)pyridin, 2-Butoxy-6-iod-3-propyl-4H- chromen-4-οη, 2-Phenylphenol und dessen Salze, 3,4,5-Trichlorpyridin-2,6-dicarbonitril, 3-[5-(4- Chlorphenyl)-2,3-dimethylisoxazolidin-3-yl]pyridin, 3-Chlor-5-(4-chlorphenyl)-4-(2,6-difluorphenyl)-6- methylpyridazin, 4-(4-Chlorphenyl)-5-(2,6-difluorphenyl)-3,6-dimethylpyridazin, 8-Hydroxychinolin, 8- Hydroxychinolinsulfat, Tebufloquin, 5-Methyl-6-octyl-3,7-dihydro[l ,2,4]triazolo[l ,5-a]pyrimidin-7- amin, 5-Ethyl-6-octyl-3,7-dihydro[l,2,4]triazolo[l,5-a]pyrimidin-7-amin, Ametoctradin, Benthiazol, Bethoxazin, Capsimycin, Carvon, Chinomethionat, Cufraneb, Cyflufenamid, Cymoxanil, Cyprosulfamide, Dazomet, Debacarb, Dichlorophen, Diclomezin, Difenzoquat, Difenzoquat Methylsulphat, Diphenylamin, Ecomat, Flumetover, Fluoromid, Flusulfamid, Flutianil, Fosetyl- Aluminium, Fosetyl-Calcium, Fosetyl-Natrium, Hexachlorbenzol, Irumamycin, Methasulfocarb, (2E)-2- {2-[({Cyclopropyl[(4-methoxyphenyl)imino]methyl}thio)methyl]phenyl}-3-methoxyacrylsaeure- methylester, Methylisothiocyanat, Metrafenon, (5-Chlor-2-methoxy-4-methylpyridin-3-yl)(2,3,4- trimethoxy-6-methylphenyl)methanon, Mildiomycin, Tolnifanid, N-(4-Chlorbenzyl)-3-[3-methoxy-4- (prop-2-yn-l-yloxy)phenyl]propanamid, N-[(4-Chlorphenyl)(cyano)methyl]-3-[3-methoxy-4-(prop-2- yn-l-yloxy)phenyl]propanamid, N-[(5-Brom-3-chlorpyridin-2-yl)methyl]-2,4-dichlorpyridin-3- carboxamid, N-[l-(5-Brom-3-chlorpyridin-2-yl)ethyl]-2,4-dichlorpyridin-3-carboxamid, N-[l-(5-Brom-(trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} ethanamide, (2E) -2- {2- [({[(E) -1- (3 - {[(E) -1-fluoro-2-phenylethenyl ] oxy} phenyl) ethylidene] amino} oxy) methyl] phenyl} -2- (methoxyimino) -N-methyl-ethanamide, 1- (2,2-dimethyl-2,3-dihydro-1 Η-indene-1 - yl) - lH-imidazole-5-carboxylic acid methyl ester, N '- {5- (difluoromethyl) -2-methyl-4- [3- (trimethylsilyl) propoxy] phenyl} -N-ethyl-N-methylimidoformamide, 0- {l - [(4-methoxyphenoxy) methyl] -2,2-dimethylpropyl} -1H-imidazole-1-carbothioate, N- [2- (4- {[3- (4-chlorophenyl) -prop-2-yn-1-yl ] oxy} -3-methoxyphenyl) ethyl] -N 2 - (methylsulfonyl) valinamide, 5-amino-1, 3,4-thiadiazole-2-thiol, propamocarb-fosetyl, 1 - [(4-methoxyphenoxy) methyl] - 2,2-dimethylpropyl 1H- imidazole-1-carboxylate, 2,3,5,6-tetrachloro-4- (methylsulfonyl) pyridine, 2-butoxy-6-iodo-3-propyl-4H-chromen-4-one, 2-phenylphenol and its salts, 3,4,5-trichloropyridine-2,6-dicarbonitrile, 3- [5- (4-chlorophenyl) -2,3-dimethylisoxazolidin-3-yl] pyridine, 3-chloro-5- (4-chlorophenyl) -4 - (2,6-difluorophenyl) -6-methylpyridazine, 4- (4-chlorophenyl) -5- (2,6-difluorophenyl) -3,6-dimethylpyridazine, 8-hydroxyquinoline, 8-hydroxyquinoline sulfate, tebufloquine, 5-methyl -6-octyl-3,7-dihydro [l, 2,4] triazolo [l, 5-a] pyrimidine-7-amine, 5-ethyl-6-octyl-3,7-dihydro [l, 2,4 ] triazolo [l, 5-a] pyrimidin-7-amine, ametoctradine, benthiazole, bethoxazine, capsimycin, carvone, quinomethionate, cufraneb, cyflufenamid, cymoxanil, cyprosulfamide, dazomet, debacarb, dichlorophen, diclomethine, difenzoquat, difenzoquat methylsulphate, diphenylamine, Ecomat, flumetover, fluoromide, flusulfamide, flutianil, fosetyl-aluminum, fosetyl-calcium, fosetyl-sodium, hexachlorobenzene, irumamycin, methasulfocarb, (2E) -2- {2 - [({cyclopropyl [(4-methoxyphenyl) imi methyl] thio) methyl] phenyl} -3-methoxyacrylic acid methyl ester, methyl isothiocyanate, metrafenone, (5-chloro-2-methoxy-4-methylpyridin-3-yl) (2,3,4-trimethoxy-6-methylphenyl ) methanone, mildiomycin, tolnifanide, N- (4-chlorobenzyl) -3- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] propanamide, N - [(4-chlorophenyl) (cyano) methyl] -3- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] propanamide, N - [(5-bromo-3-chloropyridin-2-yl) methyl] -2,4- dichloropyridine-3-carboxamide, N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl] -2,4-dichloropyridine-3-carboxamide, N- [1- (5-bromo)
3- chlorpyridin-2-yl)ethyl]-2-fluor-4-iodpyridin-3-carboxamid, N- {( )-[(Cyclopropylmethoxy)imino][6- (difluormethoxy)-2,3-difluorphenyl]methyl} -2-phenylacetamid, N- {(£')-[(Cyclopropylmethoxy)imino] [6-(difluormethoxy)-2,3-difluorphenyl]methyl}-2-phenylacetamid, Natamycin, Nickel Dimethyl- dithiocarbamat, Nitrothal-Isopropyl, Octhilinone, Oxamocarb, Oxyfenthiin, Pentachlorphenol und dessen Salze, Phenazin-1 -carbonsäure, Phenothrin, Phosphorsäure und deren Salze, Propamocarb Fosetylat, Propanosin-Natrium, Proquinazid, Pyrrolnitrin, S-Prop-2-en-l-yl 5-amino-2-(l-methylethyl)-3-chloropyridin-2-yl) ethyl] -2-fluoro-4-iodopyridine-3-carboxamide, N- {() - [(cyclopropylmethoxy) imino] [6- (difluoromethoxy) -2,3-difluorophenyl] methyl} -2-phenylacetamide, N- {(ε ' ) - [(cyclopropylmethoxy) imino] [6- (difluoromethoxy) -2,3-difluorophenyl] methyl} -2-phenylacetamide, natamycin, nickel dimethyldithiocarbamate, nitrothal isopropyl, Octhilinone, oxamocarb, oxyfenthiine, pentachlorophenol and its salts, phenazine-1-carboxylic acid, phenothrin, phosphoric acid and its salts, propamocarb fosetylate, propanosine sodium, proquinazide, pyrrolnitrin, S-prop-2-en-l-yl 5-amino 2- (l-methylethyl) -
4- (2-methylphenyl)-3-oxo-2,3-dihydro-lH-pyrazol-l-carbothioat, Tecloftalam, Triazoxid, Trichlamid,4- (2-methylphenyl) -3-oxo-2,3-dihydro-1H-pyrazole-1-carbothioate, tecloftalam, triazoxide, trichlamide,
5- Chlor-N'-phenyl-N'-prop-2-yn- 1 -ylthiophen-2-sulfonohydrazid, Zarilamid, N-Methyl-2-(l - { [5- methyl-3-(trifluormethyl)-lH-pyrazol-l-yl]acetyl}piperidin-4-yl)-N-[(lR)-l,2,3,4-tetrahydronaphthalen- l-yl]-l,3-thiazol-4-carboxamid, N-Methyl-2-(l- {[5-methyl-3-(trifluormethyl)-lH-pyrazol-l- yl]acetyl}piperidin-4-yl)-N-(l ,2,3,4-tetrahydronaphthalen-l-yl)-l,3-thiazol-4-carboxamid, 3-(Difluor- methyl)-N- [4-fluor-2-( 1 , 1 ,2,3 ,3 ,3 -hexafluorpropoxy)phenyl] - 1 -methyl- lH-pyrazol-4-carboxamid und Pentyl- {6-[( { [(1 -methyl-lH-tetrazol-5-yl)(phenyl)methyliden]amino} oxy)methyl]pyridin-2- yljcarbamat, Pyriofenon (Chlazafenon), Fenpyrazamin, Pyrimorph, (2E)-3-(4-ert-butylphenyl)-3-(2- chloropyridin-4-yl)-l-(morpholin-4-yl)prop-2-en-l-one, (2Z)-3-(4-tert-butylphenyl)-3-(2-chloropyridin- 4-yl)-l -(morpholin-4-yl)prop-2-en-l-one, (3S,6S,7R,8R)-8-benzyl-3-[({3-[(iso-butyryloxy)methoxy]-4- methoxypyridin-2-yl}carbonyl)amino]-6-methyl-4,9-dioxo-l,5-dioxonan-7-yl 2-methylpropanoate, l-(4- {4-[(5R)-5-(2,6-difluorophenyl)-4,5-dihydro-l,2-oxazol-3-yl]-l,3-thiazol-2-yl}piperidin-l -yl)-2-[5- methyl-3-(trifluoromethyl)-lH-pyrazol-l -yl]ethanone, l-(4- {4-[(5S)-5-(2,6-difluorophenyl)-4,5- dihydro- 1 ,2-oxazol-3 -yl] - 1 ,3 -thiazol-2-yl} piperidin- 1 -yl)-2- [5-methyl-3 -(trifluoromethyl)- 1 H-pyrazol- l-yl]ethanone, l-(4- {4-[5-(2,6-difluorophenyl)-4,5-dihydro-l,2-oxazol-3-yl]-l,3-thiazol-2-yl}piperidin- 1 -yl)-2- [5-methyl-3 -(trifluoromethyl)- 1 H-pyrazol- 1 -yl] ethanone, 1 -(4-methoxyphenoxy)-3 ,3 - dimethylbutan-2-yl lH-imidazole-l-carboxylate, 2,3,5,6-tetrachloro-4-(methylsulfonyl)pyridine, 2,3- dibutyl-6-chlorothieno[2,3-d]pyrimidin-4(3H)-one, 2,6-dimethyl-lH,5H-[l,4]dithiino[2,3-c:5,6- c']dipyrrole-l,3,5,7(2H,6H)-tetrone, 2-[5-methyl-3-(trifluoromethyl)-lH-pyrazol-l-yl]-l-(4- {4-[(5R)-5- phenyl-4,5-dihydro-l,2-oxazol-3-yl]-l,3-thiazol-2-yl}piperidin-l-yl)ethanone, 2-[5-methyl-3- (trifluoromethyl) H-pyrazol-l-yl]-l-(4- {4-[(5S)-5-phenyl-4,5-dihydro-l,2-oxazol-3-yl]-l,3-tW yl}piperidin-l -yl)ethanone, 2-[5-methyl-3-(trifluoromethyl)-lH-pyrazol-l-yl]-l- {4-[4-(5-phenyl-4,5- dihydro-l,2-oxazol-3-yl)-l,3-thiazol-2-yl]piperidin-l -yl} ethanone, 2-butoxy-6-iodo-3-propyl-4H- chromen-4-one, 2-chloro-5-[2-chloro-l-(2,6-difluoro-4-methoxyphenyl)-4-methyl-lH-imidazol-5- yl]pyridine, 2-phenylphenol und Salze, 3-(4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-l- yl)quinoline, 3,4,5-trichloropyridine-2,6-dicarbonitrile, 3-chloro-5-(4-chlorophenyl)-4-(2,6- difluorophenyl)-6-methylpyridazine, 4-(4-chlorophenyl)-5-(2,6-difluorophenyl)-3,6-dimethylpyridazine, 5-amino-l,3,4-thiadiazole-2-thiol, 5-chloro-N'-phenyl-N'-(prop-2-yn-l-yl)thiophene-2- sulfonohydrazide, 5-fluoro-2-[(4-fluorobenzyl)oxy]pyrimidin-4-amine, 5-fluoro-2-[(4- methylbenzyl)oxy]pyrimidin-4-amine, 5-methyl-6-octyl[l ,2,4]triazolo[ 1 ,5-a]pyrimidin-7-amine, ethyl (2Z)-3-amino-2-cyano-3-phenylacrylate, N'-(4- {[3-(4-chlorobenzyl)-l,2,4-thiadiazol-5-yl]oxy}-2,5- dimethylphenyl)-N-ethyl-N-methylimidoformamide, N-(4-chlorobenzyl)-3-[3-methoxy-4-(prop-2-yn-l- yloxy)phenyl]propanamide, N- [(4-chlorophenyl)(cyano)methyl] -3 - [3 -methoxy-4-(prop-2-yn- 1 - yloxy)phenyl]propanamide, N- [(5-bromo-3 -chloropyridin-2-yl)methyl] -2,4-dichloronicotinamide, N- [ 1 - (5-bromo-3-chloropyridin-2-yl)ethyl]-2,4-dichloronicotinamide, N-[l-(5-bromo-3-chloropyridin-2- yl)ethyl]-2-fluoro-4-iodonicotinamide, N- {(E)-[(cyclopropylmethoxy)imino][6-(difluoromethoxy)-2,3- difluorophenyl]methyl} -2-phenylacetamide, N- {(Z)-[(cyclopropylmethoxy)imino] [6-(difluoromethoxy)- 2,3-difluorophenyl]methyl} -2-phenylacetamide, N'- {4-[(3-tert-butyl-4-cyano-l,2-thiazol-5-yl)oxy]-2- chloro-5-methylphenyl}-N-ethyl-N-methylimidoformamide, N-methyl-2-(l- {[5-methyl-3-(trifluoro- methyl)-lH-pyrazol-l-yl]acetyl}piperidin-4-yl)-N-(l ,2,3,4-tetrahydronaphthalen-l-yl)-l,3-thiazole-4- carboxamide, N-methyl-2-( 1 - { [5-methyl-3 -(trifluoromethyl)- 1 H-pyrazol- 1 -yl] acetyl} piperidin-4-yl)-N- [( 1 R)- 1 ,2,3 ,4-tetrahydronaphthalen- 1 -yl] - 1 ,3 -thiazole-4-carboxamide, N-methyl-2-( 1 - { [5-methyl-3 - (trifluoromethyl)- 1 H-pyrazol- 1 -yl] acetyl} piperidin-4-yl)-N- [(1S)-1 ,2,3 ,4-tetrahydronaphthalen- 1 -yl] - l,3-thiazole-4-carboxamide, pentyl {6-[({[(l -methyl-lH-tetrazol-5-yl)(phenyl)methylene]amino} oxy)methyl]pyridin-2-yl}carbamate, phenazine-l-carboxylic acid, quinolin-8-ol, quinolin-8-ol sulfate (2: 1), tert-butyl {6- [( { [( 1 -methyl- 1 H-tetrazol-5-yl)(phenyl)methylene] amino } oxy)methyl]pyridin-2- yljcarbamate, l-methyl-3-(trifluoromethyl)-N-[2'-(trifluoromethyl)biphenyl-2-yl]-lH-pyrazole-4- carboxamide, N-(4'-chlorobiphenyl-2-yl)-3 -(difluoro-methyl)- 1 -methyl- 1 H-pyrazole-4-carboxamide, N- (2',4'-dichlorobiphenyl-2-yl)-3-(difluoromethyl)-l -methyl- lH-pyrazole-4-carboxamide, 3-(difluoro- methyl)- l-methyl-N-[4'-(trifluoromethyl)biphenyl-2-yl]-lH-pyrazole-4-carboxamide, N-(2',5'-difluoro- biphenyl-2-yl)-l-methyl-3-(trifluoromethyl)-lH-pyrazole-4-carboxamide, 3-(difluoromethyl)-l-methyl- N- [4'-(prop- 1 -yn- 1 -yl)biphenyl-2-yl] - 1 H-pyrazole-4-carboxamide, 5-fluoro- 1 ,3 -dimethyl-N- [4'-(prop- 1 - yn- 1 -yl)biphenyl-2-yl] - 1 H-pyrazole-4-carboxamide, 2-chloro-N- [4'-(prop- 1 -yn- 1 -yl)biphenyl-2- yl]nicotinamide, 3 -(difluoromethyl)-N- [4'-(3 ,3 -dimethylbut- 1 -yn- 1 -yl)biphenyl-2-yl] - 1 -methyl- 1 H- pyrazole-4-carboxamide, N-[4'-(3,3-dimethylbut-l-yn-l-yl)biphenyl-2-yl]-5-fluoro-l,3-dimethyl-lH- pyrazole-4-carboxamide, 3-(difluoromethyl)-N-(4'-ethynylbiphenyl-2-yl)-l-methyl-lH-pyrazole-4- carboxamide, N-(4'-ethynylbiphenyl-2-yl)-5-fluoro-l,3-dimethyl-lH-pyrazole-4-carboxamide, 2-chloro- N-(4'-ethynylbiphenyl-2-yl)nicotinamide, 2-chloro-N-[4'-(3,3-dimethylbut-l-yn-l-yl)biphenyl-2- yl]nicotinamide, 4-(difluoromethyl)-2-methyl-N-[4'-(trifluoromethyl)biphenyl-2-yl]-l,3-thiazole-5- carboxamide, 5-fluoro-N- [4'-(3 -hydroxy-3 -methylbut- 1 -yn- 1 -yl)biphenyl-2-yl] - 1 ,3-dimethyl- 1 H- pyrazole-4-carboxamide, 2-chloro-N- [4'-(3 -hydroxy-3 -methylbut- l-yn-l -yl)biphenyl-2-yl]nicotinamide, 3 -(difluoromethyl)-N- [4'-(3 -methoxy-3 -methylbut- 1 -yn- 1 -yl)biphenyl-2-yl] - 1 -methyl- 1 H-pyrazole-4- carboxamide, 5-fluoro-N- [4'-(3 -methoxy-3 -methylbut- 1 -yn- 1 -yl)biphenyl-2-yl] - 1 ,3-dimethyl- 1 H- pyrazole-4-carboxamide, 2-chloro-N- [4'-(3 -methoxy-3 -methylbut- 1 -yn- 1 -yl)biphenyl-2-yl]nicotinamide, (5-bromo-2-methoxy-4-methylpyridin-3-yl)(2,3,4-trimethoxy-6-methylphenyl)methanone, N-[2-(4- {[3- (4-chlorophenyl)prop-2-yn- 1 -yl] oxy } -3 -methoxyphenyl)ethyl] -N2-(methylsulfonyl)valinamide, 4-oxo- 4-[(2-phenylethyl)amino]butanoic acid, but-3-yn-l -yl {6-[({[(Z)-(l-methyl-lH-tetrazol-5- yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamate, 4-amino-5-fluoropyrimidin-2-ol (tautomeric form: 4-amino-5-fluoropyrimidin-2(lH)-one), propyl 3,4,5-trihydroxybenzoate, 1,3- dimethyl-N-(l ,l,3-trimethyl-2,3-dihydro-lH-inden-4-yl)-lH-pyrazole-4-carboxamide, 1,3-dimethyl-N- [(3R)-l,l,3-trimethyl-2,3-dihydro-lH-inden-4-yl]-lH-pyrazole-4-carboxamide, l,3-dimethyl-N-[(3S)- l,l,3-trimethyl-2,3-dihydro-lH-inden-4-yl]-lH-pyrazole-4-carboxamide, [3-(4-chloro-2-fluorophenyl)- 5-(2,4-difluorophenyl)-l,2-oxazol-4-yl](pyridin-3-yl)methanol, (S)-[3-(4-chloro-2-fluorophenyl)-5-(2,4- difluorophenyl)-l,2-oxazol-4-yl](pyridin-3-yl)methanol, (R)-[3-(4-chloro-2-fluorophenyl)-5-(2,4- difluorophenyl)-l,2-oxazol-4-yl](pyridin-3-yl)methanol, 2- {[3-(2-chlorophenyl)-2-(2,4-difluorophenyl) oxiran-2-yl]methyl}-2,4-dihydro-3H-l,2,4-triazole-3-thione, l- {[3-(2-chlorophenyl)-2-(2,4-difluoro- phenyl)oxiran-2-yl]methyl} - 1 H- 1 ,2,4-triazol-5-yl thiocyanate, 5-(allylsulfanyl)- 1 - { [3 -(2-chlorophenyl)- 2-(2,4-difluorophenyl)oxiran-2-yl]methyl} -lH-l,2,4-triazole, 2-[l-(2,4-dichlorophenyl)-5-hydroxy- 2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-l,2,4-triazole-3-thione, 2- {[rel(2R,3S)-3-(2-chlorophenyl)- 2-(2,4-difluorophenyl)oxiran-2-yl]methyl} -2,4-dihydro-3H-l,2,4-triazole-3-thione, 2- {[rel(2R,3R)-3-(2- chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-l,2,4-triazole-3-thione, 1- {[rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-lH-l,2,4-triazol-5-yl thiocyanate, 1 - { [rel(2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl} - 1 H- 1 ,2,4- triazol-5-yl thiocyanate, 5-(allylsulfanyl)-l - {[rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluoro- phenyl)oxiran-2-yl]methyl} - 1 H- 1 ,2,4-triazole, 5-(allylsulfanyl)- 1 - { [rel(2R,3R)-3-(2-chlorophenyl)-2- (2,4-difluorophenyl)oxiran-2-yl]methyl}-lH-l,2,4-triazole, 2-[(2S,4S,5S)-l-(2,4-dichlorophenyl)-5- hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-l,2,4-triazole-3-thione, 2-[(2R,4S,5S)-l-(2,4- dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H- 1 ,2,4-triazole-3 -thione, 2- [(2R,4R,5R)- 1 -(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H- 1 ,2,4- triazole-3-thione, 2-[(2S,4R,5R)-l-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4- dihydro-3H-l,2,4-triazole-3-thione, 2-[(2S,4S,5R)-l-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethyl- heptan-4-yl]-2,4-dihydro-3H-l,2,4-triazole-3-thione, 2-[(2R,4S,5R)-l-(2,4-dichlorophenyl)-5-hydroxy- 2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-l,2,4-triazole-3-thione, 2-[(2R,4R,5S)-l-(2,4-dichloro- phenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-l,2,4-triazole-3-thione, 2-[(2S,4R,5S)-5-Chloro-N'-phenyl-N'-prop-2-yn-1-yl-thiophene-2-sulfonohydrazide, zarilamide, N-methyl-2- (1 - {[5-methyl-3- (trifluoromethyl) -lH pyrazol-1-yl] acetyl} piperidin-4-yl) -N - [(1R) -l, 2,3,4-tetrahydronaphthalen-1-yl] -1,3-thiazole-4-carboxamide, N- Methyl 2- (1- {[5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -acetyl} -piperidin-4-yl) -N- (1,2,3,4-tetrahydronaphthalene-1 -yl) -l, 3-thiazole-4-carboxamide, 3- (difluoromethyl) -N- [4-fluoro-2- (1,1,3,3,3,3-hexafluoropropoxy) phenyl] -1 -methyl-1H-pyrazole-4-carboxamide and pentyl {6 - [({[(1-methyl-1H-tetrazol-5-yl) (phenyl) -methylidene] -amino} -oxy) -methyl] -pyridin-2-yl-carbamate, Pyriofenone (Chlazafenone), Fenpyrazamine, Pyrimorph, (2E) -3- (4-tert-butylphenyl) -3- (2-chloropyridin-4-yl) -1- (morpholin-4-yl) prop-2-ene 1-one, (2Z) -3- (4-tert-butylphenyl) -3- (2-chloropyridin-4-yl) -1- (morpholin-4-yl) prop-2-en-1-one, 3S, 6S, 7R, 8R) -8-benzyl-3 - [({3 - [(isobutyrylxy) methoxy] -4-methoxypyridin-2-yl} carbonyl) amino] -6-methyl-4,9- dioxo-l, 5-dioxonan-7-yl 2-methylpropanoate, 1- (4- {4- [(5R) -5- (2,6-difluorophenyl) -4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) -2 - [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] ethanone, 1- (4- {4 - [(5S) -5- (2,6-difluorophenyl) -4,5-dihydro - 1,2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl ] ethanone, 1- (4- {4- [5- (2,6-difluorophenyl) -4,5-dihydro-l, 2-oxazol-3-yl] -l, 3-thiazol-2-yl} piperidine - 1 -yl) -2- [5-methyl-3 - (trifluoromethyl) -1-H-pyrazol-1-yl] ethanone, 1- (4-methoxyphenoxy) -3,3-dimethylbutan-2-yl 1H-imidazole 1-Carboxylates, 2,3,5,6-tetrachloro-4- (methylsulfonyl) pyridines, 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidin-4 (3H) -ones, 2,6- dimethyl-1H, 5H- [1,4] dithiino [2,3-c: 5,6- c '] dipyrrole-l, 3,5,7 (2H, 6H) -tetrone, 2- [5-methyl- 3- (trifluoromethyl) -1H-pyrazol-1-yl] -1- (4- {4 - [(5R) -5-phenyl-4,5-dihydro-1,2-oxazol-3-yl] -l , 3-thiazol-2-yl} piperidin-1-yl) ethanone, 2- [5-methyl-3- (trifluoromethyl) -H-pyrazol-1-yl] -l- (4- {4 - [(5S) 5-phenyl-4,5-dihydro-1,2-oxazol-3-yl] -1,3-t-yl-1-piperidin-1-yl) ethanone, 2- [5-methyl-3- (trifluoromethyl) - 1H-pyrazol-1-yl] -1- {4- [4- (5-phenyl-4,5-dihydro-1,2-oxazol-3-yl) -l, 3-thiazol-2-yl] -piperidine -l -yl) ethanone, 2-butoxy-6-iodo-3-propyl-4H-chromen-4-one, 2-chloro-5- [2-chloro-1- (2,6-difluoro-4-methoxyphenyl ) -4-methyl-1H-imidazol-5-yl] pyridines, 2-phenylphenol and salts, 3- (4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl) quinolines , 3,4,5-tric chloropyridines-2,6-dicarbonitriles, 3-chloro-5- (4-chlorophenyl) -4- (2,6-difluorophenyl) -6-methylpyridazine, 4- (4-chlorophenyl) -5- (2,6-difluorophenyl ) -3,6-dimethylpyridazines, 5-amino-l, 3,4-thiadiazole-2-thiol, 5-chloro-N'-phenyl-N '- (prop-2-yn-1-yl) -thiophene-2 - sulfonohydrazides, 5-fluoro-2 - [(4-fluorobenzyl) oxy] pyrimidin-4-amines, 5-fluoro-2 - [(4-methylbenzyl) oxy] pyrimidin-4-amine, 5-methyl-6-octyl [l, 2,4] triazolo [1,5-a] pyrimidin-7-amine, ethyl (2Z) -3-amino-2-cyano-3-phenylacrylate, N '- (4- {[3- (4 -chlorobenzyl) -1,2,4-thiadiazol-5-yl] oxy} -2,5-dimethylphenyl) -N-ethyl-N-methylimidoformamide, N- (4-chlorobenzyl) -3- [3-methoxy-4 - (prop-2-yn-1-yloxy) phenyl] propanamide, N- [(4-chlorophenyl) (cyano) methyl] -3 - [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] propanamide, N- [(5-bromo-3-chloropyridin-2-yl) methyl] -2,4-dichloronicotinamide, N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl] - 2,4-dichloronicotinamide, N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl] -2-fluoro-4-iodonicotinamide, N- {(E) - [(cyclopropylmet hoxy) imino] [6- (difluoromethoxy) -2,3-difluorophenyl] methyl} -2-phenylacetamide, N- {(Z) - [(cyclopropylmethoxy) imino] [6- (difluoromethoxy) -2,3-difluorophenyl] methyl} -2-phenylacetamide, N '- {4 - [(3-tert-butyl-4-cyano-1,2-thiazol-5-yl) oxy] -2-chloro-5-methylphenyl} -N-ethyl N-methylimidoformamide, N-methyl-2- (1-{[5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] acetyl} piperidin-4-yl) -N- (1, 2,3,4-tetrahydronaphthalene-1-yl) -l, 3-thiazole-4-carboxamide, N-methyl-2- (1 - {[5-methyl-3 - (trifluoromethyl)-1H-pyrazole-1 -yl] acetyl} piperidin-4-yl) -N- [(1 R) -1,2,3,4-tetrahydronaphthalene-1-yl] -1,3-thiazole-4-carboxamide, N-methyl-2 - (1 - {[5-methyl-3 - (trifluoromethyl) -1-H-pyrazol-1-yl] -acetyl} -piperidin-4-yl) -N- [(1S) -1,3,3,4-tetrahydronaphthalene 1 -yl] -1,3-thiazole-4-carboxamide, pentyl {6 - [({[(1-methyl-1H-tetrazol-5-yl) (phenyl) methylene] amino} oxy) methyl] pyridine 2-yl} carbamate, phenazine-1-carboxylic acid, quinolin-8-ol, quinolin-8-ol sulfate (2: 1), tert-butyl {6- [({[( 1-methyl-1H-tetrazol-5-yl) (phenyl) methylene] amino} oxy) methyl] pyridin-2-ylcarbamate, 1-methyl-3- (trifluoromethyl) -N- [2 '- (trifluoromethyl) biphenyl -2-yl] -1H-pyrazole-4-carboxamide, N- (4'-chlorobiphenyl-2-yl) -3- (difluoro-methyl) -1-methyl-1H-pyrazole-4-carboxamide, N- (2 ', 4'-dichlorobiphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -1-methyl-N- [4'- (trifluoromethyl) biphenyl-2-yl] -1H-pyrazoles-4-carboxamides, N- (2 ', 5'-difluorobiphenyl-2-yl) -1-methyl-3- (trifluoromethyl) -1H-pyrazole- 4-carboxamides, 3- (difluoromethyl) -1-methyl-N- [4 '- (prop-1 -yn-1-yl) biphenyl-2-yl] -1 H -pyrazole-4-carboxamide, 5-fluoro - 1, 3 -dimethyl-N- [4 '- (prop-1 - yn-1-yl) biphenyl-2-yl] -1-H-pyrazole-4-carboxamide, 2-chloro-N- [4 '- (prop-1-yn-1-yl) biphenyl-2-yl] nicotinamide , 3 - (difluoromethyl) -N- [4 '- (3,3-dimethylbut-1 -yn-1-yl) biphenyl-2-yl] -1-methyl-1H-pyrazole-4-carboxamide, N- [4 '- (3,3-dimethylbut-1-yn-1-yl) biphenyl-2-yl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, 3- (difluoromethyl) - N- (4'-ethynyl-biphenyl-2-yl) -l-methyl-1H-pyrazole-4-carboxamide, N- (4'-ethynyl-biphenyl-2-yl) -5-fluoro-1,3-dimethyl-1H pyrazole-4-carboxamides, 2-chloro-N- (4'-ethynyl-biphenyl-2-yl) nicotinamide, 2-chloro-N- [4 '- (3,3-dimethylbut-1-yn-1-yl) biphenyl -2-yl] nicotinamide, 4- (difluoromethyl) -2-methyl-N- [4 '- (trifluoromethyl) biphenyl-2-yl] -1,3-thiazole-5-carboxamide, 5-fluoro-N- [ 4 '- (3-hydroxy-3-methylbut-1 -yn-1-yl) biphenyl-2-yl] - 1, 3-dimethyl-1H-pyrazole-4-carboxamide, 2-chloro-N- [4 '- (3-hydroxy-3-methylbut-1-yn-1-yl) biphenyl-2-yl] nicotinamide, 3 - (difluoromethyl) -N- [4' - (3-methoxy-3-methylbut-1 - yn-1-yl) biphenyl-2-yl] -1-meth yl-1H-pyrazole-4-carboxamide, 5-fluoro-N- [4 '- (3-methoxy-3-methylbut-1-yl-1-yl) biphenyl-2-yl] -1,3-dimethyl 1-H-pyrazole-4-carboxamide, 2-chloro-N- [4 '- (3-methoxy-3-methylbut-1-yn-1-yl) biphenyl-2-yl] nicotinamide, (5-bromo- 2-methoxy-4-methylpyridin-3-yl) (2,3,4-trimethoxy-6-methylphenyl) methanone, N- [2- (4- {[3- (4-chlorophenyl) prop-2-yn] 1 -yl] oxy} -3-methoxyphenyl) ethyl] -N 2 - (methylsulfonyl) valinamide, 4-oxo-4 - [(2-phenylethyl) amino] butanoic acid, but-3-yn-1-yl {6- [({[(Z) - (1-methyl-1H-tetrazol-5-yl) (phenyl) methylene] amino} oxy) methyl] pyridin-2-yl} carbamate, 4-amino-5-fluoropyrimidine-2-yl ol (tautomeric form: 4-amino-5-fluoropyrimidine-2 (1H) -one), propyl 3,4,5-trihydroxybenzoate, 1,3-dimethyl-N- (1, l, 3-trimethyl-2,3 -dihydro-1H-inden-4-yl) -LH-pyrazole-4-carboxamide, 1,3-dimethyl-N- [(3R) -l, l, 3-trimethyl-2,3-dihydro-1H-indene 4-yl] -1H-pyrazole-4-carboxamide, 1,3-dimethyl-N - [(3S) -1,3,1-trimethyl-2,3-dihydro-1H-inden-4-yl] - 1H-pyrazole-4-carboxamides, [3- (4-chloro-2-fluorop henyl) - 5- (2,4-difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) methanol, (S) - [3- (4-chloro-2-fluorophenyl) -5 - (2,4-difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) methanol, (R) - [3- (4-chloro-2-fluorophenyl) -5- (2, 4-difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) -methanol, 2- {[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl ] methyl} -2,4-dihydro-3H-l, 2,4-triazole-3-thionene, l- {[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxirane-2 -yl] methyl} - 1 H-1, 2,4-triazol-5-yl thiocyanate, 5- (allylsulfanyl) -1 - {[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxirane -2-yl] methyl} -LH-1, 2,4-triazoles, 2- [1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2, 4-dihydro-3H-l, 2,4-triazoles-3-thiones, 2- {[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxirane-2] yl] methyl} -2,4-dihydro-3H-l, 2,4-triazole-3-thionene, 2- {[rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4 -difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-l, 2,4-triazole-3-thionene, 1- {[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -LH-l, 2,4-triazol-5-yl thiocyanate, 1 - {[rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxirane-2] yl] methyl} -1 H -1, 2,4-triazol-5-yl thiocyanate, 5- (allylsulfanyl) -1 - {[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2 , 4-difluorophenyl) oxiran-2-yl] methyl} -1 H -1, 2,4-triazole, 5- (allylsulfanyl) -1 - {[rel (2R, 3R) -3- (2-chlorophenyl ) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-l, 2,4-triazole, 2 - [(2S, 4S, 5S) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-l, 2,4-triazole-3-thione, 2 - [(2R, 4S, 5S) -l - (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazole-3-thionene, 2- [( 2R, 4R, 5R) - 1 - (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1, 2,4- triazole-3-thiones, 2 - [(2S, 4R, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro- 3H-l, 2,4-triazole-3-thionene, 2 - [(2S, 4S, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptane-4 -yl] -2,4-dihydro-3H-l, 2,4-triazole-3-thionene, 2 - [(2R, 4S, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2 , 6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1, 2,4-triazole-3-thione, 2 - [(2R, 4R, 5S) -l- (2,4-) dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-l, 2,4-triazole-3-thione, 2 - [(2S, 4R, 5S) -
1- (2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethym^ 1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethymethylene
2- fluoro-6-(trifluoromethyl)-N-(l ,l,3 rimethyl-2,3-dihydro-lH-inden-4-yl)benzamide, 2-(6-benzyl- pyridin-2-yl)quinazoline, 2- [6-(3 -fluoro-4-methoxyphenyl)-5 -methylpyridin-2-yl] quinazoline, 3 -(4,4- difluoro-3 ,3 -dimethyl-3 ,4-dihydroisoquinolin- 1 -yl)quinoline, Abscisic acid, 3 -(difluoromethyl)-N- methoxy-l-methyl-N-[l-(2,4,6-trichlorophenyl)propan-2-yl]-lH-pyrazole-4-carboxamide, N'-[5-bromo- 6-(2,3-dihydro-lH-inden-2-yloxy)-2-methylpyridin-3-yl]-N-ethyl-N-methylimidoformami N'- {5- bromo-6-[l -(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoform N'- {5-bromo-6-[(lR)-l-(3,5-difluorophenyl)ethoxy]-2-m  2-fluoro-6- (trifluoromethyl) -N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -benzamide, 2- (6-benzylpyridin-2-yl) quinazolines , 2- [6- (3-Fluoro-4-methoxyphenyl) -5-methylpyridin-2-yl] quinazolines, 3 - (4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinolin- 1-yl ) quinoline, abscisic acid, 3 - (difluoromethyl) -N-methoxy-1-methyl-N- [1- (2,4,6-trichlorophenyl) propan-2-yl] -1H-pyrazole-4-carboxamide, N '- [5-bromo-6- (2,3-dihydro-1H-inden-2-yloxy) -2-methylpyridin-3-yl] -N-ethyl-N-methylimidoformamide N' - {5-bromo-6 - [1- (3,5-difluorophenyl) ethoxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoform N '- {5-bromo-6 - [(1R) -l- (3, 5-difluorophenyl) ethoxy] -2-m
amide, N'- {5-bromo-6-[(l S)-l-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N- methylimidoformamide, N'- {5-bromo-6-[(cis-4-isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl} -N- ethyl-N-methylimidoformamide, N'- {5-bromo-6-[(trans-4-isopropylcyclohexyl)oxy]-2-methylpyridin-3- yl}-N-ethyl-N-methylimidoformamide, N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-isopropyl- benzyl)-l-methyl-lH-pyrazole-4-carboxamide, N-cyclopropyl-N-(2-cyclopropylbenzyl)-3-(difluoro- methyl)-5-fluoro-l-methyl-lH-pyrazole-4-carboxamide, N-(2-tert-butylbenzyl)-N-cyclopropyl-3- (difluoromethyl)-5-fluoro- 1 -methyl- 1 H-pyrazole-4-carboxamide, N-(5-chloro-2-ethylbenzyl)-N- cyclopropyl-3-(difluoromethyl)-5-fluoro-l -methyl-lH-pyrazole-4-carboxamide, N-(5-chloro-2- isopropylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-l-methyl-lH-pyrazole-4-carboxamide, N- cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-5-fluorobenzyl)-5-fluoro-l-methyl-lH-pyrazole-4- carboxamide, N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(5-fluoro-2-isopropylbenzyl)-l -methyl-lH- pyrazole-4-carboxamide, N-cyclopropyl-N-(2-cyclopropyl-5-fluorobenzyl)-3-(difluoromethyl)-5-fluoro- 1 -methyl- lH-pyrazole-4-carboxamide, N-(2-cyclopentyl-5-fluorobenzyl)-N-cyclopropyl-3- (difluoromethyl)-5-fluoro-l -methyl- lH-pyrazole-4-carboxamide, N-cyclopropyl-3-(difluoromethyl)-5- fluoro-N-(2-fluoro-6-isopropylbenzyl)-l -methyl- lH-pyrazole-4-carboxamide, N-cyclopropyl-3- (difluoromethyl)-N-(2-ethyl-5-methylbenzyl)-5-fluoro-l-methyl-lH-pyrazole-4-carboxamide, N- cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-isopropyl-5-methylbenzyl)-l-methyl-lH-pyrazole-4- carboxamide, N-cyclopropyl-N-(2-cyclopropyl-5-methylbenzyl)-3-(difluoromethyl)-5-fluoro-l-methyl- lH-pyrazole-4-carboxamide, N-(2-tert-butyl-5-methylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5- fluoro-1 -methyl- lH-pyrazole-4-carboxamide, N-[5-chloro-2-(trifluoromethyl)benzyl]-N-cyclopropyl-3- (difluoromethyl)-5-fluoro-l -methyl- lH-pyrazole-4-carboxamide, N-cyclopropyl-3-(difluoromethyl)-5- fluoro- 1 -methyl-N- [5-methyl-2-(trifluoromethyl)benzyl] - 1 H-pyrazole-4-carboxamide, N- [2-chloro-6- (trifluoromethyl)benzyl]-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-l-methyl-lH-pyrazole-4- carboxamide, N-[3-chloro-2-fluoro-6-(trifluoromethyl)benzyl]-N-cyclopropyl-3-(difluoromethyl)-5- fluoro- 1 -methyl- 1 H-pyrazole-4-carboxamide, N-cyclopropyl-3 -(difluoromethyl)-N-(2-ethyl-4,5- dimethylbenzyl)-5-fluoro-l -methyl-lH-pyrazole-4-carboxamide, N-cyclopropyl-3-(difluoromethyl)-5- fluoro-N-(2-isopropylbenzyl)-l -methyl- lH-pyrazole-4-carbothioamide, 3-(difluoromethyl)-N-(7-fluoro- 1 , 1 ,3-trimethyl-2,3-dihydro- 1 H-inden-4-yl)- 1 -methyl- 1 H-pyrazole-4-carboxamide, 3-(difluoromethyl)- N- [(3R)-7-fluoro- 1 , 1 ,3 -trimethyl-2,3 -dihydro- 1 H-inden-4-yl] - 1 -methyl- 1 H-pyrazole-4-carboxamide, 3 - (difluoromethyl)-N-[(3 S)-7-fluoro- 1 , 1 ,3-trimethyl-2,3-dihydro- 1 H-inden-4-yl]- 1 -methyl- 1 H-pyrazole-4- carboxamide. amide, N '- {5-bromo-6 - [(1S) -1- (3,5-difluorophenyl) ethoxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, N'- {5-bromo-6 - [(cis -4-isopropylcyclohexyl) oxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, N '- {5-bromo-6 - [(trans-4 -isopropylcyclohexyl) oxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopropylbenzyl) -1-methyl -lH-pyrazoles-4-carboxamides, N-cyclopropyl-N- (2-cyclopropylbenzyl) -3- (difluoro-methyl) -5-fluoro-1-methyl-1H-pyrazoles-4-carboxamides, N- (2- tert-butylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, N- (5-chloro-2-ethylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, N- (5-chloro-2-isopropylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl- 1H-pyrazole-4-carboxamides, N-cyclopropyl-3- (difluoromethyl) -N- (2-ethyl-5-fluorobenzyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, N-cyclopropyl- 3- (difluoromethyl) -5-fluoro N- (5-fluoro-2-isopropylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, N-cyclopropyl-N- (2-cyclopropyl-5-fluorobenzyl) -3- (difluoromethyl) -5-fluoro 1-methyl-1H-pyrazole-4-carboxamide, N- (2-cyclopentyl-5-fluorobenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide , N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-fluoro-6-isopropylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, N-cyclopropyl-3- (difluoromethyl) -N (2-ethyl-5-methylbenzyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopropyl-5-) methylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, N-cyclopropyl-N- (2-cyclopropyl-5-methylbenzyl) -3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4 carboxamides, N- (2-tert-butyl-5-methylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, N- [5-chloro 2- (trifluoromethyl) benzyl] -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, N-cyclopropyl-3- (difluoromet hyl) -5-fluoro-1-methyl-N- [5-methyl-2- (trifluoromethyl) benzyl] -1 H -pyrazole-4-carboxamide, N- [2-chloro-6- (trifluoromethyl) benzyl] - N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, N- [3-chloro-2-fluoro-6- (trifluoromethyl) benzyl] -N-cyclopropyl-3 - (difluoromethyl) -5- fluoro-1-methyl-1H-pyrazole-4-carboxamide, N-cyclopropyl-3 - (difluoromethyl) -N- (2-ethyl-4,5-dimethylbenzyl) -5-fluoro-1-methyl-1H-pyrazole 4-carboxamides, N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopropylbenzyl) -1-methyl-1H-pyrazole-4-carbothioamide, 3- (difluoromethyl) -N- (7 fluoro-1, 1, 3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1-methyl-1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -N- [(3R ) -7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1-methyl-1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -N - [(3S) -7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1-methyl-1H-pyrazole-4-carboxamide.
Die hier mit ihrem „common name" genannten Wirkstoffe sind bekannt und beispielsweise im Pestizidhandbuch („The Pesticide Manual" 16th Ed., British Crop Protection Council 201 1) beschrieben oder im Internet recherchierbar (z.B. http://www.alanwood.net/pesticides). The active substances mentioned here with their "common name" are known and are described, for example, in the Pesticide Handbook ("The Pesticide Manual" 16th Ed., British Crop Protection Council 201 1) or searchable on the Internet (eg http://www.alanwood.net/ pesticides).
Bevorzugte Verbindungen aus diesen Gruppen sind weiterhin: Preferred compounds from these groups are furthermore:
Azoxystrobin, Boscalid, Penflufen, Bixafen, Fluopyram, Carpropamid, Spiroxamin, Fluxapyroxad, Carbendazim, Carboxin, Fenamidon, Fludioxonil, Fluopicolid, Fluoxastrobin, Fluquinconazole, Flutriafol, Ipconazole, Iprodione, Isotianil, Mefenoxam, Metalaxyl, Metominostrobin, Pencycuron, Prochloraz, Prothioconazole, Pyraclostrobin, Pyrimethanil, Sedaxane, Silthiopham, Tebuconazole, Thiram, Tolylfluanid, Triadimenol, Triazoxide, Trifloxystrobin, Triflumuron und Triticonazole. Azoxystrobin, Boscalid, Penflufen, Bixafen, Fluopyram, Carpropamid, Spiroxamine, Fluxapyroxad, Carbendazim, Carboxin, Fenamidon, Fludioxonil, Fluopicolide, Fluoxastrobin, Fluquinconazole, Flutriafol, Ipconazole, Iprodione, Isotianil, Mefenoxam, Metalaxyl, Metominostrobin, Pencycuron, Prochloraz, Prothioconazole, Pyraclostrobin, Pyrimethanil, Sedaxane, Silthiopham, Tebuconazole, Thiram, Tolylfluanid, Triadimenol, Triazoxide, Trifloxystrobin, Triflumuron and Triticonazole.
Die Verbindungen Fluopyram, Fosetyl- Aluminium, Propamocarb Hydrochlorid, Propamocarb Fosetylat, Isotianil, Fluopicolid, Isotianil, Prothioconazol, Penflufen, Tebuconazol, Triadimenol, Pyrimethanil, Fenamidon, Metalaxyl, Dimethomorph, Cyazofamid und Azoxystrobin sind eine weitere bevorzugte Gruppe von Mischpartnern. The compounds fluopyram, fosetyl-aluminum, propamocarb hydrochloride, propamocarb fosetylate, isotianil, fluopicolide, isotianil, prothioconazole, penflufen, tebuconazole, triadimenol, pyrimethanil, fenamidone, metalaxyl, dimethomorph, cyazofamide and azoxystrobin are another preferred group of mixing partners.
Die Verbindungen Bixafen, Fluopyram, Prothioconazole, Tebuconazole, Trifloxystrobin, Fluoxastrobin, Spiroxamine, Metominostrobin, Fluopicolide, Propamocarb, Propineb, Fenamidone, Isothianil, Pencycuron, Prochloraz, Fluquinconazole, Fluxapyroxad, Isopyrazam, Penthiopyrad, Ametoctradin, Azoxystrobin, Pyraclostrobin, Epoxiconazole, Propiconazole, Cyproconazole, Boscalid, Proquinazid, Benthiavalicarb, Mancozeb, Metconazole, Chlorothalonil, Fluazinam, Difenoconazole, Tricyclazole, Picoxystrobin, Flutriafol, Cymoxanil, Thiophanat-methyl, Probenazole, Tetraconazole, Metalaxyl, Isoprothiolane, Cyprodinil, Metrafenone, Dimoxystrobin, Cyzofamid, Fenpropidin, Orysastrobin, Hymexazol, Validamycin, Gentamycin, Pyroquilon, Mandipropamid, Kasugamycin, Ferimzone, Maneb, Quinoxyfen und Carbendazim sind eine weitere bevorzugte Gruppe von Mischpartnern. The compounds Bixafen, Fluopyram, Prothioconazole, Tebuconazole, Trifloxystrobin, Fluoxastrobin, Spiroxamine, Metominostrobin, Fluopicolide, Propamocarb, Propineb, Fenamidone, Isothianil, Pencycuron, Prochloraz, Fluquinconazole, Fluxapyroxad, Isopyrazam, Penthiopyrad, Ametoctradin, Azoxystrobin, Pyraclostrobin, Epoxiconazole, Propiconazole, Cyproconazole, boscalid, proquinazide, benthiavalicarb, mancozeb, metconazole, chlorothalonil, fluazinam, difenoconazole, tricyclazole, picoxystrobin, flutriafol, cymoxanil, thiophanate-methyl, probenazoles, tetraconazoles, metalaxyl, isoprothiolanes, cyprodinil, metrafenone, dimoxystrobin, cyzofamide, fenpropidin, orysastrobin Hymexazole, validamycin, gentamycin, pyroquilon, mandipropamide, kasugamycin, ferimzone, maneb, quinoxyfen and carbendazim are another preferred group of mixing partners.
Besonders bevorzugt sind solche Wirkstoffkombinationen, in denen die Verbindung der Formel (I) mit den in der Tabelle A angegebenen Mischpartnern kombiniert ist. Die in der Tabelle angegebenen bevorzugten, besonders bevorzugten und ganz besonders bevorzugten Mischungsverhältnisse sind Gewichtsverhältnisse. Das Verhältnis ist jeweils zu verstehen als Verbindung der Formel (I) zu Mischpartner Nr.1 bis 5. Particularly preferred are those drug combinations in which the compound of formula (I) is combined with the mixing partners indicated in Table A. The preferred, particularly preferred and most preferred mixing ratios given in the table are weight ratios. The ratio is to be understood as the compound of formula (I) Mixing partner no. 1 to 5.
Jede einzelne der Wirkstoffkombinationen (Mischungen) Nr. 1 bis 5 ist eine bevorzugte Ausführungsform der vorliegenden Erfindung. Each of the drug combinations (mixtures) Nos. 1 to 5 is a preferred embodiment of the present invention.
Tabelle A: Table A:
Figure imgf000011_0001
Figure imgf000011_0001
Weitere bevorzugte Mischungsverhältnisse, in denen die Verbindung der Formel (I) mit den in der Tabelle A angegebenen Mischpartnern kombiniert ist, sind 2000:1 bis 1:2000, 1000:1 bis 1:1000, 750:1 bis 1:750, 500:1 bis 1:500, 250 : 1 bis 1 : 250, 200 : 1 bis 1 : 200, 100 : 1 bis 1 : 100, 95:1 bis 1:95, 90:1 bis 1:90, 85:1 bis 1:85, 80:1 bis 1:80, 75:1 bis 1:75, 70:1 bis 1:70, 65:1 bis 1:65, 60:1 bis 1:60, 55:1 bis 1:55, 45:1 bis 1:45, 40:1 bis 1:40, 35:1 bis 1:35, 30:1 bis 1:30, 20:1 bisl:20, 15:1 bis 1:15, 10:1 bis 1:10, 9:1 bis 1:9, 8:1 bis 1:8, 7:1 bis 1:7, 6:1 bis 1:64:1 bis 1:4, 3:1 bis 1:3, 2:1 bis 1:2, 1:1. Further preferred mixing ratios in which the compound of the formula (I) is combined with the mixing partners indicated in Table A are 2000: 1 to 1: 2000, 1000: 1 to 1: 1000, 750: 1 to 1: 750, 500 : 1 to 1: 500, 250: 1 to 1: 250, 200: 1 to 1: 200, 100: 1 to 1: 100, 95: 1 to 1:95, 90: 1 to 1:90, 85: 1 to 1:85, 80: 1 to 1:80, 75: 1 to 1:75, 70: 1 to 1:70, 65: 1 to 1:65, 60: 1 to 1:60, 55: 1 to 1 : 55, 45: 1 to 1:45, 40: 1 to 1:40, 35: 1 to 1:35, 30: 1 to 1:30, 20: 1 to 1:20, 15: 1 to 1:15, 10: 1 to 1:10, 9: 1 to 1: 9, 8: 1 to 1: 8, 7: 1 to 1: 7, 6: 1 to 1: 64: 1 to 1: 4, 3: 1 to 1: 3, 2: 1 to 1: 2, 1: 1.
Wenn im Rahmen dieser Beschreibung die Kurzform des„common name" eines Wirkstoffes verwendet wird, so sind damit jeweils alle gängigen Derivate, wie die Ester und Salze, und Isomere, insbesondere optische Isomere umfasst, insbesondere die handelsübliche Form bzw. Formen. Wird mit dem„common name" ein Ester oder Salz bezeichnet, so sind damit auch jeweils alle anderen gängigen Derivate wie andere Ester und Salze, die freien Säuren und Neutralverbindungen, und Isomere, insbesondere optische Isomere umfasst, insbesondere die handelsübliche Form bzw. Formen. Die angegebenen chemischen Verbindungsnamen bezeichnen zumindest eine der von dem„common name" umfassten Verbindungen, häufig eine bevorzugte Verbindung. Die erfindungsgemäßen Wirkstoffkombinationen eignen sich sehr gut zur Bekämpfung tierischer Schädlinge oder von unerwünschten Mikroorganismen. If the abbreviated form of the "common name" of an active ingredient is used in the context of this description, then all common derivatives, such as the esters and salts, and isomers, in particular optical isomers, are included, in particular the commercially available form or forms "Common name" denotes an ester or salt, so are all other common derivatives such as other esters and salts, the free acids and neutral compounds, and isomers, in particular optical isomers, in particular the commercial form or forms. The chemical compound names given refer to at least one of the compounds encompassed by the "common name", often a preferred compound The active compound combinations according to the invention are very suitable for controlling animal pests or undesired microorganisms.
Überraschenderweise ist die antimikrobielle Wirkung bzw. die fungizide Wirkung und / oder akarizide und / oder msektizide und / oder nematizide Wirkung und / oder die pflanzenstärkende und / oder ertragssteigernde Wirkung der erfindungsgemäßen Wirkstoffkombinationen wesentlich höher als die Summe der Wirkungen der einzelnen Wirkstoffe. Es liegt ein nicht vorhersehbarer echter synergistischer Effekt vor und nicht nur eine Wirkungsergänzung. Surprisingly, the antimicrobial action or the fungicidal action and / or acaricidal and / or insecticidal and / or nematicidal action and / or the plant-strengthening and / or yield-increasing action of the active compound combinations according to the invention is substantially higher than the sum of the effects of the individual active substances. There is an unpredictable true synergistic Effect before and not just an effect supplement.
Ferner können die erfindungsgemäßen, insbesondere die in der Tabelle A aufgeführten Wirkstoffkombinationen einen oder mehrere weitere Wirkstoffe aus den im Folgenden genannten Gruppen (1-1) bis (1-29) enthalten. (1-1) Acetylcholinesterase (AChE) Inhibitoren, wie beispielsweise Carbamate, z.B. Alanycarb, Aldicarb, Bendiocarb, Benfuracarb, Butocarboxim, Butoxycarboxim, Carbaryl, Carbofuran, Carbosulfan, Ethiofencarb, Fenobucarb, Formetanate, Furathiocarb, Isoprocarb, Methiocarb, Methomyl, Metolcarb, Oxamyl, Pirimicarb, Propoxur, Thiodicarb, Thiofanox, Triazamate, Trimethacarb, XMC und Xylylcarb oder organophosphate, z.B. Acephate, Azamethiphos, Azinphos-ethyl, Azinphos-methyl, Cadusafos, Chlorethoxyfos, Chlorfenvinphos, Chlormephos, Chlorpyrifos, Chlorpyrifos-methyl, Coumaphos, Cyanophos, Demeton-S-methyl, Diazinon, Dichlorvos/DDVP, Dicrotophos, Dimethoate, Dimethylvinphos, Disulfoton, EPN, Ethion, Ethoprophos, Famphur, Fenamiphos, Fenitrothion, Fenthion, Fosthiazate, Heptenophos, Imicyafos, Isofenphos, Isopropyl 0-(methoxyaminothio- phosphoryl) salicylat, Isoxathion, Malathion, Mecarbam, Methamidophos, Methidathion, Mevinphos, Monocrotophos, Naled, Omethoate, Oxydemeton-methyl, Parathion, Parathion-methyl, Phenthoate, Phorate, Phosalone, Phosmet, Phosphamidon, Phoxim, Pirimiphos-methyl, Profenofos, Propetamphos, Prothiofos, Pyraclofos, Pyridaphenthion, Quinalphos, Sulfotep, Tebupirimfos, Temephos, Terbufos, Tetrachlorvinphos, Thiometon, Triazophos, Triclorfon und Vamidothion. Furthermore, the active compound combinations according to the invention, in particular the active substance combinations listed in Table A, can contain one or more further active compounds from the groups (1-1) to (1-29) mentioned below. (1-1) Acetylcholinesterase (AChE) inhibitors such as carbamates, e.g. Alanycarb, Aldicarb, Bendiocarb, Benfuracarb, Butocarboxime, Butoxycarboxime, Carbaryl, Carbofuran, Carbosulfan, Ethiofencarb, Fenobucarb, Formetanate, Furathiocarb, Isoprocarb, Methiocarb, Methomyl, Metolcarb, Oxamyl, Pirimicarb, Propoxur, Thiodicarb, Thiofanox, Triazamate, Trimethacarb, XMC and Xylylcarb or organophosphates, eg Acephate, Azamethiphos, Azinophos-ethyl, Azinophos-methyl, Cadusafos, Chloroethoxyfos, Chlorfenvinphos, Chlormephos, Chlorpyrifos, Chlorpyrifos-methyl, Coumaphos, Cyanophos, Demeton-S-methyl, Diazinone, Dichlorvos / DDVP, Dicrotophos, Dimethoates, Dimethylvinphos, Disulfone, EPN, Ethion, Ethoprophos, Famphur, Fenamiphos, Fenitrothion, Fenthion, Fosthiazate, Heptenophos, Imicyafos, Isofenphos, Isopropyl O- (methoxyaminothiophosphoryl) salicylate, Isoxathione, Malathion, Mecarbam, Methamidophos, Methidathione, Mevinphos, Monocrotophos, Naled, Omethoate, Oxydemeton-methyl, Parathion, Parathion-methyl, Phenthoate, Phorate, Phosalone, Phosmet, Phosphamidon, Phoxim, Pirimiphos-methyl, Profenofos, Propetamphos, Prothiofos, Pyraclofos, Pyridaphenthion, Quinalphos, Sulfotep, Tebupirimfos, Temephos, Terbufos, Tetrachlorvinphos, Thiometon, Triazophos, triclorfone and vamidothion.
(1-2) GABA-gesteuerte Chlorid-Kanal- Antagonisten, wie beispielsweise Cyclodien-organochlorine, z.B. Chlordane und Endosulfan oder Phenylpyrazole (Fiprole), z.B. Ethiprole und Fipronil. (1-2) GABA-controlled chloride channel antagonists such as cyclodiene organochlorines, e.g. Chlordanes and endosulfan or phenylpyrazoles (fiproles), e.g. Ethiprole and fipronil.
(1-3) Natrium-Kanal-Modulatoren / Spannungsabhängige Natrium-Kanal-Blocker, wie beispielsweise Pyrethroide, z.B. Acrinathrin, Allethrin, d-cis-trans Allethrin, d-trans Allethrin, Bifenthrin, Bioallethrin, Bioallethrin S-cyclopentenyl Isomer, Bioresmethrin, Cycloprothrin, Cyfluthrin, beta-Cyfluthrin, Cyhalothrin, lambda-Cyhalothrin, gamma-Cyhalothrin, Cypermethrin, alpha-Cypermethrin, beta- Cypermethrin, theta-Cypermethrin, zeta-Cypermethrin, Cyphenothrin [(lR)-trans-Isomere], Deltamethrin, Empenthrin [(EZ)-(lR)-Isomere), Esfenvalerate, Etofenprox, Fenpropathrin, Fenvalerate, Flucythrinate, Flumethrin, tau-Fluvalinate, Halfenprox, Imiprothrin, Kadethrin, Permethrin, Phenothrin [(lR)-trans-Isomer), Prallethrin, Pyrethrine (pyrethrum), Resmethrin, Silafluofen, Tefluthrin, Tetramethrin, Tetramethrin [(1R)- Isomere)], Tralomethrin und Transfluthrin oder DDT oder Methoxychlor. (1-3) Sodium channel modulators / voltage dependent sodium channel blockers such as pyrethroids, e.g. Acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha- Cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [(lR) trans isomers], deltamethrin, empenthrin [(EZ) (lR) isomers], esfenvalerates, etofenprox, fenpropathrin, fenvalerates, flucythrinates, Flumethrin, tau-fluvalinate, halfenprox, imiprothrin, kadethrin, permethrin, phenothrin [(lR) -trans-isomer), prallethrin, pyrethrin (pyrethrum), resmethrin, silafluofen, tefluthrin, tetramethrin, tetramethrin [(1R) - isomer)], Tralomethrin and transfluthrin or DDT or methoxychlor.
(1-4) Nikotinerge Acetylcholin-Rezeptor (nAChR) Agonisten, wie beispielsweise Neonikotinoide, z.B. Acetamiprid, Clothianidin, Dinotefuran, Imidacloprid, Nitenpyram, Thiacloprid und Thiamethoxam oder Nikotin oder Sulfoxaflor oder Flupyradifurone. (1-5) Nikotinerge Acetylcholin-Rezeptor (nAChR) allosterische Aktivatoren, wie beispielsweise Spinosine, z.B. Spinetoram und Spinosad. (1-4) Nicotinergic acetylcholine receptor (nAChR) agonists such as neonicotinoids, eg acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam or nicotine or sulfoxaflor or flupyradifurone. (1-5) Nicotinergic acetylcholine receptor (nAChR) allosteric activators, such as spinosines, eg spinetoram and spinosad.
(1-6) Chlorid-Kanal-Aktivatoren, wie beispielsweise Avermectine/Milbemycine, z.B. Abamectin, Emamectin-benzoat, Lepimectin und Milbemectin. (1-7) Juvenilhormon-Imitatoren, wie beispielsweise Juvenilhormon-Analoge, z.B. Hydroprene, Kinoprene und Methoprene oder Fenoxycarb oder Pyriproxyfen. (1-6) chloride channel activators, such as avermectins / milbemycins, e.g. Abamectin, Emamectin benzoate, Lepimectin and Milbemectin. (1-7) Juvenile hormone mimics, such as juvenile hormone analogs, e.g. Hydroprene, Kinoprene and Methoprene or Fenoxycarb or Pyriproxyfen.
(1-8) Wirkstoffe mit unbekannten oder nicht spezifischen Wirkmechanismen, wie beispielsweise Alkylhalide, z.B. Methylbromid und andere Alkylhalide; oder Chloropicrin oder Sulfurylfluorid oder Borax oder Brechweinstein. (1-9) Selektive Fraßhemmer, z.B. Pymetrozine oder Flonicamid. (1-8) Agents with unknown or nonspecific modes of action, such as alkyl halides, e.g. Methyl bromide and other alkyl halides; or chloropicrin or sulfuryl fluoride or borax or tartar emetic. (1-9) Selective feeding inhibitors, e.g. Pymetrozine or flonicamide.
(1-10) Milbenwachstumsinhibitoren, z.B. Clofentezine, Hexythiazox und Diflovidazin oder Etoxazole. (1-10) mite growth inhibitors, e.g. Clofentezine, hexythiazox and diflovidazine or etoxazole.
(11) Mikrobielle Disruptoren der Insektendarmmembran, z.B. Bacillus thuringiensis Subspezies israelensis, Bacillus sphaericus, Bacillus thuringiensis Subspezies aizawai, Bacillus thuringiensis Subspezies kurstaki, Bacillus thuringiensis Subspezies tenebrionis und BT Pflanzenproteine: CrylAb, CrylAc, CrylFa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34/35Abl . (11) Insect intestinal membrane microbial disruptors, e.g. Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies tenebrionis and BT plant proteins: CrylAb, CrylAc, CrylFa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34 / 35Abl.
(1-12) Inhibitoren der oxidativen Phosphorylierung, ATP-Disruptoren, wie beispielsweise Diafenthiuron oder Organozinnverbindungen, z.B. Azocyclotin, Cyhexatin und Fenbutatin-oxid oder Propargite oder Tetradifon. (1-12) Inhibitors of oxidative phosphorylation, ATP disruptors such as diafenthiuron or organotin compounds, e.g. Azocyclotin, Cyhexatin and Fenbutatin-oxide or Propargite or Tetradifon.
(1-13) Entkoppler der oxidativen Phoshorylierung durch Unterbrechung des H-Protongradienten, wie beispielsweise Chlorfenapyr, DNOC und Sulfluramid. (1-13) Decoupling of oxidative phosphorylation by interruption of the H proton gradient, such as chlorfenapyr, DNOC, and sulfluramide.
(1-14) Nikotinerge Acetylcholin-Rezeptor- Antagonisten, wie beispielsweise Bensultap, Cartap- hydrochlorid, Thiocyclam und Thiosultap-Natrium. (1-14) Nicotinergic acetylcholine receptor antagonists such as Bensultap, Cartap hydrochloride, Thiocyclam, and Thiosultap Sodium.
(1-15) Inhibitoren der Chitinbiosynthese, Typ 0, wie beispielsweise Bistrifluron, Chlorfluazuron, Diflubenzuron, Flucycloxuron, Flufenoxuron, Hexaflumuron, Lufenuron, Novaluron, Noviflumuron, Teflubenzuron und Triflumuron. (1-15) Type 0 inhibitors of chitin biosynthesis, such as bistrifluron, chlorofluorazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron and triflumuron.
(1-16) Inhibitoren der Chitinbiosynthese, Typ 1, wie beispielsweise Bupro fezin. (1-16) Inhibitors of chitin biosynthesis, type 1, such as Bupro fezin.
(1-17) Häutungsstörende Wirkstoffe, Dipteran, wie beispielsweise Cyromazine. (1-17) Moulting agents, dipteran, such as cyromazine.
(1-18) Ecdyson-Rezeptor Agonisten, wie beispielsweise Chromafenozide, Halofenozide, Methoxyfenozide und Tebufenozide. (1-19) Oktopaminerge Agonisten, wie beispielsweise Amitraz. (1-18) Ecdysone receptor agonists, such as chromafenozides, halofenozides, methoxyfenozides, and tebufenozides. (1-19) Octopaminergic agonists, such as amitraz.
(1-20) Komplex-III-Elektronentransportinhibitoren, wie beispielsweise Hydramethylnon oder Acequinocyl oder Fluacrypyrim. (1-20) complex III electron transport inhibitors such as hydramethylnone or acequinocyl or fluacrypyrim.
(1-21) Komplex-I-Elektronentransportinhibitoren, beispielsweise METI-Akarizide, z.B. Fenazaquin, Fenpyroximate, Pyrimidifen, Pyridaben, Tebufenpyrad und Tolfenpyrad oder Rotenone (Derris). (1-21) Complex I electron transport inhibitors, for example, METI acaricides, e.g. Fenazaquin, Fenpyroximate, Pyrimidifen, Pyridaben, Tebufenpyrad and Tolfenpyrad or Rotenone (Derris).
(1-22) Spannungsabhängige Natriumkanal-Blocker, z.B. Indoxacarb oder Metaflumizone. (1-22) voltage dependent sodium channel blockers, e.g. Indoxacarb or metaflumizone.
(1-23) Inhibitoren der Acetyl-CoA-Carboxylase, wie beispielsweise Tetron- und Tetramsäurederivate, z.B. Spirodiclofen, Spiromesifen und Spirotetramat. (1-23) inhibitors of acetyl-CoA carboxylase, such as tetronic and tetramic acid derivatives, e.g. Spirodiclofen, spiromesifen and spirotetramat.
(1-24) Komplex-IV-Elektronentransportinhibitoren, wie beispielsweise Phosphine, z.B. Aluminiumphosphid, Calciumphosphid, Phosphin und Zinkphosphid oder Cyanid. (1-24) Complex IV electron transport inhibitors such as phosphines, e.g. Aluminum phosphide, calcium phosphide, phosphine and zinc phosphide or cyanide.
(1-25) Komplex-II-Elektronentransportinhibitoren, wie beispielsweise Cyenopyrafen und Cyflumetofen. (1-25) Complex II electron transport inhibitors such as cyenopyrafen and cyflumetofen.
(1-28) Ryanodinrezeptor-Effektoren, wie beispielsweise Diamide, z.B. Chlorantraniliprole, Cyantraniliprole und Flubendiamide, (1-28) ryanodine receptor effectors such as diamides, e.g. Chlorantraniliprole, Cyantraniliprole and Flubendiamide,
(1-29) Weitere Wirkstoffe mit unbekanntem Wirkmechanismus, wie beispielsweise Afidopyropen, Azadirachtin, Benclothiaz, Benzoximate, Bifenazate, Bromopropylate, Chinomethionat, Cryolite, Dicofol, Diflovidazin, Fluensulfone, Flometoquin, Flufenerim, Flufenoxystrobin, Flufiprole, Fluopyram, Flupyradifurone, Fufenozide, Heptafluthrin, Imidaclothiz, Iprodione, Meperfluthrin, Paichongding, Pyflubumide, Pyrifluquinazon, Pyriminostrobin, Tetramethylfluthrin und lodmethan; desweiteren Präparate auf Basis von Bacillus firmus (1-1582, BioNem, Votivo) , sowie folgende bekannte wirksame Verbindungen:3-Brom-N- {2-brom-4-chlor-6-[(l-cyclopropylethyl)carbamoyl]phenyl}-l-(3- chlorpyridin-2-yl)-lH-pyrazol-5-carboxamid (bekannt aus WO2005/077934) und 1 - {2-Fluor-4-methyl- 5-[(2,2,2-trifluorethyl)sulfinyl]phenyl} -3-(trifluormethyl)-lH-l,2,4-triazol-5-amin (bekannt aus WO2006/043635), {l'-[(2E)-3-(4-Chlorphenyl)prop-2-en-l-yl]-5-fluorspiro[indol-3,4'-piperidin]-l(2H)- yl}(2-chlorpyridin-4-yl)methanon (bekannt aus WO2003/106457), 2-Chlor-N-[2- {l-[(2E)-3-(4- chlorphenyl)prop-2-en-l-yl]piperidin-4-yl}-4-(trifluormethyl)phenyl]isonicotinamid (bekannt aus WO2006/003494), 3-(2,5-Dimethylphenyl)-4-hydroxy-8-methoxy-l,8-diazaspiro[4.5]dec-3-en-2-on (bekannt aus WO2009/049851), 3-(2,5-Dimethylphenyl)-8-methoxy-2-oxo-l,8-diazaspiro[4.5]dec-3-en-(1-29) Other agents with unknown mechanism of action, such as afidopyropene, azadirachtin, benclothiaz, benzoximate, bifenazate, bromopropylate, quinomethionate, cryolite, dicofol, diflovidazine, fluensulfone, flometoquine, flufenerim, flufenoxystrobin, flufiprole, fluopyram, flupyradifurone, fufenocide, heptafluthrin , Imidaclothiz, iprodione, meperfluthrin, paichongding, pyflubumide, pyrifluquinazone, pyriminostrobin, tetramethylfluthrin and iodomethane; furthermore preparations based on Bacillus firmus (1-1582, BioNem, Votivo), and the following known active compounds: 3-bromo-N- {2-bromo-4-chloro-6 - [(1-cyclopropylethyl) carbamoyl] phenyl} -l- (3-chloropyridin-2-yl) -1H-pyrazole-5-carboxamide (known from WO2005 / 077934) and 1 - {2-fluoro-4-methyl-5 - [(2,2,2-trifluoroethyl ) sulfinyl] phenyl} -3- (trifluoromethyl) -1H-l, 2,4-triazol-5-amine (known from WO2006 / 043635), {1 '- [(2E) -3- (4-chlorophenyl) prop -2-en-1-yl] -5-fluorospiro [indole-3,4'-piperidin] -1 (2H) -yl} (2-chloropyridin-4-yl) -methanone (known from WO2003 / 106457), 2 Chloro-N- [2- {1 - [(2E) -3- (4-chlorophenyl) prop-2-en-1-yl] piperidin-4-yl} -4- (trifluoromethyl) phenyl] isonicotinamide (known from WO2006 / 003494), 3- (2,5-dimethylphenyl) -4-hydroxy-8-methoxy-1,8-diazaspiro [4.5] dec-3-en-2-one (known from WO2009 / 049851), 3 - (2,5-dimethylphenyl) -8-methoxy-2-oxo-l, 8-diazaspiro [4.5] dec-3-ene
4- yl-ethylcarbonat (bekannt aus WO2009/049851), 4-(But-2-in-l-yloxy)-6-(3,5-dimethylpiperidin-l-yl)-4-yl ethyl carbonate (known from WO2009 / 049851), 4- (but-2-yn-1-yloxy) -6- (3,5-dimethylpiperidin-1-yl) -
5- fluorpyrimidin (bekannt aus WO2004/099160), 4-(But-2-in-l-yloxy)-6-(3-chlorphenyl)pyrimidin (bekannt aus WO2003/076415), PF1364 (CAS-Reg.No. 1204776-60-2), 4-[5-(3,5-Dichlorphenyl)-5-5-fluoropyrimidine (known from WO2004 / 099160), 4- (but-2-yn-1-yloxy) -6- (3-chlorophenyl) pyrimidine (known from WO2003 / 076415), PF1364 (CAS reference No. 1204776) -60-2), 4- [5- (3,5-dichlorophenyl) -5-
(trifluormethyl)-4,5-dihydro-l,2-oxazol-3-yl]-2-methyl-N- {2-oxo-2-[(2,2,2- trifluorethyl)amino]ethyl}benzamid (bekannt aus WO2005/085216), 4- {5-[3-Chlor-5- (trifluormethyl)phenyl]-5-(trifluormethyl)-4,5-dihydro- 1 ,2-oxazol-3-yl} -N- {2-oxo-2-[(2,2,2- trifluorethyl)amino]ethyl}-l -naphthamid (bekannt aus WO2009/002809), Methyl-2-[2-({[3-brom-l-(3- chlorpyridin-2-yl)-lH-pyrazol-5-yl]carbonyl}amino)-5-chlor-3-methylbenzoyl]-2- methylhydrazincarboxylat (bekannt aus WO2005/085216), Methyl-2-[2-({[3-brom-l-(3-chlorpyridin-2- yl)- 1 H-pyrazol-5-yl]carbonyl} amino)-5-cyan-3-methylbenzoyl] -2-ethylhydrazincarboxylat (bekannt aus WO2005/085216), Methyl-2-[2-({[3-brom-l-(3-chlorpyridin-2-yl)-lH-pyrazol-5-yl]carbonyl}amino)-5- cyan-3-methylbenzoyl]-2-methylhydrazincarboxylat (bekannt aus WO2005/085216), Methyl-2-[3,5- dibrom-2-( { [3 -brom- 1 -(3-chlorpyridin-2-yl)- 1 H-pyrazol-5-yl]carbonyl} amino)benzoyl]-2- ethylhydrazincarboxylat (bekannt aus WO2005/085216), l-(3-Chlorpyridin-2-yl)-N-[4-cyan-2-methyl- 6-(methylcarbamoyl)phenyl]-3- {[5-(trifluormethyl)-2H-tetrazol-2-yl]methyl} -lH-pyrazol-5-carboxamid (bekannt aus WO2010/069502), N-[2-(5-Amino-l,3,4-thiadiazol-2-yl)-4-chlor-6-methylphenyl]-3-brom- l-(3-chlorpyridin-2-yl)-lH-pyrazol-5-carboxamid (bekannt aus CN102057925), 3-Chlor-N-(2- cyanpropan-2-yl)-N- [4-( 1 , 1,1,2,3 ,3 ,3 -heptafluorpropan-2-yl)-2-methylphenyl]phthalamid (bekannt aus WO2012/034472), 8-Chlor-N-[(2-chlor-5-methoxyphenyl)sulfonyl]-6-(trifluormethyl)imidazo[l,2- a]pyridin-2-carboxamid (bekannt aus WO2010/129500), 4-[5-(3,5-Dichlorphenyl)-5-(trifluormethyl)- 4,5-dihydro-l,2-oxazol-3-yl]-2-methyl-N-(l-oxidothietan-3-yl)benzamid (bekannt aus(trifluoromethyl) -4,5-dihydro-l, 2-oxazol-3-yl] -2-methyl-N- {2-oxo-2 - [(2,2,2-trifluoroethyl) amino] ethyl} benzamide ( known from WO2005 / 085216), 4- {5- [3-chloro-5- (trifluoromethyl) phenyl] -5- (trifluoromethyl) -4,5-dihydro-1,2-oxazol-3-yl} - N - {2-oxo-2 - [(2,2,2-trifluoroethyl) amino] ethyl} -l-naphthamide (known from WO2009 / 002809), methyl 2- [2 - ({[3-bromo-1- (3-chloropyridin-2-yl) -1H-pyrazol-5-yl] carbonyl} amino) -5-chloro-3-methylbenzoyl] -2-methylhydrazinecarboxylate (known from WO2005 / 085216), methyl 2- [2 - ({[3-bromo-1- (3-chloropyridin-2-yl) -1 H-pyrazol-5-yl] carbonyl} amino) -5-cyano-3-methylbenzoyl] -2-ethylhydrazinecarboxylate (known from WO2005 / 085216), methyl 2- [2- ({[3-bromo-1-one 3-chloropyridin-2-yl) -1H-pyrazol-5-yl] carbonyl} amino) -5-cyano-3-methylbenzoyl] -2-methylhydrazinecarboxylate (known from WO2005 / 085216), methyl 2- [3,5 dibromo-2- ({[3-bromo-1 - (3-chloropyridin-2-yl) -1-H-pyrazol-5-yl] carbonyl} amino) benzoyl] -2-ethylhydrazinecarboxylate (known from WO2005 / 085216) , 1- (3-Chloropyridin-2-yl) -N- [4-cyano-2-methyl-6- (methylcarbamoyl) phenyl] -3- {[5- (trifluoromethyl) -2H-tetrazol-2-yl] methyl} -1H-pyrazole-5-carboxamide (known from WO2010 / 069502), N- [2- (5-amino-1, 3,4-thiadiazol-2-yl) -4-chloro-6-methylphenyl] -3-bromo-1- (3-chloropyridin-2-yl) -1H-pyrazole-5-carboxamide (known from CN102057925), 3 Chloro-N- (2-cyano-propan-2-yl) -N- [4- (1,1,1,2,3,3,3-heptafluoropropan-2-yl) -2-methyl-phenyl] -phthalamide (known from WO2012 / 034472), 8-chloro-N - [(2-chloro-5-methoxyphenyl) sulfonyl] -6- (trifluoromethyl) imidazo [1,2-a] pyridine-2-carboxamide (known from WO2010 / 129500), 4- [5- (3,5-dichlorophenyl) -5- (trifluoromethyl) -4,5-dihydro-1,2-oxazol-3-yl] -2-methyl-N- (1-oxidothietan-3-yl ) benzamide (known from
WO2009/080250), 4-[5-(3,5-Dichlorphenyl)-5-(trifluormethyl)-4,5-dihydro-l,2-oxazol-3-yl]-2-methyl- N-(l-oxidothietan-3-yl)benzamid (bekannt aus WO2012/029672), l-[(2-Chlor-l,3-thiazol-5-yl)methyl]- 4-oxo-3-phenyl-4H-pyrido[l,2-a]pyrimidin-l-ium-2-olat (bekannt aus WO2009/099929), l-[(6- Chlo^yridin-3-yl)methyl]-4-oxo-3-phenyl-4H-pyrido[l,2-a]pyrimidin-l-ium-2-olat (bekannt aus WO2009/099929), (5S,8R)-l-[(6-Chlorpyridin-3-yl)methyl]-9-nitro-2,3,5,6,7,8-hexahydro-lH-5,8- epoxyimidazo[l,2-a]azepin (bekannt aus WO2010/069266), (2E)-l-[(6-Chlorpyridin-3-yl)methyl]-N'- nitro-2-pentylidenhydrazincarboximidamid (bekannt aus WO2010/060231), 4-(3- {2,6-Dichlor-4-[(3,3- dichlorprop-2-en-l-yl)oxy]phenoxy}propoxy)-2-methoxy-6-(trifluormethyl)pyrimidin (bekannt aus CN101337940), N-[2-(tert-Butylcarbamoyl)-4-chlor-6-methylphenyl]-l-(3-chlorpyridin-2-yl)-3- (fluormethoxy)-lH-pyrazol-5-carboxamid (bekannt aus WO2008/134969). WO2009 / 080250), 4- [5- (3,5-dichlorophenyl) -5- (trifluoromethyl) -4,5-dihydro-1,2-oxazol-3-yl] -2-methyl-N- (1) oxidothietan-3-yl) benzamide (known from WO2012 / 029672), 1 - [(2-chloro-1,3-thiazol-5-yl) methyl] -4-oxo-3-phenyl-4H-pyrido [l, 2-a] pyrimidin-1-ium-2-olate (known from WO2009 / 099929), 1 - [(6-chloro-3-yl-yl) methyl] -4-oxo-3-phenyl-4H-pyrido [ l, 2-a] pyrimidin-l-ium-2-olate (known from WO2009 / 099929), (5S, 8R) -1 - [(6-chloropyridin-3-yl) methyl] -9-nitro-2, 3,5,6,7,8-hexahydro-1H-5,8-epoxyimidazo [1,2-a] azepine (known from WO2010 / 069266), (2E) -l - [(6-chloropyridin-3-yl ) methyl] -N'-nitro-2-pentylidenehydrazinecarboximidamide (known from WO2010 / 060231), 4- (3- {2,6-dichloro-4 - [(3,3-dichloroprop-2-en-1-yl) oxy] phenoxy} propoxy) -2-methoxy-6- (trifluoromethyl) pyrimidine (known from CN101337940), N- [2- (tert-butylcarbamoyl) -4-chloro-6-methylphenyl] -1- (3-chloropyridine) 2-yl) -3- (fluoromethoxy) -1H-pyrazole-5-carboxamide (known from WO2008 / 134969).
Bevorzugte Verbindungen aus diesen Gruppen sind: Preferred compounds from these groups are:
Flometoquin, Pyflubumide, Acrinathrin, Alpha- Cypermethrin, Beta-Cyfluthrin, Cyhalothrin, Cypermethrin, Deltamethrin, Esfenvalerat, Etofenprox, Flucythrinat, Lambda-Cyhalothrin, Gamma- Cyhalothrin, Tau-fluvalinat, Transfluthrin, Zeta-Cypermethrin, Cyfluthrin, Bifenthrin, Tefluthrin, Eflusilanat, Fubfenprox, Imidacloprid, Acetamiprid, Thiamethoxam, Nitenpyram, Thiacloprid, Dinotefuran, Clothianidin, Imidaclothiz, Chlorfluazuron, Diflubenzuron, Lufenuron, Teflubenzuron, Triflumuron, Novaluron, Flufenoxuron, Hexaflumuron, Bistrifluoron, Noviflumuron, Buprofezin, Cyromazine, Methoxyfenozide, Tebufenozide, Halofenozide, Chromafenozide, Fipronil, Ethiprole, Pyrafluprole, Pyriprole, Flubendiamide, Chlorantraniliprole (Rynaxypyr), Cyantraniliprole (Cyazypyr), Emamectin, Emamectin benzoate, Abamectin, Ivermectin, Milbemectin, Lepimectin, Tebufenpyrad, Fenpyroximat, Pyridaben, Fenazaquin, Pyrimidifen, Tolfenpyrad, Dicofol, Cyenopyrafen, Cyflumetofen, Acequinocyl, Fluacrypyrin, Bifenazate, Diafenthiuron, Etoxazole, Clofentezine, Spinosad, Triarathen, Propargit, Bromopropylat, Pyrifluquinazone, Pymetrozine, Flonicamid, Pyriproxyfen, Diofenolan, Chlorfenapyr, Metaflumizone, Indoxacarb, Chlorpyrifos, Spirodiclofen, Spiromesifen, Spirotetramat, Pyridalyl, Spinetoram, Acephate, Profenofos, Flupyradifurone, Thiodicarb, Methiocarb, Sulfoxaflor, l-[2-Fluoro-4-methyl-5-[(2,2,2-trifluoroethyl) sulfinyl]phenyl]-3- (trifluoromethyl)-lH-l,2,4 riazol-5-amin,l-(3-Chlorpyridinyl)-N-[4-cyano-2-methyl-6- [(methylamino)carbonyl]phenyl]-3-[[5-(trifluoromethyl)-2H-tetrazol-2-yl]methyl]-lH-pyrazole-5- carboxamid, Fluensulfone, Fluopyram. Femer kann die Verbindungen der Formel (I) mit folgenden Herbiziden gemischt werden. Gleiches gilt für die erfindungsgemäßen Mischungen, insbesondere für solche, die in Tabelle A aufgeführt sind, welche ebenfalls mit den folgenden Herbiziden gemischt und auf Pflanzen oder Pflanzenteile angewandt werden können. In vielen Fällen weisen diese Mischungen mit Herbiziden synergistische Wirkungen auf. Beispiele für solche herbiziden Mischungspartner sind: Flometoquine, pyflubumide, acrinathrin, alpha-cypermethrin, beta-cyfluthrin, cyhalothrin, cypermethrin, deltamethrin, esfenvalerate, etofenprox, flucythrinate, lambda-cyhalothrin, gamma-cyhalothrin, tau-fluvalinate, transfluthrin, zeta-cypermethrin, cyfluthrin, bifenthrin, tefluthrin, Eflusilanate, fubfenprox, imidacloprid, acetamiprid, thiamethoxam, nitenpyram, thiacloprid, dinotefuran, clothianidin, imidaclothiz, chlorofluorazuron, diflubenzuron, lufenuron, teflubenzuron, triflumuron, novaluron, flufenoxuron, hexaflumuron, bistrifluorone, noviflumuron, buprofezin, cyromazine, methoxyfenozide, tebufenozide, halofenozide, Chromafenozide, Fipronil, Ethiprole, Pyrafluprole, Pyriprole, Flubendiamide, Chlorantraniliprole (Rynaxypyr), Cyantraniliprole (Cyazypyr), Emamectin, Emamectin benzoate, Abamectin, Ivermectin, Milbemectin, Lepimectin, Tebufenpyrad, Fenpyroximate, pyridaben, fenazaquin, pyrimidifen, tolfenpyrade, dicofol, cyenopyrafen, cyflumetofen, acequinocyl, fluacrypyrine, bifenazate, diafenthiuron, etoxazole, clofentezine, spinosad, triarathen, propargite, bromopropylate, pyrifluquinazone, pymetrozine, flonicamid, pyriproxyfen, diofenolan, chlorfenapyr, metaflumizone, Indoxacarb, chlorpyrifos, spirodiclofen, spiromesifen, spirotetramat, pyridalyl, spinetoram, acephates, profenofos, flupyradifurone, thiodicarb, methiocarb, sulfoxaflor, 1- [2-fluoro-4-methyl-5 - [(2,2,2-trifluoroethyl) sulfinyl ] phenyl] -3- (trifluoromethyl) -1H-l, 2,4-riazol-5-amine, 1- (3-chloropyridinyl) -N- [4-cyano-2-methyl-6- [(methylamino) carbonyl] phenyl] -3 - [[5- (trifluoromethyl) -2H-tetrazol-2-yl] methyl] -1H-pyrazole-5-carboxamide, fluensulfones, fluopyram. Furthermore, the compounds of the formula (I) can be mixed with the following herbicides. The same applies to the mixtures according to the invention, in particular to those listed in Table A, which can also be mixed with the following herbicides and applied to plants or plant parts. In many cases, these mixtures with herbicides have synergistic effects. Examples of such herbicidal mixture partners are:
Acetochlor, acifluorfen, acifluorfen-sodium, aclonifen, alachlor, allidochlor, alloxydim, alloxydim- sodium, ametryn, amicarbazone, amidochlor, amidosulfuron, aminocyclopyrachlor, aminocyclo- pyrachlor-potassium, aminocyclopyrachlor-methyl, aminopyralid, amitrole, ammoniumsulfamate, anilofos, asulam, atrazine, azafenidin, azimsulfuron, beflubutamid, benazolin, benazolin-ethyl, benfluralin, benfuresate, bensulfuron, bensulfuron-methyl, bensulide, bentazone, benzobicyclon, benzofenap, bicyclopyron, bifenox, bilanafos, bilanafos-sodium, bispyribac, bispyribac-sodium, bromacil, bromobutide, bromofenoxim, bromoxynil, bromoxynil-butyrate, -potassium, -heptanoate und - octanoate, busoxinone, butachlor, butafenacil, butamifos, butenachlor, butralin, butroxydim, butylate, cafenstrole, carbetamide, carfentrazone, carfentrazone-ethyl, chloramben, chlorbromuron, chlorfenac, chlorfenac-sodium, chlorfenprop, chlorflurenol, chlorflurenol-methyl, chloridazon, chlorimuron, chlorimuron-ethyl, chlorophthalim, chlorotoluron, chlorthal-dimethyl, chlorsulfuron, cinidon, cinidon- ethyl, cinmethylin, cinosulfuron, clacyfos, clethodim, clodinafop, clodinafop-propargyl, clomazone, clomeprop, clopyralid, cloransulam, cloransulam-methyl, cumyluron, cyanamide, cyanazine, cycloate, cyclopyrimorate, cyclosulfamuron, cycloxydim, cyhalofop, cyhalofop-butyl, cyprazine, 2,4-D, 2,4-D- butotyl, -butyl, -dimethylammonium, -diolamin, -ethyl, 2-ethylhexyl, -isobutyl, -isooctyl, - isopropylammonium, -potassium, -triisopropanolammonium und -trolamine, 2,4-DB, 2,4-DB-butyl, - dimethylammonium, isooctyl, -potassium und -sodium, daimuron (dymron), dalapon, dazomet, n- decanol, desmedipham, detosyl-pyrazolate (DTP), dicamba, dichlobenil, dichlorprop, dichlorprop-P, diclofop, diclofop-methyl, diclofop-P-methyl, diclosulam, difenzoquat, diflufenican, diflufenzopyr, diflufenzopyr-sodium, dimefuron, dimepiperate, dimethachlor, dimethametryn, dimethenamid, dimethenamid-P, dimetrasulfuron, dinitramine, dinoterb, diphenamid, diquat, diquat-dibromid, dithiopyr, diuron, DNOC, endothal, EPTC, esprocarb, ethalfluralin, ethametsulfuron, ethametsulfuron- methyl, ethiozin, ethofumesate, ethoxyfen, ethoxyfen-ethyl, ethoxysulfuron, etobenzanid, F-5231, i.e. N- [2-Chlor-4-fluor-5-[4-(3 -fluorpropyl)-4,5-dihydro-5-oxo- 1 H-tetrazol- 1 -yl]-phenyl] -ethansulfonamid, F- 7967, i.e. 3-[7-Chlor-5-fluor-2-(trifluormethyl)-lH-benzimidazol-4-yl]-l-methyl-6-(trifluor- methyl)pyrimidin-2,4(lH,3H)-dion, fenoxaprop, fenoxaprop-P, fenoxaprop-ethyl, fenoxaprop-P-ethyl, fenoxasulfone, fentrazamide, flamprop, flamprop-M-isopropyl, flamprop-M-methyl, flazasulfuron, florasulam, fluazifop, fluazifop-P, fluazifop-butyl, fluazifop-P-butyl, flucarbazone, flucarbazone- sodium, flucetosulfuron, fluchloralin, flufenacet, flufenpyr, flufenpyr-ethyl, flumetsulam, flumiclorac, flumiclorac-pentyl, flumioxazin, fluometuron, flurenol, flurenol-butyl, -dimethylammonium und - methyl, fluoroglycofen, fluoroglycofen-ethyl, flupropanate, flupyrsulfuron, flupyrsulfuron-methyl- sodium, fluridone, flurochloridone, fluroxypyr, fluroxypyr-meptyl, flurtamone, fluthiacet, fluthiacet- methyl, fomesafen, fomesafen-sodium, foramsulfuron, fosamine, glufosinate, glufosinate-ammonium, glufosinate-P-sodium, glufosinate-P-ammonium, glufosinate-P-sodium, glyphosate, glyphosate- ammonium, -isopropylammonium, -diammonium, -dimethylammonium, -potassium, -sodium und - trimesium, H-9201, i.e. 0-(2,4-Dimethyl-6-nitrophenyl)-0-ethyl-isopropylphosphoramidothioat, halauxifen, halosafen, halosulfuron, halosulfuron-methyl, haloxyfop, haloxyfop-P, haloxyfop- ethoxyethyl, haloxyfop-P-ethoxyethyl, haloxyfop-methyl, haloxyfop-P-methyl, hexazinone, HW-02, i.e. l-(Dimethoxyphosphoryl)-ethyl-(2,4-dichlorphenoxy)acetat, imazamethabenz, Imazamethabenz-methyl, imazamox, imazamox-ammonium, imazapic, imazapic-ammonium, imazapyr, imazapyr- isopropylammonium, imazaquin, imazaquin-ammonium, imazethapyr, imazethapyr-immonium, imazosulfuron, indanofan, indaziflam, iodosulfuron, iodosulfuron-methyl-sodium, ioxynil, ioxynil- octanoate, -potassium und sodium, ipfencarbazone, isoproturon, isouron, isoxaben, isoxaflutole, karbutilate, KUH-043, i.e. 3-({[5-(Difluormethyl)-l-methyl-3-(trifluormethyl)-lH-pyrazol-4- yl]methyl}sulfonyl)-5,5-dimethyl-4,5-dihydro-l,2-oxazol, ketospiradox, lactofen, lenacil, linuron, MCPA, MCPA-butotyl, -dimethylammonium, -2-ethylhexyl, -isopropylammonium, -potassium und - sodium, MCPB, MCPB-methyl, -ethyl und -sodium, mecoprop, mecoprop-sodium, und -butotyl, mecoprop-P, mecoprop-P-butotyl, -dimethylammonium, -2-ethylhexyl und -potassium, mefenacet, mefluidide, mesosulfuron, mesosulfuron-methyl, mesotrione, methabenzthiazuron, metam, metamifop, metamitron, metazachlor, metazosulfuron, methabenzthiazuron, methiopyrsulfuron, methiozolin, methyl isothiocyanate, metobromuron, metolachlor, S-metolachlor, metosulam, metoxuron, metribuzin, metsulfuron, metsulfuron-methyl, molinat, monolinuron, monosulfuron, monosulfuron-ester, MT-5950, i.e. N-[3-chlor-4-(l-methylethyl)-phenyl]-2-methylpentanamid, NGGC-011, napropamide, NC-310, i.e. 4-(2,4-Dichlorbenzoyl)-l-methyl-5-benzyloxypyrazol, neburon, nicosulfuron, nonanoic acid (Pelargonsäure), norflurazon, oleic acid (fatty acids), orbencarb, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxasulfuron, oxaziclomefon, oxyfluorfen, paraquat, paraquat dichloride, pebulate, pendimethalin, penoxsulam, pentachlorphenol, pentoxazone, pethoxamid, petroleum oils, phenmedipham, picloram, picolinafen, pinoxaden, piperophos, pretilachlor, primisulfuron, primisulfuron-methyl, prodiamine, profoxydim, prometon, prometryn, propachlor, propanil, propaquizafop, propazine, propham, propisochlor, propoxycarbazone, propoxycarbazone-sodium, propyrisulfuron, propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyraflufen, pyraflufen-ethyl, pyrasulfotole, pyrazolynate (pyrazolate), pyrazosulfuron, pyrazosulfuron-ethyl, pyrazoxyfen, pyribambenz, pyribambenz-isopropyl, pyribambenz-propyl, pyribenzoxim, pyributicarb, pyridafol, pyridate, pyriftalid, pyriminobac, pyriminobac-methyl, pyrimisulfan, pyrithiobac, pyrithiobac-sodium, pyroxasulfone, pyroxsulam, quinclorac, quinmerac, quinoclamine, quizalofop, quizalofop-ethyl, quizalofop-P, quizalofop-P-ethyl, quizalofop-P-tefuryl, rimsulfuron, saflufenacil, sethoxydim, siduron, simazine, simetryn, sulcotrion, sulfentrazone, sulfometuron, sulfometuron-methyl, sulfosulfuron, , SYN-523, SYP-249, i.e. l-Ethoxy-3-methyl-l -oxobut-3-en-2-yl-5-[2-chlor-4-(trifluormethyl)phenoxy]- 2-nitrobenzoat, SYP-300, i.e. l-[7-Fluor-3-oxo-4-(prop-2-in-l -yl)-3,4-dihydro-2H-l,4-benzoxazin-6- yl]-3-propyl-2-thioxoimidazolidin-4,5-dion, 2,3,6-TBA, TCA (Trifluoressigsäure), TCA-sodium, tebuthiuron, tefuryltrione, tembotrione, tepraloxydim, terbacil, terbucarb, terbumeton, terbuthylazin, terbutryn, thenylchlor, thiazopyr, thiencarbazone, thiencarbazone-methyl, thifensulfuron, thifensulfuron- methyl, thiobencarb, tiafenacil topramezone, tralkoxydim, triafamone, tri-allate, triasulfuron, triaziflam, tribenuron, tribenuron-methyl, triclopyr, trietazine, trifloxysulfuron, trifloxysulfuron-sodium, trifluralin, triflusulfuron, triflusulfuron-methyl, tritosulfuron, urea sulfate, vernolate, ZJ-0862, i.e. 3,4-Dichlor-N- {2-[(4,6-dimethoxypyrimidin-2-yl)oxy]benzyl}anilin, sowie die folgenden Verbindungen: Acetochlor, acifluorfen, acifluorfen-sodium, aclonifen, alachlor, allidochlor, alloxydim, alloxydim-sodium, ametryn, amicarbazone, amidochlor, amidosulfuron, aminocyclopyrachlor, aminocycloprachlor-potassium, aminocyclopyrachloromethyl, aminopyralid, amitrole, ammonium sulfamate, anilofos, asulam, atrazine, azafenidine, azimsulfuron, beflubutamide, benazolin, benazolin-ethyl, benfluralin, benfuresate, bensulfuron, bensulfuron-methyl, bensulide, bentazone, benzobicyclone, benzofenap, bicyclopyrone, bifenox, bilanafos, bilanafos-sodium, bispyribac, bispyribac-sodium, bromacil, bromobutide, bromofenoxime, bromoxynil, bromoxynil-butyrate, -potassium, -heptanoate and - octanoate, busoxinone, butachlor, butafenacil, butamifos, butenachlor, butraline, butroxydim, butylate, cafenstrole, carbetamide, carfentrazone, carfentrazone-ethyl, chloramben, chlorbromuron, chlorfenac , chlorfenac-sodium, chlorfenprop, chlorofluorol, chlorflurenol-methyl, chloridazon, chlorimuron, chlorimuron-ethyl, chlorophth alim, chlorotoluron, chlorothal-dimethyl, chlorosulfuron, cinidone, cinidon-ethyl, cinmethylin, cinosulfuron, clacyfos, clethodim, clodinafop, clodinafop-propargyl, clomazone, clomeprop, clopyralid, cloransulam, cloransulam-methyl, cumyluron, cyanamide, cyanazine, cycloate, cyclopyrimorate, cyclosulfamuron, cycloxydim, cyhalofop, cyhalofop-butyl, cyprazine, 2,4-D, 2,4-D-butotyl, -butyl, -dimethylammonium, -diolamine, -ethyl, 2-ethylhexyl, -isobutyl, -isooctyl, isopropylammonium, -potassium, -triisopropanolammonium and -trolamine, 2,4-DB, 2,4-DB-butyl, - dimethylammonium, isooctyl, -potassium and -sodium, daimuron (dymron), dalapon, dazomet, n-decanol, desmedipham, detosyl-pyrazolate (DTP), dicamba, dichlobenil, dichlorprop, dichlorprop-P, diclofop, diclofop-methyl, diclofop-P-methyl, diclosulam, difenzoquat, diflufenican, diflufenzopyr, diflufenzopyr-sodium, dimefuron, dimepiperate, dimethachlor, dimethametryn , dimethenamid, dimethenamid-P, dimetrasulfuron, dinitramine, dinoterb, diphenamid, diquat, diquat-dibromide, dithiopyr, diuron, DNOC, endothal, EPTC, esprocarb, ethalfluralin, ethametsulfuron, ethametsulfuron-methyl, ethiozine, ethofumesate, ethoxyfen, ethoxyfen-ethyl, ethoxysulfuron, etobenzanide, F-5231, ie N- [2-chloro-4-fluoro-5- [4- (3-fluoropropyl) -4,5-dihydro-5-oxo-1H-tetrazol-1-yl] -phenyl ] -ethanesulfonamide, F-7967, ie 3- [7-chloro-5-fluoro-2- (trifluoromethyl) -1H-benzimidazol-4-yl] -1-methyl-6- (trifluoromethyl) pyrimidine-2, 4 (1H, 3H) -dione, fenoxaprop, fenoxaprop-P, fenoxaprop-ethyl, fenoxaprop-P-ethyl, fenoxasulfone, fentrazamide, flamprop, flamprop-M-isopropyl, flamprop-M-methyl, flazasulfuron, florasulam, fluazifop, fluazifop P, fluazifop-butyl, fluazifop-p-butyl, flucarbazone, flucarbazone-sodium, flucetosulfuron, fluchloralin, flufenacet, flufenpyr, flufenpyr-ethyl, flumetsulam, flumiclorac, flumiclorac-pentyl, flumioxazine, fluometuron, flurenol, flurenol-butyl, - dimethyl ammonium and methyl, fl uoroglycofen, fluoroglycofen-ethyl, flupropanate, flupyrsulfuron, flupyrsulfuron-methyl-sodium, fluridone, flurochloridone, fluroxypyr, fluroxypyr-meptyl, flurtamone, fluthiacet, fluthiacet-methyl, fomesafen, fomesafen-sodium, foramsulfuron, fosamine, glufosinate, glufosinate-ammonium, glufosinate-P-sodium, glufosinate-P-ammonium, glufosinate-P-sodium, glyphosate, glyphosate-ammonium, -isopropylammonium, -diammonium, -dimethylammonium, -potassium, -sodium and -trimesium, H-9201, ie 0- ( 2,4-dimethyl-6-nitrophenyl) -0-ethyl-isopropylphosphoramidothioate, halo-tylose, halosafenine, halosulfuron, halosulfuron-methyl, haloxyfop, haloxyfop-P, haloxyfopethoxyethyl, haloxyfop-P-ethoxyethyl, haloxyfop-methyl, haloxyfop-P -methyl, hexazinone, HW-02, ie 1- (dimethoxyphosphoryl) -ethyl- (2,4-dichlorophenoxy) acetate, imazamethabenz, imazamethabenz-methyl, imazamox, imazamoxammonium, imazapic, imazapicammonium, imazapyr, imazapyrisopropylammonium , imazaquin, imazaquin-ammonium, imazethapyr, imazethapyr -immonium, imazosulfuron, indanofan, indaziflam, iodosulfuron, iodosulfuron-methyl-sodium, ioxynil, ioxynil-octanoate, -potassium and sodium, ipfencarbazone, isoproturon, isourone, isoxaben, isoxaflutole, karbutilate, KUH-043, ie 3 - ({[ 5- (Difluoromethyl) -1-methyl-3- (trifluoromethyl) -1H-pyrazol-4-yl] methyl} sulfonyl) -5,5-dimethyl-4,5-dihydro-1,2-oxazole, ketospiradox, lactofen , lenacil, linuron, MCPA, MCPA butotyl, dimethyl ammonium, 2-ethylhexyl, isopropyl ammonium, potassium and sodium, MCPB, MCPB methyl, ethyl and sodium, mecoprop, mecoprop-sodium mecoprop-P, mecoprop-P-butotyl, -dimethylammonium, -2-ethylhexyl and -potassium, mefenacet, mefluidide, mesosulfuron, mesosulfuron-methyl, mesotrione, methabenzthiazuron, metam, metamifop, metamitron, metazachlor, metazosulfuron, methabenzthiazuron, methiopyrsulfuron, methiozolin , methyl isothiocyanate, metobromuron, metolachlor, S-metolachlor, metosulam, metoxuron, metribuzin, metsulfuron, metsulfuron-methyl, molinate, mono linuron, monosulfuron, monosulfuron ester, MT-5950, ie N- [3-chloro-4- (1-methylethyl) phenyl] -2-methylpentanamide, NGGC-011, napropamide, NC-310, ie 4- (2 , 4-dichlorobenzoyl) -l-methyl-5-benzyloxypyrazole, neburon, nicosulfuron, nonanoic acid (pelargonic acid), norflurazon, oleic acid, orbencarb, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxasulfuron, oxaziclomefon, oxyfluorfen, paraquat , paraquat dichloride, pebulate, pendimethalin, penoxsulam, pentachlorophenol, pentoxazone, pethoxamide, petroleum oils, phenmedipham, picloram, picolinafen, pinoxaden, piperophos, pretilachlor, primisulfuron, primisulfuron-methyl, prodiamine, profoxydim, prometon, prometryn, propachlor, propanil, propaquizafop, propazine, propham, propisochlor, propoxycarbazone, propoxycarbazone-sodium, propyrisulfuron, propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyraflufen, pyraflufen-ethyl, pyrasulfotole, pyrazolynate (pyrazolate), pyrazosulfuron, pyrazosulfuron-ethyl, pyrazoxyfen, pyribambenz, pyribambenz-isopropyl, pyribambenz-propyl, pyribenzoxim, pyributicarb, pyridafol, pyridate, pyriftalid, pyriminobac, pyriminobac-methyl , pyrimisulfan, pyrithiobac, pyrithiobac-sodium, pyroxasulfone, pyroxsulam, quinclorac, quinmerac, quinoclamine, quizalofop, quizalofop-ethyl, quizalofop-P, quizalofop-P-ethyl, quizalofop-P-tefuryl, rimsulfuron, saflufenacil, sethoxydim, siduron, simazine , simetryn, sulcotrione, sulfentrazone, sulfometuron, sulfometuron-methyl, sulfosulfuron,, SYN-523, SYP-249, ie, 1-ethoxy-3-methyl-1-ox Obut-3-en-2-yl-5- [2-chloro-4- (trifluoromethyl) phenoxy] -2-nitrobenzoate, SYP-300, ie 1- [7-fluoro-3-oxo-4- (propyl) 2-in-1-yl) -3,4-dihydro-2H-1,4-benzoxazin-6-yl] -3-propyl-2-thioxoimidazolidine-4,5-dione, 2,3,6-TBA, TCA (trifluoroacetic acid), TCA-sodium, tebuthiuron, tefuryltrione, tembotrione, tepraloxydim, terbacil, terbucarb, terbumetone, terbuthylazine, terbutryn, thenylchlor, thiazopyr, thiencarbazone, thiencarbazone-methyl, thifensulfuron, thifensulfuron-methyl, thiobencarb, tiafenacil topramezone, tralkoxydim, triafamone, tri-allate, triasulfuron, triaziflam, tribenuron, tribenuron-methyl, triclopyr, trietazine, trifloxysulfuron, trifloxysulfuron-sodium, trifluralin, triflusulfuron, triflusulfuron-methyl, tritosulfuron, urea sulfate, vernolate, ZJ-0862, ie 3,4- Dichloro-N- {2 - [(4,6-dimethoxypyrimidin-2-yl) oxy] benzyl} aniline, and the following compounds:
Figure imgf000018_0001
vgl. WO 2001/094339 AI, WO 2001/079199 AI, US 20020016262 AI , WO 2002/098227 AI und WO 2012/122171 AI .
Figure imgf000018_0001
see. WO 2001/094339 A1, WO 2001/079199 Al, US 20020016262 Al, WO 2002/098227 Al and WO 2012/122171 Al.
Frucht/Gemüse-Herbizide: Atrazine, Bromacil, Diuron, Glyphosate, Linuron, Metribuzin, Simazine, Trifluralin, Fluazifop, Glufosinate, Halosulfuron Gowan, Paraquat, Propyzamide, Sethoxydim, Butafenacil, Halosulfuron, Indaziflam; Getreideherbizide : Isoproturon, Bromoxynil, Ioxynil, Phenoxies, Chlorsulfuron, Clodinafop, Diclofop, Diflufenican, Fenoxaprop, Florasulam, Fluroxypyr, Metsulfuron, Triasulfuron, Flucarbazone, Iodosulfüron, Propoxycarbazone, Picolinafen, Mesosulfuron, Beflubutamid, Pinoxaden, Amidosulfuron, Thifensulfuron, Tribenuron, Flupyrsulfuron, Sulfosulfüron, Pyrasulfotole, Pyroxsulam, Flufenacet, Tralkoxydim, Pyroxasulfon; Fruit / Vegetable Herbicides: Atrazine, Bromacil, Diuron, Glyphosate, Linuron, Metribuzin, Simazine, Trifluralin, Fluazifop, Glufosinate, Halosulfuron Gowan, Paraquat, Propyzamide, Sethoxydim, Butafenacil, Halosulfuron, Indaziflam; Cereal Herbicides: Isoproturon, Bromoxynil, Ioxynil, Phenoxies, Chlorsulfuron, Clodinafop, Diclofop, Diflufenican, Fenoxaprop, Florasulam, Fluroxypyr, Metsulfuron, Triasulfuron, Flucarbazone, Iodosulfuron, Propoxycarbazone, Picolinafen, Mesosulfuron, Beflubutamide, Pinoxaden, Amidosulfuron, Thifensulfuron, Tribenuron, Flupyrsulfuron, Sulfosulfuron, pyrasulfotole, pyroxsulam, flufenacet, tralkoxydim, pyroxasulfone;
Maisherbizide: Atrazine, Alachlor, Bromoxynil, Acetochlor, Dicamba, Clopyralid, (S)-Dimethenamid, Glufosinate, Glyphosate, Isoxaflutole, (S)-Metolachlor, Mesotrione, Nicosulfüron, Primisulfüron, Rimsulfüron, Sulcotrione, Foramsulfüron, Topramezone, Tembotrione, Saflufenacil, Thiencarbazone, Flufenacet, Pyroxasulfon; Reisherbizide: Butachlor, Propanil, Azimsulfuron, Bensulfuron, Cyhalofop, Daimuron, Fentrazamide, Imazosulfuron, Mefenacet, Oxaziclomefone, Pyrazosulfuron, Pyributicarb, Quinclorac, Thiobencarb, Indanofan, Flufenacet, Fentrazamide, Halosulfuron, Oxaziclomefone, Benzobicyclon, Pyriftalid, Penoxsulam, Bispyribac, Oxadiargyl, Ethoxysulfuron, Pretilachlor, Mesotrione, Tefuryltrione, Oxadiazone, Fenoxaprop, Pyrimisulfan; B aumwollherbizide : Diuron, Fluometuron, MSMA, Oxyfluorfen, Prometryn, Trifluralin, Carfentrazone, Clethodim, Fluazifop -butyl, Glyphosate, Norflurazon, Pendimethalin, Pyrithiobac-sodium, Trifloxysulfuron, Tepraloxydim, Glufosinate, Flumioxazin, Thidiazuron; Corn herbicides: atrazines, alachlor, bromoxynil, acetochlor, dicamba, clopyralid, (S) -dimethenamid, glufosinate, glyphosate, isoxaflutole, (S) -metolachlor, mesotrione, nicosulfuron, primisulfuron, rimsulfuron, sulcotrione, foramsulfuron, toramezone, tembotrione, saflufenacil, Thiencarbazone, flufenacet, pyroxasulfone; Rice herbicides: Butachlor, Propanil, Azimsulfuron, Bensulfuron, Cyhalofop, Daimuron, Fentrazamide, Imazosulfuron, Mefenacet, Oxaziclomefone, Pyrazosulfuron, Pyributicarb, Quinclorac, Thiobencarb, Indanofan, Flufenacet, Fentrazamide, Halosulfuron, Oxaziclomefone, Benzobicyclone, Pyriftalid, Penoxsulam, Bispyribac, Oxadiargyl, Ethoxysulfuron, pretilachlor, mesotrione, tefuryltrione, oxadiazone, fenoxaprop, pyrimisulfan; Woolly herbicides: Diuron, Fluometuron, MSMA, Oxyfluorfen, Prometryn, Trifluralin, Carfentrazone, Clethodim, Fluazifop -butyl, Glyphosate, Norflurazon, Pendimethalin, Pyrithiobac-sodium, Trifloxysulfuron, Tepraloxydim, Glufosinate, Flumioxazin, Thidiazuron;
Sojaherbizide: Alachlor, Bentazone, Trifluralin, Chlorimuron-Ethyl, Cloransulam-Methyl, Fenoxaprop, Fomesafen, Fluazifop, Glyphosate, Imazamox, Imazaquin, Imazethapyr, (S)-Metolachlor, Metribuzin, Pendimethalin, Tepraloxydim, Glufosinate; Soy herbicides: alachlor, bentazone, trifluralin, chlorimuron-ethyl, cloransulam-methyl, fenoxaprop, fomesafen, fluazifop, glyphosate, imazamox, imazaquin, imazethapyr, (S) -metolachlor, metribuzin, pendimethalin, tepraloxydim, glufosinate;
Zuckerrübenherbizide: Chloridazon, Desmedipham, Ethofumesate, Phenmedipham, Triallate, Clopyralid, Fluazifop, Lenacil, Metamitron, Quinmerac, Cycloxydim, Triflusulfuron, Tepraloxydim, Quizalofop; Sugar beet herbicides: Chloridazon, Desmedipham, Ethofumesate, Phenmedipham, Triallate, Clopyralid, Fluazifop, Lenacil, Metamitron, Quinmerac, Cycloxydim, Triflusulfuron, Tepraloxydim, Quizalofop;
Rapsherbizide: Clopyralid, Diclofop, Fluazifop, Glufosinate, Glyphosate, Metazachlor, Trifluralin Ethametsulfuron, Quinmerac, Quizalofop, Clethodim, Tepraloxydim; Rape herbicides: Clopyralid, Diclofop, Fluazifop, Glufosinate, Glyphosate, Metazachlor, Trifluralin Ethametsulfuron, Quinmerac, Quizalofop, Clethodim, Tepraloxydim;
Insbesondere bevorzugt sind Mischungen der erfindungsgemäßen Wirkstoffkombinationen mit Glyphosate. Ferner bevorzugt sind insbesondere Mischungen der erfindungsgemäßen Wirkstoffkombinationen mit Glufosinate. Particular preference is given to mixtures of the active compound combinations according to the invention with glyphosate. Further preferred are in particular mixtures of the active ingredient combinations according to the invention with glufosinate.
Die erfindungsgemäßen Wirkstoffkombinationen eignen sich bei guter Pflanzenverträglichkeit, günstiger Warmblütertoxizität und guter Umweltverträglichkeit zum Schutz von Pflanzen und Pflanzenorganen, zur Steigerung der Ernteerträge, Verbesserung der Qualität des Erntegutes und zur Bekämpfung von tierischen Schädlingen, insbesondere Insekten, Spinnentieren, Helminthen, Nematoden und Mollusken, die in der Landwirtschaft, im Gartenbau, bei der Tierzucht, in Forsten, in Gärten und Freizeiteinrichtungen, im Vorrats- und Materialschutz sowie auf dem Hygienesektor vorkommen. Sie können vorzugsweise als Pflanzenschutzmittel eingesetzt werden. Sie sind gegen normal sensible und resistente Arten sowie gegen alle oder einzelne Entwicklungs Stadien wirksam. Zu den oben erwähnten Schädlingen gehören: The active compound combinations according to the invention are suitable for good plant tolerance, favorable toxicity to warm-blooded animals and good environmental compatibility for the protection of plants and plant organs, for increasing crop yields, improving the quality of the crop and for controlling animal pests, in particular insects, arachnids, helminths, nematodes and molluscs found in agriculture, horticulture, livestock, forests, gardens and recreational facilities, in supplies and materials, and in the hygiene sector. They can preferably be used as crop protection agents. They are effective against normally sensitive and resistant species as well as against all or individual stages of development. The above mentioned pests include:
Schädlinge aus dem Stamm der Arthropoda, insbesondere aus der Klasse der Arachnida z.B. Acarus spp., Aceria kuko, Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Amphitetranychus viennensis, Argas spp., Boophilus spp., Brevipalpus spp., Bryobia graminum, Bryobia praetiosa, Centruroides spp., Chorioptes spp., Dermanyssus gallinae, Dermatophagoides pteronyssinus, Dermatophagoides farinae, Dermacentor spp., Eotetranychus spp., Epitrimerus pyri, Eutetranychus spp., Eriophyes spp., Glycyphagus domesticus, Halotydeus destructor, Hemitarsonemus spp., Hyalomma spp., Ixodes spp., Latrodectus spp., Loxosceles spp., Metatetranychus spp., Neutrombicula autumnalis, Nuphersa spp., Oligonychus spp., Ornithodorus spp., Ornithonyssus spp., Panonychus spp., Phyllocoptruta oleivora, Platytetranychus multidigituli, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Steneotarsonemus spp., Steneotarsonemus spinki, Tarsonemus spp., Tetranychus spp., Trombicula alfreddugesi, Vaejovis spp., Vasates lycopersici.; aus der Klasse der Chilopoda z.B. Geophilus spp., Scutigera spp.; aus der Ordnung oder der Klasse der Collembola z.B. Onychiurus armatus, Sminthurus viridis; aus der Klasse der Diplopoda z.B. Blaniulus guttulatus; aus der Klasse der Insecta, z.B. aus der Ordnung der Blattodea z.B. Blattella asahinai, Blattella germanica, Blatta orientalis, Leucophaea maderae (Rhypaobia maderae),, Panchlora spp., Parcoblatta spp., Periplaneta spp., Supella longipalpa, Loboptera decipiens, Neostylopyga rhombifolia, Pycnoscelus surinamensis; aus der Ordnung der Coleoptera z.B. Acalymma vittatum, Acanthoscelides obtectus, Adoretus spp., Aethina tumida, Agelastica alni, Agriotes spp., Alphitobius diaperinus, Amphimallon solstitialis, Anobium punctatum, Anoplophora spp., Anthonomus spp., Anthrenus spp., Apion spp., Apogonia spp., Atomaria spp., Attagenus spp., Baris caerulescens, Bruchidius obtectus, Bruchus spp., Cassida spp., Cerotoma trifurcata, Ceutorrhynchus spp., Chaetocnema spp., Cleonus mendicus, Conoderus spp., Cosmopolites spp., Costelytra zealandica, Ctenicera spp., Curculio spp., Cryptolestes ferrugineus, Cryptorhynchus lapathi, Cylindrocopturus spp., Dermestes spp., Diabrotica spp., Dichocrocis spp., Dicladispa armigera, Diloboderus spp., Epicaerus spp., Epilachna spp., Epitrix spp., Faustinus spp., Gibbium psylloides, Gnathocerus cornutus, Hellula undalis, Heteronychus arator, Heteronyx spp., Hylamorpha elegans, Hylotrupes bajulus, Hypera postica, Hypomeces squamosus, Hypothenemus spp., Lachnosterna consanguinea, Lasioderma serricorne, Latheticus oryzae, Lathridius spp., Lema spp., Leptinotarsa decemlineata, Leucoptera spp., Lissorhoptrus oryzophilus, Listronotus (= Hyperodes) spp., Lixus spp., Luperodes spp., Luperomorpha xanthodera, Lyctus spp., Megascelis spp., Melanotus spp., Meligethes aeneus, Melolontha spp., Migdolus spp., Monochamus spp., Naupactus xanthographus, Necrobia spp., Neogalerucella spp., Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamensis, Oryzaphagus oryzae, Otiorrhynchus spp., Oulema spp., Oulema melanopus, Oulema oryzae, Oxycetonia jucunda, Phaedon cochleariae, Phyllophaga spp., Phyllophaga helleri, Phyllotreta spp., Popillia japonica, Premnotrypes spp., Prostephanus truncatus, Psylliodes spp., Ptinus spp., Rhizobius ventralis, Rhizopertha dominica, Rhynchophorus spp., Rhynchophorus ferrugineus, Rhynchophorus palmarum, Sinoxylon perforans, Sitophilus spp., Sitophilus oryzae, Sphenophorus spp., Stegobium paniceum, Sternechus spp., Symphyletes spp., Tanymecus spp., Tenebrio molitor, Tenebrioides mauretanicus, Tribolium spp., Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus spp.; aus der Ordnung der Diptera z.B. Aedes spp., Agromyza spp., Anastrepha spp., Anopheles spp., Asphondylia spp., Bactrocera spp., Bibio hortulanus, Calliphora erythrocephala, Calliphora vicina, Ceratitis spp., Ceratitis capitata, Chironomus spp., Chrysomyia spp., Chrysops spp., Chrysozona pluvialis, Cochliomyia spp., Contarinia spp., Cordylobia anthropophaga, Cricotopus sylvestris, Culex spp., Culicoides spp., Culiseta spp., Cuterebra spp., Dacus oleae, Dasyneura spp., Delia spp., Dermatobia hominis, Drosophila spp., Drosophila suzukii, Echinocnemus spp., Euleia heraclei, Fannia spp., Gasterophilus spp., Glossina spp., Haematopota spp., Hydrellia spp., Hydrellia griseola, Hylemya spp., Hippobosca spp., Hypoderma spp., Liriomyza spp., Lucilla spp., Lutzomyia spp., Mansonia spp., Musca spp., Oestrus spp., Oscinella frit, Paratanytarsus spp., Paralauterborniella subcincta, Pegomyia spp., Phlebotomus spp., Phorbia spp., Phormia spp., Piophila casei, Platyparea poeciloptera, Prodiplosis spp., Psila rosae, Rhagoletis spp., Sarcophaga spp., Simulium spp., Stomoxys spp., Tabanus spp., Tetanops spp., Tipula spp., Hippoboscoidea (= Pupipara), Toxotrypana curvicauda; aus der Unterordnung der Heteroptera z.B. Aelia spp., Anasa tristis, Antestiopsis spp., Boisea spp., Blissus spp., Calocoris spp., Campylomma livida, Cavelerius spp., Cimex spp., Collaria spp., Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocoris hewetti, Dysdercus spp., Euschistus spp., Eurydema spp., Eurygaster spp., Halyomorpha halys, Heliopeltis spp., Horcias nobilellus, Leptocorisa spp., Leptocorisa varicornis, Leptoglossus occidentalis, Leptoglossus phyllopus, Lygocoris spp., Lygus spp., Macropes excavatus, Megacopta cribraria, Miridae, Monaionion atratum, Nezara spp., Nysius spp., Oebalus spp., Pentomidae, Piesma quadrata, Piezodorus spp., Psallus spp., Pseudacysta persea, Rhodnius spp., Sahlbergella singularis, Scaptocoris castanea, Scotinophora spp., Stephanitis nashi, Tibraca spp., Triatoma spp.; aus der Ordnung der Hemiptera z.B. Acizzia acaciaebaileyanae, Acizzia dodonaeae, Acizzia uncatoides, Acrida turrita, Acyrthosipon spp., Acrogonia spp., Aeneolamia spp., Agonoscena spp., Aleurocanthus spp., Aleyrodes proletella, Aleurolobus barodensis, Aleurothrixus floccosus, Allocaridara malayensis, Amrasca spp., Anuraphis cardui, Aonidiella spp., Aphanostigma piri, Aphis spp., Arboridia apicalis, Arytainilla spp., Aspidiella spp., Aspidiotus spp., Atanus spp., Aulacorthum solani, Bemisia tabaci, Blastopsylla occidentalis, Boreioglycaspis melaleucae, Brachycaudus helichrysi, Brachycolus spp., Brevicoryne brassicae, Cacopsylla spp., Calligypona marginata, Capulinia spp., Carneocephala fülgida, Ceratovacuna lanigera, Cercopidae, Ceroplastes spp., Chaetosiphon fragaefolii, Chionaspis tegalensis, Chlorita onukii, Chondracris rosea, Chromaphis juglandicola, Chrysomphalus aonidum, Chrysomphalus ficus, Cicadulina mbila, Coccomytilus halli, Coccus spp., Cryptomyzus ribis, Cryptoneossa spp., Ctenarytaina spp., Dalbulus spp., Dialeurodes chittendeni, Dialeurodes citri, Diaphorina citri, Diaspis spp., Diuraphis spp., Drosicha spp., Dysaphis spp., Dysmicoccus spp., Empoasca spp., Eriosoma spp., Erythroneura spp., Eucalyptolyma spp., Euphyllura spp., Euscelis bilobatus, Ferrisia spp., Fiorinia spp., Furcaspis oceanica, Geococcus coffeae, Glycaspis spp., Heteropsylla cubana, Heteropsylla spinulosa, Homalodisca coagulata, Hyalopterus arundinis, Hyalopterus pruni, Icerya spp., Idiocerus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., Lepidosaphes spp., Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., Macrosteles facifrons, Mahanarva spp., Melanaphis sacchari, Metcalfiella spp., Metcalfa pruinosa, Metopolophium dirhodum, Monellia costalis, Monelliopsis pecanis, Myzus spp., Nasonovia ribisnigri, Neomaskellia spp., Nephotettix spp., Nettigoniclla spectra, Nilaparvata lugens, Oncometopia spp., Orthezia praelonga, Oxya chinensis, Pachypsylla spp., Parabemisia myricae, Paratrioza spp., Parlatoria spp., Pemphigus spp., Peregrinus maidis, Perkinsiella spp., Phenacoccus spp., Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp., Pinnaspis aspidistrae, Planococcus spp., Prosopidopsylla flava, Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus spp., Psyllopsis spp., Psylla spp., Pteromalus spp., Pulvinaria spp., Pyrilla spp., Quadraspidiotus spp., Quesada gigas, Rastrococcus spp., Rhopalosiphum spp., Saissetia spp., Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonocephela spp., Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp., Trialeurodes vaporariorum, Trioza spp., Typhlocyba spp., Unaspis spp., Viteus vitifolii, Zygina spp.; aus der Ordnung der Hymenoptera z.B. Acromyrmex spp., Athalia spp., Atta spp., Camponotus spp., Dolichovespula spp., Diprion spp., Hoplocampa spp., Lasius spp., Linepithema (Iridiomyrmex) humile, Monomorium pharaonis, Paratrechina spp., Paravespula spp., Plagiolepis spp., Sirex spp., Solenopsis invicta, Tapinoma spp., Technomyrmex albipes, Urocerus spp., Vespa spp., Wasmannia auropunctata, Xeris spp.,; aus der Ordnung der Isopoda z.B. Armadillidium vulgare, Oniscus asellus, Porcellio scaber; aus der Ordnung der Isoptera z.B. Coptotermes spp., Cornitermes cumulans, Cryptotermes spp., Incisitermes spp., Kalotermes spp., Microtermes obesi, Nasutitermes spp., Odontotermes spp., Porotermes spp.,Reticulitermes spp.; aus der Ordnung der Lepidoptera z.B. Achroia grisella, Acronicta major, Adoxophyes spp., Aedia leucomelas, Agrotis spp., Alabama spp., Amyelois transitella, Anarsia spp., Anticarsia spp., Argyroploce spp., Autographa spp., Barathra brassicae, Blastodacna atra, Borbo cinnara, Bucculatrix thurberiella, Bupalus piniarius, Busseola spp., Cacoecia spp., Caloptilia theivora, Capua reticulana, Carpocapsa pomonella, Carposina niponensis, Cheimatobia brumata, Chilo spp., Choreutis pariana, Choristoneura spp., Chrysodeixis chalcites, Clysia ambiguella, Cnaphalocerus spp., Cnaphalocrocis medinalis, Cnephasia spp., Conopomorpha spp., Conotrachelus spp., Copitarsia spp., Cydia spp., Dalaca noctuides, Diaphania spp., Diatraea saccharalis, Diparopsis spp., Earias spp., Ecdytolopha aurantium, Elasmopalpus lignosellus, Eidana saccharina, Ephestia spp., Epinotia spp., Epiphyas postvittana, Erannis spp., Erschoviella musculana, Etiella spp., Eudocima spp., Eulia spp., Eupoecilia ambiguella, Euproctis spp., Euxoa spp., Feltia spp., Galleria mellonella, Gracillaria spp., Grapholitha spp., Hedylepta spp., Helicoverpa spp., Heliothis spp., Hofmannophila pseudospretella, Homoeosoma spp., Homona spp., Hyponomeuta padella, Kakivoria flavofasciata, Lampides spp., Laphygma spp., Laspeyresia molesta, Leucinodes orbonalis, Leucoptera spp., Lithocolletis spp., Lithophane antennata, Lobesia spp., Loxagrotis albicosta, Lymantria spp., Lyonetia spp., Malacosoma neustria, Maruca spp., Maruca testulalis, Mamestra brassicae, Melanitis leda, Mocis spp., Monopis obviella, Mythimna separata, Nemapogon cloacellus, Nymphula spp., Oiketicus spp., Omphisa spp., Operophtera spp., Oria spp., Orthaga spp., Ostrinia spp., Panolis flammea, Parnara spp., Pectinophora spp., Perileucoptera spp., Phthorimaea spp., Phyllocnistis citrella, Phyllonorycter spp., Pieris spp., Platynota stultana, Plodia interpunctella, Plusia spp., Plutella xylostella, Prays spp., Prodenia spp., Protoparce spp., Pseudaletia spp., Pseudaletia unipuncta, Pseudoplusia includens, Pyrausta nubilalis, Rachiplusia nu, Schoenobius spp., Scirpophaga spp., Scirpophaga innotata, Scotia segetum, Sesamia spp., Sesamia inferens, Sparganothis spp., Spodoptera spp., Spodoptera praefica, Stathmopoda spp., Stenoma spp., Stomopteryx subsecivella, Synanthedon spp., Tecia solanivora, Thaumetopoea spp., Thermesia gemmatalis, Tinea cloacella, Tinea pellionella, Tineola bisselliella, Tortrix spp., Trichophaga tapetzella, Trichoplusia spp., Tryporyza incertulas, Tuta absoluta, Virachola spp.; aus der Ordnung der Orthoptera oder Saltatoria z.B. Acheta domesticus, Dichroplus spp., Gryllotalpa spp., Hieroglyphus spp., Locusta spp., Melanoplus spp., Paratlanticus ussuriensis, Schistocerca gregaria; aus der Ordnung der Phthiraptera z.B. Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Phylloera vastatrix, Phtirus pubis, Trichodectes spp.; aus der Ordnung der Psocoptera z.B. Lepinotus spp., Liposcelis spp.; aus der Ordnung der Siphonaptera z.B. Ceratophyllus spp., Ctenocephalides spp., Pulex irritans, Tunga penetrans, Xenopsylla cheopsis; aus der Ordnung der Thysanoptera z.B. Anaphothrips obscurus, Baliothrips biformis, Chaetanaphothrips leeuweni, Drepanothrips reuteri, Enneothrips flavens, Frankliniella spp., Haplothrips spp., Heliothrips spp., Hercinothrips femoralis, Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniothrips cardamomi, Thrips spp.; aus der Ordnung der Zygentoma (= Thysanura), z. B. Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus, Thermobia domestica; aus der Klasse der Symphyla z.B. Scutigerella spp.; Pests of the genus Arthropoda, in particular of the class Arachnida eg Acarus spp., Aceria kuko, Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Amphitetranychus viennensis, Argas spp., Boophilus spp., Brevipalpus spp. , Bryobia graminum, Bryobia praetiosa, Centruroides spp., Chorioptes spp., Dermanyssus gallinae, Dermatophagoides pteronyssinus, Dermatophagoides farinae, Dermacentor spp., Eotetranychus spp., Epitrimerus pyri, Eutetranychus spp., Eriophyes spp., Glycyphagus domesticus, Halotydeus destructor, Hemitarsonemus Spp., Hyalomma spp., Ixodes spp., Latrodectus spp., Loxosceles spp., Metatetranychus spp., Neutrombicula autumnalis, Nuphersa spp., Oligonychus spp., Ornithodorus spp., Ornithonyssus spp., Panonychus spp., Phyllocoptruta oleivora, Platytetranychus multidigituli, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Steneotarsonemus spp., Steneotarsonemus spinki, Tarsonemus spp., Tet ranychus spp., Trombicula alfreddugesi, Vaejovis spp., Vasates lycopersici .; from the genus of Chilopoda, for example Geophilus spp., Scutigera spp .; from the order or class of the Collembola eg Onychiurus armatus, Sminthurus viridis; from the class Diplopoda eg Blaniulus guttulatus; from the class of the Insecta, eg from the order of the Blattodea eg Blattella asahinai, Blattella germanica, Blatta orientalis, Leucophaea maderae (Rhypaobia maderae), Panchlora spp., Parcoblatta spp., Periplaneta spp., Supella longipalpa, Loboptera decipiens, Neostylopyga rhombifolia , Pycnoscelus surinamensis; from the order of the Coleoptera eg Acalymma vittatum, Acanthoscelides obtectus, Adoretus spp., Aethina tumida, Agelastica alni, Agriotes spp., Alphitobius diaperinus, Amphimallon solstitialis, Anobium punctatum, Anoplophora spp., Anthonomus spp., Anthrenus spp., Apion spp. , Apogonia spp., Atomaria spp., Attagenus spp., Baris caerulescens, Bruchidius obtectus, Bruchus spp., Cassida spp., Cerotoma trifurcata, Ceutorrhynchus spp., Chaetocnema spp., Cleonus mendicus, Conoderus spp., Cosmopolites spp., Costelytra zealandica, Ctenicera spp., Curculio spp., Cryptolestes ferruginus, Cryptorhynchus lapathi, Cylindrocopturus spp., Dermestes spp., Diabrotica spp., Dichocrocis spp., Dicladispa armigera, Diloboderus spp., Epicaerus spp., Epilachna spp., Epitrix spp. , Faustinus spp., Gibbium psylloides, Gnathocerus cornutus, Hellula and alis, Heteronychus arator, Heteronyx spp., Hylamorpha elegans, Hylotrupes bajulus, Hypera postica, Hypomeces squamosus, Hypothenemus spp., Lachnosterna consanguinea, Lasioderma serricorne, Latheticus oryzae, Lathridius spp., Lema spp., Leptinotarsa decemlineata, Leucoptera spp., Lissorhoptrus oryzophilus, Listronotus (= Hyperodes) spp. , Lixus spp., Luperodes spp., Luperomorpha xanthodera, Lyctus spp., Megascelis spp., Melanotus spp., Meligethes aeneus, Melolontha spp., Migdolus spp., Monochamus spp., Naupactus xanthographus, Necrobia spp., Neogalerucella spp. Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamensis, Oryzaphagus oryzae, Otiorrhynchus spp., Oulema spp., Oulema melanopus, Oulema oryzae, Oxycetonia jucunda, Phaedon cochleariae, Phyllophaga spp., Phyllophaga helleri, Phyllotreta spp., Popillia japonica, Premnotrypes spp. Prostephanus truncatus, Psylliodes spp., Ptinus spp., Rhizobius ventralis, Rhizopertha dominica, Rhynchophorus spp., Rhynchophorus ferrugineus, Rhynchophorus palmarum, Sinoxylon perforans, Sitophilus spp., Sitophilus oryzae, Sphenophorus spp., Stegobium paniceum, Starchus spp., Symphyletes spp., Tanymecus spp., Tenebrio molitor, Tenebrioides mauretanicus, Tribolium spp., Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus spp . from the order of Diptera eg Aedes spp., Agromyza spp., Anastrepha spp., Anopheles spp., Asphondylia spp., Bactrocera spp., Bibio hortulanus, Calliphora erythrocephala, Calliphora vicina, Ceratitis spp., Ceratitis capitata, Chironomus spp. Chrysomyia spp., Chrysops spp., Chrysozona pluvialis, Cochliomyia spp., Contarinia spp., Cordylobia anthropophaga, Cricotopus sylvestris, Culex spp., Culicoides spp., Culiseta spp., Cuterebra spp., Dacus oleae, Dasyneura spp., Delia spp Dermatobia hominis, Drosophila spp., Drosophila suzukii, Echinocnemus spp., Euleia heraclei, Fannia spp., Gasterophilus spp., Glossina spp., Haematopota spp., Hydrellia spp., Hydrellia griseola, Hylemya spp., Hippobosca spp. Hypoderma spp., Liriomyza spp., Lucilla spp., Lutzomyia spp., Mansonia spp., Musca spp., Oestrus spp., Oscinella frit, Paratanytarsus spp., Paralauterborniella subcincta, Pegomyia spp., Phlebotomus spp., Phorbia spp. Phormia spp., Piophila casei, Platyparea poeciloptera, Prodiplosis spp., P sila rosae, Rhagoletis spp., Sarcophaga spp., Simulium spp., Stomoxys spp., Tabanus spp., Tetanops spp., Tipula spp., Hippoboscoidea (= Pupipara), Toxotrypana curvicauda; from the suborder of the Heteroptera eg Aelia spp., Anasa tristis, Antestiopsis spp., Boisea spp., Blissus spp., Calocoris spp., Campylomma livida, Cavelerius spp., Cimex spp., Collaria spp., Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocoris hewetti, Dysdercus spp., Euschistus spp., Eurydema spp., Eurygaster spp., Halyomorpha halys, Heliopeltis spp., Horcias nobilellus, Leptocorisa spp., Leptocorisa varicornis, Leptoglossus occidentalis, Leptoglossus phyllopus, Lygocoris spp., Lygus Spp., Macropes excavatus, Megacopta cribraria, Miridae, Monaionion atratum, Nezara spp., Nysius spp., Oebalus spp., Pentomidae, Piesma quadrata, Piezodorus spp., Psallus spp., Pseudacysta persea, Rhodnius spp., Sahlbergella singularis, Scaptocoris castanea, Scotinophora spp., Stephanitis nashi, Tibraca spp., Triatoma spp .; from the order of the Hemiptera eg Acizzia acaciaebaileyanae, Acizzia dodonaeae, Acizzia uncatoides, Acrida turrita, Acyrthosipon spp., Acrogonia spp., Aeneolamia spp., Agonoscena spp., Aleurocanthus spp., Aleyrodes proletella, Aleurolobus barodensis, Aleurothrixus floccosus, Allocaridara malayensis, Amrasca spp., Anuraphis cardui, Aonidiella spp., Aphanostigma piri, Aphis spp., Arboridia apicalis, Arytainilla spp., Aspidiella spp., Aspidiotus spp., Atanus spp., Aulacorthum solani, Bemisia tabaci, Blastopsylla occidentalis, Boreioglycaspis melaleucae, Brachycaudus helichrysi, Brachycolus spp., Brevicoryne brassicae, Cacopsylla spp., Calligypona marginata , Capulonia spp., Carneocephala fulgida, Ceratovacuna lanigera, Cercopidae, Ceroplastes spp., Chaetosiphon fragaefolii, Chionaspis tegalensis, Chlorita onukii, Chondracris rosea, Chromaphis juglandicola, Chrysomphalus aonidum, Chrysomphalus ficus, Cicadulina mbila, Coccomytilus halli, Coccus spp., Cryptomyzus ribis , Cryptoneossa spp., Ctenarytaina spp., Dalbulus spp., Dialeurodes chittendeni, Dialeurodes citri, Diaphorina citri, Diasp is spp., Diuraphis spp., Drosicha spp., Dysaphis spp., Dysmicoccus spp., Empoasca spp., Eriosoma spp., Erythroneura spp., Eucalyptolyma spp., Euphyllura spp., Euscelis bilobatus, Ferrisia spp., Fiorinia spp. , Furcaspis oceanica, Geococcus coffeae, Glycaspis spp., Heteropsylla cubana, Heteropsylla spinulosa, Homalodisca coagulata, Hyalopterus arundinis, Hyalopterus pruni, Icerya spp., Idiocerus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., Lepidosaphes spp., Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., Macrosteles facifrons, Mahanarva spp., Melanaphis sacchari, Metcalfiella spp., Metcalfa pruinosa, Metopolophium dirhodum, Monellia costalis, Monelliopsis pecanis, Myzus spp., Nasonovia ribisnigri, Neomaskellia spp., Nephotettix spp., Nettigoniclla spectra, Nilaparvata lugens, Oncometopia spp., Orthezia praelonga, Oxya chinensis, Pachypsylla spp., Parabemisia myricae, Paratrioza spp., Parlatoria spp., Pemphigus spp., Peregrinus maidis, Pe rkinsiella spp., Phenacoccus spp., Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp., Pinnaspis aspidistrae, Planococcus spp., Prosopidopsylla flava, Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus spp., Psyllopsis spp., Psylla spp., Pteromalus spp. Pulvinaria spp., Pyrilla spp., Quadraspidiotus spp., Quesada gigas, Rastrococcus spp., Rhopalosiphum spp., Saissetia spp., Scaphoid titanus, Schizaphis graminum, Selenaspidus articulatus, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp. Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonocephela spp., Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp., Trialeurodes vaporariorum, Trioza spp., Typhlocyba spp., Unaspis spp., Viteus vitifolii, Zygina spp .; from the order of the Hymenoptera eg Acromyrmex spp., Athalia spp., Atta spp., Camponotus spp., Dolichovespula spp., Diprion spp., Hoplocampa spp., Lasius spp., Linepithema (Iridiomyrmex) humile, Monomorium pharaonis, Paratrechina spp. , Paravespula spp., Plagiolepis spp., Sirex spp., Solenopsis invicta, Tapinoma spp., Technomyrmex albipes, Urocerus spp., Vespa spp., Wasmannia auropunctata, Xeris spp.,; from the order of Isopoda, for example, Armadillidium vulgare, Oniscus asellus, Porcellio scaber; from the order of the Isoptera eg Coptotermes spp., Cornitermes cumulans, Cryptotermes spp., Incisitermes spp., Kalotermes spp., Microtermes obesi, Nasutitermes spp., Odontotermes spp., Porotermes spp., Reticulitermes spp .; from the order of Lepidoptera eg Achroia grisella, Acronica major, Adoxophyes spp., Aedia leucomelas, Agrotis spp., Alabama spp., Amyelois transitella, Anarsia spp., Anticarsia spp., Argyroploce spp., Autographa spp., Barathra brassicae, Blastodacna atra, Borbo cinnara, Bucculatrix thurberiella, Bupalus piniarius, Busseola spp., Cacoecia spp., Caloptilia theivora, Capua reticulana, Carpocapsa pomonella, Carposina niponensis, Cheimatobia brumata, Chilo spp., Choreutis pariana, Choristoneura spp., Chrysodixis chalcites, Clysia ambiguella , Cnaphalocerus spp., Cnaphalocrocis medinalis, Cnephasia spp., Conopomorpha spp., Conotrachelus spp., Copitarsia spp., Cydia spp., Dalaca noctuides, Diaphania spp., Diacraea saccharalis, Diparopsis spp., Earias spp., Ecdytolopha aurantium, Elasmopalpus lignosellus, Eidana saccharina, Ephestia spp., Epinotia spp., Epiphyas postvittana, Erannis spp., Erschoviella musculana, Etiella spp., Eudocima spp., Eulia spp., Eupoecilia ambiguella, Euproctis spp. Euxoa spp., Feltia spp., Galleria mellonella, Gracillaria spp., Grapholitha spp., Hedylepta spp., Helicoverpa spp., Heliothis spp., Hofmannophila pseudospretella, Homoeosoma spp., Homona spp., Hyponomeuta padella, Kakivoria flavofasciata, Lampides spp , Laphygma spp., Laspeyresia molesta, Leucinodes orbonalis, Leucoptera spp., Lithocolletis spp., Lithophane antennata, Lobesia spp., Loxagrotis albicosta, Lymantria spp., Lyonetia spp., Malacosoma neustria, Maruca spp., Maruca testulalis, Mamestra brassicae , Melanitis leda, Mocis spp., Monopis obviella, Mythimna separata, Nemapogon cloacellus, Nymphula spp., Oiketicus spp., Omphisa spp., Operophtera spp., Oria spp., Orthaga spp., Ostrinia spp., Panolis flammea, Parnara spp , Pectinophora spp., Perileucoptera spp., Phthorimaea spp., Phyllocnis citrella, Phyllonorycter spp., Pieris spp., Platynota stultana, Plodia interpunctella, Plusia spp., Plutella xylostella, Prays spp., Prodenia spp., Protoparce spp. Pseudaletia spp., Pseudaletia Unipuncta, Pseudoplusia includens, Pyrausta nubilalis, Rachiplusia nu, Schoenobius spp., Scirpophaga spp., Scirpophaga innotata, Scotia segetum, Sesamia spp., Sesamia inferens, Sparganothis spp., Spodoptera spp., Spodoptera praefica, Stathmopoda spp., Stenoma spp. Stomopteryx subsecivella, Synanthedon spp., Tecia solanivora, Thaumetopoea spp., Thermesia gemmatalis, Tinea cloacella, Tinea pellionella, Tineola bisselliella, Tortrix spp., Trichophaga tapetzella, Trichoplusia spp., Tryporyza incertulas, Tuta absoluta, Virachola spp .; from the order of Orthoptera or Saltatoria eg Acheta domesticus, Dichroplus spp., Gryllotalpa spp., Hieroglyphus spp., Locusta spp., Melanoplus spp., Paratlanticus ussuriensis, Schistocerca gregaria; from the order of Phthiraptera eg Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Phylloera vastatrix, Phtirus pubis, Trichodectes spp .; from the order of Psocoptera eg Lepinotus spp., Liposcelis spp .; from the order of Siphonaptera, for example Ceratophyllus spp., Ctenocephalides spp., Pulex irritans, Tunga penetrans, Xenopsylla cheopsis; from the order of the Thysanoptera, for example, Anaphothrips obscurus, Baliothrips biformis, Chaetanaphothrips leeuweni, Drepanothrips reuteri, Enneothris flavens, Frankliniella spp., Haplothrips spp., Heliothrips spp., Hercinothrips femoralis, Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniothrips cardamomi, Thrips spp .; from the order of Zygentoma (= Thysanura), z. Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus, Thermobia domestica; from the class of Symphyla eg Scutigerella spp .;
Schädlinge aus dem Stamm der Mollusca, insbesondere aus der Klasse der Bivalvia, z.B. Dreissena spp., sowie aus der Klasse der Gastropoda z.B. Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Pomacea spp., Succinea spp.; Pests of the Mollusca strain, in particular of the bivalve class, e.g. Dreissena spp., As well as from the class Gastropoda e.g. Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Pomacea spp., Succinea spp .;
Tierparasiten aus den Stämmen der Plathelminthes und Nematoda, z.B. Aelurostrongylus spp., Amidostomum spp., Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Angiostrongylus spp., Anisakis spp., Anoplocephala spp., Ascaris spp., Ascaridia spp., Baylisascaris spp., Brugia malayi, Brugia timori, Bunostomum spp., Capillaria spp., Chabertia spp., Clonorchis spp., Cooperia spp., Crenosoma spp., Cyathostoma spp., Dicrocoelium spp., Dictyocaulus filaria, Diphyllobothrium latum, Dipylidium spp., Dirofilaria spp., Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Eucoleus spp., Fasciola spp., Fascioloides spp., Fasciolopsis spp., Filaroides spp., Gongylonema spp., Gyrodactylus spp., Habronema spp., Haemonchus spp., Heligmosomoides spp., Heterakis spp., Hymenolepis nana, Hyostrongulus spp., Litomosoides spp., Loa Loa, Metastrongylus spp., Metorchis spp., Mesocestoides spp., Moniezia spp., Muellerius spp., Necator spp., Nematodirus spp., Nippostrongylus spp., Oesophagostomum spp., Ollulanus spp., Onchocerca volvulus, Opisthorchis spp., ., Oslerus spp., Ostertagia spp., Oxyuris spp., Paracapillaria spp., Parafilaria spp., Paragonimus spp., Paramphistomum spp., Paranoplocephala spp., Parascaris spp., Passalurus spp., Protostrongylus spp., Schistosoma spp., Setaria spp., Spirocerca spp., Stephanofilaria spp., Stephanurus spp., Strongyloides fuelleborni, Strongyloides stercoralis, Strongylus spp., Syngamus spp., Taenia saginata, Taenia solium, Teladorsagia spp., Thelazia spp., Toxascaris spp., Toxocara spp., Trichinella spiralis, Trichinella nativa, Trichinella britovi, Trichinella nelsoni, Trichinella pseudopsiralis, Trichobilharzia spp., Trichostrongylus spp., Trichuris trichuria, Uncinaria spp., Wuchereria bancrofti; Animal parasites from the strains of Plathelminthes and Nematoda, e.g. Aelurostrongylus spp., Amidostomum spp., Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Angiostrongylus spp., Anisakis spp., Anoplocephala spp., Ascaris spp., Ascaridia spp., Baylisascaris spp., Brugia malayi, Brugia timori , Bunostomum spp., Capillaria spp., Chabertia spp., Clonorchis spp., Cooperia spp., Crenosoma spp., Cyathostoma spp., Dicrocoelium spp., Dictyocaulus filaria, Diphyllobothrium latum, Dipylidium spp., Dirofilaria spp., Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Eucoleus spp., Fasciola spp., Fascioloides spp., Fasciolopsis spp., Filaroides spp., Gongylonema spp., Gyrodactylus spp., Habronema spp., Haemonchus spp., Heligmosomoides spp., Heterakis spp., Hymenolepis nana, Hyostrongulus spp., Litomosoides spp., Loa Loa, Metastrongylus spp., Metorchis spp., Mesocestoides spp., Moniezia spp., Muellerius spp., Necator spp., Nematodirus spp., Nippostrongylus spp., Oesophagost omum spp., Ollulanus spp., Onchocerca volvulus, Opisthorchis spp.,., Oslerus spp., Ostertagia spp., Oxyuris spp., Paracapillaria spp., Parafilaria spp., Paragonimus spp., Paramphistomum spp., Paranoplocephala spp., Parascaris Spp., Passalurus spp., Protostrongylus spp., Schistosoma spp., Setaria spp., Spirocerca spp., Stephanofilaria spp., Stephanurus spp., Strongyloides fuelleborni, Strongyloides stercoralis, Strongylus spp., Syngamus spp., Taenia saginata, Taenia solium , Teladorsagia spp., Thelazia spp., Toxascaris spp., Toxocara spp., Trichinella spiralis, Trichinella nativa, Trichinella britovi, Trichinella nelsoni, Trichinella pseudopsiralis, Trichobilharzia spp., Trichostrongylus spp., Trichuris trichuria, Uncinaria spp., Wuchereria bancrofti;
Pflanzenschädlinge aus dem Stamm der Nematoda, d.h. pflanzenparasitäre Nematoden, insbesondere Aglenchus spp., Anguina spp., Aphelenchoides spp., Belonolaimus spp., Bursaphelenchus spp., Cacopaurus spp., Criconemella spp., Criconemoides spp., Ditylenchus spp., Dolichodorus spp., Globodera spp., Helicotylenchus spp., Hemicriconemoides spp., Hemicycliophora spp., Heterodera spp., Hoplolaimus spp., Longidorus spp., Meloidogyne spp., Meloinema spp., Nacobbus spp., Neotylenchus spp., Paralongidorus spp., Paraphelenchus spp., Paratrichodorus spp., Pratylenchus spp., Pseudohalenchus spp., Psilenchus spp., Punctodera spp., Quinisulcius spp., Radopholus spp., Rotylenchulus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp., Tylenchulus spp., Tylenchorhynchus spp., Xiphinema spp; Plant pests of the Nematoda strain, ie plant parasitic nematodes, in particular Aglenchus spp., Anguina spp., Aphelenchoides spp., Belonolaimus spp., Bursaphelenchus spp., Cacopaurus spp., Criconemella spp., Criconemoides spp., Ditylenchus spp., Dolichodorus spp ., Globodera spp., Helicotylenchus spp., Hemicriconemoides spp., Hemicycliophora spp., Heterodera spp., Hoplolaimus spp., Longidorus spp., Meloidogyne spp., Meloinema spp., Nacobbus spp., Neotylenchus spp., Paralongidorus spp., Paraphelenchus spp , Paratrichodorus spp., Pratylenchus spp., Pseudohalenchus spp., Psilenchus spp., Punctodera spp., Quinisulcius spp., Radopholus spp., Rotylenchulus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp. Tylenchulus spp., Tylenchorhynchus spp., Xiphinema spp;
Weiterhin lässt sich aus dem Unterreich der Protozoa die Ordnung der Coccidia z.B. Eimeria spp. bekämpfen. Furthermore, from the sub-kingdom of protozoa, the order of coccidia can be determined, e.g. Eimeria spp. fight.
Die erfindungsgemäßen Wirkstoffkombinationen, insbesondere die in der Tabelle A genannten, weisen eine erhöhte mikrobizide Wirkung auf und können zur Bekämpfung von unerwünschten Mikroorganismen, wie Fungi und Bakterien, im Pflanzenschutz und im Materialschutz eingesetzt werden. The active compound combinations according to the invention, in particular those mentioned in Table A, have an increased microbicidal activity and can be used for controlling unwanted microorganisms, such as fungi and bacteria, in crop protection and in the protection of materials.
Fungizide lassen sich Pflanzenschutz zur Bekämpfung von Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes und Deuteromycetes einsetzen. Bakterizide lassen sich im Pflanzenschutz zur Bekämpfung von Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae und Streptomycetaceae einsetzen. Fungicides can be used for the control of Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes. Bactericides can be used in crop protection for controlling Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae and Streptomycetaceae.
Beispielhaft aber nicht begrenzend seien einige Erreger von pilzlichen und bakteriellen Erkrankungen, die unter die oben aufgezählten Oberbegriffe fallen, genannt: By way of example but not limitation, some pathogens of fungal and bacterial diseases, which fall under the above-enumerated generic terms, are named:
Erkrankungen, hervorgerufen durch Erreger des Echten Mehltaus wie z.B. Blumeria- Arten, wie beispielsweise Blumeria graminis; Diseases caused by powdery mildews such as e.g. Blumeria species such as Blumeria graminis;
Podosphaera-Arten, wie beispielsweise Podosphaera leucotricha; Podosphaera species, such as Podosphaera leucotricha;
Sphaerotheca- Arten, wie beispielsweise Sphaerotheca fuliginea; Sphaerotheca species, such as Sphaerotheca fuliginea;
Uncinula-Arten, wie beispielsweise Uncinula necator; Uncinula species, such as Uncinula necator;
Erkrankungen, hervorgerufen durch Erreger von Rostkrankheiten wie z.B. Gymnosporangium- Arten, wie beispielsweise Gymnosporangium sabinae Diseases caused by causative agents of rust diseases, such as Gymnosporangium species such as Gymnosporangium sabinae
Hemileia- Arten, wie beispielsweise Hemileia vastatrix; Hemileia species, such as Hemileia vastatrix;
Phakopsora- Arten, wie beispielsweise Phakopsora pachyrhizi und Phakopsora meibomiae; Puccinia- Arten, wie beispielsweise Puccinia recondita; Phakopsora species such as Phakopsora pachyrhizi and Phakopsora meibomiae; Puccinia species, such as Puccinia recondita;
Uromyces -Arten, wie beispielsweise Uromyces appendiculatus;  Uromyces species, such as Uromyces appendiculatus;
Erkrankungen, hervorgerufen durch Erreger der Gruppe der Oomyceten wie z.B. Diseases caused by pathogens of the group of Oomycetes, e.g.
Bremia- Arten, wie beispielsweise Bremia lactucae; Bremia species such as Bremia lactucae;
Peronospora- Arten, wie beispielsweise Peronospora pisi oder P. brassicae;Peronospora species such as Peronospora pisi or P. brassicae;
Phytophthora- Arten, wie beispielsweise Phytophthora infestans; Phytophthora species, such as Phytophthora infestans;
Plasmopara-Arten, wie beispielsweise Plasmopara viticola;  Plasmopara species, such as Plasmopara viticola;
Pseudoperonospora- Arten, wie beispielsweise Pseudoperonospora humuli oder Pseudoperonospora species, such as Pseudoperonospora humuli or
Pseudoperonospora cubensis; Pseudoperonospora cubensis;
Pythium- Arten, wie beispielsweise Pythium ultimum; Pythium species such as Pythium ultimum;
Blattfleckenkrankheiten und Blattwelken, hervorgerufen durch z.B.  Leaf spot diseases and leaf wilt caused by e.g.
Alternaria-Arten, wie beispielsweise Alternaria solani;  Alternaria species, such as Alternaria solani;
Cercospora-Arten, wie beispielsweise Cercospora beticola;  Cercospora species, such as Cercospora beticola;
Cladosporium- Arten, wie beispielsweise Cladosporium cucumerinum;  Cladosporium species, such as Cladosporium cucumerinum;
Cochliobolus-Arten, wie beispielsweise Cochliobolus sativus Cochliobolus species, such as Cochliobolus sativus
(Konidienform: Drechslera, Syn: Helminthosporium);  (Conidia form: Drechslera, Syn: Helminthosporium);
Colletotrichum- Arten, wie beispielsweise Colletotrichum lindemuthanium; Colletotrichum species, such as Colletotrichum lindemuthanium;
Cycloconium- Arten, wie beispielsweise Cycloconium oleaginum; Cycloconium species such as cycloconium oleaginum;
Diaporthe- Arten, wie beispielsweise Diaporthe citri;  Slide types such as Diaporthe citri;
Elsinoe- Arten, wie beispielsweise Elsinoe fawcettii; Elsinoe species, such as Elsinoe fawcettii;
Gloeosporium- Arten, wie beispielsweise Gloeosporium laeticolor;  Gloeosporium species, such as, for example, Gloeosporium laeticolor;
Glomerella-Arten, wie beispielsweise Glomerella cingulata;  Glomerella species, such as Glomerella cingulata;
Guignardia- Arten, wie beispielsweise Guignardia bidwelli; Leptosphaeria- Arten, wie beispielsweise Leptosphaeria maculans; Guignardia species, such as Guignardia bidwelli; Leptosphaeria species, such as Leptosphaeria maculans;
Magnaporthe- Arten, wie beispielsweise Magnaporthe grisea; Magnaporthe species, such as Magnaporthe grisea;
Mycosphaerella- Arten, wie beispielsweise Mycosphaerella graminicola und Mycosphaerella fijiensis; Mycosphaerella species, such as Mycosphaerella graminicola and Mycosphaerella fijiensis;
Phaeosphaeria- Arten, wie beispielsweise Phaeosphaeria nodorum; Phaeosphaeria species, such as Phaeosphaeria nodorum;
Pyrenophora- Arten, wie beispielsweise Pyrenophora teres; Pyrenophora species, such as, for example, Pyrenophora teres;
Ramularia- Arten, wie beispielsweise Ramularia collo-cygni;  Ramularia species, such as Ramularia collo-cygni;
Rhynchosporium- Arten, wie beispielsweise Rhynchosporium secalis;  Rhynchosporium species, such as Rhynchosporium secalis;
Septoria- Arten, wie beispielsweise Septoria apii;  Septoria species, such as Septoria apii;
Typhula- Arten, wie beispielsweise Typhula incarnata;  Typhula species, such as Typhula incarnata;
Venturia- Arten, wie beispielsweise Venturia inaequalis; Venturia species such as Venturia inaequalis;
Wurzel- und Stängelkrankheiten, hervorgerufen durch z.B.  Root and stem diseases caused by e.g.
Corticium- Arten, wie beispielsweise Corticium graminearum;  Corticium species, such as Corticium graminearum;
Fusarium- Arten, wie beispielsweise Fusarium oxysporum;  Fusarium species such as Fusarium oxysporum;
Gaeumannomyces -Arten, wie beispielsweise Gaeumannomyces graminis;  Gaeumannomyces species such as Gaeumannomyces graminis;
Rhizoctonia- Arten, wie beispielsweise Rhizoctonia solani; Rhizoctonia species, such as Rhizoctonia solani;
Tapesia- Arten, wie beispielsweise Tapesia acuformis;  Tapesia species, such as Tapesia acuformis;
Thielaviopsis-Arten, wie beispielsweise Thielaviopsis basicola;  Thielaviopsis species, such as Thielaviopsis basicola;
Ähren- und Rispenerkrankungen (inklusive Maiskolben), hervorgerufen durch z.B.  Ear and panicle diseases (including corncob) caused by e.g.
Alternaria-Arten, wie beispielsweise Alternaria spp.;  Alternaria species, such as Alternaria spp .;
Aspergillus-Arten, wie beispielsweise Aspergillus flavus; Aspergillus species, such as Aspergillus flavus;
Cladosporium- Arten, wie beispielsweise Cladosporium cladosporioides;  Cladosporium species, such as Cladosporium cladosporioides;
Claviceps-Arten, wie beispielsweise Claviceps purpurea;  Claviceps species, such as Claviceps purpurea;
Fusarium- Arten, wie beispielsweise Fusarium culmorum; Gibberella- Arten, wie beispielsweise Gibberella zeae; Fusarium species such as Fusarium culmorum; Gibberella species, such as Gibberella zeae;
Monographella- Arten, wie beispielsweise Monographella nivalis; Monographella species such as Monographella nivalis;
Erkrankungen, hervorgerufen durch Brandpilze wie z.B. Diseases caused by fire fungi, e.g.
Sphacelotheca- Arten, wie beispielsweise Sphacelotheca reiliana; Sphacelotheca species, such as Sphacelotheca reiliana;
Tilletia- Arten, wie beispielsweise Tilletia caries; Tilletia species such as Tilletia caries;
Urocystis-Arten, wie beispielsweise Urocystis occulta;  Urocystis species, such as Urocystis occulta;
Ustilago-Arten, wie beispielsweise Ustilago nuda; Ustilago species such as Ustilago nuda;
Fruchtfäule hervorgerufen durch z.B. Fruit rot caused by e.g.
Aspergillus-Arten, wie beispielsweise Aspergillus flavus; Aspergillus species, such as Aspergillus flavus;
Botrytis-Arten, wie beispielsweise Botrytis cinerea; Botrytis species, such as Botrytis cinerea;
Penicillium- Arten, wie beispielsweise Penicillium expansum und Penicillium purpurogenum;  Penicillium species such as Penicillium expansum and Penicillium purpurogenum;
Sclerotinia- Arten, wie beispielsweise Sclerotinia sclerotiorum; Sclerotinia species, such as Sclerotinia sclerotiorum;
Verticilium- Arten, wie beispielsweise Verticilium alboatrum; Verticilium species such as Verticilium alboatrum;
Samen- und bodenbürtige Fäulen und Welken, sowie Sämlingserkrankungen, hervorgerufen durch z.B. Fusarium- Arten, wie beispielsweise Fusarium culmorum;  Seed and soil rots and wilts, as well as seedling diseases caused by e.g. Fusarium species such as Fusarium culmorum;
Phytophthora Arten, wie beispielsweise Phytophthora cactorum;  Phytophthora species, such as Phytophthora cactorum;
Pythium- Arten, wie beispielsweise Pythium ultimum;  Pythium species such as Pythium ultimum;
Rhizoctonia- Arten, wie beispielsweise Rhizoctonia solani;  Rhizoctonia species, such as Rhizoctonia solani;
Sclerotium- Arten, wie beispielsweise Sclerotium rolfsii;  Sclerotium species, such as Sclerotium rolfsii;
Krebserkrankungen, Gallen und Hexenbesen, hervorgerufen durch z.B. Cancers, galls and witches brooms caused by e.g.
Nectria-Arten, wie beispielsweise Nectria galligena;  Nectria species, such as Nectria galligena;
Welkeerkrankungen hervorgerufen durch z.B.  Wilt diseases caused by e.g.
Monilinia- Arten, wie beispielsweise Monilinia laxa; Deformationen von Blättern, Blüten und Früchten, hervorgerufen durch z.B. Monilinia species such as Monilinia laxa; Deformations of leaves, flowers and fruits, caused by eg
Taphrina- Arten, wie beispielsweise Taphrina deformans; Degenerationserkrankungen holziger Pflanzen, hervorgerufen durch z.B. Taphrina species, such as Taphrina deformans; Degenerative diseases of woody plants caused by e.g.
Esca-Arten, wie beispielsweise Phaeomoniella chlamydospora und Phaeoacremonium aleophilum und Fomitiporia mediterranea; Esca species such as Phaeomoniella chlamydospora and Phaeoacremonium aleophilum and Fomitiporia mediterranea;
Blüten- und Samenerkrankungen, hervorgerufen durch z.B. Flower and seed diseases caused by e.g.
Botrytis-Arten, wie beispielsweise Botrytis cinerea; Botrytis species, such as Botrytis cinerea;
Erkrankungen von Pflanzenknollen, hervorgerufen durch z.B. Diseases of plant tubers caused by e.g.
Rhizoctonia- Arten, wie beispielsweise Rhizoctonia solani; Helminthosporium- Arten, wie beispielsweise Helminthosporium solani; Rhizoctonia species, such as Rhizoctonia solani; Helminthosporium species, such as Helminthosporium solani;
Erkrankungen, hervorgerufen durch bakterielle Erreger wie z.B. Diseases caused by bacterial agents such as e.g.
Xanthomonas-Arten, wie beispielsweise Xanthomonas campestris pv. oryzae; Xanthomonas species, such as Xanthomonas campestris pv. Oryzae;
Pseudomonas-Arten, wie beispielsweise Pseudomonas syringae pv. lachrymans; Pseudomonas species, such as Pseudomonas syringae pv. Lachrymans;
Erwinia-Arten, wie beispielsweise Erwinia amylovora; Bevorzugt können die folgenden Krankheiten von Soja-Bohnen bekämpft werden: Erwinia species, such as Erwinia amylovora; Preferably, the following diseases of soybean beans can be controlled:
Pilzkrankheiten an Blättern, Stängeln, Schoten und Samen verursacht durch z.B. Fungal diseases on leaves, stems, pods and seeds caused by e.g.
Alternaria leaf spot (Alternaria spec. atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var. truncatum), Brown spot (Septoria glycines), Cercospora leaf spot and blight (Cercospora kikuchii), Choanephora leaf blight (Choanephora infundibulifera trispora (Syn.)), Dactuliophora leaf spot (Dactuliophora glycines), Downy Mildew (Peronospora manshurica), Drechslera blight (Drechslera glycini), Frogeye Leaf spot (Cercospora sojina), Leptosphaerulina Leaf Spot (Leptosphaerulina trifolii), Phyllostica Leaf Spot (Phyllosticta sojaecola), Pod and Stem Blight (Phomopsis sojae), Powdery Mildew (Microsphaera diffusa), Pyrenochaeta Leaf Spot (Pyrenochaeta glycines), Rhizoctonia Aerial, Foliage, and Web Blight (Rhizoctonia solani), Rust (Phakopsora pachyrhizi), Scab (Sphaceloma glycines), Stemphylium Leaf Blight (Stemphylium botryosum), Target Spot (Corynespora cassiicola) Alternaria leaf spot (Alternaria spec. Atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var. Truncatum), Brown spot (Septoria glycines), Cercospora leaf spot and blight (Cercospora kikuchii), Choanephora leaf blight (Choanephora infundibulifera trispora (Syn.)) , Dactuliophora leaf spot (Dactuliophora glycines), Downy Mildew (Peronospora manshurica), Drechslera blight (Drechslera glycini), Frogeye leaf spot (Cercospora sojina), Leptosphaerulina leaf spot (Leptosphaerulina trifolii), Phyllostica leaf spot (Phyllosticta sojaecola), Pod and Stem Blight (Phomopsis sojae), Powdery Mildew (Microsphaera diffusa), Pyrenochaeta Leaf Spot (Pyrenochaeta glycines), Rhizoctonia Aerial, Foliage, and Web Blight (Rhizoctonia solani), Rust (Phakopsora pachyrhizi), Scab (Sphaceloma glycines), Stemphylium Leaf Blight ( Stemphylium botryosum), Target Spot (Corynespora cassiicola)
Pilzkrankheiten an Wurzeln und der Stängelbasis verursacht durch z.B. Black Root Rot (Calonectria crotalariae), Charcoal Rot (Macrophomina phaseolina), Fusarium Blight or Wilt, Root Rot, and Pod and Collar Rot (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), Mycoleptodiscus Root Rot (Mycoleptodiscus terrestris), Neocosmo- spora (Neocosmopspora vasinfecta), Pod and Stern Blight (Diaporthe phaseolorum), Stern Canker (Diaporthe phaseolorum var. caulivora), Phytophthora Rot (Phytophthora megasperma), Brown Stern Rot (Phialophora gregata), Pythium Rot (Pythium aphanidermatum, Pythium irreguläre, Pythium debaryanum, Pythium myriotylum, Pythium ultimum), Rhizoctonia Root Rot, Stern Decay, and Damping-Off (Rhizoctonia solani), Sclerotinia Stern Decay (Sclerotinia sclerotiorum), Sclerotinia Southern Blight (Sclerotinia rolfsii), Thielaviopsis Root Rot (Thielaviopsis basicola). Die vorliegende Erfindung betrifft weiterhin Formulierungen und daraus bereitete Anwendungsformen als Pflanzenschutzmittel und/oder Schädlingsbekämpfungsmittel wie z. B. Drench-, Drip- und Spritzbrühen, umfassend mindestens eine der erfindungsgemäßen Wirkstoffkombinationen. Gegebenenfalls enthalten die Anwendungsformen weitere Pflanzenschutzmittel und/oder Schädlingsbekämpfungsmittel und/oder die Wirkung verbessernde Adjuvantien wie Penetrationsförderer, z. B. vegetative Öle wie beispielsweise Rapsöl, Sonnenblumenöl, Mineralöle wie beispielsweise Paraffinöle, Alkylester vegetativer Fettsäuren wie beispielsweise Rapsöl- oder Sojaölmethylester oder Alkanol-alkoxylate und/oder Spreitmittel wie beispielsweise Alkylsiloxane und/oder Salze z. B. organische oder anorganische Ammonium- oder Phosphoniumsalze wie beispielsweise Ammoniumsulfat oder Diammonium-hydrogenphosphat und /oder die Retention fördernde Mittel wie z. B. Dioctylsulfosuccinat oder Hydroxypropyl-guar Polymere und/oder Humectants wie z. B. Glycerin und / oder Dünger wie beispielsweise Ammonium-, Kalium- oder Phosphor-enthaltende Dünger. Fungal diseases at roots and stem base caused by eg Black Root Red (Calonectria crotalariae), Charcoal Red (Macrophomina phaseolina), Fusarium Blight or Wilt, Root Red, and Pod and Collar Red (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), Mycoleptodiscus Root Red (Mycoleptodiscus terrestris), Neocosmophora (Neocosmopspora vasinfecta), Pod and Star Blight (Diaporthe phaseolorum), Star Canker (Diaporthe phaseolorum var. Caulivora), Phytophthora red (Phytophthora megasperma), Brown Star Red (Phialophora gregata), Pythium Red (Pythium aphanidermatum, Pythium irregular , Pythium debaryanum, Pythium myriotylum, Pythium ultimum), Rhizoctonia Root Red, Star Decay, and Damping Off (Rhizoctonia solani), Sclerotinia Star Decay (Sclerotinia sclerotiorum), Sclerotinia Southern Blight (Sclerotinia rolfsii), Thielaviopsis Root Red (Thielaviopsis basicola) , The present invention further relates to formulations and application forms prepared therefrom as crop protection agents and / or pesticides such. B. drench, drip and spray, comprising at least one of the active compound combinations according to the invention. If appropriate, the use forms contain other crop protection agents and / or pesticides and / or the effect of improving adjuvants such as penetration enhancers, eg. As vegetative oils such as rapeseed oil, sunflower oil, mineral oils such as paraffin oils, alkyl esters of vegetable fatty acids such as rapeseed oil or soybean oil or alkanol alkoxylates and / or spreading agents such as alkyl siloxanes and / or salts z. As organic or inorganic ammonium or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate and / or retention-promoting agents such. As dioctylsulfosuccinate or hydroxypropyl guar polymers and / or humectants such. As glycerol and / or fertilizers such as ammonium, potassium or phosphorus-containing fertilizer.
Übliche Formulierungen sind beispielsweise wasserlösliche Flüssigkeiten (SL), Emulsionskonzentrate (EC), Emulsionen in Wasser (EW), Suspensionskonzentrate (SC, SE, FS, OD), in Wasser dispergierbare Granulate (WG), Granulate (GR) und Kapselkonzentrate (CS); diese und weitere mögliche Formuliertypen sind beispielsweise durch Crop Life International und in Pesticide Specifications, Manual on development and use of FAO and WHO specifications for pesticides, FAO Plant Production and Protection Papers - 173, prepared by the FAO/WHO Joint Meeting on Pesticide Specifications, 2004, ISBN: 9251048576 beschrieben. Gegebenenfalls enthalten die Formulierungen neben einem oder mehreren erfindungsgemäßen Wirkstoffen weitere agrochemische Wirkstoffe. Typical formulations are, for example, water-soluble liquids (SL), emulsion concentrates (EC), emulsions in water (EW), suspension concentrates (SC, SE, FS, OD), water-dispersible granules (WG), granules (GR) and capsule concentrates (CS). ; These and other possible formulation types are described, for example, by Crop Life International and in Pesticide Specifications, Manual on Development and Use of FAO and WHO Specifications for Pesticides, FAO Plant Production and Protection Papers - 173, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2004, ISBN: 9251048576. If appropriate, the formulations contain, in addition to one or more active compounds according to the invention, further agrochemical active substances.
Vorzugsweise handelt es sich um Formulierungen oder Anwendungsformen, welche Hilfsstoffe, wie beispielsweise Streckmittel, Lösemittel, Spontanitätsförderer, Trägerstoffe, Emulgiermittel, Dispergiermittel, Frostschutzmittel, Biozide, Verdicker und/oder weitere Hilfsstoffe, wie beispielsweise Adjuvantien enthalten. Ein Adjuvant in diesem Kontext ist eine Komponente, die die biologische Wirkung der Formulierung verbessert, ohne dass die Komponente selbst eine biologische Wirkung hat. Beispiele für Adjuvantien sind Mittel, die die Retention, das Spreitverhalten, das Anhaften an der Blattoberfläche oder die Penetration fördern. They are preferably formulations or use forms which contain auxiliaries, such as extenders, solvents, spontaneity promoters, carriers, emulsifiers, dispersants, antifreeze agents, biocides, thickeners and / or further auxiliaries, such as adjuvants. An adjuvant in this context is a component that enhances the biological effect of the formulation without the component itself having a biological effect. Examples of adjuvants are agents that promote retention, spreading behavior, adherence to the leaf surface, or penetration.
Diese Formulierungen werden in bekannter Weise hergestellt, z.B. durch Vermischen der Wirkstoffe mit Hilfsstoffen wie beispielsweise Streckmitteln, Lösemitteln und/oder festen Trägerstoffen und/oder weiteren Hilfsstoffen wie beispielsweise oberflächenaktive Stoffe. Die Herstellung der Formulierungen erfolgt entweder in geeigneten Anlagen oder auch vor oder während der Anwendung. These formulations are prepared in a known manner, e.g. by mixing the active ingredients with excipients such as extenders, solvents and / or solid carriers and / or other excipients such as surfactants. The preparation of the formulations is carried out either in suitable systems or before or during use.
Als Hilfsstoffe können solche Stoffe Verwendung finden, die geeignet sind, der Formulierung des Wirkstoffs oder den aus diesen Formulierungen bereiteten Anwendungsformen (wie z.B. gebrauchsfähigen Pflanzenschutzmitteln wie Spritzbrühen oder Saatgutbeizen) besondere Eigenschaften, wie bestimmte physikalische, technische und/oder biologische Eigenschaften, zu verleihen. As excipients there may be used those substances which are suitable for conferring special properties, such as certain physical, technical and / or biological properties, to the formulation of the active substance or to the forms of use prepared from these formulations (for example usable plant protection agents such as spray or seed dressing).
Als Streckmittel eignen sich z.B. Wasser, polare und unpolare organische chemische Flüssigkeiten z.B. aus den Klassen der aromatischen und nicht-aromatischen Kohlenwasserstoffe (wie Paraffine, Alkylbenzole, Alkylnaphthaline, Chlorbenzole), der Alkohole und Polyole (die ggf. auch substituiert, verethert und/oder verestert sein können), der Ketone (wie Aceton, Cyclohexanon), Ester (auch Fette und Öle) und (Poly-)Ether, der einfachen und substituierten Amine, Amide, Lactame (wie N- Alkylpyrrolidone) und Lactone, der Sulfone und Sulfoxide (wie Dimethylsulfoxid). As extender, e.g. Water, polar and non-polar organic chemical liquids e.g. from the classes of aromatic and non-aromatic hydrocarbons (such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes), alcohols and polyols (which may also be substituted, etherified and / or esterified), ketones (such as acetone, cyclohexanone), Esters (including fats and oils) and (poly) ethers, simple and substituted amines, amides, lactams (such as N-alkylpyrrolidones) and lactones, sulfones and sulfoxides (such as dimethylsulfoxide).
Im Falle der Benutzung von Wasser als Streckmittel können z.B. auch organische Lösemittel als Hilfslösemittel verwendet werden. Als flüssige Lösemittel kommen im Wesentlichen infrage: Aromaten, wie Xylol, Toluol oder Alkylnaphthaline, chlorierte Aromaten oder chlorierte aliphatische Kohlenwas- serstoffe, wie Chlorbenzole, Chlorethylene oder Methylenchlorid, aliphatische Kohlenwasserstoffe, wie Cyclohexan oder Paraffine, z.B. Erdölfraktionen, mineralische und pflanzliche Öle, Alkohole, wie Butanol oder Glykol sowie deren Ether und Ester, Ketone, wie Aceton, Methylethylketon, Meth- ylisobutylketon oder Cyclohexanon, stark polare Lösemittel wie Dimethylformamid und Dimethylsulfoxid, sowie Wasser. Grundsätzlich können alle geeigneten Lösemittel verwendet werden. Geeignete Lösemittel sind beispielsweise aromatische Kohlenwasserstoffe, wie z.B. Xylol, Toluol oder Alkylnaphthaline, chlorierte aromatische oder aliphatische Kohlenwasserstoffe, wie z.B. Chlorbenzol, Chlorethylen, oder Methylenchlorid, aliphatische Kohlenwasserstoffe, wie z.B. Cyclohexan, Paraffine, Erdölfraktionen, mineralische und pflanzliche Öle, Alkohole, wie z.B. Methanol, Ethanol, iso-Propanol, Butanol oder Glykol sowie deren Ether und Ester, Ketone wie z.B. Aceton, Methylethylketon, Methylisobutylketon oder Cyclohexanon, stark polare Lösemittel, wie Dimethylsulfoxid, sowie Wasser. In the case of using water as an extender, e.g. also organic solvents can be used as auxiliary solvents. Suitable liquid solvents are essentially: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable oils, alcohols, such as butanol or glycol, and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide and dimethyl sulfoxide, and water. In principle, all suitable solvents can be used. Suitable solvents are, for example, aromatic hydrocarbons, e.g. Xylene, toluene or alkylnaphthalenes, chlorinated aromatic or aliphatic hydrocarbons, e.g. Chlorobenzene, chloroethylene, or methylene chloride, aliphatic hydrocarbons, e.g. Cyclohexane, paraffins, petroleum fractions, mineral and vegetable oils, alcohols, e.g. Methanol, ethanol, iso-propanol, butanol or glycol and their ethers and esters, ketones such as e.g. Acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strong polar solvents, such as dimethyl sulfoxide, and water.
Grundsätzlich können alle geeigneten Trägerstoffe eingesetzt werden. Als Trägerstoffe kommen insbesondere infrage: z.B. Ammoniumsalze und natürliche Gesteinsmehle, wie Kaoline, Tonerden, Tal- kum, Kreide, Quarz, Attapulgit, Montmorillonit oder Diatomeenerde und synthetische Gesteinsmehle, wie hochdisperse Kieselsäure, Aluminiumoxid und natürliche oder synthetische Silikate, Harze, Wachse und /oder feste Düngemittel. Mischungen solcher Trägerstoffe können ebenfalls verwendet werden. Als Trägerstoffe für Granulate kommen infrage: z.B. gebrochene und fraktionierte natürliche Gesteine wie Calcit, Marmor, Bims, Sepiolith, Dolomit sowie synthetische Granulate aus anorganischen und organischen Mehlen sowie Granulate aus organischem Material wie Sägemehl, Papier, Kokosnussschalen, Maiskolben und Tabakstängel. In principle, all suitable carriers can be used. Suitable carriers are in particular: for example, ammonium salts and ground natural minerals, such as kaolins, clays, talc cumin, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and ground synthetic minerals such as fumed silica, alumina and natural or synthetic silicates, resins, waxes and / or solid fertilizers. Mixtures of such carriers can also be used. Suitable carriers for granules are: eg broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, paper, coconut shells, corn cobs and tobacco stems.
Auch verflüssigte gasförmige Streckmittel oder Lösemittel können eingesetzt werden. Insbesondere eignen sich solche Streckmittel oder Trägerstoffe, welche bei normaler Temperatur und unter Normaldruck gasförmig sind, z.B. Aerosol-Treibgase, wie Halogenkohlenwasserstoffe, sowie Butan, Propan, Stickstoff und Kohlendioxid. Also, liquefied gaseous diluents or solvents can be used. Particularly suitable are those diluents or carriers which are gaseous at normal temperature and under normal pressure, e.g. Aerosol propellants, such as halogenated hydrocarbons, as well as butane, propane, nitrogen and carbon dioxide.
Beispiele für Emulgier- und/oder Schaum erzeugende Mittel, Dispergiermittel oder Benetzungsmittel mit ionischen oder nicht-ionischen Eigenschaften oder Mischungen dieser oberflächenaktiven Stoffe sind Salze von Polyacrylsäure, Salze von Lignosulphonsäure, Salze von Phenolsulphonsäure oder Naphthalinsulphonsäure, Polykondensate von Ethylenoxid mit Fettalkoholen oder mit Fettsäuren oder mit Fettaminen, mit substituierten Phenolen (vorzugsweise Alkylphenole oder Arylphenole), Salze von Sulphobernsteinsäureestern, Taurinderivate (vorzugsweise Alkyltaurate), Phosphorsäureester von polyethoxylierten Alkoholen oder Phenole, Fettsäureester von Polyolen, und Derivate der Verbindungen enthaltend Sulphate, Sulphonate und Phosphate, z.B. Alkylarylpolyglycolether, Alkylsulfonate, Alkyl- sulfate, Arylsulfonate, Eiweißhydrolysate, Lignin- Sulfitablaugen und Methylcellulose. Die Anwesenheit einer oberflächenaktiven Substanz ist vorteilhaft, wenn einer der Wirkstoff und/oder einer der inerten Trägerstoffe nicht in Wasser löslich ist und wenn die Anwendung in Wasser erfolgt. Examples of emulsifying and / or foaming agents, dispersants or wetting agents having ionic or non-ionic properties or mixtures of these surfactants are salts of polyacrylic acid, salts of lignosulphonic acid, salts of phenolsulphonic acid or naphthalenesulphonic acid, polycondensates of ethylene oxide with fatty alcohols or with fatty acids or with fatty amines, with substituted phenols (preferably alkylphenols or arylphenols), salts of sulphosuccinic acid esters, taurine derivatives (preferably alkyl taurates), phosphoric acid esters of polyethoxylated alcohols or phenols, fatty acid esters of polyols, and derivatives of the compounds containing sulphates, sulphonates and phosphates, eg Alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates, protein hydrolysates, lignin sulfite waste liquors and methylcellulose. The presence of a surfactant is advantageous when one of the active ingredients and / or one of the inert carriers is not soluble in water and when applied in water.
Als weitere Hilfsstoffe können in den Formulierungen und den daraus abgeleiteten Anwendungsformen Farbstoffe wie anorganische Pigmente, z.B. Eisenoxid, Titanoxid, Ferrocyanblau und organische Farbstoffe, wie Alizarin-, Azo- und Metallphthalocyaninfarbstoffe und Nähr- und Spurennährstoffe, wie Salze von Eisen, Mangan, Bor, Kupfer, Kobalt, Molybdän und Zink vorhanden sein. As further adjuvants, in the formulations and the applications derived therefrom, dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes, and nutrient and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
Weiterhin enthalten sein können Stabilisatoren wie Kältestabilisatoren, Konservierungsmittel, Oxidationsschutzmittel, Lichtschutzmittel oder andere die chemische und / oder physikalische Stabilität verbessernde Mittel. Weiterhin enthalten sein können schaumerzeugende Mittel oder Entschäumer. Ferner können die Formulierungen und daraus abgeleiteten Anwendungsformen als zusätzliche Hilfsstoffe auch Haftmittel wie Carboxymethylcellulose, natürliche und synthetische pulverige, körnige oder latexförmige Polymere enthalten, wie Gummiarabikum, Polyvinylalkohol, Polyvinylacetat, sowie natürliche Phospholipide, wie Kephaline und Lecithine, und synthetische Phospholipide. Weitere Hilfsstoffe können mineralische und vegetabile Öle sein. Gegebenenfalls können noch weitere Hilfsstoffe in den Formulierungen und den daraus abgeleiteten Anwendungsformen enthalten sein. Solche Zusatzstoffe sind beispielsweise Duftstoffe, schützende Kolloide, Bindemittel, Klebstoffe, Verdicker, thixotrope Stoffe, Penetrationsförderer, Retentionsförderer, Stabilisatoren, Sequestiermittel, Komplexbildner, Humectans, Spreitmittel. Im Allgemeinen können die Wirkstoffe mit jedem festen oder flüssigen Zusatzstoff, welches für Formulierungszwecke gewöhnlich verwendet wird, kombiniert werden. Stabilizers such as cold stabilizers, preservatives, antioxidants, light stabilizers or other chemical and / or physical stability-improving agents may also be present. It may also contain foam-forming agents or defoamers. Further, the formulations and applications derived therefrom may also contain, as additional auxiliaries, adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins, and synthetic phospholipids. Other auxiliaries may be mineral and vegetable oils. Optionally, further auxiliaries may be present in the formulations and in the use forms derived therefrom. Such additives are, for example, fragrances, protective colloids, binders, adhesives, thickeners, thixotropic substances, penetration promoters, retention promoters, stabilizers, sequestrants, complexing agents, humectants, spreading agents. In general, the active ingredients can be combined with any solid or liquid additive commonly used for formulation purposes.
Als Retentionsförderer kommen alle diejenigen Substanzen in Betracht, die die dynamische Oberflächenspannung verringern wie beispielsweise Dioctylsulfosuccinat oder die die Visko-Elastizität erhöhen wie beispielsweise Hydroxypropyl-guar Polymere. Als Penetrationsförderer kommen im vorliegenden Zusammenhang alle diejenigen Substanzen in Betracht, die üblicherweise eingesetzt werden, um das Eindringen agrochemischer Wirkstoffe in Pflanzen zu verbessern. Penetrationsförderer werden in diesem Zusammenhang dadurch definiert, dass sie aus der (in der Regel wässerigen) Applikationsbrühe und/oder aus dem Spritzbelag in die Kutikula der Pflanze eindringen und dadurch die Stoffbeweglichkeit (Mobilität) der Wirkstoffe in der Kutikula erhöhen können. Die in der Literatur (Baur et al., 1997, Pesticide Science 51, 131-152) beschriebene Methode kann zur Bestimmung dieser Eigenschaft eingesetzt werden. Beispielhaft werden genannt Alkoholalkoxylate wie beispielsweise Kokosfettethoxylat (10) oder Isotridecylethoxylat (12), Fettsäureester wie beispielsweise Rapsöl- oder Sojaölmethylester, Fettamine Alkoxylate wie beispielsweise Tallowamine ethoxylat (15) oder Ammonium und / oder Phosphonium-Salze wie beispielsweise Ammoniumsulfat oder Diammonium-hydrogenphosphat. As retention promoters are all those substances which reduce the dynamic surface tension such as dioctylsulfosuccinate or increase the visco-elasticity such as hydroxypropyl guar polymers. Suitable penetration promoters in the present context are all those substances which are usually used to improve the penetration of agrochemical active substances into plants. Penetration promoters are in this context defined by the fact that they can penetrate from the (usually aqueous) application broth and / or from the spray coating into the cuticle of the plant and thereby increase the material mobility (mobility) of the active ingredients in the cuticle. The method described in the literature (Baur et al., 1997, Pesticide Science 51, 131-152) can be used to determine this property. Examples include alcohol alkoxylates such as coconut oil ethoxylate (10) or Isotridecylethoxylat (12), fatty acid esters such as rapeseed oil or soybean oil, fatty amine alkoxylates such as Tallowamine ethoxylate (15) or ammonium and / or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate.
Erfindungsgemäß können alle Pflanzen und Pflanzenteile behandelt werden. Unter Pflanzen werden hierbei alle Pflanzen und Pflanzenpopulationen verstanden, wie erwünschte und unerwünschte Wildpflanzen oder Kulturpflanzen (einschließlich natürlich vorkommender Kulturpflanzen). Kulturpflanzen können Pflanzen sein, die durch konventionelle Züchtungs- und Optimierungsmethoden oder durch biotechnologische und gentechnologische Methoden oder Kombinationen dieser Methoden erhalten werden können, einschließlich der transgenen Pflanzen und einschließlich der durch Sortenschutzrechte schützbaren oder nicht schützbaren Pflanzensorten. Zu den Pflanzen, die mit den erfindungsgemäßen Wirkstoffkombinationen behandelt werden können, zählen z. B. folgende Pflanzenarten: Turf, Reben, Getreide, beispielsweise Weizen, Gerste, Roggen, Hafer, Reis, Mais und Hirse, Triticale; Rüben, beispielsweise Zuckerrüben und Futterrüben; Früchte, beispielsweise Kernobst, Steinobst und Beerenobst, beispielsweise Äpfel, Birnen, Pflaumen, Pfirsiche, Mandeln, Kirschen und Beeren, z. B. Erdbeeren, Himbeeren, Brombeeren; Hülsenfrüchte, beispielsweise Bohnen, Linsen, Erbsen und Sojabohnen; Ölkulturen, beispielsweise Raps, Senf, Mohn, Oliven, Sonnenblumen, Kokos, Castorölpflanzen, Kakaobohnen und Erdnüsse; Gurkengewächse, beispielsweise Kürbis, Gurken und Melonen; Fasergewächse, beispielsweise Baumwolle, Flachs, Hanf und Jute; Citrusfrüchte, beispielsweise Orangen, Zitronen, Pampelmusen und Mandarinen; Gemüsesorten, beispielsweise Spinat, (Kopfj-Salat, Spargel, Kohlarten, Möhren, Zwiebeln, Tomaten, Kartoffeln und Paprika; Lorbeergewächse, beispielsweise Avocado, Cinnamomum, Kampfer, oder ebenso Pflanzen wie Tabak, Nüsse, Kaffee, Aubergine, Zuckerrohr, Tee, Pfeffer, Weinreben, Hopfen, Bananen, Naturkautschukgewächse sowie Zierpflanzen, beispielsweise Blumen, Sträucher, Laubbäume und Nadelbäume wie Koniferen. Diese Aufzählung stellt keine Limitierung dar. According to the invention, all plants and parts of plants can be treated. In this context, plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants). Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights. The plants which can be treated with the active compound combinations according to the invention include, for. The following plant species: turf, vines, cereals, for example wheat, barley, rye, oats, rice, corn and millet, triticale; Beets, for example sugar beets and fodder beets; Fruits, such as pome fruit, stone fruit and soft fruit, such as apples, pears, plums, peaches, almonds, cherries and berries, eg. Strawberries, raspberries, blackberries; Legumes, such as beans, lentils, peas and soybeans; Oil crops such as rapeseed, mustard, poppy, olive, sunflower, coconut, castor oil, cocoa beans and peanuts; Cucurbits, for example squash, cucumbers and melons; Fiber plants, for example cotton, flax, hemp and jute; Citrus fruits, for example, oranges, lemons, grapefruit and mandarins; Vegetables such as spinach, (headj salad, asparagus, cabbage, carrots, onions, tomatoes, potatoes and peppers, laurel family, such as avocado, cinnamomum, camphor or even plants such as tobacco, nuts, coffee, eggplant, sugarcane, tea, pepper , Vines, hops, bananas, natural rubber plants and ornamental plants, such as flowers, shrubs, deciduous trees and conifers, this list is not limiting.
Unter Pflanzenteilen sollen alle oberirdischen und unterirdischen Teile und Organe der Pflanzen, wie Spross, Blatt, Blüte und Wurzel verstanden werden, wobei beispielhaft, Blätter, Nadeln, Stängel, Stämme, Blüten, Fruchtkörper, Früchte und Samen sowie Wurzeln, Knollen und Rhizome aufgeführt werden. Zu den Pflanzenteilen gehört auch Erntegut sowie vegetatives und generatives Vermehrungsmaterial, beispielsweise Stecklinge, Knollen, Rhiozome, Ableger und Samen. Plant parts are to be understood as meaning all aboveground and underground parts and organs of the plants, such as shoot, leaf, flower and root, by way of example, leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds and roots, tubers and rhizomes , The plant parts also include crops as well as vegetative and generative propagation material, for example cuttings, tubers, rhiomes, offshoots and seeds.
Die erfindungsgemäße Behandlung der Pflanzen und Pflanzenteile mit den Wirkstoffkombinationen erfolgt direkt oder durch Einwirkung auf deren Umgebung, Lebensraum oder Lagerraum nach den üblichen Behandlungsmethoden, z.B. durch Tauchen, (Ver-) Spritzen, (Ver-) Sprühen, Berieseln, Verdampfen, Zerstäuben, Angießen, Vernebeln, (Ver-) Streuen, Verschäumen, Aufstreichen Verstreichen, Injizieren, Gießen (drenchen), Tröpfchenbewässerung und bei Vermehrungsmaterial, insbesondere bei Samen, weiterhin durch durch Trockenbeizen, Nassbeizen, Schlämmbeizen, Inkrustieren, ein- oder mehrschichtiges Umhüllen. The treatment according to the invention of the plants and plant parts with the active compound combinations takes place directly or by acting on their environment, habitat or storage space according to the usual treatment methods, e.g. by dipping, spraying, spraying, sprinkling, vaporizing, atomizing, casting, atomizing, sprinkling, foaming, brushing, spreading, injecting, pouring, drip irrigation and propagating material, in particular at Seeds, further by dry pickling, wet pickling, slurry pickling, encrusting, single or multi-layer wrapping.
Eine bevorzugte direkte Behandlung der Pflanzen ist die Blattapplikation, d.h. die erfindungsgemäßen Wirkstoffkombinationen werden auf das Blattwerk aufgebracht, wobei die Behandlungsfrequenz und die Aufwandmenge auf den Befallsdruck des jeweiligen Schädlings abgestimmt sein kann. A preferred direct treatment of the plants is foliar application, i. the active compound combinations according to the invention are applied to the foliage, wherein the treatment frequency and the application rate can be matched to the infestation pressure of the respective pest.
Bei systemisch wirksamen Verbindungen gelangen die erfindungsgemäßen Wirkstoffkombinationen auch über das Wurzelwerk in die Pflanzen. Die Behandlung der Pflanzen erfolgt dann durch Einwirkung der erfindungsgemäßen Wirkstoffkombinationen auf den Lebensraum der Pflanze. Das kann beispielsweise durch Drenchen, Einmischen in den Boden oder die Nährlösung sein, d.h. der Standort der Pflanze (z.B. Boden oder hydroponische Systeme) wird mit einer flüssigen Form der erfindungsgemäßen Wirkstoffkombinationen getränkt, oder durch die Bodenapplikation, d.h. die erfindungsgemäßen Wirkstoffkombinationen werden in fester Form, (z.B. in Form eines Granulats) in den Standort der Pflanzen eingebracht. Bei Wasserreiskulturen kann das auch durch Zudosieren der Erfindung in einer festen Anwendungsform (z.B. als Granulat) in ein überflutetes Reisfeld sein. In the case of systemically active compounds, the active compound combinations according to the invention also enter the plants via the root system. The treatment of the plants is then carried out by the action of the active compound combinations according to the invention on the habitat of the plant. This may be, for example, by drenching, mixing into the soil or the nutrient solution, i. the location of the plant (e.g., soil or hydroponic systems) is impregnated with a liquid form of the active compound combinations of the invention, or by the soil application, i. The active compound combinations according to the invention are introduced in solid form (for example in the form of granules) into the location of the plants. In water rice crops this may also be by metering the invention in a solid application form (e.g., as granules) into a flooded paddy field.
Die vorliegende Erfindung bezieht sich daher insbesondere auch auf ein Verfahren zum Schutz von Saatgut und keimenden Pflanzen vor dem Befall von Schädlingen, indem das Saatgut mit denerfmdungsgemäßen Wirkstoffkombinationen behandelt wird. Das erfindungsgemäße Verfahren zum Schutz von Saatgut und keimenden Pflanzen vor dem Befall von Schädlingen umfasst ein Verfahren, in dem das Saatgut gleichzeitig in einem Vorgang mit einem Wirkstoff der Formel I und Mischungspartner behandelt wird. Es umfasst auch ein Verfahren, in dem das Saatgut zu unterschiedlichen Zeiten mit einem Wirkstoff der Formel I und Mischungspartner behandelt wird. The present invention therefore also relates in particular to a method for protecting seed and germinating plants from the infestation of pests by treating the seed with the active compound combinations according to the invention. The method according to the invention for the protection of seeds and germinating plants from attack by pests comprises a method, in the seed is treated simultaneously in one operation with an active substance of formula I and mixing partners. It also includes a method in which the seed is treated at different times with an active ingredient of formula I and mixing partners.
Die Erfindung bezieht sich ebenfalls auf die Verwendung der erfindungsgemäßen Wirkstoffkombinationen zur Behandlung von Saatgut zum Schutz des Saatguts und der daraus entstehenden Pflanze vor tierischen Schädlingen. The invention also relates to the use of the active compound combinations according to the invention for the treatment of seed for the protection of the seed and the resulting plant from animal pests.
Weiterhin bezieht sich die Erfindung auf Saatgut, welches zum Schutz vor tierischen Schädlingen mit den erfindungsgemäßen Wirkstoffkombinationen behandelt wurde. Die Erfindung bezieht sich auch auf Saatgut, welches zur gleichen Zeit mit dem Wirkstoff der Formel (I) und Mischungspartner behandelt wurde. Die Erfindung bezieht sich weiterhin auf Saatgut, welches zu unterschiedlichen Zeiten mit dem Wirkstoff der Formel (I) und Mischungspartner behandelt wurde. Bei Saatgut, welches zu unterschiedlichen Zeiten mit dem Wirkstoff der Formel (I) und Mischungs-partner behandelt wurde, können die einzelnen Wirkstoffe des erfindungsgemäßen Mittels in unterschiedlichen Schichten auf dem Saatgut enthalten sein. Dabei können die Schichten, die den Wirkstoff der Formel (I) und Mischungspartner enthalten, gegebenenfalls durch eine Zwischenschicht getrennt sein. Die Erfindung bezieht sich auch auf Saatgut, bei dem der Wirkstoff der Formel (I) und Mischungspartner als Bestandteil einer Umhüllung oder als weitere Schicht oder weitere Schichten zusätzlich zu einer Umhüllung aufgebracht sind. Furthermore, the invention relates to seed which has been treated for protection against animal pests with the active compound combinations according to the invention. The invention also relates to seed which has been treated at the same time with the active ingredient of formula (I) and mixing partner. The invention further relates to seed which has been treated at different times with the active ingredient of the formula (I) and mixing partner. For seeds which have been treated at different times with the active ingredient of the formula (I) and mixing partner, the individual active ingredients of the agent according to the invention may be present in different layers on the seed. The layers containing the active ingredient of the formula (I) and mixing partner may optionally be separated by an intermediate layer. The invention also relates to seed in which the active ingredient of the formula (I) and mixing partner are applied as part of a coating or as a further layer or further layers in addition to a coating.
Des Weiteren bezieht sich die Erfindung auf Saatgut, welches nach der Behandlung mit den erfindungsgemäßen Wirkstoffkombinationen einem Filmcoating - Verfahren unterzogen wird, um Staubabrieb am Saatgut zu vermeiden. Furthermore, the invention relates to seed which, after treatment with the active compound combinations according to the invention, is subjected to a film coating process in order to avoid dust abrasion on the seed.
Einer der Vorteile der vorliegenden Erfindung ist es, dass aufgrund der besonderen systemischen Eigenschaften der erfindungsgemäßen Mittel die Behandlung des Saatguts mit diesen Mitteln nicht nur das Saatgut selbst, sondern auch die daraus hervorgehenden Pflanzen nach dem Auflaufen vor tierischen Schädlingen schützt. Auf diese Weise kann die unmittelbare Behandlung der Kultur zum Zeitpunkt der Aussaat oder kurz danach entfallen. One of the advantages of the present invention is that because of the particular systemic properties of the compositions of the invention, treatment of the seeds with these agents not only protects the seed itself but also the resulting plants after emergence from animal pests. In this way, the immediate treatment of the culture at the time of sowing or shortly afterwards can be omitted.
Ein weiterer Vorteil ist darin zu sehen, dass durch die Behandlung des Saatguts mit den erfindungsgemäßen Wirkstoffkombinationen Keimung und Auflauf des behandelten Saatguts gefördert werden können. Ebenso ist es als vorteilhaft anzusehen, dass erfindungsgemäße Wirkstoffkombinationen insbesondere auch bei transgenem Saatgut eingesetzt werden können. A further advantage is the fact that germination and emergence of the treated seed can be promoted by treating the seed with the active compound combinations according to the invention. Likewise, it is considered to be advantageous that active compound combinations according to the invention can be used in particular also in transgenic seed.
Wie bereits oben erwähnt, können erfindungsgemäß alle Pflanzen und deren Teile behandelt werden. In einer bevorzugten Ausführungsform werden wild vorkommende oder durch konventionelle biologische Zuchtmethoden, wie Kreuzung oder Protoplastenfusion erhaltenen Pflanzenarten und Pflanzensorten sowie deren Teile behandelt. Die traditionellen Vermehrungs- und Züchtungsmethoden können durch eine oder mehrere biotechnologische Methoden, wie z.B. die Verwendung von Doppelhaploiden, zufälliger und gerichteter Mutagenese, molekularen oder genetischen Markern, oder durch Bioengineering-Methoden und gentechnische Methoden unterstützt oder ergänzt werden. In einer weiteren bevorzugten Ausführungsform werden transgene Pflanzen und Pflanzensorten, die durch gentechnologische Methoden gegebenenfalls in Kombination mit konventionellen Methoden erhalten wurden (Genetic Modified Organisms) und deren Teile behandelt. Bei genetisch modifizierten Pflanzen (oder transgenen Pflanzen) handelt es sich um Pflanzen, bei denen ein heterologes Gen stabil in das Genom integriert wurde. Der Ausdruck "heterologes Gen" bedeutet im Wesentlichen ein Gen, das außerhalb der Pflanze oder der Pflanzenzelle bereitgestellt oder assembliert wird und das, wenn es in das Zellkerngenom, das Chloroplastengenom oder das Mitochondriengenom eingeführt wird, der transformierten Pflanze neue oder verbesserte agronomische oder sonstige Merkmale verleiht, und zwar dadurch, dass es ein Protein oder Polypeptid von Interesse exprimiert oder dass es ein anderes Gen, das in der Pflanze vorliegt, bzw. andere Gene, die in der Pflanze vorliegen, herunterreguliert oder abschaltet (z.B. mittels Antisense-Technologie, Cosuppressionstechnologie, RNA-Interferenz-Technologie (RNAi- Technologie) oder MikroRNA-Technologie (miRNA-Technologie)). Ein heterologes Gen, das in das Genom integriert worden ist, wird auch als Transgen bezeichnet. Ein Transgen, das in das Pflanzengenom integriert worden ist, wird Transformations-Event oder transgenes Event genannt. Die Begriffe "Teile" bzw. "Teile von Pflanzen" oder "Pflanzenteile" wurden oben erläutert. As already mentioned above, according to the invention all plants and their parts can be treated. In In a preferred embodiment, wild-type or plant species obtained by conventional biological breeding methods such as cross-breeding or protoplast fusion, and plant varieties and their parts are treated. Traditional propagation and breeding methods may be supported or supplemented by one or more biotechnological methods, such as the use of double haploids, random and directed mutagenesis, molecular or genetic markers, or bioengineering methods and genetic engineering methods. In a further preferred embodiment, transgenic plants and plant cultivars which have been obtained by genetic engineering methods, if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated. Genetically modified plants (or transgenic plants) are plants in which a heterologous gene has been stably integrated into the genome. The term "heterologous gene" essentially means a gene that is provided or assembled outside the plant or plant cell and that when introduced into the nuclear genome, the chloroplast genome or the mitochondrial genome, provides the transformed plant with new or improved agronomic or other features in that it expresses a protein or polypeptide of interest, or that it downregulates or shuts down another gene present in the plant or other genes present in the plant (eg, by antisense technology, cosuppression technology , RNA interference technology (RNAi technology) or microRNA technology (miRNA technology)). A heterologous gene that has been integrated into the genome is also called a transgene. A transgene that has been integrated into the plant genome is called a transformation event or transgenic event. The terms "parts" or "parts of plants" or "plant parts" have been explained above.
Besonders bevorzugt werden erfindungsgemäß Pflanzen der jeweils handelsüblichen oder in Gebrauch befindlichen Pflanzensorten behandelt. It is particularly preferred according to the invention to treat plants of the respective commercially available or in use plant cultivars.
Je nach Pflanzenarten bzw. Pflanzensorten, deren Standort und Wachstumsbedingungen (Böden, Klima, Vegetationsperiode, Ernährung), können durch die erfindungsgemäße Behandlung auch überadditive ("synergistische") Effekte auftreten. So sind beispielsweise erniedrigte Aufwandmengen und/oder Erweiterungen des Wirkungsspektrums und/oder eine Verstärkung der Wirkung der erfindungsgemäß verwendbaren Stoffe und Mittel, besseres Pflanzenwachstum, erhöhte Toleranz gegenüber hohen oder niedrigen Temperaturen, erhöhte Toleranz gegen Trockenheit oder gegen Wasser- bzw. Bodensalzgehalt, erhöhte Blühleistung, erleichterte Ernte, Beschleunigung der Reife, höhere Ernteerträge, größere Früchte, größere Pflanzenhöhe, intensivere grüne Farbe,des Blattes, frühere Blüte, höhere Qualität und/oder höherer Ernährungswert der Ernteprodukte, höhere Zuckerkonzentration in den Früchten, höhere Lagerfähigkeit und/oder Bearbeitbarkeit der Ernteprodukte möglich, die über die eigentlich zu erwartenden Effekte hinausgehen. Depending on the plant species or plant cultivars, their location and growth conditions (soils, climate, vegetation period, nutrition), superadditive ("synergistic") effects can also occur due to the treatment according to the invention. Thus, for example, reduced application rates and / or extensions of the spectrum of action and / or an increase in the effect of the substances and agents used according to the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering power facilitated harvesting, acceleration of ripeness, higher crop yields, larger fruits, greater plant height, more intense green color of the leaf, earlier flowering, higher quality and / or higher nutritional value of the harvested products, higher sugar concentration in the fruits, higher shelf life and / or workability of the crop Harvest products possible that go beyond the expected effects.
Zu den bevorzugten erfindungsgemäß zu behandelnden transgenen (gentechnologisch erhaltenen) Pflanzen bzw. Pflanzensorten gehören alle Pflanzen, die durch die gentechnologische Modifikation genetisches Material erhielten, welches diesen Pflanzen besondere vorteilhafte wertvolle Eigenschaften ("Traits") verleiht. Beispiele für solche Eigenschaften sind besseres Pflanzenwachstum, erhöhte Toleranz gegenüber hohen oder niedrigen Temperaturen, erhöhte Toleranz gegen Trockenheit oder gegen Wasser- bzw. Bodensalzgehalt, erhöhte Blühleistung, erleichterte Ernte, Beschleunigung der Reife, höhere Ernteerträge, höhere Qualität und/oder höherer Ernährungswert der Ernteprodukte, höhere Lagerfähigkeit und/oder Bearbeitbarkeit der Ernteprodukte. Weitere und besonders hervorgehobene Beispiele für solche Eigenschaften sind eine erhöhte Abwehr der Pflanzen gegen tierische und mikrobielle Schädlinge, wie gegenüber Insekten, Milben, pflanzenpathogenen Pilzen, Bakterien und/oder Viren sowie eine erhöhte Toleranz der Pflanzen gegen bestimmte herbizide Wirkstoffe. Als Beispiele transgener Pflanzen werden die wichtigen Kulturpflanzen, wie Getreide (Weizen, Reis), Mais, Soja, Kartoffel, Baumwolle, Raps sowie Obstpflanzen (mit den Früchten Äpfel, Birnen, Zitrusfrüchten und Weintrauben) erwähnt, wobei Mais, Soja, Kartoffel, Baumwolle und Raps besonders hervorgehoben werden. Als Eigenschaften ("Traits") werden besonders hervorgehoben die erhöhte Abwehr der Pflanzen gegen Insekten durch in den Pflanzen entstehende Toxine, insbesondere solche, die durch das genetische Material aus Bacillus thuringiensis (z.B. durch die Gene CrylA(a), CrylA(b), CrylA(c), CryllA, CrylllA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb und CrylF sowie deren Kombinationen) in den Pflanzen erzeugt werden (im folgenden "Bt Pflanzen"). Als Eigenschaften ("Traits") werden weiterhin besonders hervorgehoben die erhöhte Toleranz der Pflanzen gegenüber bestimmten herbiziden Wirkstoffen, beispielsweise Imidazolinonen, Sulfonylharnstoffen, Glyphosate oder Phosphinotricin (z.B. "PAT"- Gen). Die jeweils die gewünschten Eigenschaften ("Traits") verleihenden Gene können auch in Kombinationen miteinander in den transgenen Pflanzen vorkommen. Als Beispiele für "Bt Pflanzen" seien Maissorten, Baumwollsorten, Sojasorten und Kartoffelsorten genannt, die unter den Handelsbezeichnungen YIELD GARD® (z.B. Mais, Baumwolle, Soja), KnockOut® (z.B. Mais), StarLink® (z.B. Mais), Bollgard® (Baumwolle), Nucotn® (Baumwolle) und NewLeaf® (Kartoffel) vertrieben werden. Als Beispiele für Herbizid tolerante Pflanzen seien Maissorten, Baumwollsorten und Sojasorten genannt, die unter den Handelsbezeichnungen Roundup Ready® (Toleranz gegen Glyphosate z.B. Mais, Baumwolle, Soja), Liberty Link® (Toleranz gegen Phosphinotricin, z.B. Raps), IMI® (Toleranz gegen Imidazolinone) und STS® (Toleranz gegen Sulfonylharnstoffe z.B. Mais) vertrieben werden. Als Herbizid resistente (konventionell auf Herbizid-Toleranz gezüchtete) Pflanzen seien auch die unter der Bezeichnung Clearfield® vertriebenen Sorten (z.B. Mais) erwähnt. Selbstverständlich gelten diese Aussagen auch für in der Zukunft entwickelte bzw. zukünftig auf den Markt kommende Pflanzensorten mit diesen oder zukünftig entwickelten genetischen Eigenschaften ("Traits"). The preferred transgenic (genetically engineered) to be treated according to the invention Plants or plant varieties belong to all plants which received genetic material through the genetic engineering modification, which gives these plants particularly advantageous valuable properties ("traits"). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to bottoms salt, increased flowering, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products. Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants against certain herbicidal active substances. Examples of transgenic plants include the important crops such as cereals (wheat, rice), corn, soy, potato, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soy, potato, cotton and rapeseed should be highlighted. Traits which are particularly emphasized are the increased defense of the plants against insects by toxins which are formed in the plants, in particular those which are produced by the genetic material from Bacillus thuringiensis (for example by the genes CrylA (a), CrylA (b), CrylA (c), CryllA, CrylllA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CrylF and combinations thereof) are produced in the plants (hereinafter "Bt plants"). Traits which are furthermore particularly emphasized are the increased tolerance of the plants to certain herbicidal active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene). The genes which confer the desired properties ("traits") can also occur in combinations with one another in the transgenic plants. Examples of "Bt plants" are maize varieties, cotton varieties, soya bean varieties and potato varieties which are sold under the trade names YIELD GARD ® (for example maize, cotton, soya beans), KnockOut ® (for example maize), StarLink ® (for example maize), Bollgard ® ( cotton), NuCOTN ® (cotton) and NewLeaf ® (potato). Examples of herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties which are resistant under the trade names Roundup Ready ® (tolerance to glyphosate, for example maize, cotton, soya bean), Liberty Link ® (tolerance to phosphinotricin, for example oilseed rape), IMI ® (tolerance imidazolinones) and STS ® (tolerance to sulphonylureas, for example maize). Herbicide-resistant (conventionally grown on herbicide tolerance) plants are also the varieties marketed under the name Clearfield ® (eg corn) mentioned. Of course, these statements also apply to future or future marketed plant varieties with these or future developed genetic traits.
Die aufgeführten Pflanzen können besonders vorteilhaft erfindungsgemäß mit den erfindungsgemäßen Wirkstoffmischungen behandelt werden. Die bei den Wirkstoffkombinationen oben angegebenen Vorzugsbereiche gelten auch für die Behandlung dieser Pflanzen. Besonders hervorgehoben sei die Pflanzenbehandlung mit den im vorliegenden Text speziell aufgeführten Wirkstoffkombinationen. The listed plants can be treated particularly advantageously according to the invention with the active substance mixtures according to the invention. The preferred ranges given above for the active substance combinations also apply to the treatment of these plants. Particularly emphasized is the Plant treatment with the active compound combinations specifically mentioned in the present text.
Die gute Wirkung der erfindungsgemäßen Wirkstoffkombinationen geht aus den nachfolgenden Beispielen hervor. Während die einzelnen Wirkstoffe in der Wirkung Schwächen aufweisen, zeigen die Kombinationen eine Wirkung, die über eine einfache Wirkungssummierung hinausgeht. The good effect of the active compound combinations according to the invention is evident from the following examples. While the individual active ingredients have weaknesses in effect, the combinations show an effect that goes beyond a simple action summation.
Ein synergistischer Effekt liegt immer dann vor, wenn die Wirkung der Wirkstoffkombinationen größer ist als die Summe der Wirkungen der einzeln applizierten Wirkstoffe. A synergistic effect is always present when the effect of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.
Anwendungsbeispiele applications
Formel für den Abtötungsgrad einer Kombination aus zwei Wirkstoffen Formula for the kill rate of a combination of two drugs
Die zu erwartende Wirkung für eine gegebene Kombination zweier Wirkstoffe kann nach S.R. Colby („Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 15, 20-22, 1967) wie folgt berechnet werden: The expected effect for a given combination of two drugs can be found in S.R. Colby ("Calculating Synergistic and Antagonistic Responses of Herbicidal Combinations", Weeds 15, 20-22, 1967) are calculated as follows:
Wenn If
X den Abtötungsgrad, ausgedrückt in % der unbehandelten Kontrolle, beim Einsatz des Wirkstoffes A in einer Aufwandmenge von m g/ha oder in einer Konzentration von m ppm bedeutet, X means the degree of killing, expressed in% of the untreated control, when using the active substance A at a rate of m g / ha or in a concentration of m ppm,
Y den Abtötungsgrad, ausgedrückt in % der unbehandelten Kontrolle, beim Einsatz des Wirkstoffes B in einer Aufwandmenge von n g/ha oder in einer Konzentration von n ppm bedeutet und Y means the degree of killing, expressed in% of the untreated control, when using the active ingredient B in an application rate of n g / ha or in a concentration of n ppm, and
E den Abtötungsgrad, ausgedrückt in % der unbehandelten Kontrolle, beim Einsatz der Wirkstoffe A und B in Aufwandmengen von m und n g/ha oder in einer Konzentration von m und n ppm bedeutet, dann ist E is the killing degree, expressed in% of the untreated control, when using the active compounds A and B in application rates of m and n g / ha or in a concentration of m and n ppm, then is
X Y XY
E=X + Y- 1 00 E = X + Y- 1 00
Ist der tatsächliche Abtötungsgrad größer als der berechnet Abtötungsgrad (E), so ist die Kombination in ihrer Abtötung überadditiv, d.h. es liegt ein synergistischer Effekt vor. Beispiel A If the actual kill rate is greater than the calculated kill rate (E), the combination is over-additive in its kill, ie there is a synergistic effect. Example A
Myzus persicae - Sprühtest Myzus persicae - spray test
Lösungsmittel: 78 Gewichtsteile Aceton Solvent: 78 parts by weight of acetone
1,5 Gewichtsteile Dimethylformamid  1.5 parts by weight of dimethylformamide
Emulgator: Alkylarylpolyglykolether  Emulsifier: alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung löst man 1 Gewichtsteil Wirkstoff mit den angegebenen Gewichtsteilen Lösungsmittel und füllt mit Wasser, welches eine Emulgatorkonzentration von 1000 ppm enthält, bis zum Erreichen der gewünschten Konzentration auf. Weitere Testkonzentrationen erhält man durch Verdünnen mit emulgatorhaltigem Wasser. To prepare a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and filled with water containing an emulsifier concentration of 1000 ppm until reaching the desired concentration. Further test concentrations are obtained by dilution with emulsifier-containing water.
Chinakohlblattscheiben {Brassica pekinensis), die von allen Stadien der Grünen Pfirsichblattlaus {Myzus persicae) befallen sind, werden mit einer Wirkstoffzubereitung der gewünschten Konzentration gespritzt. Chinese cabbage leaf discs (Brassica pekinensis) infested with all stages of the green peach aphid {Myzus persicae) are sprayed with an active compound preparation of the desired concentration.
Nach der gewünschten Zeit wird die Wirkung in % bestimmt. Dabei bedeutet 100 %, dass alle Blattläuse abgetötet wurden und 0 % bedeutet, dass keine Blattläuse abgetötet wurden. Die ermittelten Abtötungswerte verrechnet man nach der Colby-Formel (siehe Blatt 1). After the desired time, the effect is determined in%. 100% means that all aphids have been killed and 0% means that no aphids have been killed. The determined kill values are calculated according to the Colby formula (see page 1).
Bei diesem Test zeigte die folgende Wirkstoffkombination gemäß vorliegender Anmeldung eine synergistisch verstärkte Wirksamkeit im Vergleich zu den einzeln angewendeten Wirkstoffen: In this test, the following active ingredient combination according to the present application showed a synergistically enhanced effectiveness in comparison to the individually applied active ingredients:
Tabelle A: Myzus persicae - Test Table A: Myzus persicae test
Figure imgf000039_0001
Figure imgf000039_0001
*gef. = gefundene Insektizide Wirkung, ** ber. = berechnete Wirkung nach der Colby-Formel Beispiel B * Found. = found insecticidal activity, ex. = calculated effect according to the Colby formula Example B
Phaedon cochleariae - Sprühtest Phaedon cochleariae - spray test
Lösungsmittel: 78,0 Gewichtsteile Aceton Solvent: 78.0 parts by weight of acetone
1,5 Gewichtsteile Dimethylformamid  1.5 parts by weight of dimethylformamide
Emulgator: Alkylarylpolyglykolether  Emulsifier: alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung löst man 1 Gewichtsteil Wirkstoff mit den angegebenen Gewichtsteilen Lösungsmittel und füllt mit Wasser, welches eine Emulgatorkonzentration von 1000 ppm enthält, bis zum Erreichen der gewünschten Konzentration auf. Weitere Testkonzentrationen erhält man durch Verdünnen mit emulgatorhaltigem Wasser. To prepare a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and filled with water containing an emulsifier concentration of 1000 ppm until reaching the desired concentration. Further test concentrations are obtained by dilution with emulsifier-containing water.
Chinakohlblattscheiben (Brassica pekinensis) werden mit einer Wirkstoffzubereitung der gewünschten Konzentration gespritzt und nach dem Abtrocknen mit Larven des Meerrettichblattkäfers (Phaedon cochleariae) besetzt. Chinese cabbage leaf discs (Brassica pekinensis) are sprayed with a preparation of active compound of the desired concentration and, after drying, are populated with larvae of the horseradish leaf beetle (Phaedon cochleariae).
Nach der gewünschten Zeit wird die Wirkung in % bestimmt. Dabei bedeutet 100 %, dass alle Käferlarven abgetötet wurden und 0 % bedeutet, dass keine Käferlarven abgetötet wurden. Die ermittelten Abtötungswerte verrechnet man nach der Colby-Formel (siehe Blatt 1). After the desired time, the effect is determined in%. 100% means that all beetle larvae have been killed and 0% means that no beetle larvae have been killed. The determined kill values are calculated according to the Colby formula (see page 1).
Bei diesem Test zeigte die folgende Wirkstoffkombination gemäß vorliegender Anmeldung eine synergistisch verstärkte Wirksamkeit im Vergleich zu den einzeln angewendeten Wirkstoffen: In this test, the following active ingredient combination according to the present application showed a synergistically enhanced effectiveness in comparison to the individually applied active ingredients:
Tabelle B: Phaedon cochleariae - Test Table B: Phaedon cochleariae test
Figure imgf000040_0001
Figure imgf000040_0001
*gef. = gefundene Insektizide Wirkung, ** ber. = berechnete Wirkung nach der Colby-Formel  * Found. = found insecticidal activity, ex. = calculated effect according to the Colby formula

Claims

Patentansprüche  claims
1. Wirkstoffkombinationen enthaltend die Verbindung der Formel (I) 1. Active substance combinations containing the compound of the formula (I)
Figure imgf000041_0001
Figure imgf000041_0001
und eine oder mehrere Verbindungen, ausgewählt aus den in der folgenden Tabelle genanntenand one or more compounds selected from those listed in the following table
Verbindungen: Links:
Figure imgf000041_0002
Figure imgf000041_0002
Wirkstoffkombinationen gemäß Anspruch 1 , in denen neben der Verbindung der Formel (I) nur eine (1) Verbindung ausgewählt aus den in der Tabelle genannten Verbindungen vorliegt.  Active substance combinations according to Claim 1, in which apart from the compound of the formula (I) only one (1) compound selected from the compounds mentioned in the table is present.
Verwendung einer Wirkstoffkombination gemäß einem der Ansprüche 1 oder 2 zur Bekämpfung tierischer Schädlinge. Use of a combination of active substances according to one of claims 1 or 2 for controlling animal pests.
Verwendung einer Wirkstoffkombination gemäß einem der Ansprüche 1 oder 2 zur Bekämpfung unerwünschter Mikroorganismen. Use of a combination of active substances according to one of claims 1 or 2 for controlling unwanted microorganisms.
Verwendung einer Wirkstoffkombination gemäß einem der Ansprüche 1 oder 2 zur Behandlung von Saatgut. Use of an active ingredient combination according to one of claims 1 or 2 for the treatment of seed.
Verwendung einer Wirkstoffkombination gemäß einem der Ansprüche 1 oder 2 an transgenen Pflanzen. Use of a combination of active substances according to one of claims 1 or 2 on transgenic plants.
7. Verfahren zur Herstellung eines Pflanzenschutzmittels, gekennzeichnet dadurch, dass man eine Wirkstoffkombination gemäß einem der Ansprüche 1 oder 2 mit Streckmitteln und/oder oberflächenaktiven Stoffen vermischt. 7. A process for the preparation of a plant protection agent, characterized in that one mixes an active substance combination according to one of claims 1 or 2 with extenders and / or surface-active substances.
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