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WO2009145824A3 - Lubricant composition with improved varnish deposit resistance - Google Patents

Lubricant composition with improved varnish deposit resistance Download PDF

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Publication number
WO2009145824A3
WO2009145824A3 PCT/US2009/001983 US2009001983W WO2009145824A3 WO 2009145824 A3 WO2009145824 A3 WO 2009145824A3 US 2009001983 W US2009001983 W US 2009001983W WO 2009145824 A3 WO2009145824 A3 WO 2009145824A3
Authority
WO
WIPO (PCT)
Prior art keywords
lubricating oil
deposit control
disclosed
lubricant composition
less
Prior art date
Application number
PCT/US2009/001983
Other languages
French (fr)
Other versions
WO2009145824A2 (en
Inventor
Andrea Blandford Wardlow
David G. L. Holt
Original Assignee
Exxonmobil Research And Engineering Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Research And Engineering Company filed Critical Exxonmobil Research And Engineering Company
Priority to JP2011501849A priority Critical patent/JP2011516637A/en
Priority to CN200980112137.3A priority patent/CN101983230B/en
Priority to EP09755187A priority patent/EP2288681A2/en
Publication of WO2009145824A2 publication Critical patent/WO2009145824A2/en
Publication of WO2009145824A3 publication Critical patent/WO2009145824A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/04—Well-defined cycloaliphatic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17—Fisher Tropsch reaction products
    • C10M2205/173—Fisher Tropsch reaction products used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C10M2215/065—Phenyl-Naphthyl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/043—Mannich bases
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066—Thiocarbamic type compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/047—Thioderivatives not containing metallic elements
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/40—Low content or no content compositions
    • C10N2030/42—Phosphor free or low phosphor content compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/40—Low content or no content compositions
    • C10N2030/45—Ash-less or low ash content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/12—Gas-turbines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/135—Steam engines or turbines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2060/00—Chemical after-treatment of the constituents of the lubricating composition
    • C10N2060/14—Chemical after-treatment of the constituents of the lubricating composition by boron or a compound containing boron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

In one embodiment, a lubricating oil with favorable deposit control is disclosed. The lubricating oil comprises, a major amount of base stock selected from the group consisting of Group II, Group III, GTL and any combination thereof, a mannich based dispersant comprising at least 0.1 and less than 2.0 weight percent of the lubricating oil, a demulsifier comprising a polyol ester and a poly oxyakylene, the demulsifiers comprising at least 0.002 to less than 2.0 weight percent of the lubricating oil, wherein the lubricating oil has a deposit control value less than 60 using 504 hour 12O0C Dry TOST sludge test. In a second embodiment a method of deposit control is disclosed. In a third embodiment a method of formulating an oil to improve deposit control and emulsion properties is disclosed.
PCT/US2009/001983 2008-03-31 2009-03-31 Lubricant composition with improved varnish deposit resistance WO2009145824A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2011501849A JP2011516637A (en) 2008-03-31 2009-03-31 Improved varnish-resistant lubricating oil composition
CN200980112137.3A CN101983230B (en) 2008-03-31 2009-03-31 Lubricant composition with improved varnish deposit resistance
EP09755187A EP2288681A2 (en) 2008-03-31 2009-03-31 Lubricant composition with improved varnish deposit resistance

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US7243208P 2008-03-31 2008-03-31
US61/072,432 2008-03-31

Publications (2)

Publication Number Publication Date
WO2009145824A2 WO2009145824A2 (en) 2009-12-03
WO2009145824A3 true WO2009145824A3 (en) 2010-02-25

Family

ID=41118141

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2009/001983 WO2009145824A2 (en) 2008-03-31 2009-03-31 Lubricant composition with improved varnish deposit resistance

Country Status (6)

Country Link
US (2) US20090247436A1 (en)
EP (1) EP2288681A2 (en)
JP (1) JP2011516637A (en)
CN (1) CN101983230B (en)
SG (1) SG188804A1 (en)
WO (1) WO2009145824A2 (en)

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JP6091042B2 (en) * 2009-06-29 2017-03-08 Ｊｘエネルギー株式会社 Rust prevention oil composition
US8716201B2 (en) * 2009-10-02 2014-05-06 Exxonmobil Research And Engineering Company Alkylated naphtylene base stock lubricant formulations
JP5725718B2 (en) * 2010-02-08 2015-05-27 Ｊｘ日鉱日石エネルギー株式会社 Lubricating oil composition for rotary gas compressor
US8623795B2 (en) * 2010-07-27 2014-01-07 Exxonmobil Research And Engineering Company Method for maintaining antiwear performance of turbine oils containing polymerized amine antioxidants and for improving the deposit formation resistance performance of turbine oils containing monomeric and/or polymeric antioxidants
WO2012015873A1 (en) * 2010-07-27 2012-02-02 Exxonmobil Research And Engineering Company Method for improving the deposit formation resistance performance of turbine oils containing amine antioxidants
US8618031B2 (en) 2010-07-27 2013-12-31 Exxonmobil Research And Engineering Company Method for improving the deposit formation resistance performance of turbine oils containing amine antioxidants
BR112013022423A2 (en) * 2011-03-23 2016-12-06 Dow Global Technologies Llc heat transfer fluid composition
US8400030B1 (en) * 2012-06-11 2013-03-19 Afton Chemical Corporation Hybrid electric transmission fluid
CN103224825B (en) * 2013-04-09 2014-04-09 天津市联瑞阻燃材料有限公司 Medium-pressure anti-combustible oil with base oil of trixylenyl phosphate and production method thereof
CN103215106A (en) * 2013-04-09 2013-07-24 天津市联瑞阻燃材料有限公司 Aviation-grade high-pressure fire resistant oil taking trixylyl phosphate as base oil and production method thereof
CN103215105B (en) * 2013-04-09 2014-04-09 天津市联瑞阻燃材料有限公司 Middle-pressure fire resistant oil taking tricresyl phosphate as base oil and production method thereof
CN103232880B (en) * 2013-04-12 2014-08-27 广西大学 Environment friendly energy-efficient heavy-load compression machine oil
US20150099675A1 (en) * 2013-10-03 2015-04-09 Exxonmobil Research And Engineering Company Compositions with improved varnish control properties
US10501701B2 (en) * 2014-12-03 2019-12-10 The Lubrizol Corporation Lubricating composition containing an oxyalkylated aromatic polyol compound
US20180100117A1 (en) * 2016-10-07 2018-04-12 Exxonmobil Research And Engineering Company Lubricating oil compositions for electric vehicle powertrains
MX2019008687A (en) * 2017-01-23 2019-09-09 Phillips 66 Co Lubricating oil composition with improved oxidation retention and reduced sludge and varnish formation.
US10253275B2 (en) 2017-07-19 2019-04-09 American Chemical Technologies, Inc. High viscosity lubricants with polyether
JP7198229B2 (en) * 2018-02-16 2022-12-28 出光興産株式会社 lubricating oil composition
CN109536258A (en) * 2018-12-19 2019-03-29 上海森帝润滑技术有限公司 Centrifugal compressor full synthetic oil
SG10202004194TA (en) * 2019-05-13 2020-12-30 Afton Chemical Corp Additive and lubricant for industrial lubrication
CN111363604A (en) * 2020-03-25 2020-07-03 天津大学 Lubricating oil composition for suppressing knocking phenomenon and application thereof
CN114164031A (en) * 2021-12-03 2022-03-11 东莞太平洋博高润滑油有限公司 Long-life synthetic air compressor oil and preparation method thereof

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Also Published As

Publication number Publication date
CN101983230B (en) 2014-04-30
US20090247436A1 (en) 2009-10-01
SG188804A1 (en) 2013-04-30
WO2009145824A2 (en) 2009-12-03
CN101983230A (en) 2011-03-02
EP2288681A2 (en) 2011-03-02
US20090253597A1 (en) 2009-10-08
JP2011516637A (en) 2011-05-26

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