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WO2008123215A1 - 変性共役ジエン系重合体の製造方法、該重合体を含む組成物及び該組成物を含むタイヤ - Google Patents

変性共役ジエン系重合体の製造方法、該重合体を含む組成物及び該組成物を含むタイヤ Download PDF

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Publication number
WO2008123215A1
WO2008123215A1 PCT/JP2008/055492 JP2008055492W WO2008123215A1 WO 2008123215 A1 WO2008123215 A1 WO 2008123215A1 JP 2008055492 W JP2008055492 W JP 2008055492W WO 2008123215 A1 WO2008123215 A1 WO 2008123215A1
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WO
WIPO (PCT)
Prior art keywords
conjugated diene
polymer
compositions
production
diene polymer
Prior art date
Application number
PCT/JP2008/055492
Other languages
English (en)
French (fr)
Inventor
Yuichi Kitagawa
Toshikazu Hoshina
Kiyoo Katou
Original Assignee
Asahi Kasei Chemicals Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Kasei Chemicals Corporation filed Critical Asahi Kasei Chemicals Corporation
Priority to EP08738792A priority Critical patent/EP2138516B1/en
Priority to US12/593,164 priority patent/US8278395B2/en
Priority to AT08738792T priority patent/ATE534674T1/de
Priority to CN2008800098159A priority patent/CN101641378B/zh
Priority to JP2009509105A priority patent/JP5342439B2/ja
Priority to KR1020097020059A priority patent/KR101049675B1/ko
Publication of WO2008123215A1 publication Critical patent/WO2008123215A1/ja

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/30Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/30Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/42Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
    • C08C19/44Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016Compositions of the tread
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/01Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L47/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Compositions of derivatives of such polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerization Catalysts (AREA)

Abstract

 本発明は、加硫処理を施して加硫ゴムとしたときに、ウエットスキッド特性、低ヒステリシスロス性、耐摩耗性、破壊強度さらに剛性のバランスに優れたタイヤのトレッド用材料として有用である共役ジエン系重合体及びその製造方法を提供することを目的の一つとする。本発明によれば、変性基を分子中に有する変性共役ジエン系重合体の製造方法であって、炭化水素溶媒中で、アルカリ金属系開始剤又はアルカリ土類金属系開始剤を用い、共役ジエン化合物を、又は共役ジエン化合物と芳香族ビニル化合物を、重合させて、共役ジエン系重合体を得る工程と、前記重合体の活性末端と、変性剤として分子中に3級アミノ基を2個以上及び該アミノ基に結合したグリシジル基を3個以上有するグリシジルアミノ基含有低分子化合物、並びに前記低分子化合物の2量体以上のオリゴマーと、を反応させる工程であって、前記変性剤の全量に対して、前記低分子化合物を75~95質量%、前記オリゴマーを25~5質量%を用いて反応させる工程と、を含む変性共役ジエン系重合体の製造方法を提供する。
PCT/JP2008/055492 2007-03-28 2008-03-25 変性共役ジエン系重合体の製造方法、該重合体を含む組成物及び該組成物を含むタイヤ WO2008123215A1 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP08738792A EP2138516B1 (en) 2007-03-28 2008-03-25 Process for production of modified conjugated diene polymer, compositions comprising the polymer, and tires containing the compositions
US12/593,164 US8278395B2 (en) 2007-03-28 2008-03-25 Process for manufacturing modified conjugated diene polymer, composition comprising the polymer, and tire comprising the composition
AT08738792T ATE534674T1 (de) 2007-03-28 2008-03-25 Verfahren zur herstellung eines modifizierten konjugierten dienpolymers, zusammensetzungen mit dem polymer und reifen mit diesen zusammensetzungen
CN2008800098159A CN101641378B (zh) 2007-03-28 2008-03-25 改性共轭二烯系聚合物的制造方法、含有该聚合物的组合物以及含有该组合物的轮胎
JP2009509105A JP5342439B2 (ja) 2007-03-28 2008-03-25 変性共役ジエン系重合体の製造方法、該重合体を含む組成物及び該組成物を含むタイヤ
KR1020097020059A KR101049675B1 (ko) 2007-03-28 2008-03-25 변성 공액 디엔계 중합체의 제조 방법, 상기 중합체를 포함하는 조성물 및 상기 조성물을 포함하는 타이어

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-084310 2007-03-28
JP2007084310 2007-03-28

Publications (1)

Publication Number Publication Date
WO2008123215A1 true WO2008123215A1 (ja) 2008-10-16

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/055492 WO2008123215A1 (ja) 2007-03-28 2008-03-25 変性共役ジエン系重合体の製造方法、該重合体を含む組成物及び該組成物を含むタイヤ

Country Status (8)

Country Link
US (1) US8278395B2 (ja)
EP (1) EP2138516B1 (ja)
JP (1) JP5342439B2 (ja)
KR (1) KR101049675B1 (ja)
CN (1) CN101641378B (ja)
AT (1) ATE534674T1 (ja)
TW (1) TWI384001B (ja)
WO (1) WO2008123215A1 (ja)

Cited By (6)

* Cited by examiner, † Cited by third party
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JP2009197118A (ja) * 2008-02-21 2009-09-03 Asahi Kasei Chemicals Corp 油展変性共役ジエン系重合体組成物
JP2009275178A (ja) * 2008-05-16 2009-11-26 Asahi Kasei Chemicals Corp 変性共役ジエン系重合体組成物及びこれを用いた加硫ゴム組成物
CN101691777B (zh) * 2009-09-24 2011-09-14 山东华腾环保科技有限公司 真空辅助便器
WO2015182078A1 (ja) * 2014-05-27 2015-12-03 株式会社ブリヂストン 重荷重用空気入りタイヤ
JP2017132986A (ja) * 2016-01-26 2017-08-03 ハンファ トータル ペトロケミカル カンパニー リミテッド 変性共役ジエン系重合体及びこれを用いたタイヤゴム組成物
WO2018198647A1 (ja) * 2017-04-28 2018-11-01 株式会社ブリヂストン 防振ゴム用ゴム組成物及び車両用防振ゴム

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KR101381445B1 (ko) * 2009-11-12 2014-04-25 주식회사 엘지화학 변성 중합 개시제, 및 이를 이용한 고 비닐 공역디엔계 공중합체
JP5097803B2 (ja) * 2010-04-05 2012-12-12 住友ゴム工業株式会社 タイヤ用ゴム組成物及び空気入りタイヤ
JP5552025B2 (ja) * 2010-10-29 2014-07-16 住友ゴム工業株式会社 タイヤ用ゴム組成物及び空気入りタイヤ
CN103814076A (zh) * 2011-09-26 2014-05-21 住友橡胶工业株式会社 轮胎用橡胶组合物及充气轮胎
JP5719743B2 (ja) * 2011-10-06 2015-05-20 住友ゴム工業株式会社 タイヤ用ゴム組成物及び空気入りタイヤ
JP6075943B2 (ja) 2011-10-17 2017-02-08 住友ゴム工業株式会社 タイヤ用ゴム組成物及び空気入りタイヤ
KR101525291B1 (ko) 2012-12-06 2015-06-02 주식회사 엘지화학 중합 개시제, 변성 공액 디엔계 중합체 및 이로부터 제조된 타이어
JP6069044B2 (ja) * 2013-03-12 2017-01-25 住友ゴム工業株式会社 ベーストレッド用ゴム組成物及び空気入りタイヤ
KR20160079323A (ko) 2014-12-26 2016-07-06 한화토탈 주식회사 변성 공액디엔계 중합체 및 그를 포함하는 조성물
WO2016199915A1 (ja) * 2015-06-12 2016-12-15 横浜ゴム株式会社 ゴム組成物およびそれを用いた空気入りタイヤ
US10815328B2 (en) 2015-11-16 2020-10-27 Bridgestone Corporation Functional initiator for anionic polymerization
BR112019005573A2 (pt) * 2016-09-23 2019-06-04 Japan Elastomer Co Ltd polímero de dieno conjugado modificado, composição de polímero de dieno conjugado modificado, pneu e método para produção de polímero de dieno conjugado modificado
KR101893384B1 (ko) * 2017-07-25 2018-08-30 금호석유화학 주식회사 공중합체의 제조방법 및 이를 포함하는 고무 조성물
DE112018006052B4 (de) * 2017-11-28 2022-03-24 The Yokohama Rubber Co., Ltd. Luftreifen
CN108469388B (zh) * 2018-02-01 2020-11-24 上海大学 湿热条件下高聚物动态储能模量的预测方法
JP7398901B2 (ja) * 2018-08-28 2023-12-15 旭化成株式会社 変性共役ジエン系重合体組成物、ゴム組成物、及びゴム組成物の製造方法
CN111796084B (zh) * 2020-06-23 2022-09-16 中策橡胶集团股份有限公司 一种缺气保用轮胎支撑胶及其筛选方法和轮胎
EP4212562A4 (en) * 2020-09-11 2024-02-28 Denka Company Limited COMPOSITION AND HARDENED PRODUCT THEREOF

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009197118A (ja) * 2008-02-21 2009-09-03 Asahi Kasei Chemicals Corp 油展変性共役ジエン系重合体組成物
JP2009275178A (ja) * 2008-05-16 2009-11-26 Asahi Kasei Chemicals Corp 変性共役ジエン系重合体組成物及びこれを用いた加硫ゴム組成物
CN101691777B (zh) * 2009-09-24 2011-09-14 山东华腾环保科技有限公司 真空辅助便器
WO2015182078A1 (ja) * 2014-05-27 2015-12-03 株式会社ブリヂストン 重荷重用空気入りタイヤ
CN105899375A (zh) * 2014-05-27 2016-08-24 株式会社普利司通 重型载重用充气轮胎
JPWO2015182078A1 (ja) * 2014-05-27 2017-04-20 株式会社ブリヂストン 重荷重用空気入りタイヤ
JP2017132986A (ja) * 2016-01-26 2017-08-03 ハンファ トータル ペトロケミカル カンパニー リミテッド 変性共役ジエン系重合体及びこれを用いたタイヤゴム組成物
WO2018198647A1 (ja) * 2017-04-28 2018-11-01 株式会社ブリヂストン 防振ゴム用ゴム組成物及び車両用防振ゴム
JP2018188522A (ja) * 2017-04-28 2018-11-29 株式会社ブリヂストン 防振ゴム用ゴム組成物及び車両用防振ゴム

Also Published As

Publication number Publication date
EP2138516B1 (en) 2011-11-23
US20100210760A1 (en) 2010-08-19
EP2138516A4 (en) 2010-08-04
TW200906877A (en) 2009-02-16
US8278395B2 (en) 2012-10-02
CN101641378A (zh) 2010-02-03
KR20090114478A (ko) 2009-11-03
EP2138516A1 (en) 2009-12-30
CN101641378B (zh) 2011-07-27
JPWO2008123215A1 (ja) 2010-07-15
KR101049675B1 (ko) 2011-07-14
JP5342439B2 (ja) 2013-11-13
ATE534674T1 (de) 2011-12-15
TWI384001B (zh) 2013-02-01

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