US20090096036A1 - Semiconductor device and method of manufacturing the same - Google Patents
Semiconductor device and method of manufacturing the same Download PDFInfo
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- US20090096036A1 US20090096036A1 US12/248,250 US24825008A US2009096036A1 US 20090096036 A1 US20090096036 A1 US 20090096036A1 US 24825008 A US24825008 A US 24825008A US 2009096036 A1 US2009096036 A1 US 2009096036A1
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- H01L21/7624—Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers using semiconductor on insulator [SOI] technology
- H01L21/76264—SOI together with lateral isolation, e.g. using local oxidation of silicon, or dielectric or polycristalline material refilled trench or air gap isolation regions, e.g. completely isolated semiconductor islands
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- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
- H01L27/12—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body
- H01L27/1203—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body the substrate comprising an insulating body on a semiconductor body, e.g. SOI
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- H01L27/12—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body
- H01L27/1203—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body the substrate comprising an insulating body on a semiconductor body, e.g. SOI
- H01L27/1207—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body the substrate comprising an insulating body on a semiconductor body, e.g. SOI combined with devices in contact with the semiconductor body, i.e. bulk/SOI hybrid circuits
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- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
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- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
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Definitions
- the present invention relates to a semiconductor device and a manufacturing technology thereof. More particularly, the present invention relates to a MISFET (Metal Insulator Semiconductor Field Effect Transistor) formed on a substrate (SOI substrate) having an SOI (Silicon on Insulator) structure.
- MISFET Metal Insulator Semiconductor Field Effect Transistor
- a diffusion layer semiconductor region constituting the source and drain is also formed inside the thin SOI layer, an external resistance of the MISFET becomes high. Further, when a silicide layer is formed on an upper portion of the diffusion layer to reduce the resistance, a silicide layer reaches up to the buried insulating layer, and this reduces a contact area between the diffusion layer and the silicide layer, and a problem arises that a contact resistance is increased and a current is reduced.
- the stacked semiconductor layers are referred to as an elevated layer), which constitutes the source and drain by the semiconductor layers elevated at both sides of the gate (gate electrode).
- an elevated layer which constitutes the source and drain by the semiconductor layers elevated at both sides of the gate (gate electrode).
- a breakdown voltage-between source and drain of the MISFET fabricated on the SOI substrate is deteriorated, there arises a problem that it can be used only in a low voltage regime.
- a high-breakdown voltage element for example, MISFET
- an ESD protection element and the like for preventing ESD are fabricated not on the SOI substrate, but on a bulk substrate.
- Non-Patent Document 1 the SOI layer and the elevated insulating layer of the SOI substrate are removed, so that a bulk region whose silicon substrate is exposed on the same substrate is formed.
- the SOI region can be formed with the MISFET (hereinafter, referred to as SOI-MISFET) and the bulk region can be formed with the MISFET (hereinafter, referred to as bulk-MISFET) by a common process without complicating the process.
- SOI-MISFET MISFET
- bulk-MISFET MISFET
- the thickness of the elevated layer is suitable to each of the SOI-MISFET and the bulk-MISFET.
- the reason is because the conditions of impurity implantation for forming a diffusion layer are adjusted by the thickness of the elevated layer.
- FUSI full silicidation processing
- the inventors of the present invention have conducted a study on the semiconductor device having an SOI-MISFET and a bulk-MISFET mounted together.
- a step of forming an elevated layer on both of the SOI-MISFET and the bulk-MISFET by selective epitaxial growth is conceivable.
- the present inventors have found out a phenomenon that the thickness of the elevated layer is varied depending on a concentration of an impurity contained in the single crystal silicon serving as a base in the selective epitaxial growth. Specifically, it was found that the lower the impurity concentration is, the thicker the elevated layer becomes.
- the gate and the source/drain are silicided at the same time, it is necessary to elevate the elevated layer of the SOI-MISFET higher than the gate so that the silicide layer of the SOI-MISFET formed on the SOI layer does not reach the buried insulating layer.
- the base (single crystal silicon) of the elevated layer of the bulk-MISFET has an impurity concentration of approximately 5 ⁇ 10 17 /cm 3 to 1 ⁇ 10 19 /cm 3 .
- an impurity concentration thereof is about 1 ⁇ 10 9 /cm 3 or more, which is higher than that of the bulk-MISFET.
- the elevated layer of the bulk-MISFET becomes too high in this manner, on the occasion of forming the diffusion layer by the bulk-MISFET and the SOI-MISFET thereafter, it becomes necessary to adjust the conditions of the impurity implantation, and thus the process becomes complicated. Further, when the elevated layer of the bulk-MISFET becomes too much higher than a gate sidewall, the gate is sometimes connected to the source or drain at the time of silicidation.
- the thickness of the elevated layer is suitable to each of the SOI-MISFET and the bulk-MISFET.
- An object of the present invention is to provide a technology capable of realizing higher integration and higher performance of a semiconductor device.
- Another object of the present invention is to provide a technology capable of manufacturing a semiconductor device provided with an SOI-MISFET and a bulk-MISFET on the same semiconductor substrate.
- a semiconductor device has: a semiconductor substrate having an SOI region and a bulk region in a periphery of the SOI region; an SOI-MISFET provided in the SOI region; and a bulk-MISFET provided in the bulk-region having a breakdown voltage higher than that of the SOI-MISFET.
- the SOI-MISFET includes: an SOI layer provided on an insulating layer buried in the semiconductor substrate; a first gate electrode provided on the SOI layer interposing a first gate insulator; and a first elevated layer provided on the SOI-layer at both sidewall sides of the first gate electrode and having a height from the SOI layer larger than that of the first gate electrode to constitute a first source and drain.
- the bulk-MISFET includes: a second gate electrode provided on the semiconductor substrate interposing a second gate insulator thicker than the first gate insulator; and a second elevated layer forming a second source and drain provided on the semiconductor substrate at both sidewall sides of the second gate electrode.
- a thickness of the first elevated layer is larger than that of the second elevated layer, and the whole of the first gate electrode and the second gate electrode are silicided, and parts of the first source and drain and the second source and drain are silicided.
- the thicknesses of the first elevated layer and the second elevated layer are optimized, and the semiconductor device having the SOI-MISFET and the bulk-MISFET mounted together can be highly integrated and highly improved in performance.
- FIG. 1 is a planar view of main parts showing a semiconductor device according to one embodiment of the present invention
- FIG. 2 is a cross-sectional view of main parts of a semiconductor substrate taken along the line A-A′ of FIG. 1 ;
- FIG. 3 is a cross-sectional view of main parts of the semiconductor substrate taken along the line B-B′ of FIG. 1 ;
- FIG. 4 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device according to one embodiment of the present invention.
- FIG. 5 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 4 ;
- FIG. 6 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 5 ;
- FIG. 7 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 6 ;
- FIG. 8 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 7 ;
- FIG. 9 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device in the same step of FIG. 8 ;
- FIG. 10 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 8 and FIG. 9 ;
- FIG. 11 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 10 ;
- FIG. 13 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 12 ;
- FIG. 14 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 13 ;
- FIG. 15 is a diagram showing a thickness of an epitaxial film to be grown as expressed by a function of the growth time with respect to a state in which a concentration of an impurity contained in a single crystal silicon layer serving as a base varies in a selective epitaxial growth method;
- FIG. 16 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 14 ;
- FIG. 17 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 16 ;
- FIG. 18 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 17 ;
- FIG. 19 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 18 ;
- FIG. 20 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 19 ;
- FIG. 21 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 20 ;
- FIG. 22 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 21 ;
- FIG. 23 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 22 ;
- FIG. 24 is a cross-sectional view of main parts of a semiconductor device according to another embodiment of the present invention.
- FIG. 25 is a cross-sectional view of main parts of a semiconductor substrate in a manufacturing step of the semiconductor device of the another embodiment of the present invention.
- FIG. 26 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 25 ;
- FIG. 27 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 26 ;
- FIG. 28 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued from FIG. 27 .
- the number of the elements when referring to the number of elements (including number of pieces, values, amount, range, and the like), the number of the elements is not limited to a specific number unless otherwise stated or except the case where the number is apparently limited to a specific number in principle. The number larger or smaller than the specified number is also applicable.
- FIGS. 1 to 3 a semiconductor device according to an embodiment of the present invention is shown.
- FIG. 1 is a planar view of main parts
- FIG. 2 is a cross-sectional view of main parts taken along the line A-A′ of FIG. 1
- FIG. 3 is a cross-sectional view of main parts taken along the line B-B′ of FIG. 1 .
- FIG. 1 to facilitate visualization, illustrations of part of members such as an insulating film (insulator) are omitted.
- the semiconductor device of the present embodiment includes: an SOI-MISFET having a gate electrode 35 a that is fully silicided and an elevated source and drain structure inside an SOI region 100 of a silicon substrate 1 ; and a bulk-MISFET (high-breakdown voltage MISFET) having a gate electrode 35 b that is fully silicided and an elevated source and drain structure inside a bulk region 200 on the silicon substrate 1 that is exposed by removing an SOI layer 3 and a buried insulating layer 2 .
- the semiconductor device of the present embodiment includes: a silicon substrate 1 having an SOI region 100 and a peripheral region of the SOI region; the SOI-MISFET provided on an main surface of the silicon substrate 1 in the SOI region 100 ; and the bulk-MISFET provided on the main surface of the silicon substrate 1 in the bulk-region 200 and having a higher breakdown voltage than the SOI-MISFET.
- the gate electrode 35 a is formed on the silicon substrate 1 , the buried insulating layer 2 , and an SOI layer 3 , interposing a gate insulator 15 .
- the SOI-MISFET includes the SOI layer 3 on the buried insulating layer 2 buried in the silicon substrate 1 , and the gate electrode 35 a provided on the SOI layer 3 interposing the gate insulator 15 .
- the SOI-MISFET includes: a channel region formed in the SOI layer 3 directly under the gate electrode 35 a ; a semiconductor region (diffusion layer) 26 a or 29 a constituting the source and the drain (diffusion layer 26 or 29 ) formed in the SOI layer 3 on both sides of the channel region, and an extension layer (diffusion layer) 32 or 33 formed in the SOI layer 3 between the semiconductor region 26 a or 29 a and the channel region.
- the SOI-MISFET includes: a sidewall 34 made of an insulating film formed at a side portion of the gate electrode 35 a ; an offset spacer formed of a silicon oxide film 22 formed between this sidewall 34 and the gate electrode 35 a ; an elevated layer 24 formed of a single crystal semiconductor layer formed on the SOI layer 3 (semiconductor region 26 a or 29 a ), and a silicide layer 36 formed to the elevated layer 24 .
- This elevated layer 24 constitutes the source and drain (diffusion layer 26 or 29 ) of the SOI-MISFET, and at this time, it becomes a layer in which an implanted impurity is diffused (diffusion layer).
- an upper portion of the elevated layer 24 is silicided. Note that, if the SOI layer 3 below the elevated layer 24 is not silicided, the elevated layer 24 may be fully silicided.
- the SOI-MISFET includes a back gate contact electrode 41 for modulating the channel via a well 6 or 8 and the buried insulating layer 2 inside a back gate contact region 300 which similarly exposes the silicon substrate 1 inside the well 6 or 8 .
- a gate electrode 35 b is formed on the same silicon substrate 1 to which the SOI-MISFET is formed interposing a gate insulator 16 .
- the gate insulator 16 here is thicker in thickness than the gate insulator 15 of the SOI-MISFET. In this manner, the gate electrode 35 b provided on the silicon substrate 1 through the gate insulator 16 thicker than the gate insulator 15 is provided.
- the bulk-MISFET includes: a channel region formed in the silicon substrate 1 directly under this gate electrode 35 b ; a semiconductor region 27 a or 30 a constituting the source and drain (diffusion layer 27 or 30 ) formed on the silicon substrate 1 at both sides of this channel region; and an extension layer (diffusion layer) 20 or 21 formed on the silicon substrate 1 between this semiconductor region 27 a or 30 a and the channel region.
- the bulk-MISFET includes: the sidewall 34 formed of an insulating film formed at the side portion of the gate electrode 35 b ; an offset spacer formed of the silicon oxide film 22 formed between this sidewall 34 and the gate electrode 35 b ; an elevated layer 25 formed of a single crystal semiconductor layer formed on this silicon substrate 1 (semiconductor region 27 a or 30 a ); and a silicide layer 37 formed to the elevated layer 25 .
- This elevated layer 25 constitutes the source and drain (diffusion layer 27 or 30 ) of the bulk-MISFET, and at this time, it becomes a layer in which an implanted impurity is diffused (diffusion layer).
- whole of the gate electrodes 35 a and 35 b are constituted by fully silicided layers (silicide layers).
- a desired threshold voltage value is realized by the work function of the silicide layer. That is, a suppression of the gate depletion which causes a trouble in the gate electrode made of polycrystalline silicon, and a low resistance of gate electrode wiring is made possible.
- a gate electrode material applied with a Ni silicide film it is not limited to this, and the material may be one whose work function is positioned approximately on the center of a bandgap of a single crystal silicon thin film, among a metal film, a metal silicided film or a metal nitride film of Ni, Co, Ti, W, Ta, Mo, Cr, Al, Pt, Pa, and Ru, etc.
- a thickness of the elevated layer 24 of the SOI-MISFET is made thicker than that of the elevated layer 25 of the bulk-MISFET, and part of the source and drain (diffusion layer 26 or 29 ) of the SOI-MISFET and the source and drain (diffusion layer 27 or 30 ) of the bulk-MISFET are silicided.
- the SOI-MISFET in the present embodiment has the elevated layer 24 on the SOI layer 3 constituting the channel and extremely thin having a thickness of, for example, about 10 nm.
- Most part of the source and drain (diffusion layer 26 or 29 ) of the SOI-MISFET including the elevated layer 24 is constituted by the silicide layer 36 , and moreover, the silicide layer 36 is constituted so as not to reach the buried insulating layer 2 .
- the bulk-MISFET has the elevated layer 25 having a smaller thickness than the elevated layer 24 of the SOI-MISFET.
- the diffusion layer 27 or 30 formed by the same process as the SOI-MISFET can be formed deeply into the silicon substrate 1 , and moreover, formed with an impurity concentration distribution moderate from the upper surface. This can realize a resistance reduction of the diffusion layer 27 or 30 and reduction of a leakage current flowing through a PN junction between the diffusion layer 27 or 30 and the silicon substrate 1 at the same time.
- the silicide layer 37 can be formed from the elevated layer 25 constituting the source and drain (diffusion layer 27 or 30 ) of the bulk-MISFET into the silicon substrate 1 (semiconductor region 27 a or 30 a ), the contact area of the silicide layer 37 with the diffusion layer 27 or 30 can be increased so that the contact resistance is reduced.
- a high-performance SOI-MISFET and a bulk-MISFET such as a high-breakdown voltage element and an ESD protection element for protecting ESD breakdown (electrostatic breakdown) can be manufactured on the same substrate without complicating the process.
- a substrate (SOI-substrate) having a Full Depletion SOI structure is used.
- the thickness of the buried insulating layer 2 is smaller than or equal to 20 nm
- the thickness of the SOI layer 3 is smaller than or equal to 20 nm.
- the thicknesses of the elevated layer 24 of the SOI-MISFET and the elevated layer 25 of the bulk-MISFET are optimized, so that the semiconductor device having the SOI-MISFET and the bulk-MISFET mounted together can be highly integrated and highly improved in performance.
- a substrate (hereinafter, referred to as SOI substrate) is prepared, which has an SOI structure constituted by a semiconductor substrate, for example, the silicon substrate 1 of a P-type single crystal, the buried insulating layer 2 having a thickness of 10 nm buried in the silicon substrate 1 , and the SOI layer 3 serving as a single crystal semiconductor layer having a thickness of 10 nm on the buried insulating layer 2 .
- the SOI layer 3 can be made thin up to a desired thickness of about 10 nm after forming a silicon oxide film on the layer by, for example, a thermal oxidation method, and removing the silicon oxide film.
- the SOI substrate having a Full Depletion SOI structure is used to obtain a steep sub-threshold factor (S-factor).
- a silicon oxide film 4 is formed on the SOI layer 3 , and a device isolation region 5 is formed on the SOI substrate. More specifically, the thin silicon oxide film 4 having a thickness of about 10 nm is first formed on the SOI layer 3 by, for example, a thermal oxidation method, and after that, a silicon nitride film is deposited by, for example, a CVD (Chemical vapor Deposition) method.
- CVD Chemical vapor Deposition
- a pattern is formed, where the silicon nitride film, the silicon oxide film 4 , the SOI layer 3 , the buried insulating layer 2 , and a part (depth of 260 nm) of the silicon substrate 1 in the desired region are removed.
- a thick silicon oxide film is deposited on the whole surface by, for example, the CVD method by a thickness to the extent that the patterned region (trench) is buried, and with taking the previously deposited silicon nitride film as a terminal point, the deposited silicon oxide film is planarized by a chemical mechanical polishing (CMP) method.
- CMP chemical mechanical polishing
- the silicon nitride film used as the terminal point of the CMP is selectively removed by, for example, hot phosphoric acid, so that the device isolation region 5 which is an STI (Shallow Trench Isolation) is formed.
- STI Shallow Trench Isolation
- a part of the upper part of the planarized silicon oxide film is selectively removed by, for example, hydrofluoric acid cleaning, and thus the thickness of the silicon oxide film buried in the pattern (trench) can be adjusted and a step between the device isolation region 5 and the SOI layer 3 can be also controlled.
- the desired region of the silicon substrate 1 is selectively formed with the P-type well 6 and a threshold voltage control diffusion layer region 7 by ion implantation through the thin silicon oxide film 4 , the thin SOI layer 3 and the thin buried insulating layer 2 by using a lithography technology.
- the desired region of the silicon substrate 1 is selectively formed with the N-type well 8 and a threshold voltage control diffusion layer region 9 .
- a photoresist pattern 10 is formed in the SOT region 100 for forming the SOI-MISFET. More specifically, a photoresist is coated on the SOI substrate, and by the lithography technology, a photoresist pattern 10 is formed so as to form the bulk region 200 for forming the bulk-MISFET and to open a back gate contact region 300 for forming a back gate contact. At this time, the photoresist pattern 10 is formed so as to stretch to the device isolation region 5 of the boundary of the SOT region 100 and the bulk region 200 , and the device isolation region 5 of the boundary of the SOT region 100 and the back gate contact region 300 .
- the silicon oxide films 4 of the opened bulk region 200 and the back gate contact region 300 are removed by, for example, hydrofluoric acid cleaning.
- a part of the upper portion of the device isolation region 5 of the bulk region 200 made of the silicon oxide film is also scraped, and in the bulk region 200 , the step between the silicon substrate 1 and the STI (device isolation region 5 ) can be adjusted, and moreover, the step on the STI generated in the photoresist boundary part can be made gentle.
- the dry etching technology with taking the buried insulating layer 2 as a stopper, the SOT layer 3 is selectively removed, and after that, the photoresist is removed.
- the surface of the silicon substrate 1 is oxidized to the extent of 10 nm by a thermal oxidation method, and by using a sacrificial oxidation method of removing the silicon oxide film thus formed, a damage layer introduced on the silicon substrate 1 may be removed by dry etching having the SOI layer 3 removed. After that, for example, a thin silicon oxide film to the extent of 10 nm is formed again on the silicon substrate 1 by a thermal oxidation method, thereby reproducing conditions similar to those of FIGS. 8 and 9 .
- a step between the surface of the silicon substrate 1 and the surface of the SOI layer 3 of the SOI region 100 is small to the extent of 20 nm. This enables the SOI-MISFET and the bulk-MISFET to be formed by the same process in the deposition and processing of the polycrystalline silicon film, which later becomes a gate, and is effective for preventing unprocessed parts of the step portion and a gate disconnection.
- a P-type well 11 and a threshold voltage control diffusion layer region 12 are selectively formed in the desired region of the silicon substrate 1 by a lithography technology and an ion implantation through the thin buried insulating layer 2 .
- an N-type well 13 and a threshold voltage control diffusion layer region 14 are selectively formed in the desired region of the silicon substrate 1 .
- the gate insulator 15 of the SOI-MISFET is formed in the SOI region 100
- the gate insulator 16 of the bulk-MISFET is formed in the bulk region 200 , and after that, for example, by a CVD method, a polycrystalline silicon film 17 having a thickness of 40 nm, a silicon oxide film 18 having a thickness of 50 nm, and a silicon nitride film 19 having a thickness of 30 nm are stacked in sequence, and by a lithography technology and anisotropic dry etching, a gate electrode and a gate protection film formed of the stacked film are formed.
- the gate insulator 15 of the SOI-MISFET in the SOI region 100 and the gate insulator 16 of the bulk-MISFET in the bulk region 200 are formed specifically as follows. First, the buried insulating layer 2 exposed on the surface of the bulk region 200 is removed, for example, by hydrofluoric acid cleaning so as to expose the surface of the silicon substrate 1 . After that, for example, by the thermal oxidation method, a thermal oxide film of 7.5 nm is formed on the silicon substrate 1 .
- the silicon oxide film 4 exposed on the surface is removed, and the thermal oxide film of 7.5 nm is formed on the SOI layer 3 .
- This is selectively removed, for example, by a lithography technology and hydrofluoric acid cleaning, and a thermal oxide film of 1.9 nm is formed on the SOI layer 3 , for example, by a thermal oxidation method.
- thermal oxide films of 7.5 nm and the thermal oxide film of 1.9 nm are nitrided by NO gas, thereby stacking and forming nitride films of 0.2 nm on the main surfaces, and the insulating film formed on the SOI layer 3 is taken as the gate insulator 15 , and the insulating film formed on the silicon substrate 1 is taken as the gate insulator 16 , respectively.
- the gate insulator 16 of the bulk-MISFET can be formed to be thicker than the gate insulator 15 of the SOI-MISFET.
- the breakdown voltage of the bulk-MISFET is made high so as to enable a high voltage operation.
- both of the regions can be formed simultaneously. Further, upon lamination and processing of the polycrystalline silicon film having a thickness of 40 nm as a gate material film, even in the step to stretch to both of the regions, both of the regions can be formed without unprocessed parts and disconnection.
- As (arsenic) ions are implanted for an N-type bulk-MISFET, and, for example, BF 2 ions are implanted for a P-type bulk-MISFET by an acceleration energy of 45 keV under conditions of implantation amounts of 3 ⁇ 10 13 /cm 2 and 5 ⁇ 10 13 /cm 2 , respectively.
- the silicon nitride film 19 and the silicon oxide film 18 serving as the gate protection films the polycrystalline silicon film 17 serving as the gate electrode and the channel region below the gate are not implanted with an impurity, and the surface region of the silicon substrate 1 has formed thereto a shallow N-type diffusion layer (hereinafter, referred to as an extension layer) 20 and a shallow P-type diffusion layer (similarly, referred to as an extension layer) 21 in a self-aligned manner ( FIG. 12 ).
- the SOI-MISFET is protected by the photoresist, so that an impurity is not implanted.
- a silicon oxide film 22 having a thickness of 10 nm and a silicon nitride film a thickness of 40 nm are deposited in sequence by a CVD method, and the silicon nitride film is selectively subjected to anisotropic etching with taking the silicon oxide film 22 as a stopper so as to form a sidewall 23 made of the silicon nitride film ( FIG. 13 ).
- the thin SOI layer 3 is protected by the silicon oxide film 22 , a reduction of the thickness due to dry etching and an introduction of damages can be prevented.
- the exposed silicon oxide film 22 is removed, and as shown in FIG. 14 , the SOI layer 3 of the SOI-MISFET serving as the source and drain region, and the silicon substrate 1 of the bulk-MISFET are exposed.
- a CDE Chemical Dry Etching
- an elevated single crystal layer formed of silicon or germanium is selectively formed on the exposed single crystal silicon (SOI layer 3 , silicon substrate 1 ).
- the inventors of the present invention have found out by experiments that the thickness of the single crystal semiconductor layer to be crystal-grown varies depending on the concentration of the impurity contained in the signal crystal silicon serving as a base. As shown in FIG. 15 , it is clear that, in relation to the growth time, the denser the impurity density contained in the silicon layer serving as the base is, the thinner the thickness of the epitaxial film to be grown becomes.
- a feature of the present embodiment is to form the impurity concentration of the SOI layer 3 serving as the base in the SOI-MISFET low at the time of performing the selective epitaxial growth by the extension layers 20 and 21 serving as the bases in the bulk-MISFET.
- the thickness of the elevated layer 24 of the SOI-MISFET can be formed thicker than that of the elevated layer 25 of the bulk-MISFET by a single epitaxial growth according to the dependency of the epitaxial film thickness on the impurity concentration of the single crystal silicon layer serving as the base.
- the elevated layer 24 having a thickness of 50 nm is formed for the SOI-MISFET, and the elevated layer 25 having a thickness of 30 nm is formed for the bulk-MISFET.
- the elevated layer 24 of the SOI-MISFET is required to be formed higher than the polycrystalline silicon film 17 serving as a gate so that the silicide layer does not reach the buried insulating layer 2 in the later silicide process.
- the N-type SOI-MISFET and the N-type bulk-MISFET are implanted with, for example, As ions by an acceleration energy of 11 keV under the conditions of the implantation amount of 4 ⁇ 10 15 /cm 2 .
- the silicon nitride film 19 and the silicon oxide film 18 serving as the gate protection films the polycrystalline silicon film 17 serving as the gate electrode and the channel region below the gate are not implanted with the impurities, and a N-type diffusion layer 26 of the SOI-MISFET and an N-type diffusion layer 27 of the bulk-MISFET are formed in a self-alignment manner ( FIG. 17 ).
- the elevated layer 24 and the SOI layer 3 therebelow are implanted with the impurities, so that the N-type diffusion layer 26 constituting the source and drain is formed. At this time, the region of the SOI layer 3 constituting the N-type diffusion layer 26 is formed as the semiconductor region 26 a .
- the elevated layer 25 and the silicon substrate 1 therebelow are implanted with the impurities, so that the N-type diffusion layer 27 constituting the source and drain is formed. At this time, the region of the silicon substrate 1 constituting the N-type diffusion layer 27 is formed as the semiconductor region 27 a.
- a diffusion layer impurity compensation region 28 of the SOI-MISFET may be formed. This aims to reduce the junction capacitance of the source and drain diffusion layer, and is provided for the purpose that the threshold voltage control diffusion layer region 7 previously implanted is compensated by implanting ions of an opposite conductivity type, and an impurity compensation region is made near to an intrinsic impurity region.
- the above described ion implantation can be performed to the SOI-MISFET and the bulk-MISFET by a common process with adjusting implantation conditions to simplify the process.
- the P-type diffusion layer 29 of the SOI-MISFET and the P-type diffusion layer 30 of the bulk-MISFET and a diffusion layer impurity compensation region 31 of the SOI-MISFET are formed ( FIG. 17 ). That is, in the P-type SOI-MISFET, the elevated layer 24 and the SOI layer 3 therebelow are implanted with the impurity, so that the P-type diffusion layer 29 constituting the source and drain is formed. At this time, the region of the SOI layer 3 constituting the P-type diffusion layer 29 is formed as the semiconductor region 29 a .
- the elevated layer 25 and the silicon substrate 1 therebelow are implanted with the impurities, so that the P-type diffusion layer 30 constituting the source and drain is formed.
- the region of the silicon substrate 1 constituting the P-type diffusion layer 30 is formed as the semiconductor region 30 a.
- the sidewall 23 formed of the silicon nitride film and the silicon nitride film 19 of the gate protection film are selectively removed ( FIG. 18 ).
- the N-type SOI-MISFET is implanted with, for example, As ions under the conditions of an acceleration energy of 4 keV and an implantation amount of 5 ⁇ 10 15 /cm 2 .
- the silicon oxide film 18 serving as the gate protection film the polycrystalline silicon film 17 serving as the gate electrode and the channel region below the gate are not implanted with the impurities, and the N-type extension layer 32 is formed in a self-alignment manner.
- the P-type SOI-MISFET is implanted with, for example, B (boron) ions under the conditions of acceleration energy of 2 keV and the implantation amount of 5 ⁇ 10 14 /cm 2 , thereby forming the P-type extension layer 33 .
- B boron
- the implanted impurity is activated and diffused, thereby controlling the distance between the extension layers 32 and 33 and the gate.
- the silicon oxide film 22 of the gate sidewall deposited in advance can play a role of as an offset spacer for controlling the distance between the extension layers 32 and 33 and the gate at the time of the ion implantation.
- the extension layers 32 and 33 since it is possible to reduce a thermal load after forming the extension layers 32 and 33 , the expansion of the extension layers due to thermal diffusion can be prevented, and the layers can be formed with high controllability.
- the extension layers 32 and 33 are amorphized by the ion implantation with a high concentration, the implanted ions of the present process do not reach the channel region directly below the gate at the sides and the semiconductor region 26 a or 29 a , and thus the regions are single crystal layers. Therefore, with these regions taken as seed layers, the extension layers can be amorphized and it becomes possible to prevent an increase of the external resistance.
- a silicon nitride film having a thickness of 40 nm is deposited on the whole surface of the SOI substrate, and the SOI substrate is subjected to the anisotropic etching, thereby forming the sidewall 34 formed of the silicon nitride film at the gate side.
- the sidewall 34 is also formed between the elevated layers 24 and 25 and the device isolation region 5 .
- the sidewall 34 plays a role of preventing formation of an excessive silicide layer in the later silicide process due to Ni (nickel) deposited on the STI diffusing up to the elevated layer.
- the silicon oxide film 18 of the gate protection film is selectively removed by, for example, hydrofluoric acid cleaning to expose the polycrystalline silicon film 17 serving as the gate ( FIG. 21 ).
- a metal film e.g., a Ni film having a thickness of 20 nm is adhered (deposited) on the whole surface of the SOI substrate, and is reacted with silicon by thermal treatment of 320° C., so as to form a silicide layer.
- the unreacted Ni film is removed by, for example, a mixed aqueous solution of hydrochloric acid and hydrogen peroxide water, and then, a thermal treatment of 550° C. is added to control a phase of the silicide layer.
- the whole region of the gate electrode formed of the exposed polycrystalline silicon film 17 and at least upper regions of the N-type and the P-type high density diffusion layers 26 , 27 , 29 , and 30 are formed of silicide layers, and the full-silicided gate electrodes 35 a and 35 b and the silicide layers 36 and 37 are formed ( FIG. 22 ).
- the polycrystalline silicon film 17 without the impurity is converted into the silicide layers (gate electrode 35 a and 35 b ) until the regions contacting the gate insulators 15 and 16 , so that the desired threshold voltage value of the MISFET is realized by the lowered resistance of the gate wiring and the work function of the silicide layer. Further, the gate depletion causing a problem in the polycrystalline silicon gate electrode can be suppressed.
- the silicide layer 36 of the upper part of the diffusion layers 26 and 29 constituting the source and drain is located higher than the boundary surface of the gate electrode 35 a and the gate insulator 15 . That is, the silicide layer 36 is formed so as not to reach the buried insulating layer 2 , and a low contact resistance can be realized without reducing the contact area with the silicide layer 36 and the diffusion layers 26 and 29 . Further, in the thermal treatment of the silicide layer formation, it is possible to prevent an abnormal diffusion of the silicide layer toward the channel region below the gate that may occur after the silicide layer reaches the buried insulating layer 2 .
- the lower boundary surface of the silicide layer 37 may be formed inside the silicon substrate 1 .
- the boundary areas of the silicide layer 37 and the diffusion layers 27 and 30 are increased, the contact resistance can be further reduced.
- a CESL (Contact Etch Stopper Layer) 38 formed of a silicon nitride film, and an inter-layer insulating film 39 formed of a silicon oxide film are performed.
- the semiconductor device structure shown in FIG. 1 to FIG. 3 is completed.
- illustration is omitted, by processing through a wiring process including deposition and patterning of a metal film, and deposition and planarization, polishing, and the like of an insulating film between wirings, the semiconductor device is substantially completed.
- a plan view of main parts of a semiconductor device according to a second embodiment of the present invention is, for example, FIG. 1 , and a cross-sectional view of main parts of a semiconductor substrate taken along the line A-A′ of FIG. 1 at this time is FIG. 24 .
- the selective epitaxial growth process is performed twice, thereby forming first and second elevated layers for the SOI-MISFET and the bulk-MISFET, respectively. This point is different from the first embodiment.
- a first elevated layer (lowermost layer) 42 is formed directly below the sidewalls 34 at both sides of the gate.
- the diffusion layers 26 and 29 are provided such that the two layers have a distance from the gate electrode 35 a , the uppermost elevated layers 24 have more distance than the lowermost layers 42 in proportion. Since this first elevated layer 42 becomes a conductive region in addition to the SOI layer 3 , the external resistance of the SOI-MISFET can be further reduced, so that the device for higher driving current can be realized. Further, by forming the thickness of this first elevated layer 42 thin, the deterioration of the high speed of the device due to an increase in parasitic capacitance between the layer and the gate electrode 35 a can be prevented.
- Formation of the gate is performed basically in conformity with the first embodiment ( FIG. 12 ), and after that, as shown in FIG. 25 , the silicon oxide film 22 having a thickness of 10 nm and a silicon nitride film having a thickness of 10 nm are deposited in sequence, for example, by a CVD method, and with the silicon oxide film 22 taken as a stopper, the silicon nitride film is selectively subjected to anisotropic etching, thereby forming a thin spacer layer 44 formed of the silicon nitride film.
- the elevated layer is formed by a selective epitaxial growth method.
- the growth time is made short, and for example, the thin first stage elevated layer (lowermost layer) 42 having a thickness of 10 nm is formed in the SOI-MISFET, and the thin first stage elevated layer (lowermost layer) 43 having a thickness of 6 nm is formed in the bulk-MISFET.
- the silicon nitride film having a thickness of 30 nm is deposited, and is subjected to anisotropic etching, thereby forming the sidewall 23 formed of the silicon nitride film.
- the first stage elevated layer 42 is formed on the SOI layer 3 , and the thickness up to the buried insulating layer 2 is increased, and therefore, contrary to the first embodiment, the deposition of the silicon nitride film serving as a stopper may be omitted.
- the elevated layers 24 and 25 serving as the upper layers are formed.
- the semiconductor single crystal layer serving as the base of the growth becomes the first stage elevated layers 42 and 43 . Consequently, the impurity concentration contained in the first stage elevated layers 42 and 43 is adjusted by, for example, ion implantation.
- the grown film thickness in the present process can be controlled anew.
- the semiconductor device shown in FIG. 24 is substantially completed.
- the SOI-MISFET and the bulk-MISFET are mounted together in the above-described embodiments, this can be also applied to the case where, for example, the pair may be SOI-MISFETs themselves or bulk-MISFETs themselves. That is, for example, the elevated layers can be provided having different heights and the impurity concentrations can be different between SOI-MISFETs.
- the present invention can be widely used for manufacturing industries for manufacturing semiconductor devices.
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Abstract
There is provided an SOI-MISFET including: an SOI layer; a gate electrode provided on the SOI layer interposing a gate insulator; and a first elevated layer provided higher in height from the SOI layer than the gate electrode at both sidewall sides of the gate electrode on the SOI layer so as to constitute a source and drain. Further, there is also provided a bulk-MISFET including: a gate electrode provided on a silicon substrate interposing a gate insulator thicker than the gate insulator of the SOI MISFET; and a second elevated layer configuring a source and drain provided on a semiconductor substrate at both sidewalls of the gate electrode. A the first elevated layer is thicker than the elevated layer, and the whole of the gate electrodes, part of the source and drain of the SOI-MISFET, and part of the source and drain of the bulk-MISFET are silicided.
Description
- The present application claims priority from Japanese Patent Application No. JP 2007-265037 filed on Oct. 11, 2007, the content of which is hereby incorporated by reference into this application.
- The present invention relates to a semiconductor device and a manufacturing technology thereof. More particularly, the present invention relates to a MISFET (Metal Insulator Semiconductor Field Effect Transistor) formed on a substrate (SOI substrate) having an SOI (Silicon on Insulator) structure.
- Accompanied with introduction of higher integration and higher performance of LSIs (semiconductor devices), the miniaturization of a MISFET constituting an LSI has been advanced, and as a gate length of the MISFET is scaled, and thus a problem of short channel effect that reduces a threshold voltage Vth has become significant. This short channel effect arises from the fact that the broadening of depletion layers of the source and drain portions of the MISFET affects up to a channel portion along with the miniaturization of the channel length.
- On the contrary, in recent years, a full depletion type SOI structure has been attracting attentions. In this structure, the depletion layer induced in a body region directly below a gate electrode reaches up to the bottom of the body region, that is, an interface of the body region and a buried insulating layer, and thus a steep sub-threshold factor (S-factor) is obtained. In general, with respect to an element having a gate length smaller than or equal to 100 nm, a thin single-crystal semiconductor layer (SOI layer) on the buried insulating layer is required to be smaller than or equal to 20 nm.
- At this time, since a diffusion layer (semiconductor region) constituting the source and drain is also formed inside the thin SOI layer, an external resistance of the MISFET becomes high. Further, when a silicide layer is formed on an upper portion of the diffusion layer to reduce the resistance, a silicide layer reaches up to the buried insulating layer, and this reduces a contact area between the diffusion layer and the silicide layer, and a problem arises that a contact resistance is increased and a current is reduced.
- To avoid these problems, it is conceivable to form a so-called elevated source and drain structure (hereinafter, the stacked semiconductor layers are referred to as an elevated layer), which constitutes the source and drain by the semiconductor layers elevated at both sides of the gate (gate electrode). This is because, by elevating, that is, stacking semiconductor layers on the SOI layer serving as a base by using a selective epitaxial growth method, the silicide layer is prevented from reaching up to the buried insulating layer and the external resistance of the MISFET can be reduced.
- Meanwhile, since a breakdown voltage-between source and drain of the MISFET fabricated on the SOI substrate is deteriorated, there arises a problem that it can be used only in a low voltage regime. Hence, it is desirable that a high-breakdown voltage element (for example, MISFET), and an ESD protection element and the like for preventing ESD (electrostatic breakdown) are fabricated not on the SOI substrate, but on a bulk substrate.
- In Hou-Yu Chen et al., “Novel 20 nm Hybrid SOI/Bulk CMOS Technology with 0.183 μm2 6 T-SRAM Cell by Immersion Lithography”, 2005 Symposium on VLSI Technology Digest of Technical Papers, 2005, pp. 16-17 (Non-Patent Document 1), the SOI layer and the elevated insulating layer of the SOI substrate are removed, so that a bulk region whose silicon substrate is exposed on the same substrate is formed. As a result, by using the SOI substrate having an extremely thin buried insulating layer having a 20-nm thickness so that a step between the bulk region and the SOI region is made low, the SOI region can be formed with the MISFET (hereinafter, referred to as SOI-MISFET) and the bulk region can be formed with the MISFET (hereinafter, referred to as bulk-MISFET) by a common process without complicating the process.
- When the SOI-MISFET and the bulk-MISFET have an elevated source and drain structure (elevated layer), it is desirable that the thickness of the elevated layer is suitable to each of the SOI-MISFET and the bulk-MISFET. The reason is because the conditions of impurity implantation for forming a diffusion layer are adjusted by the thickness of the elevated layer. Further, to avoid a problem of gate depletion in the MISFET using polycrystalline (poly-) silicon for the gate, when a full silicidation processing (FUSI) is performed for fully siliciding the polycrystalline silicon of the gate up to the gate insulator, it is necessary to avoid the gate and the source or the drain from contacting with each other at the time of silicidation.
- The inventors of the present invention have conducted a study on the semiconductor device having an SOI-MISFET and a bulk-MISFET mounted together. For example, similarly to the
Non-Patent Document 1, when the SOI-MISFET and the bulk-MISFET are formed by a same process, a step of forming an elevated layer on both of the SOI-MISFET and the bulk-MISFET by selective epitaxial growth is conceivable. In the course of such a study, the present inventors have found out a phenomenon that the thickness of the elevated layer is varied depending on a concentration of an impurity contained in the single crystal silicon serving as a base in the selective epitaxial growth. Specifically, it was found that the lower the impurity concentration is, the thicker the elevated layer becomes. - Due to this phenomenon, after simply forming the elevated layers on both of the SOI-MISFET and the bulk-MISFET by the selective epitaxial growth, when the full silicidation processing is performed for fully siliciding the polycrystalline polysilicon of the gate up to the gate insulator, the problem described below is posed.
- When the gate and the source/drain are silicided at the same time, it is necessary to elevate the elevated layer of the SOI-MISFET higher than the gate so that the silicide layer of the SOI-MISFET formed on the SOI layer does not reach the buried insulating layer. Further, in the bulk-MISFET formed on the bulk (semiconductor substrate) of a high-breakdown voltage element and the like, to increase a breakdown voltage between the source and drain, the base (single crystal silicon) of the elevated layer of the bulk-MISFET has an impurity concentration of approximately 5×1017/cm3 to 1×1019/cm3. In the meantime, in the base (single crystal silicon) of the elevated layer of the SOI-MISFET, because of the reduction of the external resistance, an impurity concentration thereof is about 1×109/cm3 or more, which is higher than that of the bulk-MISFET.
- In such a case, when the elevated layers of the SOI-MISFET and the bulk-MISFET are formed simultaneously, due to the phenomenon found out by the present inventors, even when the height of the elevated layer of one SOI-MISFET is appropriately adjusted, the elevated layer of the bulk-MISFET becomes too high in the other bulk-MISFET, because the impurity concentration of the semiconductor region (single crystal silicon) of the base is low.
- When the elevated layer of the bulk-MISFET becomes too high in this manner, on the occasion of forming the diffusion layer by the bulk-MISFET and the SOI-MISFET thereafter, it becomes necessary to adjust the conditions of the impurity implantation, and thus the process becomes complicated. Further, when the elevated layer of the bulk-MISFET becomes too much higher than a gate sidewall, the gate is sometimes connected to the source or drain at the time of silicidation.
- Therefore, as mentioned above, it is desirable that the thickness of the elevated layer is suitable to each of the SOI-MISFET and the bulk-MISFET.
- An object of the present invention is to provide a technology capable of realizing higher integration and higher performance of a semiconductor device.
- Another object of the present invention is to provide a technology capable of manufacturing a semiconductor device provided with an SOI-MISFET and a bulk-MISFET on the same semiconductor substrate.
- The above and other objects and novel characteristics of the present invention will be apparent from the description of this specification and the accompanying drawings.
- The typical ones of the inventions disclosed in this application will be briefly described as follows.
- A semiconductor device according to one embodiment of the present invention has: a semiconductor substrate having an SOI region and a bulk region in a periphery of the SOI region; an SOI-MISFET provided in the SOI region; and a bulk-MISFET provided in the bulk-region having a breakdown voltage higher than that of the SOI-MISFET.
- The SOI-MISFET includes: an SOI layer provided on an insulating layer buried in the semiconductor substrate; a first gate electrode provided on the SOI layer interposing a first gate insulator; and a first elevated layer provided on the SOI-layer at both sidewall sides of the first gate electrode and having a height from the SOI layer larger than that of the first gate electrode to constitute a first source and drain.
- Further, the bulk-MISFET includes: a second gate electrode provided on the semiconductor substrate interposing a second gate insulator thicker than the first gate insulator; and a second elevated layer forming a second source and drain provided on the semiconductor substrate at both sidewall sides of the second gate electrode.
- Here, a thickness of the first elevated layer is larger than that of the second elevated layer, and the whole of the first gate electrode and the second gate electrode are silicided, and parts of the first source and drain and the second source and drain are silicided.
- The effects obtained by typical aspects of the present invention will be briefly described below.
- According to one embodiment, the thicknesses of the first elevated layer and the second elevated layer are optimized, and the semiconductor device having the SOI-MISFET and the bulk-MISFET mounted together can be highly integrated and highly improved in performance.
-
FIG. 1 is a planar view of main parts showing a semiconductor device according to one embodiment of the present invention; -
FIG. 2 is a cross-sectional view of main parts of a semiconductor substrate taken along the line A-A′ ofFIG. 1 ; -
FIG. 3 is a cross-sectional view of main parts of the semiconductor substrate taken along the line B-B′ ofFIG. 1 ; -
FIG. 4 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device according to one embodiment of the present invention; -
FIG. 5 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 4 ; -
FIG. 6 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 5 ; -
FIG. 7 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 6 ; -
FIG. 8 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 7 ; -
FIG. 9 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device in the same step ofFIG. 8 ; -
FIG. 10 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 8 andFIG. 9 ; -
FIG. 11 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 10 ; -
FIG. 12 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 11 ; -
FIG. 13 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 12 ; -
FIG. 14 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 13 ; -
FIG. 15 is a diagram showing a thickness of an epitaxial film to be grown as expressed by a function of the growth time with respect to a state in which a concentration of an impurity contained in a single crystal silicon layer serving as a base varies in a selective epitaxial growth method; -
FIG. 16 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 14 ; -
FIG. 17 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 16 ; -
FIG. 18 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 17 ; -
FIG. 19 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 18 ; -
FIG. 20 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 19 ; -
FIG. 21 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 20 ; -
FIG. 22 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 21 ; -
FIG. 23 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 22 ; -
FIG. 24 is a cross-sectional view of main parts of a semiconductor device according to another embodiment of the present invention; -
FIG. 25 is a cross-sectional view of main parts of a semiconductor substrate in a manufacturing step of the semiconductor device of the another embodiment of the present invention; -
FIG. 26 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 25 ; -
FIG. 27 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 26 ; and -
FIG. 28 is a cross-sectional view of main parts of the semiconductor substrate in a manufacturing step of the semiconductor device continued fromFIG. 27 . - In the embodiments described below, the invention will be described in a plurality of sections or embodiments when required as a matter of convenience. However, these sections or embodiments are not irrelevant to each other unless otherwise stated, and the one relates to the entire or a part of the other as a modification example, details, or a supplementary explanation thereof.
- Also, in the embodiments described below, when referring to the number of elements (including number of pieces, values, amount, range, and the like), the number of the elements is not limited to a specific number unless otherwise stated or except the case where the number is apparently limited to a specific number in principle. The number larger or smaller than the specified number is also applicable.
- Further, in the embodiments described below, it goes without saying that the components (including element steps) are not always indispensable unless otherwise stated or except the case where the components are apparently indispensable in principle.
- Also, components having the same function are denoted by the same reference symbols throughout the drawings for describing the embodiments, and the repetitive description thereof is omitted.
- Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings. It is needless to say that materials, types of conductivity, and conditions in manufacturing are not limited to those described in the embodiments, and there are many various modifications, respectively.
- In
FIGS. 1 to 3 , a semiconductor device according to an embodiment of the present invention is shown.FIG. 1 is a planar view of main parts,FIG. 2 is a cross-sectional view of main parts taken along the line A-A′ ofFIG. 1 , andFIG. 3 is a cross-sectional view of main parts taken along the line B-B′ ofFIG. 1 . In the planar view ofFIG. 1 , to facilitate visualization, illustrations of part of members such as an insulating film (insulator) are omitted. - The semiconductor device of the present embodiment includes: an SOI-MISFET having a
gate electrode 35 a that is fully silicided and an elevated source and drain structure inside anSOI region 100 of asilicon substrate 1; and a bulk-MISFET (high-breakdown voltage MISFET) having agate electrode 35 b that is fully silicided and an elevated source and drain structure inside abulk region 200 on thesilicon substrate 1 that is exposed by removing anSOI layer 3 and a buried insulatinglayer 2. - In this manner, the semiconductor device of the present embodiment includes: a
silicon substrate 1 having anSOI region 100 and a peripheral region of the SOI region; the SOI-MISFET provided on an main surface of thesilicon substrate 1 in theSOI region 100; and the bulk-MISFET provided on the main surface of thesilicon substrate 1 in the bulk-region 200 and having a higher breakdown voltage than the SOI-MISFET. - In the SOI-MISFET inside the
SOI region 100, thegate electrode 35 a is formed on thesilicon substrate 1, the buried insulatinglayer 2, and anSOI layer 3, interposing agate insulator 15. In this manner, the SOI-MISFET includes theSOI layer 3 on the buried insulatinglayer 2 buried in thesilicon substrate 1, and thegate electrode 35 a provided on theSOI layer 3 interposing thegate insulator 15. - Further, the SOI-MISFET includes: a channel region formed in the
SOI layer 3 directly under thegate electrode 35 a; a semiconductor region (diffusion layer) 26 a or 29 a constituting the source and the drain (diffusion layer 26 or 29) formed in theSOI layer 3 on both sides of the channel region, and an extension layer (diffusion layer) 32 or 33 formed in theSOI layer 3 between thesemiconductor region - Further, the SOI-MISFET includes: a
sidewall 34 made of an insulating film formed at a side portion of thegate electrode 35 a; an offset spacer formed of asilicon oxide film 22 formed between thissidewall 34 and thegate electrode 35 a; anelevated layer 24 formed of a single crystal semiconductor layer formed on the SOI layer 3 (semiconductor region silicide layer 36 formed to theelevated layer 24. Thiselevated layer 24 constitutes the source and drain (diffusion layer 26 or 29) of the SOI-MISFET, and at this time, it becomes a layer in which an implanted impurity is diffused (diffusion layer). In this manner, among theelevated layer 24 and thesemiconductor region diffusion layer 26 or 29) of the SOI-MISFET, an upper portion of theelevated layer 24 is silicided. Note that, if theSOI layer 3 below theelevated layer 24 is not silicided, theelevated layer 24 may be fully silicided. - Further, the SOI-MISFET includes a back
gate contact electrode 41 for modulating the channel via awell layer 2 inside a backgate contact region 300 which similarly exposes thesilicon substrate 1 inside the well 6 or 8. - In the bulk-MISFET inside the
bulk region 200, agate electrode 35 b is formed on thesame silicon substrate 1 to which the SOI-MISFET is formed interposing agate insulator 16. Thegate insulator 16 here is thicker in thickness than thegate insulator 15 of the SOI-MISFET. In this manner, thegate electrode 35 b provided on thesilicon substrate 1 through thegate insulator 16 thicker than thegate insulator 15 is provided. - Further, the bulk-MISFET includes: a channel region formed in the
silicon substrate 1 directly under thisgate electrode 35 b; asemiconductor region diffusion layer 27 or 30) formed on thesilicon substrate 1 at both sides of this channel region; and an extension layer (diffusion layer) 20 or 21 formed on thesilicon substrate 1 between thissemiconductor region - Further, the bulk-MISFET includes: the
sidewall 34 formed of an insulating film formed at the side portion of thegate electrode 35 b; an offset spacer formed of thesilicon oxide film 22 formed between thissidewall 34 and thegate electrode 35 b; anelevated layer 25 formed of a single crystal semiconductor layer formed on this silicon substrate 1 (semiconductor region silicide layer 37 formed to theelevated layer 25. Thiselevated layer 25 constitutes the source and drain (diffusion layer 27 or 30) of the bulk-MISFET, and at this time, it becomes a layer in which an implanted impurity is diffused (diffusion layer). In this manner, among theelevated layer 25 and thesemiconductor region diffusion layer 27 or 30) of the bulk-MISFET, whole of theelevated layer 25 and the upper portion of thesemiconductor region - Further, whole of the
gate electrodes - Further, in the semiconductor device according to the present embodiment, a thickness of the
elevated layer 24 of the SOI-MISFET is made thicker than that of theelevated layer 25 of the bulk-MISFET, and part of the source and drain (diffusion layer 26 or 29) of the SOI-MISFET and the source and drain (diffusion layer 27 or 30) of the bulk-MISFET are silicided. - Here, the SOI-MISFET in the present embodiment has the
elevated layer 24 on theSOI layer 3 constituting the channel and extremely thin having a thickness of, for example, about 10 nm. Most part of the source and drain (diffusion layer 26 or 29) of the SOI-MISFET including theelevated layer 24 is constituted by thesilicide layer 36, and moreover, thesilicide layer 36 is constituted so as not to reach the buried insulatinglayer 2. Hence, without increasing the contact resistance of thesilicide layer 36 and thediffusion layer - Further, the bulk-MISFET has the
elevated layer 25 having a smaller thickness than theelevated layer 24 of the SOI-MISFET. Hence, thediffusion layer silicon substrate 1, and moreover, formed with an impurity concentration distribution moderate from the upper surface. This can realize a resistance reduction of thediffusion layer diffusion layer silicon substrate 1 at the same time. Further, since thesilicide layer 37 can be formed from theelevated layer 25 constituting the source and drain (diffusion layer 27 or 30) of the bulk-MISFET into the silicon substrate 1 (semiconductor region silicide layer 37 with thediffusion layer - Further, in the present embodiment, a high-performance SOI-MISFET and a bulk-MISFET such as a high-breakdown voltage element and an ESD protection element for protecting ESD breakdown (electrostatic breakdown) can be manufactured on the same substrate without complicating the process.
- In the present embodiment, a substrate (SOI-substrate) having a Full Depletion SOI structure is used. In this SOI substrate, the thickness of the buried insulating
layer 2 is smaller than or equal to 20 nm, and the thickness of theSOI layer 3 is smaller than or equal to 20 nm. By using this SOI substrate, in the SOI-MISFET, a depletion layer induced in a body region directly below thegate electrode 35 a reaches up to the bottom of the body region, that is, the boundary with the buried insulatinglayer 2, and therefore, a steep sub-threshold factor (S-factor) can be obtained. - In this manner, according to the present embodiment, the thicknesses of the
elevated layer 24 of the SOI-MISFET and theelevated layer 25 of the bulk-MISFET are optimized, so that the semiconductor device having the SOI-MISFET and the bulk-MISFET mounted together can be highly integrated and highly improved in performance. - Next, an example of a method of manufacturing the semiconductor device in the present embodiment as configured according to the foregoing will be described in an order of steps by using the drawings. While descriptions will be made by fixing a semiconductor substrate and a conductive type of the semiconductor film, the combination of the conductive type may be arbitrary, and is not limited to the conductive type described in the present embodiment.
- First, as shown in
FIG. 4 , a substrate (hereinafter, referred to as SOI substrate) is prepared, which has an SOI structure constituted by a semiconductor substrate, for example, thesilicon substrate 1 of a P-type single crystal, the buried insulatinglayer 2 having a thickness of 10 nm buried in thesilicon substrate 1, and theSOI layer 3 serving as a single crystal semiconductor layer having a thickness of 10 nm on the buried insulatinglayer 2. TheSOI layer 3 can be made thin up to a desired thickness of about 10 nm after forming a silicon oxide film on the layer by, for example, a thermal oxidation method, and removing the silicon oxide film. In the present embodiment, the SOI substrate having a Full Depletion SOI structure is used to obtain a steep sub-threshold factor (S-factor). - Subsequently, as shown in
FIG. 5 , asilicon oxide film 4 is formed on theSOI layer 3, and adevice isolation region 5 is formed on the SOI substrate. More specifically, the thinsilicon oxide film 4 having a thickness of about 10 nm is first formed on theSOI layer 3 by, for example, a thermal oxidation method, and after that, a silicon nitride film is deposited by, for example, a CVD (Chemical vapor Deposition) method. Next, by lithography technology and dry etching technology, a pattern (trench) is formed, where the silicon nitride film, thesilicon oxide film 4, theSOI layer 3, the buried insulatinglayer 2, and a part (depth of 260 nm) of thesilicon substrate 1 in the desired region are removed. Next, a thick silicon oxide film is deposited on the whole surface by, for example, the CVD method by a thickness to the extent that the patterned region (trench) is buried, and with taking the previously deposited silicon nitride film as a terminal point, the deposited silicon oxide film is planarized by a chemical mechanical polishing (CMP) method. Next, the silicon nitride film used as the terminal point of the CMP is selectively removed by, for example, hot phosphoric acid, so that thedevice isolation region 5 which is an STI (Shallow Trench Isolation) is formed. At this time, before removing the silicon nitride film, a part of the upper part of the planarized silicon oxide film is selectively removed by, for example, hydrofluoric acid cleaning, and thus the thickness of the silicon oxide film buried in the pattern (trench) can be adjusted and a step between thedevice isolation region 5 and theSOI layer 3 can be also controlled. - Subsequently, as shown in
FIG. 6 , in theSOI region 100 forming the SOI-MISFET, the desired region of thesilicon substrate 1 is selectively formed with the P-type well 6 and a threshold voltage controldiffusion layer region 7 by ion implantation through the thinsilicon oxide film 4, thethin SOI layer 3 and the thin buried insulatinglayer 2 by using a lithography technology. Subsequently, similarly, the desired region of thesilicon substrate 1 is selectively formed with the N-type well 8 and a threshold voltage controldiffusion layer region 9. - Subsequently, as shown in
FIG. 7 , in theSOT region 100 for forming the SOI-MISFET, aphotoresist pattern 10 is formed. More specifically, a photoresist is coated on the SOI substrate, and by the lithography technology, aphotoresist pattern 10 is formed so as to form thebulk region 200 for forming the bulk-MISFET and to open a backgate contact region 300 for forming a back gate contact. At this time, thephotoresist pattern 10 is formed so as to stretch to thedevice isolation region 5 of the boundary of theSOT region 100 and thebulk region 200, and thedevice isolation region 5 of the boundary of theSOT region 100 and the backgate contact region 300. - Subsequently, as shown in
FIGS. 8 and 9 , thesilicon oxide films 4 of the openedbulk region 200 and the backgate contact region 300 are removed by, for example, hydrofluoric acid cleaning. At this time, a part of the upper portion of thedevice isolation region 5 of thebulk region 200 made of the silicon oxide film is also scraped, and in thebulk region 200, the step between thesilicon substrate 1 and the STI (device isolation region 5) can be adjusted, and moreover, the step on the STI generated in the photoresist boundary part can be made gentle. Next, for example, by the dry etching technology, with taking the buried insulatinglayer 2 as a stopper, theSOT layer 3 is selectively removed, and after that, the photoresist is removed. - After this, if needed, upon removal of the buried insulating
layer 2 on thesilicon substrate 1 by, for example, hydrofluoric acid cleaning, the surface of thesilicon substrate 1 is oxidized to the extent of 10 nm by a thermal oxidation method, and by using a sacrificial oxidation method of removing the silicon oxide film thus formed, a damage layer introduced on thesilicon substrate 1 may be removed by dry etching having theSOI layer 3 removed. After that, for example, a thin silicon oxide film to the extent of 10 nm is formed again on thesilicon substrate 1 by a thermal oxidation method, thereby reproducing conditions similar to those ofFIGS. 8 and 9 . - In the
bulk region 200 and the backgate contact region 300 thus formed through the above-described process, a step between the surface of thesilicon substrate 1 and the surface of theSOI layer 3 of theSOI region 100 is small to the extent of 20 nm. This enables the SOI-MISFET and the bulk-MISFET to be formed by the same process in the deposition and processing of the polycrystalline silicon film, which later becomes a gate, and is effective for preventing unprocessed parts of the step portion and a gate disconnection. - Subsequently, as shown in
FIG. 10 , in thebulk region 200, a P-type well 11 and a threshold voltage controldiffusion layer region 12 are selectively formed in the desired region of thesilicon substrate 1 by a lithography technology and an ion implantation through the thin buried insulatinglayer 2. Subsequently, similarly, an N-type well 13 and a threshold voltage controldiffusion layer region 14 are selectively formed in the desired region of thesilicon substrate 1. - Subsequently, as shown in
FIG. 11 , thegate insulator 15 of the SOI-MISFET is formed in theSOI region 100, and thegate insulator 16 of the bulk-MISFET is formed in thebulk region 200, and after that, for example, by a CVD method, apolycrystalline silicon film 17 having a thickness of 40 nm, asilicon oxide film 18 having a thickness of 50 nm, and asilicon nitride film 19 having a thickness of 30 nm are stacked in sequence, and by a lithography technology and anisotropic dry etching, a gate electrode and a gate protection film formed of the stacked film are formed. - Here, the
gate insulator 15 of the SOI-MISFET in theSOI region 100 and thegate insulator 16 of the bulk-MISFET in thebulk region 200 are formed specifically as follows. First, the buried insulatinglayer 2 exposed on the surface of thebulk region 200 is removed, for example, by hydrofluoric acid cleaning so as to expose the surface of thesilicon substrate 1. After that, for example, by the thermal oxidation method, a thermal oxide film of 7.5 nm is formed on thesilicon substrate 1. - At this time, similarly, in the
SOI region 100, thesilicon oxide film 4 exposed on the surface is removed, and the thermal oxide film of 7.5 nm is formed on theSOI layer 3. This is selectively removed, for example, by a lithography technology and hydrofluoric acid cleaning, and a thermal oxide film of 1.9 nm is formed on theSOI layer 3, for example, by a thermal oxidation method. - The surfaces of these thermal oxide films of 7.5 nm and the thermal oxide film of 1.9 nm are nitrided by NO gas, thereby stacking and forming nitride films of 0.2 nm on the main surfaces, and the insulating film formed on the
SOI layer 3 is taken as thegate insulator 15, and the insulating film formed on thesilicon substrate 1 is taken as thegate insulator 16, respectively. - In this manner, the
gate insulator 16 of the bulk-MISFET can be formed to be thicker than thegate insulator 15 of the SOI-MISFET. As a result, the breakdown voltage of the bulk-MISFET is made high so as to enable a high voltage operation. - Further, in the present embodiment, as described above, since the step between the
SOI region 100 and thebulk region 200 is low to the extent of 20 nm, it is within an allowable range of focal depth upon the lithography, and both of the regions can be formed simultaneously. Further, upon lamination and processing of the polycrystalline silicon film having a thickness of 40 nm as a gate material film, even in the step to stretch to both of the regions, both of the regions can be formed without unprocessed parts and disconnection. - Subsequently, by a lithography technology, for example, As (arsenic) ions are implanted for an N-type bulk-MISFET, and, for example, BF2 ions are implanted for a P-type bulk-MISFET by an acceleration energy of 45 keV under conditions of implantation amounts of 3×1013/cm2 and 5×1013/cm2, respectively. At this time, by the
silicon nitride film 19 and thesilicon oxide film 18 serving as the gate protection films, thepolycrystalline silicon film 17 serving as the gate electrode and the channel region below the gate are not implanted with an impurity, and the surface region of thesilicon substrate 1 has formed thereto a shallow N-type diffusion layer (hereinafter, referred to as an extension layer) 20 and a shallow P-type diffusion layer (similarly, referred to as an extension layer) 21 in a self-aligned manner (FIG. 12 ). In this ion implantation, the SOI-MISFET is protected by the photoresist, so that an impurity is not implanted. - Subsequently, as shown in
FIG. 13 , asilicon oxide film 22 having a thickness of 10 nm and a silicon nitride film a thickness of 40 nm are deposited in sequence by a CVD method, and the silicon nitride film is selectively subjected to anisotropic etching with taking thesilicon oxide film 22 as a stopper so as to form asidewall 23 made of the silicon nitride film (FIG. 13 ). In the present technique, since thethin SOI layer 3 is protected by thesilicon oxide film 22, a reduction of the thickness due to dry etching and an introduction of damages can be prevented. - Subsequently, for example, by hydrofluoric acid cleaning, the exposed
silicon oxide film 22 is removed, and as shown inFIG. 14 , theSOI layer 3 of the SOI-MISFET serving as the source and drain region, and thesilicon substrate 1 of the bulk-MISFET are exposed. At this time, if needed, a CDE (Chemical Dry Etching) may be performed to remove a damage layers of the surfaces of theSOI layer 3 and thesilicon substrate 1 introduced due to the ion implantation or the dry etching and the like. - Subsequently, by using a selective epitaxial growth method, an elevated single crystal layer formed of silicon or germanium is selectively formed on the exposed single crystal silicon (
SOI layer 3, silicon substrate 1). - In the selective epitaxial growth method, the inventors of the present invention have found out by experiments that the thickness of the single crystal semiconductor layer to be crystal-grown varies depending on the concentration of the impurity contained in the signal crystal silicon serving as a base. As shown in
FIG. 15 , it is clear that, in relation to the growth time, the denser the impurity density contained in the silicon layer serving as the base is, the thinner the thickness of the epitaxial film to be grown becomes. - Accordingly, a feature of the present embodiment is to form the impurity concentration of the
SOI layer 3 serving as the base in the SOI-MISFET low at the time of performing the selective epitaxial growth by the extension layers 20 and 21 serving as the bases in the bulk-MISFET. As a result, as shown inFIG. 16 , the thickness of theelevated layer 24 of the SOI-MISFET can be formed thicker than that of theelevated layer 25 of the bulk-MISFET by a single epitaxial growth according to the dependency of the epitaxial film thickness on the impurity concentration of the single crystal silicon layer serving as the base. - For example, the
elevated layer 24 having a thickness of 50 nm is formed for the SOI-MISFET, and theelevated layer 25 having a thickness of 30 nm is formed for the bulk-MISFET. Here, theelevated layer 24 of the SOI-MISFET is required to be formed higher than thepolycrystalline silicon film 17 serving as a gate so that the silicide layer does not reach the buried insulatinglayer 2 in the later silicide process. - Subsequently, by using a lithography technology, the N-type SOI-MISFET and the N-type bulk-MISFET are implanted with, for example, As ions by an acceleration energy of 11 keV under the conditions of the implantation amount of 4×1015/cm2. At this time, by the
silicon nitride film 19 and thesilicon oxide film 18 serving as the gate protection films, thepolycrystalline silicon film 17 serving as the gate electrode and the channel region below the gate are not implanted with the impurities, and a N-type diffusion layer 26 of the SOI-MISFET and an N-type diffusion layer 27 of the bulk-MISFET are formed in a self-alignment manner (FIG. 17 ). That is, in the N-type SOI-MISFET, theelevated layer 24 and theSOI layer 3 therebelow are implanted with the impurities, so that the N-type diffusion layer 26 constituting the source and drain is formed. At this time, the region of theSOI layer 3 constituting the N-type diffusion layer 26 is formed as thesemiconductor region 26 a. Similarly, in the N-type bulk-MISFET, theelevated layer 25 and thesilicon substrate 1 therebelow are implanted with the impurities, so that the N-type diffusion layer 27 constituting the source and drain is formed. At this time, the region of thesilicon substrate 1 constituting the N-type diffusion layer 27 is formed as thesemiconductor region 27 a. - Further, by additionally implanting, for example, P ions by an acceleration energy of 12 keV under the conditions of an implantation amount of 5×1014/cm2, even inside the
silicon substrate 1 below the buried insulatinglayer 2 in the SOI-MISFET, a diffusion layerimpurity compensation region 28 of the SOI-MISFET may be formed. This aims to reduce the junction capacitance of the source and drain diffusion layer, and is provided for the purpose that the threshold voltage controldiffusion layer region 7 previously implanted is compensated by implanting ions of an opposite conductivity type, and an impurity compensation region is made near to an intrinsic impurity region. - The above described ion implantation can be performed to the SOI-MISFET and the bulk-MISFET by a common process with adjusting implantation conditions to simplify the process.
- Subsequently, for the P-type SOI-MISFET and bulk-MISFET also, similarly to the foregoing, the P-
type diffusion layer 29 of the SOI-MISFET and the P-type diffusion layer 30 of the bulk-MISFET and a diffusion layerimpurity compensation region 31 of the SOI-MISFET are formed (FIG. 17 ). That is, in the P-type SOI-MISFET, theelevated layer 24 and theSOI layer 3 therebelow are implanted with the impurity, so that the P-type diffusion layer 29 constituting the source and drain is formed. At this time, the region of theSOI layer 3 constituting the P-type diffusion layer 29 is formed as thesemiconductor region 29 a. Similarly, in the P-type bulk-MISFET, theelevated layer 25 and thesilicon substrate 1 therebelow are implanted with the impurities, so that the P-type diffusion layer 30 constituting the source and drain is formed. At this time, the region of thesilicon substrate 1 constituting the P-type diffusion layer 30 is formed as thesemiconductor region 30 a. - Subsequently, for example, by hot phosphoric acid cleaning, the
sidewall 23 formed of the silicon nitride film and thesilicon nitride film 19 of the gate protection film are selectively removed (FIG. 18 ). - Subsequently, as shown in
FIG. 19 , by using a lithography technology, the N-type SOI-MISFET is implanted with, for example, As ions under the conditions of an acceleration energy of 4 keV and an implantation amount of 5×1015/cm2. At this time, by thesilicon oxide film 18 serving as the gate protection film, thepolycrystalline silicon film 17 serving as the gate electrode and the channel region below the gate are not implanted with the impurities, and the N-type extension layer 32 is formed in a self-alignment manner. - Similarly, the P-type SOI-MISFET is implanted with, for example, B (boron) ions under the conditions of acceleration energy of 2 keV and the implantation amount of 5×1014/cm2, thereby forming the P-
type extension layer 33. - Subsequently, for example, by a RTA (Rapid Thermal Anneal) of 1050° C. in the nitrogen atmosphere, the implanted impurity is activated and diffused, thereby controlling the distance between the extension layers 32 and 33 and the gate.
- At this time, the
silicon oxide film 22 of the gate sidewall deposited in advance can play a role of as an offset spacer for controlling the distance between the extension layers 32 and 33 and the gate at the time of the ion implantation. - Further, in the present embodiment, since it is possible to reduce a thermal load after forming the extension layers 32 and 33, the expansion of the extension layers due to thermal diffusion can be prevented, and the layers can be formed with high controllability.
- Further, even when the extension layers 32 and 33 are amorphized by the ion implantation with a high concentration, the implanted ions of the present process do not reach the channel region directly below the gate at the sides and the
semiconductor region - Subsequently, as shown in
FIG. 20 , a silicon nitride film having a thickness of 40 nm is deposited on the whole surface of the SOI substrate, and the SOI substrate is subjected to the anisotropic etching, thereby forming thesidewall 34 formed of the silicon nitride film at the gate side. At this time, thesidewall 34 is also formed between theelevated layers device isolation region 5. Thesidewall 34 plays a role of preventing formation of an excessive silicide layer in the later silicide process due to Ni (nickel) deposited on the STI diffusing up to the elevated layer. - Subsequently, the
silicon oxide film 18 of the gate protection film is selectively removed by, for example, hydrofluoric acid cleaning to expose thepolycrystalline silicon film 17 serving as the gate (FIG. 21 ). - Subsequently, for example, by a sputtering method, a metal film, e.g., a Ni film having a thickness of 20 nm is adhered (deposited) on the whole surface of the SOI substrate, and is reacted with silicon by thermal treatment of 320° C., so as to form a silicide layer. Subsequently, the unreacted Ni film is removed by, for example, a mixed aqueous solution of hydrochloric acid and hydrogen peroxide water, and then, a thermal treatment of 550° C. is added to control a phase of the silicide layer. As a result, the whole region of the gate electrode formed of the exposed
polycrystalline silicon film 17 and at least upper regions of the N-type and the P-type high density diffusion layers 26, 27, 29, and 30 are formed of silicide layers, and the full-silicided gate electrodes FIG. 22 ). - In the above described silicidation process, the
polycrystalline silicon film 17 without the impurity is converted into the silicide layers (gate electrode gate insulators - In the SOI-MISFET, as described with reference to
FIG. 16 , since theelevated layer 24 is formed higher than thegate electrode 35 a, the lower boundary surface of thesilicide layer 36 of the upper part of the diffusion layers 26 and 29 constituting the source and drain is located higher than the boundary surface of thegate electrode 35 a and thegate insulator 15. That is, thesilicide layer 36 is formed so as not to reach the buried insulatinglayer 2, and a low contact resistance can be realized without reducing the contact area with thesilicide layer 36 and the diffusion layers 26 and 29. Further, in the thermal treatment of the silicide layer formation, it is possible to prevent an abnormal diffusion of the silicide layer toward the channel region below the gate that may occur after the silicide layer reaches the buried insulatinglayer 2. - On the other hand, in the bulk-MISFET, as described with reference to
FIG. 16 , since theelevated layer 25 is formed lower than that of the SOI-MISFET, the lower boundary surface of thesilicide layer 37 may be formed inside thesilicon substrate 1. At this time, since the boundary areas of thesilicide layer 37 and the diffusion layers 27 and 30 are increased, the contact resistance can be further reduced. - Subsequently, as shown in
FIG. 23 , deposition and planarization of a CESL (Contact Etch Stopper Layer) 38 formed of a silicon nitride film, and an inter-layerinsulating film 39 formed of a silicon oxide film are performed. - Subsequently, by forming a contact hole reaching the gate, the back gate, and the source and drain, the semiconductor device structure shown in
FIG. 1 toFIG. 3 is completed. After that, though illustration is omitted, by processing through a wiring process including deposition and patterning of a metal film, and deposition and planarization, polishing, and the like of an insulating film between wirings, the semiconductor device is substantially completed. - A plan view of main parts of a semiconductor device according to a second embodiment of the present invention is, for example,
FIG. 1 , and a cross-sectional view of main parts of a semiconductor substrate taken along the line A-A′ ofFIG. 1 at this time isFIG. 24 . - While the elevated layers of the SOI-MISFET and the bulk-MISFET have been formed by the single selective epitaxial growth process in the first embodiment, in the second embodiment, the selective epitaxial growth process is performed twice, thereby forming first and second elevated layers for the SOI-MISFET and the bulk-MISFET, respectively. This point is different from the first embodiment.
- In the SOI-MISFET according to the second embodiment, a first elevated layer (lowermost layer) 42 is formed directly below the
sidewalls 34 at both sides of the gate. Hence, the diffusion layers 26 and 29 are provided such that the two layers have a distance from thegate electrode 35 a, the uppermostelevated layers 24 have more distance than thelowermost layers 42 in proportion. Since this firstelevated layer 42 becomes a conductive region in addition to theSOI layer 3, the external resistance of the SOI-MISFET can be further reduced, so that the device for higher driving current can be realized. Further, by forming the thickness of this firstelevated layer 42 thin, the deterioration of the high speed of the device due to an increase in parasitic capacitance between the layer and thegate electrode 35 a can be prevented. - Next, an example of a manufacturing method of the semiconductor device in the present embodiment configured as described above will be described according to the steps in sequence by using the drawings. For convenience of description, though a semiconductor substrate and a conductive type of the semiconductor film will be described being fixed, a combination of the conductive types may be arbitrary, and is not limited to the conductive type described in the present embodiment.
- Formation of the gate is performed basically in conformity with the first embodiment (
FIG. 12 ), and after that, as shown inFIG. 25 , thesilicon oxide film 22 having a thickness of 10 nm and a silicon nitride film having a thickness of 10 nm are deposited in sequence, for example, by a CVD method, and with thesilicon oxide film 22 taken as a stopper, the silicon nitride film is selectively subjected to anisotropic etching, thereby forming athin spacer layer 44 formed of the silicon nitride film. - Subsequently, as shown in
FIG. 26 , similarly to the first embodiment, the elevated layer is formed by a selective epitaxial growth method. But, in the present embodiment, the growth time is made short, and for example, the thin first stage elevated layer (lowermost layer) 42 having a thickness of 10 nm is formed in the SOI-MISFET, and the thin first stage elevated layer (lowermost layer) 43 having a thickness of 6 nm is formed in the bulk-MISFET. - Subsequently, as shown in
FIG. 27 , for example, by a CVD method, the silicon nitride film having a thickness of 30 nm is deposited, and is subjected to anisotropic etching, thereby forming thesidewall 23 formed of the silicon nitride film. At this time, in the SOI-MISFET, the first stage elevatedlayer 42 is formed on theSOI layer 3, and the thickness up to the buried insulatinglayer 2 is increased, and therefore, contrary to the first embodiment, the deposition of the silicon nitride film serving as a stopper may be omitted. - Subsequently, as shown in
FIG. 28 , similarly to the first embodiment, by the selective epitaxial growth method, theelevated layers elevated layers elevated layers FIG. 15 , the grown film thickness in the present process can be controlled anew. - After that, by going through the same process as the process described with reference to
FIGS. 17 to 23 of the first embodiment, the semiconductor device shown inFIG. 24 is substantially completed. - In the foregoing, the invention made by the inventors of the present invention has been concretely described based on the embodiments. However, it is needless to say that the present invention is not limited to the foregoing embodiments and various modifications and alterations can be made within the scope of the present invention.
- For example, while descriptions have been made on the case where the SOI-MISFET and the bulk-MISFET are mounted together in the above-described embodiments, this can be also applied to the case where, for example, the pair may be SOI-MISFETs themselves or bulk-MISFETs themselves. That is, for example, the elevated layers can be provided having different heights and the impurity concentrations can be different between SOI-MISFETs.
- The present invention can be widely used for manufacturing industries for manufacturing semiconductor devices.
Claims (15)
1. A semiconductor device comprising:
a semiconductor substrate having a first region and a second region in a periphery of the first region;
a first MISFET provided on a main surface of the semiconductor substrate in the first region; and
a second MISFET having a breakdown voltage higher than that of the first MISFET provided on the main surface of the semiconductor substrate in the second region, wherein the first MISFET comprises:
a semiconductor layer provided on an insulating layer that is buried in the semiconductor substrate;
a first gate electrode provided on the semiconductor layer interposing a first gate insulator;
a first elevated layer provided at both sidewall sides of the first gate electrode so as to have a height from the semiconductor layer higher than that of the first gate electrode on the semiconductor layer and configuring a first source and drain of the first MISFET; and
a first semiconductor region configuring the first source and drain together with the first elevated layer and provided on the semiconductor substrate and below the first elevated layer, wherein
the second MISFET comprises:
a second gate electrode provided on the semiconductor substrate interposing a second gate insulator thicker than the first gate insulator;
a second elevated layer provided on the semiconductor substrate at both sidewall sides of the second gate electrode and configuring a second source and drain of the second MISFET; and
a second semiconductor region configuring the second source and drain together with the second elevated layer on the semiconductor substrate and below the second elevated layer, and wherein
a thickness of the first elevated layer is larger than that of the second elevated layer;
whole of the first gate electrode and the second gate electrode are silicided; and
part of the first source and drain and the second source and drain are silicided.
2. The semiconductor device according to claim 1 , wherein a thickness of the insulating layer is smaller than or equal to 20 nm and a thickness of the semiconductor layer is smaller than or equal to 20 nm.
3. The semiconductor device according to claim 1 , wherein an upper part or whole of the first elevated layer is silicided among the first elevated layer and the first semiconductor region configuring the first source and drain, and wherein
whole of the second elevated layer and an upper part of the second semiconductor region are silicided among the second elevated layer and the second semiconductor region configuring the second source and drain.
4. The semiconductor device according to claim 1 , wherein
the first elevated layer is provided to be distanced from the first gate electrode side such that the highest layer is more distanced than the lowermost layer of a plurality of layers in proportion.
5. The semiconductor device according to claim 1 , wherein
the first gate electrode and second gate electrode are silicided films of Ni, Co, Ti, W, Ta, Mo, Cr, Al, Pt, Pa or Ru.
6. A method of manufacturing a semiconductor device comprising the steps of:
(a) preparing a substrate that includes: a semiconductor substrate having a first region in which a first MISFET is formed and a second region in a periphery of the first region in which a second MISFET is formed; and a semiconductor layer on an insulating layer buried in the semiconductor substrate;
(b) removing the semiconductor layer and the insulating layer in the second region to expose the semiconductor substrate in the second region;
(c) forming a first gate electrode on the semiconductor layer in the first region interposing a first gate insulator;
(d) forming a second gate electrode interposing a second gate insulator that is thicker than the first gate insulator on the semiconductor substrate in the second region;
(e) forming a first extension layer having an impurity concentration higher than that of the semiconductor layer at both sidewall sides of the second gate electrode on the semiconductor substrate;
(f) depositing a first insulating film on the whole of a surface of the substrate and performing anisotropic etching to leave the first insulating films on both sidewalls of the first gate electrode and on both sidewalls of the second gate electrode after the step (e);
(g) forming a first elevated layer at both sidewall sides of the first gate electrode on the semiconductor layer by a selective epitaxial growth with taking the semiconductor layer as a base after the step (f);
(h) forming a second elevated layer at both sidewall sides of the second gate electrode on the semiconductor substrate by a selective epitaxial growth with taking the first extension layer as a base after the step (f);
(i) forming a first diffusion layer configuring a first source and drain of the first MISFET by implanting a first impurity into the first elevated layer and the semiconductor layer below the first elevated layer and diffusing the first impurity after the steps (g) and (h);
(j) forming a second diffusion layer configuring a second source and drain of the second MISFET by implanting a second impurity into the second elevated layer and the semiconductor substrate below the second elevated layer and diffusing the second impurity after the steps (g) and (h);
(k) removing the first insulating film after the steps (i) and (j); and
(l) forming a second extension layer at both sidewall sides of the first gate electrode on the semiconductor layer.
7. The method of manufacturing the semiconductor device according to claim 6 , further comprising the steps of:
(m) depositing a second insulating film on the whole surface of the substrate and performing the anisotropic etching to leave the second insulating film on both sidewalls of the second gate electrode, the second gate electrode, both sidewalls of the first elevated layer and the second elevated layer after the step (l); and
(n) depositing a metal film on the whole surface of the substrate and giving thermal processing to silicide the whole of the first gate electrode, the whole of the second gate electrode, part of the first source and drain, and part of the second source and drain after the step (m).
8. The method of manufacturing the semiconductor device according to claim 6 , wherein
the step (a) prepares the substrate to have the thickness of the insulating layer being smaller than or equal to 20 nm and the thickness of the semiconductor layer is smaller than or equal to 20 nm.
9. The method of manufacturing the semiconductor device according to claim 7 , wherein
the step (n) silicides an upper part or the whole of the first elevated layer configuring the first source and drain, and silicides the whole of the second elevated layer configuring the second source and drain and the semiconductor substrate below the second elevated layer.
10. The method of manufacturing the semiconductor device according to claim 7 , wherein
the step (n) deposits the metal films by Ni, Co, Ti, W, Ta, Mo, Cr, Al, Pt, Pa or Ru.
11. A method of manufacturing a semiconductor device comprising the steps of:
(a) preparing a substrate that includes: a semiconductor substrate having a first region in which a first MISFET is formed and a second region in a periphery of the first region in which a second MISFET is formed; and a semiconductor layer on an insulating layer buried in the semiconductor substrate;
(b) removing the semiconductor layer and the insulating layer in the second region to expose the semiconductor substrate in the second region;
(c) forming a first gate electrode on the semiconductor layer in the first region interposing a first gate insulator;
(d) forming a second gate electrode interposing a second gate insulator that is thicker than the first gate insulator on the semiconductor substrate in the second region;
(e) forming a first extension layer having an impurity concentration higher than that of the semiconductor layer at both sidewall sides of the second gate electrode on the semiconductor substrate;
(f) depositing a first insulating film on the whole of a surface of the substrate and performing anisotropic etching to leave the first insulating films on both sidewalls of the first gate electrode and on both sidewalls of the second gate electrode after the step (e);
(g) forming a first lowermost layer configuring a first elevated layer at both sidewall sides of the first gate electrode on the semiconductor layer by a selective epitaxial growth with taking the semiconductor layer as a base after the step (f);
(h) forming a second lowermost layer configuring a second elevated layer at both sidewall sides of the second gate electrode on the semiconductor substrate by a selective epitaxial growth with taking the first extension layer as a base after the step (f);
(i) depositing the second insulating film on the whole surface of the substrate and performing the anisotropic etching to leave the second insulating film on both sidewalls of the first gate electrode and on both sidewalls of the second gate electrode after the steps (g) and (h);
(j) forming a first upper layer configuring the first elevated layer on both sidewalls of the first gate electrode of the first lowermost layer by a selective epitaxial growth with taking the first lowermost layer as a base after the step (i);
(k) forming a second upper layer configuring the second elevated layer on both sidewalls of the second gate electrode of the second lowermost layer by the selective epitaxial growth with the second lowermost layer taken as a base after the step (i);
(l) forming a first diffusion layer configuring a first source and drain of the first MISFET by implanting a first impurity into the first elevated layer and the semiconductor layer below the first elevated layer and diffusing the first impurity after the steps (j) and (k);
(m) forming a second diffusion layer configuring a second source and drain of the second MISFET by implanting a second impurity into the second elevated layer and the semiconductor substrate below the second elevated layer and diffusing the second impurity after the steps (j) and (k);
(n) removing the second insulating film and the first insulating film after the steps (l) and (m); and
(o) forming a second extension layer on the semiconductor layer at both sidewalls of the first gate electrode.
12. The method of manufacturing the semiconductor device according to claim 11 , further comprising the steps of:
(p) depositing a third insulating film on the whole surface of the substrate and performing the anisotropic etching to leave the third insulating film on both sidewalls of the second gate electrode, the second gate electrode, both sidewalls of the first elevated layer and the second elevated layer after the step (o); and
(q) depositing a metal film on the whole surface of the substrate and giving thermal processing to silicide the whole of the first gate electrode, the whole of the second gate electrode, part of the first source and drain, and part of the second source and drain after the step (p).
13. The method of manufacturing the semiconductor device according to claim 11 , wherein
the step (a) prepares the substrate to have the thickness of the insulating layer being smaller than or equal to 20 nm and the thickness of the semiconductor layer is smaller than or equal to 20 nm.
14. The method of manufacturing the semiconductor device according to claim 12 , wherein
the step (q) silicides an upper part or the whole of the first elevated layer configuring the first source and drain, and silicides the whole of the second elevated layer configuring the second source and drain and the semiconductor substrate below the second elevated layer.
15. The method of manufacturing the semiconductor device according to claim 12 , wherein
the step (q) deposits the metal films by Ni, Co, Ti, W, Ta, Mo, Cr, Al, Pt, Pa or Ru.
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Also Published As
Publication number | Publication date |
---|---|
JP2009094369A (en) | 2009-04-30 |
JP5222520B2 (en) | 2013-06-26 |
TWI383490B (en) | 2013-01-21 |
TW200924167A (en) | 2009-06-01 |
US20110195566A1 (en) | 2011-08-11 |
US8183115B2 (en) | 2012-05-22 |
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