TW316912B - - Google Patents

Description

316912 A7 B7

5. Description of the invention (1) The present invention is based on a multi-component copolymer of bond segments. In particular, the present invention is based on such a copolymer containing a large «straight bond or branched olefin polymer backbone and at least a monovalent monovinylidene aromatic polymer bond segment. US-A-3,235,626; IIS-A-3,786,116 and US-A-3,862,098 show that certain polymers and polymerization techniques include joining pre-generated functional group macromolecules to a variety of main polymers. References • A variety of functionalized polymolecules (for example, allyl polystyrene prepared by deionization technology) reacted with the primary bond generation army (including ethylene and the mixture of ethylene and copolymerizable monomers containing propylene) . The polymer prepared by the aforementioned technique has a physical property of bedding, but it has proved to be difficult to process in various aspects. Such polymers have the desired properties of block copolymers to a certain extent, and include the ability to form phase-separated fields. However, since the main polymer generally lacks obvious branches, it is impeded that the improved processing properties are hindered. In addition * the molecular weight distribution of the resulting polymer is believed to be wider than expected, which results in the physical properties of the resulting polymer being particularly low in tensile strength. Printed and printed by the Staff Consumer Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs ---------- installed (please first read the notes on the back of i * e s iv this page) line WO 94 / Q7930 The polyalpha-olefin long-branched polyolefin produced first. The branch includes vinyl ct-olefin polymers. These polymers are entirely Mα-olefin-based and lack the physical properties of bond-block multicomponent polymers (such as block copolymers). US-A-5,272,236 and US-A-5,278,272 disclose ethylene homopolymers and copolymers of ethylene and substantially linear high-carbon ct-olefins. The special excitement of this kind of polymer is the long-branch branch, that is, the random bond terminal olefin polymer is mixed with the resulting product. The blending of the main polymer along the polymer has an average of up to 3 per 100 0 carbon atoms. This paper uses the Chinese National Standard (CNS) A4 specification (210X297 mm) 316912 A7 B7. 5. Description of the invention (2) key. The more complete feature of the polymer is the melt «Flow_ 比 Ι1η / Ι2έ5.63, molecular weight distribution Mw / Mn defined by the following formula: 110

Mv / Mn < 63

Printed by the Industrial and Consumer Cooperatives of the Central Bureau of Economics and Economics *. The shear stress at the starting point of crude «cracking> is greater than 4 Χ 10〇β-factor / cm 2. The reference reveals multi-component polymers. EP-A-416,815 shows the use of certain novel metal complexes as letene polymerization catalysts. Similar catalysts, metal complexes, activation techniques and polymerization products are shown #See EP-Α · 468,651; EP-A-514,828; EP-Α-520,732 and Ϊ0 93/19104 · and US-A- 5,055, 438. US-A-5,057,475 »US-A-5,096,867 * US-A-5,064,802 and US, A-5,132,380. The first round Kan Mingzang dynamic eaves spectroscopy analysis polymer example 4 results of the present invention Kan Yu A bond segment multi-component copolymer includes: A) At least one olefin polymer bond segment includes a solid ethylene homopolymer or a substantially mediated or branched ethylene and at least one C3- * D〇t-olefin The copolymer of the copolymerized monomer, B) At least one monovinylidene aromatic polymer segment, the olefin polymer segment and the monovinylidene aromatic polymer bond segment are used to include a monovinylidene aromatic polymer bond The end of the macromonomer of the segment is copolymerized with ethylene or a mixture of ethylene and ethylene with the at least one copolymerization arm. In addition, the present invention is a method for producing the aforementioned multi-component copolymers including the following segments:

The size of the printed paper is applicable to the Chinese National Standard (CNS> A4 specification (210X297 mm) 316912 A7 B7 Printed by the Beigong Consumer Cooperative of the Central Standardization Bureau of the Ministry of Economic Affairs V. Description of the invention (3) 1) Polymerization under anionic polymerization conditions At least one monovinylidene aromatic monomer «and form active military vinylidene aromatic polymer bond segments in a hydrocarbon solution. 2) Via reactive monovinylidene aromatic polymer bond segments and vinyl functional group terminators to form vinyl ends Monomer of vinylidene vinylidene aromatic polymer «, and 3) Under the Ziegler-NaUa polymerization conditions, polymerize ethylene in the presence of vinyl« vinylene vinylidene aromatic polymer bond segment Rong Ethylene and at least one S from C3-* »a-Ethylene copolymer copolymer mixture«. This polymer has the desired physical properties of a typical bond segment compound. In addition, the melting properties of this polymer are improved in comparison with the typical segment polymers (such as block / segment copolymers or segment multi-component copolymers) produced according to the prior art. In particular, the viscosity of this polymer is significantly different from that of conventional polymers in terms of shear rate, thus improving the flowability of the polymer. In addition, this polymer can blend a significant amount of monovinylidene aromatic monomers into the olefin polymer segment, so the individual fields of the polymer can be adjusted (that is, the fields that can contribute to the olefin polymer bond segment and monovinylidene can be contributed Solubility parameters of the polymer sickle field) The multi-component copolymer of the key segment of the present invention is usually used as a chess-plastic resin • Impact balance modification, compatible with incompatible polymer mixtures * for packaging or other purposes Oriented film, non-oriented film, asphalt modified_and used for sticking_formulation. The polymer of the present invention is prepared by the technical modification of US-A-3,235,626, US-A-3,786,116 and US-A-3,862,098. In the unprocessed method, the functionalized macro point ¥ (referred to as vinyl thionyl, mono Asian Ethylene aromatic polymer segment) * For example, allyl beryllyl polymers of artenyl aromatic monomers, especially allyl flats (please read the * item on the back of * Λ and then write this page). -* tr, the standard size of the line paper is used in the Chinese National Standard (CNS) A4 (210X297mm) Printed by the Central Bureau of Economic Development of the Ministry of Economic Affairs, ① Gonggong Consumer Cooperatives 1 316912 A7 B7 5. Description of the invention (4) Ethylene-based thin any means of appreciation, specially prepared by Yinyingzi polymerization reaction *. Then, the functionalized macromolecule reacts with a from the main ytterbium of the mixture of ethylene and ethylene and c3-2ea-olefins under the Zieglerata polymerization conditions of the ore solution phase. In this example, the melt index or 1 * is measured according to ASTM D-1238 (190 / 2.16), and * 11 is measured according to 9:31) 10-1238 (190/10). The "quotation of qualification" mentioned for the use of the olefin polymer bond segment means that the main polymer of the polymer replaces up to 3 «long branches / 1000 breaks. Preferred polymers contain 0.01 to 3 long bond branches / 1000 carbons, more preferably 0.01 to 2 long bond branches / 1000 carbons, and particularly preferably 0.3 to 1 long chain branches / 1000 sulfonates. Preferably, the polymer of the present invention is substantially linear as defined in the aforementioned US-A-5,272,236. The long-branch branch is defined here to be any longer-graining length that is more conducive to the aliphatic portion of any olefin copolymer intentionally added to the reactor and blended into the polymer. The long branch can be as long as the length of the main bond of the polymer. The presence of the Nagao branch can be determined using 13C nuclear magnetic resonance spectroscopy (HMR) (particularly ethylene homopolymer) or GPC-LALS or any other shift analysis technique. NMR technology is further shown in Randall, Macroiol. Sci ·: Rev. Macro · ol. Chem. Phys., C29 (2 * 3), p.285-297 (1989). GPC-LALS and similar analysis techniques are further shown in J . Liq. Chrom., 7, 1809-1821 (1984); and Mirabella, Advances in Che .., Ser. 227. Polymer Chem., 23-44 (1990). Refers to the olefin polymer "paragraph use " The term "branch" means that the main chain K of the polymer is replaced by at least some short-bond branches. This short-bond branch can contribute to the deliberate use of this paper standard in China's national standard (CNS) A4 specification (210X297 mm). Please read the back * Note the matter again on this page). Installed-line 316912

Printed by the Beigong Consumer Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs V A7 B7_V. Description of the invention (5) The pendant hydrocarbon group of the vinyl substituent residue mixed in the copolymerization monomer of the reaction mixture «that is, the copolymerization monomer». The preferred comonomer is C3-8 ct-olefin, particularly good 04-1! 〇 (-olefin. Such copolymerized monomers are usually 0.1 to 8 (^ 1 ;! 1 !, more preferably 10 to 50wtJ; most It is preferred that the number of 20 to 40wU is mixed with the polymer. The preferred α-olefin copolymer used in the polymer segment of olefin burner «contains propylene * 1-J ene, 1-pentene, 1-hexene, 3-methyl Yl-1-pentene, 4-methyl · 1-pentene, 1-octene, styrene, allylbenzene, 1-decene and their mixtures. According to a specific example of this method, the polymer is M-linked The anchovy solution method (compared to the batch method) is produced. In other words, the polymer is continuously removed from the reactor and the military UK can replenish the consumption list "continuous addition of quick slaughter". Therefore, the stable strip in the reactor can be maintained. In addition * reaction The reactor is maintained at a high conversion rate. The preferred conditions include an ethylene content of less than 10wtX of the reactor content and a polymerization temperature from 50t: to 150C. If a narrow molecular weight distribution polymer is desired (Mw / Mn from 1.Q to 2.5) , The ethylene content of the reactor is preferably lower than the 8X weight ratio of the reactor contents, especially below this condition, the largest proportion of long bond branches mixed with the olefin polymer bond segment The polymerization reaction of the olefin polymer is carried out in the presence of a catalyst system. The catalyst system includes Group 3, Group 4 or lanthanum complex compounds corresponding to the formula: LMXX'nX ”p or two Element body, where: L is a non-localized π-bearing group containing a bond of up to 50 non-argon atoms to Μ; M is a group 3, 4 of the Periodic Table of the Elements or lanthanum 羸 羼; X is up to 5Q The divalent substituent of non-hydrogen atom and L together form a gold ring containing Μ; please read the note 1 ^ item on the back * 'and then ^^ this page)-Binding · Order • Line r This paper size is applicable China's Critical Care (CNS) A4 specification (210X297mm) 8

Oxygen printing V A7 B7_ of the Industrial and Consumer Cooperatives of the Central Bureau of Economic Development of the Ministry of Economic Affairs 5. Description of the invention (6) X 'is a selective neutral Lewis _ coordination group containing up to 20 non-hydrogen atoms; X "appears in each occurrence When the monovalent ions are partially buried from: Krypton deionization · Halogen atom • Hydrocarbyl group • Glycol * box alkyl group, hydrocarbyloxy group · andramine group • Siloxy group * halohydrocarbyl group, halosilyl group, silyl nicotinyl group • Amino hydrocarbyl groups • X ”contains up to 20 non-atom atoms, and two X” groups combine to form a sigma bond or a group bonded to Μ; η is the number of Q to 3; and P is 0 to 4 "Integer" It is preferred that the pre-generated dissolved vinyl alkynyl monovinyl aromatic polymer ammonium segment is added to the polymerization mixture via continuous ore batchwise or multi-batch addition technology, and the olefin polymer ion segment is polymerized in its presence. According to the present invention, L is a single non-localized π-bonding group containing up to 50 non-hydrogen atoms and bonded to M; M is group 4 of the periodic table of elements in the oxidation state of + 2 · +3 or +4 Metal 9 X is a divalent substituent containing up to 50 non-hydrogen atoms, which together with L form a gold-containing ring containing M; X 'is a non-Niyuan containing up to 20 Neutral Lewis salty K-position; η is 0 or 1; X ”at each occurrence is a monovalent moiety containing up to 20 non-hydrogen atoms from a hydrogen anion, a hydrocarbon group, a silane group or a staggered alkyl group; and Ρ is 0, 1, or 2. *. S, fe, please read the precautions on the back before # ¾ this page)-Binding-Threaded paper size is suitable for the national standards of the troubled countries (0 «) 8 4 specifications (21 (^ 297 mm) 316912 The Ministry of Economic Affairs of the Ministry of Economic Affairs and Industry Bureau of Industry and Commerce Cooperative Printed Oxygen A7 B7 V. Description of the invention (7) The entangled divalent X substituent preferably contains up to 30 non-hydrogen atoms * non-hydrogen atoms contain at least one At least one atom of oxygen, sparse, smashing, or beating into the group 14 of the periodic table is directly bonded to the delocalized π-bonding group, and one is covalently bonded to Μ of nitrogen, phosphorus, oxygen or sulfur. Different atoms. The L group used here includes any group that can be delocalized with group 3.4 or lanthanide metal; 1 part. Examples include pentadienyl, allyl and Pentadienyl, and substituted derivatives of this group. Preferred L groups include pentadienyl * indenyl watyl, tetrahydroindenyl, tetrahydrowatyl, octahydrowatyl, pentadienyl, Cyclic S dienyl, cyclosiladienyl, benzhydryl · dihydro «group, hexahydrogen M group, decahydro M group * and methyl-substituted derivatives. It is used here to describe the aforementioned substitution indefinite Localized π The "derivative" used in the formation of a group means a non-localized κ bond in which each atom can independently replace a group arbitrarily derived from the following: a smoke group * substituted for a hydrocarbyl group, one or more of which employs hydrogen Atomic M halogen atom substitution, hydrocarbyl-substituted alkynyl group, where the gold-like group is selected from Group 14 of the Yuansuo Periodic Table. Derivatives used to form substituted delocalized π-bonded groups should have hydrocarbon groups and substituted hydrocarbon groups containing 1 to 2Q carbon atoms and containing straight-chain and branched alkyl groups, ring-like hydrocarbon groups, alkyl-substituted ring-strip hydrocarbon groups, aromatic radicals and alkyl-substituted aromatic radicals》 In addition to two or more base rings They can form a condensed ring or a condensed ring system together. Examples of the latter include indenyl, tetrahydroindenyl, phthyl and octylphthyl. «When a hydrocarbon plug replaces an organic type, Jinjin contains 14 of the periodic table One-, two-, and three-substituted trivalent metal groups * in which each hydrocarbon group contains 1 to 20 carbon atoms. In particular, the organic substituted gold-like group containing trimethylbenzene contains trimethylsilicone. (Please read the back first) The precautions will be written on this page in V). Binding. Thread r This paper size is applicable to China National Standard (CN S) A4 specification (210X297 mm) 10 Printed by the Ministry of Economic Affairs, Central Bureau of Industry and Commerce Beigong Consumer Cooperatives A7 B7____ V. Description of invention (8) Alkyl, triethylsilyl, methyldiethylsilyl, tri Phenyl box alkyl • Trimethylgermanyl group. The highly preferred substituted non-localized π bonding group used in accordance with the present invention can be represented by the following formula: R.

Among them: R 'at each occurrence is hydrogen or a free atom respectively • Alkyl, aryl, haloalkyl · alkoxy, silane and their sister parts, R ′ contains up to 20 non-hydrogen atoms • Or 2 or more IT groups together form an aliphatic or aromatic perylene ring system; and another bond indicates the substitution of the delocalized π bond group to the position of X covalently. Preferably X corresponds to the formula: -Z-Υ, where Z is a bivalent portion that includes oxygen, or a shell of one of the 14 groups of the periodic table. The Z contains up to 20 non-argon atoms; and Y includes nitrogen and phosphorus The ligand or selective Z and Y together form a condensed tortoiseshell. In the example of "Height is better", X is:-(ER * 2) q, Y'—R ,, where: / E is carbon, silicon or thread at each occurrence; the paper size is applicable to China Kneading (CNS) A4 specification (210X297mm) (please read the precautions on the back first and then m 1 Γ line 11 11 316912 A7 B7. 5. Description of the invention (9) q is an integer from 1 to 4; Y 'is nitrogen Or phosphorus; R · is argon or hydrocarbon • silyl group or halo group at each occurrence, R · contains up to 20 non-hydrogen atoms, and R ′ ′ is hydrocarbon group • silyl group or silane group at each occurrence Hydrocarbyl-, the R "'contains up to 10 carbon or silicon atoms; or two or more R-groups or one or more R-groups and R "' together form a thick containing up to 30% non-argon atoms According to the present invention, the use of a gold ion complex with a better co-isolation degree corresponds to the formula:%

• Y (please read the precautions on the back: write this page)

Cp * · — Central Standard Shoulder Shellfish Consumer Cooperative Printed by the Ministry of Economic Affairs (X ") 2 where: Μ is hao or titanium; Cp- is cyclopentadienyl; or from indenyl, wat and argon or part Hydrogenated derivative group; or the aforementioned one group M—or more than one hydrocarbon group containing up to 20-carbon partial substitution; Z is SiRh * Cr2 * SiR-8SiR " 2, CraCITi, Cr = CR *, CR " * SiR * 8, or GeR2; where: R * in each occurrence is hydrogen * hydrocarbon Qi • silyl or halogenated hydrocarbon group * R- contains up to 20 non-hydrogen atoms, Y is nitrogen or phosphorus corresponding to the formula -N (R "") Or -P (R "")-based; where: 11 " "is (hu hydrocarbon group; and set-line r This paper standard uses the Chinese National Standard (CNS) A4 specification (210X297 mm) 12 5 1. Description of the invention (10 A7 B7 Zhongji Ministry of Central Sample Feng Bureau Beigong Consumer Cooperative Ink X "is a halogen atom at each occurrence, a hydrocarbon group containing up to 20 carbons or a hydrocarbon gas group containing up to 20 carbons • or The two X ”groups are both σ-bonded or π-bonded C4-2II co-extensive. The aforementioned examples of the most highly preferred gold-limb coordination clamp compounds include compounds in which amine groups or phosphorus are removed The subgroups are methyl * ethyl • propyl, butyl, pentyl, hexyl (these aliphatic groups contain all branched or ring isomers), orthobornyl, benzyl or phenyl; CP » Cyclopentadienyl, tetramethylcyclopentadienyl, indenyl, tetrahydroindenyl, fluorenyl, tetrahydroyanyl, octahydrofluorenyl · or the aforementioned one group and M-or more methyl Ethyl • propyl • butyl, pentyl • hexyl (these further substituents include all branches or ring isomers) * original norbornyl • benzyl or phenyl substitution; and X ”is methyl • neopentyl Base · trimethylsilyl, orthobornyl, benzyl, methylbenzyl, phenyl or pentafluorophenyl. The most Μ is titanium, Z is dimethyl silane, Υ is the third -J yl amine Group, Cp · is tetramethylcyclopentadienyl, and X ”is methyl or benzyl or two X” at each occurrence to form η * -1 · 4-diphenyl-1, 3 -Butadiene or n4-l, 3-pentadiene. Examples of Group 3.4 or lanthanum jinjin that can be used in the present invention include hydrocarbyl-substituted tanned cyclopentadienyl compounds such as: [(N-third- Butyl sulfonamide) dimethyl (n cyclopentadienyl) silane] titanium Sectional group, [(N-T-butylbutylamino) dimethyl (η »-cyclopentadienyl) silane] titanium dimethyl, [(N-cyclohexylamino) dimethyl (Cyclopentadienyl) Silane] Titanium two-section base, please read first. The note binding paper size is applicable to China * National Standard (CNS) A4 specifications (210X297 mm) 13 316912 at _B7___ 5. Description of the invention (11) [(N-cyclohexylamino) dimethyl (η *>-pentadienyl) silane] titanium dimethyl, [(N-third-butyl »amino) di Methyl (tetramethyl-7 »5-cyclopentadienyl) squaryl] titanium dibenzyl, [(N-third-butylacetamino) dimethyl (tetramethyl-7? 5 -Cyclopentadienyl) silane] titanium dimethyl, [(N-cyclohexylamino) dimethyl (tetramethyl-n s_cyclopentadienyl) silane] bis-diyl, [(N-cyclohexylamino) dimethyl (tetramethyl-r »s-cyclopentadienyl) silane] titanium dimethyl, [(N-third-butylamino) di Methyl (η 5-indenyl) silane] Peptide dibasic group [[(N-Third-butylaminoamino) dimethyl (η 5-tetrahydroindenyl) silane] titanium dimethyl, [ ( -Third-butyl androstamino) dimethyl (n fluorenyl) silane] titanium dimethyl, [(N- tertiary butylamino) bis (trimethylsilyl) octatetramethyl -»7» -Cyclopentadienyl) Silyl 1 and dibenzyl group, printed by the Ministry of Economic Affairs, Zhongzhangliang Bureau, Beigong Consumer Cooperative **. Please read the back and front notes I matters & this page f [(N-benzyl amido group) (dimethyl) (n s-cyclopentadienyl) silane] peptide bis (trimethyl * silyl), [(phenylphosphide) dimethyl (tetramethyl -ns-cyclopentadienyl) silane] titanium dibenzyl group, [(N-third-butylacetamino) dimethyl (n s-cyclopentadienyl) silane] demon (11) 774- 1,4-Diphenyl-1 * 3-butanediacetyl · This paper is based on China 8) Standard of China (CNS) A4 (210X297mm) Printed by Beigong Consumer Cooperatives, Central Bureau of Economics, Ministry of Economic Affairs * . A7 ___B7_ V. Description of the invention (12) [(N-Third-butylaminoamino) dimethyl (n cyclopentadienyl) silane] Titanium (II) 77 “1,3-pentadiene, [(H-cyclohexyl face group) dimethyl ι-pentadienyl] silane] titanium (II) Π * -1,4-diphenyl-1,3-J dienyl, [U-ring Hexyl Amino) dimethyl (η cyclopentadienyl) silane] 呔 (II) Π * -1,3-pentadiene · [(Ν- 三 -butylammonio) dimethyl (tetramethyl -Π »-cyclopentadienyl) silane] Titanium (II) P 4-1,4-diphenyl-1,3-pentadiene, [(U-third-butylamino) di Methyl (tetramethyl-77 »-cyclopentadienyl) silane] titanium (II);)« -I, 3-pentadiene, [U-cyclohexyl glycosamino) dimethyl (tetramethyl -n s_cyclopentadienyl) silane] titanium (II) η 4-1,4-diphenyl-1,3 · pentadiene, [(Ν-cyclohexylamino) dimethyl (tetra Methyl-η I cyclopentadienyl) silane] Titanium (ΙΙ) η * -1,3-pentadiene, [(Bu third-butylacetamino) dimethyl U 5 indenyl) silane]呔 （II） η, 4-Diphenyl-1,3-butadiene · [(Ν- 三 -butyl-aminoamino) dimethyltetrahydroindenyl) silane 1 呔 (II) /? 4_1 , 3-pentadiene, [(Ν-benzylaminoamino) dimethyl (tetramethyl-τϊ * »-cyclopentadienyl) silane] titanium (ΙΙ) η * -1,4-diphenyl -1,3-Butadiene · [(N-Third-Butylaminoamino) dimethyl (n s-fluorenyl) silane]] (II) rj 4-1,3-pentadiene , [(»-Third-Butylamino) (Di (trimethylsilyl)) (Tetramethyl-cyclopentadienyl) silane] Titanium 4_diphenyl ― 丨, 3_Butyl The paper scale is applicable to the Chinese National Standard (CNS) A4 (210X297mm). Please read the first 1-A note wy written on the back X) * ΤΓ-线-A7 B7 Ministry of Economic Affairs Central Sample Bureau Beigong Consumer Cooperative Indian policy five, description of invention (13) diene, [(N-benzylamino) (dimethyl) (n s-cyclopentadienyl) silane] titanium bis (trimethylsilyl) • and [(Phenyl phosphide) dimethyl (tetramethyl-rj s-cyclopentadienyl} silane] titanium (II) rj 4_1,4-diphenyl-1,3-butadiene. Other compounds that can be used to prepare the catalyst according to the present invention especially contain other Group 3, 4 or steel (the compounds are of course easily known by the industry. The best example is, in the example, -ZY contains up to 10 Non-hydrogen atom acetamidosilyl, especially (third-J-ylacetamido) (dimethylsilyl). The gold complex can be made catalytically active by combining with an activation auxiliary catalyst or using activation technology. The secondary activation catalyst used here includes polymer or oligomer aluminoxane * especially methylaluminoxane, triisobutylaluminum modified methylaluminoxane, or isobutylaluminoxane; Lewis compounds such as Ci-3Q ^ group substituted 13 group compounds, especially tri (hydrocarbyl) aluminum-or tri (hydrocarbyl)》 compound and its _ chemical (alloy halogenated) derivatives, each squaryl or halogenated hydrocarbon group contains 1 to 10 Carbons • more special perfluorinated tris (aryl) compounds * and the most special compounds (pentafluorophenyl) "alkanes; non-polymer compatible compounds produced by non-S-site chicks (including use of this under oxidizing conditions Etc.) Especially use ammonium-, non-K compatible with non-K anions; Oxygen grade-, Europium- · silicon- or Fine ^ Fu, or compatible with non-coordinating yin "Zi's iron suspicion; body hydrolysis (detailed below); and the combination of the aforementioned activation auxiliary catalyst and technology. The aforementioned activation auxiliary catalyst and activation technology were previously taught in the following References for different complexes: EP-A-277,003, US-A-5,153,157, US-A-5,064,802, EP-A-468,651, EP-A-520,732 and WO 93/23412 The national standards of the competing countries (Renyang) 8 4 specifications (210 > < 297mm) (read the note on the back first ^ item and then this page) • fm- fm

I I I I I I ft ^ I I I n I n ^ n n in n n n I I n I n I ^ 1 · I I I 16 3X6912 at B7

Central Committee of the Ministry of Agriculture and Fisheries Cooperation Du V. Description of the invention (14) The combination of neutral Lewis acids: trialkylaluminum compounds containing 1 to 4 carbons per alkyl group and trihalides containing 1 to 20 carbons per hydrocarbon group Combination of (hydrocarbyl) sugar compounds, especially tris (pentahydrophenyl) borane, and combinations of these neutral Lewis acid mixtures with polymer or oligomer aluminoxane * and single neutral Lewis acid, especially The combination of Ang (pentafluorophenyl) borane and polymer or oligomer aluminoxane is a particularly good auxiliary catalyst. A specific example of an ion generating compound applied as a secondary catalyst in the present invention includes a cation which is a Bronsted acid which can give a proton, and a compatible non-valent valence young child A. As used herein, the term > non-coordination # means that the anion or substance will not coordinate with the precursor complex containing Group 4 metal and the catalyst derivative derived therefrom, or it can only be combined with such The substance is weakly coordinated and therefore remains sufficiently replaced by neutral Louis M1. Non-coordinating anions specifically mean that when the complex with a cationic gold complex is used as a «charge-balance deionization, it will not reluctantly transfer the Yin Sizi substituent or its fragments to the Yang ions, thus forming a neutral complex of Yin Yang. " Compatible deionization " is an anion that does not decompose to neutral when the initial complex is decomposed, and does not interfere with the required post-brew polymerization or other uses of the complex. The preferred deionization is to contain a single coordination complex including a «golden core or gold-like core whose deionization can balance the active charge of the active catalyst species (metal ions) generated when the two components are combined. It must be easy enough to be replaced by ene, diene and acetylenic unplaned compounds or other neutral Lewis sickles such as ethers or please kind. Dangdang Jinbao especially contains aluminum. Sudang Jinlong includes but is not limited to boron, phosphorous and silicon. Compounds containing larvae including coordination complexes containing a single gold or gold-like atom are of course well known, and many of them please read first

surface? Of note ·

Order

This paper scale is applicable to the Chinese national standard (CNS M4 specification (210X297 mm) 17 A7 B7 V. Description of invention (15) Available in the market • Special deionized compounds containing military-atom atoms. The preferred auxiliary catalyst may be Μ is represented by the following general formula: (L- · H)-+ (Ad-) where: L «is a neutral Lewis _; (L--H) + is Bronsted acid;

Ad • is a non-coordinating compatible anion containing d · valence, and d is an integer from 1 to 3. Special good Arf_ corresponds to the formula: [M'K * Qn ·] · * -where: k is 1, 2 or 3; η 'is an integer from 2 to 6; η'-k: d; Μ' is selected from Element 13 of the periodic table; and Q at each occurrence are selected from shovel ions, dialkyl male bases, tooth donors, hydrocarbyl groups, hydrocarbyl oxygen scavengers, and-substituted hydrocarbon groups, halogen-substituted hydrocarbon gas Group, and halogen-substituted silyl hydrocarbyl groups (including perfluorinated hydrocarbyl groups with fully hydrocarbyloxy groups and perhalogenated silyl hydrocarbyl groups), Q contains up to 20 㑩 carbon, but Q is the number of occurrences of deionization No more than once. Examples of hydrocarbon oxyanion Q groups are shown in U.S. Patent 5,296,433. • In a better example, d is 1, which means that the relative chicks contain a single negative price and are A-. The activated auxiliary catalyst including boron, which is particularly useful for preparing the catalyst of the present invention, can be represented by the following general formula: [L * -H] · [BQ «] * Among them: This paper scale is applicable to the Chinese National Kneading Rate (CNS) A4 Specifications (210X297mm) < Please read the note $ item on the back first and then n I% 4-write this page) Order M Ministry of Economic Development Central Bureau of Industry and Commerce 5 industrial and consumer cooperatives printed version 5. Description of invention (16) A7 B7

The Ministry of Economic Affairs of the People's Republic of China shall print the $ LL for the Beigong Consumer Cooperative as defined above; B is the oxidation state of 3; Hydrocarbyloxy-, or fluorinated silane-based hydrocarbyl groups, the number of times Q is a hydrocarbyl group does not exceed one pass. The best Q at each occurrence is a fluorinated aryl group, especially pentafluorophenyl. Examples of compounds that can be used to prepare the improved catalyst of the present invention as activated auxiliary catalysts are tri-substituted ammonium paralysis such as: trimethylammonium tetraphenylphosphonate M, triethylammonium tetraphenylcarbosulfate, tripropylammonium tetraphenyl Tritonic acid, tris (n-butyl) ammonium tetraphenyl acid M, tris (tertiary-butyl) ammonium tetraphenyl »acid salt, Ν · Ν-dimethylbenzene tetraphenylbenzyl acid , Ν, Ν-diethylanilinium tetrabenzyl_acid, Ν, Ν-dimethyl-2,4,6-trimethylbenzylammonium tetrabenyl «acid, trimethyl lysine (pentafluorobenzene Base) borate, triethylammonium (pentafluorophenyl) borate, tripropylammonium (pentafluorophenyl) boric acid ", tri (n-butyl) ammonium (pentafluorobenzyl) salt, Tri (second-butyl) ammonium (pentaphenylphenyl) borate », N, N-dimethylanilinium (pentafluorophenyl) borate, N, N_dimethylanilinium n-butyl Chia (pentafluorobenzyl) borate, N, N-dimethylbenzylammonium tris (pentafluorophenyl) molybdate M, dimethylbenzylammonium (4- (tert-butyldimethyl) Silyl) -2,3,5,6-tetrafluorophenyl) carboxylic acid «, {], (1-dimethylanilinium (4- (triisopropyl silicon Alkyl) -2, 3, 5, 6-tetrabromophenyl) gallic acid gallium, N, N-dimethylanilinium pentafluorobenzene gas (pentafluorophenyl) millate · N, N-di Ethylanilinium (pentafluorophenyl) «acid, N, N-dimethyl-2,4,6-trimethylanilinium (pentafluorophenyl) benzoic acid trimethylammonium (2 , 3,4,6-Tetrafluorophenyl) phosphonate, triethylammonium (2,3,4,6-tetrafluorophenyl) metabolic acid ", tripropylammonium (2,3 paper size Applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) Please read the note on the back side first. Binding 19 316912 Α7 _ Β7 5. Description of the invention (Π), 4,6-tetrafluorophenyl) acid Washing, tris (n-butyl) ammonium (2,3,4,6-tetratetraphenyl) smashing acid «, dimethyl (third-butyl) ammonium (2,3,4,6- Tetrafluorobenzyl) acid M · N, N-dimethylbenzene (2,3,4,6-tetrafluorophenyl) lanate, (1, {1-diethylanilinium ( 2,3,4,6-tetrafluorophenyl) _acid, and!}, N-dimethyl-2,4,6-trimethylbenzylammonium (2,3,4,6-tetrafluoro Phenyl) boric acid "; dialkyl ammonium salts such as: di- (isopropyl) ammonium (pentafluorophenyl) sodium oleate • and di Ammonium cyclic (pentylbenzyl) nicotinate; three-substituted reticulum for example: triphenylphosphonium (pentafluorobenzyl) hexanoate, tris (o-tolyl) supplier (pentaphenyl)> ; Strontium oxalate • and tris (2,6-dimethylbenzyl) phosphorus (pentafluorophenyl) smashing acid Μ ·· di-substituted oxygen "for example: diphenyloxy europium (pentafluorophenyl) Borate · Di (o-methylbenzyl) oxygen anchor (penta-phenylbenzyl) borate, and bis (2,6-dimethylbenzyl) oxonium (pentafluorobenzyl) smashing acid silt; di-substituted Examples of IW: diphenyl & (pentafluorophenyl) lanolin acid · di (o-tolyl) is thin (pentafluorophenyl) sulnate • and bis (2,6-xylyl) is too Thin (pentafluorophenyl) bromide acid. Preferred ions are Ν * Ν-dimethylanilinium and tributylammonium. Another kind of ion-generating activated secondary catalyst includes the following formula: "Ion oxide and non-coordinating compatible deionized salt: This paper size is applicable to China National Standard (CNS) A4 specification (210X297mm) f Please read the matters needing attention on the back first 11 ^ 1 Write this page} Printed by the Ministry of Economic Affairs of the Ministry of Economic Affairs of the Beigong Consumer Cooperative Fifth, Invention Description (18) A7B7 Printed by the Zhongji Ministry of Economic Affairs of the Ministry of Economic Affairs Suggestions: 〇χβ ♦ is a ionic oxidant containing valence; e is 1.2 or 3: and Ad and d are as defined above. «Examples of zizi oxidants include Uerrocenium) · Nicotine-substituted androgenic, Ag * or Pb〃. A -_ 's best example is "An example is the anion defined above for a living auxiliary catalyst containing brucemeieric acid *. Special (pentafluorophenyl)« (acid. Another kind of ion-generating activated auxiliary contact The medium includes the carbene male ion represented by the following formula and the non-coordinating compatible male broodstock: © * A 'where: ○ is Ci-8a carbene male cockroach; and A- as defined above. Preferred carbene The anchor is a trimethylbenzyl kumquat ion and a triphenylmethyl anchor. Another type of auxiliary catalyst for generative activation includes silane male refractory and non-coordinating compatible anions. The following formula represents R3Si ( X *), * A- where: R is Ci-ie nicotine · S is 0 or 1, and X 'and A · are as defined above. The preferred catalyzed activation catalyst for the squalene male alligator is trimethylsilyl maleic Pentaoxyphenyl "acid, triethylsilyl, pentafluorophenyl, plutonium, and silver carp substituted adducts. Silane salts are shown in j.Cheai Soc. Please read first

"Face" 's attention to "Issues Re-I Binding" The paper size is applicable to the Chinese National Standard (CNS) Λ4 specifications (210X297 mm) 21 5. Invention description (19) A7B7

Chei.Conia., 1993, 383-384 and La Xinjiang bert, JB, et al., Organ〇Betallics, 1994, 13, 2430-2443 ° Certain enzymes, sulfur enzymes, silane enzymes and fatty and Luan (Pentafluorophenyl) Borane complexes are also effective catalyst activators and can be used in the present invention. Such auxiliary catalysts are shown in US-A-5,296,433. This «« solution technology is included in the support of "non-coordinating anions with anions" in the presence of solution under electrolysis conditions «chemical oxidation of gold huo complex. In this technology, the cocoon dissolving, supporting electrolyte and enzymatic dissociation potential are used to make the reaction process larger »It does not produce enzymatic dissociation products that promote the inactivation of the Jinyi complex catalyst. Especially when the solution is: under "solution conditions (usually 0 to ιοου temperature) can dissolve the branch» Enzymatic solution and is an inert liquid. " Emotional solvent 〃 is a solvent that will not be destroyed or oxidized under the conditions of the enzymatic hydrolysis reaction. Generally speaking, in view of the required «solution conditions, it is possible to use a Hong Kong agent and a supporting solution that are not affected by the use of electrolysis. Better dissolve _ Contains difluorobenzene (all isomers) · Dimethyl ethane (DME) and its mixture, please read first. The quasi-electrolytes containing anode and cathode (called working pole and counter pole respectively) are performed. The main materials of the 霣 池 are glass, plastic, ceramics and glass coated metal. The beaker is made of inert guide material, which means the guide material is not affected by the reaction mixture or reaction conditions. Platinum or palladium are better inert conductive materials. Usually ion-permeable membranes, such as fine glass frit, divide the pond into individual compartments: the working pole-pointing compartment and the counter-pole compartment. The working electrode is immersed in the reaction medium. • The reaction medium includes the gold complex to be activated. • The solvent supports the materials needed for the decomposition and any other conditioning or determination of the resulting complex. The counter electrode is immersed in the mixture of the solvent and the supporting solution. The paper standard is free to use the Chinese National Standard (CNS) A4 specification (210X297 mm) Description of the invention (20). The required voltage can be determined by calculation or calculation, or by using the reference "Such as the silver electrode is not buried in the pond, and the pond is buried in the test. The back pond« flow, that is When there is no need, the withdrawal of the flow will be settled when the solution exists. When the m flow is reduced from the expected value to the background value, the electrolysis is completed. In this way, it is easy to detect the complete conversion of the complex of gold and gold. Dissolution is a salt that includes bright ions and incompatible coordination anions A-. The best support is "Resolution is the corresponding formula: G * · A_'s formula: G * is not reactive towards the starting and the resulting complex The "Diaozi, and eight_definition are as before. The example of the cation G * includes up to 40 non-argon atoms of tetrahydrocarbyl substituted ammonium or progeny chicks. The preferred kuma ions are tetra-n-butylammonium- and tetraethylammonium- Seedlings Ο In the process of deactivation of the lotus root body and the activation of the compound of the present invention The chicks are sent to the counter-butterfly and A- is moved to the working electrode to become the anion of the resulting oxidation product. The solvent or the stabilizing ion that supports the decomposition of the photocatalyst is equal to the number of ft of the metal oxide complex formed by the electrical plug-in with the working electrode Molar amount. It is better to support the disintegration of each hydrocarbon group or perfluoroaryl group containing 1 to 10 carbons (perfluoroaryl group) to the salts of tetrahydrocarbyl bromide, especially tetra-n-butylammonium. (Pentafluorophenyl) benzoic acid. In preferred examples, disilazane, especially II (trimethylsilane), is compatible with non-coordinating deionized sources (such as the fourth dioxin of pentafluorophenylbenzyl sulfonate) Ammonium sulfonate) is included in the enzymolysis, so the in-situ production of silane anchors activates the auxiliary catalyst. The aforementioned activation technique and ion-generating auxiliary catalyst are also preferred to contain three (hydrocarbyl) aluminum or 1-4 carbons for each hydrocarbon group. Three (ye base) pinane compounds, oligomers; write this page)

、 TT • T- · The paper scale is applicable to China National Standard (CNS) A4 specification (210X297 mm) 23 A7 _B7_ V. Description of invention (21) or polymer aluminoxane compound, or each hydrocarbon group contains 1 to 4 The mixture of carbon tri (hydrocarbyl) aluminum compound and polymer into oligomer aluminoxane is used in combination. Ο The ear of the catalyst / cocatalyst used is preferably 1: 10,000 to 100: 1, more preferably 1: 5000 Up to 10: 1 · Best in the garden of 1: 10 to 1: 1. In the example of the present invention, the auxiliary catalyst can be used in combination with a tri (hydrocarbon group) aluminum compound or oligomer or polymer aluminoxane containing 1 to 10 carbons in each valent hydrocarbon group. Activated cocatalyst mixtures can also be used. These silver compounds can be used because of their advantageous ability to remove insoluble substances such as oxygen, water and aldehydes from the polymerization mixture. Preferred aluminum compounds include trialkyl aluminum compounds in which each alkyl group contains 2 to 6 carbons, in particular the alkyl group is methyl • ethyl, propyl • isopropyl • n-butyl • isobutyl, pentyl • Neopentyl or isopentyl, and methylaluminoxane * changed to methylaluminoxane (that is, modified methylaluminoxane by reaction with triisobutylaluminum) (ΜΜΑ0) and isobutylaluminum "alkyl. The molar ratio of Jinyi complex to aluminide is preferably from 1: 10,000 to 100: 1, more preferably from 1: 1000 to 10: 1, and best from 1: 500 to 1: 1. The best activated secondary catalysts include strong Lewis acid and aluminoxane * especially Thai (pentafluorophenyl) sulfane and methylaluminoxane, modified methylaluminoxane or diisobutylaluminoxane. Printed by the Industrial and Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs «. Generally speaking, the catalyst can be used at a temperature of -loot! To 300C in the garden when the solvent is combined with the gold employment complex and the auxiliary catalyst or activated gold complex preparation. The catalyst can be prepared separately by combining the individual components before use, or prepared in situ by combining the individual components in the presence of the monomer to be polymerized. Because the catalyst prepared by this method has a high effective character, it is better to generate the catalyst on site. The catalyst components are sensitive to water and gas and must be processed under an inert atmosphere such as nitrogen, argon or helium. This paper scale is applicable to the Chinese National Standard (CNS) A4 grid (210X297mm) 24 A7 B7 5. Invention description (22) and transfer . Generally speaking, the polymerization can be completed under the Ziegler Natta or Kaninsky-Sinn type polymerization reaction conditions well known in the prior art. That is, the temperature is 0-250X3 and the pressure is from atmospheric pressure to UJOO atmospheric pressure (0.1 to 100MPa). Catalyst used for polymerization: The molar ratio of the polymerizable compound is preferably l〇-ia: 1 to 10 · 1: 1: 1, more preferably l〇-ia: 1 to l〇-s: 1. A suitable solvent for the polymerization of the bond segment of the ene smoke polymer is a non-coordinating inert liquid *. Preferably, the vinylidene aromatic polymer is a solvent in which the segment can be dissolved. Examples include ring systems and aliphatic hydrocarbons such as cyclohexane * cycloheptane, methylcyclohexane, methylcycloheptane and mixtures thereof; perfluorinated hydrocarbons such as perfluorinated C4-iO alkanes, aromatic Group and alkyl substituted aromatic compounds such as benzene, toluene • xylene and mixtures thereof; and mixtures of the aforementioned solvents. The preferred procedure is to initiate the formation of a vinyl vinyl monovinylidene aromatic polymer bond segment through the use of a lithium alkyl group, to isolate any «by-products, and to separate the resulting polymer solution before or during the polymerization of the vinyl polymer bond segment. Add to Ziegler Natta reaction mixture. Another example: • It is also possible to recover and separate the monovinylidene aromatic polymer bond segment from the reaction mixture used for preparation. • It is later dissolved again and added to the olefin polymer segment to prepare a spare reaction mixture. The conditions of the deionization polymerization reaction are particularly special. The polymerization reactors used in this monovinylidene aromatic polymer segment are previously known and can be used to prepare monovinylidene aromatic homopolymers or vinyl aromatic monomers. Conditions of block copolymers of ene monomers. The bond segment of the monovinylidene aromatic polymer is preferably a block vinylidene aromatic homopolymer or a vinyl aromatic army tt having a vinyl unsaturation of □ as a block copolymer of co-rolled diene monomer. If the monovinylidene aromatic polymer is a block-based co-paper, the Chinese rubbing rate is applicable (CNS Μ4 specification (210Χ297mm) (please read the note Ϋ on the back first and then; 1 pack-fill this page ) Printed and printed by Beigong Consumer Cooperative of Central Kneading Bureau of Ministry of Economy and Economics 25 516912 A7 B7 V. Description of the invention (23) The polymer is expected to be prepared by sequentially polymerizing the active polymer anion. In this way, in addition to monovinylidene aromatic monomer «Externally, the monovinylidene aromatic polymer segment contains a diene polymer block. The preferred diene monomer is co-diene, preferably 1,3-butadiene, isoprene or mixtures thereof The monovinylidene aromatic monomer is a compound of the formula: R2

C = CH 2 (Please read the back. Note $ item before filling out this page) Outfit. Printed by the Ministry of Economic Affairs in the squat shoulder shoulder work consumer cooperative. Here η is an integer from 0 to 3. IU contains up to 5 The alkyl group of the carbon atom and R2 are hydrogen or methyl. The preferred monovinylidene aromatic monomer is styrene * vinyl toluene (all isomers * single or mixed) α-methylstyrene and mixtures thereof. Very good alkenyl aromatic monohydrazines are styrene and a mixture of styrene and (X-methyl stupid ethylene. Preferred monovinylidene aromatic polymer segments contain 1 to 10 OdwU army vinylidene aromatic tan before functionalization ». The purity of monomers and solvents needs to be carefully controlled during the polymerization of Yindiaozi. It can be used for purification by single residue or solvent contact with molecular sieves, or by distillation or degassing. Reactive before the addition of lithium alkyl initiator Impurities can also be removed by " blank #, that is, the * grade reacts with the contaminants and removes the contaminants by adding a small amount of lithium hydrocarbon groups, but it is not enough to initiate the polymerization reaction of the purified military body. The preferred lithium alkyl compound is alkane The group contains 2 to 6 sulfon atoms, especially the second-butyl lithium. The single addition can be carried out before or after the initiation of the polymerization. The polymerization reaction can be carried out for a sufficient time to achieve the desired product properties and conversion. When the reaction time is 10 minutes to 3 hours • preferably 20 minutes to shovel to 2 hours. The standard paper size is applicable to the Chinese National Standard (CNS) A4 specifications (210X297 mm) 26 Ministry of Economic Affairs Central Bureau of Standardization Shellfish A7 B7 printed by consumer cooperatives Description (24) The vinyl termination or functionalization of the bond segment of the monovinylidene aromatic polymer can be accomplished by any known technique. Preferably, the activated monovinylidene aromatic polymer prepared by the aforementioned sickle polymerization technique The silver carp section is terminated by adding allyl gas to the reaction mixture and then separating the lithium oxide by-products. The preferred reaction mixture is passed to the second reactor for the Ziegler Natta polymerization reaction conditions to produce the polymer reaction product The operation is carried out. The ratio of the two-stage polymer bond segments can be reacted in the range of 1 to 99 ¥ 1%. The preferred vinylene polymer bond segments include 1 to 50wtX «multi-component copolymers and have a molecular weight (Mw) From 5,000 to 2,000,000. The molecule 1 of the multi-component co-polymer of the bond segment can be changed from 10,000 to 4,000,000, preferably from 15,000 to 100,000. The industry understands that the invention shown here can be used in the past. In particular, if any of the ingredients are not present, the following examples are provided for further illustration but are not to be considered as limiting their scope. Unless stated to the contrary, all parts and percentages of apricots are expressed on a weight basis.

nJSLL (a) Preparation of alkenyl polystyrene (APS). 13kg cyclohexane was locked into the 20-liter stainless steel reactor. The reactor was heated to 50t !, and a small ft polystyrene vinyl lithium solution (12g, 0.12M) was added in cyclohexane until it was removed until the visible light absorbance was measured at 400η. Then 772 g of 0.16 M second-para-lithium lithium in cyclohexane solution was added to the reactor, followed by 1128 g of alumina to purify styrene. The temperature of the anti-E device is maintained at 36-421, while consuming all the stupid vinyl monomer (60 minutes). The reaction mixture was cooled to 31¾ by adding 3 9g of allyl chloride and dissolved in cyclohexanol. The paper size is suitable for China National Standard (CNS) A4 specification (210X297mm) (please read the precautions on the back and fill in this page) -Subscribe to 27 A7 _'_ B7_ V. Invention description (25) The reaction mixture (both components have been ventilated with an aerated aluminum column) to eliminate active polystyrene deionization. The polymer solution M and the like are washed once with accumulated water and dissolved under reduced pressure at 100C for 8 to 3 hours to remove. The remaining polymer (shown as a-1) is a solitary solid. The size exclusion chromatography (SEC) measures the molecular weight (Mw) of the allyl end group product to 5600 g / Bol (polystyrene standard). A material of about 15 wtX produces an unfunctionalized coupling product with a molecular weight twice that of the allyl end product. Additional APS samples were prepared using process conditions generally as described above. The resulting polymer had a molecular weight (Mw) of 560Qg / mol (a-2 is shown as a-2) and 5783 g / nol (a-3 is shown as a-3). The content of unfunctionalized complex product in all samples is about 153 !. (b) Manufacture APS solution (350g polymer / 1500 · 1 toluene) in the dry suspect box. The solution is generally activated alumina (A-2 · available from La Roche Chemical Company). In a 2 liter Barr reactor, 210 g of pure nail stupid and a solution of 89 g APS in APS were locked. In the reactor, octene (280 g), hydrogen △ PHa = 0.2 MPa, (30 psi), and 4.3 MPa, (500 psi) ethylene were read. The mixture was heated to 80C and N- (tertiary-butylpyridylamino) (77 s-tetramethylcyclopentadienyl) dimethylsilane titanium dimethyl and pentafluorophenylalkane (molby 1 : 1) Catalyst mixture Μ Inject multiple times to add a total of 4WB〇l (MTi mainly) ° The mixture reacts until the uptake of ethylene is stopped, and then discharged into the nitrogen container. The solution was poured into a mixture of approximately 2 L of acetone and 0.5 L of formazan, at which time the polymer segment precipitated. "Polymer" filtration and recovery and the evaporation of 130 g of reduced evaporation leaving 41 g of the multi-component polymer product of the key segment. The polymer is dissolved in toluene again, and the antioxidant Irganox 1010 is added from Ciba-Gigy). The size of this paper is applicable to the Chinese National Standard (CNS) A4 (210X297 mm). S169i2 _B7_ printed by the cooperative. V. Description of the invention (26) Isopropylase was used to re-enter the material. Polymer size exclusion analysis (SEC) analysis was found to contain less than 1 wtX unreacted polystyrene macromonomer. The foregoing experimental conditions were substantially repeated, but changed as described in Table 1. The results of Examples 1 to 4 are shown in Table 1. This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) 29 A7 ____ B7 V. Description of the invention (27) Table 1 Example H2 C, H «# (kPa) MPa Octane g APS g APS type catalyst uaiol Yield 8 1 200 3.4 280 89 a-1 4 41 2 70 1.0 80 85 a-2 27 66 3 0 1.0 40 80 a-3 27 50 4 0 1.0 70 175 a-4 46 47 The results of the analysis of the content of Landing Army millet by NMR are shown in Table 2. Table 2 Examples of ethylene content, octene content, styrene content scale (96) (%) (96) 1 53 42 5 2 31 54 15 3 35 47 18 4 25 41 34 Printed copolymerization of Beigong Consumer Cooperative, Central Bureau of Economic Development, Ministry of Economic Affairs The physical shape should be the lotus-transmission 9-submicroscope using a Philips CM〃 / STEH 霣 子 microscope Landing. The multi-component polymer compression molded board segment is obtained using Reichert-Ju_ng FC4E ultraaicrotoae to cold travel technology. The MRuO «steam dyeing of this segment is 5-10 minutes. M 320 to 1290kX magnified photography. The image shows a polystyrene field bundle with a diameter of 13 to 15nn, indicating that the polymer has a phase-separated morphology. The mechanical properties of the polymer are obtained from the round section of the plastic sample. The data is based on the use of Rheonetric mechanical spectrometer / dynamic light stripper RMS 800 / The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 30 516912 V. Description of the invention (28) A7 B7 RDS-II Badger got. Carry out the perfusion scan and the badger to obtain the amount of the game, the loss of the game and the temperature function in TanS of 1 second μ. A representative DMS scan is shown in the first circle, which compares the commercially available hydrogenated styrene block copolymer (kraton ™ G-1650) with the bond-component multicomponent polymer of Example 4. The DMS of the multi-component polymer of the segment shows the low and high glass transition degree of the block copolymer, indicating the presence of individual polystyrene phases and polyolefin phases. "Please be aware of the precautions first.

Printed by the Ministry of Economic Affairs of the Central Bureau of Industry and Consumer Cooperatives «. This paper scale is applicable to China National Standards (CNS > A4 specification (210X297 mm) 31

Claims (1)

316912 A8 B8 C8 D8 Six 'Application patent scope No. 85106717 Patent Application Amendments to the Patent Scope Amendment Date: July 1986 1. A bond segment multi-component copolymer, which includes: Α) At least one olefin polymer segment from 1 to 99 wU, including A solid linear ethylene homopolymer or a substantially linear or branched ethylene copolymer and at least one comonomer selected from C3-2Da-olefin-based monomers, and B) at least one polystyrene bond from 99 to 1 wt% Segment, the olefin polymer segment and polystyrene polymer segment are copolymerized with ethylene or monoethylene and at least one C3-2〇a-olefin via the terminal vinyl functional group of a styrene macromonomer with an allyl end group The mixture of the compounds is carried out in the presence of a zombie system. Copolymerization is carried out. The zombie system contains a residual complex corresponding to the following chemical formula: Z- (please read the fate note f first Please fill in this item X) Cp * -Μ (Χ ") 2 Printed by the Ministry of Economic Affairs Central Bureau of Industry and Consumer Cooperatives IL where: ~~ M is chromium or titanium; Cp " is cyclopentadienyl; or selected from indenyl , Fluorenyl and hydrogenated or partially hydrogenated derivatives; or one of the aforementioned groups containing one or more More than 20 hydrocarbon groups partially substituted; Z is SiR-a, (iR * 2, SiR * 3SiRe2, CRVCR-2, CR ** = CR ", CR " 2SiR * 2, or GeRMs; where: R " in each At the time of occurrence, they are hydrogen, hydrocarbyl, or halohydrocarbon. This paper size is applicable to China National Bran Standard (CNS) A4 specification (210X297 mm) 3 Gong 69ί2 Α8 Β8 C8 D8 Beigong Consumer Cooperatives of the Central Bureau of the Ministry of Economic Affairs Print the patent application base, R · contains up to 20 non-hydrogen atoms, Y contains nitrogen or phosphorus corresponding to the formula -H (R "") or -P (R "") _; where: R · ' '' Is a Ct-u hydrocarbon group; and X "is a halogen atom at each occurrence * a hydrocarbon group containing up to 20% nitrate or a hydrocarbon gas group containing up to 20% sulfonate * or two fex" groups together are cr-bonded or 7Ϊ Bonding (: 4-28 conjugated diene, and an activated auxiliary catalyst. 2. The multi-component copolymer of the segment as claimed in item 1 of the patent application, wherein the activated auxiliary catalyst used in its preparation is three (Pentafluorophenyl) borane. 3. A method of generating segmented multi-component copolymers includes: 1) Under anionic polymerization conditions, polymerize styrene to form in a hydrocarbon solution Activated styrene polymer, 2) A vinyl styrene polymer hybrid is formed by the reaction of the activated styrene polymer bond segment with allyl vapor, and 3) In the presence of vinyl-terminated styrene polymer • Polymerize ethylene or a mixture of ethylene and at least one C3-2D〇t-olefin comonomer at a temperature from 0 ° C to 250t and a pressure from 0.1 to 100 MPa. 4. The method as claimed in item 3 of the patent application, in which the olefin polymer ring segment generated in step 3) is generated at a high monomer conversion rate in a tandem solution method operating under steady-state conditions, including low ethylene content The 10% halo ratio and the polymerization temperature in the reactor contents are 50 ° C to 150t. The size of this paper is easy to use Chinese Linjia rubbing rate (CNS > A4 specification (210X297mm) ----------- ^ 朵 — (please read the note $ item on the back first and then fill in this to buy) Order