RU2018125874A - Способ получения полиуретановых пен - Google Patents
Способ получения полиуретановых пен Download PDFInfo
- Publication number
- RU2018125874A RU2018125874A RU2018125874A RU2018125874A RU2018125874A RU 2018125874 A RU2018125874 A RU 2018125874A RU 2018125874 A RU2018125874 A RU 2018125874A RU 2018125874 A RU2018125874 A RU 2018125874A RU 2018125874 A RU2018125874 A RU 2018125874A
- Authority
- RU
- Russia
- Prior art keywords
- polyether polyol
- proportion
- propylene oxide
- polyurethane foam
- hydroxyl groups
- Prior art date
Links
- 229920005830 Polyurethane Foam Polymers 0.000 title claims 2
- 239000011496 polyurethane foam Substances 0.000 title claims 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000004721 Polyphenylene oxide Substances 0.000 claims 9
- 229920000570 polyether Polymers 0.000 claims 9
- 229920005862 polyol Polymers 0.000 claims 9
- 150000003077 polyols Chemical class 0.000 claims 9
- 238000000034 method Methods 0.000 claims 8
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 3
- 229920000728 polyester Polymers 0.000 claims 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 2
- 125000002947 alkylene group Chemical group 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 239000006260 foam Substances 0.000 claims 1
- 238000005187 foaming Methods 0.000 claims 1
- 238000001879 gelation Methods 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229920001228 polyisocyanate Polymers 0.000 claims 1
- 239000005056 polyisocyanate Substances 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/485—Polyethers containing oxyethylene units and other oxyalkylene units containing mixed oxyethylene-oxypropylene or oxyethylene-higher oxyalkylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4816—Two or more polyethers of different physical or chemical nature mixtures of two or more polyetherpolyols having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4845—Polyethers containing oxyethylene units and other oxyalkylene units containing oxypropylene or higher oxyalkylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
- C08G18/7621—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring being toluene diisocyanate including isomer mixtures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Claims (8)
1. Способ получения полиуретановой пены, имеющей эластичность по меньшей мере 50%, включающий реакцию: (i) первого полиэфирполиола, имеющего полиэфирные цепи, содержащие долю этиленоксида не более 20%, долю первичных гидроксильных групп не более, чем 25%; (ii) второго полиэфирполиола, имеющего полиэфирные цепи, содержащие долю этиленоксида по меньшей мере 50%, и (iii) одного или более ароматических полиизоцианатов в присутствии одного или более катализаторов гелеобразования или вспенивания.
2. Способ по п.1, отличающийся тем, что первый полиэфирполиол содержит долю пропиленоксида по меньшей мере 80%.
3. Способ по п.1 или 2, отличающийся тем, что первый полиэфирполиол получают полимеризацией с открытием цикла алкиленоксида в гидроксилсодержащий начальный материал, в присутствии комбинированного металлического цианидного комплексного катализатора.
4. Способ по любому одному из пп.1-3, отличающийся тем, что второй полиэфирполиол содержит долю пропиленоксида по меньшей мере 65%.
5. Способ по любому одному из пп.1-4, отличающийся тем, что доля первичных гидроксильных групп во втором полиэфирполиоле не менее, чем 20%.
6. Способ по любому одному из пп.1-5, отличающийся тем, что остаток доли алкиленоксидов в полиэфирной цепи второго полиэфирполиола получен из пропиленоксида.
7. Способ по любому одному из пп.1-6, отличающийся тем, что массовое процентное отношение первого полиэфирполиола ко второму полиэфирполиолу составляет по меньшей мере 18:1.
8. Пена, получаемая способом по любому предшествующему пункту.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IN6795/CHE/2015 | 2015-12-21 | ||
| IN6795CH2015 | 2015-12-21 | ||
| PCT/EP2016/081785 WO2017108711A1 (en) | 2015-12-21 | 2016-12-19 | Process for the production of polyurethane foams |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2018125874A true RU2018125874A (ru) | 2020-01-24 |
| RU2018125874A3 RU2018125874A3 (ru) | 2020-04-23 |
| RU2734761C2 RU2734761C2 (ru) | 2020-10-23 |
Family
ID=57755271
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2018125874A RU2734761C2 (ru) | 2015-12-21 | 2016-12-19 | Способ получения полиуретановых пен |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US11814467B2 (ru) |
| EP (1) | EP3394137B2 (ru) |
| KR (1) | KR20180097552A (ru) |
| CN (1) | CN108368230B (ru) |
| BR (1) | BR112018012507B1 (ru) |
| LT (1) | LT3394137T (ru) |
| PL (1) | PL3394137T5 (ru) |
| PT (1) | PT3394137T (ru) |
| RU (1) | RU2734761C2 (ru) |
| SG (2) | SG10202005842QA (ru) |
| WO (1) | WO2017108711A1 (ru) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111333804A (zh) * | 2020-04-13 | 2020-06-26 | 江苏德励达新材料有限公司 | 一种制备亲肤性聚氨酯凝胶的聚氨酯体系 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5596059A (en) | 1995-07-26 | 1997-01-21 | Arco Chemical Technology, L.P. | Polyether polyols suitable for mflexible polyurethane foam prepared by co-initiation of aqueous solutions of solid polyhydroxyl initiators |
| US5605939A (en) | 1996-01-26 | 1997-02-25 | Arco Chemical Technology, L.P. | Poly(oxypropylene/oxyethylene) random polyols useful in preparing flexible high resilience foam with reduced tendencies toward shrinkage and foam prepared therewith |
| DE19649829A1 (de) * | 1996-12-02 | 1998-06-04 | Bayer Ag | Weichelastische Polyurethanschaumstoffe und ein Verfahren zu deren Herstellung |
| DE19649828A1 (de) | 1996-12-02 | 1998-06-04 | Bayer Ag | Verfahren zur diskontinuierlichen Herstellung von weichelastischen, offenzelligen Polyurethanschaumstoffen |
| WO1998042763A1 (en) | 1997-03-25 | 1998-10-01 | Huntsman Ici Chemicals Llc | Process for preparing flexible polyurethane foam |
| US6008263A (en) * | 1998-04-03 | 1999-12-28 | Lyondell Chemical Worldwide, Inc. | Molded and slab polyurethane foam prepared from double metal cyanide complex-catalyzed polyoxyalkylene polyols and polyols suitable for the preparation thereof |
| US6063897A (en) | 1998-05-05 | 2000-05-16 | Arco Chemical Technology, L.P. | Acid-treated double metal cyanide complex catalysts |
| DE60120390T2 (de) | 2000-04-14 | 2007-05-16 | Asahi Glass Co., Ltd. | Verfahren zur herstellung von flexiblem polyurethanschaum |
| EP1178061A1 (en) | 2000-08-01 | 2002-02-06 | Huntsman International Llc | Process for preparing a polyurethane material |
| EP1589071B1 (en) | 2003-01-28 | 2012-11-14 | Asahi Glass Company, Limited | Polyether polyol composition and use thereof |
| US6855742B2 (en) * | 2003-01-28 | 2005-02-15 | Bayer Antwerp, N.V. | Agents for reducing the force-to-crush (FTC) of high support flexible foams |
| DE102004031836A1 (de) | 2004-06-30 | 2006-01-19 | Basf Ag | Verfahren zur Herstellung von Polyetheralkoholen |
| DE102004047406A1 (de) * | 2004-09-28 | 2006-03-30 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Weichschaumstoffen |
| DE102004051048A1 (de) | 2004-10-19 | 2006-04-20 | Bayer Materialscience Ag | Weichelastische Schaumstoffe geringer Rohdichten und Stauchhärte |
| CN101497691A (zh) * | 2008-12-31 | 2009-08-05 | 青岛科技大学 | 一种高活性端羟基聚环氧氯丙烷醚多元醇及其制备方法 |
| PL2513182T3 (pl) | 2009-12-17 | 2019-06-28 | Dow Global Technologies Llc | Pianka poliuretanowa z miękkim chwytem powierzchni |
| CN103228690B (zh) | 2010-09-29 | 2016-03-09 | 陶氏环球技术有限责任公司 | 制备高气流和低压缩变定粘弹性聚氨酯泡沫体的方法 |
| MX2015006236A (es) * | 2012-11-23 | 2015-08-14 | Bayer Materialscience Ag | Procedimiento de produccion de espumas de pu moldeadas flexibles. |
| EP3356442B1 (en) * | 2015-09-29 | 2020-04-08 | Basf Se | High-resiliency polyurethane foam |
| WO2017062150A1 (en) * | 2015-10-08 | 2017-04-13 | Dow Global Technologies Llc | High resiliency polyurethane foams made with high functionality, high equivalent weight polyols with mainly secondary hydroxyl groups |
-
2016
- 2016-12-19 EP EP16822969.8A patent/EP3394137B2/en active Active
- 2016-12-19 SG SG10202005842QA patent/SG10202005842QA/en unknown
- 2016-12-19 PL PL16822969.8T patent/PL3394137T5/pl unknown
- 2016-12-19 WO PCT/EP2016/081785 patent/WO2017108711A1/en active Application Filing
- 2016-12-19 KR KR1020187017189A patent/KR20180097552A/ko not_active Application Discontinuation
- 2016-12-19 BR BR112018012507-5A patent/BR112018012507B1/pt active IP Right Grant
- 2016-12-19 SG SG11201804524TA patent/SG11201804524TA/en unknown
- 2016-12-19 LT LTEP16822969.8T patent/LT3394137T/lt unknown
- 2016-12-19 CN CN201680074639.1A patent/CN108368230B/zh active Active
- 2016-12-19 US US16/063,952 patent/US11814467B2/en active Active
- 2016-12-19 RU RU2018125874A patent/RU2734761C2/ru active
- 2016-12-19 PT PT168229698T patent/PT3394137T/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR112018012507A2 (pt) | 2018-12-11 |
| EP3394137B2 (en) | 2024-03-20 |
| LT3394137T (lt) | 2021-06-10 |
| BR112018012507B1 (pt) | 2022-03-22 |
| PL3394137T3 (pl) | 2021-09-20 |
| US20200270391A1 (en) | 2020-08-27 |
| WO2017108711A1 (en) | 2017-06-29 |
| KR20180097552A (ko) | 2018-08-31 |
| RU2018125874A3 (ru) | 2020-04-23 |
| US11814467B2 (en) | 2023-11-14 |
| PL3394137T5 (pl) | 2024-05-13 |
| EP3394137A1 (en) | 2018-10-31 |
| SG10202005842QA (en) | 2020-07-29 |
| PT3394137T (pt) | 2021-06-02 |
| SG11201804524TA (en) | 2018-07-30 |
| EP3394137B1 (en) | 2021-03-31 |
| RU2734761C2 (ru) | 2020-10-23 |
| CN108368230A (zh) | 2018-08-03 |
| CN108368230B (zh) | 2021-08-20 |
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