KR900018190A - 저비점 발포제의 존재하에서 우레탄 및 이소시아누레이트 발포체의 제조방법 - Google Patents
저비점 발포제의 존재하에서 우레탄 및 이소시아누레이트 발포체의 제조방법 Download PDFInfo
- Publication number
- KR900018190A KR900018190A KR1019900006514A KR900006514A KR900018190A KR 900018190 A KR900018190 A KR 900018190A KR 1019900006514 A KR1019900006514 A KR 1019900006514A KR 900006514 A KR900006514 A KR 900006514A KR 900018190 A KR900018190 A KR 900018190A
- Authority
- KR
- South Korea
- Prior art keywords
- boiling point
- compound
- halocarbon
- blowing agent
- active hydrogen
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/147—Halogen containing compounds containing carbon and halogen atoms only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 유기 폴리이소시아네이트와 활성 수소-함유 화합물을 물 및 발포제의 존재하에서 접촉 및 반응시킴을 포함하여 강성 독립기포 폴리시아네이트계 발포체를 제조함에 있어서, 발포제가 비점이 222K 내지 272K인 1개 이상의 할로카본 화합물을 포함하며 비점이 273K이상인 유기 화합물은 거의 함유하지 않음을 특징으로 하는 방법.
- 제1항에 있어서 할로카본 화합물의 비점이 235K 내지 272K인 방법.
- 제1항에 있어서, 할로카본이 클로로카본, 브로모카본, 플루오로카본, 클로로플루오로카본 또는 브로모플루오로카본 및 메탄, 에탄 프로판, 에틸렌, 프로필렌, 사이클로알칸 또는 이의 혼합물의 첨가물인 방법.
- 제1항 내지 3항중 어느 한 항에 있어서, 할로카본 화합물이 클로로플루오로에탄, 플루오로에탄 또는 이의 혼합물인 방법.
- 제4항에 있어서, 클로로플루오로에탄이 클로로펜타플루오로에탄(R-115), 클로로테트라플루오로에탄(R-124 또는 이성체 R-124a)또는 클로로디플루오로에탄(R-142b)인 방법.
- 제4항에 있어서, 플루오로에탄이 테트라플루오로 에탄(R-134 또는 이성체 R-134a), 트리플루오로에탄(R-143), 디플루올에탄(R-152a) 또는 플루오로에탄(R-161)인 방법.
- 제4항에 있어서, 할로카본 화합물이 클로로 디플루오로에탄(R-142b) 또는 테트라플루오로에탄(R-134) 또는 이성체 (R-134a)인 방법.
- 제1항에 내지 7항중 어느 한 항에 있어서, 물이 존재하는 활성 수소-함유 화합물의 총 중량을 기준하여 0.5 내지 10.0중량%로 제공되는 방법.
- (a)당량이 50 내지 700인 적어도 1개의 활성 수소-함유 화합물, 및 (b)존재하는 성분(a) 및 (b)의 총중량을 기준하여 1내지 25중량%의 발포제를 포함하는 이소시아네이트 반응성 조성물에 있어서, 발포제가 비점이 222K 내지 272K인 1개 이상의 할로카본 화합물을 포함하며 비점이 273K이상인 유기 화합물은 거의 함유하지 않음을 특징으로하는 조성물.
- 유기 폴리이소시아네이트와 활성 수소-함유 화합물을 물 및 발포제의 종재항서 접촉 및 반응시켜 제조한 강성, 독립기포 폴리이소시아네이트계 발포체에 있어서, 생성된 발포체가 그의 기포내에 (a)(a) 및 (b)의 총 몰을 기준하여 비점이 222K 내지 272K 인 적어도 1개의 유기 화합물 10내지 75몰%, 및(b)(a) 및 (b)의 총몰을 기준하여 이산화탄소 25내지 90몰%를 포함하는 가스상 혼합물을 함유함을 특징으로 하는 발포체.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/350,174 US4972003A (en) | 1989-05-10 | 1989-05-10 | Foaming system for rigid urethane and isocyanurate foams |
US350.174 | 1989-05-10 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR900018190A true KR900018190A (ko) | 1990-12-20 |
KR0155948B1 KR0155948B1 (ko) | 1998-12-01 |
Family
ID=23375523
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019900006514A KR0155948B1 (ko) | 1989-05-10 | 1990-05-09 | 저비점 발포제의 존재하에서 우레탄 및 이소시아누레이트 발포체의 제조방법 |
Country Status (18)
Country | Link |
---|---|
US (1) | US4972003A (ko) |
EP (1) | EP0398148B1 (ko) |
JP (2) | JPH037738A (ko) |
KR (1) | KR0155948B1 (ko) |
AR (1) | AR244726A1 (ko) |
AT (1) | ATE164608T1 (ko) |
AU (1) | AU622023B2 (ko) |
BR (1) | BR9002194A (ko) |
CA (1) | CA2016328C (ko) |
DD (1) | DD297980A5 (ko) |
DE (1) | DE69032188T2 (ko) |
DK (1) | DK0398148T3 (ko) |
ES (1) | ES2113850T3 (ko) |
GR (1) | GR3026714T3 (ko) |
MX (1) | MX166373B (ko) |
NO (1) | NO179178C (ko) |
NZ (1) | NZ233595A (ko) |
TW (1) | TW203620B (ko) |
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DE3903336A1 (de) * | 1989-02-04 | 1990-08-09 | Bayer Ag | Verwendung von c(pfeil abwaerts)3(pfeil abwaerts)- bis c(pfeil abwaerts)5(pfeil abwaerts)-polyfluoralkanen als treibgase |
GB8919675D0 (en) * | 1989-08-31 | 1989-10-11 | Ici Plc | Polymeric foams |
DE59010682D1 (de) * | 1989-12-12 | 1997-04-24 | Solvay | Verfahren zur Herstellung von Schaumstoffen mit Hilfe von Fluoralkanen |
US5516811A (en) * | 1990-03-23 | 1996-05-14 | E. I. Du Pont De Nemours And Company | Polymer foams containing blocking agents |
ES2080299T5 (es) * | 1990-03-23 | 2001-02-01 | Du Pont | Espumas polimericas que contienen agentes bloqueantes. |
US5912279A (en) * | 1990-03-23 | 1999-06-15 | E. I. Du Pont De Nemours And Company | Polymer foams containing blocking agents |
US6121337A (en) * | 1990-03-23 | 2000-09-19 | E. I. Du Pont De Nemours And Company | Compositions containing 1,1,2,2-tetrafluoroethane (HFC-134) for closed-cell polymer foam production |
WO1991014724A2 (en) * | 1990-03-23 | 1991-10-03 | E.I. Du Pont De Nemours And Company | Polymer foams containing gas barrier resins |
US5262077A (en) * | 1990-04-25 | 1993-11-16 | E. I. Du Pont De Nemours And Company | Halocarbon blends |
CA2079776A1 (en) * | 1990-04-25 | 1991-10-26 | Donald B. Bivens | Halocarbon blends |
JP3030106B2 (ja) * | 1991-02-22 | 2000-04-10 | 三洋電機株式会社 | 低沸点発泡剤のミキシング装置 |
US5264464A (en) * | 1991-04-29 | 1993-11-23 | Basf Corporation | On-site generation of polyurethane foam using an HCFC as a sole blowing agent |
US5164419A (en) * | 1991-05-20 | 1992-11-17 | E. I. Du Pont De Nemours And Company | Blowing agent and process for preparing polyurethane foam |
US5093377A (en) * | 1991-08-19 | 1992-03-03 | E. I. Du Pont De Nemours And Company | Blowing agent and process for preparing polyurethane foam |
US5112878A (en) * | 1991-09-23 | 1992-05-12 | Olin Corporation | Catalysts for extending the shelf life of formulations for producing rigid polyurethane foams |
JPH05306880A (ja) * | 1992-04-10 | 1993-11-19 | Sanyo Electric Co Ltd | 硬質ポリウレタンフォームを使用した断熱箱体 |
SE470464B (sv) * | 1992-09-10 | 1994-04-18 | Electrolux Res & Innovation | Isolering för kyl- eller frysskåp |
WO1994011460A1 (en) * | 1992-11-19 | 1994-05-26 | E.I. Du Pont De Nemours And Company | Refrigerant compositions including 1,1,2-trifluoroethane |
BE1006443A3 (fr) * | 1992-12-23 | 1994-08-30 | Solvay | Procede de preparation d'un materiau polymerique cellulaire et premelanges utilisables pour la preparation de ce materiau. |
AU5814894A (en) * | 1992-12-23 | 1994-07-19 | Solvay (Societe Anonyme) | Mixtures useful for preparing a cellular polymeric material |
CA2107274C (en) * | 1992-12-31 | 1998-11-03 | Valeri L. Valoppi | 1,1,1,2-tetrafluoroethane as a blowing agent in integral skin polyurethane shoe soles |
US5539008A (en) * | 1993-12-29 | 1996-07-23 | Minnesota Mining And Manufacturing Company | Foamable composition containing unsaturated perfluorochemical blowing agent |
US5409961A (en) * | 1994-07-08 | 1995-04-25 | Basf Corporation | Rigid closed cell polyisocyanate based foams for use as positive flotation materials in watercraft |
US5488072A (en) * | 1995-02-06 | 1996-01-30 | Basf Corporation | Rigid closed cell polyisocyanate based foams for use as positive flotation materials in watercraft |
US5470891A (en) * | 1995-04-10 | 1995-11-28 | Basf Corporation | Dimensionally stable closed cell rigid polyisocyanate based foam prepared from a froth foaming mixture |
US5840212A (en) * | 1996-10-23 | 1998-11-24 | Bayer Corporation | Rigid foams with improved insulation properties and a process for the production of such foams |
EP0882760B1 (en) * | 1997-06-03 | 2003-11-05 | Asahi Glass Company Ltd. | Method for producing foamed synthetic resin |
JP2002524630A (ja) | 1998-09-10 | 2002-08-06 | ザ ダウ ケミカル カンパニー | 水により発泡した硬質ポリウレタンフォームを製造するために有用なポリオール |
US5958992A (en) * | 1998-11-24 | 1999-09-28 | Elf Atochem North America, Inc. | Blowing agent blends |
US6136877A (en) * | 1999-03-26 | 2000-10-24 | Elf Atochem North America, Inc. | 142b/124 blowing agent blends |
US6117917A (en) * | 1999-04-12 | 2000-09-12 | Elf Atochem North America, Inc. | Blowing agent blends and use thereof |
US6262136B1 (en) | 1999-05-26 | 2001-07-17 | Bayer Corporation | Storage stable foam-forming system |
US20040126564A1 (en) * | 2000-11-15 | 2004-07-01 | Atlas Roofing Corporation | Thermosetting plastic foams and methods of production thereof using adhesion additives |
US6866923B2 (en) * | 2000-11-15 | 2005-03-15 | Atlas Roofing Corporation | Thermosetting plastic foams and methods of production thereof using adhesion additives |
US6534556B2 (en) | 2001-02-20 | 2003-03-18 | Basf Corporation | Sprayable autofrothing polyisocyanate foam and delivery system |
US6753357B2 (en) * | 2001-12-18 | 2004-06-22 | Foam Supplies, Inc. | Rigid foam compositions and method employing methyl formate as a blowing agent |
JP5286953B2 (ja) * | 2002-01-16 | 2013-09-11 | 旭硝子株式会社 | 硬質ポリウレタンフォームの製造方法 |
US20030213189A1 (en) * | 2002-05-16 | 2003-11-20 | Goldman Arthur S. | Thermoplastic polymer extrusion bending |
MX2007001331A (es) * | 2004-08-04 | 2008-03-11 | Foam Supplies Inc | Variacion de la reactividad y degradacion del catalizador en espuma de poliuretano. |
US20060052468A1 (en) * | 2004-09-08 | 2006-03-09 | Chris Janzen | Resin composition for use in a froth spraying system |
US11091602B2 (en) | 2007-03-29 | 2021-08-17 | Arkema Inc. | Blowing agent compositions of carbon dioxide and hydrochlorofluoroolefins |
US9206297B2 (en) | 2007-03-29 | 2015-12-08 | Arkema Inc. | Blowing agent compositions of hydrochlorofluoroolefins |
US8895635B2 (en) | 2007-03-29 | 2014-11-25 | Arkema Inc. | Blowing agent compositions of hydrochlorofluoroolefins |
US11208536B2 (en) | 2007-03-29 | 2021-12-28 | Arkema Inc. | Blowing agent compositions of hydrofluoroolefins and hydrochlorofluoroolefins |
WO2010088320A1 (en) | 2009-01-29 | 2010-08-05 | Arkema Inc. | Tetrafluoropropene based blowing agent compositions |
US20100216903A1 (en) | 2009-02-20 | 2010-08-26 | Bayer Materialscience Llc | Foam-forming system with reduced vapor pressure |
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JPH01103689A (ja) * | 1987-10-15 | 1989-04-20 | Daikin Ind Ltd | 冷媒 |
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DE3824354A1 (de) * | 1988-07-19 | 1990-01-25 | Basf Ag, 67063 Ludwigshafen | Verfahren zur herstellung von zellhaltigen kunststoffen nach dem polyisocyanat-polyadditionsverfahren mittels lagerstabiler, treibmittelhaltiger emulsionen und diese emulsionen |
JPH0347823A (ja) * | 1989-04-07 | 1991-02-28 | Asahi Glass Co Ltd | ポリオール組成物、およびそれを用いた硬質ポリウレタンフォームの製造方法 |
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-
1989
- 1989-05-10 US US07/350,174 patent/US4972003A/en not_active Expired - Lifetime
-
1990
- 1990-05-05 TW TW079103675A patent/TW203620B/zh active
- 1990-05-07 JP JP2115926A patent/JPH037738A/ja active Pending
- 1990-05-08 NZ NZ233595A patent/NZ233595A/xx unknown
- 1990-05-08 BR BR909002194A patent/BR9002194A/pt not_active IP Right Cessation
- 1990-05-08 DD DD90340466A patent/DD297980A5/de unknown
- 1990-05-09 MX MX020647A patent/MX166373B/es unknown
- 1990-05-09 AU AU54826/90A patent/AU622023B2/en not_active Expired
- 1990-05-09 EP EP90108749A patent/EP0398148B1/en not_active Expired - Lifetime
- 1990-05-09 KR KR1019900006514A patent/KR0155948B1/ko not_active IP Right Cessation
- 1990-05-09 NO NO902046A patent/NO179178C/no not_active IP Right Cessation
- 1990-05-09 DK DK90108749T patent/DK0398148T3/da active
- 1990-05-09 AR AR90316810A patent/AR244726A1/es active
- 1990-05-09 CA CA002016328A patent/CA2016328C/en not_active Expired - Lifetime
- 1990-05-09 DE DE69032188T patent/DE69032188T2/de not_active Expired - Lifetime
- 1990-05-09 ES ES90108749T patent/ES2113850T3/es not_active Expired - Lifetime
- 1990-05-09 AT AT90108749T patent/ATE164608T1/de not_active IP Right Cessation
-
1998
- 1998-04-23 GR GR980400902T patent/GR3026714T3/el unknown
-
2002
- 2002-02-04 JP JP2002027192A patent/JP2002234927A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
AR244726A1 (es) | 1993-11-30 |
TW203620B (ko) | 1993-04-11 |
EP0398148B1 (en) | 1998-04-01 |
KR0155948B1 (ko) | 1998-12-01 |
ES2113850T3 (es) | 1998-05-16 |
ATE164608T1 (de) | 1998-04-15 |
CA2016328C (en) | 2000-06-27 |
DE69032188D1 (de) | 1998-05-07 |
DK0398148T3 (da) | 1999-01-11 |
JP2002234927A (ja) | 2002-08-23 |
EP0398148A3 (en) | 1991-03-27 |
BR9002194A (pt) | 1991-08-13 |
NO179178C (no) | 1996-08-21 |
NZ233595A (en) | 1993-04-28 |
DD297980A5 (de) | 1992-01-30 |
EP0398148A2 (en) | 1990-11-22 |
US4972003A (en) | 1990-11-20 |
NO902046L (no) | 1990-11-12 |
NO179178B (no) | 1996-05-13 |
MX166373B (es) | 1993-01-05 |
CA2016328A1 (en) | 1990-11-10 |
NO902046D0 (no) | 1990-05-09 |
AU622023B2 (en) | 1992-03-26 |
AU5482690A (en) | 1990-11-15 |
GR3026714T3 (en) | 1998-07-31 |
DE69032188T2 (de) | 1998-07-30 |
JPH037738A (ja) | 1991-01-14 |
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